JPH0134376B2 - - Google Patents
Info
- Publication number
- JPH0134376B2 JPH0134376B2 JP56127774A JP12777481A JPH0134376B2 JP H0134376 B2 JPH0134376 B2 JP H0134376B2 JP 56127774 A JP56127774 A JP 56127774A JP 12777481 A JP12777481 A JP 12777481A JP H0134376 B2 JPH0134376 B2 JP H0134376B2
- Authority
- JP
- Japan
- Prior art keywords
- yellow
- color
- toner
- dye
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000049 pigment Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 21
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
- 239000000463 material Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 238000004040 coloring Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- -1 etc. Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- JFMYRCRXYIIGBB-UHFFFAOYSA-N 2-[(2,4-dichlorophenyl)diazenyl]-n-[4-[4-[[2-[(2,4-dichlorophenyl)diazenyl]-3-oxobutanoyl]amino]-3-methylphenyl]-2-methylphenyl]-3-oxobutanamide Chemical compound C=1C=C(C=2C=C(C)C(NC(=O)C(N=NC=3C(=CC(Cl)=CC=3)Cl)C(C)=O)=CC=2)C=C(C)C=1NC(=O)C(C(=O)C)N=NC1=CC=C(Cl)C=C1Cl JFMYRCRXYIIGBB-UHFFFAOYSA-N 0.000 description 2
- QTSNFLIDNYOATQ-UHFFFAOYSA-N 2-[(4-chloro-2-nitrophenyl)diazenyl]-n-(2-chlorophenyl)-3-oxobutanamide Chemical compound C=1C=CC=C(Cl)C=1NC(=O)C(C(=O)C)N=NC1=CC=C(Cl)C=C1[N+]([O-])=O QTSNFLIDNYOATQ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 235000012752 quinoline yellow Nutrition 0.000 description 2
- 229940051201 quinoline yellow Drugs 0.000 description 2
- 239000004172 quinoline yellow Substances 0.000 description 2
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 2
- 239000001054 red pigment Substances 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- DWDURZSYQTXVIN-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]aniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 DWDURZSYQTXVIN-UHFFFAOYSA-N 0.000 description 1
- MPVDXIMFBOLMNW-ISLYRVAYSA-N 7-hydroxy-8-[(E)-phenyldiazenyl]naphthalene-1,3-disulfonic acid Chemical compound OC1=CC=C2C=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C2=C1\N=N\C1=CC=CC=C1 MPVDXIMFBOLMNW-ISLYRVAYSA-N 0.000 description 1
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- REEFSLKDEDEWAO-UHFFFAOYSA-N Chloraniformethan Chemical compound ClC1=CC=C(NC(NC=O)C(Cl)(Cl)Cl)C=C1Cl REEFSLKDEDEWAO-UHFFFAOYSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- JPIYZTWMUGTEHX-UHFFFAOYSA-N auramine O free base Chemical compound C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 JPIYZTWMUGTEHX-UHFFFAOYSA-N 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- HEQCHSSPWMWXBH-UHFFFAOYSA-L barium(2+) 1-[(2-carboxyphenyl)diazenyl]naphthalen-2-olate Chemical compound [Ba++].Oc1ccc2ccccc2c1N=Nc1ccccc1C([O-])=O.Oc1ccc2ccccc2c1N=Nc1ccccc1C([O-])=O HEQCHSSPWMWXBH-UHFFFAOYSA-L 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical class [H]OC(*)=O 0.000 description 1
- HBHZKFOUIUMKHV-UHFFFAOYSA-N chembl1982121 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HBHZKFOUIUMKHV-UHFFFAOYSA-N 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- YOCIQNIEQYCORH-UHFFFAOYSA-M chembl2028361 Chemical compound [Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=CC=C1 YOCIQNIEQYCORH-UHFFFAOYSA-M 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- FQMCMHQTSGVJIP-UHFFFAOYSA-N ethanol;2-(2-hydroxyethoxy)ethanol Chemical compound CCO.OCCOCCO FQMCMHQTSGVJIP-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- PLYDMIIYRWUYBP-UHFFFAOYSA-N ethyl 4-[[2-chloro-4-[3-chloro-4-[(3-ethoxycarbonyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-oxo-1-phenyl-4h-pyrazole-3-carboxylate Chemical compound CCOC(=O)C1=NN(C=2C=CC=CC=2)C(=O)C1N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(=N1)C(=O)OCC)C(=O)N1C1=CC=CC=C1 PLYDMIIYRWUYBP-UHFFFAOYSA-N 0.000 description 1
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- HTENFZMEHKCNMD-UHFFFAOYSA-N helio brilliant orange rk Chemical compound C1=CC=C2C(=O)C(C=C3Br)=C4C5=C2C1=C(Br)C=C5C(=O)C1=CC=CC3=C14 HTENFZMEHKCNMD-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- VENDXQNWODZJGB-UHFFFAOYSA-N n-(4-amino-5-methoxy-2-methylphenyl)benzamide Chemical compound C1=C(N)C(OC)=CC(NC(=O)C=2C=CC=CC=2)=C1C VENDXQNWODZJGB-UHFFFAOYSA-N 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000012736 patent blue V Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 108091008695 photoreceptors Proteins 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 229940081623 rose bengal Drugs 0.000 description 1
- 229930187593 rose bengal Natural products 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- STRXNPAVPKGJQR-UHFFFAOYSA-N rose bengal A Natural products O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 STRXNPAVPKGJQR-UHFFFAOYSA-N 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- RBKBGHZMNFTKRE-UHFFFAOYSA-K trisodium 2-[(2-oxido-3-sulfo-6-sulfonatonaphthalen-1-yl)diazenyl]benzoate Chemical compound C1=CC=C(C(=C1)C(=O)[O-])N=NC2=C3C=CC(=CC3=CC(=C2[O-])S(=O)(=O)O)S(=O)(=O)[O-].[Na+].[Na+].[Na+] RBKBGHZMNFTKRE-UHFFFAOYSA-K 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- UGCDBQWJXSAYIL-UHFFFAOYSA-N vat blue 6 Chemical compound O=C1C2=CC=CC=C2C(=O)C(C=C2Cl)=C1C1=C2NC2=C(C(=O)C=3C(=CC=CC=3)C3=O)C3=CC(Cl)=C2N1 UGCDBQWJXSAYIL-UHFFFAOYSA-N 0.000 description 1
- JEVGKYBUANQAKG-UHFFFAOYSA-N victoria blue R Chemical compound [Cl-].C12=CC=CC=C2C(=[NH+]CC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 JEVGKYBUANQAKG-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/09—Colouring agents for toner particles
- G03G9/0928—Compounds capable to generate colouring agents by chemical reaction
Description
【発明の詳細な説明】
本発明は、電子写真による２色画像を形成する
ためのトナーに関し、更に詳細には無色ないし淡
色のロイコ染料と顕色剤および着色剤を含むトナ
ーに関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a toner for forming two-color images by electrophotography, and more particularly to a toner containing a colorless or light-colored leuco dye, a color developer, and a colorant.
２色画像の形成方法に関しては、多くの特許が
出願されており、その中で例えば特開昭54−3537
号、同55−65963号、その他多数の特許に公開さ
れているように、波長応答の異なる２種類の光導
電体層を積層した感光体を使用し、色の異なる逆
極性の現像剤を用いる方法が代表的である。 Many patents have been filed regarding methods for forming two-color images, including Japanese Patent Application Laid-Open No. 54-3537.
No. 55-65963, and many other patents, a photoreceptor with two types of photoconductor layers with different wavelength responses is used, and developers with different colors and opposite polarities are used. The method is representative.
この方法は、１回の露光、現像で２色画像を得
ることに特徴があるが、２種類の現像剤を使用す
るために、それぞれの現像剤によるエツジ効果が
現われたり、現像剤が混合して帯電量が低下して
記録画像濃度が低下するなどの欠点がある。 This method is characterized by obtaining a two-color image with one exposure and development, but because two types of developers are used, edge effects may appear due to each developer, and the developers may be mixed. However, there are drawbacks such as a decrease in the amount of charge and a decrease in the density of the recorded image.
さらに、この場合には２種類の現像剤を使用す
るため一般用の黒一色のものに比べて複写装置が
複雑なものとなる欠点もある。 Furthermore, in this case, since two types of developer are used, there is a drawback that the copying apparatus is more complicated than that of a general-purpose black one.
本発明は上記のような欠点を改善したもので、
通常の電子写真複写機を使用して黒色画像のコピ
ーを得、次にジエチレングリコールなどにより所
望の部分を変色させることの出来るトナーを提供
するものである。 The present invention improves the above-mentioned drawbacks,
The present invention provides a toner that can be used to obtain a copy of a black image using a conventional electrophotographic copying machine and then discolored in desired areas using diethylene glycol or the like.
即ち本発明は、無色ないし淡色のロイコ染料と
該染料の顕色剤よりなる染料発色型の感熱記録材
料、および黒以外の有彩色の着色顔料あるいは染
料を含んだトナーであり、このトナーを通常の電
子写真複写機に装入し、複写を行なうことにより
ロイコ染料と着色顔料あるいは染料が混在した黒
色やその他の色のコピーを得る。次にジエチレン
グリコール、ポリエチレングリコール等をそのま
ま、あるいは水やアルコール、アセトン等でうす
めた消色剤を異色画像にしたい部分に、筆やフエ
ルトペン等で塗布するとロイコ染料発色した染料
の色が消えて、着色顔料あるいは染料の色に変わ
り受像シート上に２色画像が形成されるものであ
る。 That is, the present invention relates to a dye-coloring type heat-sensitive recording material comprising a colorless or light-colored leuco dye and a color developer for the dye, and a toner containing a colored pigment or dye of a chromatic color other than black. By loading it into an electrophotographic copying machine and making copies, copies of black or other colors containing a mixture of leuco dye and coloring pigment or dye can be obtained. Next, when you apply a color erasing agent such as diethylene glycol, polyethylene glycol, etc. directly or diluted with water, alcohol, acetone, etc. to the area where you want to create a different color image with a brush or felt pen, the color of the leuco dye color will disappear. A two-color image is formed on the image-receiving sheet by changing the color of the colored pigment or dye.
ロイコ染料発色画像は、ジエチレングリコー
ル、ポリエチレングリコール等や、プラスチツク
に含まれる可塑剤と接触すると発色した色が消え
てしまう特性を持つている。本発明はこうしたロ
イコ染料発色画像の特性を利用して２色画像を得
るためのトナーである。 Leuco dye-colored images have the characteristic that the color will disappear when they come into contact with diethylene glycol, polyethylene glycol, etc., or plasticizers contained in plastics. The present invention is a toner for obtaining a two-color image by utilizing the characteristics of such a leuco dye colored image.
次に、本発明において使用する材料については
説明すると、ロイコ染料としては、クリスタルバ
イオレツトラクトン等のトリフエニルメタン系染
料、フルオラン系染料、オーラミンン系染料、ス
ピロピラン系染料等、染料発色型感熱記録紙に使
用されている染料が全て使用出来る。顕色剤とし
ては、ビスフエノールＡ、パラフエニルフエノー
ル、フエノール樹脂等のフエノール類、安息香酸
金属塩等のカルポン酸金属塩、その他酸性物質
等。また感熱発色の増感剤としてステアリン酸ア
マイド、パルミチン酸アマイド等の脂肪酸アマイ
ド、ステアリン酸亜鉛等の脂肪酸金属塩、脂肪
酸、その他のワツクスが使用できる。 Next, to explain the materials used in the present invention, examples of leuco dyes include triphenylmethane dyes such as crystal violet lactone, fluoran dyes, auramine dyes, spiropyran dyes, dye-coloring thermosensitive recording paper, etc. All dyes used in can be used. Examples of color developers include phenols such as bisphenol A, paraphenylphenol, and phenolic resins, metal salts of carboxyl acids such as metal salts of benzoate, and other acidic substances. Further, as a sensitizer for heat-sensitive color development, fatty acid amides such as stearamide and palmitic acid amide, fatty acid metal salts such as zinc stearate, fatty acids, and other waxes can be used.
着色用の顔料及び染料の適当な例を示すと次の
通りであるが、本発明はこれらに限られるもので
はない。これらの顔料、染料は単独でも、あるい
は２種以上の組合せでも使用することができる。 Suitable examples of pigments and dyes for coloring are shown below, but the present invention is not limited thereto. These pigments and dyes can be used alone or in combination of two or more.
黄色顔料
黄鉛、亜鉛黄、カドミウムエロー、黄色酸化
鉄、ミネラルフアストエロー、ニツケルチタンエ
ロー、ネーブルスエロー、ナフトールエローＳ、
ハンザーイエローＧ、ハンザイエロー10G、ベン
ジンエローＧ、ベンジンエローGR、キノリンエ
ローレーキ、パーマネントエローNCG、タート
ラジンレーキ。Yellow pigment: yellow lead, zinc yellow, cadmium yellow, yellow iron oxide, mineral fast yellow, nickel titanium yellow, navel yellow, naphthol yellow S,
Hanser Yellow G, Hansa Yellow 10G, Benzine Yellow G, Benzine Yellow GR, Quinoline Yellow Lake, Permanent Yellow NCG, Tartrazine Lake.
橙色顔料
赤色黄鉛、モリブデンオレンジ、パーマネント
オレンジGTR、ピラゾロンオレンジ、バルカン
オレンジ、インダンスレンブリリアントオレンジ
RK、ベンジンオレンジＧ、インダンスレンブリ
リアントオレンジGK。Orange pigments Red yellow lead, molybdenum orange, permanent orange GTR, pyrazolone orange, vulcan orange, indanthrene brilliant orange
RK, Benzine Orange G, Indanthrene Brilliant Orange GK.
赤色顔料
ベンガラ、カドミウムレツド、鉛丹、硫化水
銀、カドミウムパーマネントレツド4R、リソー
ルレツド、ピラゾロンレツド、ウオツチンクレツ
ドカルシユーム塩、レーキレツドＤ、ブリリアン
トカーミン6B、エオシンレーキ、ローダミンレ
ーキＢ、アリザリンレーキ、ブリリアントカーミ
ン3B。Red pigment red pigment, cadmium red, red lead, mercury sulfide, cadmium permanent red 4R, resol red, pyrazolone red, wortstone red calcium salt, lake red D, brilliant carmine 6B, eosin lake, rhodamine lake B, alizarin lake , Brilliant Carmine 3B.
紫外顔料
マンガン紫、フアストバイオレツドＢ、メチル
バイオレツトレーキ。Ultraviolet pigments: manganese violet, fast violet B, methyl violet lake.
青色顔料
紺青、コバルトブルー、アルカリブルーレー
キ、ビクトリアブルーレーキ、フタロシアニンブ
ルー、無金属フタロシアニンブルー、フタロシア
ニンブルー部分塩素化物、フアストスカイブル
ー、インダンスレンブルーBC。Blue pigments: navy blue, cobalt blue, alkali blue lake, Victoria blue lake, phthalocyanine blue, metal-free phthalocyanine blue, partially chlorinated phthalocyanine blue, fast sky blue, indanthrene blue BC.
緑色顔料
クロムグリーン、酸化クロム、ピグメントグリ
ーンＢ、マラカイトグリーンレーキ、フアナルイ
エローグリーンＧ。Green pigments Chrome Green, Chromium Oxide, Pigment Green B, Malachite Green Lake, Huanal Yellow Green G.
白色顔料
亜鉛華、酸化チタン、アンチモン白、硫化亜
鉛。White pigments: zinc white, titanium oxide, antimony white, zinc sulfide.
体質顔料
バライト粉、炭酸バリウム、クレー、酸性白土
乃至は活性白土、シリカ、ガラス粉、ホワイトカ
ーボン、タルク、アルミナホワイト。Extender pigments Barite powder, barium carbonate, clay, acid clay or activated clay, silica, glass powder, white carbon, talc, alumina white.
塩基性・酸性・分散・直接染料等
ニグロシン、メチレンブルー、ローズベンガ
ル、キノリンイエロー、ウルトラマリンブルー
等。Basic, acidic, dispersed, direct dyes, etc. Nigrosine, methylene blue, rose bengal, quinoline yellow, ultramarine blue, etc.
又本発明のトナーの使用かれる樹脂としては、
ポリスチレン、アクリル樹脂、エポキシ樹脂、ポ
リアミド樹脂、スチレン−アクリル共重合体、ポ
リ塩化ビニル、ポリ塩化ビニリデン、フエノール
樹脂、ロジン、シエラツク、バルサム、アスフア
ルト等の合成樹脂や天然樹脂を挙げることができ
る。これらの樹脂は単独でも、あるいは２種類以
上組合せの形でも使用し得る。 Furthermore, the resin used in the toner of the present invention is as follows:
Synthetic resins and natural resins such as polystyrene, acrylic resin, epoxy resin, polyamide resin, styrene-acrylic copolymer, polyvinyl chloride, polyvinylidene chloride, phenolic resin, rosin, silica, balsam, and asphalt can be mentioned. These resins can be used alone or in combination of two or more.
さらに又、本発明のトナーには、例えば流動性
の向上、極性付与等を目的として各種の添加剤を
加えることが出来る。 Furthermore, various additives can be added to the toner of the present invention for the purpose of improving fluidity, imparting polarity, etc., for example.
本発明のトナーは上記の材料を所定の配合比に
混合して熱溶融混練したのち粉砕分級して作製
し、これをキヤリヤー鉄粉などと混合して二成分
現像剤として複写機に供されるか、またはトナー
中に磁性物質を配合させて、一成分現像剤として
も使用することができる。 The toner of the present invention is prepared by mixing the above-mentioned materials in a predetermined ratio, hot-melting, kneading, pulverizing and classifying the materials, and then mixing this with carrier iron powder and the like to provide a two-component developer to a copying machine. Alternatively, the toner can be used as a one-component developer by incorporating a magnetic substance into the toner.
トナーを構成する各材料の使用量は、樹脂分95
重量％以下、好ましくは70〜90重量％、ロイコ染
料と顕色剤よりなる感熱発色材料は１〜35重量％
好ましくは５〜25重量％、着色顔料または染料は
１〜20重量％好ましくは３〜10重量％であり、極
性付与剤、流動性向上剤等は10重量％である。 The amount of each material used to make up the toner is 95% resin.
Less than 70% by weight, preferably 70 to 90% by weight, and 1 to 35% by weight of a thermosensitive color forming material consisting of a leuco dye and a color developer.
Preferably, the content is 5 to 25% by weight, the content of coloring pigments or dyes is 1 to 20% by weight, preferably 3 to 10% by weight, and the content of polarizers, fluidity improvers, etc. is 10% by weight.
本発明のトナーを使用して得られたコピーの発
色画像を消色させるには、ジエチレングリコー
ル、ポリエチレングリコール、ポリオキシエチレ
ンアルキルエーテル等のエーテル結合を持つ有機
物質、ジ−２−エチルヘキシルフタレート等に代
表されるプラスチツク用の可塑剤、エタノールア
ミン等のアミン化合物をそのまま使用するか、あ
るいは、水・アルコール・アセトン等に任意の割
合でうすめて使用する。 In order to erase the colored images of copies obtained using the toner of the present invention, organic substances having an ether bond such as diethylene glycol, polyethylene glycol, polyoxyethylene alkyl ether, di-2-ethylhexyl phthalate, etc. Plasticizers for plastics and amine compounds such as ethanolamine can be used as they are, or diluted in water, alcohol, acetone, etc. in any proportion.
次に本発明を実施例にて具体的に説明する。 Next, the present invention will be specifically explained with reference to Examples.
実施例 １
ポリスチレン 100重量部
フルオラン系ロイコ染料 ５ 〃
ビスフエノールＡ ５ 〃
ローダミンレーキＢ ３ 〃
パーマネントエローNCG １ 〃
上記の材料を混合して混融し冷却固化する。固
化物を粉砕し、分級した後さらにシリカを0.3重
量％加えて、５〜15μ程度の粒子径をもつトナー
を得た。このトナー１重量当り10重量部のキヤリ
ヤー鉄粉と混合して現像剤とし、電子写真複写機
に黒色画像のコピーを得た。このコピーの一部に
ジエチレングリコールのエタノール溶液を塗布し
たところ、その部分だけが鮮明な赤色画像に変化
した。Example 1 Polystyrene 100 parts by weight Fluorane leuco dye 5 Bisphenol A 5 Rhodamine Lake B 3 Permanent Yellow NCG 1 The above materials are mixed, blended, and solidified by cooling. After pulverizing and classifying the solidified product, 0.3% by weight of silica was added to obtain a toner having a particle size of about 5 to 15 μm. This toner was mixed with 10 parts by weight of carrier iron powder to form a developer, and a black image copy was obtained using an electrophotographic copying machine. When a diethylene glycol ethanol solution was applied to a part of the copy, only that part turned into a bright red image.
実施例 ２
ポリスチレン 100重量部
フルオラン系ロイコ染料 ５ 〃
ビスフエノールＡ ５ 〃
黄鉛 ３ 〃
ハンザイエロー10G １ 〃
上記材料を用い実施例１と同様にして黒色のコ
ピーを得た。このコピーの一部にジエチレングリ
コールの水希釈液を塗布したところ、その部分だ
けが黄色に変化した。Example 2 Polystyrene 100 parts by weight Fluorane leuco dye 5 Bisphenol A 5 Yellow lead 3 Hansa Yellow 10G 1 A black copy was obtained in the same manner as in Example 1 using the above materials. When a diluted diethylene glycol solution was applied to a portion of the copy, only that portion turned yellow.
以上の如く、本発明のトナーを用いれば、従来
の電子写真複写機によつてコピーがとれ、簡単な
処理により画像部を変色させることができ、例え
ば押印部のみを赤色に変える等の操作が簡単に行
えるものである。 As described above, by using the toner of the present invention, copies can be made with a conventional electrophotographic copying machine, and the image area can be changed in color through simple processing, such as changing only the stamp area to red. It's easy to do.
Claims (1)
剤および黒以外の着色顔料あるいは染料を少なく
とも含むトナーであつて、消色剤によりトナー画
像のロイコ染料を消色し２色画像を形成するため
の電子写真用トナー。1. A toner containing at least a colorless or light-colored leuco dye, a color developer for the dye, and a colored pigment or dye other than black, for erasing the leuco dye in a toner image with a color erasing agent to form a two-color image. Toner for electrophotography.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56127774A JPS5830765A (en) | 1981-08-17 | 1981-08-17 | Electrophotographic developer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56127774A JPS5830765A (en) | 1981-08-17 | 1981-08-17 | Electrophotographic developer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5830765A JPS5830765A (en) | 1983-02-23 |
| JPH0134376B2 true JPH0134376B2 (en) | 1989-07-19 |
Family
ID=14968356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56127774A Granted JPS5830765A (en) | 1981-08-17 | 1981-08-17 | Electrophotographic developer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5830765A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0750335B2 (en) * | 1985-07-11 | 1995-05-31 | 富士ゼロックス株式会社 | Dry toner for preventing re-copying and image forming method |
| US4711832A (en) * | 1986-05-05 | 1987-12-08 | Eastman Kodak Company | Colored electroscopic toners containing quenched esterified rhodamine dyes |
| DE69937656T2 (en) * | 1998-01-23 | 2008-05-21 | Kabushiki Kaisha Toshiba, Kawasaki | Decolorizing method of discoloring recording material |
| JP3315360B2 (en) * | 1998-01-23 | 2002-08-19 | 株式会社東芝 | Erasable image forming material erasing method |
-
1981
- 1981-08-17 JP JP56127774A patent/JPS5830765A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5830765A (en) | 1983-02-23 |
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