JPH01229083A - Heat-resistant coating composition - Google Patents
Heat-resistant coating compositionInfo
- Publication number
- JPH01229083A JPH01229083A JP5492888A JP5492888A JPH01229083A JP H01229083 A JPH01229083 A JP H01229083A JP 5492888 A JP5492888 A JP 5492888A JP 5492888 A JP5492888 A JP 5492888A JP H01229083 A JPH01229083 A JP H01229083A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- component
- weight
- parts
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008199 coating composition Substances 0.000 title claims description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 15
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 15
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 14
- 239000011707 mineral Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 11
- 229920002050 silicone resin Polymers 0.000 claims abstract description 8
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 239000011591 potassium Substances 0.000 claims abstract description 6
- 239000000945 filler Substances 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 239000011575 calcium Substances 0.000 abstract description 3
- 229910052604 silicate mineral Inorganic materials 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 16
- 125000004429 atom Chemical group 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000017525 heat dissipation Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052615 phyllosilicate Inorganic materials 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は耐熱性被覆組成物に関するもので、特に珪素樹
脂、弗素樹脂及びエポキシ樹脂のオリゴマーからなる三
成分共重合系混合物にカルシウム含量が少なくカリウム
含量の高い天然鉱物微粉末を添加したことを特徴とする
耐熱性の著しく優れた新規の被覆組成物に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a heat-resistant coating composition, in particular a three-component copolymer mixture comprising oligomers of silicone resin, fluororesin and epoxy resin, which has a low calcium content and a high potassium content. The present invention relates to a novel coating composition with extremely excellent heat resistance, which is characterized by the addition of fine natural mineral powder with high heat resistance.
従来技術
一般に耐熱、耐蝕被覆物の材料としてはエポキシ樹脂が
広く知られているが、その耐熱性は充分ではなく、また
シリコン系塗料や弗素系塗料の最近の進歩も著しいもの
があるが、これらの塗料が同れも夫々特有の問題点を有
し、耐熱温度、耐蝕性、接着性等の性能面でも充分満足
すべきものが得られていないことは周知の通りである。PRIOR ART Although epoxy resins are widely known as materials for heat-resistant and corrosion-resistant coatings, their heat resistance is not sufficient, and recent advances in silicone-based paints and fluorine-based paints have also been remarkable. It is well known that all paints have their own problems, and that they are not fully satisfactory in terms of performance such as heat resistance, corrosion resistance, and adhesion.
発明が解決しようとする問題点
従って本発明は従来の耐熱塗料の各種の問題点を研究し
た結果、エポキシ、シリコン、弗素の三成分系く上２段
に放熱剤を添加した新規の塗料を提供することを目的と
するものである。Problems to be Solved by the Invention Therefore, as a result of research into various problems of conventional heat-resistant paints, the present invention provides a new paint that has a three-component system of epoxy, silicone, and fluorine, and has a heat dissipating agent added to the top two layers. The purpose is to
本発明者は研究の結果、エポキシ樹脂、ウレタン樹脂等
の従来からの耐熱塗料オリゴマー成分がシリコン樹脂成
分及び弗素樹脂成分と均質に混合、共重合し得ることを
知り、エポキシ樹脂成分にシリコン樹脂成分と弗素樹脂
成分を組み合わせ、さらにこれに熱放散性充填剤を添加
することによってこれまでの耐熱塗料よりも著しく優れ
た耐熱性を有する新規の放熱型塗料を開発することに成
功した。As a result of research, the present inventor found that conventional heat-resistant paint oligomer components such as epoxy resins and urethane resins can be homogeneously mixed and copolymerized with silicone resin components and fluororesin components. By combining this with a fluororesin component and adding a heat-dissipating filler to this, we succeeded in developing a new heat-dissipating paint that has significantly better heat resistance than conventional heat-resistant paints.
すなわち、本発明は珪素樹脂系オリゴマー、弗素樹脂系
オリゴマー及びエポキシ樹脂系オリゴマーを混合して均
質の三成分果共重合物をつくり、これにカリウム含有１
の高い天然鉱物微粉末を充填剤として添加することによ
ってその熱放散性を高め、耐熱性の著しい向上に成功し
たものである。本発明ではエポキシ樹脂は常温硬化型接
着媒質として使用されるものであり、また珪素樹脂成分
は耐熱性向上、弗素樹脂成分は撥水、撥油等の防汚性の
向上のために使用されるものである。エポキシ樹脂とし
ては従来から一般使用されているビスフェノールＡ型エ
ポキシ樹脂でもよいが、ノボラック型のエポキシ樹脂が
本発明の目的にはより好適でるり、２２２７２４０〜６
０％含有のノゲシ、り系エポキシ樹脂が％て有効である
。本発明ではさらにこれらの三成分某共重合ベヒクルに
特殊の金属酸化物混合体である天然鉱物微粉末を添９０
することによってその熱放散性の著しい向上に成功した
ものである。この天然鉱物としてはカルシウム含有量の
少ないもので、しかもカリウム含有量の高いものであれ
ばよく、一般に韓国産の層状珪酸塩鉱物が本発明の目的
のために好適に使用され得ることが知られている。That is, in the present invention, a homogeneous three-component fruit copolymer is prepared by mixing a silicone resin oligomer, a fluororesin oligomer, and an epoxy resin oligomer, and a potassium-containing 1
By adding fine natural mineral powder with a high viscosity as a filler, we have succeeded in increasing its heat dissipation properties and significantly improving its heat resistance. In the present invention, the epoxy resin is used as a room temperature curing adhesive medium, the silicone resin component is used to improve heat resistance, and the fluororesin component is used to improve stain resistance such as water repellency and oil repellency. It is something. As the epoxy resin, bisphenol A type epoxy resins that have been commonly used may be used, but novolak type epoxy resins are more suitable for the purpose of the present invention.
A 0%-containing epoxy resin is effective. In the present invention, natural mineral fine powder, which is a special metal oxide mixture, is further added to these three-component copolymer vehicles.
By doing so, we succeeded in significantly improving its heat dissipation properties. This natural mineral may be one with a low calcium content and a high potassium content, and it is generally known that phyllosilicate minerals produced in Korea can be suitably used for the purpose of the present invention. ing.
実施例
以下に本発明の実施例を示す。これらの実施例において
は成分比率は重量比であり、また天然鉱物微粉末として
は韓国産層状珪酸塩鉱物が使用され、その元素組成はｄ
＋ Ｓ＋ ＋ Ｏ、Ｎａ ＋Ｋ 、 Ｍｇ等を主成分と
するもので、Ｋ原子２個。Examples Examples of the present invention are shown below. In these examples, the component ratios are weight ratios, and the natural mineral fine powder used is Korean phyllosilicate mineral, whose elemental composition is d.
+ S+ + O, Na + K, Mg, etc. are the main components, and there are 2 K atoms.
０原子６個、 Ｓｉ原子３個とＭ原子１個、０原子４個
とＦ原子２個、 Ｍｇ原子６個、０原子４個とＦ原子２
個、 Ｓｉ原子３個と屁原子１個及びＯ原子６個から８
層構造の多層構造単位体が連続するものであった。6 0 atoms, 3 Si atoms and 1 M atom, 4 0 atoms and 2 F atoms, 6 Mg atoms, 4 0 atoms and 2 F atoms
3 Si atoms, 1 fart atom, and 6 to 8 O atoms
The multilayer structural units of the layered structure were continuous.
実施例１゜
変性用シリコン樹脂（信越シリコン、ＫＣ−２２４）１
５重量部
ノポラ、り型エポキシ樹脂（東部化１１ｉ３ｊ、 ＹＤ
−６６２）３０重量部
溶剤（トルエン） ２５重量部弗
素樹脂オリゴマー（旭硝子、ＡＧ−６５０）１０重１部
鉱物實微粉末（韓国産） ２０重量部の
組αからなる塗料ベヒクル１００＊量部をシリコン変性
ポリアミン硬化剤（信越シリコン、ＫＣ−２２４）２５
重重部と混合して常温硬化させた膜厚４８０μの錫メツ
キ鋼板の試験片で従来のエポキシ塗料及びウレタン塗料
と比較した。１００Ｃに加熱された菫布鋼板の冷却速度
は第１表に示すように本発明の組成物の熱放散性の愛ル
ていることが立証でれ几。Example 1゜Modified silicone resin (Shin-Etsu Silicon, KC-224) 1
5 parts by weight Nopora, ri-type epoxy resin (Tobu Ka 11i3j, YD
-662) 30 parts by weight Solvent (Toluene) 25 parts by weight Fluororesin oligomer (Asahi Glass, AG-650) 10 parts by weight 1 part Mineral powder (produced in Korea) 20 parts by weight Paint vehicle consisting of group α 100 * parts by weight Silicon modified polyamine curing agent (Shin-Etsu Silicon, KC-224) 25
Comparisons were made with conventional epoxy paints and urethane paints using a test piece of tin-plated steel plate with a film thickness of 480 μm that was mixed with a heavy weight part and cured at room temperature. The cooling rate of the violet steel plate heated to 100C is shown in Table 1, which proves that the heat dissipation properties of the composition of the present invention depend on the cooling rate.
第 １ 表
実施例２゜
エポキシ変性シリコン樹脂（信越シリコン、Ｒ８−１０
０２Ｔ）
３５重量部
溶剤（メチルセルソルブ） １５重量部溶
剤（セルソルブアセテート） １０重量部溶
剤（ダイア七トンアルコール） １０重を部
弗素樹脂オリゴマー（旭硝子、ＡＧ−６５０）１０重退
部
鉱物質微粉末（韓国産） ２０重量部から
なる組成の塗料ベヒクル１００重量部を、シリコン変性
ポリアミン硬化剤（信越シリコン、 ＫＣ−２２４＞
２５重量部と混合して得られた塗膜はｐＡ水性１００．
撥油性１６の優れた防汚効果と共に耐熱性も以下に示す
通りの優れたものであった。Table 1 Example 2 Epoxy modified silicone resin (Shin-Etsu Silicon, R8-10
02T) 35 parts by weight Solvent (Methyl Cellsolve) 15 parts by weight Solvent (Cellsolve Acetate) 10 parts by weight Solvent (Dia Seventon Alcohol) 10 parts by weight Fluororesin oligomer (Asahi Glass, AG-650) 10 parts by weight Mineral material 100 parts by weight of a paint vehicle having a composition of 20 parts by weight of fine powder (produced in Korea) was mixed with a silicone-modified polyamine curing agent (Shin-Etsu Silicon, KC-224).
The coating film obtained by mixing with 25 parts by weight has an aqueous pA of 100.
In addition to the excellent antifouling effect of oil repellency 16, the heat resistance was also excellent as shown below.
実施例３
シリコンエポキシ樹脂（東しシリコン、５Ｒ−２１１５
）５０重量部
ノボラック型エポキシ樹脂（東都化成、ＹＤ−６６１）
１０重量部
溶剤（トルエン） １０重量部弗素樹
脂オリゴマー（旭硝子、ＡＣ−６５０）１０重量部
鉱物微粉末（韓国産） ２０重量部の
組成のベヒクルに硬化剤としてアミン変性シリコン（東
しシリコン、５Ｒ−２１１５Ｋ）１０重重部を加えて得
られた塗料をアルミ鍋に内面塗装したものと無塗装のア
ルミ鍋とで内面温度上昇時間を比較した。アルミ鍋は深
さ７０ ｍ ＋直径１２０圏の片手鍋を使用し、水６０
０ｃ、ｃ、を入れたものを水温４０Ｃからガス加熱した
。結果は以下の通りで本発明の塗料を内面塗装したもの
の方が加熱効率が優れていることが立証された。Example 3 Silicon epoxy resin (Toshi Silicon, 5R-2115
) 50 parts by weight novolac type epoxy resin (Toto Kasei, YD-661)
10 parts by weight of solvent (toluene) 10 parts by weight of fluororesin oligomer (Asahi Glass, AC-650) 10 parts by weight of fine mineral powder (produced in Korea) 20 parts by weight of vehicle with amine-modified silicone (Toshi Silicone, 5R) as a curing agent -2115K) The inner surface temperature rise time was compared between an aluminum pot whose inner surface was coated with a paint obtained by adding 10 parts of the paint and an uncoated aluminum pot. Use an aluminum pot with a depth of 70 m and a diameter of 120 m, and use 60 m of water.
The mixture containing 0c and c was heated with gas from a water temperature of 40C. The results are as follows, and it was proved that the heating efficiency of the inner surface coated with the paint of the present invention was better.
実施例４
塩化ビニル樹脂５０％、鉱物質微粉末５０％の、組成物
と塩化ビニル樹脂だけとで放熱試験用・ぐイブ（１００
Ｃｒ＋＋）を作り、試験開始温度７Ｇ、５０ｒのスチー
ム加熱で夫々に入口温度、中心温度、出口温度を測定し
た。試験結果は以下の通りとなり、不発明の組成物の放
熱効果が立証された。Example 4 A composition containing 50% vinyl chloride resin and 50% mineral fine powder and only vinyl chloride resin were used for heat radiation testing.
Cr++) was prepared, and the inlet temperature, center temperature, and outlet temperature were measured at a test starting temperature of 7G and steam heating of 50r. The test results were as follows, proving the heat dissipation effect of the inventive composition.
発明の効果
以上の実施例からも知られるように、本発明の組成物は
従来のエポキシ、ウレタン系の耐熱塗料と比較して優れ
た放熱効果を有することは明白である。Effects of the Invention As can be seen from the above examples, it is clear that the composition of the present invention has superior heat dissipation effects compared to conventional epoxy and urethane-based heat-resistant paints.
特許出願人 榊 治 義 外−名Patent applicant Osamu Sakaki outside name
Claims (1)
系成分よりなる三成分共重合系混合物にカリウム含有量
の高い天然鉱物微粉末を熱放散性充填剤として添加した
ことを特徴とする耐熱性被覆組成物。1. Heat resistance characterized by adding natural mineral fine powder with high potassium content as a heat-dissipating filler to a three-component copolymer mixture consisting of a silicone resin component, a fluororesin component, and an epoxy resin component Coating composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5492888A JPH01229083A (en) | 1988-03-10 | 1988-03-10 | Heat-resistant coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5492888A JPH01229083A (en) | 1988-03-10 | 1988-03-10 | Heat-resistant coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01229083A true JPH01229083A (en) | 1989-09-12 |
Family
ID=12984282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5492888A Pending JPH01229083A (en) | 1988-03-10 | 1988-03-10 | Heat-resistant coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01229083A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255237A (en) * | 2015-10-22 | 2016-01-20 | 重庆广播电视大学 | Building insulating material for inner wall |
-
1988
- 1988-03-10 JP JP5492888A patent/JPH01229083A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255237A (en) * | 2015-10-22 | 2016-01-20 | 重庆广播电视大学 | Building insulating material for inner wall |
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