JPH01290509A - Preparation of zinc peroxide - Google Patents
Preparation of zinc peroxideInfo
- Publication number
- JPH01290509A JPH01290509A JP11900088A JP11900088A JPH01290509A JP H01290509 A JPH01290509 A JP H01290509A JP 11900088 A JP11900088 A JP 11900088A JP 11900088 A JP11900088 A JP 11900088A JP H01290509 A JPH01290509 A JP H01290509A
- Authority
- JP
- Japan
- Prior art keywords
- zinc
- carbonate
- peroxide
- hydrogen
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229940105296 zinc peroxide Drugs 0.000 title claims abstract description 29
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 43
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000011701 zinc Substances 0.000 claims abstract description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000011667 zinc carbonate Substances 0.000 claims abstract description 10
- 229910000010 zinc carbonate Inorganic materials 0.000 claims abstract description 10
- 235000004416 zinc carbonate Nutrition 0.000 claims abstract description 10
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims abstract description 10
- 229940007718 zinc hydroxide Drugs 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 29
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 16
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 13
- 239000001099 ammonium carbonate Substances 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 239000011787 zinc oxide Substances 0.000 claims description 13
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 claims description 8
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 8
- 235000011181 potassium carbonates Nutrition 0.000 claims description 8
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 7
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 7
- 239000011736 potassium bicarbonate Substances 0.000 claims description 7
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 7
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 7
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 7
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 7
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 7
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 6
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 235000017550 sodium carbonate Nutrition 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 abstract description 18
- 238000000034 method Methods 0.000 abstract description 17
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 6
- 239000006185 dispersion Substances 0.000 abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 2
- 239000012295 chemical reaction liquid Substances 0.000 abstract description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 8
- 239000004033 plastic Substances 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 238000004073 vulcanization Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 150000003752 zinc compounds Chemical class 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 150000007514 bases Chemical class 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 3
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- -1 zinc oxide in water Chemical class 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- GGZZISOUXJHYOY-UHFFFAOYSA-N 8-amino-4-hydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C2C(N)=CC=CC2=C1O GGZZISOUXJHYOY-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- AKJVMGQSGCSQBU-UHFFFAOYSA-N zinc azanidylidenezinc Chemical compound [Zn++].[N-]=[Zn].[N-]=[Zn] AKJVMGQSGCSQBU-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］。[Detailed description of the invention] [Industrial application field].
本発明は過酸化亜鉛の製造法に関し、詳細には■酸化唾
鉛、塩基性炭酸唾鉛、炭酸亜鉛および水酸化亜鉛よりな
る群から選択される１種または２種以上と、
■炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウム
、炭酸水素カリウム、炭酸アンモニウム、炭酸水素アン
モニウム、水酸化ナトリウム、水酸化カリウムおよびア
ンモニアよりなる群から選択される１種または２挿具−
１−の化合物、および
■過酸化水素
をＯ乃至８０℃の範囲で反応させることにより、過酸化
亜鉛の分解温度と過酸化物含賃を任意に調節することの
できる過酸化亜鉛の製造法に関するものである。The present invention relates to a method for producing zinc peroxide, in particular: (1) one or more selected from the group consisting of salivary lead oxide, basic salivary lead carbonate, zinc carbonate, and zinc hydroxide; (2) sodium carbonate; One or two inserts selected from the group consisting of sodium bicarbonate, potassium carbonate, potassium bicarbonate, ammonium carbonate, ammonium bicarbonate, sodium hydroxide, potassium hydroxide, and ammonia.
This invention relates to a method for producing zinc peroxide in which the decomposition temperature and peroxide content of zinc peroxide can be arbitrarily adjusted by reacting the compound of 1- and (1) hydrogen peroxide at a temperature ranging from 0 to 80°C. It is something.
［従来の技術］
過酸化亜鉛は、主として■水酸化亜鉛と過酸化水素とを
反応させる方法、あるいは＠酸化亜鉛と過酸化本末とを
反応させる方法により製造されているが、この他、■１
′！！基性炭酸亜鉛や炭酸亜鉛と過酸化水素とを反応さ
せる方法、■硝酸亜鉛と過酸化カリウムを反応させる方
法、■硫酸亜鉛と過酸化バリウムを反応させる方法、あ
るいは■ジエチル亜鉛と過酸化水素を反応させる方法等
によっても製造することができる。[Prior art] Zinc peroxide is mainly produced by (1) a method of reacting zinc hydroxide with hydrogen peroxide, or (2) a method of reacting @zinc oxide with peroxide base powder.
′! ! A method of reacting basic zinc carbonate or zinc carbonate with hydrogen peroxide, a method of reacting zinc nitrate with potassium peroxide, a method of reacting zinc sulfate with barium peroxide, or a method of reacting diethyl zinc with hydrogen peroxide. It can also be produced by a reaction method or the like.
一般に過酸化亜鉛はＺｎＯ２のほかＺｎＯとＺｎ（ＯＨ
）２ を含む混合物として得られ、市販されている過酸
化亜鉛のＺｎ０７含７政は５０〜Ｑ Ｑ ｉ 賃％の範
囲にある。上記方法のうち比較的Ｚｎ０７含−１，の高
い過酸化亜鉛を得る方法としては、酸化亜鉛と過酸化水
素とを反応させる方法、あるいはジエチル亜鉛と過酸化
水素とを反応させる方法であり、殊に後者の方法では、
ＺｎＯ２含量が８０屯量％を超えるものが得られる。In general, zinc peroxide includes ZnO2, ZnO and Zn(OH
Zn07 content of commercially available zinc peroxide obtained as a mixture containing )2 is in the range of 50 to QQi%. Among the above methods, methods for obtaining zinc peroxide with a relatively high Zn07 content include a method of reacting zinc oxide with hydrogen peroxide, or a method of reacting diethylzinc with hydrogen peroxide, which is particularly In the latter method,
A product having a ZnO2 content of more than 80 tonne weight % is obtained.
これら種々の方法で製造される過酸化亜鉛は１８０乃至
２１０℃の温度範囲で分解し、酸よを放出して酸化亜鉛
となる。Zinc peroxide produced by these various methods decomposes in a temperature range of 180 to 210°C, releases acid, and becomes zinc oxide.
またこうして得られる過酸化亜鉛は、酸化性の散剤や軟
こう剤として消毒、脱臭などの医薬、化粧品に利用され
る他、各種プラスチックの発泡助剤、各種ゴム製品の加
硫促進助剤、架橋剤あるいは発泡助剤として、更には様
々の有機・無機化合物合成分野における高温酸化反応に
おいても、また熱分解することにより酸化亜鉛の微粉体
を生成する化合物としても有効に利用されている。Zinc peroxide obtained in this way is used as an oxidizing powder and ointment in medicines and cosmetics for disinfection and deodorization, as well as as a foaming aid for various plastics, as a vulcanization accelerating aid for various rubber products, and as a crosslinking agent. It is also effectively used as a foaming aid, in high-temperature oxidation reactions in various fields of organic and inorganic compound synthesis, and as a compound that produces fine zinc oxide powder by thermal decomposition.
［発明が解決しようとする課題］
しかし過酸化亜鉛を各種プラスチックの発泡助剤、各種
ゴムの加硫促進助剤、架橋剤あるいは発泡助剤等として
利用する場合、プラスチックやゴムの加工温度に適応す
る温度で分解・発泡することが大切であるが、通常の製
法により得た過酸化亜鉛では分解温度がおおよそ１８０
乃至２１０℃の範囲であり、製造方法によって分解温度
が異なるばかりでなく、Ｚｎ０ｚ含にも５０乃至６０毛
ｈ１％の範囲であって必ずしも一定しておらず、分解温
度とその時発生するガス量は製法によってかなり変動す
るが、それらを必要に応じて調整することは行われてい
ない。[Problem to be solved by the invention] However, when using zinc peroxide as a foaming aid for various plastics, a vulcanization accelerating aid for various rubbers, a crosslinking agent, a foaming aid, etc., it is difficult to adapt to the processing temperature of plastics and rubber. It is important to decompose and foam at a temperature of approximately
The decomposition temperature is in the range of 210°C to 210°C, and not only does it differ depending on the manufacturing method, but also in the case of ZnOz, it is in the range of 50 to 60 h1%, which is not necessarily constant, and the decomposition temperature and the amount of gas generated at that time are They vary considerably depending on the manufacturing method, but these are not adjusted as necessary.
本発明はこの様な事情に着目してなされたものであって
、その目的は得られる過酸化亜鉛の分解温度を比較広範
囲で、例えば１８０乃至２４０℃の範囲で、しかもＺｎ
Ｏ２含量をたとえば２０乃至８０重社％の範囲で任意に
制御することのできる過酸化亜鉛の製造法を提供しよう
とするものである。The present invention was made in view of these circumstances, and its purpose is to maintain the decomposition temperature of the resulting zinc peroxide over a relatively wide range, for example, in the range of 180 to 240°C, and to
It is an object of the present invention to provide a method for producing zinc peroxide in which the O2 content can be arbitrarily controlled within the range of, for example, 20 to 80%.
［課題を解決するための手段］
上記の課題を解決することのできた本発明に係る過酸化
亜鉛の製造法とは。[Means for Solving the Problems] What is the method for producing zinc peroxide according to the present invention that can solve the above problems?
■酸化亜鉛、塩基性炭酸亜鉛、炭酸亜鉛および水酸化亜
鉛よりなる群から選択される１種または２種以上の亜鉛
含有化合物の亜鉛１グラム原子当たり、
■炭酸カリウム、炭酸水素ナトリウム、炭酸カリウム、
炭酸水素カリウム、炭酸アンモニウム、炭酸水素アンモ
ニウム、水酸化ナトリウム、水酸化カリウムおよびアン
モニアよりなる群から選択される化合物の１種または２
種以上を０．００５乃至０．５モルの範囲で水に分散も
しくは溶解させた後、
（０過酸化水素を０．１乃至２モルの範囲で徐々に添加
し、
Ｏ乃至８０℃の範囲で反応させるところに要旨を有する
ものである。■per gram atom of zinc of one or more zinc-containing compounds selected from the group consisting of zinc oxide, basic zinc carbonate, zinc carbonate and zinc hydroxide; ■potassium carbonate, sodium hydrogen carbonate, potassium carbonate;
One or two compounds selected from the group consisting of potassium hydrogen carbonate, ammonium carbonate, ammonium hydrogen carbonate, sodium hydroxide, potassium hydroxide, and ammonia.
After dispersing or dissolving the above seeds in water in a range of 0.005 to 0.5 mol, (0) gradually add hydrogen peroxide in a range of 0.1 to 2 mol, and at a temperature of 0 to 80°C. The gist of this is that it involves a reaction.
かくしてず！Ｉられる過酸化亜鉛は分解温度が１８０乃
至２４０℃の範囲で、しかもＺｎ０ｚ含楡が２０乃至８
０１ Ｑ％の範囲にあり、使用される加工温度に応じた
温度で分解し、Ｒつその際発生するガス発生量も任意に
制御し得るものとなる。Kokutoshizu! The decomposition temperature of zinc peroxide is in the range of 180 to 240°C, and the Zn0z content is in the range of 20 to 8
It is in the range of 0.01Q%, decomposes at a temperature that corresponds to the processing temperature used, and the amount of gas generated during the R reaction can be controlled arbitrarily.
［作用］
本発明において使用される亜鉛含有化合物＜＝＞は、酸
化亜鉛、塩基性ＩＲ酸亜鉛、炭酸亜鉛あるいは水酸化亜
鉛よりなる群から選択される１種または２種以上である
が、通常透明性並鉛白、活性亜鉛もと呼ばれている炭酸
根や水酸化物を含むものであってもかまわない。[Function] The zinc-containing compound <=> used in the present invention is one or more selected from the group consisting of zinc oxide, basic IR acid zinc, zinc carbonate, or zinc hydroxide, but usually It does not matter if it contains transparent lead white, active zinc, or carbonate radicals or hydroxides.
しかしＥ配置外の亜鉛化合物、例えば硝酸亜鉛、Ｍ酸１
１！鉛などの亜鉛塩、あるいはジエチル亜鉛などの有機
亜鉛化合物などは、製造工程が煩雑で■１つ価格的にも
高価につくという理由から実用性を欠く。However, zinc compounds outside the E configuration, such as zinc nitrate, M acid 1
1! Zinc salts such as lead or organic zinc compounds such as diethylzinc are impractical because their manufacturing processes are complicated and they are expensive.
この様な理由から亜鉛含有化合物としては酸化唾鉛、塩
基性炭酸亜鉛、炭酸亜鉛あるいは水酸化亜鉛が使用され
るものであり、これらの群から選択される亜鉛含有化合
物は、その亜鉛１グラム原子当たり、■炭酸ナトリウム
、炭酸水素ナトリウム、炭酸カリウム、炭酸水素カリウ
ム、炭酸アンモニウム、炭酸水素アンモニウム、水酸化
ナトリウム、水酸化カリウムおよびアンモニアよりなる
群から選択される化合物の１種または２種以上の０．０
０５乃至０．５モル、好ましくは０．０５乃至０．３モ
ルの範囲で、水に分散あるいは溶解させて使用される。For this reason, salivary lead oxide, basic zinc carbonate, zinc carbonate, or zinc hydroxide are used as zinc-containing compounds, and zinc-containing compounds selected from these groups have a concentration of 1 gram atom of zinc. ■One or more compounds selected from the group consisting of sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, ammonium carbonate, ammonium hydrogen carbonate, sodium hydroxide, potassium hydroxide, and ammonia. .0
It is used after being dispersed or dissolved in water in a range of 0.05 to 0.5 mol, preferably 0.05 to 0.3 mol.
水の使用Ｑは、酸化亜鉛、１１！基性炭酸亜鉛などの亜
鉛化合物粉末が攪拌操作によって十分混合分散し、しか
も添加される各種炭酸アルカリ、アンモニウム塩、水酸
化アルカリ等が完全に溶解し得る量以北であればよい、
またアンモニアはガスとして吹込んでもよく、あるいは
アンモニア水として使用してもよいが、操作上便利なの
はアンモニア水として使用する方法である。Water usage Q is zinc oxide, 11! It is sufficient that the zinc compound powder such as basic zinc carbonate can be sufficiently mixed and dispersed by stirring operation, and furthermore, the amount must be above the level where various alkali carbonates, ammonium salts, alkali hydroxides, etc. to be added can be completely dissolved.
Further, ammonia may be blown in as a gas or may be used as aqueous ammonia, but the method of using it as aqueous ammonia is more convenient in terms of operation.
上記各原料の添加混合順としては、酸化亜鉛などの亜鉛
含有化合物を水に分散したのち、炭酸アルカリなどの塩
基性化合物をそのまま必要量加えて溶解する方法、炭酸
アルカリ、などの塩基性化合物を予め水に溶解した液を
亜鉛含有化合物に添加して溶解させる方法、あるいはこ
れら塩基性化合物を溶解した液に酸化亜鉛などの亜鉛化
合物を添加分散させる方法等を適宜選択して採用するこ
とができる。The order of addition and mixing of each of the above raw materials is to disperse a zinc-containing compound such as zinc oxide in water, then add and dissolve the required amount of a basic compound such as alkali carbonate, or to dissolve a basic compound such as alkali carbonate. A method of adding and dissolving a solution preliminarily dissolved in water to a zinc-containing compound, or a method of adding and dispersing a zinc compound such as zinc oxide to a solution of these basic compounds can be selected and adopted as appropriate. .
添加する炭酸アルカリなどの塩基性化合物の量が０．０
０５モル未満では、生成する過酸化亜鉛の分解温度が殆
んど変わらず分解温度調整の目的が有効に果たせない、
一方０．５モルを超えても分解温度はそれ以北変化せず
、およそ２４０℃のほぼ一定の分解温度を示すものとな
る。The amount of basic compounds such as alkali carbonate added is 0.0
If the amount is less than 0.05 mol, the decomposition temperature of the zinc peroxide produced will hardly change and the purpose of adjusting the decomposition temperature cannot be effectively achieved.
On the other hand, even if the amount exceeds 0.5 mol, the decomposition temperature does not change further and shows a substantially constant decomposition temperature of about 240°C.
未発り１においては、かくして得られる分散液に■過酸
化水素を亜鉛１グラム原子当たり０．１乃至２モルの範
囲、好ましくは０．５乃至１．５モルの範囲で添加する
。過酸化水素としては、市販されている３０〜３５％濃
度の過酸化水素水を使用すればよい、過酸化水素の添加
速度は特に制限されないが、過酸化水素の反応効率を考
えると、反応初期は比較的速く添加し、反応の進行につ
れて徐々にゆっくり添加するのがよい、但し過酸化水素
の添加速度自体が最終生成物である過酸化亜鉛の分解温
度に影響を及ぼす訳ではなく、Ｚｎ０７含量に数％の差
が生ずる程度である。In the case of 1, hydrogen peroxide is added to the thus obtained dispersion in an amount of 0.1 to 2 mol, preferably 0.5 to 1.5 mol, per gram atom of zinc. As hydrogen peroxide, commercially available hydrogen peroxide solution with a concentration of 30 to 35% may be used.The addition rate of hydrogen peroxide is not particularly limited, but considering the reaction efficiency of hydrogen peroxide, It is best to add hydrogen peroxide relatively quickly, and then gradually add it slowly as the reaction progresses. However, the rate of addition of hydrogen peroxide itself does not affect the decomposition temperature of the final product, zinc peroxide, and the Zn07 content The difference is only a few percentage points.
酸化亜鉛等の亜鉛化合物の分散液に過酸化水素を添加す
ると、発熱反応により系の液温は数十庇上５１するが、
反応温度はＯ乃至８０℃の範囲に収まる様に調整される
０反応液温が高いほど最終生成物である過酸化亜鉛粉末
中に粗粒物が生成し易くなり、この粗粒物は各種プラス
チック等の発泡助剤として使用したときにボイドの原因
になるばかりでなく、独立気泡の中に一部連続気泡が混
在するようになるので好ましくない、それ故反応液温は
４０乃至４５℃程度以下、特に厳密に粗粒物を少なくす
るには３０乃至３５℃以下とすることが望ましい。When hydrogen peroxide is added to a dispersion of a zinc compound such as zinc oxide, the temperature of the system increases by several tens of eels51 due to an exothermic reaction.
The reaction temperature is adjusted to be within the range of 0 to 80°C.The higher the reaction temperature, the more coarse particles are likely to be formed in the final product, zinc peroxide powder, and these coarse particles can be used for various plastics. When used as a foaming aid, it not only causes voids, but also causes some open cells to be mixed in with the closed cells, which is undesirable.Therefore, the temperature of the reaction liquid should be below about 40 to 45°C. In particular, in order to strictly reduce the amount of coarse particles, it is desirable to keep the temperature at 30 to 35°C.
本発明により■酸化亜鉛、塩基性炭酸亜鉛、炭酸亜鉛あ
るいは水酸化亜鉛よりなる群から選択される１種または
２種以上と、■炭酸ナトリウム、炭酸水素ナトリウム、
炭酸カリウム、炭酸水素カリウム、炭酸アンモニウム、
炭酸水素アンモニウム、水酸化ナトリウム、水酸化カリ
ウムおよびアンモニアよりなる群から選択される１種ま
たは２種以上、及びＯ過酸化水素、の各添加量を適正に
Ａ’ｌすると共に、反応液温を適正に調節することによ
り、生成する過酸化亜鉛の分解温度と過酸化水素水を制
御することができ、それにより各種プラスチックの発泡
助剤、各種ゴムの加硫促進助剤、架橋剤あるいは発泡助
剤等として利用する場合の加工温度に対応した温度で分
解し、かつ適正なｊＭのガスを発生し得るものにコント
ロールすることがＭ ｉ＠となり、最適条件での使用が
できるようになった。According to the present invention, (1) one or more selected from the group consisting of zinc oxide, basic zinc carbonate, zinc carbonate or zinc hydroxide; (2) sodium carbonate, sodium hydrogen carbonate;
Potassium carbonate, potassium hydrogen carbonate, ammonium carbonate,
One or more selected from the group consisting of ammonium hydrogen carbonate, sodium hydroxide, potassium hydroxide, and ammonia, and hydrogen peroxide, are added in appropriate amounts, and the temperature of the reaction solution is adjusted. By properly adjusting the decomposition temperature of zinc peroxide and hydrogen peroxide solution, it can be used as a foaming agent for various plastics, a vulcanization accelerating agent for various rubbers, a crosslinking agent, or a foaming agent. M i@ has become possible to decompose at a temperature corresponding to the processing temperature when used as an agent, etc., and to generate a gas with an appropriate jM, making it possible to use it under optimal conditions.
尚加硫促進助剤あるいは発泡助剤等の具備すべき条件と
しては。In addition, conditions such as a vulcanization accelerator or a foaming aid should be met.
■分解温度が最適温度となるように調節できること、 （２）粒子が小さいこと。■The decomposition temperature can be adjusted to the optimum temperature; (2) Particles are small.
■分解所要時間が短いこと。■The time required for disassembly is short.
■発生するガスが無毒・無臭であること、■貯蔵安定性
が良好であること、
などが要求されるが、本発明によれば用途、使用条件等
に応じて上記の要求を満たす過酸化亜鉛を製造すること
ができる。■The generated gas is non-toxic and odorless; ■It has good storage stability. According to the present invention, zinc peroxide satisfies the above requirements depending on the application, usage conditions, etc. can be manufactured.
またこの過酸化亜鉛は、他の各種加硫促進剤や発泡剤と
併用することもでき、更には有機・無機化合物合成分野
における高温酸化反応において、あるいは熱分解するこ
とによって酸化亜鉛の微粉体を製造する原料としても有
用なものである。In addition, this zinc peroxide can be used in combination with various other vulcanization accelerators and blowing agents, and it can also be used in high-temperature oxidation reactions in the field of organic and inorganic compound synthesis, or by thermal decomposition to form zinc oxide fine powder. It is also useful as a raw material for manufacturing.
［実施例］
以下実施例を挙げて本発明の構成及び作用効果を具体的
に説明するが、本発明はもとより下記の実施例に限定さ
れるものではない。[Examples] The structure and effects of the present invention will be specifically explained below with reference to Examples, but the present invention is not limited to the following Examples.
実施例
（０酸化亜鉛、塩基性炭酸亜鉛、炭酸亜鉛および水酸化
亜鉛よりなる群から選択される１！４または２種以上と
、
■炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウム
、炭酸水素カリウム、炭酸アンモニウム、炭酸水素アン
モニウム、水酸化ナトリウム、水酸化カリウムおよびア
ンモニアよりなる群から選択される１種または２種以上
とを、第１表および第２表に示す礒で水に分散あるいは
溶解させたのち、第１表および第２表に示す
■過酸化水素楡を徐々に添加し反応を進める。Examples (1, 4, or 2 or more selected from the group consisting of zinc oxide, basic zinc carbonate, zinc carbonate, and zinc hydroxide, and ■ sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, carbonic acid After dispersing or dissolving one or more selected from the group consisting of ammonium, ammonium hydrogen carbonate, sodium hydroxide, potassium hydroxide and ammonia in water using the powder shown in Tables 1 and 2, , as shown in Tables 1 and 2. ① Hydrogen peroxide is gradually added to proceed with the reaction.
反応液温、過酸化亜鉛のＺｎＯ２含量、および分解温度
などは第１表および第２表に示した。The reaction solution temperature, ZnO2 content of zinc peroxide, decomposition temperature, etc. are shown in Tables 1 and 2.
ただし過酸化亜鉛のＺｎＯ２含量は過マンガン酸カリウ
ムによる酸化還元滴定により求め、分解温度は理学’ｉ
ｔｔ機（株）製の示差熱分解装２１（高温形ＴＧ−ＤＴ
Ａ８１１２８）（）を用いて測定した。However, the ZnO2 content of zinc peroxide is determined by redox titration with potassium permanganate, and the decomposition temperature is determined by Rigaku'i.
Differential pyrolysis device 21 (high temperature type TG-DT) manufactured by ttki Co., Ltd.
A81128) ().
（以 下 余 白）
［９，用の効果］
本発明は以上のように構成されており、発明の効果を要
約すると以下の通りである。(Margins below) [9. Effects of Use] The present invention is configured as described above, and the effects of the invention are summarized as follows.
（１）ＮＩ化亜鉛、塩基性炭酸亜鉛、炭酸亜鉛および水
酸化亜鉛よりなる群から選択される１種以上と、炭酸ナ
トリウム、炭酸水素ナトリウム、炭酸カリウム、炭酸水
素カリウム、炭酸アンモニウム、炭酸水素アンモニウム
、水酸化ナトリウム、水酸化カリウムおよびアンモニア
よりなる群から選択される１種以上とを水に分散あるい
は溶解させた後、過酸化水素を添加することによって製
造される過酸化亜鉛は添加量を変えることにより、分解
温度を１８０乃至２４０℃の温度領域で自由に制御する
ことができ、且つＺｎＯ２含闇も過酸化水素添加Ｖを変
えることにより調節することが可能となった。(1) One or more selected from the group consisting of zinc nitride, basic zinc carbonate, zinc carbonate, and zinc hydroxide, and sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, ammonium carbonate, and ammonium hydrogen carbonate. Zinc peroxide is produced by dispersing or dissolving in water one or more selected from the group consisting of , sodium hydroxide, potassium hydroxide, and ammonia, and then adding hydrogen peroxide in varying amounts. As a result, the decomposition temperature can be freely controlled in the temperature range of 180 to 240°C, and the ZnO2 darkness can also be adjusted by changing the hydrogen peroxide addition V.
（２）過酸化亜鉛の分解温度とＺｎＯ２含驕を調節する
ことにより、各種プラスチックの発泡助剤、各種ゴムの
加硫促進助剤、架橋剤あるいは発泡助剤等として、該プ
ラスチックおよびゴムの加工温度である１８０乃至２４
０℃の温度に適応する温度領域で分解発泡する過酸化亜
鉛を製造し得ることになった・
（３）本発明によって得られる過酸化亜鉛は、酸化性の
散剤や軟こう剤として消毒、脱臭などの医薬、化粧品に
利用される他：有機・無機化合物合成分野における高温
酸化反応においても、熱分解することにより酸化亜鉛の
微粉体を生成する原料としても有用である。(2) By adjusting the decomposition temperature and ZnO2 content of zinc peroxide, it can be used as a foaming aid for various plastics, a vulcanization accelerating aid for various rubbers, a crosslinking agent, a foaming aid, etc. for the processing of plastics and rubber. Temperature 180 to 24
It has become possible to produce zinc peroxide that decomposes and foams in a temperature range that is compatible with the temperature of 0°C. In addition to its use in pharmaceuticals and cosmetics, it is also useful as a raw material for producing fine zinc oxide powder through thermal decomposition in high-temperature oxidation reactions in the field of organic and inorganic compound synthesis.
Claims (1)
化亜鉛よりなる群から選択される１種または２種以上の
亜鉛含有化合物の亜鉛１グラム原子当たり、 （ｂ）炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリ
ウム、炭酸水素カリウム、炭酸アンモニウム、炭酸水素
アンモニウム、水酸化ナトリウム、水酸化カリウムおよ
びアンモニアよりなる群から選択される化合物の１種ま
たは２種以上を０．００５乃至０．５モルの範囲で水に
分散もしくは溶解させた後、 （ｃ）過酸化水素を０．１乃至２モルの範囲で徐々に添
加し、 ０乃至８０℃の範囲で反応させることを特徴とする過酸
化亜鉛の製造法。[Scope of Claims] (a) per gram atom of zinc of one or more zinc-containing compounds selected from the group consisting of zinc oxide, basic zinc carbonate, zinc carbonate and zinc hydroxide; (b) One or more compounds selected from the group consisting of sodium carbonate, sodium hydrogen carbonate, potassium carbonate, potassium hydrogen carbonate, ammonium carbonate, ammonium hydrogen carbonate, sodium hydroxide, potassium hydroxide, and ammonia in an amount of 0.005 to After dispersing or dissolving in water in a range of 0.5 mol, (c) hydrogen peroxide is gradually added in a range of 0.1 to 2 mol, and the reaction is carried out in a range of 0 to 80 ° C. A method for producing zinc peroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11900088A JPH01290509A (en) | 1988-05-16 | 1988-05-16 | Preparation of zinc peroxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11900088A JPH01290509A (en) | 1988-05-16 | 1988-05-16 | Preparation of zinc peroxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01290509A true JPH01290509A (en) | 1989-11-22 |
Family
ID=14750517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11900088A Pending JPH01290509A (en) | 1988-05-16 | 1988-05-16 | Preparation of zinc peroxide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01290509A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110274598A1 (en) * | 2008-04-14 | 2011-11-10 | Akridge James R | Sustainable recovery of metal compounds |
| WO2012169611A1 (en) * | 2011-06-10 | 2012-12-13 | 堺化学工業株式会社 | Rounded zinc peroxide particles, rounded zinc oxide particles, manufacturing method therefor, cosmetic material, and heat-dissipating filler |
-
1988
- 1988-05-16 JP JP11900088A patent/JPH01290509A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110274598A1 (en) * | 2008-04-14 | 2011-11-10 | Akridge James R | Sustainable recovery of metal compounds |
| WO2012169611A1 (en) * | 2011-06-10 | 2012-12-13 | 堺化学工業株式会社 | Rounded zinc peroxide particles, rounded zinc oxide particles, manufacturing method therefor, cosmetic material, and heat-dissipating filler |
| US20140212669A1 (en) * | 2011-06-10 | 2014-07-31 | Sakai Chemical Industry Co., Ltd. | Rounded zinc peroxide particles, rounded zinc oxide particles, method for prodcution thereof, cosmetic and heat releasing filler |
| JPWO2012169611A1 (en) * | 2011-06-10 | 2015-02-23 | 堺化学工業株式会社 | Round zinc peroxide particles, round zinc oxide particles, production methods thereof, cosmetics and heat dissipating fillers |
| US9376319B2 (en) | 2011-06-10 | 2016-06-28 | Sakai Chemical Industry Co., Ltd. | Rounded zinc peroxide particles, rounded zinc oxide particles, method for production thereof, cosmetic and heat releasing filler |
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