JPH01155884A - Composition for water-soluble toy - Google Patents
Composition for water-soluble toyInfo
- Publication number
- JPH01155884A JPH01155884A JP31417387A JP31417387A JPH01155884A JP H01155884 A JPH01155884 A JP H01155884A JP 31417387 A JP31417387 A JP 31417387A JP 31417387 A JP31417387 A JP 31417387A JP H01155884 A JPH01155884 A JP H01155884A
- Authority
- JP
- Japan
- Prior art keywords
- water
- composition
- color
- toy
- alkaline substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000975 dye Substances 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 7
- CPBJMKMKNCRKQB-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-2-benzofuran-1-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 CPBJMKMKNCRKQB-UHFFFAOYSA-N 0.000 claims abstract description 3
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000945 filler Substances 0.000 claims abstract description 3
- 239000003086 colorant Substances 0.000 claims abstract 2
- LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 abstract description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 6
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 abstract description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract description 3
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 abstract description 2
- 235000019828 potassium polyphosphate Nutrition 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 abstract 1
- 235000019797 dipotassium phosphate Nutrition 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- -1 thymolphtalein Chemical compound 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 2
- 235000019801 trisodium phosphate Nutrition 0.000 description 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
Landscapes
- Toys (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、水に溶解すると空気中の炭酸ガスにより、中
和され、自然に消色をする液体を作るための水溶性玩具
用組成物に関するものである。Detailed Description of the Invention (Industrial Application Field) The present invention provides a water-soluble toy composition for producing a liquid that, when dissolved in water, is neutralized by carbon dioxide gas in the air and naturally discolors. It is related to.
（従来の技術及び問題点）
玩具で、布に振りかけると、自然に色が消える液が販売
されている。然し乍ら、この物は、色が消える原理上、
通気性のある容器に入っていると、空気中の炭酸ガスに
より、中和され、時間の経過と共に色が薄（なり、最終
的には透明になり、商品としては、成り立たなくなる。(Prior Art and Problems) Toys are sold with a liquid whose color disappears naturally when sprinkled on cloth. However, due to the principle that color disappears, this item
If it is stored in a breathable container, it will be neutralized by carbon dioxide gas in the air, and over time it will become lighter in color and eventually become transparent, making it unsuitable as a product.
（問題点を解決するための手段）
本発明は、この欠点を解消すべく、研究し、水に溶解し
た時点で初めて自然に消色する色水になる様、組成を配
合した水溶性玩具組成物を提供しようとするもので、そ
の要旨とするところは、ある一定のアルカリ性のｐｉ（
において、所定の色に発色し、ｐＨが下がると無色にな
る粉末状の染料、例えばフェノールフタレイン、チモー
ルフタレイン、オルトクレゾールフタレインなどのフタ
レイン系の染料、もしくは、パラニトロフェノールとア
ルカリ性物質を混合してなる水溶性玩具用組成物にある
。(Means for Solving the Problems) In order to eliminate this drawback, the present invention has been developed to provide a water-soluble toy composition that has been researched and has a composition so that it becomes colored water that naturally disappears only when dissolved in water. The purpose is to provide a certain amount of alkaline PI (
In the process, powdered dyes that develop a predetermined color and become colorless when the pH drops, such as phthalein dyes such as phenolphthalein, thymol phthalein, orthocresol phthalein, or paranitrophenol and an alkaline substance are used. A composition for a water-soluble toy is obtained by mixing the following.
本発明の水溶性玩具用組成物は、粉末の状態では、空気
中に放置しておいても、炭酸ガスの影響を受けず、水に
溶解すると、いつの時点でも同じ様な色水ができる。ま
た、商品の保管流通においても、粉末である為、容積、
重量とも液体の物に比べ小さく、経費が安価ですむ。In powder form, the water-soluble toy composition of the present invention is not affected by carbon dioxide even when left in the air, and when dissolved in water, it produces water of the same color at any time. In addition, when storing and distributing the product, since it is a powder, the volume and
It is smaller in weight and less expensive than liquid materials.
また、例えば本発明の水溶性玩具用組成物を、水鉄砲の
液に使用する場合には、最初から液体の物では、その都
度容器付で購入しなければならないが、粉末状あるいは
固形状としておくことができるので、容器は必要なく、
簡単なパッケージですみ、安価に購入する事が出来、子
供が使う玩具用組成物として、極めて適切である。In addition, for example, when the water-soluble toy composition of the present invention is used as liquid for water guns, if it is liquid from the beginning, it must be purchased with a container each time, but it must be purchased in powder or solid form. You don't need a container because you can
It requires a simple package, can be purchased at low cost, and is extremely suitable as a composition for toys used by children.
本発明の水溶性玩具用組成物において、粉末を構成する
アルカリ性物質は、安全性の点から食品添加物として用
いられるものが望ましい０例えば、炭酸ナトリウム、リ
ン酸水素二カリウム、リン酸水素二ナトリウム、リン酸
三カリウム、リン酸三ナトリウム、ポリリン酸カリウム
、ポリリン酸ナトリウム、メタリン酸カリウム、メタリ
ン酸ナトリウム、プロピオン酸ナトリウムなどの一種、
又は、二種以上の混合物が挙げられる。In the water-soluble toy composition of the present invention, the alkaline substance constituting the powder is preferably one used as a food additive from the viewpoint of safety. For example, sodium carbonate, dipotassium hydrogen phosphate, disodium hydrogen phosphate, etc. , tripotassium phosphate, trisodium phosphate, potassium polyphosphate, sodium polyphosphate, potassium metaphosphate, sodium metaphosphate, sodium propionate, etc.
Alternatively, a mixture of two or more types may be mentioned.
又、本発明の水溶性玩具用組成物において、粉末を構成
する顕色剤又は、増量剤としてはアルカリ性物質と同じ
く安全性の点から食品又は、食品添加物として用いられ
るものが望ましい。例えば、ブドウ糖、乳糖、砂糖、食
塩、ボウ硝、などの−種、又は、二種以上の混合物が考
えられ。In addition, in the water-soluble toy composition of the present invention, the color developer or filler constituting the powder is preferably one that can be used in foods or food additives from the viewpoint of safety, like alkaline substances. For example, species such as glucose, lactose, sugar, salt, and sulfate, or a mixture of two or more species can be considered.
以下に実施例を示す。Examples are shown below.
実施例１゜
フェノールフタレイン ６部
リン酸三ナトリウム ９４部
上記混合物０．５ｇを取り、水２５０ｃｃに溶かすと赤
い液ができた、この液を布に振りかけたところ、赤い色
は２〜３分で消えた。Example 1 Phenolphthalein 6 parts Trisodium phosphate 94 parts Take 0.5 g of the above mixture and dissolve it in 250 cc of water to create a red liquid. When this liquid was sprinkled on a cloth, the red color remained for 2 to 3 minutes. It disappeared.
実施例２゜
チモールフタレイン １部
炭酸ナトリウム ４８部
食塩 ５１部
上記上記物１ｇを取り、水１００ｃｃに溶かすと青い液
ができた。この液を布に振りかけたところ、青い色は２
〜３分で消えた。又、食塩を入れる事により、青の色が
食塩を入れない物に比べ、より鮮やかになった。Example 2 Thymolphthalein 1 part Sodium carbonate 48 parts Salt 51 parts 1 g of the above product was taken and dissolved in 100 cc of water to form a blue liquid. When I sprinkled this liquid on the cloth, the blue color was 2.
It disappeared in ~3 minutes. Also, by adding salt, the blue color became more vivid compared to the product without salt.
（発明の効果）
本発明によれば、空気中に放置しても炭酸ガスの影響を
受けず、水に溶解すると、何時の時点でも同じような色
水ができ、また商品の流通保管においても、粉末状（場
合によっては固形状とすることが出来る）であるから、
容積、重量とも液体の物に比較して経費が著しく安価で
且つ取扱いが容易な水溶性玩具用組成物を提供できるの
で、本発明は産業上極めて有用である。(Effects of the Invention) According to the present invention, even when left in the air, it is not affected by carbon dioxide gas, when dissolved in water, the same colored water is produced at any time, and even during distribution and storage of products. , since it is in powder form (in some cases it can be made into solid form),
The present invention is industrially extremely useful because it can provide a water-soluble toy composition that is significantly cheaper in volume and weight than liquid compositions and is easy to handle.
−へ− to
Claims (2)
に発色し、ｐＨが下がると無色になる粉末状の染料、例
えばフェノールフタレイン、チモールフタレイン、オル
トクレゾールフタレインなどのフタレイン系の染料、も
しくは、パラニトロフェノールとアルカリ性物質を混合
してなる水溶性玩具用組成物。(1) Powdered dyes that develop a predetermined color at a certain alkaline pH and become colorless when the pH drops, such as phthalein dyes such as phenolphthalein, thymol phthalein, ortho-cresol phthalein, Alternatively, a water-soluble toy composition prepared by mixing para-nitrophenol and an alkaline substance.
増量剤を含む特許請求の範囲第１項記載の水溶性玩具用
組成物。(2) A color developer that makes colors vivid when dissolved in water, or
The water-soluble toy composition according to claim 1, which contains a filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31417387A JPH01155884A (en) | 1987-12-14 | 1987-12-14 | Composition for water-soluble toy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31417387A JPH01155884A (en) | 1987-12-14 | 1987-12-14 | Composition for water-soluble toy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01155884A true JPH01155884A (en) | 1989-06-19 |
Family
ID=18050128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31417387A Pending JPH01155884A (en) | 1987-12-14 | 1987-12-14 | Composition for water-soluble toy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01155884A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5088598A (en) * | 1989-04-25 | 1992-02-18 | Daicel Chemical Industries, Ltd. | Plastic-model kit |
| JP2009509116A (en) * | 2005-09-15 | 2009-03-05 | ホーム・フォーカス・ディベロップメント・リミテッド | Liquid bullet firing and detection device and combinations thereof |
| CN105222644A (en) * | 2015-09-07 | 2016-01-06 | 黄文佳 | A kind of manufacture method of water gun |
| CN105928419A (en) * | 2015-09-07 | 2016-09-07 | 黄文佳 | Water gun |
| CN106091805A (en) * | 2015-09-07 | 2016-11-09 | 黄文佳 | A kind of manufacture method of water gun water-storing bottle |
| CN106978135A (en) * | 2015-09-07 | 2017-07-25 | 钱小英 | Toy effervescent tablet |
-
1987
- 1987-12-14 JP JP31417387A patent/JPH01155884A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5088598A (en) * | 1989-04-25 | 1992-02-18 | Daicel Chemical Industries, Ltd. | Plastic-model kit |
| JP2009509116A (en) * | 2005-09-15 | 2009-03-05 | ホーム・フォーカス・ディベロップメント・リミテッド | Liquid bullet firing and detection device and combinations thereof |
| CN105222644A (en) * | 2015-09-07 | 2016-01-06 | 黄文佳 | A kind of manufacture method of water gun |
| CN105928419A (en) * | 2015-09-07 | 2016-09-07 | 黄文佳 | Water gun |
| CN105973065A (en) * | 2015-09-07 | 2016-09-28 | 黄文佳 | Manufacturing method for water gun |
| CN106066135A (en) * | 2015-09-07 | 2016-11-02 | 黄文佳 | A kind of water gun |
| CN106066134A (en) * | 2015-09-07 | 2016-11-02 | 黄文佳 | A kind of water gun |
| CN106091805A (en) * | 2015-09-07 | 2016-11-09 | 黄文佳 | A kind of manufacture method of water gun water-storing bottle |
| CN106123683A (en) * | 2015-09-07 | 2016-11-16 | 黄文佳 | A kind of manufacture method of water gun water-storing bottle |
| CN106123684A (en) * | 2015-09-07 | 2016-11-16 | 黄文佳 | A kind of manufacture method of water gun |
| CN106152872A (en) * | 2015-09-07 | 2016-11-23 | 黄文佳 | A kind of manufacture method of water gun water-storing bottle |
| CN106197143A (en) * | 2015-09-07 | 2016-12-07 | 黄文佳 | A kind of manufacture method of water gun |
| CN106978135A (en) * | 2015-09-07 | 2017-07-25 | 钱小英 | Toy effervescent tablet |
| CN107014244A (en) * | 2015-09-07 | 2017-08-04 | 钱小英 | A kind of toy effervescent tablet |
| CN107084641A (en) * | 2015-09-07 | 2017-08-22 | 钱小英 | A kind of water gun effervescent tablet |
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