JPH0143826B2 - - Google Patents
Info
- Publication number
- JPH0143826B2 JPH0143826B2 JP56099413A JP9941381A JPH0143826B2 JP H0143826 B2 JPH0143826 B2 JP H0143826B2 JP 56099413 A JP56099413 A JP 56099413A JP 9941381 A JP9941381 A JP 9941381A JP H0143826 B2 JPH0143826 B2 JP H0143826B2
- Authority
- JP
- Japan
- Prior art keywords
- spinning nozzles
- alloy
- resistance
- present
- platinum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910045601 alloy Inorganic materials 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 15
- 238000009987 spinning Methods 0.000 claims description 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- 238000003483 aging Methods 0.000 claims description 6
- 229910052738 indium Inorganic materials 0.000 claims description 5
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 239000002253 acid Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 229920000297 Rayon Polymers 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JUWSSMXCCAMYGX-UHFFFAOYSA-N gold platinum Chemical compound [Pt].[Au] JUWSSMXCCAMYGX-UHFFFAOYSA-N 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
Landscapes
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Description
本発明はレーヨン系、アクリル系繊維紡糸ノズ
ル用材料として使用する合金の改良に関するもの
である。
従来、上述の如きレーヨン系、アクリル系繊維
紡糸ノズル用材料としては金−白金（30〜50重量
％（以下、「ｗ／ｏ」と略す。））合金が多用され
ている。この合金は、時効処理前は薄板、絞り、
細孔加工性が優れているが、時効処理後の耐摩耗
性、耐圧力が低い為、完成品として使用している
場合、摩耗のため吐出孔の紡糸面側のかどが減つ
たり、破損したりするという欠点があつた。
本発明は上記の欠点を解消せんが為になされた
ものであり、加工性、耐摩耗性、耐酸、耐アルカ
リ性及び特に時効硬化後の硬さに優れた紡糸ノズ
ル用合金を提供せんとするものである。
本発明による紡糸ノズル用合金のは白金65←
95w／ｏ、インジウム２〜20w／ｏ、残部、パラ
ジウムよりなる時効硬化性を具備したものであ
る。
本発明による紡糸ノズル用合金に於いて、イン
ジウムを添加した理由は固溶体領域まで加熱し、
急冷する溶体化処理を行つた後、適当な温度で時
効させると著しい時効硬化性を現わす為である。
その添加量が2w／ｏ未満では、硬さの改善げ
殆んどなく、20w／ｏを超えると白金とインジウ
ムの金属間化合物の量が多くなり、加工性が悪く
なるからである。また、パラジウムを添加した理
由は、インジウムの添加による耐酸性、耐アルカ
リ性の低下を防止するためである。白金の組成を
65〜95w／ｏとしたのは、95w／ｏを超えると錫
に対するパラジウムの添加量が少なく局部腐食が
起きやすくなり、65w／ｏより少ないと、白金に
対するパラジウムの添加量が多すぎ、耐酸、耐ア
ルカリ性が劣化するためである。
以下、本発明による紡糸ノズル用合金の効果を
明瞭ならしめる為に実施例及び従来例について述
べる。
第１表に示す成分組成の実施例No.１〜No.３の紡
糸ノズル用合金と従来例No.４の紡糸ノズル用合金
の溶体化処理後の硬度、加工性、時効後の硬度、
耐摩耗性及び耐酸、耐アルカリ性について試験し
たところ第２表のような結果を得た。
The present invention relates to improvements in alloys used as materials for rayon-based and acrylic-based fiber spinning nozzles. Conventionally, gold-platinum (30 to 50% by weight (hereinafter abbreviated as "w/o")) alloy has been frequently used as a material for the above-mentioned rayon-based and acrylic-based fiber spinning nozzles. This alloy is thin sheet, drawn, and
Although it has excellent pore processability, the abrasion resistance and pressure resistance after aging treatment are low, so when used as a finished product, the edge of the spun surface side of the discharge hole may be reduced or damaged due to wear. It had the disadvantage of doing things like that. The present invention has been made in order to eliminate the above-mentioned drawbacks, and it is an object of the present invention to provide an alloy for spinning nozzles that has excellent workability, wear resistance, acid resistance, alkali resistance, and especially hardness after age hardening. It is. The alloy for spinning nozzles according to the present invention is platinum 65←
It has age hardening properties and is composed of 95 w/o, indium 2 to 20 w/o, and the balance palladium. The reason for adding indium to the alloy for spinning nozzles according to the present invention is that it can be heated to a solid solution region,
This is because, after performing solution treatment by rapid cooling, it exhibits remarkable age hardening properties when aged at an appropriate temperature. If the amount added is less than 2 w/o, there is little improvement in hardness, and if it exceeds 20 w/o, the amount of the intermetallic compound of platinum and indium increases, resulting in poor workability. Moreover, the reason for adding palladium is to prevent the acid resistance and alkali resistance from decreasing due to the addition of indium. The composition of platinum
The reason why the range is 65 to 95 w/o is that if it exceeds 95 w/o, the amount of palladium added to tin will be small and local corrosion will easily occur, and if it is less than 65 w/o, the amount of palladium added to platinum will be too large, resulting in poor acid resistance. This is because alkali resistance deteriorates. Examples and conventional examples will be described below in order to clarify the effects of the alloy for spinning nozzles according to the present invention. Hardness after solution treatment, workability, hardness after aging of the alloys for spinning nozzles of Examples No. 1 to No. 3 and the alloy for spinning nozzles of Conventional Example No. 4 having the component compositions shown in Table 1,
When tested for abrasion resistance, acid resistance, and alkali resistance, the results shown in Table 2 were obtained.
【表】【table】
【表】
なお、耐摩耗試験は内径50μｍ、、かどの曲率
半径5μｍの吐出孔70個を持つノズルよりレーヨ
ン繊維を10Kg／cm2の圧力で2000時間紡糸した後の
吐出孔のかどの曲率半径によつて行なつた。
上記で明らかなように本発明による紡糸ノズル
用合金は従来の紡糸ノズル用合金に比し時効硬化
後の硬さが著しく優れ、加工性及び耐酸、耐アル
カリ性については従来の紡糸ノズル用合金と同等
に優れ、耐摩耗性についても優れていることが判
る。
以上詳記した通り、本発明による紡糸ノズル用
合金は加工性、耐酸、耐アルカリ性、特に時効硬
化後の硬さ、耐摩耗性が極めて優れているので、
従来の紡糸ノズル用合金にとつて代わることので
きる画期的なものと言える。[Table] The abrasion resistance test was conducted using a nozzle with an inner diameter of 50 μm and a corner radius of curvature of 5 μm, after spinning rayon fiber at a pressure of 10 kg/cm 2 for 2000 hours. I turned over and went. As is clear from the above, the alloy for spinning nozzles according to the present invention has significantly superior hardness after age hardening compared to conventional alloys for spinning nozzles, and is equivalent to conventional alloys for spinning nozzles in terms of workability and acid and alkali resistance. It can be seen that it has excellent properties and wear resistance. As detailed above, the alloy for spinning nozzles according to the present invention has extremely excellent workability, acid resistance, alkali resistance, especially hardness after age hardening, and wear resistance.
It can be said to be a revolutionary product that can replace conventional alloys for spinning nozzles.
Claims (1)
及び残部パラジウムよりなる時効硬化性を具備し
た紡糸ノズル用合金。1 Platinum 65-95% by weight, Indium 2-20% by weight
An alloy for spinning nozzles having age hardening properties and the balance being palladium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9941381A JPS581035A (en) | 1981-06-26 | 1981-06-26 | Allow for spinning nozzle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9941381A JPS581035A (en) | 1981-06-26 | 1981-06-26 | Allow for spinning nozzle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS581035A JPS581035A (en) | 1983-01-06 |
| JPH0143826B2 true JPH0143826B2 (en) | 1989-09-22 |
Family
ID=14246787
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9941381A Granted JPS581035A (en) | 1981-06-26 | 1981-06-26 | Allow for spinning nozzle |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS581035A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5080493A (en) * | 1973-11-22 | 1975-06-30 |
-
1981
- 1981-06-26 JP JP9941381A patent/JPS581035A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5080493A (en) * | 1973-11-22 | 1975-06-30 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS581035A (en) | 1983-01-06 |
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