JPH01319557A - Production of organism-latching-preventive composition - Google Patents
Production of organism-latching-preventive compositionInfo
- Publication number
- JPH01319557A JPH01319557A JP15241488A JP15241488A JPH01319557A JP H01319557 A JPH01319557 A JP H01319557A JP 15241488 A JP15241488 A JP 15241488A JP 15241488 A JP15241488 A JP 15241488A JP H01319557 A JPH01319557 A JP H01319557A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- polyvinyl chloride
- plasticizer
- parts
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000004014 plasticizer Substances 0.000 claims abstract description 22
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 20
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920001577 copolymer Polymers 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 abstract description 12
- 239000013535 sea water Substances 0.000 abstract description 10
- 239000003381 stabilizer Substances 0.000 abstract description 6
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000000049 pigment Substances 0.000 abstract description 3
- 241000238586 Cirripedia Species 0.000 abstract description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000008157 edible vegetable oil Substances 0.000 abstract description 2
- ALOUNLDAKADEEB-UHFFFAOYSA-N dimethyl sebacate Chemical compound COC(=O)CCCCCCCCC(=O)OC ALOUNLDAKADEEB-UHFFFAOYSA-N 0.000 abstract 2
- 229940014772 dimethyl sebacate Drugs 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000010721 machine oil Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 241000195493 Cryptophyta Species 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000237858 Gastropoda Species 0.000 description 3
- -1 Phthalate ester Chemical class 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 235000015170 shellfish Nutrition 0.000 description 3
- 240000007087 Apium graveolens Species 0.000 description 2
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 2
- 235000010591 Appio Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 101100313164 Caenorhabditis elegans sea-1 gene Proteins 0.000 description 1
- 206010067125 Liver injury Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000007227 biological adhesion Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 231100000234 hepatic damage Toxicity 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000008818 liver damage Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は生物体付着防止組成物の製造方法に関し、船舶
、浮島、ブイのように長期間海や河川に浮かばせたりあ
るいは火力発゛屯の如く海水を大量に使用する場合等に
適用されるものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for producing a biological adhesion prevention composition. This is applied when large quantities of seawater are used, such as in cases where large amounts of seawater are used.
[従来の技術と課題]
周知の如く、船舶、浮島、ブイのように長期間海や河川
水に浮かばせたり、あるいは発電所のパイプや輸送用の
パイプ、その他律材、魚介類の関連資料なと水中に埋没
しである箇所には、海洋の場合にはフジッボや烏貝等の
貝類や藻、微生物等か付着し、河川、湖の場合には水掻
、微生物、苔等が付着する。従って、長期間使用するに
つれてそれらか堆積し、抵抗力か太き(なったり腐蝕か
生じるという問題か生じ、また火力発電においては取入
れ口か狭くなるなどという問題が生した。[Conventional Technologies and Issues] As is well-known, materials such as ships, floating islands, buoys, etc. that are kept floating in the sea or river water for long periods of time, power plant pipes, transportation pipes, and other materials related to lumber and seafood. In the case of the ocean, shellfish such as Fujitbo and snails, algae, microorganisms, etc. will adhere to places that are buried in water, and in the case of rivers and lakes, water webs, microorganisms, moss, etc. will adhere to them. Therefore, as they are used for a long period of time, they accumulate, leading to problems such as increased resistance, thickening, and corrosion, and problems such as narrowing of intake ports in thermal power generation.
このため、従来ては、■海水等と接する箇所に亜酸化銅
、水銀系、有機スス系等の薬品を混入させた塗料を塗布
し、これを微量ずつ海中に流出させて付着した生物体の
成長を防止したり退治したりする方法、あるいは■テフ
ロンなとの合成樹脂からなる被膜祠により表向を加工す
る方法などの手段か取られていた。For this reason, in the past, paint mixed with chemicals such as cuprous oxide, mercury, and organic soot was applied to areas that would come into contact with seawater, etc., and this was poured into the sea little by little to remove attached living organisms. Measures were taken to prevent or exterminate the growth, or to treat the surface with a coating made of synthetic resin such as Teflon.
しかしながら、従来技術によれば、以下に述べる問題点
を有する。However, the conventional technology has the following problems.
(1)塗料を塗布する場合は、塗料か海水中等に流出す
る為、塗料を構成する薬品の毒性か問題になるとともに
、コスト高になる。また、塗料の塗り直しに多くの時間
を費やし、保守の手間や経費か大変である。(1) When applying paint, the paint leaks into seawater, etc., which raises the issue of the toxicity of the chemicals that make up the paint, and increases costs. Furthermore, it takes a lot of time to reapply the paint, which increases the labor and expense of maintenance.
(2)被膜刊を表面加工する場合は、被膜祠への生物体
の(=1着を若干送らせるという効果は認められるか、
十分に生物体の何着を防止することができず、生物体を
掻ぎ落す必要があった。(2) When surface-processing the membrane shrine, is there an effect of sending some living organisms (= 1 piece) to the membrane shrine?
It was not possible to sufficiently prevent the living organisms from getting onto them, and it was necessary to scrape off the living organisms.
本発明は上記事情に鑑みてなされたもので、フジッボや
烏貝や藻等の生物体が船舶の船底や火力発電の海水取入
れ口等に付着するのを著しく低減[課題を解決するため
の手段]
本願発明は、ポリ塩化ビニル樹脂又はポリ塩化ビニルを
含む共重合体100重量部に対し、可塑剤と浦からなる
混合物250〜650重量部を加えたものあるいはこれ
らに更に安定剤、顔料を加えたものを加熱、混合すると
ともに、前記混合物のうち浦の添加量を可塑旧と油との
混合物100重量部に対し10〜90重量部とすること
を要旨とする。The present invention has been made in view of the above-mentioned circumstances, and is intended to significantly reduce the adhesion of biological bodies such as barnacles, snails, and algae to the bottoms of ships, seawater intakes of thermal power plants, etc. [Means for solving the problem] In the present invention, 250 to 650 parts by weight of a mixture consisting of a plasticizer and URA is added to 100 parts by weight of a polyvinyl chloride resin or a copolymer containing polyvinyl chloride, or a stabilizer and a pigment are further added to these. The substance is heated and mixed, and the amount of ura added to the mixture is 10 to 90 parts by weight per 100 parts by weight of the mixture of plasticizer and oil.
本発明に係るポリ塩化ビニルを含む共重合体としては、
例えはポリ塩化ビニルと酢酸ビニルの共重合体等か挙げ
られる。The copolymer containing polyvinyl chloride according to the present invention includes:
An example is a copolymer of polyvinyl chloride and vinyl acetate.
本発明に係る可塑剤としては、例えばジオクチルフタレ
−1・、シブチルフタレ−1・、シイソシルフタレ−I
・等のフタル酸エステル系可塑剤、シメチルセハゲ−1
−、ンブチルセハケートなとのセバンン酸系可塑剤、ト
リエチルヘキンルトリメリテ−1−なとのトリメリット
ルホスフェ−1・竹の燐酸エステル系可塑剤、メタクリ
ル酸エステル系nJ塑剤か挙げられる。Examples of the plasticizer according to the present invention include dioctyl phthale-1, sibutyl phthale-1, and cyisosyl phthale-I.
Phthalate ester plasticizers such as ・Simethylsehage-1
-, sebanic acid plasticizers such as nbutyl sehacate, trimerityl phosphate-1 and bamboo phosphate plasticizers, and methacrylic acid ester nJ plasticizers. It will be done.
本発明に係る浦としては、例えば機器浦、食用油、絶縁
油、廃油等が挙げられる。Examples of the ura according to the present invention include equipment ura, edible oil, insulating oil, waste oil, and the like.
本発明において、上記可塑剤と浦の混合物の添加量は、
ポリ塩化ビニル樹脂又はポリ塩化ビニルを含む共重合体
100重量部に対し250〜650重量部とする。この
理由は、可塑剤と油の混合物か250重量部未満の場合
形成された生物体(=1着防止組成物か硬ずきて変形性
か悪くなり、逆に650重量部を越えると柔がずきて組
成物の保持性か悪くなるがらである。また、上記浦の添
加量は、可塑剤と油の合計ffi 1 0 0重間部に
対し10〜90重量部とする。この理由は、]0重量部
未満では浦を添加する効果が十分発揮できず、又90重
量部を越えるとセリ−状になりにくくなるためである。In the present invention, the amount of the mixture of plasticizer and ura added is as follows:
The amount is 250 to 650 parts by weight per 100 parts by weight of the polyvinyl chloride resin or copolymer containing polyvinyl chloride. The reason for this is that if the mixture of plasticizer and oil is less than 250 parts by weight, the biological bodies (= 1-wear prevention composition) will become hard and have poor deformability; In addition, the amount of the above-mentioned ura added is 10 to 90 parts by weight per 100 parts by weight of the total plasticizer and oil.The reason for this is ] If it is less than 0 parts by weight, the effect of adding ura cannot be sufficiently exhibited, and if it exceeds 90 parts by weight, it becomes difficult to form a celery.
本発明において、各原料を一緒に加熱混合しても良いし
、あるいは可塑剤と油の混合物を加熱しておきそこにポ
リ塩化ビニル樹脂又はポリ塩化ビニルを含む共重合体を
加えて加熱混合してもよい。In the present invention, each raw material may be heated and mixed together, or a mixture of a plasticizer and an oil may be heated, and a polyvinyl chloride resin or a copolymer containing polyvinyl chloride may be added thereto and then heated and mixed. You can.
ここで、加熱温度は略1 6 0〜220℃程度で、加
熱時間は10〜30分程度とする。Here, the heating temperature is about 160 to 220°C, and the heating time is about 10 to 30 minutes.
[作用]
本発明において、ポリ塩化ビニル樹脂又はポリ塩化ビニ
ルを含む共重合体は溶融して可塑剤,浦と一体化するか
、加熱混合が終了した後室温に戻すとセリ−状の固形物
となる。そして、この固形物は、再加熱(略9 0 ’
C以上)すると容易に液状となる。液状物を対象物の所
定の箇所に公知の方/1.(例えばスプレーなど)で塗
布して、作意の形状にする。その結果、その対象物か長
期間海水や河川の水中等に浸漬していても本発明に係る
組成物を塗布した箇所には貝類等の付着は全く見当らな
い。また、その組成物は公知の方法を用いて塗布できる
ため加工か容易であり、腐蝕の恐れもない。[Function] In the present invention, the polyvinyl chloride resin or the copolymer containing polyvinyl chloride is melted and integrated with the plasticizer and ura, or when heated and mixed and returned to room temperature, it forms a celery-like solid. becomes. This solid material is then reheated (approximately 90'
C or higher), it becomes liquid easily. Those who are known to apply a liquid substance to a predetermined location on an object/1. (for example, by spraying) and form it into the desired shape. As a result, even if the object was immersed in seawater or river water for a long period of time, no shellfish or the like was found to be attached to the area to which the composition of the present invention was applied. Further, since the composition can be applied using known methods, it is easy to process and there is no fear of corrosion.
[実施例コ 以下、本発明の実施例について説明する。[Example code] Examples of the present invention will be described below.
(実施例1)
ポリ塩化ビニル樹脂 1. O O重量部ンオ
クチルフタジート(可塑剤)
300重量部
絶縁油 200重量部錫系安定剤
10重量部上記原月利うち、まず
ジオクチルフタレート及び絶縁油を]90°Cに加熱す
る。つぎに、これらにポリ塩化ビニル樹脂及び安定剤を
少しずつ添加混合し全体を190°Cに擲て10分間均
一に混合する。この後、室温まで低下させたところゼリ
ー状固形物となった(方法コ)。一方、この方法]とは
別に、上記全原料を同時に混合撹拌しながら加熱L 1
90 ’Cにて10分間均一に混合した後、室温に低下
させたところ、セリ−状の固形物を得た(方法2)。次
に、この様にして得られたセリー状固形物を140 ’
Cに再加熱して3mmX200mmX400mmのシー
トを形成【7た。(Example 1) Polyvinyl chloride resin 1. O Parts by weight Octyl phthalate (plasticizer) 300 parts by weight Insulating oil 200 parts by weight Tin stabilizer 10 parts by weight First, dioctyl phthalate and insulating oil were heated to 90°C. Next, a polyvinyl chloride resin and a stabilizer are added and mixed little by little, and the whole is heated to 190°C and mixed uniformly for 10 minutes. Thereafter, when the temperature was lowered to room temperature, it became a jelly-like solid (Method C). On the other hand, apart from this method], all the above raw materials were heated while being mixed and stirred at the same time.
After uniformly mixing for 10 minutes at 90'C, the mixture was cooled to room temperature to obtain a celery-like solid (Method 2). Next, the celery-like solid obtained in this way was
C. to form a sheet of 3 mm x 200 mm x 400 mm [7].
上記実施例1によれば、ポリ塩化ビニル樹脂。According to Example 1 above, polyvinyl chloride resin.
ジオクチルフタレ−1・(可塑剤)、絶縁面、及び錫系
安定剤を適宜加熱・混合してセリー状固形物を形成し、
これを所定の形状にシートを作るため、係るン−1・を
船舶の常に海水に浸漬している船底性に貼りつけて使用
すれば、以下に述べる種々の効果か得られる。Dioctylphthale-1 (plasticizer), an insulating surface, and a tin-based stabilizer are appropriately heated and mixed to form a celery-like solid,
In order to make a sheet in a predetermined shape, if the N-1 is used by pasting it on the bottom of a ship, which is constantly immersed in seawater, various effects described below can be obtained.
Q) l記ン−1・か(1,?”Z L、た箇所ての海
中の生物体のイ・I’ i:’+を極端に少なくてきる
。事実、上記方法]12に係るシートを、ポリエチレン
板、ポリウレタン板、鉄板とともに3ケ月海洋中に沈め
ておいたところ、本発明に係るシー1・にはほとんと生
物体かイ・1石せず、他の板には貝類、藻類等多く伺2
’j L−ていた。Q) 1,?"Z L, the I'i:'+ of underwater living organisms is extremely reduced. In fact, the sheet related to the above method] 12 was submerged in the ocean for three months together with a polyethylene plate, a polyurethane plate, and an iron plate, and found that there was hardly any living organisms on Sea 1 according to the present invention, and shellfish and algae on the other plates. Etc. a lot of questions 2
'j L-was.
■上記シートは公知の方法を用いて貼着できるため加工
か′d易であり、かかるシートで覆われた部分の腐蝕の
恐れもない。(2) Since the above-mentioned sheet can be attached using a known method, it is easy to process, and there is no fear of corrosion of the portion covered with the sheet.
■上記シートかセリ−状であるため、対象物となる構造
体に凹凸かあっても施工性か良好である。(2) Since the sheet is in the form of a celery, it has good workability even if the target structure has unevenness.
また、面密着力か強い。Also, it has strong surface adhesion.
■従来の如く塗料を使用する必要かないため、肝性か生
じる恐れもな(、またコスト高になるのを回避できる。■As there is no need to use paint as in the past, there is no risk of liver damage (and high costs can be avoided).
(実施例2)
ポリ塩化ビニル樹脂 100重量部ジメチルセ
ハゲー1・(可塑剤)200重量部絶縁絶縁面
250重量部錫系安定剤
]O重量部置部各j皇イー1を実施例ユにおける方法
1.方法2と同様にし2てセリ−状の固形物を形成し、
その後実施例]と同様な形状のシートとじた。こうして
得られたン−1・についても実際に実験したところ実施
例]と同様な効果か111られた。(Example 2) Polyvinyl chloride resin 100 parts by weight Dimethyl chloride 1 (plasticizer) 200 parts by weight Insulating insulation surface
250 parts by weight tin stabilizer
] Method 1 in Example 1. Form a celery-like solid in the same manner as method 2,
Thereafter, sheets of the same shape as in Example] were bound. When the thus obtained N-1 was actually tested, it was found that the same effect as in Example 111 was obtained.
なお、上記実施例では、可塑剤としてジオクチルフタ1
ノート、ンメチルセハケートを、浦として絶縁面を用い
た場合について述べたが、これに限定されず、前記[手
段と作用]の欄で既述した種々の可塑剤、油を用いても
よい。また、本発明においては上述したポリ塩化ビニル
樹脂の他、顔料等の添加剤を加えてもよい。In the above example, dioctyl phthalate 1 was used as the plasticizer.
Note: Although the case where the insulating surface is used as the ura is described, the present invention is not limited to this, and various plasticizers and oils mentioned in the above [Means and Effects] column may also be used. . Furthermore, in the present invention, additives such as pigments may be added in addition to the above-mentioned polyvinyl chloride resin.
[発明の効果]
以上詳述した如く本発明によれば、フジッボや烏貝や藻
等の生物体か船舶の船底や火力発電の海水取入れ口等に
411着するのを著しく低減するとともに、加工性1施
工性2作業性等の点で優れた生物体イ・j着防1に組成
物を製造する方法を提供できる。[Effects of the Invention] As described in detail above, according to the present invention, it is possible to significantly reduce the amount of living organisms such as Fujibo, snails, and algae deposited on the bottoms of ships, seawater intakes for thermal power generation, etc., and to improve workability. It is possible to provide a method for producing a composition that is excellent in terms of (1) workability, (2) workability, etc., and is resistant to adhesion to living organisms.
出願人代理人 弁理士 鈴江武彦 −つ −Applicant's agent: Patent attorney Takehiko Suzue −tsu −
Claims (1)
100重量部に対し、可塑剤と油からなる混合物250
〜650重量部を加えたものあるいはこれらに更に安定
剤、顔料を加えたものを加熱、混合するとともに、前記
混合物のうち油の添加量を可塑材と油との混合物100
重量部に対し10〜90重量部とすることを特徴とする
生物体付着防止組成物の製造方法。250 parts by weight of a mixture consisting of a plasticizer and oil per 100 parts by weight of a polyvinyl chloride resin or a copolymer containing polyvinyl chloride
~650 parts by weight of the plasticizer and the oil are heated and mixed, and the amount of oil added to the mixture is reduced to 100 parts by weight of the plasticizer and the oil.
A method for producing a composition for preventing attachment of living organisms, characterized in that the amount is 10 to 90 parts by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15241488A JPH01319557A (en) | 1988-06-22 | 1988-06-22 | Production of organism-latching-preventive composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15241488A JPH01319557A (en) | 1988-06-22 | 1988-06-22 | Production of organism-latching-preventive composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01319557A true JPH01319557A (en) | 1989-12-25 |
Family
ID=15539991
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15241488A Pending JPH01319557A (en) | 1988-06-22 | 1988-06-22 | Production of organism-latching-preventive composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01319557A (en) |
-
1988
- 1988-06-22 JP JP15241488A patent/JPH01319557A/en active Pending
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