JPH01258714A - Electret filter - Google Patents

Electret filter

Info

Publication number
JPH01258714A
JPH01258714A JP63085985A JP8598588A JPH01258714A JP H01258714 A JPH01258714 A JP H01258714A JP 63085985 A JP63085985 A JP 63085985A JP 8598588 A JP8598588 A JP 8598588A JP H01258714 A JPH01258714 A JP H01258714A
Authority
JP
Japan
Prior art keywords
filter
electret
vapor
electret filter
deposited metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63085985A
Other languages
Japanese (ja)
Other versions
JP2536584B2 (en
Inventor
Yatsuhiro Tani
谷 八紘
Satoshi Takase
敏 高瀬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Priority to JP63085985A priority Critical patent/JP2536584B2/en
Priority to DE3839956A priority patent/DE3839956C2/en
Priority to US07/276,617 priority patent/US5112677A/en
Publication of JPH01258714A publication Critical patent/JPH01258714A/en
Priority to US07/770,564 priority patent/US5110620A/en
Application granted granted Critical
Publication of JP2536584B2 publication Critical patent/JP2536584B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Nonwoven Fabrics (AREA)

Abstract

PURPOSE:To prevent a decrease in the collection efficiency of the title filter over a long period by forming the filter with the porous sheet of dielectric polymer, and using an electret sheet having a vapor-deposited metal layer. CONSTITUTION:A vapor-deposited metal film is applied on the porous sheet of a dielectric polymer to form an electret, and a highly charged electret filter is obtained. The high electrostatic charge of the electret filter can be stabilized over a long period by its vapor-deposited metal film. Although the reason why the electret filter is highly charged after the application of the vapor-deposited metal layer is not fully clarified, the surface potential distribution is extremely uniformized over the entire surface of the filter as compared with an electret filter with no vapor-deposited metal film, and hence an increase in the electrostatic charge may result from the uniform injection of charges due to the vapor- deposited metal film. The collection efficiency of the obtained electret filter is not decreased even after long use.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はクリーンルームの空気清浄、ビルの空気調和や
工場排気の浄化用等のエアーフィルター、空気清浄機、
掃除機、複写機などのエアーフィルターやマスクなどに
用いることのできる高帯電量エレクトレフトフィルター
に関するものである。
Detailed Description of the Invention (Industrial Application Field) The present invention relates to air filters, air purifiers, etc. for clean room air purification, building air conditioning, factory exhaust purification, etc.
This invention relates to a high-charge electric left filter that can be used for air filters and masks for vacuum cleaners, copying machines, etc.

(従来技術) 従来、エレクトレットフィルターには特公昭56−47
299に開示さているエレクトレットフィルターがある
。このフィルターはフィーレムをエレクトレット化し、
次いで小繊維化してシート化されるため、フィルターの
もつ帯電量は大きいが、フィルムのスプリット幅を狭く
切ることが出来ないため、繊維が矩型で繊維の形状によ
る機械的捕集効果が小さく、これが原因でフィルターを
長期にわたって使用すると静電気の中和現象によって捕
集効率が経時的に低下し捕集効率が回復しないと言う問
題があった。特公昭53−40073に開示されている
絶縁フィルムをアース電極上に敷いて、その上に繊維シ
ートを置き、エレクトレット化する方法から作製される
フィルターは繊維シートが多孔質のために帯電量が低く
、高い捕集効率が得られないと言う問題があった。
(Prior art) Conventionally, electret filters were
There is an electret filter disclosed in No. 299. This filter turns Feelem into an electret,
Since the filter is then made into small fibers and made into a sheet, the amount of charge that the filter has is large, but because the film cannot be cut into narrow split widths, the fibers are rectangular and the mechanical collection effect due to the shape of the fibers is small. Due to this, when the filter is used for a long period of time, the collection efficiency decreases over time due to the neutralization phenomenon of static electricity, and there is a problem that the collection efficiency does not recover. The filter manufactured by the method disclosed in Japanese Patent Publication No. 53-40073, in which an insulating film is spread on a ground electrode and a fiber sheet is placed on top of it to form an electret, has a low charge amount because the fiber sheet is porous. However, there was a problem in that high collection efficiency could not be obtained.

(発明が解決しようとする問題点) 本発明はかかる従来技術における問題点すなわち長期に
わたって使用しても捕集効率が低下しない、高レベルに
帯電したエレクトレットフィルターの提供を目的とする
ものである。
(Problems to be Solved by the Invention) The present invention aims to solve the problems in the prior art, namely to provide a highly charged electret filter whose collection efficiency does not decrease even after long-term use.

(問題点を解決するための手段) 本発明は高分子誘電体の多孔質シートで構成され、該シ
ートが金属蒸着層を有するエレクトレットシートである
ことを特徴とする高帯電景エレクトレフトフィルターに
関するものである。
(Means for Solving the Problems) The present invention relates to a highly charged electreft filter comprising a porous sheet of polymeric dielectric material, the sheet being an electret sheet having a metal vapor deposited layer. It is.

本発明において、高分子誘電体の多孔質シートに金属蒸
着膜を施して後、エレクトレノト化すると極めて高い帯
電量のエレクトレットフィルターが得られ、加えてこの
高帯電量エレクトレットフィルターは金属蒸着膜によっ
て、その帯電量が長間にわたって安定であるとδう特徴
を有する。
In the present invention, an electret filter with an extremely high charge amount can be obtained by applying a metal vapor deposited film to a porous polymer dielectric sheet and then converting it into an electret filter. It has the characteristic that the amount of charge is stable over a long period of time.

本発明において、金属薄着層を施して後、荷電し晶帯T
Llとなる理由は明確ではないが、未蒸着のエレクトレ
ットフィルターと比較すると、表面電位分布がエレクト
レットフィルター全面にわたって非常に均一となること
から、金属蒸着膜による電荷注入の均一化が帯電量向上
と関係があると推測される。
In the present invention, after applying a thin metal layer, a charged crystal band T
The reason for Ll is not clear, but compared to an undeposited electret filter, the surface potential distribution is very uniform over the entire surface of the electret filter, so it seems that the uniformity of charge injection by the metal deposited film is related to the increase in the amount of charge. It is assumed that there is.

本発明において、高分子誘電体にはポリプロピレン、ポ
リエチレン、ポリ−3−メチル−1−ブテン、ポリ−4
−メチル−1−ペンテン、ポリ弗化ビニリデン、ポリテ
トラフロロエチレンポリカーボネーI・、ポリスチレン
、ポリ塩化ビニリデン、ポリ塩化ビニル、ポリエチレン
テレフタレート、ポリアミド、ポリアクリロニルトリル
、ポリサルホン、ポリフェニレンオキサイド等があげら
れるが、好ましくはポリプロピレン、ポリ−3−メチル
−1−ブテン、ポリ−4−メチル−1−ペンテン、ポリ
弗化ビニリデン、ポリカーボネートなどである。
In the present invention, polymer dielectrics include polypropylene, polyethylene, poly-3-methyl-1-butene, poly-4
-Methyl-1-pentene, polyvinylidene fluoride, polytetrafluoroethylene polycarbonate I, polystyrene, polyvinylidene chloride, polyvinyl chloride, polyethylene terephthalate, polyamide, polyacrylonyl tolyl, polysulfone, polyphenylene oxide, etc. , preferably polypropylene, poly-3-methyl-1-butene, poly-4-methyl-1-pentene, polyvinylidene fluoride, polycarbonate, and the like.

本発明において、多孔質シートには不織布、織物、編物
などの繊維シート、多孔質フィルム、多孔質フオームな
どが挙げられる 本発明において、金属蒸着層は通常、真空下で舊気状態
の金属を多孔質材シートの表面に付着させることで形成
される。その厚さは500オングストローム以下、好ま
しくは200オングストローム以下より好ましくは10
0オングストローム以下がよい。これらの金属蒸着層の
厚さはコンダクトメータ(日立製作所CDM−3>によ
り、その電気抵抗を測定して求められる。
In the present invention, porous sheets include fiber sheets such as nonwoven fabrics, woven fabrics, and knitted fabrics, porous films, porous foams, etc. In the present invention, the metal vapor-deposited layer is usually formed by forming a porous metal layer under vacuum. It is formed by adhering it to the surface of a material sheet. Its thickness is less than 500 angstroms, preferably less than 200 angstroms, more preferably 10
The thickness is preferably 0 angstrom or less. The thickness of these metal vapor deposited layers is determined by measuring their electrical resistance using a conductometer (Hitachi CDM-3).

本発明において、金属蒸着層は連結した膜状であるが、
不連続の層であってもさしつかえない。
In the present invention, the metal vapor deposited layer is in the form of a connected film, but
There is no problem even if the layer is discontinuous.

金属蒸着層が薄くなると膜状となり得す、独立した微粒
子状となるが、こうした場合にも膜状の場合と同様の効
果がある。
When the metal vapor deposition layer becomes thinner, it may become film-like or independent fine particles, but in such cases, the same effect as in the film-like case can be obtained.

本発明において、多孔質シート中での金属蒸着層は、多
孔質シートの表面、表裏両面又は内部に形成される。
In the present invention, the metal vapor deposition layer in the porous sheet is formed on the surface of the porous sheet, on both the front and back surfaces, or inside the porous sheet.

本発明において、金属蒸着層はアルミニウム、銀、錫、
銅などが挙げられる。中でも銀、銅は抗菌機能を付与し
たエレクトレットフィルターとして使用できる。
In the present invention, the metal vapor deposition layer includes aluminum, silver, tin,
Examples include copper. Among them, silver and copper can be used as electret filters with antibacterial functions.

本発明において高帯電量エレクトレフトフィルターにす
る荷電方法としてはコロナ荷電、電界荷電、熱間電界荷
電、電子線照射などがあるが、特にこれらに限定するも
のではない、コロナ放電、電界荷電の場合は10kv/
cm以上、好ましくは15kv/1以上の電界強度が適
しており、電子線照射の場合は0.1〜l Mradの
照射が望ましい。
In the present invention, charging methods for producing a high charge amount electric left filter include corona charging, electric field charging, hot electric field charging, electron beam irradiation, etc., but are not particularly limited to these. is 10kv/
An electric field strength of 1 cm or more, preferably 15 kv/1 or more is suitable, and in the case of electron beam irradiation, an irradiation of 0.1 to 1 Mrad is desirable.

本発明において高帯電量エレクトレフトフィルターは(
11式により求められる単繊維捕集効率比η/η。が1
.5以上を有する。
In the present invention, the high charge amount electric left filter is (
Single fiber collection efficiency ratio η/η determined by Equation 11. is 1
.. It has 5 or more.

η。:従来法で作製されるエレクトレットフィルターの
単繊維捕集効率 η :本発明の高帯電量エレクトレットフィルターの単
繊維捕集効率 Eo :従来法で作製されるエレクトレットフィルター
の実測される粒子捕集効率 E :本発明の高帯電量エレクトレットフィルターの実
測される粒子捕集効率 ここにおいて、従来法で作製されるエレクi−レフトフ
ィルターとは本発明における金属蒸着層を有していない
多孔質シートを本発明におけると同じ荷電方法でエレク
トレットフィルターとすることを意味する。
η. : Single fiber collection efficiency η of the electret filter produced by the conventional method : Single fiber collection efficiency Eo of the high charge amount electret filter of the present invention : Actual measured particle collection efficiency E of the electret filter produced by the conventional method :Actually measured particle collection efficiency of the high charge amount electret filter of the present invention.Here, the Electret filter produced by the conventional method refers to the porous sheet that does not have a metal deposited layer in the present invention. This means that the electret filter is made using the same charging method as in .

粒子捕集効率の測定は直径0.3μmのNaCI!、粒
子を線速5cm/seeで試験用フィルターに供給した
ときのフィルターの上流側と下流側とのNaC1粒子濃
度をレーザーパーティクルカウンター(リオンKA −
14”)で計測しく2)式から求めた値である。
The particle collection efficiency was measured using NaCI! with a diameter of 0.3 μm. When particles were supplied to the test filter at a linear velocity of 5 cm/see, the NaCl particle concentration on the upstream and downstream sides of the filter was measured using a laser particle counter (Rion KA-
14") and is the value obtained from equation 2).

ただし、 CI =試験用フィルターの上流側における0、3μ−
直径のNaC1−粒子濃度 C2:試験用フィルターの下流側における0、3μm直
径のNaC1粒子濃度 この1.5倍の単繊維捕集効率の増大は機械的な捕集効
率の寄与は小さく、そのほとんどが静電気的な捕集効率
の増大なのであり、つまり帯電量が従来法のエレクトレ
ットフィルターに比べ大幅に(約1.5倍に)増えたこ
とを示している。
However, CI = 0,3 μ- on the upstream side of the test filter
NaC1-particle concentration C2: concentration of NaC1 particles with a diameter of 0.3 μm on the downstream side of the test filter This 1.5-fold increase in single fiber collection efficiency has a small contribution from mechanical collection efficiency, and most of it This is an increase in electrostatic collection efficiency, which means that the amount of charge has increased significantly (about 1.5 times) compared to the conventional electret filter.

本発明によるエレクトレットフィルターの荷電量(粒子
捕集効率から求めた値)は0.8nc/c+a以上、好
ましくは1.0nc/c−以上である。(従来法では0
.3〜0.6nc/cdで0.6nc/c−以上の荷電
は付与できなかった)。
The amount of charge (value determined from particle collection efficiency) of the electret filter according to the present invention is 0.8 nc/c+a or more, preferably 1.0 nc/c- or more. (In the conventional method, 0
.. 3 to 0.6 nc/cd, it was not possible to impart a charge of 0.6 nc/c- or more).

次の実施例で更に具体的に示す。This will be shown in more detail in the following example.

(実施例) 実施例1 繊維径1.5μ−のポリプロピレンメルトブロー不織布
シート(繊維130g/r4)に銀を厚さ300オング
ストロームの金属蒸着加工を施した。
(Examples) Example 1 A polypropylene melt-blown nonwoven fabric sheet (fibers 130 g/r4) with a fiber diameter of 1.5 .mu.m was subjected to metal vapor deposition processing with silver to a thickness of 300 angstroms.

次いで、コロナ針電極を用いて半導体シートを敷いたア
ース電極面上に銀蒸着加工を施したメルトブロー不織布
シートを置き、20kv/CIlの高電圧を4秒間印加
して高帯電量エレクトレットフィルターを作製した。こ
のエレクトレットフィルターを試験線速5cm/sec
で0.3μ面のNaC1粒子の捕集効率をレーザーバー
ティクカウンター(リオンKA−14)で測定した。又
、同時に高帯電量エレクトレフトフィルターの圧力損失
をマノスターゲージにて測定した。
Next, a melt-blown nonwoven fabric sheet treated with silver vapor deposition was placed on the ground electrode surface covered with a semiconductor sheet using a corona needle electrode, and a high voltage of 20 kv/Cl was applied for 4 seconds to produce a high charge amount electret filter. . This electret filter was tested at a linear speed of 5 cm/sec.
The collection efficiency of NaCl particles with a 0.3μ surface was measured using a laser vertical counter (Rion KA-14). At the same time, the pressure loss of the high-charge electrified left filter was measured using a Manostar gauge.

比較例! 実施例1のメルトブロー不織布を銀蒸着加工を施さずに
実施例1と同じ荷電条件でエレクトレット化し、比較例
1のエレクトレットフィルターを作製し、粒子捕集効率
と圧力損失を測定した。
Comparative example! The melt-blown nonwoven fabric of Example 1 was made into an electret under the same charging conditions as in Example 1 without being subjected to silver vapor deposition to produce an electret filter of Comparative Example 1, and the particle collection efficiency and pressure loss were measured.

表−1 表1に実施例1と比較例1の結果を示した。Table-1 Table 1 shows the results of Example 1 and Comparative Example 1.

実施例1の圧力損失は比較例1と変わることなく、単繊
維捕集効率比η/η。のみが1.8と著しい増加を示し
、本発明における金属蒸着層の効果が明らかであった。
The pressure loss of Example 1 was the same as that of Comparative Example 1, and the single fiber collection efficiency ratio η/η. only showed a remarkable increase of 1.8, and the effect of the metal vapor deposited layer in the present invention was clear.

実施例2 実施例1のメルトブロー不織布シートにアルミニウムを
厚さ50オングストロームの金属蒸着加工を施した。
Example 2 The melt-blown nonwoven fabric sheet of Example 1 was subjected to metal vapor deposition processing of aluminum to a thickness of 50 angstroms.

次いで、コロナ針電極を用いて半導体シートを敷いたア
ース電極面上にアルミニウム蒸着加工を施したメルトブ
ロー不織布シートを置き、20kv /1の高電圧を4
秒間印加して高帯電量エレクトレットフィルターを作製
した。
Next, using a corona needle electrode, a melt-blown nonwoven fabric sheet treated with aluminum vapor deposition was placed on the ground electrode surface covered with a semiconductor sheet, and a high voltage of 20 kv/1 was applied to the ground electrode surface for 4 hours.
A high charge amount electret filter was produced by applying the voltage for a second.

このエレクトレットフィルターを試験線速5C1l/s
ecで0.3μ−のNaCI!、粒子の捕集効率を効率
をレーザーバーティクカウンター(リオンKA −14
)で測定した。又、同時に高帯電量エレクトレットフィ
ルターの圧力損失をマノスターゲージにて測定した。
This electret filter was tested at a linear speed of 5C1l/s.
0.3μ-NaCI in ec! , to measure the particle collection efficiency using a laser vertical counter (Rion KA-14).
) was measured. At the same time, the pressure loss of the high charge amount electret filter was measured using a Manostar gauge.

比較例2 比較例1のエレクトレットメルトブロー不織布シートに
アルミニウムを50オングストロームの金属蒸着加工を
施した。
Comparative Example 2 The electret melt-blown nonwoven fabric sheet of Comparative Example 1 was subjected to metal vapor deposition processing of 50 angstroms of aluminum.

次いでこのエレクトレットフィルターを実施例2と同じ
試験条件で捕集効率と圧力損失を測定した。
Next, the collection efficiency and pressure loss of this electret filter were measured under the same test conditions as in Example 2.

実施例2と比較例2の結果を表2に示した。比較例2は
金属蒸着加工を荷電処理後に施しても、何んら帯電量の
向上には効果がないことを示している。
The results of Example 2 and Comparative Example 2 are shown in Table 2. Comparative Example 2 shows that even if the metal vapor deposition process is performed after the charging process, there is no effect on improving the amount of charging.

実施例2はアルミニウムの金属蒸着層厚さが薄いと、荷
電処理による帯電量の増大が極めて著しかった。
In Example 2, when the thickness of the aluminum metal vapor deposited layer was thin, the amount of charge increased significantly due to the charging treatment.

実施例3 繊維径4μ曙のポリプロピレンスパンボンド(繊維f1
40g/n()に銅を100オングストロームの厚さで
金属蒸着加工を施した。
Example 3 Polypropylene spunbond with a fiber diameter of 4 μm (fiber f1
40 g/n() was subjected to metal vapor deposition processing with copper to a thickness of 100 angstroms.

次いで、実施例1と同様の荷電条件で高帯電量エレクト
レットフィルターを作成した。このエレクトレットフィ
ルターを実施例2と同様、捕集効率と圧力…失を測定し
た。結果を表3に示す。
Next, a high charge amount electret filter was created under the same charging conditions as in Example 1. The collection efficiency and pressure loss of this electret filter were measured in the same manner as in Example 2. The results are shown in Table 3.

比較例4 実施例3のスパンボンドを金属蒸着加工を施すことなく
、実施例1と同様の荷電条件でエレクトレットフィルタ
ーを作成し、次いで、実施例1と同じ試験条件で捕集効
率と圧力[員失を測定した。
Comparative Example 4 An electret filter was created using the spunbond material of Example 3 under the same charging conditions as in Example 1 without undergoing metal vapor deposition processing. The loss was measured.

結果を表3に示す。The results are shown in Table 3.

表−3 次に、実施例2と比較例1.2の表面電位を川口電機製
S−211型の表面電位計で測定した。この結果を表4
に示した。この結果から明らかなごとく、金属蒸着加工
を施して後、荷電処理して作製した高帯電量エレクトレ
ットフィルターは外界に対し、非常に高い表面電位を示
した。
Table 3 Next, the surface potentials of Example 2 and Comparative Example 1.2 were measured using a Kawaguchi Electric S-211 surface potential meter. This result is shown in Table 4.
It was shown to. As is clear from these results, the highly charged electret filter produced by performing metal vapor deposition and then charging showed a very high surface potential with respect to the outside world.

表−4 実施例2と比較例1との単繊維捕集効率の耐久性を第1
図に示した。この図から明らかなごとく、実施例1は比
較例1に比べて、初期においても、経時後においても高
いレベルを保持している。
Table 4 The durability of single fiber collection efficiency of Example 2 and Comparative Example 1 was
Shown in the figure. As is clear from this figure, Example 1 maintains a higher level than Comparative Example 1 both at the initial stage and after time.

(発明の効果) 本発明によると粒子捕集効率が向上し、長期にわたって
粒子捕集効率の安定なエレクトレフトフィルターを提供
することができる。
(Effects of the Invention) According to the present invention, it is possible to provide an electric left filter with improved particle collection efficiency and stable particle collection efficiency over a long period of time.

【図面の簡単な説明】 第1図は本発明で得られたエレクトレットフィルターと
従来からのエレクトレフトフィルターにおける単繊維捕
集効率の経時変化を示している。 昂1 図 期間(斗)
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 shows changes over time in the single fiber collection efficiency of the electret filter obtained by the present invention and the conventional electret filter. Kou 1 figure period (Dou)

Claims (1)

【特許請求の範囲】[Claims]  高分子誘電体の多孔質シートで構成され、該シートが
金属蒸着層を有したエレクトレットシートであることを
特徴とする高帯電量エレクトレットフイルター
A high charge amount electret filter comprising a porous sheet of polymeric dielectric material, the sheet being an electret sheet having a metal vapor deposited layer.
JP63085985A 1987-11-28 1988-04-06 Electret filter Expired - Lifetime JP2536584B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP63085985A JP2536584B2 (en) 1988-04-06 1988-04-06 Electret filter
DE3839956A DE3839956C2 (en) 1987-11-28 1988-11-26 Electret film and process for its production
US07/276,617 US5112677A (en) 1987-11-28 1988-11-28 Electret sheet and a method for the production of the same
US07/770,564 US5110620A (en) 1987-11-28 1991-10-03 Method for the production of an electret sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63085985A JP2536584B2 (en) 1988-04-06 1988-04-06 Electret filter

Publications (2)

Publication Number Publication Date
JPH01258714A true JPH01258714A (en) 1989-10-16
JP2536584B2 JP2536584B2 (en) 1996-09-18

Family

ID=13873983

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63085985A Expired - Lifetime JP2536584B2 (en) 1987-11-28 1988-04-06 Electret filter

Country Status (1)

Country Link
JP (1) JP2536584B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007105645A (en) * 2005-10-14 2007-04-26 Hitachi Appliances Inc Pre-filter for air conditioner, and air conditioner using it
WO2013026193A1 (en) * 2011-08-23 2013-02-28 Empire Technology Development Llc Self-cleaning electret filter
US8809766B2 (en) 2010-06-29 2014-08-19 Empire Technology Development Llc Methods and systems for detecting or collecting particles

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10010892B2 (en) * 2013-10-15 2018-07-03 Yupo Corporation Filter

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007105645A (en) * 2005-10-14 2007-04-26 Hitachi Appliances Inc Pre-filter for air conditioner, and air conditioner using it
JP4636990B2 (en) * 2005-10-14 2011-02-23 日立アプライアンス株式会社 Pre-filter for air conditioner and air conditioner using the same
US8809766B2 (en) 2010-06-29 2014-08-19 Empire Technology Development Llc Methods and systems for detecting or collecting particles
WO2013026193A1 (en) * 2011-08-23 2013-02-28 Empire Technology Development Llc Self-cleaning electret filter
US8597405B2 (en) 2011-08-23 2013-12-03 Empire Technology Development Llc Self-cleaning electret filter
CN103702762A (en) * 2011-08-23 2014-04-02 英派尔科技开发有限公司 Self-cleaning electret filter

Also Published As

Publication number Publication date
JP2536584B2 (en) 1996-09-18

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