JPH01284597A - Detergent composition of low irritativeness - Google Patents
Detergent composition of low irritativenessInfo
- Publication number
- JPH01284597A JPH01284597A JP63115540A JP11554088A JPH01284597A JP H01284597 A JPH01284597 A JP H01284597A JP 63115540 A JP63115540 A JP 63115540A JP 11554088 A JP11554088 A JP 11554088A JP H01284597 A JPH01284597 A JP H01284597A
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- active agent
- surface active
- hydroxyethyl
- 2coom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000003599 detergent Substances 0.000 title abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 5
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 125000005037 alkyl phenyl group Chemical group 0.000 claims abstract description 4
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims abstract 2
- 238000004140 cleaning Methods 0.000 claims description 17
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 230000000774 hypoallergenic effect Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims 2
- 239000013543 active substance Substances 0.000 claims 1
- -1 alkyl saccharide Chemical class 0.000 abstract description 19
- 239000004094 surface-active agent Substances 0.000 abstract description 10
- 238000005187 foaming Methods 0.000 abstract description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract description 2
- 239000008103 glucose Substances 0.000 abstract description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 229960004418 trolamine Drugs 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 210000004209 hair Anatomy 0.000 description 6
- 239000000049 pigment Substances 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 4
- 230000007794 irritation Effects 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- VIBDJEWPNNCFQO-UHFFFAOYSA-N ethane-1,1,2-triol Chemical compound OCC(O)O VIBDJEWPNNCFQO-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 125000001905 inorganic group Chemical group 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、低刺激性洗浄剤組成物に関し、更に詳しくは
、アミドアミン型両性界面活性剤及びアルキルサツカラ
イド系界面活性剤を含有し、起泡ツバ洗浄力等に優れ、
しかも皮膚や毛髪に対する刺激性が低く、温和な洗浄剤
組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a hypoallergenic detergent composition, more specifically, it contains an amidoamine type amphoteric surfactant and an alkyl saccharide type surfactant, and Excellent foam brim cleaning power, etc.
Moreover, the present invention relates to a mild detergent composition that has low irritation to the skin and hair.
〔従来の技術及びその課題」
アミドアミン型両性界面活性剤は、石鹸、アルキルサル
フェート、アルキルエーテルサルフェート等のアニオン
界面活性剤に比べ、皮膚や眼粘膜に対する刺激性が低く
、極めて温和な界面活性剤であることが知られている。[Prior art and its problems] Amidamine-type amphoteric surfactants are extremely mild surfactants that are less irritating to the skin and eye mucous membranes than anionic surfactants such as soaps, alkyl sulfates, and alkyl ether sulfates. It is known that there is.
しかしながら、このアミドアミン型両性界面活性剤は、
洗浄剤組成物に要求される起泡力等が劣ることなど、い
くつかの欠点があり、洗浄剤組成物の主成分として用い
ることは難しく、その−成分として利用されているにす
ぎなかった。However, this amidoamine type amphoteric surfactant
It has several drawbacks, such as poor foaming power required for cleaning compositions, and it is difficult to use it as a main component of cleaning compositions, so it has only been used as a sub-component.
また、アルキルサツカライド系界面活性剤は低刺激性で
あることが知られているが（米国特許第３，２１９，６
５６号、第３，５９８，８６５号、第４．２２３，１２
９号）、単独で用いるには起泡性や洗浄性に問題があシ
、洗浄剤組成物としてはアニオン性界面活性７１１（％
開昭５９−１３０２１０号）や非イオン？リマー（％開
昭６０−１８５９４号）と併用して用いていた。Additionally, alkyl saccharide surfactants are known to be hypoallergenic (U.S. Pat. No. 3,219,6
No. 56, No. 3,598,865, No. 4.223,12
No. 9), there are problems with foaming and cleaning properties when used alone, and anionic surfactant 711 (%
No. 59-130210) or non-ionic? It was used in combination with Rimmer (%KAI No. 18594/1983).
斯かる実状において本発明者らは鋭意研究を行った結果
、アミドアミン型両性界面活性剤とアルキルサツカライ
ド系界面活性剤を含有する洗浄剤組成物は、皮膚や毛髪
に対する刺激性が低く、シかも起泡力や洗浄力等にも優
れ、皮膚洗浄剤、シャンシー、食器用洗浄剤、ウール等
の角質繊維用洗浄剤等の多岐にわたって好適に用いられ
ることを見出し、本発明を完成した。Under these circumstances, the present inventors conducted extensive research and found that a cleaning composition containing an amidoamine type amphoteric surfactant and an alkyl saccharide type surfactant has low irritation to the skin and hair, and may be The present invention was completed based on the discovery that it has excellent foaming power and cleaning power, and can be suitably used in a wide variety of applications, including skin cleansers, shampoos, dishwashing detergents, and detergents for horny fibers such as wool.
すなわち、本発明は次の成分（Ａ）及びＣＢ）（Ａ）一
般式（Ｉ）又は（ＩＩ）
〔式中、Ｋ１及びＲ３は各々炭素数７〜１９の飽和又は
不飽オロ炭化水素基金示し、Ｉ：Ｒ２及びＲ４は基−Ｃ
Ｉ−１２ＣＯＯＭ又は−ＣＨ２Ｃ１（２ＣＯＯＭ （Ｍ
は水素、アルカリ金属又はアルカノールアミンを示す）
を示し、ｉｔ、は水素、基−ＣＩ（、Ｃ００Ｍ又は−Ｃ
Ｈ，Ｃｆｉ２ＣＯＯＭ （Ｍは水素、アルカリ金属又は
アルカノールアミンを示す）を示す〕
で表わされるアミドアミン型両性界面活性剤（均一般式
（Ｉｌｌ）
Ｒ６−０−（Ｇ） ｎ （Ｉ
ｌｌ）（式中、Ｒ６は炭素数８〜１８のアルキル、アル
ケニル、 分Ｍアルキル又はアルキルフェニル基金示し
、Ｇは炭素数５〜６の還元糖を示し、ｎは１〜１０の数
を示す）
で表わされるアルキルサツカライド系界面活性剤
を含有することを特徴とする低刺激性洗浄剤組成物を提
供するものである。That is, the present invention provides the following components (A) and CB) (A) general formula (I) or (II) [wherein K1 and R3 each represent a saturated or unsaturated orohydrocarbon group having 7 to 19 carbon atoms] , I: R2 and R4 are groups -C
I-12COOM or -CH2C1(2COOM (M
indicates hydrogen, alkali metal or alkanolamine)
, it is hydrogen, group -CI (, C00M or -C
H,Cfi2COOM (M represents hydrogen, alkali metal or alkanolamine)] Amidoamine type amphoteric surfactant (homogeneous general formula (Ill) R6-0-(G) n (I
(In the formula, R6 represents an alkyl, alkenyl, alkyl or alkylphenyl group having 8 to 18 carbon atoms, G represents a reducing sugar having 5 to 6 carbon atoms, and n represents a number from 1 to 10.) The present invention provides a hypoallergenic detergent composition containing an alkyl saccharide surfactant represented by:
本発明の（ト）成分でるるアミドアミン型両性界面活性
剤のうち、一般式（すで表わされるものの好ましい具体
例としては、Ｎ−ラウロイル−Ｎ′−力ルボキシメチル
ーＮ’ −（２−ヒドロキシエチル）エチレンシアミン
、Ｎ−ラウロイル−Ｎ′−力ルボキシエチルーＮ’ −
（２−ヒドロキシエチル）エチレンシアミン、Ｎ−ミリ
ストイル−Ｎ′−力ルボキシメチルーＮ’−（２−ヒド
ロキシエチル）エチレンシアミン、Ｎ−ミＩ）ストイル
−Ｎ′−カルボキシエチル−Ｎ’−（２−ヒドロキシエ
チル）エチレンシアミン、Ｎ−ツリルミトイルーＮ′−
カルボキシメチル−Ｎ’ −（２−ヒドロキシエチル）
エチレンシアミン、Ｎ−ノＱルミトイルーＮ′−力ルボ
キシエチルーＮ’−（２−ヒドロキシエチル）エチレン
シアミン及びこれらの塩等が挙げられる。また、一般式
（ＩＩ）で表わされるものの好ましい具体例としては、
Ｎ−ラウロイル−Ｎ−（２−ヒドロキシエチルＪ −Ｎ
’−カルボキシメチルエチレンシアミン、Ｎ−ラウロイ
ル−Ｎ−（２−ヒドロキシエチル）−Ｎ’、Ｎ’−ビス
（カルボキシメチル）エチレンシアミン、Ｎ−ラ’ｙロ
イル−Ｎ−（２−ヒドロキシエチル）−Ｎ’、Ｎ’−ヒ
ス（カルボキシエチル）エチレンシアミン、Ｎ−ミリス
トイル−Ｎ−（２−ヒドロキシエチル） −Ｎ’−カル
ボキシメチルエチレンシアミン、Ｎ−ミリストイル−Ｎ
−（２−ヒドロキシエチル）−Ｎ’、Ｎ’−ビス（カル
ボキシメチル）エチレンシアミン、Ｎ−ミリストイル−
Ｎ−（２−ヒドロキシエチル） −Ｎ’、Ｎ’−ビス（
カルボキシエチル）エチレンシアミン、Ｎ−ノリルミト
イルーＮ−（２−ヒドロキシエチル） −Ｎ’−力ルボ
キシメチルエチレンゾアミン、Ｎ−ノリルミトイルーＮ
−（２−ヒドロキシエチル）−Ｎ’、Ｎ’−ビス（カル
ボキシメチル）エチレンシアミン、Ｎ−ノリルミトイル
ーＮ’−（２−ヒドロキシエチル）−Ｎ’、Ｎ’−ビス
（カルボキシエチル）エチレンシアミン及びこれらの堰
等が挙けられる。Among the amidoamine type amphoteric surfactants which are component (g) of the present invention, preferred specific examples of those represented by the general formula (already shown) include N-lauroyl-N'-hydroxymethyl-N'-(2-hydroxyethyl) Ethylenecyamine, N-lauroyl-N'-carboxyethyl-N'-
(2-hydroxyethyl)ethylenecyamine, N-myristoyl-N'-carboxymethyl-N'-(2-hydroxyethyl)ethylenecyamine, N-myristoyl-N'-carboxyethyl-N'-(2 -Hydroxyethyl) ethylenecyamine, N-turirumitoyl-N'-
Carboxymethyl-N'-(2-hydroxyethyl)
Examples include ethylenecyamine, N-no-Q-lumitoyl-N'-hydroxyethyl-N'-(2-hydroxyethyl)ethylenecyamine, and salts thereof. Further, as preferred specific examples of those represented by general formula (II),
N-lauroyl-N-(2-hydroxyethyl J -N
'-Carboxymethylethylenecyamine, N-lauroyl-N-(2-hydroxyethyl)-N', N'-bis(carboxymethyl)ethylenecyamine, N-lauroyl-N-(2-hydroxyethyl )-N', N'-his(carboxyethyl)ethylenecyamine, N-myristoyl-N-(2-hydroxyethyl) -N'-carboxymethylethylenecyamine, N-myristoyl-N
-(2-hydroxyethyl)-N', N'-bis(carboxymethyl)ethylenecyamine, N-myristoyl-
N-(2-hydroxyethyl) -N', N'-bis(
carboxyethyl) ethylenecyamine, N-norylmitoyl-N-(2-hydroxyethyl)-N'-carboxymethylethylenezoamine, N-norylmitoyl-N
-(2-hydroxyethyl)-N',N'-bis(carboxymethyl)ethylenecyamine, N-norylmitoyl-N'-(2-hydroxyethyl)-N',N'-bis(carboxyethyl)ethylenecyamine and these weirs.
塩としてはナトリウム瓜弄のアルカリ金属塩、マグネシ
ウム塩等のアルカリ土類金属塩、トリエタノールアミン
塩等のアルカノールアミン塩、さらにはアンモニウム塩
等が挙けられる。また、これらの塩を用いた場合、夾雑
物として無機塩類を含みやすいが、これらの無機塩の一
部または全部を除き、最終液体洗浄剤組成物中の夾雑無
機塩類量が１重量％（以下単に％で示す）以下となるよ
うにした、脱塩したアミドアミン型両性界面活性剤を用
いるのが好ましい。Examples of the salt include alkali metal salts such as sodium chloride, alkaline earth metal salts such as magnesium salts, alkanolamine salts such as triethanolamine salts, and ammonium salts. In addition, when these salts are used, they tend to contain inorganic salts as contaminants, but if some or all of these inorganic salts are removed, the amount of contaminant inorganic salts in the final liquid cleaning composition is 1% by weight (hereinafter referred to as 1% by weight). It is preferable to use a desalted amidoamine type amphoteric surfactant having the following properties (expressed simply in %):
脱塩したアミドアミン型両性界面活性剤は溶媒抽出、電
気透析その他の方法で調製することができるが、特に、
下記一般式（Ｉａ）で示される２級アミドアミノ酸をア
ンモニアもしくはトリエタノールアミンの塩とし、最終
液体洗浄剤組成物中の夾雑無機基量が１％となるよう調
整したものが好ましい。Desalted amidoamine-type amphoteric surfactants can be prepared by solvent extraction, electrodialysis, and other methods, but in particular,
It is preferable to use a secondary amide amino acid represented by the following general formula (Ia) as a salt of ammonia or triethanolamine, and adjust the amount of contaminant inorganic groups in the final liquid cleaning composition to 1%.
本発明の（Ｂ）成分であるアルキルサツカライド系界面
活性剤は％ （ＩｌｌＪ式中ｓ式中６が炭素数８〜１
８、好ましくは１２〜１４のアルキル、アルケニル、分
岐アルキル又はアルキルフェニル基で、親水基のサツカ
ライド［（ｉｌｌ）式中、Ｇ〕が炭素数５〜６の還元糖
全基本単位とするものである。還元糖としては、グルコ
ース、ガンクトース、フルクトースが好ましり、−般式
（Ｉｌｌ）中、ｎで示されるサツカライド重会度は１〜
１０、荷に１〜５が好ましい。The alkyl saccharide surfactant which is the component (B) of the present invention is
8, preferably a 12 to 14 alkyl, alkenyl, branched alkyl, or alkylphenyl group, in which the hydrophilic saccharide [G in the formula (ill)] is the entire basic unit of a reducing sugar having 5 to 6 carbon atoms. . As the reducing sugar, glucose, gunctose, and fructose are preferred;
10, preferably 1 to 5.
本発明の洗浄剤組成物中に、（Ａ）成分は１％以上、（
Ｂ）成分は０．１％以上配合されればよいが、特に液体
洗浄剤としては、（８）成分１〜３５％、（Ｂ）成分０
．１〜３０％程度、ペースト状洗浄剤としては、（〜成
分１．０〜６０％、（Ｂ）成分０．１〜６０％程度配合
されることが好ましい。In the cleaning composition of the present invention, component (A) contains 1% or more of (
Component B) may be blended in an amount of 0.1% or more, but especially for liquid cleaning agents, component (8) should be 1 to 35%, component (B) 0.
．． It is preferable that about 1 to 30% of the component (-) and about 0.1 to 60% of the component (B) be blended in the paste-like cleaning agent.
本発明の洗浄剤組成物には、上記必須成分の他、洗浄剤
に通常用いられる成分、例えば皮膚、毛髪洗浄剤であれ
ば、高級脂肪酸塩、アルキルアミンオキサイド、Ｈ旨肪
酸アルカノールアマイド、スクワレン、ラノリン等の感
触向上剤；ゾロピレングリコール、ンルビトール、グリ
セリン等の保湿剤；カルボキシビニル破すマー、メチル
セルロース、エタノール、赦すオキシエチレングリコー
ルゾステアレート寺の粘度調整剤；パール化剤等の外観
調整剤；その他、香料、色素、紫外線吸収剤、酸化防止
剤、殺菌剤、抗炎症剤、防腐剤等を、また食器用、衣料
用洗浄剤であれば起泡剤、消泡剤、汚れ再付着防止剤、
金属イオン封鎖剤、螢光染料、酵素等、酸化防止剤、そ
の他防腐剤、色素、香料等を必要に応じて配合すること
ができる。In addition to the above-mentioned essential ingredients, the cleaning composition of the present invention contains ingredients commonly used in cleaning agents, such as higher fatty acid salts, alkylamine oxides, H fatty acid alkanolamides, and squalene in the case of skin and hair cleaning agents. Feel-improving agents such as , lanolin; Humectants such as zolopyrene glycol, nlubitol, glycerin; Viscosity modifiers such as carboxyvinyl breakers, methyl cellulose, ethanol, and oxyethylene glycol zostearate; Appearance adjustment agents such as pearlizing agents. Other additives include fragrances, pigments, ultraviolet absorbers, antioxidants, bactericidal agents, anti-inflammatory agents, preservatives, etc., as well as foaming agents, antifoaming agents, and dirt reattachment for dishwashing and clothing detergents. inhibitor,
Sequestering agents, fluorescent dyes, enzymes, antioxidants, other preservatives, pigments, fragrances, etc. can be added as necessary.
〔発明の効果」
不発明の洗浄剤組成物は、皮膚や毛髪に対する刺激性が
低く、シかも起泡力や洗浄力にも優れ、皮膚洗浄剤、シ
ャンシー、食器用洗浄剤、ウール等金中心とする衣料用
洗浄剤として好適に用いられる。[Effects of the invention] The uninvented cleaning composition has low irritation to the skin and hair, has excellent foaming power and cleaning power, and is useful for skin cleansers, shampoos, dishwashing detergents, wool, etc. It is suitably used as a laundry detergent.
実施例１
第１表に示す組成の洗浄剤組成物を調製し、次の方法に
よシ評価した。結果を第１表に示す。Example 1 A cleaning composition having the composition shown in Table 1 was prepared and evaluated according to the following method. The results are shown in Table 1.
＝１２−
（起泡力）
各洗浄剤組成物の１％水溶液に人工汚れとしてラノリン
０．１％を加え、２５℃において平型ゾロペラを用いて
シリンダー中で回転数１１０００ｒｐ、１０秒毎反転の
粂件で５分間攪拌し、３０秒後の泡量を測定した。=12- (Foaming power) 0.1% lanolin was added as an artificial stain to a 1% aqueous solution of each cleaning composition, and the mixture was heated in a cylinder at 11,000 rpm at 25°C using a flat Zolopella, with rotation every 10 seconds. The mixture was stirred for 5 minutes at a stirring temperature, and the amount of foam was measured after 30 seconds.
（泡の外感）
洗浄剤組成物１１を２０２のかもしに塗布し、１分間泡
立てた後、生じた泡の外観を次の基準により評価した。(External appearance of foam) Cleaning composition 11 was applied to No. 202 foam, and after lathering for 1 minute, the appearance of the resulting foam was evaluated according to the following criteria.
○：泡の外観がきめ細かくクリーミーである
△：泡の外観が普通である
×：泡の外観がきめが荒く良くない
実施例２
第２表に示す組成のシャンシー組成物を調製した。各シ
ャンシー組成物１７を用い、３０ｒの入毛ｆ：４０ｃの
水で湿らせ水２０ｆを含んだものを洗髪し、その官能評
価を女性、ｅネジ−２０名によシ下記の基準で行った。○: The appearance of the foam is fine and creamy. △: The appearance of the foam is normal. ×: The appearance of the foam is rough and not good. Example 2 Chassis compositions having the compositions shown in Table 2 were prepared. Using each shampoo composition 17, the hair was moistened with 30R of water and 40C of water, and the hair was washed with 20F of water, and the sensory evaluation was conducted by 20 female e-screws according to the following criteria. .
（評価基準）
○：良い
△：ふつう
×：悪い
以下余白
＝１７＝
第２表から明らかなように、本発明品であるシャンシー
Ａは、泡量、泡質共に優れたものである。(Evaluation Criteria) ○: Good △: Average ×: Bad Below margin = 17 = As is clear from Table 2, Chansea A, the product of the present invention, is excellent in both foam quantity and foam quality.
実施例３〜６
次に示す洗浄剤組成物を調製した。これらは、いずれも
皮膚に対する刺激性が極めて低く、シかも洗浄性、起泡
性とも良好でめった。Examples 3 to 6 The following cleaning compositions were prepared. All of these had extremely low irritation to the skin, good cleansing properties, and good foaming properties.
Ｃｏ ＯＧｇ、ｓ １０ラウ
リン酸ゾエタノールアミド １香料、
色素 適 量水
２々う、え（実施例
４） 羊毛軽質洗浄剤：
Ｎ−ラウロイル−Ｎ′−力ルボキシメチル
（％）Ｃｓｚ −ＯＧ２．５
５ラウリルゾメチルアミンオキシド
５メチルセルロース
０．５エチルアルコール
８香 料
適 量水
ノ々ランスＣ１２（−） Ｇ２．Ｓ
５α−オレフィンスルホン
ｆｌｆｆｉ トＩＪエタノ−５ルアミン塩
ラウリン酸ゾエタノールアミド ２カ
ルボキシビニル？リマ−０，５
エチルアルコール ８香
料、色素、濁シ剤 適 量水
バランスＣ
Ｉ２ ０ Ｇｚ、ｓ
１５ラウリン酸ゾエタノールアミド
３カチオン化セルロース
（ｐｏｌｙｍｅｒ ＪＲ４００，ＵＣＣ社ｓ ）０．２
香料５色素 通 量水
バランス以上Co OGg, s 10 lauric acid zoethanolamide 1 fragrance,
Pigment Appropriate amount of water
Example 4 Light detergent for wool: N-lauroyl-N'-hydroxymethyl
(%)Csz-OG2.5
5 laurylzomethylamine oxide
5 methyl cellulose
0.5 ethyl alcohol
8 fragrances
Appropriate amount of water
Nono Lance C12 (-) G2. S
5α-olefin sulfone flffi toIJ ethanol-5-lamine salt lauric acid zoethanolamide 2 carboxyvinyl? Limer-0.5 Ethyl alcohol 8 Fragrance, pigment, clouding agent Appropriate amount Water
Balance C
I2 0 Gz,s
15 Lauric acid zoethanolamide
Tri-cationized cellulose (polymer JR400, UCC Corporation) 0.2
Fragrance 5 pigments volume water
More than balance
Claims (1)
又は不飽和炭化水素基を示し、Ｒ＿２及びＲ＿４は基−
ＣＨ＿２ＣＯＯＭ又は−ＣＨ＿２ＣＨ＿２ＣＯＯＭ（Ｍ
は水素、アルカリ金属又はアルカノールアミンを示す）
を示し、Ｒ＿５は水素、基−ＣＨ＿２ＣＯＯＭ又は−Ｃ
Ｈ＿２ＣＨ＿２ＣＯＯＭ（Ｍは水素、アルカリ金属又は
アルカノールアミンを示す）を示す〕 で表わされるアミドアミン型両性界面活性剤（Ｂ）一般
式（III） Ｒ＿６−Ｏ−（Ｇ）＿ｎ（III） （式中、Ｒ＿６は炭素数８〜１８のアルキル、アルケニ
ル、分岐アルキル又はアルキルフェニル基を示し、Ｇは
炭素数５〜６の還元糖を示し、ｎは１〜１０の数を示す
） で表わされるアルキルサッカライド系界面活性剤 を含有することを特徴とする低刺激性洗浄剤組成物。[Claims] 1. The following components (A) and (B) (A) General formula (I) or (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲Mathematical formulas, chemical formulas, tables, etc. ▼(II) [In the formula, R_1 and R_3 each represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R_2 and R_4 are groups -
CH_2COOM or -CH_2CH_2COOM(M
indicates hydrogen, alkali metal or alkanolamine)
, R_5 is hydrogen, group -CH_2COOM or -C
H_2CH_2COOM (M represents hydrogen, an alkali metal, or an alkanolamine)] Amidoamine type amphoteric surfactant (B) general formula (III) R_6-O-(G)_n(III) (wherein R_6 represents an alkyl, alkenyl, branched alkyl or alkylphenyl group having 8 to 18 carbon atoms, G represents a reducing sugar having 5 to 6 carbon atoms, and n represents a number from 1 to 10) A hypoallergenic cleaning composition characterized in that it contains an active agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63115540A JP2561125B2 (en) | 1988-05-12 | 1988-05-12 | Hypoallergenic detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63115540A JP2561125B2 (en) | 1988-05-12 | 1988-05-12 | Hypoallergenic detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01284597A true JPH01284597A (en) | 1989-11-15 |
| JP2561125B2 JP2561125B2 (en) | 1996-12-04 |
Family
ID=14665061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63115540A Expired - Fee Related JP2561125B2 (en) | 1988-05-12 | 1988-05-12 | Hypoallergenic detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2561125B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03174499A (en) * | 1989-12-04 | 1991-07-29 | Kao Corp | Detergent composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5531841A (en) * | 1978-08-26 | 1980-03-06 | Lion Fat Oil Co Ltd | Shampoo composition |
| JPS6469695A (en) * | 1987-09-09 | 1989-03-15 | Shiseido Co Ltd | Detergent composition |
-
1988
- 1988-05-12 JP JP63115540A patent/JP2561125B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5531841A (en) * | 1978-08-26 | 1980-03-06 | Lion Fat Oil Co Ltd | Shampoo composition |
| JPS6469695A (en) * | 1987-09-09 | 1989-03-15 | Shiseido Co Ltd | Detergent composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03174499A (en) * | 1989-12-04 | 1991-07-29 | Kao Corp | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2561125B2 (en) | 1996-12-04 |
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