JPH0195727A - Production of calcium enriched milk drink - Google Patents

Production of calcium enriched milk drink

Info

Publication number
JPH0195727A
JPH0195727A JP62250680A JP25068087A JPH0195727A JP H0195727 A JPH0195727 A JP H0195727A JP 62250680 A JP62250680 A JP 62250680A JP 25068087 A JP25068087 A JP 25068087A JP H0195727 A JPH0195727 A JP H0195727A
Authority
JP
Japan
Prior art keywords
calcium
complex
milk
maltose
lactose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62250680A
Other languages
Japanese (ja)
Other versions
JPH0824533B2 (en
Inventor
Tadashi Nakatsubo
正 中坪
Tamotsu Kuwata
桑田 有
Michio Kanbe
道雄 神辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Meiji Dairies Corp
Original Assignee
Meiji Milk Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Meiji Milk Products Co Ltd filed Critical Meiji Milk Products Co Ltd
Priority to JP62250680A priority Critical patent/JPH0824533B2/en
Publication of JPH0195727A publication Critical patent/JPH0195727A/en
Publication of JPH0824533B2 publication Critical patent/JPH0824533B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To obtain a calcium enriched milk drink neither forming precipitate caused by reaction of milk protein nor leading to reduction in taste, by adding a complex of calcium hydroxide and maltose or a complex of calcium hydroxide and lactose to a milk drink to enrich calcium of milk drink. CONSTITUTION:Thick malt syrup of maltose is dissolved in water and further calcium hydroxide is dissolved in the solution to give a calcium maltose complex or lactose is dissolved in water and further calcium hydroxide is dissolved to give a calcium lactose complex, which is neutralized and supplied with cow's milk to produce a calcium enriched milk drink.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はカルシウム源として水酸化カルシウムと麦芽糖
の複合体または/および水酸化カルシウムと乳糖の複合
体を使用したカルシウム強化乳飲料の製造方法に関する
ものである。
Detailed Description of the Invention (Industrial Application Field) The present invention relates to a method for producing a calcium-fortified milk beverage using a complex of calcium hydroxide and maltose and/or a complex of calcium hydroxide and lactose as a calcium source. It is something.

本発明においては水酸化カルシウムと麦芽糖の複合体、
水酸化カルシウムと乳糖の複合体を用いてカルシウム強
化を行い、カルシウム塩を添加する場合に起るような異
味感はなく、飲用時の抵抗感なしにカルシウムとして1
00mg%程度まで乳飲料のカルシウム強化ができるの
で、乳飲料界に益するところ大なるものがある。
In the present invention, a complex of calcium hydroxide and maltose,
Calcium is fortified using a complex of calcium hydroxide and lactose, and there is no off-taste that occurs when calcium salts are added.
Since it is possible to fortify milk beverages with calcium up to about 0.00 mg%, there is a great benefit to the dairy beverage industry.

(従来技術) 一般に牛乳には約100mg%のカルシウムが含まれて
おり、牛乳またはこれを利用した各種乳飲料はカルシウ
ム供給源ともいえるものである。しかしながら近年カル
シウムの必要性が呼ばれ、牛乳ですらカルシウムの強化
が要求されるようになった。
(Prior Art) Generally, milk contains about 100 mg% of calcium, and milk or various milk drinks made from milk can be said to be a source of calcium. However, in recent years, the necessity of calcium has been recognized, and even milk has come to be required to be enriched with calcium.

従来、牛乳、乳飲料にカルシウムを強化する場合、その
安定性を保つためりん酸カルシウムや炭酸カルシウムな
ど不溶性かつ乳蛋白質と反応性のないカルシウム塩を添
加して熱殺菌するか、熱殺菌後に可溶性カルシウム塩を
添加するなどして行なわれていた。
Conventionally, when milk and milk drinks are fortified with calcium, in order to maintain their stability, calcium salts that are insoluble and non-reactive with milk proteins, such as calcium phosphate or calcium carbonate, are added and heat sterilized, or soluble calcium salts are added after heat sterilization. This was done by adding calcium salts.

しかし、カルシウム塩の添加ではいずれの方式にしでも
多かれ、少かれ沈澱の生成や風味上の欠点を有し、根本
的な解決がまたれていた。
However, in all methods of adding calcium salts, there are some drawbacks such as the formation of precipitates and flavor problems, and fundamental solutions have not yet been found.

一方では、豆乳のカルシウム強化策として水酸化カルシ
ウムと蔗糖の複合体の使用が開示されている(特開昭6
l−25458)。
On the other hand, the use of a complex of calcium hydroxide and sucrose as a calcium fortification measure for soy milk has been disclosed (Japanese Patent Application Laid-open No. 6
l-25458).

ここで、カルシウム・蔗糖複合体を豆乳に添加すると多
量のカルシウムを豆乳中に含有せしめることができその
上豆乳蛋白質の凝固沈澱や渋味、収れん味といった欠点
も生じないとされているが、本発明者らがカルシウム・
蔗糖複合体の乳飲料への適用を試みたところ、乳蛋白質
の安定性には問題なかったものの味覚上の欠点が新たに
認められた。すなわち牛乳中にカルシウム換算量で10
0mg%添加した場合、該複合体に由来する蔗糖は乳飲
料の1%もの濃度となり乳飲料としては甘味過剰になり
飲用に耐えないものとなったのである。
It is said that if a calcium-sucrose complex is added to soymilk, a large amount of calcium can be contained in the soymilk, and there will be no disadvantages such as coagulation and precipitation of soymilk proteins, astringency, or astringency. The inventors discovered that calcium
When trying to apply the sucrose complex to milk drinks, although there were no problems with the stability of milk proteins, new taste defects were discovered. In other words, the amount of calcium in milk is 10
When 0 mg% of the sucrose was added, the concentration of sucrose derived from the complex was as high as 1% of the milk drink, making it too sweet for a milk drink to be drinkable.

(問題点を解決するための手段) 本発明者らは、乳蛋白質と無反応かつ、呈味性にも問題
のない水溶性の乳飲料用カルシウム強化剤を求めて鋭意
研究したところ、水酸化カルシウムと麦芽糖の複合体と
水酸化カルシウムと乳糖の複合体を見出し、これら問題
点を解決することができた。
(Means for Solving the Problems) The present inventors conducted extensive research in search of a water-soluble calcium fortifier for milk drinks that does not react with milk proteins and has no problems with taste, and found that hydroxylation We discovered a complex of calcium and maltose and a complex of calcium hydroxide and lactose, and were able to solve these problems.

即ち、水酸化カルシウムと麦芽糖もしくは乳糖の複合体
がそれ自体甘味が少なく、カルシウム換算量で100m
g%までの添加であればほとんど問題はなく、かつ、乳
蛋白質の凝固も認められないこと、また、驚くべきこと
には麦芽糖複合体は他の複合体に比較してカルシウム含
量が2倍と多く、同一カルシウム含有を得るための複合
体の量は他の複合体の半量で足りることなどを見出した
ものである。
In other words, the complex of calcium hydroxide and maltose or lactose itself has little sweetness, and the amount of calcium equivalent to 100 m
There is almost no problem when added up to g%, and no coagulation of milk protein is observed.Also, surprisingly, the maltose complex has twice the calcium content compared to other complexes. In many cases, it has been discovered that half the amount of other complexes is sufficient to obtain the same calcium content.

本発明は水酸化カルシウムと麦芽糖の複合体または/お
よび水酸化カルシウムと乳糖の複合体を乳飲料に存在せ
しめることを特徴とするカルシウム強化乳飲料の製造方
法である。
The present invention is a method for producing a calcium-enriched milk beverage, which is characterized in that a complex of calcium hydroxide and maltose and/or a complex of calcium hydroxide and lactose is present in the milk beverage.

また、本発明においては、水酸化カルシウムと麦芽糖の
複合体または/および水酸化カルシウムと乳糖の複合体
の乳飲料における存在量がカルシウム換算量として20
〜100mg%であるのが好まし11.1 本発明においては、まず、水酸化カルシウムと麦芽糖の
複合体及び水酸化カルシウムと乳糖の複合体が製造され
る。
Further, in the present invention, the amount of the complex of calcium hydroxide and maltose and/or the complex of calcium hydroxide and lactose in the milk drink is 20% as calcium equivalent amount.
Preferably, the content is 100 mg% to 100 mg%.11.1 In the present invention, first, a complex of calcium hydroxide and maltose and a complex of calcium hydroxide and lactose are produced.

水酸化カルシウムと麦芽糖の複合体を製造するには、含
水率15%の麦芽糖水飴を40%(重量%)の濃度にな
るように水と溶解し、激しく攪拌しつつ麦芽糖の43%
量の水酸化カルシウムを徐々に添加して溶解させ、カル
シウム・麦芽糖複合体を生成させる。
To produce a complex of calcium hydroxide and maltose, maltose syrup with a water content of 15% is dissolved in water to a concentration of 40% (weight%), and while vigorously stirring, maltose syrup containing 43% of maltose is dissolved.
A quantity of calcium hydroxide is gradually added and dissolved to form a calcium-maltose complex.

また、水酸化カルシウムと乳糖の複合体を製造するには
、乳糖を17%(重量%)の濃度になるように水に溶解
し、激しく攪拌しつつ乳糖の22%量の水酸化カルシウ
ムを徐々に添加して溶解させ、カルシウム・乳糖複合体
を生成させる。
In addition, to produce a complex of calcium hydroxide and lactose, lactose is dissolved in water to a concentration of 17% (wt%), and while stirring vigorously, calcium hydroxide in an amount of 22% of the lactose is gradually added. and dissolve it to generate a calcium-lactose complex.

ここに得られた水酸化カルシウムと麦芽糖の複合体また
は/および水酸化カルシウムと乳糖の複合体は溶液状の
まま又は濃縮し、更には乾燥して牛乳その他の乳飲料に
添加される。
The complex of calcium hydroxide and maltose and/or complex of calcium hydroxide and lactose obtained here is added to milk or other milk beverages in a solution state or after being concentrated and further dried.

添加に際しては、アルカリ側への急激な傾斜による蛋白
質の変性を避ける意味で、添加は攪拌しつつ徐々に行い
添加終了後直ちにクエン酸にて中和しPH6,9〜7.
2とする。しかるのち130℃〜140°Cの瞬間殺菌
を行い製品とする。
At the time of addition, in order to avoid denaturation of the protein due to a sharp inclination toward the alkaline side, the addition is done gradually while stirring, and immediately after the addition is completed, it is neutralized with citric acid to a pH of 6,9 to 7.
Set it to 2. Thereafter, the product is instantaneously sterilized at 130°C to 140°C.

水酸化カルシウムと麦芽糖の複合体または/および水酸
化カルシウムと乳糖の複合体の牛乳等の乳飲料への添加
量は、乳飲料における存在量でカルシウム換算量として
20〜100mg%程度が好ましい。20mg%以下で
はカルシウム強化の意味から好ましくなく、また、10
0mg% を超えると蛋白質が不安定になったり、味覚
の変化をまねいたりすることがあって好ましくない。
The amount of the complex of calcium hydroxide and maltose and/or the complex of calcium hydroxide and lactose added to a milk drink such as milk is preferably about 20 to 100 mg% in terms of calcium equivalent amount in the milk drink. If it is less than 20 mg%, it is not preferable from the point of view of calcium reinforcement;
If it exceeds 0 mg%, the protein may become unstable or the taste may change, which is not preferable.

次に本発明の実施例を示す。Next, examples of the present invention will be shown.

実施例1 カルシウム・麦芽糖複合体によりカルシウムを50mg
%強化した牛乳50Qを試作した。
Example 1 Calcium 50mg by calcium maltose complex
We made a prototype of 50Q% fortified milk.

まず、含水率15%の麦芽糖水飴126gを水140g
に攪拌しつつ室温にて溶解し、のち攪拌を強め水酸化カ
ルシウム46gを徐々に加えて溶解、カルシウム・麦芽
糖複合体とした。
First, add 126g of maltose syrup with a water content of 15% to 140g of water.
The mixture was dissolved at room temperature with stirring, and then the stirring was strengthened and 46 g of calcium hydroxide was gradually added and dissolved to obtain a calcium/maltose complex.

均質化処理を経た牛乳45Qを攪拌しつつこれに前記カ
ルシウム・麦芽糖複合体液全量312gを徐々に加えた
のち、攪拌を続行し水50gとクエン酸80gよりなる
酸液の全量を徐々に添加してpH7,0に中和し、牛乳
を補充、最終511とした。しかるのち、130℃、2
秒の瞬間殺菌を行い、カルシウム強化牛乳とした。
While stirring the homogenized milk 45Q, the total amount of the calcium/maltose complex liquid (312 g) was gradually added thereto, and then, while stirring was continued, the total amount of the acid solution consisting of 50 g of water and 80 g of citric acid was gradually added. It was neutralized to pH 7.0 and supplemented with milk to give a final pH of 511. After that, 130℃, 2
The milk was instantaneously sterilized for a few seconds and made into calcium-fortified milk.

得られたカルシウム強化牛乳は、凝固もなく、対照とし
た牛乳とほぼ同等の風味を有していた。
The obtained calcium-fortified milk had no curdling and had almost the same flavor as the control milk.

実施例2 カルシウム・乳糖複合体によりカルシウムを100m%
強化した牛乳50Ωを試作した。
Example 2 Calcium 100m% by calcium-lactose complex
We made a prototype of fortified milk 50Ω.

乳糖423gを水2.07kgに攪拌しつつ室温にて溶
解し、のち攪拌を強め水酸化カルシウム93gを徐々に
加えて溶解、カルシウム・乳糖複合体液とした。
423 g of lactose was dissolved in 2.07 kg of water at room temperature with stirring, and then the stirring was strengthened and 93 g of calcium hydroxide was gradually added and dissolved to obtain a calcium-lactose complex liquid.

均質化処理孔4(IQを攪拌し、これに前記カルシウム
・糖複合体の全量を徐々に加えた。添加終了後水液を攪
拌しつつ、これにクエン酸160gと水100gよりな
る酸液の全量を徐々に加えてpH7,0に中和、牛乳を
補充して最終50flとした。のち、130℃、2秒の
瞬間殺菌を行い、カルシウム強化牛乳とした。 得られ
たカルシウム強化牛乳は、凝固もなく、風味はカルシウ
ム非強化の牛乳とほとんど変らなかった。
Homogenization treatment hole 4 (IQ) was stirred and the entire amount of the calcium-sugar complex was gradually added thereto. After the addition was completed, an acid solution consisting of 160 g of citric acid and 100 g of water was added to the aqueous solution while stirring the aqueous solution. The entire amount was gradually added to neutralize the pH to 7.0, and milk was added to make a final volume of 50 fl.Later, instant sterilization was carried out at 130°C for 2 seconds to obtain calcium-fortified milk.The obtained calcium-fortified milk was There was no curdling and the flavor was almost the same as non-calcium fortified milk.

実施例3 カルシウム・麦芽糖複合体によりカルシウムを100m
g%強化した牛乳50Qを試作した。
Example 3 Calcium 100m by calcium maltose complex
A prototype of milk 50Q fortified with g% was produced.

実施例1で示した麦芽糖水飴252gを水280gに溶
解し、急激な攪拌を行いつつ水酸化カルシウム92gを
徐々に加えてカルシウム・麦芽糖複合体を形成せしめた
252 g of the maltose starch syrup shown in Example 1 was dissolved in 280 g of water, and 92 g of calcium hydroxide was gradually added with rapid stirring to form a calcium-maltose complex.

均質化処理孔45ρを攪拌しつつこれに前記カルシウム
・麦芽糖複合体液全量を徐々に添加したのち、クエン酸
160gと水100gよりなる酸液の全量を徐々に加え
てpH7,0に中和、牛乳を補充して最終50Qとした
。しかるのち130℃、2秒の殺菌を行い、カルシウム
強化牛乳とした。
After gradually adding the entire amount of the calcium-maltose complex liquid to the homogenization treatment hole 45ρ while stirring, the entire amount of the acid solution consisting of 160 g of citric acid and 100 g of water was gradually added to neutralize the pH to 7.0, and the milk was was supplemented to make the final 50Q. The milk was then sterilized at 130°C for 2 seconds to produce calcium-fortified milk.

得られたカルシウム強化牛乳は物性、風味において対照
とした牛乳に何ら劣ることはなかった。
The obtained calcium-fortified milk was not inferior to the control milk in terms of physical properties and flavor.

=7− 手続補正書 昭和62年11月11日=7- Procedural amendment November 11, 1986

Claims (2)

【特許請求の範囲】[Claims] (1)水酸化カルシウムと麦芽糖の複合体または/およ
び水酸化カルシウムと乳糖の複合体を乳飲料に存在せし
めることを特徴とするカルシウム強化乳飲料の製造方法
(1) A method for producing a calcium-enriched milk drink, which comprises making a complex of calcium hydroxide and maltose or/and a complex of calcium hydroxide and lactose exist in the milk drink.
(2)水酸化カルシウムと麦芽糖の複合体または/およ
び水酸化カルシウムと乳糖の複合体の乳飲料における存
在量がカルシウム換算量として20〜100mg%であ
ることを特徴とする特許請求の範囲第1項記載のカルシ
ウム強化乳飲料の製造方法。
(2) Claim 1, characterized in that the amount of the complex of calcium hydroxide and maltose and/or the complex of calcium hydroxide and lactose in the milk drink is 20 to 100 mg% in terms of calcium. A method for producing a calcium-fortified milk beverage as described in Section 1.
JP62250680A 1987-10-06 1987-10-06 Method for producing calcium-fortified milk drink Expired - Lifetime JPH0824533B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62250680A JPH0824533B2 (en) 1987-10-06 1987-10-06 Method for producing calcium-fortified milk drink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62250680A JPH0824533B2 (en) 1987-10-06 1987-10-06 Method for producing calcium-fortified milk drink

Publications (2)

Publication Number Publication Date
JPH0195727A true JPH0195727A (en) 1989-04-13
JPH0824533B2 JPH0824533B2 (en) 1996-03-13

Family

ID=17211448

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62250680A Expired - Lifetime JPH0824533B2 (en) 1987-10-06 1987-10-06 Method for producing calcium-fortified milk drink

Country Status (1)

Country Link
JP (1) JPH0824533B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5181208A (en) * 1988-07-18 1993-01-19 Robert Bosch Gmbh Computation-conserving traffic data transmission method and apparatus

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6125458A (en) * 1984-07-13 1986-02-04 Meiji Milk Prod Co Ltd Preparation of calcium-enriched soybean milk

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6125458A (en) * 1984-07-13 1986-02-04 Meiji Milk Prod Co Ltd Preparation of calcium-enriched soybean milk

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5181208A (en) * 1988-07-18 1993-01-19 Robert Bosch Gmbh Computation-conserving traffic data transmission method and apparatus

Also Published As

Publication number Publication date
JPH0824533B2 (en) 1996-03-13

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