JPH01225785A - Tarnish inhibitor for steel sheet added to washing water - Google Patents
Tarnish inhibitor for steel sheet added to washing waterInfo
- Publication number
- JPH01225785A JPH01225785A JP5294888A JP5294888A JPH01225785A JP H01225785 A JPH01225785 A JP H01225785A JP 5294888 A JP5294888 A JP 5294888A JP 5294888 A JP5294888 A JP 5294888A JP H01225785 A JPH01225785 A JP H01225785A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning
- cyclohexylamine
- acid
- tarnish
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 23
- 239000010959 steel Substances 0.000 title claims abstract description 23
- 239000003112 inhibitor Substances 0.000 title claims abstract description 14
- 238000005406 washing Methods 0.000 title abstract description 3
- 238000004140 cleaning Methods 0.000 claims abstract description 43
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000002253 acid Substances 0.000 claims abstract description 22
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract 3
- 238000002845 discoloration Methods 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000003449 preventive effect Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 11
- 150000001412 amines Chemical class 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000004649 discoloration prevention Methods 0.000 description 5
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- KWMLJOLKUYYJFJ-UHFFFAOYSA-N 2,3,4,5,6,7-Hexahydroxyheptanoic acid Chemical compound OCC(O)C(O)C(O)C(O)C(O)C(O)=O KWMLJOLKUYYJFJ-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000005973 Carvone Substances 0.000 description 2
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 2
- 238000005097 cold rolling Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は薬剤洗浄や電解洗浄により表面が活性化され
た鋼板の変色を防止するために、洗浄水に添加するため
の洗浄水用鋼板変色防止剤に関するものである。[Detailed Description of the Invention] [Field of Industrial Application] This invention is a method for discoloring steel sheets for use in cleaning water that is added to cleaning water in order to prevent discoloration of steel sheets whose surfaces have been activated by chemical cleaning or electrolytic cleaning. It relates to inhibitors.
鋼板の種類は多岐にわたり、熱間圧延、冷間圧延、焼鈍
、めっき、塗装などの各工程で製品として出荷される。There are many different types of steel sheets, and they are shipped as products after undergoing various processes such as hot rolling, cold rolling, annealing, plating, and painting.
各々の工程では、鋼板表面を清浄にする目的で、酸洗浄
、アルカリ洗浄等の薬剤洗浄や電解洗浄などが施される
。これらの洗浄後は、表面に付着している不純物を除去
するために、工業用水や純水などにより洗浄（リンス）
される。In each process, chemical cleaning such as acid cleaning, alkaline cleaning, electrolytic cleaning, etc. are performed for the purpose of cleaning the steel plate surface. After cleaning, rinse with industrial water or pure water to remove impurities adhering to the surface.
be done.
上記洗浄で清浄になった鋼板は、表面が活性化されてい
るため、腐食が起りやすくなっており、製品が発錆によ
り変色を生ずる。発錆、変色した鋼板は製品価値が低下
するのみならず、後工程に対する悪影響、例えばめっき
不良などを引き起す。Since the surface of the steel plate that has been cleaned by the above cleaning is activated, corrosion is more likely to occur, and the product becomes discolored due to rusting. Rusted or discolored steel sheets not only reduce product value, but also cause adverse effects on subsequent processes, such as poor plating.
発錆、変色した鋼板は、不良部の切断による製品歩留り
の低下（不良率数％に達する場合がある）や、洗浄のや
り直しによる工程増加により多大な損失を招く。不良品
が発生するのは、主として低速運転時やライン停止時で
ある。これらの対策としては、ルーパーを利用した酸洗
、冷間圧延の連続化や、ＣＡＬ、 Ｃ入円４と呼ばれる
連続焼鈍設備が実用化されており、上記障害は軽減され
ている。Rusted or discolored steel sheets cause a reduction in product yield due to cutting of defective parts (the defective rate may reach several percent) and increase in process costs due to re-cleaning, resulting in large losses. Defective products mainly occur during low-speed operation or when the line is stopped. As countermeasures against these problems, the above-mentioned problems have been alleviated by making continuous pickling and cold rolling using a looper, and continuous annealing equipment called CAL and C-containing circle 4.
しかしながら、全ての場合に設備的に対応できる訳では
なく、例えば高級鋼のＩ２造には、非連続式の電解洗浄
が行われている。この場合は次のコイルを洗浄するのに
溶接が必要になり、通常３〜５分ラインが停止する６ま
た溶接不良などにより低速運転が余儀なくされる場合が
あり、不良品が発生しているのが現状である。However, the equipment cannot handle all cases; for example, discontinuous electrolytic cleaning is performed on I2 structures made of high-grade steel. In this case, welding is required to clean the next coil, and the line usually stops for 3 to 5 minutes6.Also, low-speed operation may be forced due to poor welding, which may result in defective products. is the current situation.
この発明の目的は、上記問題点を解決するため、薬剤洗
浄や電解洗浄により表面が活性化された鋼板の変色を防
止し、製品品質および製品歩留りの向」二が可能な洗浄
水用鋼板変色防止剤を提供することである。The purpose of this invention is to solve the above-mentioned problems by preventing discoloration of steel plates whose surfaces have been activated by chemical cleaning or electrolytic cleaning, and to improve product quality and product yield. The objective is to provide an inhibitor.
本発明は、次の洗浄水用鋼板変色防止剤である。 The present invention is the following steel sheet discoloration inhibitor for washing water.
（１）シクロヘキシルアミンから成る洗浄水用鋼板変色
防止剤。゛
（２）シクロヘキシルアミンと、炭素数６〜１４のカル
ボン酸、オキシカルボン酸またはこれらの水溶性塩から
成る洗浄水用鋼板変色防止剤。(1) Steel sheet discoloration inhibitor for cleaning water consisting of cyclohexylamine. (2) A steel sheet discoloration inhibitor for cleaning water comprising cyclohexylamine and a carboxylic acid having 6 to 14 carbon atoms, an oxycarboxylic acid, or a water-soluble salt thereof.
本発明の洗浄水用鋼板変色防止剤は、シクロヘキシルア
ミン単独であっても極めて優れた変色防止効果を示すが
、シクロヘキシルアミンとカルボン酸、オキシカルボン
酸またはこれらの水溶性塩との併用により、さらに亮い
効果が得られる。The steel plate discoloration inhibitor for cleaning water of the present invention shows an extremely excellent discoloration prevention effect even when cyclohexylamine is used alone, but when cyclohexylamine is used in combination with a carboxylic acid, oxycarboxylic acid, or a water-soluble salt thereof, it has an even more effective discoloration prevention effect. A bright effect can be obtained.
カルボンｊｆｌｌ、オキシカルボン酸としては炭素数６
〜１４のものであって、１価でも多価でもよい。Carvone jflll, 6 carbon atoms as oxycarboxylic acid
~14, and may be monovalent or polyvalent.
例えば１価カルボン酸としてはヘキサン酸、ヘプトン酸
、ドデカン酸（ラウリル酸）など、２価カルボン酸とし
てはヘキサンニ酸、ヘプトンニ酸、オクタンニ酸、デカ
ンニ酸、ドデカンニ酸など、オキシカルボン酸としては
グルコン酸、クエン酸など力く例示できる。なお、これ
らは水溶性塩でもよい。For example, monovalent carboxylic acids include hexanoic acid, heptonic acid, and dodecanoic acid (lauric acid); divalent carboxylic acids include hexanoic acid, heptonic acid, octanniic acid, decanniic acid, and dodecanniic acid; and oxycarboxylic acids include gluconic acid. , citric acid are examples. Note that these may be water-soluble salts.
本発明の洗浄水用鋼板変色防止剤がシクロヘキシルアミ
ンとカルボン１俊、オキシカルボン酸またはそれらの水
溶性塩とを含む場合、その配合割合は処理対象等に応じ
て適宜決定されるが、一般にはシクロヘキシルアミンに
対してカルボン酸、オキシカルボン酸またはそれらの水
溶性塩を０．０１〜１０重量％配合するのが好ましい。When the steel sheet discoloration inhibitor for cleaning water of the present invention contains cyclohexylamine and carboxylic acid, oxycarboxylic acid, or a water-soluble salt thereof, the blending ratio is determined as appropriate depending on the object to be treated, etc., but in general, It is preferable to mix 0.01 to 10% by weight of carboxylic acid, oxycarboxylic acid, or a water-soluble salt thereof based on cyclohexylamine.
カルボン１浚、オキシカルボン酸またはそれらの塩は、
高濃度添加すればそれら単独でも鋼板の変色防止効果を
示すが、シクロヘキシルアミンとの併用により、カルボ
ン酸、オキシカルボン酸またはその塩の濃度は極く低濃
度でも効果を示す。これらのカルボン酸、オキシカルボ
ン酸またはその塩は高濃度添加により、後工程の焼鈍時
にカーボン汚れが発生し、化成処理不良やめっき不良を
引き起すため、極力低濃度にする必要があるが、シクロ
ヘキシルアミンとの併用によりそのような問題は解決さ
れる。Carvone 1, oxycarboxylic acid or their salts are
When added at a high concentration, they alone exhibit the effect of preventing discoloration of steel sheets, but when used in combination with cyclohexylamine, the effect is exhibited even at extremely low concentrations of carboxylic acid, oxycarboxylic acid, or their salts. When these carboxylic acids, oxycarboxylic acids, or their salts are added in high concentrations, carbon stains occur during annealing in the subsequent process, causing defects in chemical conversion treatment and plating, so it is necessary to keep the concentration as low as possible, but cyclohexyl Combination use with amines solves such problems.
本発明の洗浄水用鋼板変色防止剤は、シクロヘキシルア
ミンとカルボン酸、オキシカルボン酸またはそれらの塩
とを併用する場合、両者が予め混合されたものであって
もよく、それぞれ別個に洗浄水に添加して配合されるも
のであってもよい。When using the steel sheet discoloration inhibitor for cleaning water of the present invention in combination with cyclohexylamine and carboxylic acid, oxycarboxylic acid, or their salts, the two may be mixed in advance, or they may be added to the cleaning water separately. It may be added and blended.
本発明の洗浄水用鋼板変色防止剤は、シクロヘキシルア
ミン、カルボン酸、オキシカルボン酸またはそれらの水
溶性塩の他に、他の改質剤等の添加剤を含むものであっ
てもよい。The steel plate discoloration inhibitor for cleaning water of the present invention may contain additives such as other modifiers in addition to cyclohexylamine, carboxylic acid, oxycarboxylic acid, or water-soluble salts thereof.
本発明の洗浄水用鋼板変色防止剤は、酸洗浄、アルカリ
洗浄等の薬剤洗浄または電解洗浄後の各リンス工程の洗
浄水に利用することができる。具体的な使用方法として
は、例えば５０〜８０℃の洗浄水に対して、通常２００
〜３００ｍｇ／ＱＴＡ加するのが有効である。The steel sheet discoloration prevention agent for cleaning water of the present invention can be used in cleaning water for each rinsing process after chemical cleaning such as acid cleaning or alkaline cleaning or electrolytic cleaning. As a specific method of use, for example, 200
It is effective to add ~300mg/QTA.
低速運転時やライン停止時に、鋼板が発錆、変色を起す
場所は、一般に薬剤または電解洗浄後の散水部、洗浄水
槽内、洗浄水槽出口以降乾燥前までの間である。従って
このような場所で発生する発錆、変色を防止するために
は変色防止剤を洗浄水に添加する方法が有効であり、こ
の洗浄水をさらに薬剤または電解洗浄後の散水に使用す
るのが効果的である。また次善の方法としては、薬剤ま
たは電解洗浄後の散水部に変色防＋１剤を塗布または吹
きつける方法がある。例えば変色防止剤を含む洗浄水を
ポンプアップして噴霧する。または変色防１Ｆ剤を直接
噴霧するなどの方法が採用可能である。During low-speed operation or when the line is stopped, the locations where steel plates rust or discolor are generally the water sprinkling area after chemical or electrolytic cleaning, inside the cleaning tank, and from the outlet of the cleaning tank until drying. Therefore, in order to prevent rusting and discoloration that occur in such places, it is effective to add an anti-discoloration agent to the cleaning water, and it is also recommended to use this cleaning water for spraying chemicals or water after electrolytic cleaning. Effective. The next best method is to apply or spray an anti-discoloration +1 agent to the water spraying area after chemical or electrolytic cleaning. For example, cleaning water containing an anti-tarnishing agent is pumped up and sprayed. Alternatively, a method such as directly spraying the discoloration preventive agent 1F can be adopted.
電解洗浄後の冷延鋼板を切断したもの（ＳＰＣＣ−５Ｒ
。Cut cold rolled steel plate after electrolytic cleaning (SPCC-5R
.
６００ Ｘ １００ Ｘ ８ ｍｒｎ厚さ）を試験片と
した。この試験片をトルエンによる超音波脱脂３０分後
汚れをふきとり、さらに水洗後メタノールに浸漬し、ド
ライヤーで冷風乾燥して、試験片にカッターでクロスカ
ットを入れた。一方、８０℃に加温した厚木市水に所定
の薬剤を添加した後、上記試験片を５分間浸漬した。試
験片を取出してメタノールに浸漬し、ドライヤーで冷風
乾燥した。600 x 100 x 8 mrn thickness) was used as a test piece. After ultrasonic degreasing using toluene for 30 minutes, this test piece was wiped clean, washed with water, immersed in methanol, dried with cold air using a dryer, and cross-cutted with a cutter. On the other hand, after adding a predetermined chemical to Atsugi city water heated to 80°C, the test piece was immersed for 5 minutes. The test piece was taken out, immersed in methanol, and dried with cold air using a dryer.
処理後の試験片を目視ｖｆｌ察し、発錆、変色の発生状
況を下記基準で評価した。The test pieces after treatment were visually inspected by VFL, and the occurrence of rust and discoloration was evaluated according to the following criteria.
◎・・・非常に優れる（発錆、変色は全くない。）○・
・優れる（発錆、変色は殆んどない。）△・・・やや劣
る（介錯、変色が若干ある。）Ｘ・・・劣る（介錯、変
色が顕著である。）結果を第１表に示す。◎...Excellent (no rusting or discoloration at all.)○・
・Excellent (almost no rusting or discoloration) △: Slightly inferior (some inclusions and discoloration) X: Poor (significant inclusions and discoloration) Results are shown in Table 1. show.
第１表
第１表より、アミン類のなかでもとりわけシクロヘキシ
ルアミンが優れた効果を示し、またカルボン酸やオキシ
カルボン酸との併用においてもシクロヘキシルアミンが
優れた相乗効果を示し、この場合にはシクロヘキシルア
ミンの添加量を低くしても有効に作用することが明らか
である。Table 1 From Table 1, cyclohexylamine shows particularly excellent effects among amines, and cyclohexylamine also shows excellent synergistic effects when used in combination with carboxylic acids and oxycarboxylic acids; in this case, cyclohexylamine It is clear that even if the amount of amine added is reduced, it works effectively.
本発明によれば、シクロヘキシルアミンを必須成分とし
たため、他のアミン類に比べて優れた発錆および変色防
止効果があり、特にシクロヘキシルアミンとカルボン酸
、オキシカルボン酸またはそれらの水溶性塩とを併用す
るときは相乗効果によりさらに優れた発錆および変色防
止効果が得られる。According to the present invention, since cyclohexylamine is an essential component, it has excellent rust and discoloration prevention effects compared to other amines, and in particular, cyclohexylamine and carboxylic acid, oxycarboxylic acid, or their water-soluble salts are combined. When used in combination, even better rust and discoloration prevention effects can be obtained due to the synergistic effect.
代理人 弁理士 柳 原 成Agent: Patent attorney Sei Yanagi Hara
Claims (2)
防止剤。(1) Steel plate discoloration inhibitor for cleaning water consisting of cyclohexylamine.
ボン酸、オキシカルボン酸またはこれらの水溶性塩から
成る洗浄水用鋼板変色防止剤。(2) A discoloration preventive agent for steel sheets for cleaning water, comprising cyclohexylamine and a carboxylic acid having 6 to 14 carbon atoms, an oxycarboxylic acid, or a water-soluble salt thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5294888A JPH01225785A (en) | 1988-03-07 | 1988-03-07 | Tarnish inhibitor for steel sheet added to washing water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5294888A JPH01225785A (en) | 1988-03-07 | 1988-03-07 | Tarnish inhibitor for steel sheet added to washing water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01225785A true JPH01225785A (en) | 1989-09-08 |
| JPH0333784B2 JPH0333784B2 (en) | 1991-05-20 |
Family
ID=12929100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5294888A Granted JPH01225785A (en) | 1988-03-07 | 1988-03-07 | Tarnish inhibitor for steel sheet added to washing water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01225785A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010062873A (en) * | 1999-12-20 | 2001-07-09 | 이구택 | Pickling composition having a good surface whiteness for the steels |
| US10385460B2 (en) * | 2014-08-08 | 2019-08-20 | Nch Corporation | Composition and method for treating white rust |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5215530A (en) * | 1975-07-29 | 1977-02-05 | Okura Ind Co Ltd | Quick curing anaerobic adhesive composition |
| JPS62116788A (en) * | 1985-09-17 | 1987-05-28 | カルゴン コ−ポレ−シヨン | Nover boiler corrosion inhibiting composition and method |
-
1988
- 1988-03-07 JP JP5294888A patent/JPH01225785A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5215530A (en) * | 1975-07-29 | 1977-02-05 | Okura Ind Co Ltd | Quick curing anaerobic adhesive composition |
| JPS62116788A (en) * | 1985-09-17 | 1987-05-28 | カルゴン コ−ポレ−シヨン | Nover boiler corrosion inhibiting composition and method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010062873A (en) * | 1999-12-20 | 2001-07-09 | 이구택 | Pickling composition having a good surface whiteness for the steels |
| US10385460B2 (en) * | 2014-08-08 | 2019-08-20 | Nch Corporation | Composition and method for treating white rust |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0333784B2 (en) | 1991-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100394601B1 (en) | Tinned steel anti-corrosive cleaner | |
| CN104862719A (en) | Environmental-protection type multifunctional efficient acid washing mist inhibition corrosion inhibitor | |
| GB2051872A (en) | Metal oxide remover composition | |
| CN111364047A (en) | Wax removing water and preparation method thereof | |
| JP2013087357A (en) | Rust removal/rust preventive agent and rust removal/rust prevention method | |
| US5614028A (en) | Method of cleaning and passivating a metal surface with acidic system and ethoxylated tertiary dodecyl mercaptan | |
| US20090148335A1 (en) | Process for surface treatment of metals | |
| JP4335737B2 (en) | Method for producing Si-containing steel sheet | |
| JPH06192693A (en) | Aqueous detergent composition | |
| US5296042A (en) | Composition and process for treating sheet steel | |
| US2836566A (en) | Cleaning composition and method | |
| JP4317298B2 (en) | Metal discoloration inhibitor composition, discoloration prevention liquid, and discoloration prevention method | |
| JPH01225785A (en) | Tarnish inhibitor for steel sheet added to washing water | |
| JPS62260083A (en) | Method for chemically cleaning surface of stainless steel | |
| JPH07835B2 (en) | Steel plate discoloration prevention method | |
| JP4750386B2 (en) | Water washing treatment method for pickled steel strip | |
| JP4927322B2 (en) | Discoloration inhibitor composition for hot-rolled steel sheet, discoloration prevention liquid and discoloration prevention method | |
| JPH03240981A (en) | Discoloration preventive agent for steel sheet | |
| JPH02305985A (en) | Method for preventing discoloration of steel | |
| US20080202554A1 (en) | Process for surface treatment of metals | |
| JPH02125887A (en) | Steel sheet discoloration inhibitor for washing water | |
| STREICHER | Synergistic inhibition of ferric ion corrosion during chemical cleaning of metal surfaces | |
| JP2959365B2 (en) | How to prevent discoloration of steel sheet | |
| JPH0329872B2 (en) | ||
| JPH07113190A (en) | Smut removing liquid |