JPH0115379B2 - - Google Patents
Info
- Publication number
- JPH0115379B2 JPH0115379B2 JP9611379A JP9611379A JPH0115379B2 JP H0115379 B2 JPH0115379 B2 JP H0115379B2 JP 9611379 A JP9611379 A JP 9611379A JP 9611379 A JP9611379 A JP 9611379A JP H0115379 B2 JPH0115379 B2 JP H0115379B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- component
- resin
- polypropylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 polypropylene Polymers 0.000 claims description 20
- 239000004743 Polypropylene Substances 0.000 claims description 19
- 229920001155 polypropylene Polymers 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 150000008064 anhydrides Chemical class 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000010410 layer Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- UIERETOOQGIECD-ARJAWSKDSA-N angelic acid Chemical compound C\C=C(\C)C(O)=O UIERETOOQGIECD-ARJAWSKDSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は樹脂―金属積層物に関する。
ポリプロピレンをアルミニウムなどの金属と積
層しても、ポリプロピレンは無極性材料であるた
め接着力を有していない。従来、この接着力の向
上を図るためポリプロピレン、金属の表面に放
電処理、クロム酸処理、火炎処理、各種エツチン
グなどの表面処理を行なう方法、ポリオレフイ
ンに無水マレイン酸をグラフトした変性ポリオレ
フインを用いる方法（特公昭42−10757号公報、
同47−4822号公報など）、酸変性ポリオレフイ
ンに炭化水素合成エラストマーを配合した組成物
を用いる方法（特開昭52−80334号公報）などが
ある。
しかしながら、これらの方法では表面処理に時
間と経費がかかつたり、接着強度が十分でなかつ
たり、あるいはエラストマーを加えると耐熱性、
耐油性、耐溶剤性が低下するという欠点がある。
本発明は、このような欠点を解消し接着力の高
い樹脂―金属積層物の提供を目的とするものであ
る。すなわち本発明は、(A)不飽和カルボン酸ある
いはその無水物で変性された結晶性ポリプロピレ
ンもしくは該ポリプロピレンと未変性結晶性ポリ
プロピレンとの混合物99〜40重量部および(B)エチ
レン単独重合体またはエチレン―酢酸ビニル共重
合体１〜60重量部よりなる樹脂層と金属層からな
る樹脂―金属積層物を提供するものである。
本発明において(A)成分として用いる不飽和カル
ボン酸あるいはその無水物で変性された結晶性ポ
リプロピレンとは、プロピレン単独重合体、プロ
ピレンを主成分とするエチレン、ブテン―１、ヘ
キセン―１などとの共重合体あるいはこれらの混
合物に対しアクリル酸、マレイン酸、イタコン
酸、フマル酸、クロトン酸、シトラコン酸、ソル
ビン酸、メサコン酸、アンゲリカ酸等の不飽和カ
ルボン酸またはこれらの無水物を単独で、もしく
は適宜に組合せて付加せしめて一部あるいは全部
を変性したポリオレフインを意味し、その製法は
特に制限されず、溶融性、溶液法等の公知方法を
任意に適用できる。不飽和カルボン酸またはその
無水物は結晶性ポリプロピレンに対して0.001〜
15％、好ましくは0.005〜10％含有せしめる。ま
た、未変性結晶性ポリプロピレンとはこのような
変性処理を受けない上記重合体または共重合体を
意味する。
次に、本発明では(B)成分としてエチレン単独重
合体またはエチレン―酢酸ビニル共重合体を用い
る。エチレン単独重合体にあつては低密度、中密
度および高密度のいずれの重合体も使用できる。
上記(A)、(B)両成分の配合割合については、(A)成
分99〜40重量部に対して(B)成分１〜60重量部、好
ましくは(A)成分97〜60重量部に対して(B)成分３〜
40重量部とすべきである。(B)成分の量がこの範囲
外であると、得られる積層物の層間接着強度は満
足しうるものとならない。また、上記両成分は予
め溶融混練して組成物としておく。
一方、金属としてはアルミニウム、鉄、トタ
ン、ブリキ、銅などがあり、これらは未加工の板
状体であつてもよくアルミニウム箔のような加工
品であつてもよい。
本発明の樹脂―金属積層物は、積層に際して接
着剤などの使用を必要とせず、金属が板状体であ
り樹脂がフイルムもしくはシートの場合は両者を
二層もしくはそれ以上の多層に積層して熱圧着す
ればよい。また、金属が板状体あるいは他の加工
品の形状であるときは、樹脂層を粉体塗装や溶液
あるいはエマルジヨン塗装を適用して金属層に積
層することができる。
このようにして得られる本発明の樹脂―金属積
層物は両者間の接着力が高く、しかも耐溶剤性、
耐熱性にすぐれている。したがつて、各種食品の
包装資材、飲料缶、工業材料、建材等として有効
に利用することができる。
次に、本発明を実施例により詳しく説明する。
製造例 １
変性ポリプロピレンＡの製造
ポリプロピレン（プロピレン・エチレンランダ
ムコポリマー、エチレン含有量３重量％、MI：
7g／10分、密度0.91g／cm3）100重量部、無水マレ
イン酸20重量部、末端ヒドロキシル化１，４―ポ
リブタジエン（数平均分子量3000）５重量部およ
びジクミルパーオキサイド２重量部をキシレン
600重量部に添加し、120℃で60分間撹拌、溶解し
たのち、140℃で90分間撹拌しながら反応させた。
次いで反応物を大量のアセトン中に入れ、反応生
成物を沈澱させ、乾燥することによつて白色粉状
の無水マレイン酸変性ポリプロピレンを得た。な
お、無水マレイン酸付加量は6.7重量％（酸価測
定法）であつた。
製造例 ２
変性ポリプロピレンＢの製造
ポリプロピレン（プロピレン―エチレンランダ
ムコポリマー、エチレン含有量３重量％、MI：
7g／10分、密度0.91g／cm3）100重量部、無水マレ
イン酸10重量部およびジクミルパーオキサイド２
重量部をキシレン600重量部に添加し120℃で60分
間撹拌、溶解し、140℃で90分間撹拌しながら反
応させた。次いで反応物を大量のアセトン中に入
れ、反応生成物を沈澱させ、乾燥することによつ
て白色粉状の無水マレイン酸変性ポリマロピレン
を得た。なお、無水マレイン酸付加量は0.6重量
％（酸価測定法）であつた。
実施例 １
製造例１で得られた変性ポリプロピレンＡ、未
変性ポリプロピレンおよび低密度ポリエチレンの
組成を表―１に示したように種々変え、押出機に
より190℃で溶融押出しペレツトを得た。このペ
レツトを190℃で圧縮成形し、厚さ約300μのシー
トを成形した。
このシートと厚さ80μのアルミニウム板を重ね
合せ、温度220℃、圧力１Kgで１秒間加熱圧着し
て樹脂―金属積層物を得た。この積層物のＴ剥離
強度を表―１に示す。
The present invention relates to resin-metal laminates. Even if polypropylene is laminated with a metal such as aluminum, it does not have adhesive strength because polypropylene is a nonpolar material. Conventionally, in order to improve this adhesive strength, there have been methods to perform surface treatments such as electrical discharge treatment, chromic acid treatment, flame treatment, and various types of etching on the surface of polypropylene and metal, and methods to use modified polyolefin in which maleic anhydride is grafted onto polyolefin ( Special Publication No. 42-10757,
47-4822, etc.), and a method using a composition in which a hydrocarbon synthetic elastomer is blended with an acid-modified polyolefin (Japanese Patent Application Laid-open No. 52-80334). However, these methods require time and expense for surface treatment, insufficient adhesive strength, or the addition of elastomers may result in poor heat resistance,
It has the disadvantage of reduced oil resistance and solvent resistance. The present invention aims to eliminate such drawbacks and provide a resin-metal laminate with high adhesive strength. That is, the present invention provides (A) 99 to 40 parts by weight of a crystalline polypropylene modified with an unsaturated carboxylic acid or its anhydride or a mixture of said polypropylene and unmodified crystalline polypropylene, and (B) an ethylene homopolymer or ethylene. - A resin-metal laminate comprising a resin layer comprising 1 to 60 parts by weight of a vinyl acetate copolymer and a metal layer. In the present invention, the crystalline polypropylene modified with an unsaturated carboxylic acid or its anhydride used as component (A) refers to a propylene homopolymer, a polymer containing ethylene, butene-1, hexene-1, etc. mainly composed of propylene. For copolymers or mixtures thereof, unsaturated carboxylic acids such as acrylic acid, maleic acid, itaconic acid, fumaric acid, crotonic acid, citraconic acid, sorbic acid, mesaconic acid, angelic acid or their anhydrides alone, Alternatively, it refers to a polyolefin that is partially or completely modified by adding an appropriate combination, and the manufacturing method thereof is not particularly limited, and any known method such as a melting method or a solution method can be applied. Unsaturated carboxylic acid or its anhydride is 0.001~ for crystalline polypropylene
The content is 15%, preferably 0.005 to 10%. Moreover, unmodified crystalline polypropylene means the above-mentioned polymer or copolymer that is not subjected to such modification treatment. Next, in the present invention, an ethylene homopolymer or an ethylene-vinyl acetate copolymer is used as the component (B). As for the ethylene homopolymer, any of low density, medium density and high density polymers can be used. Regarding the blending ratio of both components (A) and (B) above, 1 to 60 parts by weight of component (B) to 99 to 40 parts by weight of component (A), preferably 97 to 60 parts by weight of component (A). On the other hand, (B) component 3~
Should be 40 parts by weight. If the amount of component (B) is outside this range, the interlayer adhesive strength of the resulting laminate will not be satisfactory. Further, both of the above components are melted and kneaded in advance to form a composition. On the other hand, metals include aluminum, iron, galvanized iron, tinplate, copper, etc., and these may be in the form of unprocessed plates or processed products such as aluminum foil. The resin-metal laminate of the present invention does not require the use of an adhesive or the like during lamination, and when the metal is a plate-like body and the resin is a film or sheet, the two or more layers can be laminated into two or more layers. Just heat and press it. Further, when the metal is in the form of a plate or other processed product, the resin layer can be laminated onto the metal layer by applying powder coating, solution coating, or emulsion coating. The resin-metal laminate of the present invention obtained in this manner has high adhesive strength between the two, and also has solvent resistance and
Excellent heat resistance. Therefore, it can be effectively used as packaging materials for various foods, beverage cans, industrial materials, building materials, etc. Next, the present invention will be explained in detail with reference to examples. Production example 1 Production of modified polypropylene A Polypropylene (propylene/ethylene random copolymer, ethylene content 3% by weight, MI:
7 g/10 min, density 0.91 g/cm 3 ), 100 parts by weight of maleic anhydride, 5 parts by weight of terminal hydroxylated 1,4-polybutadiene (number average molecular weight 3000), and 2 parts by weight of dicumyl peroxide in xylene.
The mixture was added to 600 parts by weight, stirred and dissolved at 120°C for 60 minutes, and reacted at 140°C for 90 minutes with stirring.
Next, the reaction product was poured into a large amount of acetone, and the reaction product was precipitated and dried to obtain maleic anhydride-modified polypropylene in the form of a white powder. The amount of maleic anhydride added was 6.7% by weight (acid value measurement method). Production Example 2 Production of modified polypropylene B Polypropylene (propylene-ethylene random copolymer, ethylene content 3% by weight, MI:
7g/10min, density 0.91g/ cm3 ) 100 parts by weight, maleic anhydride 10 parts by weight and dicumyl peroxide 2
Parts by weight were added to 600 parts by weight of xylene, stirred and dissolved at 120°C for 60 minutes, and reacted at 140°C for 90 minutes with stirring. Next, the reaction product was poured into a large amount of acetone, and the reaction product was precipitated and dried to obtain a white powdery maleic anhydride-modified polymaropyrene. The amount of maleic anhydride added was 0.6% by weight (acid value measurement method). Example 1 The compositions of modified polypropylene A, unmodified polypropylene and low density polyethylene obtained in Production Example 1 were varied as shown in Table 1, and pellets were obtained by melt extrusion at 190°C using an extruder. This pellet was compression molded at 190°C to form a sheet approximately 300μ thick. This sheet and an 80 μm thick aluminum plate were laminated and heat-pressed at a temperature of 220° C. and a pressure of 1 kg for 1 second to obtain a resin-metal laminate. Table 1 shows the T peel strength of this laminate.
【表】
実施例２〜５および比較例１
各成分の種類と配合割合（重量部）を変更した
こと以外は実施例１に準じて行なつた。条件およ
び結果を表―２に示す。[Table] Examples 2 to 5 and Comparative Example 1 The procedure of Example 1 was followed except that the types and blending ratios (parts by weight) of each component were changed. The conditions and results are shown in Table 2.
【表】
なお、接着力の向上のためにはエチレン・プロ
ピレンゴムなどのゴム物質の添加が有効である
が、当該ゴム物質の添加により耐溶剤性などの他
の物性が低下するので、限定された用途に使用す
る場合を除いて、一般的には好ましくない。
比較例 ２〜６
表―３に示す組成の樹脂を用いたこと以外は、
実施例１に準じて行ない樹脂―金属積層物を得
た。この積層物のＴ剥離強度および耐溶剤性試験
（ガソリンに24時間浸漬後の剥離強度とそのとき
の状態）の結果を、実施例４の結果と共に表―３
に示す。[Table] Although it is effective to add rubber substances such as ethylene/propylene rubber to improve adhesive strength, it is limited because the addition of such rubber substances reduces other physical properties such as solvent resistance. Generally undesirable, except when used for specific purposes. Comparative Examples 2 to 6 Except for using resins with the compositions shown in Table 3,
A resin-metal laminate was obtained in accordance with Example 1. The results of the T-peel strength and solvent resistance test (peel strength after immersion in gasoline for 24 hours and the state at that time) of this laminate are shown in Table 3 along with the results of Example 4.
Shown below.
Claims (1)
性された結晶性ポリプロピレンもしくは該ポリプ
ロピレンと未変性結晶性ポリプロピレンとの混合
物99〜40重量部および(B)エチレン単独重合体また
はエチレン―酢酸ビニル共重合体１〜60重量部よ
りなる樹脂層と金属層からなる樹脂―金属積層
物。 ２ 樹脂層の(A)成分と(B)成分の配合割合が(A)成分
97〜60重量部に対して(B)成分３〜40重量部である
特許請求の範囲第１項記載の樹脂―金属積層物。[Scope of Claims] 1 (A) 99 to 40 parts by weight of crystalline polypropylene modified with an unsaturated carboxylic acid or its anhydride or a mixture of said polypropylene and unmodified crystalline polypropylene, and (B) ethylene homopolymer Or a resin-metal laminate comprising a resin layer comprising 1 to 60 parts by weight of an ethylene-vinyl acetate copolymer and a metal layer. 2 The blending ratio of component (A) and component (B) in the resin layer is (A) component.
The resin-metal laminate according to claim 1, wherein the amount of component (B) is 3 to 40 parts by weight based on 97 to 60 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9611379A JPS5621850A (en) | 1979-07-30 | 1979-07-30 | Resinnmetal laminate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9611379A JPS5621850A (en) | 1979-07-30 | 1979-07-30 | Resinnmetal laminate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5621850A JPS5621850A (en) | 1981-02-28 |
| JPH0115379B2 true JPH0115379B2 (en) | 1989-03-16 |
Family
ID=14156327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9611379A Granted JPS5621850A (en) | 1979-07-30 | 1979-07-30 | Resinnmetal laminate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5621850A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58136440A (en) * | 1982-02-08 | 1983-08-13 | 三井東圧化学株式会社 | Metallic laminate |
-
1979
- 1979-07-30 JP JP9611379A patent/JPS5621850A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5621850A (en) | 1981-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4198327A (en) | Grafted polyolefin composition having improved adhesiveness | |
| JPS58103569A (en) | Adhesive blend and composite structure | |
| US4537836A (en) | Composite structures | |
| JPH0267386A (en) | Adhesive composition for bonding metal to polyolefin | |
| JPS5831106B2 (en) | thermoplastic resin composition | |
| JPS6011056B2 (en) | Modified ethylene polymer composition | |
| JPH0244843B2 (en) | ||
| JPH0115379B2 (en) | ||
| JPS629135B2 (en) | ||
| JPS6367497B2 (en) | ||
| JPS6154591B2 (en) | ||
| JPH02245042A (en) | Adhesive polypropylene composition | |
| JPS5962613A (en) | Preparation of modified polyolefin | |
| JPS6411464B2 (en) | ||
| JPH0157673B2 (en) | ||
| JPS5927975A (en) | Adhesive for aromatic resin | |
| JPH0146313B2 (en) | ||
| JPH0367111B2 (en) | ||
| JPS5845051A (en) | Laminate | |
| JPS59202847A (en) | Manufacture of laminate | |
| JPH0466266B2 (en) | ||
| JPS6348894B2 (en) | ||
| JPH04255349A (en) | Plastic container | |
| JPS5889642A (en) | Modified polypropylene composition and laminates using the same | |
| JPH0221417B2 (en) |