JPH01281932A - Stainless steel sheet excellent in detergency against finger print - Google Patents
Stainless steel sheet excellent in detergency against finger printInfo
- Publication number
- JPH01281932A JPH01281932A JP11206688A JP11206688A JPH01281932A JP H01281932 A JPH01281932 A JP H01281932A JP 11206688 A JP11206688 A JP 11206688A JP 11206688 A JP11206688 A JP 11206688A JP H01281932 A JPH01281932 A JP H01281932A
- Authority
- JP
- Japan
- Prior art keywords
- stainless steel
- steel sheet
- water
- soluble polymer
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 26
- 239000010935 stainless steel Substances 0.000 title claims abstract description 26
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 11
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 abstract description 12
- 210000004243 sweat Anatomy 0.000 abstract description 6
- 229920002125 Sokalan® Polymers 0.000 abstract description 4
- 239000004584 polyacrylic acid Substances 0.000 abstract description 4
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 229920002401 polyacrylamide Polymers 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 239000012190 activator Substances 0.000 abstract 4
- 239000000356 contaminant Substances 0.000 abstract 3
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、指紋が１弓着しにくく、しがも付着しても水
洗により容易に除去することかで゛きるステンレス鋼板
に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a stainless steel plate on which fingerprints are unlikely to adhere, and even if fingerprints do adhere thereto, they can be easily removed by washing with water.
（従米技術）
ステンレス鋼板は、耐食性、機械的性質、外観などに優
れ−（いるので、近２年、鉄道中面、建築拐料、装飾品
など−・の使用が増加している。(U.S. technology) Stainless steel sheets have excellent corrosion resistance, mechanical properties, and appearance, so their use in railway interiors, construction materials, decorations, etc. has been increasing in the past two years.
ステンレスｇＡ板を」−記用途に使用するＪ易介、辿常
裸の状態で使用するが、ステンレス鋼板は、指紋や汗な
どの汚れがイ」着し易く、しかもイ・１着した場合、非
常に目立ち易い。また、汚れを伺χ１したまま放置して
おくと、汚れは、沈着、変質して、除去されにくくなる
。さらに、指紋や汗などの汚れには、食塩が含まれてい
るため、汚れを放：Ｖｔ しておくと、腐食される懸念
もある。このため、従来汚れが１１１着して、目立つよ
うになった場合、表面を洗浄剤で洗い、除去していた。Stainless steel plates are used for writing purposes, and they are usually used bare, but stainless steel plates tend to attract dirt such as fingerprints and sweat, and if they are exposed to dirt, Very noticeable. Furthermore, if dirt is left untreated, the dirt will settle and deteriorate, making it difficult to remove. Furthermore, since stains such as fingerprints and sweat contain salt, there is a risk of corrosion if the stains are left alone. For this reason, conventionally, when dirt has accumulated and become noticeable, the surface has been washed with a cleaning agent to remove it.
この指紋などの汚れを防止する）ｊ法として、従来」：
り行なわれている方法は、表面を育成もしくは無機ポリ
マーの水に不溶な皮膜で被覆・Ｖる方法である。Conventional method to prevent stains such as fingerprints:
The most commonly used method is to grow or coat the surface with a water-insoluble film of an inorganic polymer.
（発明が解決しようとする問題点）
この方法にＪ：れば、汚れは、裸の状態より（；１着し
にくくなるが、付着した場合、水洗では容易に除去でき
ないという欠点があった。(Problems to be Solved by the Invention) This method has the disadvantage that stains are more difficult to remove than in a bare condition, but if they do adhere, they cannot be easily removed by washing with water.
このため、汚れが４８１着しにくい状態のままて゛、付
着した場合は、水洗で容易に除去できるようにする必要
があった。For this reason, it is necessary to maintain a state in which dirt is difficult to adhere to, and to easily remove it by washing with water if it adheres.
（問題ツユを解決するための手段）
本発明は、ステンレス鋼板の表面にノニオン系界面活性
剤な含イｊする水溶性ポリマー皮膜を形成して、指紋や
汗などの汚れを付着しにくくシ、また、水洗で容易に除
去できるようにした。(Means for solving the problem) The present invention forms a water-soluble polymer film containing a nonionic surfactant on the surface of a stainless steel plate to prevent stains such as fingerprints and sweat from adhering to it. Additionally, it can be easily removed by washing with water.
ここで、皮膜に含有さぜるノニオン系界面活性剤として
は、市販のもので十分である。しかし、ＩＩ Ｌ Ｄ値
（分子の疎水基と親木基の平衡度合）１１＝１６のもの
が指紋水洗除去性に蝮れている。添付図面は、Ｉｔ Ｌ
Ｂ値が８〜１５〕のノニオン系界面活性剤が０．１％
の水溶液を調整して、この水溶液をガーゼに染み込まぜ
、そのガーゼでステンレス鋼板に飼料さぜた人工指紋を
洗浄して、指紋の洗浄除去性を調査したものであるが、
界面活性剤は、１１１゜１３値Ｊ １ ＝ ：ｌ ６の
ものか、洗浄除去性に優れていることがわかる。Here, as the nonionic surfactant to be mixed into the film, commercially available ones are sufficient. However, those having an IILD value (degree of equilibrium between the hydrophobic group and the parent group of the molecule) of 11=16 are poor in fingerprint washing removability. The attached drawings are It L
0.1% nonionic surfactant with a B value of 8 to 15]
An aqueous solution was prepared, this aqueous solution was impregnated with gauze, and the gauze was used to wash artificial fingerprints mixed with feed on a stainless steel plate, and the removability of the fingerprints was investigated.
It can be seen that the surfactant has a 111°13 value J 1 = :l 6 and has excellent cleaning removability.
なお、界面活性剤として、ノニオン系のものを含有させ
るようにしたのは、イオン系であると、ステンレス鋼板
に付着し、美観を失う懸念があるからである１、
水溶性ポリマーとしては、水に可溶で、鋼板に塗布した
場合に界面活性剤を保持した状態で・水溶性フィルムを
形成できるものであれはよい。例えば、ポリアクリル酸
、ポリアクリルアミド、ポリメタクリル酸、メチルセル
ロース、カルボキンメチルセルロース、ポリビニルピロ
リドン、ポリヒドロキンルエチルアクリレー１、ポリビ
ニルアルコールなどである。なお、これらのポリマーに
は、加熱すると、変質して水に不溶になるものか含まれ
ているが、そのようなものは、フィルムにする場合常温
乾燥することにより行う。The reason why we included a nonionic surfactant was because there is a concern that if an ionic surfactant were used, it would adhere to the stainless steel plate and lose its aesthetic appearance1. Any material that is soluble in water and can form a water-soluble film while retaining the surfactant when applied to a steel plate is suitable. Examples include polyacrylic acid, polyacrylamide, polymethacrylic acid, methyl cellulose, carboxyl methyl cellulose, polyvinylpyrrolidone, polyhydrokine ethyl acrylate 1, polyvinyl alcohol, and the like. Note that some of these polymers change in quality and become insoluble in water when heated, and when such polymers are made into a film, they are dried at room temperature.
ステンレス鋼板への水溶性ポリマー皮膜の形成は、ノニ
オン系界面活性剤を添加した水溶性ポリマーの水溶液を
脱脂、洗浄したステンレス鋼板に塗布して、乾燥すれば
、形成することができる。。A water-soluble polymer film can be formed on a stainless steel plate by applying an aqueous solution of a water-soluble polymer to which a nonionic surfactant has been added to a degreased and washed stainless steel plate and drying it. .
この水溶性ポリマー皮膜の形成は、ステンレス鋼板製造
時に行ってもよく、部材に加工するｊ易介は、加工後に
行ってもよい。The formation of this water-soluble polymer film may be performed during the production of the stainless steel sheet, and the processing for forming a member may be performed after processing.
（作用）
本発明のステンレス鋼板は、水溶性ポリマーの皮膜を被
覆しているので、指紋や汗などの汚れか（＝１着しにく
い。また、飼料した指紋は、皮膜が水溶性ポリマーであ
り、しかも界面活性剤を含有しているので、洗浄剤を使
用しなくても水洗で容易に除去、い。、え、皮膜、１劣
化、ア、え蹴合も表面を水洗ｒれは、新たな皮膜面にす
ることができる。さらに、皮膜が不要になったときは、
水洗すれば、皮膜を除去することができる。(Function) The stainless steel plate of the present invention is coated with a water-soluble polymer film, so it is difficult to attract dirt such as fingerprints and sweat. Moreover, since it contains a surfactant, it can be easily removed by washing with water without using a cleaning agent. The coating surface can be made into
The film can be removed by washing with water.
（実施例）
ＩＩ Ｌ Ｂ値が１３のノニオン系界面活性剤［花王（
株）製エマルデン１の０．１％と、ポリビニルアルコー
ルＡ［信越化学工業（株）製ＰΔ−０５（ケン化度８８
％）１、ポリビニルアルコール１３１同Ｃ−０５（ケン
化度９８％）］またはポリアクリル酸［和光紬薬工業（
株）製（の′いずれか１種とを５％含有するポリビニル
アルコール水溶液またはポリアクリル酸を脱脂処理済ス
テンレス鋼板に塗布、常温乾燥することによりノニオン
系界面活性剤未含有および含有水溶性ポリマー皮膜を形
成した。 “
−・方、これとは別にアクリルエマルン゛ヨン［三洋化
成工業（株）製ＮＳ−１０３］の２０％水溶液を脱ＩＩ
Ｉ？処理済ステンレス鋼板に塗布して、１２０℃で乾燥
することにＪ：り硬化させ、水に不溶性のアクリル樹脂
の皮膜を形成した。(Example) IILB Nonionic surfactant with a B value of 13 [Kao (
0.1% of Emulden 1 manufactured by Shin-Etsu Chemical Co., Ltd. and polyvinyl alcohol A [PΔ-05 manufactured by Shin-Etsu Chemical Co., Ltd. (Saponification degree 88
%) 1, polyvinyl alcohol 131 C-05 (saponification degree 98%)] or polyacrylic acid [Wako Tsumugi Kogyo Co., Ltd.
Aqueous polyvinyl alcohol solution or polyacrylic acid containing 5% of any one of the following products manufactured by Co., Ltd. is coated on a degreased stainless steel plate and dried at room temperature to form a water-soluble polymer film that does not contain or contains nonionic surfactants. Separately, a 20% aqueous solution of acrylic emulsion [NS-103 manufactured by Sanyo Chemical Industries, Ltd.] was dehydrated.
I? It was applied to a treated stainless steel plate and cured by drying at 120° C. to form a water-insoluble acrylic resin film.
次に、以上のようにして皮膜を形成したステンレス鋼板
と裸ステンレス鋼板に人工指紋を（−ｔ Ｘｉさせ、指
紋封着防止性と、水洗による（＝ｔ ｆｆｉ指紋の除去
性とを調査した。この結果を表１に示す。Next, artificial fingerprints were applied to the stainless steel plate on which the film was formed as described above and the bare stainless steel plate (-t Xi), and the fingerprint sealing prevention property and the removability of the fingerprint (=t ffi) by washing with water were investigated. The results are shown in Table 1.
なお、人工指紋の付着は、人工指紋液（′ｌ−ｒ開昭５
６−４２１３９号）をシリコンゴム栓に塗布して、それ
をステンレス鋼板表面に押し伺ける方法により行った。In addition, artificial fingerprints can be attached using artificial fingerprint liquid ('l-r Kaisho 5
No. 6-42139) was applied to a silicone rubber stopper, and the coating was applied to the surface of a stainless steel plate.
表１に示すように、本発明のステンレス鋼板は、指紋が
イ」着しても水洗で容易に除去できる５、（発明の効果
）
以」二のごとく、本発明のステンレス鋼板は、従来の有
機溶剤可ｍ性の有機ポリマーを塗布したものより指紋洗
浄性に優れている。As shown in Table 1, even if fingerprints are deposited on the stainless steel plate of the present invention, they can be easily removed by washing with water. It has better fingerprint cleaning properties than those coated with organic solvent-soluble organic polymers.
添付図面は、ステンレス鋼板にイ・１着した人」−指紋
をＩＩ Ｌ Ｂ値か８〜１９のノニオン系界面活性剤水
溶液（濃度０．１％）含浸ガーゼで洗浄した場合の界面
活性剤Ｉｔ Ｌ Ｂ値と指紋洗浄性との関係を示すグラ
フである。The attached drawing shows the surfactant It when a person's fingerprint is washed with gauze impregnated with a nonionic surfactant aqueous solution (concentration 0.1%) with a IILB value of 8 to 19 on a stainless steel plate. It is a graph showing the relationship between the LB value and the fingerprint cleanability.
Claims (2)
含有する水溶性ポリマー皮膜を形成したことを特徴とす
る指紋洗浄性に優れたステンレス鋼板。(1) A stainless steel plate with excellent fingerprint cleaning properties, characterized in that a water-soluble polymer film containing a nonionic surfactant is formed on the surface of the stainless steel plate.
あることを特徴とする特許請求の範囲第１項に記載の指
紋洗浄性に優れたステンレス鋼板。(2) The stainless steel plate with excellent fingerprint cleaning properties according to claim 1, wherein the nonionic surfactant has an HLB value of 11 to 16.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11206688A JPH01281932A (en) | 1988-05-09 | 1988-05-09 | Stainless steel sheet excellent in detergency against finger print |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11206688A JPH01281932A (en) | 1988-05-09 | 1988-05-09 | Stainless steel sheet excellent in detergency against finger print |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01281932A true JPH01281932A (en) | 1989-11-13 |
Family
ID=14577200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11206688A Pending JPH01281932A (en) | 1988-05-09 | 1988-05-09 | Stainless steel sheet excellent in detergency against finger print |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01281932A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1082076C (en) * | 1999-06-29 | 2002-04-03 | 上海宝钢集团公司 | Fingerprint-resistant chromate treating agent |
| CN1082075C (en) * | 1999-06-29 | 2002-04-03 | 上海宝钢集团公司 | Fingerprint resisting water-base paint |
| JP2009040056A (en) * | 2008-09-19 | 2009-02-26 | Lintec Corp | Hard coat film for touch panel or display |
| WO2011013497A1 (en) * | 2009-07-30 | 2011-02-03 | ハリマ化成株式会社 | Photocurable hydrophilic coating agent, hydrophilic coating film, and hydrophilically coated article |
| CN104002518A (en) * | 2014-05-15 | 2014-08-27 | 合肥禾盛新型材料有限公司 | Pollution-proof special effect panel and making method thereof |
| CN111100545A (en) * | 2019-12-20 | 2020-05-05 | 上海维凯光电新材料有限公司 | High-wear-resistance anti-fingerprint ultraviolet curing coating composition and preparation method thereof |
-
1988
- 1988-05-09 JP JP11206688A patent/JPH01281932A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1082076C (en) * | 1999-06-29 | 2002-04-03 | 上海宝钢集团公司 | Fingerprint-resistant chromate treating agent |
| CN1082075C (en) * | 1999-06-29 | 2002-04-03 | 上海宝钢集团公司 | Fingerprint resisting water-base paint |
| JP2009040056A (en) * | 2008-09-19 | 2009-02-26 | Lintec Corp | Hard coat film for touch panel or display |
| WO2011013497A1 (en) * | 2009-07-30 | 2011-02-03 | ハリマ化成株式会社 | Photocurable hydrophilic coating agent, hydrophilic coating film, and hydrophilically coated article |
| JPWO2011013497A1 (en) * | 2009-07-30 | 2013-01-07 | ハリマ化成株式会社 | Photocurable hydrophilic coating, hydrophilic coating, and hydrophilic article |
| JP5341105B2 (en) * | 2009-07-30 | 2013-11-13 | ハリマ化成株式会社 | Photocurable hydrophilic coating, hydrophilic coating, and hydrophilic article |
| CN104002518A (en) * | 2014-05-15 | 2014-08-27 | 合肥禾盛新型材料有限公司 | Pollution-proof special effect panel and making method thereof |
| CN111100545A (en) * | 2019-12-20 | 2020-05-05 | 上海维凯光电新材料有限公司 | High-wear-resistance anti-fingerprint ultraviolet curing coating composition and preparation method thereof |
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