JPH01212248A - Glaze composition for artificial tooth - Google Patents
Glaze composition for artificial toothInfo
- Publication number
- JPH01212248A JPH01212248A JP63036507A JP3650788A JPH01212248A JP H01212248 A JPH01212248 A JP H01212248A JP 63036507 A JP63036507 A JP 63036507A JP 3650788 A JP3650788 A JP 3650788A JP H01212248 A JPH01212248 A JP H01212248A
- Authority
- JP
- Japan
- Prior art keywords
- glaze
- glaze composition
- compsn
- artificial teeth
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 39
- 239000010433 feldspar Substances 0.000 claims abstract description 8
- 239000013078 crystal Substances 0.000 claims abstract description 7
- 230000009477 glass transition Effects 0.000 claims abstract 2
- 239000003086 colorant Substances 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 239000011029 spinel Substances 0.000 claims description 2
- 229910052596 spinel Inorganic materials 0.000 claims description 2
- 239000011521 glass Substances 0.000 abstract description 20
- 239000000463 material Substances 0.000 abstract description 20
- 239000000126 substance Substances 0.000 abstract description 14
- 229910052573 porcelain Inorganic materials 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 238000007496 glass forming Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000005388 borosilicate glass Substances 0.000 abstract 1
- 239000001506 calcium phosphate Substances 0.000 abstract 1
- 229910000389 calcium phosphate Inorganic materials 0.000 abstract 1
- 235000011010 calcium phosphates Nutrition 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000002585 base Substances 0.000 description 11
- 210000000332 tooth crown Anatomy 0.000 description 9
- 238000010304 firing Methods 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 238000004040 coloring Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 210000000214 mouth Anatomy 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- LKJPSUCKSLORMF-UHFFFAOYSA-N Monolinuron Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C=C1 LKJPSUCKSLORMF-UHFFFAOYSA-N 0.000 description 1
- QVMHUALAQYRRBM-UHFFFAOYSA-N [P].[P] Chemical compound [P].[P] QVMHUALAQYRRBM-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0007—Compositions for glass with special properties for biologically-compatible glass
- C03C4/0021—Compositions for glass with special properties for biologically-compatible glass for dental use
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Glass Compositions (AREA)
- Dental Preparations (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の目的〕
（産業上の利用分野）
本発明は、人工歯１例えば結晶化ガラスや陶材製の人工
歯冠などの表面あるいは内面を着色するのに用いられる
釉薬組成物に関する。更に詳しくは、本発、明、は釉薬
の人工歯の基材に対する制約がなく、その焼成温度が低
く、かつ、施釉処理が簡便であるなどの優れた特性を有
する人工歯用釉薬組成物に関するものである。[Detailed Description of the Invention] [Object of the Invention] (Industrial Application Field) The present invention is used to color the surface or inner surface of an artificial tooth 1, such as an artificial tooth crown made of crystallized glass or porcelain. The present invention relates to a glaze composition. More specifically, the present invention relates to a glaze composition for artificial teeth that has excellent properties such as no restrictions on the base material of the glazed artificial tooth, a low firing temperature, and easy glazing treatment. It is something.
（従来の技術）
人工歯、例えば人工歯冠、インレー、ブリッジなどは結
晶化ガラス系、陶材系、レジン系など各種の材料を用い
て製作されるようになったが、口膣内での審美性を高め
ることが要請されている。(Prior art) Artificial teeth, such as artificial crowns, inlays, and bridges, have come to be manufactured using various materials such as crystallized glass, porcelain, and resin. There is a need to improve aesthetics.
即ち１人工歯牙や人工歯冠などと生体歯牙の外観をより
近似させ１口腔内での審美性を高めることが要請されて
いる。That is, there is a demand for improving the aesthetics within an oral cavity by making the appearance of a living tooth more similar to that of an artificial tooth or crown.
この種の目的のために釉薬（絵付は材、カラーリング材
、スティンともいわれる）が使用されるが、従来、この
種の人工歯冠などに対して用いられる釉薬としては、一
般にＳｉｎ、 、 ＡＩ、Ｏ，を主成分とするガラスあ
るいは長石系結晶化ガラスがあるが、これは主に陶材で
製作された長石系セラミック歯を対象としたものである
。しかし、これを結晶化ガラスからなる人工歯科基材に
適用した場合、釉薬の焼成時に基材と釉薬との熱膨張差
が大きいため剥離やクラックが発生し、また両者間の濡
れ性（相性）が悪いため密着性や付着性において問題が
生じやすい。Glazes (also called painting materials, coloring materials, and stains) are used for this kind of purpose, but conventionally, the glazes used for this kind of artificial tooth crowns are generally Sin, AI, etc. , O, or feldspar-based crystallized glass is available, but this is mainly intended for feldspar-based ceramic teeth made of porcelain. However, when this is applied to an artificial dental base material made of crystallized glass, peeling and cracking occur due to the large difference in thermal expansion between the base material and the glaze when the glaze is fired, and the wettability (compatibility) between the two. Due to poor adhesion, problems tend to occur in terms of adhesion and adhesion.
また、上記釉薬の焼成温度は９００〜１０００℃であり
、軟化温度の低い結晶化ガラスからなる人工歯科基材に
用いると釉薬の焼成時に基材が軟化変形するため使用で
きず、耐酸性、耐アルカリ性、耐水性などの化学的耐久
性及び口腔内長期安定性の面でも十分なものではない。In addition, the firing temperature of the above glaze is 900 to 1000°C, and if it is used for an artificial dental base material made of crystallized glass with a low softening temperature, the base material will soften and deform when the glaze is fired, so it cannot be used, and the acid resistance and It is also insufficient in terms of chemical durability such as alkalinity and water resistance, and long-term stability in the oral cavity.
さらに、特開昭６０−１７７８０２号にはリン酸力ルシ
ュウム系歯科基材に適用される同質系のスティン、即ち
原子比Ｃａ／Ｐを特定化したリン酸化リチウムに酸化リ
チウムを配合してなるリン酸力ルシュウム系の釉薬組成
物が開示されている。このものは人工歯科基材がリン酸
力ルシュウム系のものに限定されてしまうという難があ
る。Furthermore, JP-A No. 60-177802 discloses a homogeneous stain that is applied to phosphoric acid dental base materials, that is, a phosphorus phosphor made by blending lithium oxide with lithium phosphate with a specified atomic ratio Ca/P. An acidurium-based glaze composition is disclosed. This method has the disadvantage that the artificial dental base material is limited to those based on lucium phosphate.
（発明が解決しようとする課題）
本発明者らは、前記した従来の人工歯に適用される釉薬
の欠点、限界を解決すべく鋭意検討した結果、５ｉｎ２
．とＢ、０．を主成分としたホウケイ酸系ガラス質を形
成する釉薬が、適用基材に制約を受けず、低温焼成が可
能で、かつ化学的耐久性９口腔自長期安定性に優れてい
ることを見い出し１本発明を完成するに至った。(Problems to be Solved by the Invention) As a result of intensive study to solve the drawbacks and limitations of the glaze applied to the conventional artificial teeth described above, the present inventors found that the 5in2
．． and B, 0. It has been discovered that a borosilicate-based glass-forming glaze, which is mainly composed of The present invention has now been completed.
（課題を解決するための手段）
本発明を概説すれば、本発明は人工歯に適用する釉薬組
成物において、前記釉薬組成物の構成成分と組成割合（
重量％）が、
Ｓｉｎ、 ・・・・・・・・・・・・・・・ ５５
〜７０％Ｂ２Ｏ３・・・・・・・・・・・・・・・
０．１〜２５％ＡＩｔ、０３ ・・・・・・・・・・
・・・・・ ２〜１０％Ｎａ、Ｏ・・川・・・・・・
・・・・ ０．１〜１０％Ｋ２Ｏ・・・・・・・・・
・・・・・・ ０．１〜１０％であることを特徴とす
る人工歯用釉薬組成物に関するものである。また、本発
明は釉薬の適用基材に対する制約をさらに改善するため
に、前記した釉薬組成物５０〜８０重量部と長石系結晶
５０〜２０重量部とからなる人工歯用釉薬組成物にも関
するものである。(Means for Solving the Problems) To summarize the present invention, in a glaze composition applied to artificial teeth, the constituent components and composition ratios of the glaze composition (
Weight%) is Sin, ・・・・・・・・・・・・・・・ 55
~70%B2O3・・・・・・・・・・・・・・・
0.1~25%AIt, 03 ・・・・・・・・・・・・
...2~10% Na, O... River...
・・・・・・ 0.1~10%K2O・・・・・・・・・
...... The present invention relates to a glaze composition for artificial teeth characterized by a content of 0.1 to 10%. Furthermore, the present invention also relates to a glaze composition for artificial teeth comprising 50 to 80 parts by weight of the glaze composition described above and 50 to 20 parts by weight of feldspar crystals, in order to further improve restrictions on the substrate to which the glaze is applied. It is something.
以下、本発明の構成を詳しく説明する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明において、釉薬の構成成分ならびにその組成割合
の決定は次の点を配慮してなされた。即ち、人工歯の基
材として種々の結晶化ガラス系のものが盛んに、研究開
発されている実情に鑑み、これら基材に十分適合するこ
とは勿論、従前の陶材系にも適合する人体に無害な釉薬
を構成する成分とその組成割合を決定しなけ九ばならな
い。In the present invention, the constituent components of the glaze and their composition ratios were determined with the following points in mind. In other words, in view of the fact that various crystallized glass-based materials are being actively researched and developed as base materials for artificial teeth, it is clear that the human body is not only fully compatible with these base materials, but also compatible with conventional porcelain-based materials. The ingredients that make up the glaze and their composition ratios must be determined.
これを結晶化ガラス、例えばリン酸力ルシュウム系結晶
化ガラスを例にとって説明する。This will be explained by taking as an example a crystallized glass, for example, a lucium phosphate crystallized glass.
リン酸力ルシュウム系結晶化ガラスからなり、鋳造法で
製作した人工歯冠（キャスタブル・クラウン）の場合、
高い温度で焼成すると軟化変形したりサーマルショック
によって破損しやすく、釉薬処理、すなわち絵付は処理
はできるだけ低い温度で行なうことが必要であり、具体
的には少くとも基材の軟化変形温度以下で行なう必要が
ある。In the case of artificial tooth crowns (castable crowns) made of rhusium phosphate crystallized glass and manufactured using the casting method,
Firing at high temperatures tends to cause softening and deformation or damage due to thermal shock, so glazing, or painting, must be done at as low a temperature as possible, specifically at least below the softening and deforming temperature of the base material. There is a need.
その際、キャスタブル・クラウンと釉薬の熱膨張係数は
マツチングしていることが重要であり、例えば４，０〜
１００ Ｘ １Ｇ″″’／’Ｃ（３０〜３８０℃）の範
囲で適宜選択できるものが好ましい。At that time, it is important that the thermal expansion coefficients of the castable crown and glaze are matched, for example 4.0~
It is preferable that the temperature can be appropriately selected within the range of 100 x 1 G''''/'C (30 to 380°C).
一方、釉薬を焼成したあとの被覆は、化学的耐久性と口
腔内長期安定性が良好で、かつ適当な機械的強度を有す
ることが必要である。化学的耐久性は、液浸による重量
減で評価され１例えば耐酸性・耐アルカリ性・耐水性な
どに優九でいることが必要である。On the other hand, the coating after firing the glaze needs to have good chemical durability and long-term stability in the oral cavity, as well as appropriate mechanical strength. Chemical durability is evaluated by the weight loss due to liquid immersion, and it is necessary to have excellent acid resistance, alkali resistance, water resistance, etc., for example.
本発明においては、以上の観点から釉薬の構成成分を化
学的耐久性に優れるＳｉｎ、とＢ！０３を主成分とした
ホウケイ酸ガラスに求め、化学耐久性、軟比特性、ガラ
スの溶解性（釉薬焼成時の各成分の溶解性）、熱膨張特
性を加味して次の基本組成を得た。In the present invention, from the above viewpoint, the constituent components of the glaze are Sin, which has excellent chemical durability, and B! The following basic composition was obtained by considering chemical durability, soft ratio properties, glass solubility (solubility of each component during glaze firing), and thermal expansion properties. .
即ち、本発明の人工歯用釉薬組成物の基本組成は、
Ｓｉｎ、 ・・・・・・・・・・・・・・・ ５５
〜７０重量％Ｂ２Ｏ３・・・・・・・・・・・・・・・
０．１〜２５重量％Ａｆｆｉ、Ｏ，・・・・・・・・
・・・・・・・ ２〜１０重量％Ｎａ、０ ・・・・
・・・・・・・・・・・ ０．１〜１０重量％に２０
・・・・・・・・・・・・・・・ ０．１〜１０重量
％からなるものである。That is, the basic composition of the glaze composition for artificial teeth of the present invention is: Sin, 55
~70% by weight B2O3・・・・・・・・・・・・・・・
0.1-25% by weight Affi, O,...
・・・・・・2～10wt% Na, 0 ・・・・・・
・・・・・・・・・・・・ 20 to 0.1 to 10% by weight
・・・・・・・・・・・・・・・ It consists of 0.1 to 10% by weight.
なお、前記の組成割合は、次の点を考慮して決めたもの
である。Note that the above composition ratio was determined in consideration of the following points.
（ｉ ） Ｓｉｎ、成分は、多量に用いるとガラス（
釉薬の焼成後に形減されるガラス質状のもののこと。(i) Sin, the component, when used in large quantities, produces glass (
A vitreous substance that is reduced in shape after the glaze is fired.
以下同じ）の溶解性を悪くし、溶解温度を高くしてしま
う、また少量だと化学的耐久性が急激に悪化する。The same applies hereafter)), which impairs the solubility and raises the melting temperature, and in small amounts, the chemical durability deteriorates rapidly.
（ｎ） ａ、ｏ、成分は、多量に用いるとホウ酸の揮
発が激しくなり、化学的耐久性が悪くなる。また少量だ
と粘性が上昇してしまい軟化特性が悪化する。(n) When a, o, and components are used in large amounts, boric acid volatilizes violently and chemical durability deteriorates. Moreover, if the amount is small, the viscosity will increase and the softening properties will deteriorate.
（ｉｉｉ）Ａ６０３成分は、多量に用いると溶解性を低
下させ、また少量だと化学的耐久性が悪くなる。(iii) If the A603 component is used in a large amount, the solubility will decrease, and if it is used in a small amount, the chemical durability will deteriorate.
（ｔｖ） Ｎａ、０． Ｋ、０成分は、 （Ｓｉｎ
、 ＋ Ｂｌ ｏｇ ）との比により熱膨張係数（α）
を変えることができるが、１０％以上だと化学的耐久性
を悪化させる。(tv) Na, 0. The K, 0 component is (Sin
, +Blog), the coefficient of thermal expansion (α)
However, if it exceeds 10%, chemical durability will deteriorate.
また少量だと溶解性や軟化特性を悪くする。Moreover, if it is used in a small amount, the solubility and softening properties will deteriorate.
本発明は、前記した基本組成にかえて種々の変更が可能
で、ある１例えば、
（イ） ＺｎＯを１０％まで添加することにより化学
的耐久性、軟化特性を改善することができる。In the present invention, various changes can be made to the basic composition described above. For example, (a) chemical durability and softening properties can be improved by adding up to 10% of ZnO.
（ロ） ＢａＯを１０％まで添加することにより溶解
性。(b) Solubility by adding up to 10% BaO.
化学的耐久性を改善することができる。Chemical durability can be improved.
（ハ） Ｌｉ、０ｔｔ１０％まで添加することにより
、 Ｓｉｎ。(c) By adding Li up to 0tt10%, Sin.
成分の溶解性を助けたり、軟化特性や熱膨張率を制御す
ることができる。It can aid in component solubility and control softening properties and coefficient of thermal expansion.
（ニ） Ｔｉｅ、を５％まで添加することにより軟化
特性を改善することができる。(iv) The softening properties can be improved by adding up to 5% of Tie.
（ホ） ＺｒＯ，を５％まで添加することにより、化
学的耐久性を改善することができる。(e) Chemical durability can be improved by adding up to 5% of ZrO.
さらに本発明においては、前記基本組成の釉薬組成物に
対し、一定割合の長石系結晶を用いることにより軟化変
形温度が結晶化ガラス系よりも高く、かつ膨張係数が比
較的大きい陶材やメタルボンド（金属と陶材の複合体）
人工歯に有用な釉薬組成物とすることができる０例えば
、前記基本組成の釉薬組成物を５０〜８０重量部、長石
系結晶を５０〜２０重量部配合（全体を１００重量部）
することにより、熱膨張係数１３０〜ｉｓｏ ｘ ｉｏ
−’／’ｃ （長石系結晶無配合のもの４Ｏ−１００Ｘ
ＩＯ″″７／℃）の釉薬を調製することができる。Furthermore, in the present invention, by using a certain proportion of feldspathic crystals in the glaze composition having the above-mentioned basic composition, the softening deformation temperature is higher than that of crystallized glass, and the porcelain and metal bonds have a relatively large coefficient of expansion. (Composite of metal and porcelain)
For example, 50 to 80 parts by weight of the glaze composition having the above basic composition and 50 to 20 parts by weight of feldspar crystals (total 100 parts by weight) can be used as a glaze composition useful for artificial teeth.
By doing so, the coefficient of thermal expansion is 130~iso x io
-'/'c (without feldspar crystals 4O-100X
A glaze of IO″″7/°C) can be prepared.
以上に説明した本発明の釉薬組成物には、必要により着
色剤を配合することができる０例えば、Ｖ、 Ｃｒ、
Ｍｎ、 Ｆａ、 Ｃｏ、 Ｎｉ、 Ｃｕ、 Ａｇ、 Ａ
ｕ、 Ｃｅ、 Ｎｄ等の金属酸化物系着色剤あるいは金
属酸化物スピネル系着色剤を添加することができる。し
かしながら着色剤を用いる場合、その量が少ない場合は
着色剤としての効果が得られず、また多い場合は色調が
濃くなりすぎて生体歯牙の色調とかけ離れてしまうので
注意を要する。The glaze composition of the present invention described above may contain a coloring agent if necessary. For example, V, Cr,
Mn, Fa, Co, Ni, Cu, Ag, A
A metal oxide coloring agent such as u, Ce, or Nd or a metal oxide spinel coloring agent can be added. However, when using a coloring agent, care must be taken because if the amount is small, the effect as a coloring agent will not be obtained, and if the amount is large, the color tone will be too dark and will differ from the color tone of living teeth.
なお１本発明においては当業界において通常着色助剤と
して用いられているＡｌ１，０． 、 Ｓｉｎ、などは
前記したように基本組成に含まれているので強いて添加
する必要はない。In addition, in the present invention, Al1,0. , Sin, etc. are included in the basic composition as described above, so there is no need to forcefully add them.
本発明において、前記した人工歯用釉薬組成物を構成す
る各成分は、原料調合され、溶融（１５００℃、４時間
）、水砕又はフィルム成形、ボールミルによる粉砕１分
級（２８０メツシユ）、顔料や分散媒体の混２合、など
を通じて最終的に釉薬の塗布用ペーストにされ、各種人
工歯上に適用される。In the present invention, each component constituting the above-mentioned glaze composition for artificial teeth is prepared by mixing raw materials, melting (1500°C, 4 hours), pulverizing with water or film forming, pulverizing with a ball mill (1 class (280 meshes)), pigments, etc. Through mixing with a dispersion medium, etc., it is finally made into a paste for glazing, which is then applied to various types of artificial teeth.
（実施例）
次に、本発明を実施例により更に詳しく説明するが、本
発明はこれら実施例のものに限定されるものではなく、
当業者によるあらゆる変形、変質をも包括するものであ
る。(Examples) Next, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited to these Examples.
It also includes all modifications and alterations made by those skilled in the art.
実施例１〜８
下記第１表に示される原料を用いて釉薬用ペーストを調
製した。Examples 1 to 8 Glaze pastes were prepared using the raw materials shown in Table 1 below.
即ち、第１表に記載の原料を白金るつぼを用いて電気炉
で１５００℃に４時間溶融して均一なガラスとした。That is, the raw materials listed in Table 1 were melted in an electric furnace at 1500° C. for 4 hours using a platinum crucible to obtain a uniform glass.
次にこれを水砕、乾燥し、所望の粒径になるまでボール
ミルで粉砕し、２８０メツシユのふるいで分級した。Next, this was crushed, dried, ground in a ball mill until the desired particle size was obtained, and classified using a 280-mesh sieve.
分級したガラス粉末ニＺｒＯ，、Ｔ１０２ｅ ＶｘＯｓ
を主成分とする着色剤を１０％添加するとともにグリセ
リンで練和し、釉薬のペースト状物を得た。Classified glass powder ZrO, T102e VxOs
A glaze paste was obtained by adding 10% of a coloring agent containing as a main component and kneading with glycerin.
該ペーストを、熱膨張係数が約６０Ｘ１０″”／’Ｃの
リン酸力ルシュウム系結晶化ガラス歯冠（実施例１．２
，３．６）、熱膨張係数が約ｇｏ ｘ １０−’／’Ｃ
のマイカ系結晶化ガラス歯冠（実施例４）、熱膨張係数
が約１００Ｘ １０−’／’Ｃのリン酸力ルシュウム系
結晶化ガラス歯冠（実施例５）、及び陶材系又はメタル
ボンド歯冠（実施例７，８）にそれぞれ塗布し、第１表
に記載の条件で焼成した。The paste was applied to a lucium phosphate-based crystallized glass tooth crown (Example 1.2
, 3.6), the coefficient of thermal expansion is approximately go x 10-'/'C
A mica-based crystallized glass tooth crown (Example 4), a lucium phosphate crystallized glass tooth crown with a thermal expansion coefficient of about 100X 10-'/'C (Example 5), and a porcelain-based or metal bond It was applied to each tooth crown (Examples 7 and 8) and fired under the conditions listed in Table 1.
例えば、実施例３のペーストを重量％でＳｉＯ□５０、
Ｐ、０．７． Ａｎ、０．１８． Ｍｇ０５．
ＣａＯ１４，Ｌｉ、０３、ＴｉＯ，３からなり、熱膨張
係数が６０ Ｘ １０−’／’Ｃのリン酸力ルシュウム
系結晶化ガラス歯冠に塗布し、これを陶材焼成炉（ポー
セレンファーネス）を用いて８００＠で焼成したところ
、天然歯と同様の光沢及び色調を呈した審美性に優れた
人工歯冠を得ることができた。また結晶化ガラス基材と
釉薬層とは強固に密着し、剥離やクラックの発生はなか
った。第１表に各釉薬の密度、熱膨張係数及び焼成温度
をあわせて示す。For example, the paste of Example 3 was SiO□50 in weight percent,
P, 0.7. An, 0.18. Mg05.
It is made of CaO14, Li, 03, TiO, 3, and is coated on a lucium phosphate crystallized tooth crown with a coefficient of thermal expansion of 60 x 10-'/'C, and then heated in a porcelain furnace. When fired at 800@, it was possible to obtain an aesthetically superior artificial tooth crown that had the same gloss and color as a natural tooth. Further, the crystallized glass base material and the glaze layer were firmly adhered to each other, and no peeling or cracking occurred. Table 1 also shows the density, thermal expansion coefficient, and firing temperature of each glaze.
第 １ 表
の長石系結晶
〔発明の効果〕
本発明の人工歯用釉薬組成物は、低温度で焼成すること
ができるとともに、熱膨張係数を広い範囲に調整するこ
とができるため、次のような直接的あるいは間接的な効
果がある；
（ｉ） 被着色物である結晶化ガラス系、陶材系。Table 1 Feldspar crystals [Effects of the invention] The glaze composition for artificial teeth of the present invention can be fired at a low temperature and the coefficient of thermal expansion can be adjusted within a wide range. (i) Crystallized glass-based and porcelain-based materials to be colored.
メタルボンド系などの人工歯の釉薬焼成時の熱による変
形や 変質を防止することができる。It can prevent deformation and deterioration due to heat during glaze firing of artificial teeth such as metal bond type.
（…） カラーリング焼成工程における昇温、冷却時の
熱衝撃が緩和される。(...) Thermal shock during heating and cooling during the coloring firing process is alleviated.
（ｉｎ） 各種の人工歯゛の基材と釉薬層は強固に密
着し１両者の間に剥離やクラックを発生させない。(in) The base material and glaze layer of various artificial teeth are firmly adhered to each other, and no peeling or cracking occurs between the two.
（ｔｖ） カラーリング時間を短縮することができる
。(tv) Coloring time can be shortened.
（ｖ） 焼成炉の長寿命化、劣化防止を図ることがで
きる。(v) It is possible to extend the life of the kiln and prevent deterioration.
Claims (1)
成物の構成成分と組成割合（重量％）が、ＳｉＯ＿２・
・・・・・・・・・・・・・・５５〜７０％Ｂ＿２Ｏ＿
３・・・・・・・・・・・・・・・０．１〜２５％Ａｌ
＿２Ｏ＿３・・・・・・・・・・・・・・・２〜１０％
Ｎａ＿２Ｏ・・・・・・・・・・・・・・・０．１〜１
０％Ｋ＿２Ｏ・・・・・・・・・・・・・・・０．１〜
１０％であることを特徴とする人工歯用釉薬組成物。 ２、釉薬組成物の熱膨張係数が４０〜１００×１０＾−
＾７／℃（３０〜３８０℃）、ガラス転移温度（Ｔｇ）
が４００〜５５０℃である請求項１記載の人工歯用釉薬
組成物。 ３、人工歯科に適用する釉薬組成物において、前記釉薬
組成物が請求項１記載の釉薬組成物５０〜８０重量部及
び長石系結晶５０〜２０重量部から成るものであること
を特徴とする人工歯用釉薬組成物。 ４、釉薬組成物に金属酸化物系着色剤あるいは金属酸化
物スピネル系着色剤を１〜２０重量％添加したものであ
る請求項１〜３のいずれか１つに記載の人工歯用釉薬組
成物。[Claims] 1. In a glaze composition applied to artificial teeth, the constituent components and composition ratio (wt%) of the glaze composition are SiO_2.
・・・・・・・・・・・・・・・55～70%B_2O_
3・・・・・・・・・・・・・・・0.1~25%Al
_2O_3・・・・・・・・・・・・2～10%
Na_2O・・・・・・・・・・・・0.1～1
0%K_2O・・・・・・・・・・・・0.1～
A glaze composition for artificial teeth, characterized in that the glaze composition is 10%. 2. The thermal expansion coefficient of the glaze composition is 40 to 100 x 10^-
^7/℃ (30-380℃), glass transition temperature (Tg)
The glaze composition for artificial teeth according to claim 1, wherein the temperature is 400 to 550°C. 3. A glaze composition applied to artificial dentistry, characterized in that the glaze composition comprises 50 to 80 parts by weight of the glaze composition according to claim 1 and 50 to 20 parts by weight of feldspar crystals. Tooth glaze composition. 4. The glaze composition for artificial teeth according to any one of claims 1 to 3, wherein 1 to 20% by weight of a metal oxide colorant or a metal oxide spinel colorant is added to the glaze composition. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63036507A JPH01212248A (en) | 1988-02-20 | 1988-02-20 | Glaze composition for artificial tooth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63036507A JPH01212248A (en) | 1988-02-20 | 1988-02-20 | Glaze composition for artificial tooth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01212248A true JPH01212248A (en) | 1989-08-25 |
Family
ID=12471743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63036507A Pending JPH01212248A (en) | 1988-02-20 | 1988-02-20 | Glaze composition for artificial tooth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01212248A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0468435A2 (en) * | 1990-07-24 | 1992-01-29 | DENTSLPLY GmbH | Dental ceramic composition for titanium prostheses |
| JPH04257508A (en) * | 1990-10-03 | 1992-09-11 | Ducera Dental Gmbh | Ceramic processing material for preconditioning of artificial metal tooth |
| EP0759289A2 (en) * | 1995-08-18 | 1997-02-26 | American Thermocraft Corp. | Porcelain coating compositions for low expansion porcelain cores and the resulting all-ceramic dental restorations |
| WO1997045377A1 (en) * | 1996-05-29 | 1997-12-04 | Springbok Dental Handelsgesellschaft Mbh | Silicate glass composition and process for modification of ceramic materials |
| EP0885606A2 (en) * | 1997-06-12 | 1998-12-23 | Ivoclar Ag | Alkali-silicate glass |
| US6121175A (en) * | 1997-06-12 | 2000-09-19 | Ivoclar Ag | Alkali silicate glass |
| JP2003503430A (en) * | 1999-07-02 | 2003-01-28 | ジェネリック／ペントロン インコーポレイテッド | Porcelain compositions for low expansion all porcelain cores and alloys |
| JP2016108173A (en) * | 2014-12-03 | 2016-06-20 | クラレノリタケデンタル株式会社 | Glass material and dental prosthesis |
| DE102017204015A1 (en) | 2017-03-10 | 2018-09-13 | Schott Ag | Glass frit, enamel composition and method of making enamelled glass ceramic articles and their use |
| JP2019127429A (en) * | 2018-01-26 | 2019-08-01 | 株式会社松風 | Low melting point glass composition having excellent water resistance |
| EP3733617B1 (en) | 2019-05-03 | 2022-05-18 | VITA-ZAHNFABRIK H. Rauter GmbH & Co. KG | Low-melting glass ceramic |
| JP2022130523A (en) * | 2018-01-26 | 2022-09-06 | 株式会社松風 | Low-melting-point glass composition with excellent water resistance |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5331716A (en) * | 1976-09-03 | 1978-03-25 | Wada Seimitsu Shiken | Enamel for dentist |
| JPS59195551A (en) * | 1983-03-09 | 1984-11-06 | セラムコ インコーポレーテツド | Dental semitransparent glaze composition |
-
1988
- 1988-02-20 JP JP63036507A patent/JPH01212248A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5331716A (en) * | 1976-09-03 | 1978-03-25 | Wada Seimitsu Shiken | Enamel for dentist |
| JPS59195551A (en) * | 1983-03-09 | 1984-11-06 | セラムコ インコーポレーテツド | Dental semitransparent glaze composition |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0468435A2 (en) * | 1990-07-24 | 1992-01-29 | DENTSLPLY GmbH | Dental ceramic composition for titanium prostheses |
| JPH04257508A (en) * | 1990-10-03 | 1992-09-11 | Ducera Dental Gmbh | Ceramic processing material for preconditioning of artificial metal tooth |
| EP0759289A3 (en) * | 1995-08-18 | 2000-04-26 | American Thermocraft Corp. | Porcelain coating compositions for low expansion porcelain cores and the resulting all-ceramic dental restorations |
| EP0759289A2 (en) * | 1995-08-18 | 1997-02-26 | American Thermocraft Corp. | Porcelain coating compositions for low expansion porcelain cores and the resulting all-ceramic dental restorations |
| WO1997045377A1 (en) * | 1996-05-29 | 1997-12-04 | Springbok Dental Handelsgesellschaft Mbh | Silicate glass composition and process for modification of ceramic materials |
| US6306784B1 (en) * | 1997-06-12 | 2001-10-23 | Ivoclar Ag | Alkali silicate glass |
| EP0885606A3 (en) * | 1997-06-12 | 1999-07-28 | Ivoclar Ag | Alkali-silicate glass |
| US6121175A (en) * | 1997-06-12 | 2000-09-19 | Ivoclar Ag | Alkali silicate glass |
| EP0885606A2 (en) * | 1997-06-12 | 1998-12-23 | Ivoclar Ag | Alkali-silicate glass |
| JP2003503430A (en) * | 1999-07-02 | 2003-01-28 | ジェネリック／ペントロン インコーポレイテッド | Porcelain compositions for low expansion all porcelain cores and alloys |
| EP2087877A1 (en) * | 1999-07-02 | 2009-08-12 | Pentron Ceramics, Inc. | Porcelain compositions for low expansion all-porcelain cores and alloys |
| JP4716633B2 (en) * | 1999-07-02 | 2011-07-06 | ジェネリック／ペントロン インコーポレイテッド | Porcelain composition for low expansion all porcelain cores and alloys |
| JP2016108173A (en) * | 2014-12-03 | 2016-06-20 | クラレノリタケデンタル株式会社 | Glass material and dental prosthesis |
| DE102017204015A1 (en) | 2017-03-10 | 2018-09-13 | Schott Ag | Glass frit, enamel composition and method of making enamelled glass ceramic articles and their use |
| JP2019127429A (en) * | 2018-01-26 | 2019-08-01 | 株式会社松風 | Low melting point glass composition having excellent water resistance |
| KR20190091206A (en) * | 2018-01-26 | 2019-08-05 | 소후 인코포레이티드 | Low melting point glass composition excellent in water resistance |
| JP2022130523A (en) * | 2018-01-26 | 2022-09-06 | 株式会社松風 | Low-melting-point glass composition with excellent water resistance |
| EP3733617B1 (en) | 2019-05-03 | 2022-05-18 | VITA-ZAHNFABRIK H. Rauter GmbH & Co. KG | Low-melting glass ceramic |
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