JPH01179A - organic platinum ink - Google Patents
organic platinum inkInfo
- Publication number
- JPH01179A JPH01179A JP62-154771A JP15477187A JPH01179A JP H01179 A JPH01179 A JP H01179A JP 15477187 A JP15477187 A JP 15477187A JP H01179 A JPH01179 A JP H01179A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- platinum
- organic
- ink
- mercaptide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims description 56
- 229910052697 platinum Inorganic materials 0.000 title claims description 28
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 16
- 239000000341 volatile oil Substances 0.000 claims description 13
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 11
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- 235000007586 terpenes Nutrition 0.000 claims description 6
- 239000010624 camphor oil Substances 0.000 claims description 5
- 229960000411 camphor oil Drugs 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- 229920000180 alkyd Polymers 0.000 claims description 4
- 239000001293 FEMA 3089 Substances 0.000 claims description 2
- 235000019501 Lemon oil Nutrition 0.000 claims description 2
- 235000019502 Orange oil Nutrition 0.000 claims description 2
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims description 2
- 239000010501 lemon oil Substances 0.000 claims description 2
- 239000001525 mentha piperita l. herb oil Substances 0.000 claims description 2
- 239000010502 orange oil Substances 0.000 claims description 2
- 235000019477 peppermint oil Nutrition 0.000 claims description 2
- 239000010668 rosemary oil Substances 0.000 claims description 2
- 229940058206 rosemary oil Drugs 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims 1
- 239000004925 Acrylic resin Substances 0.000 claims 1
- 239000000976 ink Substances 0.000 description 22
- 239000000919 ceramic Substances 0.000 description 5
- KIDPOJWGQRZHFM-UHFFFAOYSA-N platinum;hydrate Chemical compound O.[Pt] KIDPOJWGQRZHFM-UHFFFAOYSA-N 0.000 description 5
- 238000007650 screen-printing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BELGWZJTSQHCPY-UHFFFAOYSA-N C12(C(=O)CC(CC1)C2(C)C)C.[Pt] Chemical compound C12(C(=O)CC(CC1)C2(C)C)C.[Pt] BELGWZJTSQHCPY-UHFFFAOYSA-N 0.000 description 3
- -1 benzene hydrocarbons Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 150000003058 platinum compounds Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 150000001621 bismuth Chemical class 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002343 gold Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003303 ruthenium Chemical class 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、セラミック、ガラス製品の表面の装飾、電子
工業用等に使用される有機白金インクに関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an organic platinum ink used for surface decoration of ceramics and glass products, electronic industry, and the like.
（従来技術とその問題点）
陶器等のセラミック製品やガラス製品の表面にインクを
使用して文字や図形を描いてその装飾効果を倍増させる
ことが従来から広く行われている。(Prior Art and its Problems) It has been widely practiced to double the decorative effect of ceramic products such as pottery and glass products by drawing letters and figures using ink on the surface of the products.
該文字や図形を描く際には単なるインクではなく、金や
銀等の貴金属光沢を有する有機貴金属インクを使用して
所謂全文字等を形成し、より高級な雰囲気を醸し出すこ
とも行われている。When drawing such letters and figures, instead of using simple ink, organic precious metal ink with the luster of precious metals such as gold and silver is used to form so-called full letters, creating a more luxurious atmosphere. .
これらの有機貴金属インクのうち、白金を貴金属として
含有するインクとして汎用されているものの白金源は、
「水白金」と呼ばれる、主成分が硫化バルサムと白金の
化合物であるが、該白金化合物の詳細は不明であり、量
産はされていない。Among these organic noble metal inks, the platinum source for the commonly used inks containing platinum as a noble metal is:
It is a compound called "water platinum" whose main components are balsam sulfide and platinum, but the details of the platinum compound are unknown and it is not mass-produced.
更に該水白金は低粘度であるため印刷性に乏しく通常の
スクリーン印刷等には使用できないという欠点がある。Furthermore, since the water-platinum has a low viscosity, it has poor printability and cannot be used for ordinary screen printing.
（発明の目的）
本発明は、有機白金インクの白金源として従来使用され
ていた水白金に換えて、より粘度の高い白金化合物を使
用して白金源を明確にして大量生産を可能にするととも
に、有機バインダを加えて印刷性をより向上させた有機
白金インクを提供することを目的とする。(Object of the Invention) The present invention uses a platinum compound with higher viscosity in place of water platinum, which has been conventionally used as a platinum source for organic platinum ink, to clarify the platinum source and enable mass production. The purpose of the present invention is to provide an organic platinum ink with improved printability by adding an organic binder.
（問題点を解決するための手段）
本発明は、白金精油メルカプチド、少なくとも１種類の
樹脂酸の金属塩、有機バインダ及び溶剤を含有すること
を特徴とする有機白金インクである。(Means for Solving the Problems) The present invention is an organic platinum ink characterized by containing platinum essential oil mercaptide, at least one metal salt of a resin acid, an organic binder, and a solvent.
以下本発明をより詳細に説明する。The present invention will be explained in more detail below.
本発明における白金精油メルカプチドとは、精油と硫黄
華を反応させる（例えば１６０〜１７０℃で数時間）こ
とにより生成する精油メルカプタンに塩化白金酸又はそ
の塩を反応させることにより得られる化合物であり、該
化合物は通常２０〜３０重量％の白金を含んでいる。父
上記精油とは、種々の植物から得られる特有の芳香を有
する揮発性油の総称であり、該精油は、テレビン油、ハ
ツカ油、ラベンダ油、レモン油、オレンジ油、ローズマ
リー油及び樟脳油等を意味し、これらは通常テルペン系
又はベンゼン系炭化水素、アルコール、アルデヒド、ケ
トン又はフェノール等から成る数種の成分の混合物であ
る。The platinum essential oil mercaptide in the present invention is a compound obtained by reacting chloroplatinic acid or its salt with essential oil mercaptan produced by reacting essential oil with sulfur flower (for example, at 160 to 170 ° C. for several hours), The compounds usually contain 20-30% by weight of platinum. The above essential oil is a general term for volatile oils with a unique aroma obtained from various plants, and these essential oils include turpentine oil, peppermint oil, lavender oil, lemon oil, orange oil, rosemary oil, camphor oil, etc. These are usually mixtures of several components, such as terpene or benzene hydrocarbons, alcohols, aldehydes, ketones or phenols.
樹脂酸の金属塩は従来から汎用されている、金塩、銀塩
、パラジウム塩、ロジウム塩及びルテニウム塩等の貴金
属塩及び、ビスマス塩及びクロム塩等の卑金属塩を含み
、これらの樹脂酸の金属塩の１又は２種以上を使用する
。Metal salts of resin acids include noble metal salts such as gold salts, silver salts, palladium salts, rhodium salts, and ruthenium salts, and base metal salts such as bismuth salts and chromium salts, which have been widely used. One or more metal salts are used.
本発明における有機バインダとは、従来使用されている
ものの他、アルキド樹脂、尿素樹脂、ロジン誘導体及び
テルペン系樹脂等を使用することができる。使用できる
アルキド樹脂としては、°？マニ油及びロジン変性アル
キド樹脂があり、尿素樹脂としてはｎ−ブチルエーテル
型ブチル化尿素樹脂等がある。父上記ロジン誘導体樹脂
とは、天然ロジンを化学処理して該天然ロジンよりも粘
度を大きくした該天然ロジンから得られる物質の総称で
あり、例えばロジンのグリセリンエステル、ロジンのペ
ンタエリスリトールエステル、水素添加したロジンのメ
チルエステル、マレイン酸変性シタロジンエステル等が
含まれる。更にテルペン系樹脂としてテルペン重合体及
びα−ピネン重合体等を使用することができる。As the organic binder in the present invention, in addition to those conventionally used, alkyd resins, urea resins, rosin derivatives, terpene resins, etc. can be used. As alkyd resins that can be used, °? There are sesame oil and rosin-modified alkyd resins, and urea resins include n-butyl ether type butylated urea resins. The above-mentioned rosin derivative resin is a general term for substances obtained from natural rosin that has been chemically treated to have a higher viscosity than the natural rosin, such as rosin glycerin ester, rosin pentaerythritol ester, hydrogenated rosin, etc. These include methyl ester of rosin, maleic acid-modified citarosine ester, etc. Furthermore, terpene polymers, α-pinene polymers, etc. can be used as the terpene resin.
又本発明においては、上記白金精油メルカプチド、上記
樹脂酸の金属塩及び上記有機バインダの他に必須成分と
して、これら成分の溶剤、例えばテルペンアルコールを
含む。該溶剤は上記物質を溶解しかつ該物質を含むイン
クが陶器等に塗布された場合に比較的短時間で乾くよう
な揮発性物質であることが好ましい。Further, in the present invention, in addition to the platinum essential oil mercaptide, the metal salt of the resin acid, and the organic binder, a solvent for these components, such as a terpene alcohol, is included as an essential component. The solvent is preferably a volatile substance that dissolves the substance and dries in a relatively short time when an ink containing the substance is applied to ceramics or the like.
本発明における有機白金インクは、前記白金精油メルカ
プチド、前記樹脂酸の金属塩、有機バインダ及び溶剤の
必須成分の他に、カンファーやアスファルト等の添加物
を含むことができる。The organic platinum ink in the present invention can contain additives such as camphor and asphalt in addition to the essential components of the platinum essential oil mercaptide, the metal salt of the resin acid, the organic binder, and the solvent.
以下本発明に係わる有機白金インクの実施例を記載する
が、該実施例は本発明を限定するものではない。Examples of organic platinum inks according to the present invention will be described below, but these examples are not intended to limit the present invention.
（実施例） 下記の成分を混合して有機白金インクとした。(Example) An organic platinum ink was prepared by mixing the following components.
白金樟脳油メルカプチド・・・７．０重量％樹脂酸ロジ
ウム・・・０．０５ｆｆｉ１％樹脂酸ビスマス・・・０
．４ｆｆｉ１％樹脂酸クロム・・・０．０！１ｆｉｔ％
天然ロジン・・・２５重量％
ロジン誘導体樹脂・・・５．０重量％
テルペン系樹脂・・・７．０重量％
カンファー・・・６．５重量％
アスファルト・・・１．０重量％
酢酸ベンジル・・・ａ、ｏｍｉ％
テルペンアルコール・・・残部。Platinum camphor oil mercaptide...7.0% by weight Rhodium resinate...0.05ffi1% Bismuth resinate...0
．． 4ffi1% chromium resin acid...0.0!1fit%
Natural rosin...25% by weight Rosin derivative resin...5.0% by weight Terpene resin...7.0% by weight Camphor...6.5% by weight Asphalt...1.0% by weight Benzyl acetate ...a, omi% Terpene alcohol...remainder.
適度な粘性を有する該インクを陶器表面へ刷毛、スクリ
ーン印刷を用いて塗布し、５００〜９００℃で１０分〜
３０分加熱して焼成させた。The ink with appropriate viscosity is applied to the ceramic surface using a brush or screen printing, and heated at 500 to 900°C for 10 minutes.
It was heated and baked for 30 minutes.
一方白金樟脳油メルカプチド７．０重量％を水白金７．
０重量％で置換した以外は上記した組成と同一組成を有
する有機白金インクを同様の条件で陶器上に塗布した。Meanwhile, 7.0% by weight of platinum camphor oil mercaptide was added to 7.0% by weight of platinum camphor oil.
An organic platinum ink having the same composition as above was applied on ceramic under the same conditions except that the ink was replaced with 0% by weight.
実施例インクは、陶器表面のうち塗布された部分全体に
均一に付着し滑らかな表面を形成したが、水白金を使用
したインクではスクリーン印刷に適さない。The example inks adhered uniformly to the entire coated portion of the pottery surface and formed a smooth surface, but inks using water-platinum are not suitable for screen printing.
（発明の効果）
本発明の有機白金インクでは、従来の粘度が低く成分が
特定されなかった水白金の換わりに、粘度の高い白金精
油メルカプチドを使用し、かつ有機バインダを併用して
粘度を向上させているため、本発明の有機白金インクは
特定成分を化学的に合成することにより大量生産が可能
になり、更にスクリーン印刷等の通常の印刷、及び筆や
刷毛等による塗布に対して十分な粘度を有するインクと
なり、装飾用、電子工業用の有機白金インクとしての性
能が飛躍的に向上する。(Effects of the Invention) The organic platinum ink of the present invention uses platinum essential oil mercaptide, which has a high viscosity, instead of water platinum, which has a low viscosity and whose components have not been specified, and also uses an organic binder to improve the viscosity. Therefore, the organic platinum ink of the present invention can be mass-produced by chemically synthesizing specific components, and is also sufficiently durable for ordinary printing such as screen printing and application with a brush or brush. The resulting ink has viscosity, and its performance as an organic platinum ink for decorative and electronic industries is dramatically improved.
出願人 田中貴金属工業株式会社Applicant: Tanaka Kikinzoku Kogyo Co., Ltd.
Claims (3)
酸の金属塩、有機バインダ及び溶剤を含有することを特
徴とする有機白金インク。(1) An organic platinum ink containing platinum essential oil mercaptide, at least one metal salt of a resin acid, an organic binder, and a solvent.
ン油、ハッカ油、ラベンダ油、レモン油、オレンジ油、
ローズマリー油及び樟脳油から成る群から選択される１
又は２以上から成る特許請求の範囲第１項に記載の有機
白金インク(2) Platinum essential oil The main components of mercaptide essential oil are turpentine oil, peppermint oil, lavender oil, lemon oil, orange oil,
1 selected from the group consisting of rosemary oil and camphor oil
or an organic platinum ink according to claim 1 consisting of two or more
ン誘導体、テルペン系樹脂及びアクリル系樹脂から成る
群から選択されるバインダである特許請求の範囲第１項
又は第２項に記載の有機白金インク。(3) The organic platinum ink according to claim 1 or 2, wherein the organic binder is a binder selected from the group consisting of alkyd resins, urea resins, rosin derivatives, terpene resins, and acrylic resins. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15477187A JPH0765015B2 (en) | 1987-06-22 | 1987-06-22 | Organic platinum ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15477187A JPH0765015B2 (en) | 1987-06-22 | 1987-06-22 | Organic platinum ink |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH01179A true JPH01179A (en) | 1989-01-05 |
| JPS64179A JPS64179A (en) | 1989-01-05 |
| JPH0765015B2 JPH0765015B2 (en) | 1995-07-12 |
Family
ID=15591536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15477187A Expired - Lifetime JPH0765015B2 (en) | 1987-06-22 | 1987-06-22 | Organic platinum ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0765015B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4952836A (en) * | 1989-04-27 | 1990-08-28 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Piezoelectrostatic generator |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61136977A (en) * | 1984-12-06 | 1986-06-24 | アルプス電気株式会社 | Electroconductive paste for thick film circuit |
-
1987
- 1987-06-22 JP JP15477187A patent/JPH0765015B2/en not_active Expired - Lifetime
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