JPH01221265A - Image forming device - Google Patents

Image forming device

Info

Publication number
JPH01221265A
JPH01221265A JP4798388A JP4798388A JPH01221265A JP H01221265 A JPH01221265 A JP H01221265A JP 4798388 A JP4798388 A JP 4798388A JP 4798388 A JP4798388 A JP 4798388A JP H01221265 A JPH01221265 A JP H01221265A
Authority
JP
Japan
Prior art keywords
light
layer
image
thermochromic layer
photoreceptor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4798388A
Other languages
Japanese (ja)
Inventor
Tsuneo Handa
恒雄 半田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp filed Critical Seiko Epson Corp
Priority to JP4798388A priority Critical patent/JPH01221265A/en
Publication of JPH01221265A publication Critical patent/JPH01221265A/en
Pending legal-status Critical Current

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Landscapes

  • Printers Or Recording Devices Using Electromagnetic And Radiation Means (AREA)
  • Electrophotography Using Other Than Carlson'S Method (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Dot-Matrix Printers And Others (AREA)
  • Electronic Switches (AREA)

Abstract

PURPOSE:To output many sheets of the same copy at a high speed and to enable a photosensitive material to be stably used again, by a method wherein the photosensitive material contains a thermochromic layer, and a photoconductive layer, and erazing of an image is confirmed based on a reflection scattered amount of light of the photosensitive material. CONSTITUTION:A photosensitive material 1 is of an endless belt state, and forms an image moving in the arrow 2 direction. A thermal head 3 as a heat application means, a unit 5 emitting uniform light, an infrared heating lamp 1 as an image erazing means of a thermochromic layer 15, a light beam emission means 12, and a light receiving sensor 13 are arranged inside the belt. The thermochromic layer 15 is of resin in which organic low molecular material particle is dispersed, and is formed by coating on a transparent substrate 16 to be dried. A transparent conductive material layer 17 is formed on a surface contrary to the thermochromic layer 15 of the transparent substrate 16, and a photoconductive material layer 18 is established thereon. Since an initial state of the thermochromic layer 15 is transparent and is of a state wherein light is not scattered, by detecting return to the initial state by a scattering amount of light, the detection can be performed at high sensitivity by using intensive light.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は電子写真技術を応用した新規な感光体を使った
新規な画像形成方法による画像形成装置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an image forming apparatus using a novel image forming method using a novel photoreceptor applying electrophotographic technology.

[従来の技術] 従来の感光体はA1の様な導電性基体上に光導電層を形
成したものであった。また従来の画像形成方法は、光導
電層表面を帯電する工程、光導電層表面にレーザービー
ム等の集束光を強度変調しながら照射しあるいは更に光
導電層面を走査することにより光照射部の帯電を消去し
静電潜像を形成する工程を含んでいた。
[Prior Art] A conventional photoreceptor has a photoconductive layer formed on a conductive substrate such as A1. In addition, conventional image forming methods include a step of charging the surface of the photoconductive layer, irradiating the surface of the photoconductive layer with focused light such as a laser beam while modulating the intensity, or further scanning the surface of the photoconductive layer to charge the light irradiated area. It included a step of erasing the image and forming an electrostatic latent image.

[発明が解決しようとする課M] しかし、かかる従来の感光体及び画像形成方法による画
像形成装置では、−枚印字毎にレーザービーム等で静電
潜像を形成しなければならなかった。この場合レーザー
ビームの強度に限界があり、さらに強度変調スピードに
も限界があり、同−1稿の多数枚出力を迅速に行うこと
はかなり無理があった。また多数枚処理のためにゼロッ
クス社がゼロリソグラフィ技術による画像形成装置を提
案しているが、この方式では感光体を使い捨て方式とし
ているためにメンテナンスがかかり、ランニングコスト
が上昇するという欠点があった。
[Problem M to be Solved by the Invention] However, in an image forming apparatus using such a conventional photoreceptor and image forming method, an electrostatic latent image must be formed using a laser beam or the like every time one sheet is printed. In this case, there is a limit to the intensity of the laser beam, and there is also a limit to the intensity modulation speed, so it is quite impossible to quickly output multiple copies of the same manuscript. In addition, Xerox Corporation has proposed an image forming device using xerolithography technology for processing a large number of sheets, but this method requires maintenance and increases running costs because the photoreceptor is disposable. .

そこで本発明では、従来のこのような問題点を解決する
ため、再使用可能でかつ一度画像形成を行えば簡単かつ
迅速な工程で同一原稿を複数枚出力できる新規な感光体
と新規な画像形成方法による画像形成装置を提供するこ
とを目的とするものである。
Therefore, in order to solve these conventional problems, the present invention has developed a new photoreceptor that is reusable and can output multiple sheets of the same original in a simple and quick process once image formation is performed, and a new image forming method. An object of the present invention is to provide an image forming apparatus using a method.

[課題を解決するための手段] 上記課題を解決するため、本発明の画像形成装置の感光
体は、サーモクロミック層、光導電層を含むことを特徴
とする。また本発明の画像形成装置は、該感光体、全面
透明なサーモクロミック層に不透明な画像を形成する熱
印加手段、該サーモクロミック層を版として静電潜像を
形成する手段、該静電潜像を可視像化する手段、サーモ
クロミック層の画像消去のためのサーモクロミック層の
全面加熱手段、該画像消去の確認を該感光体の光の反射
散乱量により行う手段、を備えたことを特徴とする。
[Means for Solving the Problems] In order to solve the above problems, the photoreceptor of the image forming apparatus of the present invention is characterized in that it includes a thermochromic layer and a photoconductive layer. Further, the image forming apparatus of the present invention includes the photoreceptor, a heat applying means for forming an opaque image on the entirely transparent thermochromic layer, a means for forming an electrostatic latent image using the thermochromic layer as a plate, and the electrostatic latent image. A means for visualizing an image, a means for heating the entire surface of the thermochromic layer for erasing the image on the thermochromic layer, and a means for confirming the erasure of the image by the amount of reflection and scattering of light from the photoreceptor. Features.

[作用] 上記のように構成された感光体は、熱によりサーモクロ
ミック層に像を一度形成すると、均一全面露光によりサ
ーモクロミック層に形成された像を版として何度も光導
電層に画像形成ができ現像が行え同一原稿を多数枚迅速
に出力できる。またサーモクロミック層の初期状態が透
明であり光を散乱しない状態なので初期状態への復帰を
光の散乱量で検出することにより強い光を使って高感度
ビ検出できる。したがって感光体に最小の熱印加でサー
モクロミック層を完全に可逆にできるので感光体の劣化
も少なく感光体は何回でも再使用できる。  1 以下、実施例により本発明の詳細を示す。
[Function] Once an image is formed on the thermochromic layer by heat, the photoreceptor configured as described above uses the image formed on the thermochromic layer by uniform overall exposure as a plate to form an image many times on the photoconductive layer. It is possible to perform development and quickly output multiple copies of the same original. Furthermore, since the initial state of the thermochromic layer is transparent and does not scatter light, high-sensitivity detection using strong light is possible by detecting the return to the initial state based on the amount of light scattering. Therefore, since the thermochromic layer can be completely reversible with minimal heat application to the photoreceptor, there is little deterioration of the photoreceptor and the photoreceptor can be reused any number of times. 1 Hereinafter, the details of the present invention will be illustrated by examples.

[実施例] 第1図に本発明の画像形成装置の一実施例の概略図を示
す、この例では感光体1は無端のベルト状であり矢印2
の方向に動きながら画像を形成していく、ベルトの内側
に熱印加手段であるサーマルヘッド3、均一光発生のユ
ニット5、サーモクロミック層の画像消去手段である赤
外線加熱ランプ11、光ビーム発生手段12、受光セン
サ13が配置されてありスペースの利用効率が良く装置
がコンパクトになっている。
[Embodiment] FIG. 1 shows a schematic diagram of an embodiment of an image forming apparatus of the present invention. In this example, a photoreceptor 1 is in the shape of an endless belt, and arrow 2
A thermal head 3 is a means for applying heat to the inside of the belt, a unit 5 for generating uniform light, an infrared heating lamp 11 is a means for erasing an image of the thermochromic layer, and a light beam generating means forms an image while moving in the direction of the belt. 12. The light-receiving sensor 13 is arranged, so space is used efficiently and the device is compact.

第2図に本発明の第1図の感光体1の構成を示す。15
のサーモクロミック層は第4回ノンインパクトプリンテ
ィング技術論文集p、57−60に示されたもので1μ
m程度の有機低分子物質粒子を樹脂中に分散させたもの
で、厚みは1o−20μm程度でその表面に樹脂保護層
を設けたものである。PET、アラミドのような10−
50μm程度の透明基体16上に塗布乾燥させて形成す
る。透明基体16のサーモクロミック層15と反対の面
に透明導電体層17が形成されている。透明導電体層1
7としては工TOあるいは半透明のCrあるいはAu金
属層をスパッタ、あるいは真空蒸着で形成しである。透
明導電体層17上には光導電体層18を設ける。光導電
体層18としては有機感光体層が望ましく、層全体が透
明である必要がある。一般の有機光感光体はこの条件を
満足する。有機感光体としては電荷発生層と電荷移動層
の二層からなる機能分離型が良い特性を示す。
FIG. 2 shows the structure of the photoreceptor 1 shown in FIG. 1 according to the present invention. 15
The thermochromic layer is the one shown in the 4th Non-Impact Printing Technology Papers, p. 57-60, and has a thickness of 1μ.
It is made by dispersing organic low-molecular substance particles of about 100 µm in size in a resin, and has a thickness of about 10-20 µm, with a resin protective layer provided on its surface. 10- like PET, aramid
It is formed by coating and drying on a transparent substrate 16 of about 50 μm. A transparent conductor layer 17 is formed on the surface of the transparent substrate 16 opposite to the thermochromic layer 15 . Transparent conductor layer 1
The layer 7 is formed by forming a TO layer or a semi-transparent Cr or Au metal layer by sputtering or vacuum evaporation. A photoconductor layer 18 is provided on the transparent conductor layer 17. The photoconductor layer 18 is preferably an organic photoreceptor layer, and the entire layer must be transparent. General organic photoreceptors satisfy this condition. As an organic photoreceptor, a functionally separated type consisting of two layers, a charge generation layer and a charge transfer layer, exhibits good characteristics.

電荷発生層としてはフタロシアニン系あるいはアゾ系の
顔料粒子を樹脂に分散させた膜である。電荷移動層とし
てはヒドラゾン系、スチルベン系、ベンジジン系などの
材料を樹脂に相溶させた膜である。膜厚はトータルで1
0−20μm程度である。
The charge generation layer is a film in which phthalocyanine or azo pigment particles are dispersed in a resin. The charge transfer layer is a film made by dissolving hydrazone-based, stilbene-based, benzidine-based, or other materials in a resin. The total film thickness is 1
It is about 0-20 μm.

本構成の感光体の場合、サーモクロミック層は透明状態
と不透明状態を可逆的にとることができ、サーモクロミ
ック層にサーマルヘッド等の熱印加手段を用いて可視像
を形成できる。第2図を用いてこの点を説明する。室温
のはじめの状態を全面透明にしておく。孜にサーマルヘ
ッド等により加熱してT3まで昇温すると加熱した部分
のみやや不透明状態になりその後室温まで戻すと完全な
不透明状態になり可視像をえることができる。サーモク
ロミック層全体をT2まで加熱してその後室温まで戻す
ことにより全面が透明状態になりはじめの状態に戻せる
。このサイクルを繰り返すことができサーモクロミック
層は何度も造形酸ができる。この可視像を露光マスクと
して利用することにより、サーモクロミック層側から感
光体に全面露光することにより光導電体上に何度でもパ
ターン露光することが可能である。従って一度画像を書
き込めば感光体は画像を記憶しており容易に同一の静電
潜像が形成でき画像の複数枚の出力が可能である。
In the case of the photoreceptor having this configuration, the thermochromic layer can reversibly take on a transparent state and an opaque state, and a visible image can be formed on the thermochromic layer using heat application means such as a thermal head. This point will be explained using FIG. The initial state of room temperature is completely transparent. When heated with a thermal head or the like to raise the temperature to T3, only the heated portion becomes slightly opaque, and when the temperature is then returned to room temperature, it becomes completely opaque and a visible image can be obtained. By heating the entire thermochromic layer to T2 and then returning it to room temperature, the entire surface becomes transparent and can be returned to its initial state. This cycle can be repeated and the thermochromic layer can be shaped over and over again. By using this visible image as an exposure mask, it is possible to pattern-expose the photoconductor any number of times by exposing the entire surface of the photoconductor to light from the thermochromic layer side. Therefore, once an image is written, the photoreceptor stores the image, and the same electrostatic latent image can be easily formed, making it possible to output a plurality of images.

第4図の画像形成工程図を基に第1図の画像形成′装置
の作動を説明する。1の感光体ベルトの内側にサークロ
ミック層15があるようになっている。はじめにサーモ
クロミック層15を透明状態にしておく、この状態のサ
ーモクロミック層にサーマルヘッド3を接触させ形成し
たい画像に応じてサーマルヘッド3に通電発熱しこの熱
によりサーモクロミック層15に部分的に不透明部19
を形成し画像を書き込む(第4図(A))。次に光導電
層18上にコロトロンあるいはスコロトロンのコロナイ
オン発生器4により全面均一帯電を行う(第4図(B)
)、  本例ではマイナスに帯電されている。更にこの
状態でサーモクロミック層側から感光体に全面露光ラン
プ5により均一光を発生させる。発生される均一光20
を照射すると光導電JW18にパターン露光される。つ
まりサーマルヘッドで加熱した部分に対応した光導電層
の部分の帯電電荷が消失される(第4図(C))、  
この場合全面均一露光でありビームなどに形成する必要
もなく小出力の光源で光量は十分に確、保でき非常に短
時間の露光でよい0次に得られた静電潜像を現像器6の
プラスのトナー21で正現像することにより可視像化す
る(第4図(D))。現像器6は従来の電子写真プロセ
スで使われている一成分あるいは二成分の現像器でよい
。その後記録紙7を感光体に接触させ記録紙裏面よりコ
ロトロン8によりマイナスのイオンを照射し感光体上の
トナー21を記録紙7に移して(第4図(E))、ヒー
トローラー9の間を通して定着処理をして画像形成を終
了する。複数枚出力するときは工程(B)にもどってプ
ロセスを繰り返し必要枚数の出力を行う0画像出力を終
了すると、赤外線加熱ランプ11によりT2までサーモ
クロミック層全体を加熱して全面透明にもどし次の画像
形成に備える。赤外線加熱ランプは熱容量が小さくレス
ポンスがすばやいので加熱の制御が非常に容易である。
The operation of the image forming apparatus shown in FIG. 1 will be explained based on the image forming process diagram shown in FIG. A circumchromic layer 15 is provided inside the photoreceptor belt 1. First, the thermochromic layer 15 is made transparent. The thermal head 3 is brought into contact with the thermochromic layer in this state, and electricity is applied to the thermal head 3 to generate heat according to the image desired to be formed. This heat makes the thermochromic layer 15 partially opaque. Part 19
is formed and an image is written (FIG. 4(A)). Next, the entire surface of the photoconductive layer 18 is uniformly charged by a corona ion generator 4 of a corotron or scorotron (FIG. 4(B)).
), in this example it is negatively charged. Furthermore, in this state, uniform light is generated from the thermochromic layer side onto the photoreceptor by the entire surface exposure lamp 5. Uniform light 20 generated
When irradiated with , the photoconductive JW 18 is exposed in a pattern. In other words, the electrical charge in the portion of the photoconductive layer corresponding to the portion heated by the thermal head is eliminated (FIG. 4(C)).
In this case, the entire surface is uniformly exposed, there is no need to form a beam, etc., the amount of light can be sufficiently secured and maintained with a small output light source, and the electrostatic latent image obtained at order 0 is transferred to the developer 6. The image is visualized by normal development with the positive toner 21 (FIG. 4(D)). Developer device 6 may be a one-component or two-component developer used in conventional electrophotographic processes. After that, the recording paper 7 is brought into contact with the photoreceptor, and negative ions are irradiated from the back side of the recording paper by the corotron 8 to transfer the toner 21 on the photoreceptor to the recording paper 7 (FIG. 4(E)), and between the heat rollers 9. The image formation is completed by performing fixing processing. When outputting multiple sheets, return to step (B) and repeat the process to output the required number of sheets. When the zero image output is finished, the entire thermochromic layer is heated to T2 with the infrared heating lamp 11 to return the entire surface to transparency, and the next step is performed. Prepare for image formation. Infrared heat lamps have a small heat capacity and a quick response, making heating control very easy.

このとき、サーモクロミック層が全面透明の初期状態に
戻る。ことを確実にしないと次の画像形成ができなくな
る。感光体の経時変化等を考慮すると感光体の表面温度
の制御だけでは確実に初期状態(に戻せない、そのため
本発明では感光体の光反射散乱量を検出して光反射散乱
量をゼロにするように赤外線加熱ランプの光出力を制御
するようにしている。そのためにレーザーあるいはタン
グステンランプなどからなる光ビーム発生手段12と受
光センサ13を感光体1のサーモクロミック層側にgi
tしている。光ビーム発生手段12からの出射光は平行
光となるようにする。感光体が初期状態にあれば透明で
あるので光ビーム発生手段から出射された光は感光体で
散乱されることなく感光体を透過するか決まった角度で
反射するかである。
At this time, the thermochromic layer returns to its initial state where the entire surface is transparent. If this is not done, the next image formation will not be possible. Taking into account changes in the photoreceptor over time, it is not possible to reliably return it to its initial state just by controlling the surface temperature of the photoreceptor. Therefore, in the present invention, the amount of light reflected and scattered by the photoreceptor is detected and the amount of light reflected and scattered is reduced to zero. The light output of the infrared heating lamp is controlled in this manner.For this purpose, a light beam generating means 12 consisting of a laser or a tungsten lamp, and a light receiving sensor 13 are mounted on the thermochromic layer side of the photoreceptor 1.
I'm doing t. The light emitted from the light beam generating means 12 is made to be parallel light. Since the photoreceptor is transparent in its initial state, the light emitted from the light beam generating means either passes through the photoreceptor without being scattered by the photoreceptor, or is reflected at a predetermined angle.

受光センサ13を上記の反射光を検出しない位置に配置
すると初期状態では受光センサの光検出量はゼロになる
。光ビーム出力強度を十分に上げることにより光ビーム
出力の変動があっても透明状態の検出精度を上げること
ができるので確実に初期状態にできる。またこの検出方
式をとることにより必要以上に感光体を加熱しなくてす
むので加熱による性能劣化をゼロないし最小にでき感光
体の信頼性を確保できる。光ビーム発生手段12と受光
センサ13の配置は第1図の例では赤外線加熱−ランプ
11の後になっている。この後除電ランプ14により感
光体全面の除電を行い画像形成工程を終了する。
If the light receiving sensor 13 is placed at a position where the above reflected light is not detected, the amount of light detected by the light receiving sensor becomes zero in the initial state. By sufficiently increasing the light beam output intensity, the detection accuracy of the transparent state can be increased even if the light beam output varies, so that the initial state can be reliably set. Further, by adopting this detection method, it is not necessary to heat the photoreceptor more than necessary, so that performance deterioration due to heating can be minimized to zero, and reliability of the photoreceptor can be ensured. The light beam generating means 12 and the light receiving sensor 13 are arranged after the infrared heating lamp 11 in the example shown in FIG. Thereafter, the charge is removed from the entire surface of the photoreceptor using the charge removal lamp 14, and the image forming process is completed.

[発明の効果] 以上述べたように本発明の画像形成装置は特に同一原稿
の多数枚出力を高速で行うことができ、しかも感光体を
安定して再使用できるのでランニングコストが低くメン
テナンスのかからない印刷機を提供できる。
[Effects of the Invention] As described above, the image forming apparatus of the present invention is particularly capable of outputting multiple sheets of the same original at high speed, and furthermore, since the photoreceptor can be reused stably, running costs are low and maintenance is not required. We can provide printing machines.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の画像形成装置の一実施例の概略図であ
る。 第2図は、本発明の実施例の感光体の構成を示す断面図
である。 第3図は本発明の感光体のサーモクロミック層の相変化
の状態を示す特性図である。 第4図は本発明の画像形成装置の作動を示す画像形成工
程図である。 1・・・感光体 2・・・感光体の移動方向 3・・・サーマルヘッド 4・・・コロナイオン発生器 5・・・全面露光ランプ 6・・・現像器 7・・・記録紙 8・・・コロトロン 9・・・定着器 10・・クリーナー 11・・赤外線加熱ランプ 12・・光ビーム発生手段 13・・受光センサ 14・・除電ランプ 15・・サーモクロミック層 16・・透明基体 17・・透明導電体層 18・・光導電層 19・・不透明部 20・・均一光 21・・トナー 以  上 出願人 セイコーエプソン株式会社 代理人 弁理士 最上 務(化1名) 4、)hj臼ン済生y番 第1図 第3図
FIG. 1 is a schematic diagram of an embodiment of an image forming apparatus according to the present invention. FIG. 2 is a sectional view showing the structure of a photoreceptor according to an embodiment of the present invention. FIG. 3 is a characteristic diagram showing the state of phase change of the thermochromic layer of the photoreceptor of the present invention. FIG. 4 is an image forming process diagram showing the operation of the image forming apparatus of the present invention. 1...Photoconductor 2...Movement direction of photoconductor 3...Thermal head 4...Corona ion generator 5...Full surface exposure lamp 6...Developer 7...Recording paper 8... ... Corotron 9 ... Fixing device 10 ... Cleaner 11 ... Infrared heating lamp 12 ... Light beam generating means 13 ... Light receiving sensor 14 ... Static elimination lamp 15 ... Thermochromic layer 16 ... Transparent substrate 17 ... Transparent conductor layer 18... Photoconductive layer 19... Opaque portion 20... Uniform light 21... Toner and above Applicant Seiko Epson Co., Ltd. Agent Patent attorney Tsutomu Mogami (1 person) 4.) hj finished Raw number y Figure 1 Figure 3

Claims (1)

【特許請求の範囲】[Claims] 1、透明状態、不透明状態を可逆的にとるサーモクロミ
ック層と光導電層をふくんだ感光体、全面透明なサーモ
クロミック層に不透明な画像を形成する熱印加手段、該
サーモクロミック層を版として静電潜像を形成する手段
、該静電潜像を可視像化する手段、サーモクロミック層
の画像消去のためのサーモクロミック層の全面加熱手段
、該画像消去の確認を該感光体の光の反射散乱量により
行う手段、を備えたことを特徴とする画像形成装置。
1. A photoreceptor including a thermochromic layer and a photoconductive layer that reversibly change between a transparent state and an opaque state, a heat application means for forming an opaque image on the entirely transparent thermochromic layer, and the thermochromic layer used as a plate. means for forming an electrostatic latent image; means for visualizing the electrostatic latent image; means for heating the entire surface of the thermochromic layer for erasing the image on the thermochromic layer; An image forming apparatus characterized by comprising: means for determining the amount of reflection and scattering.
JP4798388A 1988-03-01 1988-03-01 Image forming device Pending JPH01221265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4798388A JPH01221265A (en) 1988-03-01 1988-03-01 Image forming device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4798388A JPH01221265A (en) 1988-03-01 1988-03-01 Image forming device

Publications (1)

Publication Number Publication Date
JPH01221265A true JPH01221265A (en) 1989-09-04

Family

ID=12790549

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4798388A Pending JPH01221265A (en) 1988-03-01 1988-03-01 Image forming device

Country Status (1)

Country Link
JP (1) JPH01221265A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4992560A (en) * 1989-06-08 1991-02-12 The United States Of America As Represented By The United States Department Of Energy Method of preparing novel fluorinated laser dyes
US5047559A (en) * 1989-06-08 1991-09-10 United States Department Of Energy Novel fluorinated laser dyes
US5111472A (en) * 1989-06-08 1992-05-05 The United States Of America As Represented By The United States Department Of Energy Fluorinated laser dyes
US6188506B1 (en) * 1997-11-05 2001-02-13 Colortronics Technologies L.L.C. Conductive color-changing ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4992560A (en) * 1989-06-08 1991-02-12 The United States Of America As Represented By The United States Department Of Energy Method of preparing novel fluorinated laser dyes
US5047559A (en) * 1989-06-08 1991-09-10 United States Department Of Energy Novel fluorinated laser dyes
US5111472A (en) * 1989-06-08 1992-05-05 The United States Of America As Represented By The United States Department Of Energy Fluorinated laser dyes
US6188506B1 (en) * 1997-11-05 2001-02-13 Colortronics Technologies L.L.C. Conductive color-changing ink

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