JPH01273543A - Highly antioxidant fatty oil - Google Patents
Highly antioxidant fatty oilInfo
- Publication number
- JPH01273543A JPH01273543A JP63103498A JP10349888A JPH01273543A JP H01273543 A JPH01273543 A JP H01273543A JP 63103498 A JP63103498 A JP 63103498A JP 10349888 A JP10349888 A JP 10349888A JP H01273543 A JPH01273543 A JP H01273543A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- fatty oil
- almond
- almonds
- roasted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003078 antioxidant effect Effects 0.000 title claims description 14
- 239000010685 fatty oil Substances 0.000 title abstract 6
- 239000003963 antioxidant agent Substances 0.000 title description 6
- 235000020224 almond Nutrition 0.000 claims abstract description 28
- 241000220304 Prunus dulcis Species 0.000 claims abstract 7
- 239000003921 oil Substances 0.000 abstract description 25
- 239000000796 flavoring agent Substances 0.000 abstract description 14
- 235000019634 flavors Nutrition 0.000 abstract description 14
- 235000011437 Amygdalus communis Nutrition 0.000 abstract description 9
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 230000002085 persistent effect Effects 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 24
- 244000144725 Amygdalus communis Species 0.000 description 23
- 239000003925 fat Substances 0.000 description 18
- 235000006708 antioxidants Nutrition 0.000 description 5
- 235000013606 potato chips Nutrition 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229930003799 tocopherol Natural products 0.000 description 2
- 239000011732 tocopherol Substances 0.000 description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000003893 Prunus dulcis var amara Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229940069445 licorice extract Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000005195 poor health Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000020985 whole grains Nutrition 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Edible Oils And Fats (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【発明の詳細な説明】
■ 産業上の利用分野
本発明は、好ましいアーモンドの風味を有し、かつ抗酸
化性にすぐれた油脂に関するものである。DETAILED DESCRIPTION OF THE INVENTION (1) Industrial Application Field The present invention relates to an oil or fat that has a desirable almond flavor and has excellent antioxidant properties.
■ 従来の技術及び本光明が解決しようとしている課題
従来から油脂の抗酸化性をた◆かめるために、ジブチル
ヒドロキシトルエン(8HT)、ブチルヒドロキシアニ
ソール(8HA)、没食子酸プロピル等の合成抗酸化剤
や、トコフェロール、甘草抽出物、各種スパイス類、ア
ミノ酸と糖との褐変反応生成物等の天然抗酸化剤が使用
されてきた。■ Conventional technology and the problems that this Komei is trying to solve ◆ In order to check the antioxidant properties of oils and fats, synthetic antioxidants such as dibutylhydroxytoluene (8HT), butylhydroxyanisole (8HA), propyl gallate, etc. Natural antioxidants such as tocopherols, licorice extract, various spices, and browning reaction products of amino acids and sugars have been used.
しかしながら、合成抗酸化剤は衡生上の安全性の面で、
天然抗酸化剤はその効果の点で、夫々今一つ充分でない
うらみがあった。なお、油脂に水素添加することによっ
てその不飽和度を減じ、抗酸化性を向上することもでき
るが、水素添加プることによって油脂そのものの物性が
変ってしまい又は風味の点でも好ましくない場合が多く
、抗酸化性向上の手段として余り適切であるとはいえな
い。However, synthetic antioxidants have poor health and safety issues.
Natural antioxidants have been lacking in their effectiveness. Furthermore, by hydrogenating fats and oils, it is possible to reduce the degree of unsaturation and improve antioxidant properties, but hydrogenation may change the physical properties of the fats and oils themselves and may be undesirable in terms of flavor. In most cases, it cannot be said to be very suitable as a means of improving antioxidant properties.
たとえば、ポテトチップに使用するフライ油は、従来は
保存性が悪いため風味が劣化しやすいので水素添加して
保存性の良いものにして使用していた。しかし、水素添
加油は口溶けが悪いため、ある程度は保存性を犠牲にし
ても水素添加しないも゛のが使用されるようになってき
ている。本発明はかかる課題を解決したものである。For example, frying oil used for potato chips has traditionally had a poor shelf life and tends to lose its flavor, so it has been hydrogenated to make it more shelf-stable. However, since hydrogenated oil does not dissolve well in the mouth, non-hydrogenated oils are now being used, even if it means sacrificing shelf life to some extent. The present invention solves this problem.
■ 課題を解決するための手段
本発明は、アーモンドをこげ臭が光生ずる程度以上に過
剰に焙煎し、これを油脂に漸次浸漬し、アーモンド中の
成分を油脂中に浸出させ又は分散さゼて抗酸化性の高い
油脂としたものである。以下にその詳細を説明する。■Means for Solving the Problems The present invention involves roasting almonds excessively to the extent that a burnt odor is produced, and gradually immersing the almonds in oil and fat so that the components in the almonds are leached or dispersed into the oil and fat. It is made into an oil with high antioxidant properties. The details will be explained below.
本発明で使用するアーモンドは、その品種、産地等の如
何にかかわりなくいずれも採用される。Any almond can be used in the present invention, regardless of its variety, production area, etc.
従って、カリフォルニア産、地中海沿岸産等の差又はス
ィートアーモンドとビターアーモンドの差を問わない。Therefore, it does not matter whether the almonds are produced in California or the Mediterranean region, or the difference between sweet almonds and bitter almonds.
焙煎するに際しては全粒のままでも粉砕したものでも構
わない。粉砕の程度は粗砕から磨砕までの範囲を含むこ
ととし、粉砕の時期は焙煎の前又は後のいずれか又はそ
の前及び後に、夫々要に臨み適宜行うこととする。When roasting, whole grains or crushed grains may be used. The degree of pulverization includes a range from coarse pulverization to grinding, and the pulverization is performed either before or after roasting, or before and after roasting, depending on the need.
焙煎手段は常法によることとするが焙煎の程度は本発明
において特徴的である。即ち、本願においては、これを
こげ臭(本願においてこげ臭とは、アーモンドの好まし
い芳香であるいわゆるロースト臭というのはこれに含ま
れないこととし、過剰の焙煎によって生じる必ずしも好
ましからざる培煎臭ないし旭焼臭をいうことと覆る。以
下もおなじ)が光生覆る程度以上に焙煎でるのである。The roasting method is a conventional method, but the degree of roasting is characteristic of the present invention. That is, in this application, this is defined as a burnt odor (in this application, burnt odor does not include the so-called roast odor, which is a desirable aroma of almonds, and refers to an undesirable cultivated odor or odor caused by excessive roasting). The Asahi roast smell (the same goes for the following) is roasted to a degree that is even more pronounced than Kosei.
従って、極端な場合、アーモンドが一部又は可成り炭化
したものであってもよい。ただし、現実的には経済性の
点からその殆んどが炭化しない程度において焙煎する。Therefore, in extreme cases, the almonds may be partially or significantly carbonized. However, realistically, from an economic point of view, roasting is done to the extent that most of it does not become carbonized.
たとえば、全粒アーモンドを熱風焙煎機にて焙煎するの
に、熱風の温度的130〜140℃で50〜150分間
処理する。For example, when whole almonds are roasted in a hot air roaster, they are treated with hot air at a temperature of 130 to 140° C. for 50 to 150 minutes.
本発明の処理対象物である油脂とは、通常の食用油脂で
ある。植物性・動物性のいずれも使用でき、また天然油
脂肪の他、水素添加、エステル交換、分別等の処理を経
たものも使用できる。The fats and oils to be treated in the present invention are ordinary edible fats and oils. Both vegetable and animal sources can be used, and in addition to natural oils and fats, those that have undergone treatments such as hydrogenation, transesterification, and fractionation can also be used.
本発明では、アーモンドを過剰焙煎後、”これを油脂に
浸漬し、アーモンド中の成分を油脂中に溶出ないし分散
させ、その後不溶分を除去するのである。たとえば、品
温115〜125℃の油脂にアーモンドを加えて30分
間撹拌し、その後60〜70℃に一昼夜放置し、ついで
これを濾過するなどによる。この場合、アーモンドの使
用量は油脂100部に対して大よそ5部以上程度使用す
ればよい。In the present invention, after over-roasting almonds, they are immersed in oil to dissolve or disperse the components in the almonds into the oil and fat, and then insoluble components are removed. Almonds are added to fat and oil, stirred for 30 minutes, then left at 60 to 70°C overnight, and then filtered.In this case, the amount of almonds used is approximately 5 parts or more per 100 parts of fat or oil. do it.
■ 作用
アーモンドを本発明におけるような焙煎処理を施すと理
由不詳乍ら抗酸化性の油性物質を生成するようである。(2) Effect When almonds are roasted as in the present invention, they appear to produce antioxidant oily substances for unknown reasons.
このことは従来全く知られていなかった。焙煎条件が通
常の温度と時間の条件、つまりロースト臭生成に好まし
い条件下でアーモンドを焙煎してもかがる抗酸化作用は
発現しない。This was completely unknown until now. Even if almonds are roasted under normal roasting conditions of temperature and time, that is, under conditions favorable for producing a roasted odor, the antioxidant effect does not appear.
ただ、余り高温すぎ又は長時間すぎるとアーモンドのこ
げ臭が過剰となり油脂の風味上好ましくないことがある
が、本願目的を達しつる程度の抗酸化性発現のためには
、それ程過熱焙煎する必要はない。香味と抗酸化効果の
点からこげ臭が発生する以上の適宜の温度・時間下で処
理しさえすればよい。However, if the temperature is too high or for too long, the burnt odor of almonds may become excessive and the flavor of the fat may be unfavorable, but in order to achieve the purpose of this application, it is necessary to roast at such a high temperature. There isn't. From the point of view of flavor and antioxidant effect, it is sufficient to process at an appropriate temperature and time above the level at which a burnt odor occurs.
■ 実施例
(実施例1)
アーモンドを100℃又は135℃にて0.15.50
.100又は200分間焙煎し、これを粉砕した。その
粉砕?!F120部(重量部。以下おなし)と純製ラー
ド又は魚硬化油(上屏融点30℃)80部とを混合し、
115〜125℃・30分間撹拌後、60〜70℃で一
昼夜放置し、不溶物を分別除去して、表1に示す通りの
各種試料を得た。■ Example (Example 1) Almonds at 100℃ or 135℃ 0.15.50
.. It was roasted for 100 or 200 minutes and ground. That shatter? ! Mix 120 parts of F1 (parts by weight, hereinafter referred to as "no" below) and 80 parts of pure lard or hardened fish oil (upper melting point 30 ° C.),
After stirring at 115 to 125°C for 30 minutes, the mixture was left at 60 to 70°C for a day and night, and insoluble materials were separated and removed to obtain various samples as shown in Table 1.
各試料調製時のアーモンドの条理条件、油脂の種類及び
得られた試料の試験成績を表1にまとめた。Table 1 summarizes the almond conditioning conditions, the type of oil and fat, and the test results of the obtained samples during the preparation of each sample.
なお、同表には試料aa用の元の油脂の試験成績(試料
番@し一部及びF−0)も併せて示しである。In addition, the same table also shows the test results of the original fats and oils for sample aa (sample numbers @ part and F-0).
上表によれば焙煎時間が短いもの(F−1ないしF−2
)は殆んど抗酸化効果の増加が認められないがそれ以上
、焙煎時間が永いものは次第に抗酸化効果も増大してい
る。しかしこの方法による限りは風味の点で焙煎温度な
いし時間には制限があることが示唆されている。According to the table above, those with short roasting time (F-1 to F-2
), there is almost no increase in the antioxidant effect, but the longer the roasting time is, the more the antioxidant effect gradually increases. However, it has been suggested that as long as this method is used, there are limitations to the roasting temperature and time in terms of flavor.
(実施例2)
アーモンドを135°C・100分間焙煎し、これを粉
砕した。粉砕物20部をトコフェロール2001)I)
TIをふくむfi製パーム油80部に投入し115〜1
25℃・30分間撹拌した後、60〜70℃において一
昼夜放置し、不溶物を濾過して本発明品を得た。この油
脂で1〜21111厚さにスライスし水洗した馬鈴しよ
を180’C:・3〜5分間フライしてポテトチップと
した。余分の油を振り落してから包装し、30℃雰囲気
中に保存してその風味の変化を検した。その結果を表2
に示す。(Example 2) Almonds were roasted at 135°C for 100 minutes and ground. Tocopherol 2001) I)
Pour into 80 parts of fi palm oil containing TI and add 115 to 1
After stirring at 25° C. for 30 minutes, the mixture was left at 60 to 70° C. for a day and night, and insoluble matter was filtered to obtain a product of the present invention. Potato chips sliced into 1-21111 thick slices and washed with water were fried at 180'C for 3-5 minutes using this oil to make potato chips. After shaking off excess oil, it was packaged and stored in an atmosphere at 30°C to examine changes in flavor. Table 2 shows the results.
Shown below.
表2
データは保存されたポテトチップの官能検査く試食)結
果を示す。良とは風味良好、やや不良〜不良は油脂の酸
化臭などが感知されて風味が良くないものである。木表
かられかるように、本発明品でフライされたポテトチッ
プは5ケ月間保存後もなお良好な風味を保っていた。Table 2 Data shows the results of a sensory test (tasting) of stored potato chips. Good means that the flavor is good, and somewhat poor to poor means that the flavor is not good due to the oxidized odor of fats and oils being detected. As can be seen from the table, the potato chips fried with the product of the present invention still maintained good flavor even after being stored for 5 months.
■ 効果
本発明は常識を超える処理をしたアーモンドが全く意外
にも抗酸化性にすぐれた物質を有していることを発見し
て完成されたものである。その有効物質は未だ明らかで
はないにも拘らず、本願の処邪法によるときは著しく油
脂の抗酸化性を向上させることができ、油処理した食品
等の品質・風味を長期間良好に保つことができるもので
ある。■ Effects The present invention was completed through the discovery that almonds, which have been processed beyond common sense, contain a substance that has excellent antioxidative properties, which is quite unexpected. Although its effective substance is not yet clear, the anti-oxidant properties of fats and oils can be significantly improved when the method of the present application is used, and the quality and flavor of oil-treated foods can be maintained for a long period of time. It is something that can be done.
なお、アーモンドの過剰焙煎により生じるこげ臭は必ず
しも直ちに油脂の風味を低下させることにはならず、焙
煎の程度にもよるが、こげ奥は油脂により希釈化され或
いはマスキングされて意外に最終製品・油脂の風味に貢
献することができるものである。It should be noted that the burnt odor caused by over-roasting almonds does not necessarily immediately reduce the flavor of the fat and oil, and although it depends on the degree of roasting, the deep burnt odor may be diluted or masked by the fat and may unexpectedly affect the final taste. It can contribute to the flavor of products and fats and oils.
特許出願人 江崎グリコ株式会社 仙田製油株式会社Patent applicant: Ezaki Glico Co., Ltd. Senda Oil Co., Ltd.
Claims (1)
中に浸漬し、アーモンド中の成分を油脂中に浸出させ又
は分散させてなることを特徴とする抗酸化性にすぐれた
油脂。This oil and fat with excellent antioxidant properties is obtained by immersing almonds that have been roasted to a level above which a burnt odor occurs in oil and fat so that the components in the almonds are leached or dispersed in the oil and fat.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63103498A JPH0732673B2 (en) | 1988-04-26 | 1988-04-26 | Oils and fats with excellent antioxidant properties |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63103498A JPH0732673B2 (en) | 1988-04-26 | 1988-04-26 | Oils and fats with excellent antioxidant properties |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01273543A true JPH01273543A (en) | 1989-11-01 |
JPH0732673B2 JPH0732673B2 (en) | 1995-04-12 |
Family
ID=14355652
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63103498A Expired - Lifetime JPH0732673B2 (en) | 1988-04-26 | 1988-04-26 | Oils and fats with excellent antioxidant properties |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0732673B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002069481A (en) * | 2000-09-01 | 2002-03-08 | Kanegafuchi Chem Ind Co Ltd | Oil and fat composition and method of manufacture |
FR2951615A1 (en) * | 2009-10-27 | 2011-04-29 | Huileries De La Croix Verte Et La Tourangelle Sas | Aromatizing vegetable fatty substance/oil with dry fruit/seed comprises e.g. mixing substance/oil with dry fruit/seed, soaking mixture in hot to form first liquid phase and marc, pressing marc to form second liquid phase and mixing phases |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101465930B1 (en) * | 2014-01-14 | 2014-11-26 | 성균관대학교산학협력단 | Method For Improving Anti-Oxidation Of Fat Using Rice Bran |
-
1988
- 1988-04-26 JP JP63103498A patent/JPH0732673B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002069481A (en) * | 2000-09-01 | 2002-03-08 | Kanegafuchi Chem Ind Co Ltd | Oil and fat composition and method of manufacture |
FR2951615A1 (en) * | 2009-10-27 | 2011-04-29 | Huileries De La Croix Verte Et La Tourangelle Sas | Aromatizing vegetable fatty substance/oil with dry fruit/seed comprises e.g. mixing substance/oil with dry fruit/seed, soaking mixture in hot to form first liquid phase and marc, pressing marc to form second liquid phase and mixing phases |
Also Published As
Publication number | Publication date |
---|---|
JPH0732673B2 (en) | 1995-04-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3180109B2 (en) | Fat composition for frying | |
JP7078198B1 (en) | Oil and fat composition for roux | |
US20200367523A1 (en) | Agent for reducing oiliness of cooked food and method for reducing oiliness of cooked food | |
JP6235185B1 (en) | Miso soup composition for pickling meat and method for producing the same | |
JPH0728660B2 (en) | Flavor oil manufacturing method | |
JP6459161B2 (en) | Confectionery fats and foods using the same | |
CN113519634A (en) | Nut chili oil and preparation method thereof | |
JPH01273543A (en) | Highly antioxidant fatty oil | |
US5229156A (en) | Flavor oil and process for producing the same | |
KR20200038930A (en) | Heat odor inhibitor of heating and cooking oil and fat composition, method for suppressing heat odor of heating and cooking oil and fat composition, and method for producing oil and fat composition for heating and cooking | |
JP2906712B2 (en) | Production method of flavor oil | |
KR910007317B1 (en) | Process for making flavoured edible oil | |
KR0139284B1 (en) | Flavour oil and process for producing the same | |
JPH05987B2 (en) | ||
JP7009289B2 (en) | How to suppress the green leaf-like flavor of Japanese pepper oil | |
CN107114748B (en) | Method for producing solvent | |
JPH02131541A (en) | Seasoning oil and preparation thereof | |
JPS6244598B2 (en) | ||
KR102613945B1 (en) | Pasta sauce comprising (using) Perilla | |
JPH05146251A (en) | Flavor oil and production thereof | |
US2026697A (en) | Prevention of oxidation | |
JP2637196B2 (en) | Production method of flavor oil | |
US2282781A (en) | Imitation olive oil | |
US2282819A (en) | Treatment of hydrogenated oils | |
US2093971A (en) | Stabilization of glyceride oils against oxidation |