JPH01286711A - Fire spread preventive coating peeling agent and method of peeling wire/cable fire spread preventive coating - Google Patents

Fire spread preventive coating peeling agent and method of peeling wire/cable fire spread preventive coating

Info

Publication number
JPH01286711A
JPH01286711A JP63113155A JP11315588A JPH01286711A JP H01286711 A JPH01286711 A JP H01286711A JP 63113155 A JP63113155 A JP 63113155A JP 11315588 A JP11315588 A JP 11315588A JP H01286711 A JPH01286711 A JP H01286711A
Authority
JP
Japan
Prior art keywords
fire spread
coating
spread prevention
preventive coating
peeling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63113155A
Other languages
Japanese (ja)
Other versions
JPH0728492B2 (en
Inventor
Shinkichi Nakagawa
中川 真吉
Seiji Suzuki
鈴木 静二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Cable Ltd
Original Assignee
Hitachi Cable Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Cable Ltd filed Critical Hitachi Cable Ltd
Priority to JP63113155A priority Critical patent/JPH0728492B2/en
Publication of JPH01286711A publication Critical patent/JPH01286711A/en
Publication of JPH0728492B2 publication Critical patent/JPH0728492B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Removal Of Insulation Or Armoring From Wires Or Cables (AREA)

Abstract

PURPOSE:To peel a fire spread preventive coating provided on a wire/cable at an ambient temperature without adverse influence on the inner material of the wire or the like by peeling the coating with a fire spread preventive coating peeling agent containing water, aqueous emulsion and silicate anhydride in diethylene glycol monoethyl ether acetate. CONSTITUTION:Aqueous emulsion and silicate anhydride are so contained in diethylene glycol monoethyl ether acetate having a function of swelling fire spread preventive coating as to coat the outer periphery of the coating with water by increasing the viscosity of the wafer to reduce its volatility to form a peeling agent. Thus, it can easily coat as fire spread preventive coating, and peel the coating without adverse influence on the material such as a cable sheath or the like.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、電線・ケーブル等の外周に設けられた延焼防
止被覆を効率的に剥離できる剥離剤およびこれを使用し
た電線・ケーブル延焼防止被覆の剥離方法に関するもの
である。
Detailed Description of the Invention [Industrial Field of Application] The present invention provides a stripping agent that can efficiently strip the fire spread prevention coating provided on the outer periphery of electric wires, cables, etc., and a fire spread prevention coating for electric wires and cables using the same. This invention relates to a peeling method.

[従来の技術] 電線・ケーブルの延焼を防止するための一方法として、
シース外周に延焼防止塗料を塗布する方法が採用されて
きている。延焼防止塗料は、一般に、水性エマルジョン
をベースに有機難燃剤、無機充填剤、不燃性繊維、可塑
剤等を加えたものであり、これらの延焼防止塗料を電線
・ケーブルのシース外周に塗布し乾燥させると、シース
と接着した延焼防止被覆が形成される。電線・ケーブル
のシースとしては、ポリエチレン、ビニル、クロロプレ
ンゴム、シリコーンゴム等が用いられているが、特にビ
ニルシースと延焼防止塗料とは良(接着する。このため
、電線・ケーブルを撤去する場合に延焼防止被覆を剥離
する作業が困難になっている。
[Prior art] As a method to prevent the spread of fire in electric wires and cables,
A method of applying fire spread prevention paint to the outer periphery of the sheath has been adopted. Fire spread prevention paint is generally a water-based emulsion with organic flame retardants, inorganic fillers, noncombustible fibers, plasticizers, etc. added, and these fire spread prevention paints are applied to the outer periphery of the sheath of electric wires and cables and allowed to dry. This forms a fire spread prevention coating that adheres to the sheath. Polyethylene, vinyl, chloroprene rubber, silicone rubber, etc. are used as sheaths for electric wires and cables, but vinyl sheaths and fire-spread prevention paints are particularly sensitive (adhesive. It has become difficult to remove the protective coating.

一般に、延焼防止被覆を剥離する方法としては、アルカ
リ性水溶液を用いる方法、あるいはジクロロメタンを主
材料とした剥離液を用いる方法がある。
Generally, methods for removing the fire spread prevention coating include a method using an alkaline aqueous solution or a method using a stripping liquid mainly composed of dichloromethane.

[発明が解決しようとする課題] しかし、アルカリ性水溶液を用いる方法は、−部の耐ア
ルカリ性に劣るエマルジョンポリマに対しては効果があ
るものの、通常の延焼防止被覆に対しては剥離効果が殆
どない。又、ジクロロメタンを主材料とした剥離液を用
いる方法は延焼防止被覆を膨潤させると共に、ケーブル
シースをも膨潤させるという問題がある。すなわち、電
線・ケーブルは複数本がグループとなって布設され、こ
れらを−括して延焼防止被覆が設けられるが、グループ
の中の一部の電線・ケーブルのみの撤去および張替えの
場合、全体の延焼防止被覆を剥離してから撤去および張
替えが行われ、再度、延焼防止被覆が設けられることに
なる。このように、延焼防止塗料の剥離に際しては、撤
去する電線・ケーブルのみならず、その後も更に使用さ
れる電線・ケーブルにも剥離液の影響が及ぶことになる
ので、電線・ケーブルシースを膨潤させない剥離剤が望
まれる。
[Problems to be Solved by the Invention] However, although the method using an alkaline aqueous solution is effective against emulsion polymers with inferior alkali resistance, it has almost no peeling effect on ordinary fire spread prevention coatings. . Further, the method using a stripping liquid mainly composed of dichloromethane has the problem that it swells the fire spread prevention coating and also swells the cable sheath. In other words, multiple wires/cables are laid in groups, and a fire spread prevention coating is provided to bundle them together, but if only some of the wires/cables in the group are removed and replaced, the entire wire/cable will be covered. After the fire spread prevention coating is peeled off, it is removed and replaced, and the fire spread prevention coating is reinstalled. In this way, when removing the fire spread prevention paint, the stripper will affect not only the wires and cables that are to be removed, but also the wires and cables that will be used afterward, so do not allow the wires and cable sheaths to swell. A release agent is desired.

本発明は、上記に基いてなされたもので、剥離性に優れ
、しかも電線・ケーブルシース等の内部プラスチック材
料に悪影響を与えずに常温での剥離が可能である延焼防
止被覆剥離剤およびこれを用いた電線・ケーブル延焼防
止被覆の剥離方法の提供を目的とするものである。
The present invention has been made based on the above, and provides a fire spread prevention coating stripping agent that has excellent peelability and can be peeled off at room temperature without adversely affecting internal plastic materials such as electric wires and cable sheaths. The purpose of this invention is to provide a method for peeling off the fire spread prevention coating of electric wires and cables.

[課題を解決するための手段] 本発明の剥離剤は、ジエチレングリコールモノエチルエ
ーテルアセテートに水、水性エマルシコン及び無水珪酸
を含有せしめてなることを特徴とするものである。また
、本発明の剥離方法は、電線・ケーブル外周に上記剥離
剤を塗布することにより延焼防止被覆にジエチレングリ
コールモノエチルエーテルアセテートを浸透させ、しか
る後延焼防止被覆を剥離することを特徴とするものであ
る。
[Means for Solving the Problems] The release agent of the present invention is characterized in that it contains diethylene glycol monoethyl ether acetate, water, an aqueous emulsicon, and silicic anhydride. Furthermore, the stripping method of the present invention is characterized in that diethylene glycol monoethyl ether acetate is infiltrated into the fire spread prevention coating by applying the above stripping agent to the outer periphery of the electric wire/cable, and then the fire spread prevention coating is peeled off. be.

本発明が適用される延焼防止被覆を形成する塗料として
は、水性エマルジョンをベースに有機難燃剤、難燃助剤
、無機充填剤、不燃性繊維、可塑剤等を加えたものが代
表例としてあげられる。水性エマルジョンとしては、酢
酸ビニル系エマルジョン、アクリル系エマルジョンなど
が、有機難燃剤としては、塩素化パラフィン、塩素化ナ
フタリン、デカブロモジフェニルオキサイド、ポリりん
酸アンモニウムなどが、難燃助剤としては、二酸化アン
チモン、はう酸亜鉛などが、無機充填剤としては水和ア
ルミナ、炭酸カルシウム、含水ケイ酸マグネシウム、ク
レー、チタン白、タルクなどが、不燃性繊維としては、
セラミック繊維、フェノール繊維、ガラス繊維などが、
可塑剤としては、トリス(β−クロロエチル)ホスフェ
ート、塩素化ビフェニル、フタル酸ジブチルなどがそれ
ぞれあげられる。
Typical examples of paints that form the fire spread prevention coating to which the present invention is applied include those based on aqueous emulsions with organic flame retardants, flame retardant aids, inorganic fillers, nonflammable fibers, plasticizers, etc. It will be done. Examples of aqueous emulsions include vinyl acetate emulsions and acrylic emulsions; examples of organic flame retardants include chlorinated paraffin, chlorinated naphthalene, decabromodiphenyl oxide, and ammonium polyphosphate; examples of flame retardant aids include carbon dioxide. Antimony, zinc oxalate, etc. are used as inorganic fillers, hydrated alumina, calcium carbonate, hydrated magnesium silicate, clay, titanium white, talc, etc. are used as non-combustible fibers.
Ceramic fibers, phenolic fibers, glass fibers, etc.
Examples of plasticizers include tris(β-chloroethyl) phosphate, chlorinated biphenyls, and dibutyl phthalate.

ジエチレングリコールモノエチルエーテルアセテートは
延焼防止被覆を膨潤させる機能を有するものである。こ
のものは、水との相溶性に優れており、どの割合でも希
釈できる。ジエチレングリコールモノエチルエーテルア
セテートに水を加えることによりその揮発性を低下させ
、安全性を大幅に改善できる。しかし、ジエチレングリ
コールモノエチルエーテルアセテ−トル水系では粘度が
極めて低いため、延焼防止被覆外周に設ける際のへケ゛
塗が困難であると共に、付着量が少ないため作業性に問
題がある。本発明ではこれを解決するために、ジエチレ
ングリコールモノエチルエーテルアセテ−トル水系に、
水性エマルジョン及び無水珪酸を含有せしめることによ
り増粘して塗料化し、これを延焼防止被覆外周に塗布で
きるようにしたものである。
Diethylene glycol monoethyl ether acetate has the function of swelling the fire spread prevention coating. This material has excellent compatibility with water and can be diluted at any ratio. Adding water to diethylene glycol monoethyl ether acetate can reduce its volatility and significantly improve its safety. However, since diethylene glycol monoethyl ether acetate aqueous systems have extremely low viscosity, it is difficult to apply the coating to the outer periphery of the fire spread prevention coating, and the amount of adhesion is small, causing problems in workability. In the present invention, in order to solve this problem, diethylene glycol monoethyl ether acetate aqueous system is
By containing an aqueous emulsion and silicic anhydride, the viscosity is increased to form a paint, which can be applied to the outer periphery of the fire spread prevention coating.

無水珪酸は、平均粒径が8〜20mμの微粒子状のもの
が増粘作用の点から好ましく、ジエチレングリコールモ
ノエチルエーテルアセテート100重量部に対し3〜1
0重量部含有せしめることにより増粘し、ハケ塗りが可
能になる。
The silicic anhydride is preferably in the form of fine particles with an average particle size of 8 to 20 mμ from the viewpoint of thickening effect, and is 3 to 1 part by weight per 100 parts by weight of diethylene glycol monoethyl ether acetate.
Containing 0 parts by weight increases the viscosity and makes it possible to apply with a brush.

水性エマルジョンは、剥離剤の乾燥後に塗膜を形成させ
るために含有させるもので、これによって剥離剤に含ま
れる無水珪酸等の無機粉末が脱落するのが防止される。
The aqueous emulsion is contained in order to form a coating film after drying of the release agent, and thereby prevents inorganic powder such as silicic anhydride contained in the release agent from falling off.

水性エマルジョンとしては、酢酸ビニル系エマルジョン
、アクリル系エマルジョンなどがあげられ、ジエチレン
グリコールモノエチルエーテルアセテート100重量部
に対して0.3〜5重量部の範囲で含有させることが好
ましい。
Examples of aqueous emulsions include vinyl acetate emulsions and acrylic emulsions, and the content thereof is preferably from 0.3 to 5 parts by weight per 100 parts by weight of diethylene glycol monoethyl ether acetate.

なお、本発明における延焼防止被覆剥離剤には、上記成
分のほかに必要に応じてクレー、酸化チタンのような無
機充填剤、顔料その他の添加剤を加えてもよい。
In addition to the above-mentioned components, clay, inorganic fillers such as titanium oxide, pigments, and other additives may be added to the fire spread prevention coating stripping agent of the present invention, if necessary.

[発明の実施例] 第1表に示すように2種類の延焼防止塗料A、Bを調整
し、これをビニルシースケーブル(外径12mm)外周
に乾燥後の厚さが1.5mmとなるように塗布し、塗布
後室温で120時間乾燥して延焼防止被覆とした。次に
、第2表に示すように4種類の剥離剤a。
[Embodiment of the Invention] As shown in Table 1, two types of fire spread prevention paints A and B were prepared and applied to the outer circumference of a vinyl sheathed cable (outer diameter 12 mm) so that the thickness after drying was 1.5 mm. After coating, it was dried at room temperature for 120 hours to obtain a fire spread prevention coating. Next, as shown in Table 2, four types of release agents a.

b、c、dを調整し、これら剥離剤をケーブルの延焼防
止被覆外周にハケ塗りにより塗布した。なお、塗布量は
、ケーブル長さ20cm当り14gとした。
b, c, and d were adjusted, and these release agents were applied to the outer periphery of the cable to prevent the spread of fire by brushing. The coating amount was 14 g per 20 cm of cable length.

延焼防止被覆とビニルシースとの剥離状況およびビニル
シース特性について評価した結果を第3表に示した。
Table 3 shows the results of evaluating the degree of peeling between the fire spread prevention coating and the vinyl sheath and the characteristics of the vinyl sheath.

第1表 延焼防止塗料配合 第3表から明らかな通り、ジエチレングリコールモノエ
チルエーテルアセテートを用いた剥離剤の場合は室温で
24時間後に容易に剥離を行えることができた。又、延
焼防止被覆を剥離した後のビニルシースの溶媒吸収率は
2%以下であり、ビニルシースへの影響は殆どなく、引
張強さおよび伸びの低下は極めて少ない。これに対し、
ジクロロメタンを使用した場合(比較例)、剥離は容易
に行えるがビニルシースを膨潤軟化させることから、引
張強さは大幅に低下し、逆に伸びが太き(なる。
Table 1: Fire spread prevention paint formulation As is clear from Table 3, in the case of the stripping agent using diethylene glycol monoethyl ether acetate, it was possible to easily strip the coating after 24 hours at room temperature. Further, the solvent absorption rate of the vinyl sheath after the fire spread prevention coating is peeled off is 2% or less, which has almost no effect on the vinyl sheath, and the decrease in tensile strength and elongation is extremely small. On the other hand,
When dichloromethane is used (comparative example), peeling is easy, but since the vinyl sheath swells and softens, the tensile strength decreases significantly and the elongation increases.

[発明の効果コ 以上説明してきた通り、本発明によれば、延焼防止被覆
への塗布が容易であり、しかもケーブルシース等の材料
に悪影響を与えることなく延焼防止被覆の剥離を行うこ
とができる延焼防止被覆剥離剤を実現でき、この使用に
より、極めて容易に電線・ケーブル外周の延焼防止被覆
を剥離することができるようになる。
[Effects of the Invention] As explained above, according to the present invention, it is easy to apply the fire spread prevention coating, and the fire spread prevention coating can be peeled off without adversely affecting materials such as cable sheaths. A fire spread prevention coating stripping agent can be realized, and by using this agent, the fire spread prevention coating on the outer periphery of electric wires and cables can be removed extremely easily.

又、本発明の剥離剤は、室温で十分な剥離効果を有する
と共に、揮発性、毒性が殆どなく安全性に優れたもので
ある。
Further, the stripping agent of the present invention has a sufficient stripping effect at room temperature, has little volatility and toxicity, and is excellent in safety.

Claims (1)

【特許請求の範囲】 1)ジエチレングリコールモノエチルエーテルアセテー
トに水、水性エマルジョン及び無水珪酸を含有せしめて
なることを特徴とする延焼防止被覆剥離剤。 2)電線・ケーブル上に設けられた延焼防止被覆の外周
にジエチレングリコールモノエチルエーテルアセテート
に水、水性エマルジョン及び無水珪酸を含有せしめてな
る延焼防止被覆剥離剤を塗布し、しかる後延焼防止被覆
を剥離することを特徴とする電線・ケーブル延焼防止被
覆の剥離方法。
[Scope of Claims] 1) A fire spread prevention coating stripping agent comprising diethylene glycol monoethyl ether acetate containing water, an aqueous emulsion, and silicic anhydride. 2) Apply a fire spread prevention coating remover made of diethylene glycol monoethyl ether acetate containing water, an aqueous emulsion, and silicic anhydride to the outer periphery of the fire spread prevention coating provided on electric wires and cables, and then peel off the fire spread prevention coating. A method for peeling off a fire spread prevention coating for electric wires and cables.
JP63113155A 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat Expired - Lifetime JPH0728492B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63113155A JPH0728492B2 (en) 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63113155A JPH0728492B2 (en) 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Publications (2)

Publication Number Publication Date
JPH01286711A true JPH01286711A (en) 1989-11-17
JPH0728492B2 JPH0728492B2 (en) 1995-03-29

Family

ID=14604959

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63113155A Expired - Lifetime JPH0728492B2 (en) 1988-05-10 1988-05-10 Fire spread prevention coating remover and method for peeling wire / cable spread prevention coat

Country Status (1)

Country Link
JP (1) JPH0728492B2 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63154006A (en) * 1986-12-12 1988-06-27 日立電線株式会社 Method of removing fire-spread-proof covering of wire and cable
JPS63154007A (en) * 1986-12-17 1988-06-27 日立電線株式会社 Fire-spread-proof covering remover and method of removing fire-spread-covering of wire and cable
JPS63171106A (en) * 1987-01-08 1988-07-14 日立電線株式会社 Flame-spread-proof covering remover and method of removing flame-spread-proof covering of wire and cable
JPS63171107A (en) * 1987-01-08 1988-07-14 日立電線株式会社 Flame-spread-proof covering remover and method of removing flame-spread-proof covering of wire and cable
JPH01117614A (en) * 1987-10-30 1989-05-10 Hitachi Cable Ltd Stripping agent of coating for preventing of spread of fire

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63154006A (en) * 1986-12-12 1988-06-27 日立電線株式会社 Method of removing fire-spread-proof covering of wire and cable
JPS63154007A (en) * 1986-12-17 1988-06-27 日立電線株式会社 Fire-spread-proof covering remover and method of removing fire-spread-covering of wire and cable
JPS63171106A (en) * 1987-01-08 1988-07-14 日立電線株式会社 Flame-spread-proof covering remover and method of removing flame-spread-proof covering of wire and cable
JPS63171107A (en) * 1987-01-08 1988-07-14 日立電線株式会社 Flame-spread-proof covering remover and method of removing flame-spread-proof covering of wire and cable
JPH01117614A (en) * 1987-10-30 1989-05-10 Hitachi Cable Ltd Stripping agent of coating for preventing of spread of fire

Also Published As

Publication number Publication date
JPH0728492B2 (en) 1995-03-29

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