JPH01132899A - Incombustible gypsum board base paper - Google Patents

Incombustible gypsum board base paper

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Publication number
JPH01132899A
JPH01132899A JP28337387A JP28337387A JPH01132899A JP H01132899 A JPH01132899 A JP H01132899A JP 28337387 A JP28337387 A JP 28337387A JP 28337387 A JP28337387 A JP 28337387A JP H01132899 A JPH01132899 A JP H01132899A
Authority
JP
Japan
Prior art keywords
layer
gypsum board
base paper
noncombustible
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28337387A
Other languages
Japanese (ja)
Inventor
Naomi Goto
尚美 後藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JUJO ITAGAMI KK
Original Assignee
JUJO ITAGAMI KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JUJO ITAGAMI KK filed Critical JUJO ITAGAMI KK
Priority to JP28337387A priority Critical patent/JPH01132899A/en
Publication of JPH01132899A publication Critical patent/JPH01132899A/en
Pending legal-status Critical Current

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Abstract

PURPOSE: To obtain a gypsum board base paper comprising a noncombustible layer having a surface layer consisting essentially of an inorganic powder and a back layer comprising a water absorbent paper stock layer and having a high degree of flame retardance without using asbestos. CONSTITUTION: A noncombustible gypsum board base paper is obtained by using a noncombustible layer (a) prepared by compounding a fibrous material (e.g. pulp) and a binder (e.g. a styrene-butadiene rubber) with an inorganic powder (preferably aluminum hydroxide, etc.), as a principal component and carrying out papermaking as a surface layer and a water absorbent paper stock layer (b) comprising a waste paper, etc., as a back layer. A water nonabsorbing paper stock layer may preferably be provided as an interlayer.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は不燃性石膏ボード原紙に関する。[Detailed description of the invention] Industrial applications The present invention relates to noncombustible gypsum board base paper.

従来の技術 従来の不燃性石膏ボード原紙は、特公昭50−8457
号公報に示される如く、石膏に接する層が吸水性紙料か
らなり、中間層が非吸水性紙料からなり、最外層が不燃
性繊維からなる三層構造のものである。前記不燃性繊維
としては、岩綿、アスベストまたはガラス繊維であり、
アスベストが実用化されている。
Conventional technology Conventional noncombustible gypsum board base paper was published in Japanese Patent Publication No. 50-8457.
As shown in the publication, it has a three-layer structure in which the layer in contact with gypsum is made of water-absorbing paper stock, the middle layer is made of non-water-absorbing paper stock, and the outermost layer is made of non-flammable fibers. The noncombustible fiber is rock wool, asbestos or glass fiber,
Asbestos has been put into practical use.

発明が解決しようとする問題点 前述の不燃性石膏ボード原紙の最外層に主として使用さ
れるアスベストは、健康上有害とされ、近来アスベスト
飛散による公害上の問題がある。
Problems to be Solved by the Invention Asbestos, which is mainly used in the outermost layer of the above-mentioned noncombustible gypsum board base paper, is considered to be harmful to health, and recently there has been a pollution problem due to asbestos scattering.

問題点を解決するための手段 本発明は、石膏層を積層して石膏ボードを形成する多層
構造の石膏ボード原紙を、表層がアスベストを含まない
無機粉体を主体とする不燃性層からなり、裏層が吸水性
紙料層からなる構成とし、または前記両層の中間層が非
吸水性紙料層からなる三層構成とすることにより、前述
の問題点を解決し得たものである。
Means for Solving the Problems The present invention provides a multilayered gypsum board base paper in which gypsum layers are laminated to form a gypsum board. The above-mentioned problems can be solved by using a three-layer structure in which the back layer is made of a water-absorbing paper stock layer, or the intermediate layer between the two layers is a non-water-absorbing paper stock layer.

前述の構成の不燃性石膏ボード原紙は、以下に示す抄造
方法により抄造される。
The noncombustible gypsum board base paper having the above-mentioned structure is made by the paper making method shown below.

本発明の不燃性石膏ボード原紙は、主として無機粉体と
抄紙性に必要な繊維およびバインダよりなる紙料スラリ
を不燃性層として表層の形成に、従来同様石膏に接する
面に用いられてきた吸水性紙料を接着層として下層の形
成に用い、通常の板紙多層抄き抄紙機で抄造される。
The noncombustible gypsum board base paper of the present invention uses a paper stock slurry mainly consisting of inorganic powder, fibers necessary for paper making, and a binder as a noncombustible layer to form the surface layer, and as in the past, water absorbing material was used on the surface in contact with gypsum. The paper stock is used as an adhesive layer to form the lower layer, and the paper is made using a normal paperboard multilayer paper machine.

前記不燃性層の無機粉体としては、水酸化アルミニウム
、水酸化マグネシウム、塩基性炭酸マグネシウム、炭酸
カルシウム、タルク、カオリン、硫酸カルシウム等が用
いられる。前記無機粉体中水酸化アルミニウムおよび水
酸化マグネシウムは、加熱されると酸化物と水蒸気とに
分解され、該水蒸気が石膏ボード原紙に自己消火性を付
与するが故に、−段と不燃性を向上せしめるので特に好
ましい。
As the inorganic powder for the nonflammable layer, aluminum hydroxide, magnesium hydroxide, basic magnesium carbonate, calcium carbonate, talc, kaolin, calcium sulfate, etc. are used. The aluminum hydroxide and magnesium hydroxide in the inorganic powder are decomposed into oxides and water vapor when heated, and the water vapor imparts self-extinguishing properties to the gypsum board base paper, thereby significantly improving its nonflammability. This is particularly preferable because it makes it easier.

前記無機粉体の1種又は2種以上を繊維材料およびバイ
ンダと共に紙料スラリとなし、不燃性層として抄造し、
シート化する。
One or more of the inorganic powders are made into a paper stock slurry together with a fiber material and a binder, and the paper is made into a nonflammable layer,
Make it into a sheet.

前記繊維材料は、不燃性層の抄造、シート化に当り、シ
ート強度を保持せしめるために必要であり、通常、バル
ブや故紙が原料として使用されるが、不燃性石膏ボード
と・しての使用目的によっては、他の繊維材料、例えば
ポリエステル等の有機繊維や、ガラス等の無機繊維を単
独でまたは前記パルプ系原料と併用して使用することも
できる。
The above-mentioned fiber material is necessary to maintain the strength of the sheet when forming the non-combustible layer into a sheet, and normally valves and waste paper are used as raw materials, but it is also used as a non-combustible gypsum board. Depending on the purpose, other fiber materials, such as organic fibers such as polyester or inorganic fibers such as glass, may be used alone or in combination with the pulp-based raw material.

前記バインダとしては、スチレン・ブタジェン・ラバや
アクリル酸の共重合体等のラテックス ポリビニルアル
コール ポリアクリル7ミド、変性澱粉等の水溶性高分
子等の1種または2種以上を使用する。
As the binder, one or more of water-soluble polymers such as latex such as styrene-butadiene-rubber and acrylic acid copolymer, polyvinyl alcohol, polyacryl 7mide, and modified starch are used.

前記無機粉体、繊維及びバインダの配合割合は、主に不
燃性石膏ボードとなったときに要求される耐火度により
決定されるが、一般的には無機粉体20〜90重量%(
以下%は重量%を表わス)、パルプ5〜50%、バイン
ダ2〜20%である。無機粉体が20%以下では耐火性
が劣り、90%以上では十分な強度を有するシートが得
難くなる。特に水酸化アルミニウムまたは水酸化マグネ
シウムを無機粉体中5%以上使用することが望ましい。
The proportions of the inorganic powder, fibers, and binder are determined mainly by the fire resistance required for noncombustible gypsum board, but generally the inorganic powder is 20 to 90% by weight (
% represents weight %), pulp is 5 to 50%, and binder is 2 to 20%. If the amount of inorganic powder is less than 20%, the fire resistance will be poor, and if it is more than 90%, it will be difficult to obtain a sheet with sufficient strength. In particular, it is desirable to use 5% or more of aluminum hydroxide or magnesium hydroxide in the inorganic powder.

前記不燃性石膏ボード原紙の石膏に接する層は、基本的
には無サイズで新聞故紙を主体とする吸水性紙料よりな
る。
The layer of the non-combustible gypsum board base paper that is in contact with the gypsum is basically made of a water-absorbing paper stock of no size and mainly consisting of waste newspaper.

前述の各材料からシートを得る方法としては、周知の各
種の方法を用いることができるが、繊維材料がパルプで
ある場合は、無機粉体、バルブおよびバインダ等からな
る混合物スラ、りを抄紙機によって抄造する方法が一般
的である。前述原紙の抄造の際、前記不燃性紙料による
層を最外層とし、従来の石膏ボード原紙同様下層を接着
層とし場合により中間層を設け、各層を抄き合わせて多
層構造とすることは、多層抄き抄紙機により実現可能と
なる。
Various well-known methods can be used to obtain sheets from each of the above-mentioned materials, but when the fiber material is pulp, a mixture slurry consisting of inorganic powder, valves, binder, etc. A common method is to make paper by. When making the above-mentioned base paper, the layer made of the above-mentioned non-combustible paper stock is the outermost layer, the lower layer is an adhesive layer like the conventional gypsum board base paper, and if necessary, an intermediate layer is provided, and each layer is combined to form a multilayer structure. This can be realized using a multi-layer paper machine.

作     用 本発明は、前述の構成とすることにより健康上有害なア
スベストを一切使用することがなく、石膏ポートの裏面
を構成する石膏ボード原紙の層が不燃性層よりなるので
、石膏ボードとして難燃度の高い不燃性石膏ボードを得
ることができる。
Function The present invention, having the above-mentioned structure, does not use any asbestos that is harmful to health, and since the layer of gypsum board base paper that forms the back side of the gypsum port is made of a nonflammable layer, it is difficult to use as a gypsum board. Noncombustible gypsum board with high flammability can be obtained.

実  施  例 以下本発明の構成を図面に示す実施例に基いて説明する
Embodiments The structure of the present invention will be explained below based on embodiments shown in the drawings.

尚以下の実施例中の「部」および「%」はそれぞれ固形
分重量部および重量%を示す。
In addition, "part" and "%" in the following examples indicate solid content parts by weight and weight %, respectively.

〔実施例1〕 以下に示す原料配合で混合した紙料を用いて常法により
抄紙機で抄造し、坪量2801//rr?の、第1図に
示す如き、2層構造の不燃性石膏ボード原料を得た。
[Example 1] Using a paper stock mixed with the raw material composition shown below, a paper was made using a paper machine in a conventional manner to produce a paper with a basis weight of 2801//rr. A noncombustible gypsum board raw material having a two-layer structure as shown in FIG. 1 was obtained.

配合組成 a、不燃性層      (坪量180g/F7/>バ
ルブ         18  部 新聞故紙        14〃 ガラス繊維       1 〃 水酸化アルミニウム   20〃 タルク          41〃 SBRラテツクス     6 〃 硫酸バンド          0.5%ポリアミド・
エピクロルヒドリン湿潤紙力向上剤         
  0.5%アクリルスチレン系共重合体サイズ剤 2.5% 凝集剤            0.1〃b0石膏層接
着層(吸水性紙量層) (坪量100y / Trl) 新聞故紙       100  部 バンド           1.2%前述の配合組成
により抄造された不燃性石膏ボード原紙の吸水性紙料層
例を上面とし、前記原紙上に石膏スラリを流展し、成形
、加熱乾燥して石膏ボードを作成した。該石膏ボードの
燃焼テスト結果は次の如くである。
Blend composition a, non-flammable layer (Basic weight 180g/F7/> Bulb 18 parts Newspaper waste 14 Glass fiber 1 Aluminum hydroxide 20 Talc 41 SBR latex 6 Sulfuric acid band 0.5% polyamide
Epichlorohydrin wet paper strength improver
0.5% Acrylic styrene copolymer sizing agent 2.5% Coagulant 0.1 b0 Gypsum layer adhesive layer (water-absorbing paper layer) (Basic weight 100y/Trl) Waste newspaper 100 parts Band 1.2% A gypsum board was prepared by spreading a gypsum slurry onto the base paper, forming it, and drying it by heating, using the water-absorbing paper layer example of the noncombustible gypsum board base paper made from the above-mentioned composition as the upper surface. The combustion test results of the gypsum board are as follows.

テスト方法・・・・・・JISA−1321結果: 単位面積当り発煙係数(Ca)    24.9残炎時
間            0秒全厚さにわたる溶融亀
裂等(朋)  無し有害な変形等          
無し排気温度曲線     標準温度曲線内前記結果か
ら明かな如く、本実施例の不燃性石膏ボード原紙を使用
した石膏ボードは難燃1級である。
Test method: JISA-1321 results: Smoke generation coefficient (Ca) per unit area: 24.9 Afterflame time: 0 seconds No melt cracks, etc. throughout the entire thickness, etc. No harmful deformation, etc.
None Exhaust temperature curve Inside standard temperature curve As is clear from the above results, the gypsum board using the noncombustible gypsum board base paper of this example is flame retardant class 1.

更に、前記石膏ボードを折り曲げて破断面を観察したと
ころ、前記石膏層と不燃性石膏ボード原紙との間で剥離
は見られず、乾燥接着性は良好で、前記原紙は十分な接
着力を有するものであった。
Furthermore, when the gypsum board was bent and the fractured surface was observed, no peeling was observed between the gypsum layer and the noncombustible gypsum board base paper, and the dry adhesion was good, and the base paper had sufficient adhesive strength. It was something.

また、前記石膏ボードを20°C9湿度95%下で1時
間保持した後、該石膏ボードを折り曲げて破断面を観察
したところ、前記石膏層と原紙との間で剥離はなく、十
分な接着力を保持していた。即ち高湿接着性も良好であ
った。
Furthermore, after holding the gypsum board at 20°C and 95% humidity for 1 hour, the gypsum board was bent and the fractured surface was observed. There was no peeling between the gypsum layer and the base paper, and sufficient adhesive strength was observed. was held. That is, the high-humidity adhesion was also good.

〔実施例2〕 以下に示す原料配合で混合した紙料を用いて常法により
抄紙機で抄造し、坪量280g/rlの、第2図に示す
如き、3層構造の不燃性石膏ボード原紙を得た。
[Example 2] A non-combustible gypsum board base paper with a three-layer structure as shown in Fig. 2 and having a basis weight of 280 g/rl was produced using a paper stock mixed with the raw material composition shown below using a paper machine in a conventional manner. I got it.

配合組成 a、不燃性層      (坪量80.jil/m’)
パルプ         18  部 ガラス繊維       1 〃 水酸化アルミニウム   25〃 タルク         50〃 SBRラテックス     6 〃 硫酸バンド           1%ポリアミド・エ
ピクロルヒドリン湿潤紙力向上剤          
 0.5%アクリルスチレン系共重合体サイズ剤 2.5% 凝集剤            0.2%C1中間層 
      (坪量100,9’/イ)新聞故紙   
     55  部 雑誌故紙        27〃 水酸化アルミニウム   6 〃 タルク         12〃 サイズ            0,8%硫酸バンド 
         5.4%b、 接着層(吸水性紙料
層)(坪量100y/rI?)新聞故紙       
 100部 バンド            1.2%前述の配合組
成により抄造された不燃性石膏ボード原紙を使用して、
前実施例同様に石膏ホードを作成した。該石膏ボードの
燃料テスト結果は次の如くである。
Blend composition a, nonflammable layer (basis weight 80.jil/m')
Pulp 18 parts Glass fiber 1 Aluminum hydroxide 25 Talc 50 SBR latex 6 Band sulfate 1% polyamide/epichlorohydrin wet paper strength agent
0.5% Acrylic styrene copolymer sizing agent 2.5% Flocculant 0.2% C1 intermediate layer
(Basic weight 100,9'/a) Waste newspaper
55 Magazine waste paper 27〃 Aluminum hydroxide 6〃 Talc 12〃 Size 0.8% sulfuric acid band
5.4%b, adhesive layer (water-absorbing paper layer) (basis weight 100y/rI?) Waste newspaper
100 parts band 1.2% Using non-combustible gypsum board base paper made with the above-mentioned composition,
A gypsum hoard was made in the same manner as in the previous example. The fuel test results for the gypsum board are as follows.

テスト方法・・・・・・JISA−1321結果: 単位面積当り発煙係数(Ca)    18.7残炎時
間            0秒全厚さにわたる溶解亀
裂等(朋)  無し有害な変形等          
無し排気温度曲線     標準温度回線内前記結果か
ら明らかな如く、本実施例の不燃性石膏ボード原紙を使
用した石膏ボードは難燃1級である。
Test method: JISA-1321 results: Smoke generation coefficient (Ca) per unit area: 18.7 Afterflame time: 0 seconds No dissolution cracks throughout the entire thickness (tomo) No harmful deformation, etc.
None Exhaust Temperature Curve Inside Standard Temperature Line As is clear from the above results, the gypsum board using the noncombustible gypsum board base paper of this example is flame retardant class 1.

更に、前実施例同様乾燥接着性および高湿接着性のテス
ト結果も良好であった。
Furthermore, as in the previous example, the test results for dry adhesion and high humidity adhesion were also good.

発明の効果 前述の構成をなす本発明の不燃性石膏ボード原紙は、前
記説明で明かな通り、下記の諸効果を奏する。
Effects of the Invention As is clear from the above description, the noncombustible gypsum board base paper of the present invention having the above-mentioned configuration has the following effects.

イ6健康上有害なアスベストを使用しない。B6: Do not use asbestos, which is harmful to health.

口0石膏ボードの表面層に含まれる可燃物材料が不燃性
無機粉体中に存在するため、石膏ボードとして難燃度が
高くなる。
Since the combustible material contained in the surface layer of the gypsum board is present in the nonflammable inorganic powder, the gypsum board has a high degree of flame retardancy.

ハ、材料の配合により、所望の難燃度および強度を有す
る不燃性石膏ボードの製造が可能である。
C. Noncombustible gypsum board with desired flame retardancy and strength can be manufactured by mixing the materials.

二2石膏層と原紙との間の接着層が従来の石膏ボード原
紙と同じ組成であるため、石膏スラリーと原紙との接着
性が良好である。
22 Since the adhesive layer between the gypsum layer and the base paper has the same composition as the conventional gypsum board base paper, the adhesiveness between the gypsum slurry and the base paper is good.

ホ、従来の石膏ボード原紙と同じ組成の接着層を有する
ため、抄紙機による抄造時にあっても抄紙機の金網、フ
ェルト、カンバス等の諸抄紙要具に関する要具トラブル
等が発生せず、原紙抄造の生産性が良好である。
E. Since it has an adhesive layer with the same composition as conventional gypsum board base paper, there is no problem with various paper making tools such as wire mesh, felt, canvas, etc. of the paper machine even during paper making using a paper machine, and the base paper The productivity of papermaking is good.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は二層構造の実施例の拡大断面図、第2図は三層
構造の実施例の拡大断面図である。 a:不燃性層、b:吸水性紙料層、C:中間層O
FIG. 1 is an enlarged sectional view of a two-layer structure embodiment, and FIG. 2 is an enlarged sectional view of a three-layer structure embodiment. a: Nonflammable layer, b: Water-absorbing paper layer, C: Intermediate layer O

Claims (1)

【特許請求の範囲】 1、石膏層を積層して石膏ボードを形成する多層構造の
石膏ボード原紙において、該石膏 ボード原紙の表層がアスベストを含まない無機粉体を主
体とする不燃性層からなり、裏層が吸水性紙料層からな
ることを特徴とする不燃性石膏ボード原紙。 2、石膏層を積層して石膏ボードを形成する多層構成の
石膏ボード原紙において、該石膏 ボード原紙の表層がアスベストを含まない無機粉体を主
体とする不燃性層からなり、裏層が吸水性紙料層からな
り、中間層が非吸水性紙料層からなることを特徴とする
不燃性石膏ボード原紙。 3、無機粉体を主体とする不燃性層が水酸化アルミニウ
ムまたは水酸化マグネシウムを5重量%以上含有する不
燃性層である特許請求の範囲第1項または第2項記載の
不燃性石膏 ボード原紙。
[Claims] 1. A gypsum board base paper with a multilayer structure in which gypsum layers are laminated to form a gypsum board, in which the surface layer of the gypsum board base paper is composed of a noncombustible layer mainly composed of inorganic powder that does not contain asbestos. , a noncombustible gypsum board base paper characterized by a backing layer consisting of a water-absorbing paper stock layer. 2. In a gypsum board base paper with a multilayer structure in which gypsum layers are laminated to form a gypsum board, the surface layer of the gypsum board base paper is composed of a noncombustible layer mainly composed of inorganic powder that does not contain asbestos, and the back layer is water absorbent. A noncombustible gypsum board base paper comprising a paper stock layer, and an intermediate layer consisting of a non-water-absorbing paper stock layer. 3. The noncombustible gypsum board base paper according to claim 1 or 2, wherein the noncombustible layer mainly composed of inorganic powder is a noncombustible layer containing 5% by weight or more of aluminum hydroxide or magnesium hydroxide. .
JP28337387A 1987-11-10 1987-11-10 Incombustible gypsum board base paper Pending JPH01132899A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28337387A JPH01132899A (en) 1987-11-10 1987-11-10 Incombustible gypsum board base paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28337387A JPH01132899A (en) 1987-11-10 1987-11-10 Incombustible gypsum board base paper

Publications (1)

Publication Number Publication Date
JPH01132899A true JPH01132899A (en) 1989-05-25

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ID=17664661

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28337387A Pending JPH01132899A (en) 1987-11-10 1987-11-10 Incombustible gypsum board base paper

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JP (1) JPH01132899A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10377108B2 (en) * 2012-02-17 2019-08-13 United States Gypsum Company Gypsum products with high efficiency heat sink additives
WO2023037857A1 (en) * 2021-09-09 2023-03-16 凸版印刷株式会社 Self-extinguishing building material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5158414A (en) * 1974-11-20 1976-05-21 Yoshino Gypsum Co SETSUKOBOODOYOGENSHI
JPS5313557B2 (en) * 1975-04-15 1978-05-11
JPS5393557A (en) * 1977-01-24 1978-08-16 Masakatsu Makino Stone material rotary machine
JPS5347105B2 (en) * 1973-07-06 1978-12-19
JPS59157500A (en) * 1983-02-28 1984-09-06 児島 安喜 Method of filling up drilled hole for blasting
JPS59157397A (en) * 1983-02-26 1984-09-06 新富士製紙株式会社 Paperboard for gypsum board

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5347105B2 (en) * 1973-07-06 1978-12-19
JPS5158414A (en) * 1974-11-20 1976-05-21 Yoshino Gypsum Co SETSUKOBOODOYOGENSHI
JPS5313557B2 (en) * 1975-04-15 1978-05-11
JPS5393557A (en) * 1977-01-24 1978-08-16 Masakatsu Makino Stone material rotary machine
JPS59157397A (en) * 1983-02-26 1984-09-06 新富士製紙株式会社 Paperboard for gypsum board
JPS59157500A (en) * 1983-02-28 1984-09-06 児島 安喜 Method of filling up drilled hole for blasting

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10377108B2 (en) * 2012-02-17 2019-08-13 United States Gypsum Company Gypsum products with high efficiency heat sink additives
WO2023037857A1 (en) * 2021-09-09 2023-03-16 凸版印刷株式会社 Self-extinguishing building material

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