JPH0149427B2 - - Google Patents
Info
- Publication number
- JPH0149427B2 JPH0149427B2 JP60041305A JP4130585A JPH0149427B2 JP H0149427 B2 JPH0149427 B2 JP H0149427B2 JP 60041305 A JP60041305 A JP 60041305A JP 4130585 A JP4130585 A JP 4130585A JP H0149427 B2 JPH0149427 B2 JP H0149427B2
- Authority
- JP
- Japan
- Prior art keywords
- printing
- printing ink
- solvent
- present
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007639 printing Methods 0.000 claims description 138
- 239000000976 ink Substances 0.000 claims description 91
- 150000001875 compounds Chemical class 0.000 claims description 28
- 239000002904 solvent Substances 0.000 claims description 15
- 239000002966 varnish Substances 0.000 claims description 12
- -1 vinyl compound Chemical class 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 150000007824 aliphatic compounds Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000001035 drying Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
- 238000003860 storage Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 5
- 239000002250 absorbent Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- KHAVLLBUVKBTBG-UHFFFAOYSA-N dec-9-enoic acid Chemical compound OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 235000010187 litholrubine BK Nutrition 0.000 description 2
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- JXNPEDYJTDQORS-HZJYTTRNSA-N (9Z,12Z)-octadecadien-1-ol Chemical compound CCCCC\C=C/C\C=C/CCCCCCCCO JXNPEDYJTDQORS-HZJYTTRNSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- CQKHFONAFZDDKV-VAWYXSNFSA-N (e)-dodec-1-en-1-ol Chemical compound CCCCCCCCCC\C=C\O CQKHFONAFZDDKV-VAWYXSNFSA-N 0.000 description 1
- JHEPBQHNVNUAFL-AATRIKPKSA-N (e)-hex-1-en-1-ol Chemical compound CCCC\C=C\O JHEPBQHNVNUAFL-AATRIKPKSA-N 0.000 description 1
- GWSURTDMLUFMJH-FOCLMDBBSA-N (e)-hexadec-1-en-1-ol Chemical compound CCCCCCCCCCCCCC\C=C\O GWSURTDMLUFMJH-FOCLMDBBSA-N 0.000 description 1
- NSOAQRMLVFRWIT-UHFFFAOYSA-N 1-ethenoxydecane Chemical compound CCCCCCCCCCOC=C NSOAQRMLVFRWIT-UHFFFAOYSA-N 0.000 description 1
- LAYAKLSFVAPMEL-UHFFFAOYSA-N 1-ethenoxydodecane Chemical compound CCCCCCCCCCCCOC=C LAYAKLSFVAPMEL-UHFFFAOYSA-N 0.000 description 1
- SWZSKZZXXULJHU-UHFFFAOYSA-N 1-ethenoxyheptane Chemical compound CCCCCCCOC=C SWZSKZZXXULJHU-UHFFFAOYSA-N 0.000 description 1
- YAOJJEJGPZRYJF-UHFFFAOYSA-N 1-ethenoxyhexane Chemical compound CCCCCCOC=C YAOJJEJGPZRYJF-UHFFFAOYSA-N 0.000 description 1
- MIMKRVLJPMYKID-UHFFFAOYSA-N 1-ethenoxynonane Chemical compound CCCCCCCCCOC=C MIMKRVLJPMYKID-UHFFFAOYSA-N 0.000 description 1
- QJJDJWUCRAPCOL-UHFFFAOYSA-N 1-ethenoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOC=C QJJDJWUCRAPCOL-UHFFFAOYSA-N 0.000 description 1
- XXCVIFJHBFNFBO-UHFFFAOYSA-N 1-ethenoxyoctane Chemical compound CCCCCCCCOC=C XXCVIFJHBFNFBO-UHFFFAOYSA-N 0.000 description 1
- LPYHXIHXJREIMY-UHFFFAOYSA-N 1-ethenoxytetradecane Chemical compound CCCCCCCCCCCCCCOC=C LPYHXIHXJREIMY-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- RCSBILYQLVXLJG-UHFFFAOYSA-N 2-Propenyl hexanoate Chemical compound CCCCCC(=O)OCC=C RCSBILYQLVXLJG-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- DKGXIVRSAKPDHF-UHFFFAOYSA-N 6-chloro-3-methyl-1-phenylpyrimidine-2,4-dione Chemical compound O=C1N(C)C(=O)C=C(Cl)N1C1=CC=CC=C1 DKGXIVRSAKPDHF-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011981 development test Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- LPUZTLKYAOOFDX-QXMHVHEDSA-N ethenyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC=C LPUZTLKYAOOFDX-QXMHVHEDSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- LZWYWAIOTBEZFN-UHFFFAOYSA-N ethenyl hexanoate Chemical compound CCCCCC(=O)OC=C LZWYWAIOTBEZFN-UHFFFAOYSA-N 0.000 description 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
- QBDADGJLZNIRFQ-UHFFFAOYSA-N ethenyl octanoate Chemical compound CCCCCCCC(=O)OC=C QBDADGJLZNIRFQ-UHFFFAOYSA-N 0.000 description 1
- ZQZUENMXBZVXIZ-UHFFFAOYSA-N ethenyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OC=C ZQZUENMXBZVXIZ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- JXNPEDYJTDQORS-UHFFFAOYSA-N linoleyl alcohol Natural products CCCCCC=CCC=CCCCCCCCCO JXNPEDYJTDQORS-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- NIMAFSFVBYEOTB-UHFFFAOYSA-N n,n'-ditert-butylpropane-1,3-diamine Chemical compound CC(C)(C)NCCCNC(C)(C)C NIMAFSFVBYEOTB-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- NHLUYCJZUXOUBX-UHFFFAOYSA-N nonadec-1-ene Chemical compound CCCCCCCCCCCCCCCCCC=C NHLUYCJZUXOUBX-UHFFFAOYSA-N 0.000 description 1
- UVMYOBBALQKLKK-UHFFFAOYSA-N nonadecene Natural products CCCCCCCCCCCC=CCCCCCC UVMYOBBALQKLKK-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- DQVOTEHORLHPRW-UHFFFAOYSA-N prop-2-enyl decanoate Chemical compound CCCCCCCCCC(=O)OCC=C DQVOTEHORLHPRW-UHFFFAOYSA-N 0.000 description 1
- HPCIWDZYMSZAEZ-UHFFFAOYSA-N prop-2-enyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC=C HPCIWDZYMSZAEZ-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- VQOXUMQBYILCKR-UHFFFAOYSA-N tridecaene Natural products CCCCCCCCCCCC=C VQOXUMQBYILCKR-UHFFFAOYSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
（産業上の利用分野）
本発明は、印刷インキに関し、更に詳しく云え
ば、特に紙等の吸収性被印刷材の印刷に適し、且
つ優れた印刷作業性を与える印刷インキに関す
る。
（従来の技術）
従来、各種の被印刷材に図柄を与えるために
種々の印刷インキが知られている。
例えば、プラスチツクフイルム、金属、ガラス
等の非吸収性被印刷材の印刷に対しては、含有す
る溶剤の蒸発によつて乾燥する溶剤蒸発型の印刷
インキが使用され、また紙を代表とする吸収性被
印刷材に対しては、含有する溶剤が吸収されて乾
燥する印刷インキ、例えば、平版印刷インキ、凹
版印刷インキ、凸版印刷インキ、シルクスクリー
ン印刷インキ等が知られている。
（発明が解決しようとしている問題点）
上述の如き各種の印刷インキは、いずれもそれ
ぞれの印刷形式に応じた印刷版の表面に薄膜のイ
ンキを付与し、付与されたインキを被印刷材に転
写し、溶剤の蒸発、溶剤の吸収、ワニスの酸化重
合等によつて乾燥させて印刷インキをセツトする
ものである。
従つて、これらの印刷インキは、転写後は速や
かに乾燥するのが好ましく、そのように工夫され
ているが、一方では印刷インキの保存中あるいは
印刷中は、これらの印刷インキがなるべく乾燥し
ないことが要求される。これらの相反する要求を
調整すべく、その乾燥性がコントロールされてい
る。
しかしながら、従来の印刷操作は、なかには長
時間連続して行なわれるものもあるが、大部分
は、時々中断される場合が多く、例えば、一日の
作業が終了すると、その後は翌朝の作業まで放置
されることになる。このような場合においては印
刷インキは上述の如き適度の乾燥性が付与されて
いるため、中断時に印刷機の印刷版やブランケツ
トには付着している印刷インキ層がその中断中に
機上で乾燥することになる。
このように機上で乾燥すると、そのままでは次
回の印刷開始時に満足できる印刷が行なえないた
めに、印刷の中断後は直ちに印刷インキを取除く
か、あるいは印刷の開始前に付着した印刷インキ
を取除くことが必要となる。
このような作業は、例えば１〜２時間の時間を
要求されるため、その間は印刷ができず、またそ
の作業に人員を要するため、工業上非常に不経済
な事態となつている。
従つて、印刷インキの保存中、印刷前の準備段
階あるいは印刷中断時に印刷機上で乾燥せず、そ
れにも係わらず、印刷後の被印刷材上では十分な
乾燥速度を有する印刷インキが理想であり、且つ
そのような印刷インキが強く要求されている。こ
れらの要求は、相反する要求であるため、従来は
上記の如き特性を有する印刷インキは提供し得な
かつた。
本発明者は上述の如き従来技術の欠点を解決
し、上述の業界の要望に応えるべく鋭意研究の結
果、従来の印刷インキ、特に重合型の印刷インキ
に、特定の化合物を添加するときは、保存中や印
刷機上では非常に乾燥が遅く、従つて印刷操作
を、例えば夜間中断したとしても、その印刷機上
では印刷インキが乾燥しないため、次の印刷開始
時に印刷機の機掃が不要で直ちに印刷が開始で
き、それにも係わらず被印刷材上では付与された
印刷インキの乾燥が十分に速いインキが得られる
ことを知見して本発明を完成した。
すなわち、本発明は、着色剤、ワニスおよび溶
剤からなる印刷インキに、溶剤可溶性の重合性化
合物を添加したことを特徴とする印刷インキであ
る。
次に本発明を更に詳細に説明すると、本発明の
印刷インキを構成する着色剤は、従来の印刷イン
キに使用されている顔料あるいは染料であつて、
従来公知の顔料あるいは染料は本発明の印刷イン
キの着色剤としていずれもそのまま使用できるも
のである。また、その使用量も従来公知の印刷イ
ンキと同様でよく、例えば、印刷インキ100重量
部中で、例えば約10〜40重量部を占める割合が一
般的である。
また、本発明の印刷インキを構成するワニス
も、従来公知の印刷インキ用ワニスはいずれも本
発明においてそのまま使用できるものであり、そ
の使用量も従来と同様に、例えば印刷インキ100
重量部中で約50〜80重量部を占める割合が一般的
である。
本発明の印刷インキのワニスとして好ましいも
のは、従来の平版印刷インキ等に使用されている
天然または合成の酸化重合型樹脂、すなわちそれ
らの構造中に重合性二重結合を有し、空気中の酸
素によつて重合硬化して被膜を構成するものであ
る。これらの平版印刷インキ用のワニスは、多数
のものが公知であり、本発明においてはこれら公
知のものがいずれも使用し得る。
本発明の印刷インキを構成する溶剤は、インキ
の粘度、稠度、フロー等を修正をするために加え
られるものであり、印刷インキ用として従来使用
されている各種の有機溶剤はいずれも使用し得る
ものであり、その使用量は、印刷インキ100重量
部中で約５〜80重量部を占める割合が一般的であ
る。またこのような溶剤は、下記の特定の重合性
化合物で全部または１部を置換することもでき
る。
本発明で使用し、主として本発明を特徴づける
溶剤可溶性の重合性化合物は、印刷インキが空気
に接触したり、熱によつて印刷インキ中に生じた
重合開始ラジカルに作用して、それらの開始ラジ
カルあるいは成長ラジカルの作用を消滅あるいは
弱化させる作用をするものである。
このような作用を有する従来公知の溶剤可溶性
の重合性化合物は、いずれも本発明において使用
できるものであるが、本発明において特に好適な
ものは常態で液状であり、且つ常態では不揮発性
〜難揮発性の重合性化合物である。
これらの重合性化合物が常態で液状または溶剤
可溶性でないときは、印刷機上での印刷インキの
乾燥が速くなり、また揮発性であると作業上衛生
の点で問題があり、また印刷機上での印刷インキ
の早すぎる乾燥を抑えることが困難となる。
本発明では、上記の如き重合性化合物を印刷イ
ンキ中に添加するときは、印刷インキの保存中あ
るいは印刷機上では、印刷インキにこれらの重合
性化合物が存在し、且つこれらの重合性化合物は
揮発性でないために、印刷インキの重合すなわち
乾燥が遅れ、従つて前述の如き従来技術の問題点
が解決されたものである。
更に、本発明の印刷インキが被印刷材に付与さ
れると、特に被印刷材が紙の如き吸収性の被印刷
材であるときは、印刷インキ中の溶剤および該溶
剤中に溶解している上記の重合性化合物が、被印
刷材中に速やかに吸収されるため、被印刷材上に
残つた着色剤とワニスからなる成分は、従来の印
刷インキと同様に速やかに乾燥することを知見
し、本発明の目的が完全に達成されたものであ
る。
従つて、本発明の印刷インキは、特に紙の如き
吸収性の被印刷材の印刷、例えば平版印刷用のイ
ンキとして有用である。
また、上記の如き溶剤可溶性の重合性化合物
は、本発明の印刷インキの溶剤の代りに使用して
もよいし、また溶剤の１部としても使用できるも
のであるが、あまりに多量に使用するのは経済的
ではなく、また印刷後の乾燥を過度に遅らせるこ
とがあり、また使用量が少なすぎるときは、本発
明の効果が十分に達成できない。
本発明者の詳細な研究によれば、本発明で使用
する上記の如き溶剤可溶性の重合性化合物は印刷
インキ100重量部中で一般的には約２〜60重量部
を占める割合、より好ましくは約５〜40重量部を
占める割合であり、このような使用割合において
本発明の目的が十分に達成することができる。
本発明で使用する上記の如き作用をする溶剤可
溶性の重合性化合物について、更に具体的に説明
すれば、このような溶剤可溶性の重合性化合物
は、その構造中に少なくとも１個の重合性二重結
合を有する化合物であり、好ましい具体例により
例示すれば、第１の群として中〜高級の不飽和脂
肪酸またはその各種誘導体、例えばエステルが挙
げられ、好適なものとして、カプロレイン酸、ウ
ンデシレン酸、エライジン酸、オレイン酸、リノ
ール酸、リノレン酸、リシノール酸、等の脂肪
酸、これらのメチル、エチル、プロピル、ブチ
ル、ヘプチル、ヘキシル、オクチル、ベンジルエ
ステル等のアルコールエステル、エチレングリコ
ール、グリセリン等の多価アルコールのモノ〜ト
リエステル等が挙げられる。
第２群のものとして、炭素数が約６〜30の脂肪
族炭化水素が挙げられ、好適なものとしては、ノ
ネン、デセン、ウンデセン、トリデセン、テトラ
デセン、ヘキサデセン、オクタデセン、ノナデセ
ン、ドコデセン等のオレフイン、ヘキセノール、
ヘプチノール、ドデセノール、ヘキサデセノー
ル、オレイルアルコール、リノレイルアルコー
ル、リシノレイルアルコール等の不飽和アルコー
ルまたはこれらの各種エステルが挙げられる。
第３群のものとしては、各種のビニル化合物が
挙げられ、好ましいものとしては、C4〜C20のア
ルキル基を有するスチレンあるいはそれらの誘導
体、ビニルヘキシルエーテル、ビニルヘプチルエ
ーテル、ビニルオクチルエーテル、ビニルノニル
エーテル、ビニルデシルエーテル、ビニルラウリ
ルエーテル、ビニルミリスチルエーテル、ビニル
ステアリルエーテル等、ビニルオレイルエーテ
ル、（メタ）アクリル酸ヘキシル、（メタ）アクリ
ル酸シクロヘキシル、（メタ）アクリル酸ヘプチ
ル、（メタ）アクリル酸オクチル、（メタ）アクリ
ル酸―２―エチルヘキシル、（メタ）アクリル酸
ノニル、（メタ）アクリル酸デシル、（メタ）アク
リル酸ドデシル、（メタ）アクリル酸テトラデシ
ル、（メタ）アクリル酸ヘキサデシル等の（メタ）
アクリル酸エステル、カプロン酸ビニル、カプリ
ル酸ビニル、ラウリン酸ビニル、ミリスチン酸ビ
ニル、ステアリン酸ビニル、オレイン酸ビニル等
のビニルエステル、カプリン酸アリル、カプロン
酸アリル、ミリスチン酸アリル、ステアリン酸ア
リル等のアリルエステル等が挙げられる。
以上の如き溶剤可溶性の重合性化合物は、上述
の通り、ある程度以上の分子量、すなわち、常温
で不揮発性〜難揮発性である程度の分子量を有す
る一方、ワニスの如き高分子量を有さないことが
好適である。分子量の低すぎるときは、揮発によ
り印刷機上での早すぎる乾燥を抑えられず、また
分子量が高すぎると、この溶剤可溶性の重合性化
合物自体が不溶性の被膜を形成し、同様に早すぎ
る乾燥を抑えることができない。以上の例示は、
本発明を説明するためのものであつて、上記以外
の溶剤可溶性の重合性化合物であつても、上記と
同様な機能を有するものは本発明に当然包含され
るものである。
本発明の印刷インキは、上記の如き成分を必須
成分とするが、その他必要に応じて、従来の印刷
インキに通常使用される各種の添加剤は、いずれ
も本発明の印刷インキに同様に使用し得るもので
ある。
本発明の印刷インキは、前記の如き溶剤可溶性
の重合性化合物を印刷インキに添加する外は、そ
の製造は従来公知の製造方法は、例えばロールに
よる混合練肉等がいずれも使用できる。
（作用・効果）
以上の如き本発明のよれば、すでに述べた通
り、印刷インキ中に特定の溶剤可溶性の重合性化
合物を適当な量で添加することによつて、印刷イ
ンキの保存中あるいは印刷機上での印刷インキの
早すぎる乾燥を防止できるため、印刷操作を中断
し、かなりの時間が経過しても、印刷機上の印刷
インキは実質的にそのままで未乾燥であるから、
次の印刷開始時に何らの機掃や特別の準備操作を
要しないで直ちに印刷を開始ができる。従つて、
従来技術における印刷機の手数がかかり不経済な
機掃や印刷安定化までの不経済なならし運転等の
種々の問題点が解決された。それにも係わらず、
特に吸収性の被印刷材に印刷後の印刷インキの速
やかな乾燥は何ら阻害されないものである。
次に実施例および比較例を挙げて本発明を更に
具体的に説明する。なお、文中、部とあるのは重
量基準である。
実施例 １
酸化重合型ワニス225部とトール油脂肪酸ベン
ジルエステル（溶剤可溶性の重合性化合物）70部
とを混合し、該混合物64.1部、ブリリアントカー
ミン6B20部、ナフテン酸マンガン0.8部および日
石５号ソルベント15.1部を配合し、三本ロールで
混合練肉し、タツク値が9.2の本発明の印刷イン
キを得た。
この印刷インキ0.15mlを４分割RIテスターでア
ート紙に展色した。そのアート紙の展色面の光沢
を測定したところ73％であつた。一方、上記印刷
インキをRIテスター上に一夜放置した後同様に
展色したものの光沢は46％であり、印刷インキの
優れた保存安定性を示した、なお、アート紙上で
の印刷インキの乾燥時間は４時間であつた。ま
た、上記の印刷インキテストを行つた後、印刷機
を何ら洗浄することなく一夜放置し、翌朝再度印
刷を試みたところ、何らの支障もなくそのまま印
刷が可能であつた。
比較例 １
酸化重合型ワニス225部と日石５号ソルベント
70部とを混合し、この混合物65.3部、ブリリアン
トカーミン6B20部、ナフテン酸マンガン0.8部お
よび日石５号ソルベント13.9部を三本ロールで混
合練肉し、タツク値が9.1である比較用の印刷イ
ンキを得た。
このインキについて実施例１と同様にして展色
試験を行つたところ、光沢は74％であるに対し、
RIテスター上に一夜放置した場合の光沢は19％
であり、印刷インキの保存安定性が不十分である
ことを示した。また、アート紙上での印刷インキ
の乾燥時間は４時間であつた。
また、印刷試験後一夜放置後の再印刷では、印
刷版面のインキが乾燥し不溶性の膜を生じ、印刷
インキの転移不良を生じ、そのままでは再印刷が
不能であつた。
実施例 ２〜７
実施例１の重合性化合物に代えて、下記第１表
に示す他の重合性化合物を用い、他は実施例１と
同様にして印刷インキを調製し、同様にテストし
たところ、下記第１表の結果を得た。
(Industrial Application Field) The present invention relates to a printing ink, and more specifically, to a printing ink that is particularly suitable for printing on absorbent printing materials such as paper and provides excellent printing workability. (Prior Art) Conventionally, various printing inks have been known for imparting designs to various printing materials. For example, for printing on non-absorbent printing materials such as plastic film, metal, and glass, solvent evaporation printing inks are used, which dry by evaporation of the solvent they contain; Printing inks that dry by absorbing the solvent they contain, such as lithographic printing inks, intaglio printing inks, letterpress printing inks, and silk screen printing inks, are known for printing on flexible printing materials. (Problems to be Solved by the Invention) The various printing inks mentioned above apply a thin film of ink to the surface of a printing plate according to each printing format, and then transfer the applied ink to the printing material. The printing ink is then dried by evaporation of the solvent, absorption of the solvent, oxidative polymerization of the varnish, etc. to set the printing ink. Therefore, it is preferable that these printing inks dry quickly after transfer, and measures have been taken to do so, but on the other hand, it is desirable to prevent these printing inks from drying as much as possible during storage or printing. is required. In order to adjust these conflicting demands, the drying properties are controlled. However, while some traditional printing operations may be continuous for long periods of time, most are often interrupted from time to time, such as when a day's work is finished and then left until the next morning's work. will be done. In such cases, the printing ink is given appropriate drying properties as described above, so the printing ink layer adhering to the printing plate or blanket of the printing press during the interruption dries on the press during the interruption. I will do it. If it dries on the machine in this way, you will not be able to print satisfactorily the next time you start printing, so either remove the printing ink immediately after printing is interrupted, or remove the adhering printing ink before printing starts. It is necessary to remove it. Such work requires, for example, 1 to 2 hours, during which time printing cannot be performed, and the work requires manpower, making it extremely uneconomical from an industrial standpoint. Therefore, it is ideal to have a printing ink that does not dry out on the printing press during storage, during pre-printing preparations or during printing interruptions, but which nevertheless has a sufficient drying speed on the printing substrate after printing. Yes, and there is a strong demand for such printing inks. Since these requirements are contradictory, it has not been possible to provide a printing ink having the above-mentioned characteristics in the past. The inventor of the present invention solved the above-mentioned drawbacks of the conventional technology and, as a result of intensive research in order to meet the above-mentioned demands of the industry, found that when adding a specific compound to a conventional printing ink, especially a polymeric printing ink, Drying is very slow during storage or on the printing press. Therefore, even if printing operations are interrupted, for example at night, the printing ink will not dry on the printing press, so there is no need to clean the printing press when the next printing starts. The present invention was completed based on the finding that an ink can be obtained that allows printing to be started immediately and, despite this, the applied printing ink dries sufficiently quickly on the printing material. That is, the present invention is a printing ink characterized by adding a solvent-soluble polymerizable compound to a printing ink consisting of a colorant, a varnish, and a solvent. Next, to explain the present invention in more detail, the colorant constituting the printing ink of the present invention is a pigment or dye used in conventional printing inks, and
Any conventionally known pigment or dye can be used as it is as a coloring agent in the printing ink of the present invention. Further, the amount used may be the same as that of conventionally known printing inks, and for example, the amount used is generally about 10 to 40 parts by weight in 100 parts by weight of printing ink. Further, as for the varnish constituting the printing ink of the present invention, any conventionally known printing ink varnish can be used as is in the present invention, and the amount used is the same as before, for example, 100% of the printing ink.
It generally accounts for about 50 to 80 parts by weight. Preferable varnishes for the printing ink of the present invention are natural or synthetic oxidation-polymerizable resins used in conventional lithographic printing inks, that is, those having polymerizable double bonds in their structure and It polymerizes and hardens with oxygen to form a coating. Many varnishes for these lithographic printing inks are known, and any of these varnishes can be used in the present invention. The solvent constituting the printing ink of the present invention is added to modify the viscosity, consistency, flow, etc. of the ink, and any of the various organic solvents conventionally used for printing inks can be used. The amount used is generally about 5 to 80 parts by weight per 100 parts by weight of printing ink. Moreover, such a solvent can also be substituted in whole or in part with a specific polymerizable compound described below. The solvent-soluble polymerizable compound used in the present invention and which mainly characterizes the present invention acts on polymerization initiating radicals generated in the printing ink when the printing ink comes into contact with air or due to heat, thereby initiating the polymerization. It acts to eliminate or weaken the action of radicals or growing radicals. Any of the conventionally known solvent-soluble polymerizable compounds having such an effect can be used in the present invention, but those that are particularly suitable for the present invention are liquid in normal state, and are non-volatile to non-volatile in normal state. It is a volatile polymerizable compound. If these polymerizable compounds are normally liquid or not soluble in solvents, the printing ink dries quickly on the printing press, and if they are volatile, they pose problems in terms of work hygiene, and It becomes difficult to prevent the printing ink from drying too quickly. In the present invention, when the above polymerizable compounds are added to printing ink, these polymerizable compounds are present in the printing ink during storage of the printing ink or on the printing machine, and these polymerizable compounds are Due to its non-volatility, the polymerization and drying of the printing ink is delayed, thus solving the problems of the prior art as described above. Further, when the printing ink of the present invention is applied to a printing material, especially when the printing material is an absorbent printing material such as paper, the printing ink is dissolved in the solvent in the printing ink and the solvent is dissolved in the printing ink. It has been discovered that because the above polymerizable compound is quickly absorbed into the printing material, the components consisting of the colorant and varnish remaining on the printing material dry quickly like conventional printing inks. , the objectives of the present invention have been fully achieved. Therefore, the printing ink of the present invention is particularly useful as an ink for printing on absorbent printing materials such as paper, for example for lithographic printing. Furthermore, the above-mentioned solvent-soluble polymerizable compounds may be used in place of the solvent in the printing ink of the present invention, or may be used as part of the solvent, but should not be used in too large a quantity. is not economical and may excessively delay drying after printing, and if the amount used is too small, the effects of the present invention cannot be fully achieved. According to the inventor's detailed research, the above-mentioned solvent-soluble polymerizable compound used in the present invention generally accounts for about 2 to 60 parts by weight in 100 parts by weight of the printing ink, and more preferably The proportion is about 5 to 40 parts by weight, and the purpose of the present invention can be fully achieved at such a proportion. To explain in more detail about the solvent-soluble polymerizable compound used in the present invention that functions as described above, such a solvent-soluble polymerizable compound has at least one polymerizable double polymer in its structure. It is a compound having a bond, and to give preferable specific examples, the first group includes medium to high unsaturated fatty acids or various derivatives thereof, such as esters, and preferable examples include caproleic acid, undecylenic acid, and elaidine. acids, fatty acids such as oleic acid, linoleic acid, linolenic acid, ricinoleic acid, alcohol esters of these such as methyl, ethyl, propyl, butyl, heptyl, hexyl, octyl, and benzyl esters, polyhydric alcohols such as ethylene glycol, glycerin, etc. Examples include mono-triesters of. The second group includes aliphatic hydrocarbons having about 6 to 30 carbon atoms, and preferred examples include olefins such as nonene, decene, undecene, tridecene, tetradecene, hexadecene, octadecene, nonadecene, and docodecene; hexenol,
Examples include unsaturated alcohols such as heptinol, dodecenol, hexadecenol, oleyl alcohol, linoleyl alcohol, and ricinoleyl alcohol, and various esters thereof. The third group includes various vinyl compounds, and preferred ones include styrene having a C4 to C20 alkyl group or derivatives thereof, vinylhexyl ether, vinylheptyl ether, vinyl octyl ether, and vinyl nonyl ether. , vinyl decyl ether, vinyl lauryl ether, vinyl myristyl ether, vinyl stearyl ether, etc., vinyl oleyl ether, hexyl (meth)acrylate, cyclohexyl (meth)acrylate, heptyl (meth)acrylate, octyl (meth)acrylate, (Meth) such as 2-ethylhexyl (meth)acrylate, nonyl (meth)acrylate, decyl (meth)acrylate, dodecyl (meth)acrylate, tetradecyl (meth)acrylate, hexadecyl (meth)acrylate, etc.
Acrylic esters, vinyl esters such as vinyl caproate, vinyl caprylate, vinyl laurate, vinyl myristate, vinyl stearate, vinyl oleate, allyls such as allyl caprate, allyl caproate, allyl myristate, and allyl stearate. Examples include esters. As mentioned above, the solvent-soluble polymerizable compound described above has a molecular weight above a certain level, that is, a certain molecular weight that is non-volatile to hardly volatile at room temperature, but preferably does not have a high molecular weight such as that of varnish. It is. If the molecular weight is too low, it will not be possible to prevent premature drying on the printing press due to volatilization, and if the molecular weight is too high, this solvent-soluble polymerizable compound itself will form an insoluble film, which will also cause premature drying. I can't suppress it. The above example is
The present invention is intended to explain the present invention, and even solvent-soluble polymerizable compounds other than those described above, which have the same functions as those described above, are naturally included in the present invention. The printing ink of the present invention has the above-mentioned components as essential components, but if necessary, various additives normally used in conventional printing inks can also be used in the printing ink of the present invention. It is possible. The printing ink of the present invention can be manufactured by any conventionally known manufacturing method such as kneading with a roll, etc., except that the above-mentioned solvent-soluble polymerizable compound is added to the printing ink. (Function/Effect) According to the present invention as described above, by adding an appropriate amount of a specific solvent-soluble polymerizable compound to the printing ink, the printing ink can be used during storage or during printing. Premature drying of the printing ink on the press can be prevented, so even if the printing operation is interrupted and a considerable period of time has elapsed, the printing ink on the press remains essentially intact and undried.
Printing can be started immediately without any cleaning or special preparation operations required when starting the next printing. Therefore,
Various problems in the prior art, such as time-consuming and uneconomical cleaning of the printing press and uneconomical running-in operation until printing stabilization, have been solved. Despite that,
In particular, the rapid drying of the printing ink after printing on absorbent printing materials is not hindered in any way. Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples. Note that parts in the text are based on weight. Example 1 225 parts of oxidative polymerization type varnish and 70 parts of tall oil fatty acid benzyl ester (solvent-soluble polymerizable compound) were mixed, and 64.1 parts of the mixture, 20 parts of brilliant carmine 6B, 0.8 parts of manganese naphthenate and Nisseki No. 5 were mixed. 15.1 parts of solvent was blended and mixed and kneaded using three rolls to obtain a printing ink of the present invention having a tack value of 9.2. 0.15 ml of this printing ink was applied to art paper using a 4-part RI tester. When the gloss of the color surface of the art paper was measured, it was 73%. On the other hand, when the above printing ink was left on an RI tester overnight and then developed in the same way, the gloss was 46%, indicating the excellent storage stability of the printing ink.The drying time of the printing ink on art paper It was hot for 4 hours. Furthermore, after performing the above printing ink test, the printing press was left overnight without any cleaning, and when printing was attempted again the next morning, printing was possible without any problems. Comparative example 1 225 parts of oxidative polymerization type varnish and Nisseki No. 5 solvent
70 parts of this mixture, 65.3 parts of this mixture, 20 parts of brilliant carmine 6B, 0.8 parts of manganese naphthenate, and 13.9 parts of Nisseki No. Got the ink. When this ink was subjected to a color development test in the same manner as in Example 1, the gloss was 74%, while
Gloss is 19% when left overnight on RI tester
This showed that the storage stability of the printing ink was insufficient. The drying time of the printing ink on art paper was 4 hours. In addition, when reprinting was performed after the printing test was left overnight, the ink on the printing plate surface dried and formed an insoluble film, resulting in poor transfer of the printing ink, and reprinting was not possible as it was. Examples 2 to 7 Printing inks were prepared in the same manner as in Example 1 except that other polymerizable compounds shown in Table 1 below were used in place of the polymerizable compound in Example 1, and tested in the same manner. , the results shown in Table 1 below were obtained.
【表】
エーテル
尚、上記実施例２〜７の印刷インキは、いずれ
も印刷機上で一夜放置しても乾燥しなかつた。Table: Ether The printing inks of Examples 2 to 7 did not dry even when left on the printing press overnight.
Claims (1)
および溶剤からなる印刷インキにおいて、上記溶
剤可溶性の重合性化合物が、常温で不揮発性〜難
揮発性であるアルコール性水酸基を有さない中〜
高級不飽和脂肪酸またはその誘導体、重合性二重
結合を有する炭素数６〜30の脂肪族化合物又は炭
素数３〜20のアルキル基を有するビニル化合物で
あることを特徴とする印刷インキ。 ２ 溶剤可溶性の重合性化合物が、印刷インキ
100重量部中で約２〜60重量部の割合で存在する
特許請求の範囲第１項に記載の印刷インキ。 ３ 溶剤可溶性の重合性化合物が、常温で液状で
ある特許請求の範囲第１項に記載の印刷インキ。[Scope of Claims] 1. A printing ink comprising a colorant, a varnish, a solvent-soluble polymerizable compound, and a solvent, wherein the solvent-soluble polymerizable compound has an alcoholic hydroxyl group that is non-volatile to hardly volatile at room temperature. I don't do it~
A printing ink characterized by being a higher unsaturated fatty acid or a derivative thereof, an aliphatic compound having 6 to 30 carbon atoms having a polymerizable double bond, or a vinyl compound having an alkyl group having 3 to 20 carbon atoms. 2 Solvent-soluble polymerizable compounds are used in printing inks.
Printing ink according to claim 1, present in a proportion of about 2 to 60 parts by weight in 100 parts by weight. 3. The printing ink according to claim 1, wherein the solvent-soluble polymerizable compound is liquid at room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60041305A JPS61203183A (en) | 1985-03-04 | 1985-03-04 | Printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60041305A JPS61203183A (en) | 1985-03-04 | 1985-03-04 | Printing ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61203183A JPS61203183A (en) | 1986-09-09 |
| JPH0149427B2 true JPH0149427B2 (en) | 1989-10-24 |
Family
ID=12604773
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60041305A Granted JPS61203183A (en) | 1985-03-04 | 1985-03-04 | Printing ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61203183A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7951232B2 (en) * | 2006-02-09 | 2011-05-31 | Elevance Renewable Sciences, Inc. | Surface coating compositions and methods |
-
1985
- 1985-03-04 JP JP60041305A patent/JPS61203183A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61203183A (en) | 1986-09-09 |
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