JPH0121257B2 - - Google Patents

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Publication number
JPH0121257B2
JPH0121257B2 JP58082250A JP8225083A JPH0121257B2 JP H0121257 B2 JPH0121257 B2 JP H0121257B2 JP 58082250 A JP58082250 A JP 58082250A JP 8225083 A JP8225083 A JP 8225083A JP H0121257 B2 JPH0121257 B2 JP H0121257B2
Authority
JP
Japan
Prior art keywords
fiber
heat
fibers
adhesive
latent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP58082250A
Other languages
Japanese (ja)
Other versions
JPS59211668A (en
Inventor
Taizo Sugihara
Hiroshi Sonoda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JNC Corp
Original Assignee
Chisso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chisso Corp filed Critical Chisso Corp
Priority to JP58082250A priority Critical patent/JPS59211668A/en
Publication of JPS59211668A publication Critical patent/JPS59211668A/en
Publication of JPH0121257B2 publication Critical patent/JPH0121257B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】 本発明は軽量で弾力性に富み、かつ、毛羽抜け
等の無い、繊維間が強固に接合された繊維構造物
に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a fiber structure that is lightweight, highly elastic, free from shedding, and in which fibers are firmly joined.

熱可塑性重合体より成る繊維を延伸した後その
軟化点近くに加熱すると、この繊維に捲縮が発生
することがしばしば観られるが、このような現象
を熱処理による潜在捲縮の発現と言い、そのよう
な性質の繊維を潜在捲縮性を有する繊維と言う。
潜在捲縮の発現による捲縮は一般にスパイラル状
であり、繊維に強い弾力性を与えることが出来
る。潜在捲縮性を有する繊維のウエブを熱処理
し、潜在捲縮の発現に伴う繊維間の絡合により形
態を安定化させた弾力性に富む不織布等の繊維構
造物とする方法が従来より知られている。ところ
が、良好な潜在捲縮性を有する繊維は捲縮の発現
に際し大きなウエブ収縮を伴い、このウエブ収縮
が繊維構造物の幅や厚みを不均一にし、密度斑の
原因となるため、良好な弾力性と均質性は両立し
難かつた。更に、このようにして得られた不織布
は繊維間の交絡によつて形態を保持しているにす
ぎないので強力が低く毛羽抜けが起り易く、実用
上の問題が多かつた。
When fibers made of thermoplastic polymers are drawn and then heated to near their softening point, crimp is often observed in the fibers. This phenomenon is called the development of latent crimp due to heat treatment. Fibers with such properties are called fibers with latent crimp properties.
The crimp caused by the development of latent crimp is generally spiral-shaped and can impart strong elasticity to the fiber. Conventionally, a method has been known in which a web of fibers having latent crimp is heat-treated to produce a fiber structure such as a highly elastic nonwoven fabric whose form is stabilized by entanglement between fibers due to the development of latent crimp. ing. However, fibers with good latent crimp properties undergo large web shrinkage when crimp occurs, and this web shrinkage makes the width and thickness of the fiber structure uneven, causing density unevenness. Gender and homogeneity were difficult to coexist. Furthermore, the nonwoven fabric obtained in this way only maintains its shape through the intertwining of the fibers, so it has low strength and is prone to fluffing, resulting in many practical problems.

融点の異なる2種類の重合体を鞘芯型あるいは
並列型に複合紡糸して復た複合繊維(以下熱接着
性複合繊維と称することがある)を両成分の融点
間の温度で熱処理し、低融点成分の融着により繊
維間の結合を発現させる不織布等の繊維成形物の
製造法も公知である。この場合においても該複合
繊維が潜在捲縮性を有するものであれば、熱処理
時にウエブの収縮が起り、得られる不織布は品質
の変動の大きなものとなる。上記複合繊維が潜在
捲縮性を有しない場合においては、繊維構造物は
複合繊維の低融点成分部による融着により構造が
安定化され強力も大きく、熱処理による形状の変
化も小さく均質である等の利点がある。しかし、
このような潜在捲縮性を有しない繊維から成る繊
維構造物はその嵩高性および弾力性を該繊維の自
然発現捲縮(紡糸・延伸等繊維製造工程で発現し
た捲縮をいう)あるいは機械的に付与された捲縮
に依存するため捲縮密度が小さく、ソフトな風合
あるいは弾力性に富んだ風合は得られないという
欠点がある。潜在捲縮性を有しない熱接着性複合
繊維を用いてソフトで弾力性のある繊維構造物を
得る方法として熱接着のための熱処理によつて変
形しない他の繊維素材を混合することも公知であ
るが、熱接着性複合繊維間の接着点の数が減少
し、かつ熱接着性複合繊維と他素材との接着強度
が不充分なため、ここでも強力不足、毛羽抜け等
の問題が発生する。
Composite fibers (hereinafter sometimes referred to as thermoadhesive composite fibers) obtained by composite spinning two types of polymers with different melting points in a sheath-core type or parallel type are heat-treated at a temperature between the melting points of both components to create a low A method for producing a fiber molded article such as a nonwoven fabric is also known, in which bonding between fibers is developed by fusing melting point components. Even in this case, if the composite fiber has latent crimp properties, the web will shrink during heat treatment, resulting in large variations in quality of the resulting nonwoven fabric. When the above-mentioned composite fibers do not have latent crimpability, the structure of the fiber structure is stabilized and strong due to the fusion of the low melting point components of the composite fibers, and the shape change due to heat treatment is small and homogeneous. There are advantages. but,
Fiber structures made of fibers that do not have such latent crimp properties can be improved in bulk and elasticity by natural crimp of the fibers (crimps developed during fiber manufacturing processes such as spinning and drawing) or mechanically. Since it depends on the crimps imparted to the fabric, the crimping density is low and a soft texture or a texture rich in elasticity cannot be obtained. As a method of obtaining a soft and elastic fiber structure using heat-adhesive composite fibers that do not have latent crimp properties, it is also known to mix other fiber materials that do not deform by heat treatment for heat-adhesion. However, because the number of bonding points between heat-adhesive composite fibers is reduced and the adhesive strength between heat-adhesive composite fibers and other materials is insufficient, problems such as insufficient strength and shedding of fuzz occur here as well. .

本発明は在来の繊維構造物の上記諸欠点を解消
すべくなされたものであり、潜在捲縮性を有しな
い熱接着性複合繊維(A)40〜80重量%と、潜在捲縮
性を有する熱接着性繊維(B)60〜20重量%とから成
る繊維混合物の熱処理により、熱接着性繊維(B)の
潜在捲縮性の発現による繊維間の交絡と、熱接着
性複合繊維(A)および熱接着性繊維(B)の熱接着性の
発現による繊維間の接着の双方によつて形態が安
定化された繊維構造物である。
The present invention was made in order to eliminate the above-mentioned drawbacks of conventional fiber structures, and uses 40 to 80% by weight of heat-adhesive composite fibers (A) that do not have latent crimpability and By heat treatment of a fiber mixture consisting of 60 to 20% by weight of heat-adhesive fibers (B), the heat-adhesive composite fibers (A ) and the fiber structure is stabilized by both fiber-to-fiber adhesion due to the development of thermal adhesive properties of the thermal adhesive fiber (B).

本発明で使用する潜在捲縮性を有しない熱接着
性複合繊維(A)とは、繊維形成性重合体(第1成
分)と融点が第1成分のそれより20℃以上低い1
種又は2種以上の重合体(第2成分)とを並列型
にもしくは第2成分を鞘成分とする鞘芯型に配し
た複合繊維であつて実質的に潜在捲縮性を有しな
いものをいう。複合形態が鞘芯型の場合には潜在
捲縮性の小さな繊維が得易いが、並列型の場合で
あつても紡糸、延伸条件を選ぶことにより潜在捲
縮性を無くすることが可能であり、特公昭55−
17807が例示できる。実質的に潜在捲縮性を有し
ないとは、パラレルウエブを熱処理した際の面積
収縮率が5%以下のものをいう。
The heat-adhesive composite fiber (A) without latent crimpability used in the present invention is composed of a fiber-forming polymer (first component) and a fiber-forming polymer (first component) having a melting point lower than that of the first component by at least 20°C.
Composite fibers in which a seed or two or more polymers (second component) are arranged in parallel or in a sheath-core type with the second component as a sheath component, and which have substantially no latent crimpability. say. When the composite form is a sheath-core type, it is easy to obtain fibers with low latent crimpability, but even in the case of a parallel type, latent crimpability can be eliminated by selecting the spinning and drawing conditions. ,Special Public Service 1977-
17807 is an example. The term "substantially free of latent crimp" refers to a parallel web having an area shrinkage rate of 5% or less when heat treated.

本発明で使用する潜在捲縮性を有する熱接着性
繊維(B)とは、上述の熱接着性複合繊維(A)の第2成
分の融点以下の融点を有する重合体が繊維表面の
全部もしくは一部を長さ方向に連続して形成し、
かつ、パラレルウエブを熱処理した際の面積収縮
率が20%以上となる様な潜在捲縮性を有するもの
をいい、複数成分から成る複合繊維もしくは均一
組成の繊維のいずれであつても良い。一般に、並
列型複合繊維は潜在捲縮性であり、均一組成の繊
維であつても原料樹脂の選定、紡糸条件や延伸条
件の選定により潜在捲縮性とすることが出来、例
えば延伸温度を低く接定することは一般に有効で
ある。
The heat-adhesive fiber (B) with latent crimpability used in the present invention means that a polymer having a melting point lower than the melting point of the second component of the above-mentioned heat-adhesive conjugate fiber (A) covers the entire fiber surface or A part is formed continuously in the length direction,
It also refers to a material that has latent crimpability such that the area shrinkage rate is 20% or more when the parallel web is heat-treated, and it may be either a composite fiber made of multiple components or a fiber with a uniform composition. In general, parallel composite fibers are latent crimpable, and even if they are fibers with a uniform composition, they can be rendered latent crimpable by selecting the raw material resin, spinning conditions, and drawing conditions.For example, by lowering the drawing temperature. It is generally effective to connect the

上記熱接着性複合繊維(A)と熱接着性繊維(B)との
混合は、開繊機、カード、ランダムウエバー等公
知の装置で行うことが出来る。熱接着性複合繊維
(A)の配合量を40〜80重量%と限定する理由は、該
複合繊維(A)の配合量が40重量%未満では熱処理時
に発生する収縮が大きくなり過ぎ得られる繊維構
造物が不均質になり易く、80重量%を超すと弾力
性の劣つたものになり、いずれも好ましくないた
めである。
The heat-adhesive conjugate fiber (A) and the heat-adhesive fiber (B) can be mixed using a known device such as a spreader, a card, or a random webber. Heat-adhesive composite fiber
The reason why the amount of (A) is limited to 40 to 80% by weight is that if the amount of composite fiber (A) is less than 40% by weight, the shrinkage that occurs during heat treatment will be too large and the resulting fiber structure will be non-uniform. This is because if the content exceeds 80% by weight, the elasticity becomes poor, both of which are undesirable.

このようにして得られた混合繊維ウエブは熱接
着性複合繊維(A)の第2成分の融点以上、第1成分
の融点以下の温度で熱処理されて繊維構造物とな
る。熱処理の方法としては熱風、過熱水蒸気、赤
外線等を用いた加熱炉あるいは熱ロール等の公知
の加熱手段を適宜選択して使用することが出来
る。このような熱処理によつて熱接着性繊維(B)は
潜在捲縮性を発現して周囲の繊維との絡合を強
め、同時に、熱接着性複合繊維(A)の第2成分なら
びに熱接着性繊維(B)の双方が繊維間の接触点にお
いて融着する。
The mixed fiber web thus obtained is heat-treated at a temperature higher than the melting point of the second component and lower than the melting point of the first component of the heat-adhesive conjugate fiber (A) to form a fiber structure. As a heat treatment method, any known heating means such as a heating furnace using hot air, superheated steam, infrared rays, or a heated roll can be appropriately selected and used. Through such heat treatment, the heat-adhesive fiber (B) develops latent crimpability and strengthens the entanglement with the surrounding fibers, and at the same time, the second component of the heat-adhesive composite fiber (A) and the heat-adhesive Both fibers (B) are fused at the point of contact between the fibers.

本発明の繊維構造物はそれを構成する繊維の全
てが熱接着性であるため繊維間の接着点も多く、
強度が高く抜毛や毛羽の無に構造であると共に、
潜在捲縮性の発現による繊維間の絡合により弾力
性に富む風合の優れた繊維構造物である。このよ
うな繊維構造物は、薄物では使いすておしめ等の
衛生材の表面材に、厚物ではマツトレス、布団、
枕等の詰物に、成形品ではブラジヤーパツド、フ
エルトペンや化粧筆の穂、フエルトペンの中芯等
種々の分野で使用できる。
Since all of the fibers constituting the fiber structure of the present invention are thermally adhesive, there are many bonding points between the fibers.
It has a high strength structure that does not pull hair or fuzz, and
It is a fiber structure with excellent elasticity and texture due to the entanglement of fibers due to latent crimpability. Such fiber structures are used for thin materials such as disposable diapers and other sanitary materials, and thick materials such as pine tresses, futons, etc.
It can be used in various fields such as stuffing for pillows, brassiere pads in molded products, tips for felt pens and makeup brushes, and cores for felt pens.

実施例によつて本発明を更に説明する。 The invention will be further explained by examples.

実施例 1 高密度ポリエチレン(MI15、d0.961、MP132
℃)を鞘成分とし、結晶性ポリプロピレン
(MFR=8、MP=168℃)を芯成分とし、重量
比で1:1に配した鞘芯型複合繊維を紡糸速度
800m/分で紡糸し、延伸温度120℃で4倍に延伸
し、10山/25mmの機械捲縮をかけた後切断して、
単繊維繊度3デニール、繊維長64mmの熱接着性複
合繊維(1)を得た。このものは潜在捲縮性がほとん
ど無く、フラツトカードとして140℃で熱処理し
たところ面積収縮率は2%以下であつた。
Example 1 High density polyethylene (MI15, d0.961, MP132
℃) as the sheath component and crystalline polypropylene (MFR = 8, MP = 168℃) as the core component, and the sheath-core composite fibers are arranged at a weight ratio of 1:1 at a spinning speed.
Spun at 800 m/min, stretched 4 times at a stretching temperature of 120°C, mechanically crimped at 10 threads/25 mm, and then cut.
A thermoadhesive composite fiber (1) having a single fiber fineness of 3 denier and a fiber length of 64 mm was obtained. This material had almost no latent crimp, and when heat treated as a flat card at 140°C, the area shrinkage was less than 2%.

エチレン・プロピレン・ブテン−1共重合体
(C= 28.3%、C= 44.5%、MFR6.5、MP123℃)を紡
糸速度600m/分で紡糸し、60℃で3倍に延伸し、
8山/25mmの機械捲縮をかけた後切断して、単繊
維繊度3デニール、繊維長64mmの熱接着性繊維(2)
を得た。このものをパラレルウエブとして120℃
で熱処理したところ25山/25mmの高捲縮を発生
し、面積収縮率は30%であつた。
Ethylene-propylene-butene-1 copolymer (C = 2 8.3%, C = 4 4.5%, MFR 6.5, MP 123°C) was spun at a spinning speed of 600 m/min, stretched 3 times at 60°C,
Machine crimped with 8 threads/25mm and then cut to produce heat-adhesive fibers with single fiber fineness of 3 denier and fiber length of 64mm (2)
I got it. This material is used as a parallel web at 120℃.
When it was heat-treated, high crimp of 25 peaks/25mm occurred, and the area shrinkage rate was 30%.

上記熱接着性複合繊維(1)と熱接着性繊維(2)を
50:50の重量比で混合し、フラツトカードを2回
通して目付20g/m2のパラレルウエブとした。こ
のウエブを140℃の熱風循環式ドライヤを通して
熱処理し、ドライヤー出口で室温の金属/ゴムの
エンボスロールで型付を行つて不織布とした。こ
のものは毛羽や抜毛が無く、嵩高で弾力性に富
み、使いすておしめ、ナプキン等の表面材として
好適な素材であつた。
The above heat-adhesive composite fiber (1) and heat-adhesive fiber (2)
They were mixed at a weight ratio of 50:50 and passed through a flat card twice to form a parallel web with a basis weight of 20 g/m 2 . This web was heat-treated by passing through a hot air circulation dryer at 140°C, and at the exit of the dryer, it was molded with a metal/rubber embossing roll at room temperature to form a nonwoven fabric. This material was free of fluff and hair loss, was bulky and highly elastic, and was suitable as a surface material for disposable diapers, napkins, etc.

実施例 2 結晶性ポリプロピレン(MFR5、MP168℃)
を第1成分とし、高密度ポリエチレン(MI20、
MP132℃)を第2成分とし重量比1:1で並列
型に配して800m/分で複合紡糸し、120℃で4.5
倍に延伸し、切断して単繊維繊度6デニール、繊
維長76mmの熱接着性複合繊維(3)を得た。このもの
は潜在捲縮性が全く無く、パラレルウエブとして
140℃で熱処理したところ面積収縮率は1%以下
であつた。
Example 2 Crystalline polypropylene (MFR5, MP168℃)
The first component is high-density polyethylene (MI20,
MP132℃) was used as the second component and was placed in parallel at a weight ratio of 1:1, and composite spinning was performed at 800 m/min.
It was stretched twice and cut to obtain a heat-adhesive composite fiber (3) having a single fiber fineness of 6 denier and a fiber length of 76 mm. This material has no latent crimp properties and is used as a parallel web.
When heat treated at 140°C, the area shrinkage was less than 1%.

結晶性ポリプロピレン(MFR10、MP165℃)
を第1成分とし、エチレン酢酸ビニル共重合体
(MI20、酢ビ含量20%、MP92℃)と低密度ポリ
エチレン(MI20、MP112℃)の重量比で1:3
の混合物を第2成分とし重量比1:1で並列型に
配して600m/分で複合紡糸し、40℃で3倍に延
伸し、切断して単繊維繊度6デニール、繊維長38
mmの熱接着性繊維(4)を得た。このものをパラレル
ウエブとして90℃で熱処理したところ20山/25mm
の捲縮が発生し、面積収縮率は35%であつた。
Crystalline polypropylene (MFR10, MP165℃)
is the first component, and the weight ratio of ethylene vinyl acetate copolymer (MI20, vinyl acetate content 20%, MP92℃) and low density polyethylene (MI20, MP112℃) is 1:3.
A mixture of the above was used as the second component, and the mixture was arranged in parallel at a weight ratio of 1:1, and composite spinning was performed at 600 m/min, drawn at 40°C to 3 times the original size, and cut to obtain a single fiber with a fineness of 6 denier and a fiber length of 38.
A thermoadhesive fiber (4) of mm was obtained. When this material was heat-treated at 90℃ as a parallel web, there were 20 threads/25mm.
Crimp occurred, and the area shrinkage rate was 35%.

上記熱接着性複合繊維(3)と熱接着性繊維(4)を
75:25の重量比で混合し、カードを通して目付20
g/mのスライバーとした。このスライバーを
140℃に加熱された内径10mmの金属パイプの中を
5m/分で通して熱処理し、直径10mmの棒状に成
形した。このものは弾力性と通水性に富み、孔径
9mmの液状芳香剤の容器に詰める含浸材として使
用したところ挿入が容易で、かつ、容器の開孔部
との密着性が良く液漏れが発生しない好適な材料
であつた。
The above heat-adhesive composite fiber (3) and heat-adhesive fiber (4)
Mix at a weight ratio of 75:25 and pass through a card to obtain a basis weight of 20
g/m sliver. this sliver
The material was heat-treated by passing it through a metal pipe with an inner diameter of 10 mm heated to 140°C at a rate of 5 m/min, and then formed into a rod shape with a diameter of 10 mm. This material has high elasticity and water permeability, and when used as an impregnating material in liquid fragrance containers with a pore diameter of 9 mm, it was easy to insert, and it adhered well to the opening of the container, preventing liquid leakage. It was a suitable material.

実施例 3 実施例2で用いた熱接着性複合繊維(3)と100℃
の熱処理で22山/25mmの潜在捲縮を発現し、ウエ
ブの面積収縮率が25%であるポリエステル繊維
(MP110℃、単繊維繊度4デニール、繊維長51
mm)を40:60の重量比で混合し、巾65インチのロ
ーラカードを通して目付2000g/m2のウエブとし
た。このウエブを145℃の熱風サクシヨン式乾燥
機で10分間熱処理して繊維間が網目状に融着した
厚さ100mmの繊維構造物を得た。この繊維構造物
を巾92cm、長さ195cmに切断し、その上下に木
綿/ポリエステル(30/70重量比)のウエブ(目
付200g/m2)を積層し、シングルサイズの布団
用側地に収納し、キルテイングして敷布団を得
た。このものは柔軟でかつ弾力性に富んた底つき
感の無い優れた風合を有し、吸湿性および保温性
の良好な敷布団であつた。
Example 3 Heat-adhesive composite fiber (3) used in Example 2 and 100°C
Polyester fiber (MP110℃, single fiber fineness 4 denier, fiber length 51
mm) at a weight ratio of 40:60 and passed through a roller card with a width of 65 inches to form a web with a basis weight of 2000 g/m 2 . This web was heat-treated in a hot air suction dryer at 145° C. for 10 minutes to obtain a fiber structure with a thickness of 100 mm in which the fibers were fused in a mesh pattern. This fiber structure was cut into 92cm wide and 195cm long pieces, and cotton/polyester (30/70 weight ratio) webs (basis weight 200g/m 2 ) were layered on the top and bottom, and the pieces were stored in a single-sized futon side fabric. Then, I quilted it and got a mattress. This mattress was soft and elastic, had an excellent feel without feeling bottomed out, and had good moisture absorption and heat retention properties.

Claims (1)

【特許請求の範囲】[Claims] 1 潜在捲縮性を有しない熱接着性複合繊維(A)40
〜80重量%と、潜在捲縮性を有する熱接着性繊維
(B)60〜20重量%とから成る繊維混合物の熱処理に
より熱接着性繊維(B)の潜在捲縮性の発現による繊
維間の交絡と、熱接着性複合繊維(A)および熱接着
性繊維(B)の熱接着性の発現による繊維間の接着の
双方によつて形態が安定化されたことを特徴とす
る繊維構造物。
1 Heat-adhesive composite fiber without latent crimp (A) 40
~80% by weight, thermal adhesive fiber with latent crimp properties
(B) By heat treatment of a fiber mixture consisting of 60 to 20% by weight, the heat-adhesive fibers (B) develop latent crimpability, resulting in entanglement between the fibers, and the heat-adhesive composite fibers (A) and the heat-adhesive fibers. A fibrous structure characterized in that the form of (B) is stabilized by both adhesion between fibers due to the development of thermal adhesive properties.
JP58082250A 1983-05-11 1983-05-11 Fiber structure Granted JPS59211668A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58082250A JPS59211668A (en) 1983-05-11 1983-05-11 Fiber structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58082250A JPS59211668A (en) 1983-05-11 1983-05-11 Fiber structure

Publications (2)

Publication Number Publication Date
JPS59211668A JPS59211668A (en) 1984-11-30
JPH0121257B2 true JPH0121257B2 (en) 1989-04-20

Family

ID=13769183

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58082250A Granted JPS59211668A (en) 1983-05-11 1983-05-11 Fiber structure

Country Status (1)

Country Link
JP (1) JPS59211668A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2545248B2 (en) * 1987-12-04 1996-10-16 チッソ株式会社 Stretchable non-woven fabric
JP5842353B2 (en) * 2010-04-13 2016-01-13 Jnc株式会社 Bulky nonwoven fabric
JP5831840B2 (en) 2011-07-12 2015-12-09 Jnc株式会社 Stretchable nonwoven fabric and method for producing the same
US20230039925A1 (en) * 2019-12-25 2023-02-09 Kao Corporation Heating implement

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50116769A (en) * 1974-02-26 1975-09-12
JPS521133A (en) * 1976-06-18 1977-01-06 Chisso Corp Heat-bonding composite fibers and a process for manufacturing them
JPS5212830A (en) * 1975-07-21 1977-01-31 Kyocera Corp Exposure warning circuit
JPS5361454A (en) * 1976-11-11 1978-06-01 Chisso Corp Brassiere cup and method of producing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50116769A (en) * 1974-02-26 1975-09-12
JPS5212830A (en) * 1975-07-21 1977-01-31 Kyocera Corp Exposure warning circuit
JPS521133A (en) * 1976-06-18 1977-01-06 Chisso Corp Heat-bonding composite fibers and a process for manufacturing them
JPS5361454A (en) * 1976-11-11 1978-06-01 Chisso Corp Brassiere cup and method of producing same

Also Published As

Publication number Publication date
JPS59211668A (en) 1984-11-30

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