JPH01294393A - Method for bonding plane warmer - Google Patents

Method for bonding plane warmer

Info

Publication number
JPH01294393A
JPH01294393A JP63124317A JP12431788A JPH01294393A JP H01294393 A JPH01294393 A JP H01294393A JP 63124317 A JP63124317 A JP 63124317A JP 12431788 A JP12431788 A JP 12431788A JP H01294393 A JPH01294393 A JP H01294393A
Authority
JP
Japan
Prior art keywords
heating
dielectric
adhesive
adhesive sheet
bonding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63124317A
Other languages
Japanese (ja)
Inventor
Yoshio Kishimoto
岸本 良雄
Hiroshi Kobayashi
寛 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP63124317A priority Critical patent/JPH01294393A/en
Publication of JPH01294393A publication Critical patent/JPH01294393A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/34Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement"
    • B29C65/3404Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint
    • B29C65/3408Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising single particles, e.g. fillers or discontinuous fibre-reinforcements
    • B29C65/3412Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using heated elements which remain in the joint, e.g. "verlorenes Schweisselement" characterised by the type of heated elements which remain in the joint comprising single particles, e.g. fillers or discontinuous fibre-reinforcements comprising fillers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/04Dielectric heating, e.g. high-frequency welding, i.e. radio frequency welding of plastic materials having dielectric properties, e.g. PVC
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4855Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by their physical properties, e.g. being electrically-conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4865Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding containing additives
    • B29C65/487Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding containing additives characterised by their shape, e.g. being fibres or being spherical
    • B29C65/4875Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding containing additives characterised by their shape, e.g. being fibres or being spherical being spherical, e.g. particles or powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/50Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
    • B29C65/5057Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like positioned between the surfaces to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/45Joining of substantially the whole surface of the articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/729Textile or other fibrous material made from plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/729Textile or other fibrous material made from plastics
    • B29C66/7294Non woven mats, e.g. felt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/832Reciprocating joining or pressing tools
    • B29C66/8322Joining or pressing tools reciprocating along one axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/303Particular design of joint configurations the joint involving an anchoring effect
    • B29C66/3034Particular design of joint configurations the joint involving an anchoring effect making use of additional elements, e.g. meshes
    • B29C66/30341Particular design of joint configurations the joint involving an anchoring effect making use of additional elements, e.g. meshes non-integral with the parts to be joined, e.g. making use of extra elements

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Surface Heating Bodies (AREA)

Abstract

PURPOSE:To achieve the bonding with good feeling efficiently as to time and cost, by heating and melting an adhesive sheet containing electrically conductive particles through dielectric heating to bond two plane base members, upper and lower ones, for use in a plane warmer. CONSTITUTION:A flexible heating wire 1a is disposed on a hot-melt adhesive sheet and heat fused to produce an dielectric heating adhesive sheet 1. This is sandwiched between a nap-raising right side cloth 3 as an upper plane base member and a heat insulating felt 2 as a lower plane base member and these are placed between the electrode plates 4 to be heated and bonded together by a high frequency power supply 5. Here the polymeric sheet containing electrically conductive particles shows the properties of Maxwell-Wagner type composite dielectric and produces a large amount of heat due to dielectric loss so that it can be used as an adhesive with large heating effect by dielectric heating. Thus, the bonding can be achieved very efficiently as to cost and time.

Description

【発明の詳細な説明】[Detailed description of the invention]

産業上の利用分野 本発明は、主に電気カーペットとして利用する面状採暖
具の接着方法に関する。 従来の技術 従来、電気カーペット等に用いる表布はニードルパンチ
フェルトなどの不織布やフレンチパイル等を使用してお
り、比較的表面は平滑で、クツション性のない硬質のも
のであった。このようなニードルパンチフェルト等の平
滑表布では、ホットメルト接着剤を用いて熱プレス接着
が容易であったのに対し、一般カーペットのようなりッ
ション性のよい立毛表布は熱プレス工程で毛が倒れるこ
とから、中にヒータを組込んだ電気カーペットに立毛表
布を使用することには種々の難しさと制約があった。具
体的に立毛表布をヒータユニットに接着する方法として
、■ホットプレスによりホットメルト接着剤を融着させ
る方法0ホットメルト接着剤を塗布と同時に接着させる
方法■溶剤系′または水性エマルジョン系接着剤を塗工
後貼り合わせ、時間をかけて接着する方法ゆ接着剤塗工
後短時間で化学架橋し硬化させ接着する方法等がある。 発明が解決しようとする課題 しかしながら■の方法は立毛が倒れ、風合を損ねるとい
う問題点がある。また厚手の表布の場合、接着加熱時間
も長く要す。■の方法では工程的に難しく、工程ロスが
大きい。■の方法では、溶剤系の場合、溶剤臭がひどく
、また水性エマルジョン系では長い接着時間を要す。さ
らに@の方法は材料が限られており、種々の性能を満足
する材料はきわめて少ない。 本発明の面状採暖具の接着方法は、このような効率が悪
く、かつ表布の風合いを損ねるという課題を解決し、時
間的にもコスト的にも効率的でfJ’つ風合いのよい接
着方法を提供するものである。 課題を解決するための手段 上記課題を解決し、本発明の面状採暖具の接着方法は導
電粒子含有接着剤シートを用い、それを誘電加熱によっ
て加熱させ、面状採暖具用の上下二枚の面状基材を接着
させるものである。 作   用 上記方法において、誘電加熱方法により導電粒子含有接
着剤シートが乾燥固化され、上下二枚の面状基材が接着
することになる。 実施例 以下、本発明の一実施例を図面を用いて説明する。 図において、カーボンブラックを含有した105Ω”C
71のエチレンヂ酢酸ビニル共重合体系ホットーハイフ
l メルト接着剤シート(150μm厚)上に可撓性線状発
熱線1g(最外被覆としてポリエチレン接着層がついて
いる)を配し、熱融着し、発熱線基材1とした。これを
面状基材上としての立毛表布3および面状基材下として
の断熱フェルト2とによりサンドイッチ状に重ね、電極
板4間に設置し、高周波電源5にて、画電極板4間に1
2MHzで高周波電界を40秒間かけ、加熱接着した。 接着直後のピーリング接着強度は4.3 KSI/ 2
.5 cm幅であった。 次に本発明の内容を詳しく説明する。 導電粒子含有接着剤とは導電粒子あるいは導電性ウィス
カーが、接着剤中に分散されたものを言うが、ホットメ
ルト接着剤中に分散し、体積固有抵抗を102〜108
Ω・口にしたものが最適である。この体積固有抵抗が低
すぎると発熱が過度に大きく発火し、高すぎると発熱効
率が低く接着できない。導電粒子または導電性ウィスカ
ーとしては、カーボンブラック、銅、アルミニウム、酸
化スズ、酸化亜鉛よりなるものが適するが、中でもカー
ボンブラック、アルミニウムが最も適している。この導
電粒子含有接着剤シートはマクスウェル−ワグナ形の複
合誘電体としての性質を示し、高周波電界中で、大きな
誘電率と大きな誘電損率を示し、誘電損による大きな発
熱をする。このようにホットメルト接着剤を導電粒子含
有接着剤とすることにより誘電加熱による発熱効果の大
きい接着剤とすることができ、これをさらに本発明のよ
うにシート状にして利用することにより最も簡便で、低
コスト、高効率の接着方法を提供することができる。こ
の導電粒子含有接着剤シートが正の大きな抵抗温度係数
(PTCと略す)を有すわば、融点まで速く加熱され、
その後は温度上昇が少ないから、より適切に加熱できる
。このPTC材料は結晶性高分子をマl−IJクス高分
子とすることにより構成できる。 本発明における誘電加熱方法とは、高周波電界下で誘電
損率の高い接着剤を発熱させ、接着するもので、マイク
ロ波をあてることによっても同様に加熱接着できる。高
周波電界としては2 M Hz〜数iQQMHzの範囲
のものを用いる。中でも6〜3 Q M Hz程度が実
際的である。この誘電加熱方法を適用する時、接着剤の
みが最もよく加熱され、他の基材は直接的にはあまり加
熱されないのが効率的である。すなわち、接着剤の誘電
損率が他の基材に比べて桁違いに大きいことが大切であ
る。本発明における導電粒子含有接着剤シートはこの条
件を満たしている。接着剤基材中に可撓性線状発熱線を
有する場合でも発熱用導線が断線がなく、連続した線で
あれば高周波電界中における局所発熱効果は生じない。 また、比較的大きな誘電率(ε=5〜10)をもつ軟質
ポリ塩化ビニル外被の電線であっても、本発明における
接着剤の誘電損率の方が桁違いに大きいため、本発明の
接着方法は非常に有効である。 発明の効果 本発明は非常に簡便な方法で面状採暖具の接着を可能に
するもので、コスト的にも時間的にも非常に高効率の接
着方法を提供するものである。また、導電粒子含有接着
シートは熱伝導率がよく、熱を面方向に広げる効果も有
する。
INDUSTRIAL APPLICATION FIELD The present invention relates to a method of adhering a planar heating device mainly used as an electric carpet. BACKGROUND OF THE INVENTION Conventionally, outer fabrics used for electric carpets and the like have been made of nonwoven fabrics such as needle punch felt, French pile, etc., and have relatively smooth surfaces and are hard with no cushioning properties. Smooth outer fabrics such as needle punch felt can be easily bonded by heat press using hot melt adhesive, whereas raised outer fabrics with good cushioning properties, such as general carpets, are bristled during the heat press process. There are various difficulties and restrictions in using raised fabric for electric carpets with built-in heaters, as the fabric may fall over. Specifically, the methods for adhering the raised outer fabric to the heater unit include: ■ A method of fusing a hot melt adhesive using a hot press. A method of adhering the hot melt adhesive at the same time as application. ■ A solvent-based or water-based emulsion adhesive. There are two methods: one method involves applying an adhesive and then bonding it over time, and the other method involves chemically crosslinking and curing the adhesive in a short period of time after applying the adhesive. Problems to be Solved by the Invention However, method (2) has a problem in that the raised pile falls down and the texture is impaired. In addition, in the case of a thick outer fabric, it takes a long time to heat the adhesive. Method (2) is difficult in terms of process and involves large process losses. In method (2), if a solvent-based adhesive is used, the solvent odor is severe, and if an aqueous emulsion-based adhesive is used, a long bonding time is required. Furthermore, the materials used in the @ method are limited, and there are very few materials that satisfy various performances. The bonding method for sheet heating equipment of the present invention solves the problem of poor efficiency and impairing the texture of the outer fabric, and achieves a bonding method that is efficient in terms of time and cost and has a good texture. The present invention provides a method. Means for Solving the Problems Solving the above problems, the method of adhering a planar heating device of the present invention uses an adhesive sheet containing conductive particles, heats it by dielectric heating, and attaches the upper and lower sheets of the planar heating device. It is used to bond two planar base materials. Function In the above method, the conductive particle-containing adhesive sheet is dried and solidified by the dielectric heating method, and the two planar substrates, the upper and lower sheets, are bonded together. EXAMPLE Hereinafter, an example of the present invention will be described with reference to the drawings. In the figure, 105Ω”C containing carbon black
71 ethylene divinyl acetate copolymer Hot-High Melt adhesive sheet (150 μm thick), 1 g of flexible linear heating wire (with a polyethylene adhesive layer as the outermost coating) is placed, heat-sealed, and heat-generating. It was set as wire base material 1. This is layered in a sandwich-like manner with a raised cloth 3 on the planar base material and a heat insulating felt 2 as the bottom of the planar base material, and placed between the electrode plates 4. to 1
A high frequency electric field of 2 MHz was applied for 40 seconds to heat and bond. Peeling adhesive strength immediately after adhesion is 4.3 KSI/2
.. It was 5 cm wide. Next, the content of the present invention will be explained in detail. Conductive particle-containing adhesive refers to an adhesive in which conductive particles or conductive whiskers are dispersed in a hot melt adhesive, with a volume resistivity of 102 to 108.
Ω・The best thing is what you eat. If this volume resistivity is too low, the heat generated will be too large, and if it is too high, the heat generation efficiency will be low and bonding will not be possible. Suitable conductive particles or conductive whiskers include those made of carbon black, copper, aluminum, tin oxide, and zinc oxide, of which carbon black and aluminum are most suitable. This adhesive sheet containing conductive particles exhibits properties as a Maxwell-Wagner type composite dielectric, exhibits a large dielectric constant and a large dielectric loss factor in a high frequency electric field, and generates a large amount of heat due to the dielectric loss. In this way, by using a hot melt adhesive as an adhesive containing conductive particles, it is possible to create an adhesive that has a large heat generation effect due to dielectric heating, and it is also most convenient to use it in the form of a sheet as in the present invention. Therefore, it is possible to provide a low-cost, high-efficiency bonding method. If this conductive particle-containing adhesive sheet has a large positive temperature coefficient of resistance (abbreviated as PTC), it will be quickly heated to the melting point.
After that, the temperature rise is small, so it can be heated more appropriately. This PTC material can be constructed by using a crystalline polymer as a Marx polymer. The dielectric heating method in the present invention is a method in which an adhesive having a high dielectric loss factor is heated under a high frequency electric field for bonding, and heat bonding can also be achieved by applying microwaves. As the high frequency electric field, one in the range of 2 MHz to several iQQMHz is used. Among them, about 6 to 3 Q MHz is practical. When applying this dielectric heating method, it is efficient that only the adhesive is heated most of the time, and other substrates are not heated directly. That is, it is important that the dielectric loss factor of the adhesive be orders of magnitude higher than that of other base materials. The conductive particle-containing adhesive sheet of the present invention satisfies this condition. Even when a flexible linear heating wire is included in the adhesive base material, if the heating conductor is a continuous wire without breakage, no local heating effect will occur in a high frequency electric field. Furthermore, even for electric wires coated with soft polyvinyl chloride having a relatively large dielectric constant (ε=5 to 10), the dielectric loss factor of the adhesive used in the present invention is orders of magnitude larger, so the present invention The adhesive method is very effective. Effects of the Invention The present invention enables bonding of planar heating devices using a very simple method, and provides a bonding method that is extremely efficient in terms of cost and time. Further, the conductive particle-containing adhesive sheet has good thermal conductivity and has the effect of spreading heat in the surface direction.

【図面の簡単な説明】[Brief explanation of the drawing]

図は本発明における誘電加熱による電気カーペットの接
着方法を示す図。 1・・・・・・発熱線基材、2・・・・・・断熱フェル
ト、3・・・・・・表布、4・・・・・・電極板、5・
−・・・・高周波電界。 代理人の氏名 弁理士 中 尾 敏 男 ほか1名/−
−−発熱線基材 /a、 −一一可撓ノト住[=1〜でドζ状発3守シ(
を泉?−絣涜色ブエルト 3−立毛表布 4− 電」i坂 、5−  高凧液電源 手続補正書(自発) 昭和63年12月27日 昭和63年彷許願第124317号 2発明の名称 誘電加熱接着シートおよびそれを用いた面状採暖具3補
正をする者 事件との関係      特   許   出   願
  大佐 所  大阪府門真市大字門真1′I06番地
名 称 (582)松下電器産業株式会社代表者   
 谷  井  昭  雄 4代理人 〒571 住 所  大阪府門真市大字門真1006番地松下電器
産業株式会社内 6、補正の内容 (2)願書の請求項の数の欄の「6」を「8」に訂正し
ます。 (3)明細書を別紙の通り全文訂正します。 (4)図面を別紙の通り訂正し1す。 全文訂正明細書 1、発明の名称 誘電加熱接着シートおよびそれを用いた面状採暖具 2、特許請求の範囲 子または導電性ウィスカーを分散させてなる導シート。 (4)ホットメルト接着剤がポリエチレン、エチレン−
酢酸ビニル共重合体、ポリアミド、ポリエステルあるい
はこれら各々の共重合体より選ばれた少くとも1つを主
成分とする請求項1記載〜108Ω・臨の体積固有抵抗
を持つ請求項1記抗温度係数を有する材料である請求項
2または配線し、接着して配線シートとし、これを上下
二枚の面状基材中にはさんで、誘電加熱方法により加熱
させて融着してなる面状採暖具。 (8)可撓性線状発熱線の最外被覆が、誘電加熱接着シ
ートを構成するホ7)メルト接着剤と同−具。 3、発明の詳細な説明 り電工の利用男性 本発明は、主に電気カーペットに用いる誘電加熱接着シ
ートおよびそれを用いた面状採暖具に関する。 従来の技術 従来、電電カーペット等て用いる表布はニードルパンチ
フェルトなどの不織布やフレンチパイル等を使用してお
り、比較的表面は平滑で、クツション性のない硬質のも
のであった。このようなニードルパンチフェルト等の平
滑表布では、ホットメルト接着剤を用いて熱プレス接着
が容易であったのに対し、一般カーペットのようなりソ
ション性のよい立毛表布は熱プレス工程で毛が倒れるこ
とから、中にヒータを組込んだ電気カーペットに立毛表
布を使用することには種々の難しさと制約があった。具
体的に立毛表布をヒータユニットに接着する方法として
、■ホットプレスによりホットメルト接着剤を融着させ
る方法■ホントメルト接着剤を塗布と同時に接着させる
方法■溶剤系または水性エマルジョン系接着剤を塗工後
貼り合わせ1時間をかけて接着する方法■接着剤塗工後
短時間で化学架橋し硬化させ接着する方法等がある。 発明が解決しようとする課題 しかしながら■の方法は立毛が倒れ、風合を損ねるとい
う問題点がある。また厚手の表布の場合。 接着加熱時間も長く要す。■の方法では工程的に難しく
、工程ロスが大きい。■の方法では、溶剤系の場合、溶
剤臭がひどく、まだ水性エマル′ジョン系では長い接着
時間を要す。さらに■の方法は材料が限られており、種
々の性能を満足する材料はきわめて少ない。 本発明の面状採暖具の接着方法は、このような効率が悪
く、かつ表布の風合いを損ねるという課題を解決し、時
間的にもコスト的にも効率的でかつ風合いのよい接着方
法を提供するものである。 課題を解決するだめの手段 上記課題を解決するため1本発明の誘電接着シートおよ
びそれを用いた面状採暖具は、誘電加熱接着シートを用
い、それを誘電加熱によって表面を加熱溶融させ、面状
採暖具用の上下二枚の面状基材を接着させたものである
。 作用 上記構成において、誘電加熱方法により誘電加熱接着シ
ートが加熱溶融され、上下二枚の面状基材が接着するこ
とになる。 実施例 以下1本発明の一実施例を図面を用いて説明する。 図において、カーボンブラックを含有した105Ω・備
のエチレン−酢酸ビニル共重合体系ホットメルト接着剤
シー)(150μm厚)上に可撓性線状発熱線1&(最
外被覆としてポリエチレン接着層がついている)を配し
、熱融着し、発熱線を配線した誘電加熱接着シート1と
した。これを面状基材上としての立毛表布3および面状
基材下としての断熱フェルト2とによりサンドイッチ状
に重ね、電極板4間に設置し、高周波電源5にて。 画電極板4間に12MH2で高周波電界を40秒間かけ
、加熱接着した。接着直後のビーリング接着強度は4.
3KP/2−5’m幅であった。 次に本発明の内容を詳しく説明する。 本発明の誘電加熱接着シートは、少くともその表面がホ
ットメルト接着剤よりなる誘電加熱発熱シートよりなり
、前記発熱シートは高分子中に導電粒子まだは導電性ウ
ィスカーを分散させてなる導電粒子含有高分子シートよ
り構成される。本発明の誘電加熱接着シートの構成とし
ては、シート全体がホットメルト接着性をもつものと、
発熱シートの表面にのみ、ホットメルト接着剤が形成さ
れたものの2つがある。 導電粒子含有高分子シートとは導電粒子あるいは導電性
ウィスカーが、高分子中に分散されたものを言うが1体
積固有抵抗を1o2〜108Ω・備にしだものが最適で
ある。この体積固有抵抗が低すぎると発熱が過度に大き
く発火し、高すぎると発熱効率が低く接着できない。導
電粒子まだは導電性ウィスカーとしては、カーボンプラ
・ツク、銅。 アルミニウム、酸化スズ、酸化亜鉛よりなるものが適す
るが、中でもカーボンブラック、アルミニウムが最も適
している。この導電粒子含有高分子シートはマクスウェ
ル−ワグナ形の複合誘電体としての性質を示し、高周波
電界中で、大きな誘電率(2000〜300Q以上)と
大きな誘電損率を示し、誘電損による大きな発熱をする
。このようにホ7)メルト接着剤を導電粒子含有接着剤
とすることにより、誘T7Il]熱による発熱効果の大
きい接着剤とすることができ、これをさらに本発明のよ
うにシート状にして利用することにより最も簡便で、低
コスト、高効率の接着方法を提供することができる。こ
の導電粒子含有高分子シートが正の大きな抵抗温度係数
(PTCと略す)を有すれば。 表面のホットメルト接着剤の融点まで速く加熱され、そ
の後は温度上昇が少ないから、より適切に加熱できる。 このPTC材料は結晶性高分子をマトリクス高分子とす
ることにより構成できる。 本発明における誘電加熱方法とは、高周波電界下で誘電
損率の高い接着性シートを発熱させ、接着するもので、
マイクロ波をあてることによっても同様に加熱接着でき
る。高周波電界としては2M)lz〜数100MH7の
範囲のものを用いる。中でも6〜80 M )lz程度
が実際的である。この誘電加熱方法を適用する時、接着
剤のみが最もよく加熱され、他の基材は直接的にはあ1
り加熱されないのが効率的である。すなわち、接着剤の
誘電損率が他の基材に比べて佑違いに大きいことが大切
である。本発明における導電粒子含有高分子シートはこ
の条件を満たしている。接着剤基材中に可撓性線状発熱
線を有する場合でも発熱用導線が断線がなく、連続した
線であれば高周波電界中における局所発熱効果は生じな
い。また、比較的大きな誘電率(ε=5〜10)をもつ
軟質ポリ塩化ビニル昇級の電線であっても、本発明にお
ける接着シートの誘電損率の方が桁違いに大きいため2
本発明の接着方法は非常に有効である。 発明の効果 本発明は非常に簡便な方法で面状採暖具の接着を可能に
するもので、コスト的にも時間的にも非常に高効率の接
着方法を提供するものである。まだ、導電粒子含有高分
子シートは熱伝導率がよく。 熱を面方向に広げる効果も有する。
The figure shows a method of adhering an electric carpet using dielectric heating according to the present invention. DESCRIPTION OF SYMBOLS 1...Heating wire base material, 2...Insulating felt, 3...Outer fabric, 4...Electrode plate, 5...
−・・・High frequency electric field. Name of agent: Patent attorney Toshio Nakao and 1 other person/-
--Heating wire base material/a, -11 flexible note housing [= 1~ and do ζ-shaped 3 shields (
Izumi? - Kasuri Shokuiro Vuelto 3 - Raised Outer Cloth 4 - Den'i Saka, 5 - High Kite Liquid Power Supply Procedure Amendment (Spontaneous) December 27, 1988 Wandering Application No. 124317 2 Name of Invention Dielectric Heating Adhesive sheet and its relation to the case of a person who corrects a surface heating device using the same Patent application Colonel Address 1'I06 Oaza Kadoma, Kadoma City, Osaka Name (582) Representative of Matsushita Electric Industrial Co., Ltd.
Akio Tanii 4 Agent 571 Address 6, Matsushita Electric Industrial Co., Ltd., 1006 Oaza Kadoma, Kadoma City, Osaka Prefecture Details of the amendment (2) Changed "6" in the number of claims column of the application to "8" Correct. (3) Correct the entire statement as shown in the attached document. (4) Correct the drawing as shown in the attached sheet. Full text correction specification 1, name of the invention, dielectric heating adhesive sheet and planar heating device using the same 2, claim 2, a conductive sheet formed by dispersing conductive whiskers. (4) Hot melt adhesive is polyethylene, ethylene-
Claim 1, wherein the main component is at least one selected from vinyl acetate copolymer, polyamide, polyester, or a copolymer of each of these, and has a volume resistivity of 108 Ω·min. Claim 2 or a sheet heating material made by wiring and gluing to form a wiring sheet, sandwiching this between two upper and lower sheet substrates, and heating and fusing them using a dielectric heating method. Ingredients. (8) The outermost covering of the flexible linear heating wire constitutes a dielectric heating adhesive sheet.7) The same tool as the melt adhesive. 3. Detailed Description of the Invention The present invention relates to a dielectric heating adhesive sheet mainly used for electric carpets and a planar heating device using the same. BACKGROUND OF THE INVENTION Conventionally, the outer fabric used for electric carpets and the like has been made of nonwoven fabrics such as needle punch felt, French pile, etc., and has a relatively smooth surface and is hard and has no cushioning properties. Smooth outer fabrics such as needle punch felt can be easily bonded by heat press using hot melt adhesive, whereas raised outer fabrics with good damping properties, such as ordinary carpets, do not fluff during the heat press process. There are various difficulties and restrictions in using raised fabric for electric carpets with built-in heaters, as the fabric may fall over. Specifically, the methods for adhering the raised outer fabric to the heater unit are: ■Method of fusing hot melt adhesive by hot press ■Method of adhering real melt adhesive at the same time as application ■Method of using solvent-based or water-based emulsion adhesive There is a method of bonding over an hour after coating and bonding. There is a method of chemically crosslinking and curing the adhesive in a short period of time after applying the adhesive. Problems to be Solved by the Invention However, method (2) has a problem in that the raised pile falls down and the texture is impaired. Also for thick outer fabrics. It also takes a long time to heat the adhesive. Method (2) is difficult in terms of process and involves large process losses. In method (2), if a solvent is used, the solvent odor is severe, and if it is an aqueous emulsion, a long bonding time is required. Furthermore, the materials used in method (2) are limited, and there are very few materials that satisfy various performances. The bonding method for sheet heating equipment of the present invention solves the problem of poor efficiency and spoiling the texture of the outer fabric, and provides a bonding method that is efficient in terms of time and cost and has a good texture. This is what we provide. Means for Solving the Problems In order to solve the above problems, the dielectric adhesive sheet of the present invention and the planar heating device using the same use a dielectric heating adhesive sheet, the surface of which is heated and melted by dielectric heating, and the surface of the sheet is heated and melted. It is made by gluing together two planar substrates for a heating device. Function In the above structure, the dielectric heating adhesive sheet is heated and melted by the dielectric heating method, and the two planar base materials, the upper and lower sheets, are bonded together. Embodiment One embodiment of the present invention will be described below with reference to the drawings. In the figure, a flexible linear heating wire 1 & (a polyethylene adhesive layer is attached as the outermost coating) is placed on a 105 Ω ethylene-vinyl acetate copolymer hot melt adhesive sheet (150 μm thick) containing carbon black. ) was arranged and heat-sealed to obtain a dielectric heating adhesive sheet 1 in which heating wires were wired. This was layered in a sandwich-like manner with a raised outer cloth 3 on the planar base material and a heat insulating felt 2 as the bottom of the planar base material, placed between electrode plates 4, and powered by a high frequency power source 5. A high frequency electric field of 12 MH2 was applied between the picture electrode plates 4 for 40 seconds to bond them together by heating. Bealing adhesive strength immediately after adhesion is 4.
It was 3KP/2-5'm wide. Next, the content of the present invention will be explained in detail. The dielectric heat-adhesive sheet of the present invention comprises a dielectric heat-generating sheet at least whose surface is made of a hot melt adhesive, and the heat-generating sheet contains conductive particles formed by dispersing conductive particles or conductive whiskers in a polymer. Composed of polymer sheet. The structure of the dielectric heating adhesive sheet of the present invention includes that the entire sheet has hot melt adhesive properties,
There are two types in which hot melt adhesive is formed only on the surface of the heat generating sheet. The conductive particle-containing polymer sheet refers to one in which conductive particles or conductive whiskers are dispersed in a polymer, and a sheet having a volume resistivity of 102 to 108 Ω is most suitable. If this volume resistivity is too low, the heat generated will be too large, and if it is too high, the heat generation efficiency will be low and bonding will not be possible. Conductive particles and conductive whiskers include carbon plastic, copper. Suitable materials include aluminum, tin oxide, and zinc oxide, with carbon black and aluminum being the most suitable. This conductive particle-containing polymer sheet exhibits properties as a Maxwell-Wagner type composite dielectric, exhibiting a large dielectric constant (2000 to 300 Q or more) and a large dielectric loss factor in a high-frequency electric field, and generating large amounts of heat due to dielectric loss. do. In this way, by using the melt adhesive as an adhesive containing conductive particles, it is possible to obtain an adhesive with a large heat generation effect due to heat, and this can be further used in the form of a sheet as in the present invention. By doing so, it is possible to provide the most simple, low-cost, and highly efficient bonding method. If this conductive particle-containing polymer sheet has a large positive temperature coefficient of resistance (abbreviated as PTC). It is quickly heated to the melting point of the hot-melt adhesive on the surface, and since there is little temperature rise thereafter, it can be heated more appropriately. This PTC material can be constructed by using a crystalline polymer as a matrix polymer. The dielectric heating method in the present invention is a method in which an adhesive sheet with a high dielectric loss factor is heated and bonded under a high frequency electric field.
Heat bonding can be similarly achieved by applying microwaves. The high frequency electric field used is one in the range of 2M)lz to several 100MH7. Among them, about 6 to 80 M)lz is practical. When applying this dielectric heating method, only the adhesive is best heated, other substrates are not directly heated.
It is efficient that there is no heating. In other words, it is important that the dielectric loss factor of the adhesive be significantly larger than that of other base materials. The conductive particle-containing polymer sheet of the present invention satisfies this condition. Even when a flexible linear heating wire is included in the adhesive base material, if the heating conductor is a continuous wire without breakage, no local heating effect will occur in a high frequency electric field. In addition, even if the wire is made of soft polyvinyl chloride with a relatively large dielectric constant (ε=5 to 10), the dielectric loss factor of the adhesive sheet in the present invention is orders of magnitude larger.
The bonding method of the present invention is very effective. Effects of the Invention The present invention enables bonding of planar heating devices using a very simple method, and provides a bonding method that is extremely efficient in terms of cost and time. However, polymer sheets containing conductive particles have good thermal conductivity. It also has the effect of spreading heat in the plane direction.

【図面の簡単な説明】[Brief explanation of the drawing]

図は本発明における誘電加熱による電気カーペットの接
着方法を示す図。 1・・・・・・発熱線を配線した誘電加熱接着シート、
2・・・・・・断熱フェルト、3・・・・・・表布、4
・・・・・・電極板。 5・・・・・・高周波電界。
The figure shows a method of adhering an electric carpet using dielectric heating according to the present invention. 1... Dielectric heating adhesive sheet with heating wire wired,
2...Insulating felt, 3...Outer fabric, 4
・・・・・・Electrode plate. 5...High frequency electric field.

Claims (6)

【特許請求の範囲】[Claims] (1)ホットメルト接着剤中に導電性粒子または導電性
ウィスカーを分散させてなる導電粒子含有接着剤シート
上に、可撓性線状発熱線を配線し、接着して配線シート
とし、これを上下二枚の面状基材中にはさんで、誘電加
熱方法により加熱させて融着してなる面状採暖具の接着
方法。
(1) A flexible linear heating wire is wired onto a conductive particle-containing adhesive sheet made by dispersing conductive particles or conductive whiskers in a hot melt adhesive, and the wire is bonded to form a wiring sheet. A method for adhering a planar heating device, which is sandwiched between two planar substrates (upper and lower) and heated and fused using a dielectric heating method.
(2)ホットメルト接着剤がポリエチレン、エチレン−
酢酸ビニル共重合体、ポリアミドあるいはこれら各々の
共重合体より選ばれた少くとも1つを主成分とする請求
項1記載の面状採暖具の接着方法。
(2) Hot melt adhesive is polyethylene, ethylene-
2. The method for bonding a planar heating device according to claim 1, wherein the main component is at least one selected from vinyl acetate copolymer, polyamide, or a copolymer of each of these.
(3)導電粒子含有接着剤シートが室温にて10^2〜
10^8Ω・cmの体積固有抵抗を持つ請求項1記載の
面状採暖具の接着方法。
(3) The conductive particle-containing adhesive sheet is heated to 10^2~ at room temperature.
The method for adhering a planar heating device according to claim 1, which has a volume resistivity of 10^8 Ω·cm.
(4)導電粒子または導電性ウィスカーがカーボンブラ
ックまたはアルミニウムである請求項3記載の面状採暖
具の接着方法。
(4) The method for adhering a planar heating device according to claim 3, wherein the conductive particles or conductive whiskers are carbon black or aluminum.
(5)導電粒子含有接着剤シートが、正の大きな抵抗温
度係数を有する材料である請求項3または4記載の面状
採暖具の接着方法。
(5) The method for adhering a planar heating device according to claim 3 or 4, wherein the conductive particle-containing adhesive sheet is a material having a large positive temperature coefficient of resistance.
(6)可撓性線状発熱線の最外被覆が、導電粒子含有接
着剤シートを構成するホットメルト接着剤と同一の材料
より構成された請求項1記載の面状採暖具の接着方法。
(6) The method for adhering a planar heating device according to claim 1, wherein the outermost coating of the flexible linear heating wire is made of the same material as the hot melt adhesive constituting the conductive particle-containing adhesive sheet.
JP63124317A 1988-05-20 1988-05-20 Method for bonding plane warmer Pending JPH01294393A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63124317A JPH01294393A (en) 1988-05-20 1988-05-20 Method for bonding plane warmer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63124317A JPH01294393A (en) 1988-05-20 1988-05-20 Method for bonding plane warmer

Publications (1)

Publication Number Publication Date
JPH01294393A true JPH01294393A (en) 1989-11-28

Family

ID=14882339

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63124317A Pending JPH01294393A (en) 1988-05-20 1988-05-20 Method for bonding plane warmer

Country Status (1)

Country Link
JP (1) JPH01294393A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007507384A (en) * 2003-10-07 2007-03-29 ベール フランス ルファッシェ エス・アー・エス Heating device especially for automobiles having a PTC element
CN103862671A (en) * 2014-02-22 2014-06-18 李文忠 Hot melt adhesive technology for plastic film engineering construction
WO2018147352A1 (en) * 2017-02-09 2018-08-16 リンテック株式会社 Dielectric heating adhesive film and adhesion method using dielectric heating adhesive film
CN109890923A (en) * 2016-10-27 2019-06-14 琳得科株式会社 Dielectric heating adhesive film and the adhering method for having used dielectric heating adhesive film

Citations (3)

* Cited by examiner, † Cited by third party
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JPS5878382A (en) * 1981-11-04 1983-05-11 松下電器産業株式会社 Panel heating implement and method of producing same
JPS58106784A (en) * 1981-12-16 1983-06-25 松下電器産業株式会社 Panel heating implement
JPS62280004A (en) * 1986-05-30 1987-12-04 Showa Aircraft Ind Co Ltd Pole plate panel for high prequency heating pressing device

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Publication number Priority date Publication date Assignee Title
JPS5878382A (en) * 1981-11-04 1983-05-11 松下電器産業株式会社 Panel heating implement and method of producing same
JPS58106784A (en) * 1981-12-16 1983-06-25 松下電器産業株式会社 Panel heating implement
JPS62280004A (en) * 1986-05-30 1987-12-04 Showa Aircraft Ind Co Ltd Pole plate panel for high prequency heating pressing device

Cited By (13)

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Publication number Priority date Publication date Assignee Title
JP2007507384A (en) * 2003-10-07 2007-03-29 ベール フランス ルファッシェ エス・アー・エス Heating device especially for automobiles having a PTC element
CN103862671A (en) * 2014-02-22 2014-06-18 李文忠 Hot melt adhesive technology for plastic film engineering construction
CN109890923B (en) * 2016-10-27 2022-05-17 琳得科株式会社 Dielectric heating adhesive film and adhesive method using dielectric heating adhesive film
US11673340B2 (en) 2016-10-27 2023-06-13 Lintec Corporation Dielectric-heating bonding film and bonding method using dielectric-heating bonding film
CN109890923A (en) * 2016-10-27 2019-06-14 琳得科株式会社 Dielectric heating adhesive film and the adhering method for having used dielectric heating adhesive film
JPWO2018079355A1 (en) * 2016-10-27 2019-09-12 リンテック株式会社 Dielectric heating adhesive film and bonding method using dielectric heating adhesive film
JPWO2018079356A1 (en) * 2016-10-27 2019-09-12 リンテック株式会社 Dielectric heating adhesive film and bonding method using dielectric heating adhesive film
US11541607B2 (en) 2016-10-27 2023-01-03 Lintec Corporation Dielectric-heating bonding film and bonding method using dielectric-heating bonding film
WO2018147351A1 (en) * 2017-02-09 2018-08-16 リンテック株式会社 Dielectric heating adhesive film and adhesion method using dielectric heating adhesive film
JPWO2018147351A1 (en) * 2017-02-09 2019-11-07 リンテック株式会社 Dielectric heating adhesive film and bonding method using dielectric heating adhesive film
JPWO2018147352A1 (en) * 2017-02-09 2019-11-07 リンテック株式会社 Dielectric heating adhesive film and bonding method using dielectric heating adhesive film
CN110300782A (en) * 2017-02-09 2019-10-01 琳得科株式会社 Dielectric heating adhesive film and the adhering method for having used dielectric heating adhesive film
WO2018147352A1 (en) * 2017-02-09 2018-08-16 リンテック株式会社 Dielectric heating adhesive film and adhesion method using dielectric heating adhesive film

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