JPH01185272A - Manufacture of racket frame or stick - Google Patents

Manufacture of racket frame or stick

Info

Publication number
JPH01185272A
JPH01185272A JP63009238A JP923888A JPH01185272A JP H01185272 A JPH01185272 A JP H01185272A JP 63009238 A JP63009238 A JP 63009238A JP 923888 A JP923888 A JP 923888A JP H01185272 A JPH01185272 A JP H01185272A
Authority
JP
Japan
Prior art keywords
mold
hand
resin
thermoplastic resin
reinforcing continuous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63009238A
Other languages
Japanese (ja)
Inventor
Motozumi Kitayama
北山 素純
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP63009238A priority Critical patent/JPH01185272A/en
Publication of JPH01185272A publication Critical patent/JPH01185272A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To enhance productivity of the racket frame or stick stated in the caption and improve reduction of weight, rigidity and strength thereof in a slim configuration by setting a core covered with reinforcing continuous fibers in a metallic mold, injecting or extruding preheated and molten thermoplastic resin through an injection port provided on the metallic mold and hardening and taking the resin out of the mold. CONSTITUTION:A plurality of reinforcing continuous fiber layer 2 are spread along the outer periphery of a core 1, then the core 1 covered with the reinforcing continuous fiber layers 2 is set in a metallic mold 3. The metallic mold 3 consists of a left-hand metallic mold 31 and a right-hand metallic mold 32 and both right and left-hand molds 32, 31 are constructed to be capable of being opened and closed. The left-hand mold 31 and the right-hand mold 32 are closed and thermoplastic resin preheated and molten in a cylinder 5 is injected or extruded in the mold through an injection port 4 provided on the right-hand mold 32, then cooled and taken out of the mold. The thermoplastic resin is either one of such substances as a homopolymer of polyphenylene oxide or a blend consisting of nylon and polystylenic resin, or liquid crystal polymer, polycarbonate, acetal resin or terpolymer composed of acrylonitrile-butadiene-stylene and so forth.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、テニス、バドミントン、スカッシュ、ラケ
ットボール等のラケットフレーム、更にはゲートボール
用のスティック等の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for manufacturing racket frames for tennis, badminton, squash, racquetball, etc., and furthermore, sticks for gateball.

〔従来の技術〕[Conventional technology]

従来、例えばテニスのラケットフレームでは、スィート
エリアを広くし、ボールのコントロールを高めるために
フレーム面積を大きくする必要が生じ、そのためフレー
ムの材質強度が高く、軽量であるという要望を満たすも
のとして、繊維強化のプラスチックス(FRP)を使用
したラケットフレームが製造されている。FRPを使用
したラケットフレームは、軽量化並びに大型化を図るの
に都合が良く、しかも設計の自由度が大きい。FRP製
ラケットフレームの製造方法としては、熱硬化性樹脂を
含浸した補強繊維を半硬化状態にした所謂プリプレグを
発泡体又はチューブ等の芯材の外周に多数枚積層し、金
型内で加熱硬化する方法や予め外周に補強繊維を被覆し
た芯材を金型内にセントした後、金型を閉じ金型に取付
けられた注入口より熱硬化性樹脂を注入し、加熱硬化す
る方法や、予め芯材の外周に被覆した補強繊維に熱硬化
性樹脂を含浸し、金型内で加熱硬化する方法又はこれら
を組合せた方法、更には補強用短繊維又は長繊維を含有
する熱可塑性樹脂のベレット等を予熱、射出、冷却、脱
型する方法等が知られている(特開昭61−45780
号公報、特開昭61−45782号公報、特開昭61−
167513号公報)。
Conventionally, for example, in tennis racket frames, it was necessary to increase the frame area in order to widen the sweet area and improve control of the ball, so fiber was used as a material to meet the demands for a frame with high strength and light weight. Racket frames are manufactured using reinforced plastics (FRP). A racket frame using FRP is convenient for reducing weight and increasing size, and has a large degree of freedom in design. The manufacturing method for FRP racket frames involves laminating a large number of so-called prepregs, which are semi-hardened reinforcing fibers impregnated with thermosetting resin, around the outer periphery of a core material such as a foam or tube, and then heating and hardening them in a mold. There are two methods: a core material whose outer periphery is coated with reinforcing fibers is placed in a mold, the mold is closed, a thermosetting resin is injected through an injection port attached to the mold, and the thermosetting resin is heated and cured; A method in which reinforcing fibers coated around the outer periphery of a core material are impregnated with a thermosetting resin and heated and cured in a mold, or a combination of these methods, and a thermoplastic resin pellet containing reinforcing short fibers or long fibers. Methods of preheating, injection, cooling, demolding, etc. are known (Japanese Patent Laid-Open No. 61-45780
JP-A-61-45782, JP-A-61-
167513).

〔解決しようとする課題〕[Problem to be solved]

従来のFRP製ラケットフレームの製造方法のうち、熱
硬化性樹脂を用いる方法では、加熱硬化に多大の時間を
要する点に問題がある。その対策の1つとしては、熱硬
化性樹脂の硬化時間の短縮化があるが、その場合には、
プリプレグの保存保証期間(シェルライフ)が短く、ゲ
ルタイムが短くなるという問題が生じていた。別の対策
としては、脱型し得るだけの短時間で加熱硬化し、脱型
後オーブン等で後硬化(ポストキュア)するという金型
使用サイクルを早める方法があるが、その場合にも多少
金型内での加熱時間は短(なるものの、後硬化の時間も
含めて大きな効果は期待できないものであった。
Among conventional methods for manufacturing FRP racket frames, methods using thermosetting resins have a problem in that heating and curing takes a long time. One of the countermeasures is to shorten the curing time of thermosetting resin, but in that case,
There has been a problem that the shelf life (shell life) of prepreg is short and the gel time is short. Another countermeasure is to speed up the mold usage cycle by heating and curing in a short time that allows demolding, and post-curing in an oven after demolding. Although the heating time in the mold was short, no significant effect could be expected due to the post-curing time.

一方、補強用短繊維又は長繊維を含有する熱可塑性樹脂
のベレット等を予熱、射出、冷却、脱型する方法の場合
には、成形時間は大幅に短縮できるが、FRPとしての
剛性、強度が非常に低いためにラケットに必要な剛性、
強度を発現させるには、厚肉にせざるを得す、最近のラ
ケットの傾向であるスリムな形状で軽量のラケットとい
う要望に応じられないという問題があった。
On the other hand, in the case of a method of preheating, injecting, cooling, and demolding thermoplastic resin pellets containing reinforcing short fibers or long fibers, the molding time can be significantly shortened, but the rigidity and strength of FRP are reduced. The stiffness required for the racket, due to very low
In order to develop strength, the wall must be made thicker, and there was a problem in that it could not meet the recent trend in rackets, which is the desire for slim-shaped and lightweight rackets.

そこで、この発明は、熱硬化性樹脂を用いた場合に生ず
るFRPの長時間硬化性の問題及び短繊維又は長繊維を
含有する熱可塑性樹脂を用いた場合に生ずるFRPの低
剛性、低強度の問題を解決し、生産性並びにスリムな形
状で高剛性、高強度の軽量ラケットフレーム又はゲート
ボール等に使用されるスティックの製造方法を提供する
ことを目的とする。
Therefore, this invention addresses the problem of long-term curing of FRP that occurs when thermosetting resin is used, and the low rigidity and low strength of FRP that occurs when thermoplastic resin containing short fibers or long fibers is used. The purpose of the present invention is to solve the problems and provide a method for manufacturing a lightweight racket frame or a stick used for gateball, etc., which has high productivity, slim shape, high rigidity, and high strength.

〔課題を解決するための手段〕[Means to solve the problem]

上述の目的を達成するため、この発明は、芯材の外周に
補強用連続繊維の層を被覆する工程と、補強用連続繊維
が被覆された芯材を金型内にセットする工程と、金型を
閉じ金型に取付けられた注入口より予熱・融解された熱
可塑性樹脂を射出又は押出す工程と、金型内の熱可塑性
樹脂を冷却させて硬化させ、脱型する工程とから成るも
のである。
In order to achieve the above-mentioned object, the present invention includes a step of coating the outer periphery of a core material with a layer of reinforcing continuous fibers, a step of setting the core material covered with the reinforcing continuous fibers in a mold, and a step of covering the outer periphery of a core material with a layer of reinforcing continuous fibers, A process consisting of the process of closing the mold and injecting or extruding the preheated and melted thermoplastic resin from an injection port attached to the mold, and the process of cooling and hardening the thermoplastic resin in the mold and removing it from the mold. It is.

〔作用〕[Effect]

この発明においては、熱硬化性樹脂のFRPを使用しな
いために長時間硬化性に関する問題はなくなり、短繊維
又は長繊維を含有する熱可塑性樹脂FRPを使用しない
ためにスリムな形状で軽量化を図ったときに低剛性、低
強度の問題がなくなり、生産性並びにスリムな形状で軽
量性、剛性、強度を向上させたラケットフレーム、ステ
ィックを得ることが可能となる。
In this invention, since the thermosetting resin FRP is not used, there is no problem regarding long-term hardening, and since the thermoplastic resin FRP containing short fibers or long fibers is not used, the slim shape and weight reduction are achieved. This eliminates the problems of low rigidity and low strength, and makes it possible to obtain racket frames and sticks with improved productivity, slim shape, light weight, rigidity, and strength.

〔実施例〕〔Example〕

以下に、この発明の好適な実施例を図面を参照しつつ説
明する。
Preferred embodiments of the present invention will be described below with reference to the drawings.

まず、第1図に示すように芯材1の外周に補強用連続繊
維層2を複数層被覆し、次いで第2図に示すように補強
用連続繊維層2が被覆された芯材1を金型3内にセット
する。金型3は、左金型3■と右金型32とから構成し
てあり、左右の金型31及び32は開閉可能に構成しで
ある。左金型31と右金型32とを閉じ、右金型32に
取付けられた注入口4からシリンダ5内で予熱、融解さ
れた熱可塑性樹脂を射出又は押出した後に冷却、脱型す
る。
First, as shown in FIG. 1, the outer periphery of the core material 1 is covered with a plurality of reinforcing continuous fiber layers 2, and then, as shown in FIG. Set in mold 3. The mold 3 is composed of a left mold 3 and a right mold 32, and the left and right molds 31 and 32 are configured to be openable and closable. The left mold 31 and the right mold 32 are closed, and the thermoplastic resin preheated and melted in the cylinder 5 is injected or extruded from the injection port 4 attached to the right mold 32, and then cooled and demolded.

芯材1としては、合成樹脂発泡体、例えば比重が0.0
4〜0.1のポリウレタンフォーム、アクリルフオーム
等或いは合成樹脂又はエラストマー製のチューブ等が使
用される。
As the core material 1, a synthetic resin foam, for example, a specific gravity of 0.0 is used.
4 to 0.1 polyurethane foam, acrylic foam, or a tube made of synthetic resin or elastomer is used.

また、補強用連続繊維層2としては、ガラス、カーボン
、ケブラー(アラミド)、ボロン、炭化珪素、セラミッ
ク、アルミナ等の繊維を単独又は複数組合せて使用可能
である。これらの連続繊維を織物(クロス)や編み物に
ット)やm′1Ji(ブレード)或いはノンウーブン一
方向引揃え(UD)繊維等が単独又は複数組合せの形態
で使用される。
Further, as the reinforcing continuous fiber layer 2, fibers such as glass, carbon, Kevlar (aramid), boron, silicon carbide, ceramic, alumina, etc. can be used alone or in combination. These continuous fibers may be used singly or in combinations of woven (cloth), knitted (knit), m'1Ji (braid), non-woven unidirectionally aligned (UD) fibers, and the like.

芯材1の外周に被覆され、金型3内にセットされた状態
の補強用連続繊維層2にはまだ樹脂は含浸されていない
。芯材1の外周に補強用連続繊維層2を被覆する手段と
しては、第3図に示すように、使用可能な補強用連続繊
維21を複数のボビン5に巻取り、ブレーダ−(編上機
)にセットし、予め1.6mの長さに裁断した芯材1に
補強用連続繊維21を編み上げる。また、別の被覆手段
としては、第4図に示すように、補強用連続繊維を編ん
だものや織ったもの或いは所々高分子材料のテープ又は
接着剤で固定することにより得られる一方向シート状に
引揃えたもの(U D)等22で芯材1をぐるぐる巻い
ていく。更に別の被覆手段としては、第5図に示すよう
に、予め補強用連続繊維でチューブ状物23を作成して
おき、このチューブ状物23に芯材1を挿入しても良い
The reinforcing continuous fiber layer 2 coated on the outer periphery of the core material 1 and set in the mold 3 is not yet impregnated with resin. As shown in FIG. 3, as a means for covering the outer periphery of the core material 1 with the reinforcing continuous fiber layer 2, usable reinforcing continuous fibers 21 are wound around a plurality of bobbins 5, and a braider (knitting machine) is used. ), and the reinforcing continuous fibers 21 are knitted onto the core material 1 which has been cut into a length of 1.6 m in advance. In addition, as another covering means, as shown in Fig. 4, a unidirectional sheet-like material obtained by knitting or weaving reinforcing continuous fibers, or fixing in places with polymer material tape or adhesive is available. Wrap the core material 1 around the core material 1 with a piece (UD) etc. 22 that are aligned. As another covering means, as shown in FIG. 5, a tube-shaped article 23 may be prepared in advance from reinforcing continuous fibers, and the core material 1 may be inserted into this tube-shaped article 23.

金型3に補強用連続繊維層2が被覆された芯材1をセン
トするには、金型3のキャビティに沿った形状に芯材1
を折り曲げ、更に必要ならば折り曲げられて形づくられ
たフレームの必要個所に補強用連続繊維N2を部分的に
付加しても良い。補強用連続繊維層2で被覆された芯材
1を金型3内にセットした後に金型3を閉じ、金型3に
取付けられた注入口4からシリンダ5内で予熱、融解さ
れた熱可塑性樹脂を射出又は押出すことにより樹脂が金
型3内に行きわたり、樹脂が補強用連続繊維層2に含浸
した後、冷却、脱型する。このとき、樹脂の冷却工程の
前に内圧をかけることにより均一な厚みの樹脂層と、表
面にボイド、ひけのない成形品を得ることができる。内
圧をかける方法としては、芯材1に発泡性芯材を使用す
る方法や合成樹脂又はエラストマー製のチューブをエア
ーで膨張させる方法等が採用可能である。
To insert the core material 1 coated with the reinforcing continuous fiber layer 2 into the mold 3, insert the core material 1 into the mold 3 in a shape that follows the cavity of the mold 3.
, and if necessary, reinforcing continuous fibers N2 may be partially added to the necessary portions of the bent frame. After the core material 1 covered with the reinforcing continuous fiber layer 2 is set in the mold 3, the mold 3 is closed, and the preheated and melted thermoplastic is poured into the cylinder 5 through the injection port 4 attached to the mold 3. By injecting or extruding the resin, the resin is spread throughout the mold 3, and after impregnating the reinforcing continuous fiber layer 2 with the resin, it is cooled and demolded. At this time, by applying internal pressure before the resin cooling step, it is possible to obtain a resin layer with a uniform thickness and a molded product with no voids or sink marks on the surface. As a method of applying internal pressure, a method of using a foamable core material for the core material 1, a method of expanding a synthetic resin or elastomer tube with air, etc. can be adopted.

注入口4から金型3内に注入する熱可塑性樹脂としては
、ポリフェニレンオキシドのホモポリマー又はナイロン
やポリスチレン系樹脂とのブレンド(アロイ)或いは液
晶ポリマー、ポリカーボネート、アセタール樹脂又はア
クリロニトリル・ブタジェン・スチレンの三元共重合体
等であり、薄肉部分の成形性、補強用連続繊維層2への
含浸性に優れた融解状態で低粘度の熱可塑性樹脂が望ま
しい。更には、これらの熱可塑性樹脂のペレット等の中
に補強用の短繊維や長繊維或いは充填剤等を予め含有さ
せることもできるが、融解状態での粘度を高め、薄肉部
分の成形性、補強連続繊維層2への含浸性を妨げる傾向
にあるので必ずしも好ましくない。
The thermoplastic resin injected into the mold 3 from the injection port 4 may be a homopolymer of polyphenylene oxide, a blend (alloy) with nylon or polystyrene resin, a liquid crystal polymer, polycarbonate, an acetal resin, or acrylonitrile-butadiene-styrene. It is desirable to use a thermoplastic resin that is a copolymer or the like and has a low viscosity in a molten state and is excellent in moldability of thin portions and impregnation into the reinforcing continuous fiber layer 2. Furthermore, reinforcing short fibers, long fibers, fillers, etc. can be included in advance in these thermoplastic resin pellets, etc., but this increases the viscosity in the molten state and improves the formability and reinforcement of thin parts. This is not necessarily preferable since it tends to impede impregnation into the continuous fiber layer 2.

また、補強用連続繊維層2と熱可塑性樹脂との組合せか
らなるFRPを使用した製造方法として、熱可塑性樹脂
の場合に通常行われるように補強用連続繊維に予め熱可
塑性樹脂を含浸した所謂プリプレグを芯材の外周に多数
枚積層する方法は、熱硬化性樹脂と違ってプリプレグが
非常に剛直であるために非常に困難であった。その対策
の1つとして、プリプレグを予熱・半融解状態にして剛
直性を低下させることはできても、芯材の外周に積層中
、室温近くに冷却してしまい、剛直性が回復するという
問題があり、別の対策としては、比較的融解温度、軟化
温度の低い熱可塑性樹脂を用いたプリプレグを積層作業
の限界に近い温度下で芯材の外周に複数枚積層し、金型
内で加熱成形し冷却、脱型して製品を得たが、夏季、車
のトランク内で熱せられ変形するという問題があった。
In addition, as a manufacturing method using FRP consisting of a combination of the reinforcing continuous fiber layer 2 and a thermoplastic resin, a so-called prepreg in which the reinforcing continuous fibers are pre-impregnated with a thermoplastic resin, as is usually done in the case of thermoplastic resins, is used. The method of laminating a large number of sheets around the outer periphery of a core material was extremely difficult because, unlike thermosetting resins, prepregs are extremely rigid. One solution to this problem is that even though it is possible to preheat and semi-melt the prepreg to reduce its rigidity, it cools down to near room temperature while being laminated around the outer periphery of the core material, causing the rigidity to recover. Another countermeasure is to laminate multiple sheets of prepreg made of thermoplastic resin with relatively low melting and softening temperatures around the core material at temperatures close to the limits of lamination work, and then heat them in a mold. A product was obtained by molding, cooling, and demolding, but there was a problem that it would become heated and deformed in the trunk of a car during the summer.

なお、図示する実施例では、ラケットフレームの製造に
ついて説明したが、ゲートボール等のスティックをこの
ようにして製造することも勿論可能である。
In the illustrated embodiment, the manufacturing of a racket frame has been described, but it is of course possible to manufacture a stick for gateball or the like in this manner.

〔効果〕〔effect〕

以上説明したように、この発明によれば、熱硬化性樹脂
における長時間硬化性に関する問題が解決され、短繊維
又は長繊維を含有する熱可塑性樹脂のFRPを使用しな
いためにスリムな形状で軽量にしたときの低剛性、低強
度の問題がなくなり、生産性並びにスリムな形状で軽量
性、剛性、強度を向上させることができる。また、プリ
プレグを使用したものと異なり、金型セット時に熟練者
でなくとも余裕をもってセントすることができ、セット
時に修正が必要な個所に繊維層を部分的に付加すること
もできるので、作業性並びに生産性が向上し、仕上がり
精度も優れるものである。
As explained above, according to the present invention, the problem of long-time curing in thermosetting resins is solved, and since FRP, which is a thermoplastic resin containing short fibers or long fibers, is not used, the invention has a slim shape and is lightweight. This eliminates the problems of low rigidity and low strength that occur when the product is used, and improves productivity as well as lightness, rigidity, and strength with a slim shape. In addition, unlike those using prepreg, even non-experts can easily set the mold, and fiber layers can be added partially to areas that require modification during mold setting, making work easier. In addition, productivity is improved and finishing accuracy is also excellent.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は芯材に補強用繊維層を被覆したものを示す斜視
図、第2図は第1図に示すものを金型にセントした状態
を示す斜視図、第3図は第1図に示すものを作る手段の
一例を示す説明図、第4図は第1図に示すものを作る別
の手段を示す斜視図、第5図は第1図に示すものを作る
更に別の手段を示す斜視図である。 1 ・・・芯 材、 2 ・・・補強用連続繊維層、 3 ・・・金 型、 4 ・・・注入口。 出願人 株式会社 ブリデストン 代理人 弁理士 増 1)竹 夫
Figure 1 is a perspective view showing the core material covered with a reinforcing fiber layer, Figure 2 is a perspective view showing the core material shown in Figure 1 placed in a mold, and Figure 3 is the same as Figure 1. FIG. 4 is a perspective view showing another means for making the thing shown in FIG. 1, and FIG. 5 shows still another means for making the thing shown in FIG. 1. FIG. 1...Core material, 2...Continuous fiber layer for reinforcement, 3...Mold, 4...Inlet. Applicant Brideston Co., Ltd. Agent Patent Attorney Masu 1) Takeo

Claims (1)

【特許請求の範囲】 1、芯材の外周に補強用連続繊維の層を被覆する工程と
、 補強用連続繊維が被覆された芯材を金型内にセットする
工程と、 金型を閉じ金型に取付けられた注入口より予熱融解され
た熱可塑性樹脂を射出又は押出す工程と、 金型内の熱可塑性樹脂を冷却させて硬化させ、脱型する
工程とから成るラケットフレーム又はスティックの製造
方法。
[Claims] 1. A step of coating the outer periphery of the core material with a layer of reinforcing continuous fibers, a step of setting the core material coated with the reinforcing continuous fibers in a mold, and closing the mold. Manufacturing of racket frames or sticks consists of a process of injecting or extruding preheated melted thermoplastic resin from an injection port attached to the mold, and a process of cooling and hardening the thermoplastic resin in the mold and removing it from the mold. Method.
JP63009238A 1988-01-19 1988-01-19 Manufacture of racket frame or stick Pending JPH01185272A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63009238A JPH01185272A (en) 1988-01-19 1988-01-19 Manufacture of racket frame or stick

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63009238A JPH01185272A (en) 1988-01-19 1988-01-19 Manufacture of racket frame or stick

Publications (1)

Publication Number Publication Date
JPH01185272A true JPH01185272A (en) 1989-07-24

Family

ID=11714822

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63009238A Pending JPH01185272A (en) 1988-01-19 1988-01-19 Manufacture of racket frame or stick

Country Status (1)

Country Link
JP (1) JPH01185272A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2716376A1 (en) * 1994-02-24 1995-08-25 Wilson Sporting Goods Resin transfer racket frame reinforced with continuous fibers.
WO1997036653A1 (en) * 1996-04-02 1997-10-09 Toray Industries, Inc. Frp racket and method for producing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2716376A1 (en) * 1994-02-24 1995-08-25 Wilson Sporting Goods Resin transfer racket frame reinforced with continuous fibers.
WO1997036653A1 (en) * 1996-04-02 1997-10-09 Toray Industries, Inc. Frp racket and method for producing the same
US5897447A (en) * 1996-04-02 1999-04-27 Toray Industries, Inc. FRP racket and method for producing the same

Similar Documents

Publication Publication Date Title
CA1129453A (en) Games rackets
US9333690B2 (en) Method for manufacturing a fiber-reinforced composite material
US5176868A (en) Long fiber reinforced thermoplastic frame especially for a tennis racquet
US5294139A (en) Ski
US4443507A (en) Heat-moldable laminate and process for molding said laminated structures
GB1469039A (en) Elongate composite aritcles
US5075056A (en) Process for the production of a ball game racket frame
JPH02175217A (en) Manufacture of glass fiber mat reinforced resin panel
JPH01185272A (en) Manufacture of racket frame or stick
TW201434613A (en) Method for molding hollow molding and method for manufacturing fiber reinforced plastic
JP2515222B2 (en) Racket frame
JPH0686841A (en) Golf club head and its manufacture
KR100649629B1 (en) Method for manufacturing fiber reinforced plastics product having partition wall therein, and die therefor
JP2563236B2 (en) Racket frame manufacturing method
KR20210037134A (en) Method for preparing continous fiber reinforcement plastic window
JP2996911B2 (en) Racket frame manufacturing method
JPH02180281A (en) Wooden golf club head and manufacture thereof
JPH04261678A (en) Racket frame and manufacture of the same
JPS61234882A (en) Production of racket frame and stick
JP2922253B2 (en) Golf club head for golf and manufacturing method thereof
JPH04261680A (en) Club head for golf and manufacture of the same
JPH01110376A (en) Method for manufacturing bat of fiber-reinforced plastics
JPH02180282A (en) Iron golf club head and manufacture thereof
JPH04261681A (en) Bat and manufacture of the same
KR100650171B1 (en) Method for manufacturing frame for inline skate using fiber reinforced plastics and die therefor