JPH01110953A - High moistureproof laminated film - Google Patents
High moistureproof laminated filmInfo
- Publication number
- JPH01110953A JPH01110953A JP26833987A JP26833987A JPH01110953A JP H01110953 A JPH01110953 A JP H01110953A JP 26833987 A JP26833987 A JP 26833987A JP 26833987 A JP26833987 A JP 26833987A JP H01110953 A JPH01110953 A JP H01110953A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- pvdc
- pctfe
- thickness
- laminated film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 claims abstract description 12
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 claims abstract description 12
- -1 polychlorotrifluoroethylene Polymers 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- 238000010030 laminating Methods 0.000 claims abstract description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 abstract description 31
- 229920001328 Polyvinylidene chloride Polymers 0.000 abstract description 9
- 239000005033 polyvinylidene chloride Substances 0.000 abstract description 9
- 238000003475 lamination Methods 0.000 abstract description 3
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 abstract description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 abstract description 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 abstract description 2
- 229920000098 polyolefin Polymers 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 239000012793 heat-sealing layer Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000005401 electroluminescence Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002639 bone cement Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
この発明は高防湿積層フィルムに関し、特にEL用の防
湿層、自動車用内装材、食品等の包装材として有効に利
用されるものでおる。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a highly moisture-proof laminated film, which is particularly effectively used as a moisture-proof layer for EL, interior materials for automobiles, and packaging materials for foods and the like.
(従来の技術)
従来から防湿性フィルムとして塩化ごニリデン樹脂層(
PVDC¥rJ)がポリエヂレデレフタレート(P E
T )やポリプロピレン(PP)フィルムに積層され
包装フィルムとして広く使用されている。(Conventional technology) Nylidene chloride resin layer (
PVDC¥rJ) is polyethylene derephthalate (P E
It is widely used as a packaging film by laminating it on T) or polypropylene (PP) film.
一方、ポリクロロトリフルオロエチレン樹脂口(PCT
FEIM)もエレクトロルミネセンス(EL)用の防湿
フィルムとして広く使用されている。On the other hand, polychlorotrifluoroethylene resin (PCT)
FEIM) is also widely used as a moisture barrier film for electroluminescence (EL).
(発明が解決しようとする問題点)
これら従来の技術で使用されるPVDCfmは、低温で
の防湿性に対し、高温での防湿性は若干悪くなるがそれ
程度化なくほぼ一定の防湿性を有する。(Problems to be Solved by the Invention) The PVDCfm used in these conventional technologies has almost constant moisture resistance at high temperatures, although the moisture resistance at high temperatures is slightly worse than at low temperatures. .
一方、PCTFE層はPVDC層に比し低温での防湿性
が秀れ、高温では劣る。On the other hand, the PCTFE layer has better moisture resistance at low temperatures than the PVDC layer, but is inferior at high temperatures.
従って、PVDC層は低温側で、PCTFE層は高温側
でそれぞれ防湿性に問題点がおり、その改善が望まれて
いた。(第1図参照)
(問題点を解決しようとする手段)
この発明はこれらの問題点を解決すべくなされたもので
あり、高温、低温のどちら側でも高防湿性を有するフィ
ルムを提供するものである。Therefore, the PVDC layer has problems with moisture resistance on the low temperature side, and the PCTFE layer has problems with moisture resistance on the high temperature side, and improvements have been desired. (See Figure 1) (Means for solving the problems) This invention was made to solve these problems, and provides a film that has high moisture resistance at both high and low temperatures. It is.
具体的には塩化ビニリデン樹脂層とポリクロロトリフル
オロエチレン樹脂層とを積層してなる高防湿積層フィル
ムでおる。Specifically, it is a highly moisture-proof laminated film formed by laminating a vinylidene chloride resin layer and a polychlorotrifluoroethylene resin layer.
即ち、全く新しい層構成の積層フィルムを提供するもの
である。That is, it provides a laminated film with a completely new layer structure.
PVDCeの厚みは50〜500A1m(好ましくは1
00〜300μmPCTFE層の厚みは50〜300μ
m(好ましくは100〜250μm)が良い。The thickness of PVDCe is 50 to 500 A1 m (preferably 1 m
00~300μm PCTFE layer thickness is 50~300μm
m (preferably 100 to 250 μm).
又、PVDC層とPCTFE層との積層は10〜30μ
m厚みの変性ポリオレフィン層(変性POI脅)、等を
介しての熱接竹や接骨剤によるラミネートや共押出によ
る積層でも良い。Also, the lamination thickness of the PVDC layer and PCTFE layer is 10 to 30μ.
It may also be laminated by thermal bonding or bone cement via a modified polyolefin layer (modified POI) having a thickness of m, or by co-extrusion.
pvoc層の上にはヒートシール層として20〜100
μm厚みの変性PIやエチレンビニールアルコール層等
を設けても良い。20 to 100 as a heat seal layer on top of the pvoc layer.
A modified PI, ethylene vinyl alcohol layer, etc. with a μm thickness may be provided.
更に保護層としてポリプロピレン層やポリエチレン層を
設けても良い。Furthermore, a polypropylene layer or a polyethylene layer may be provided as a protective layer.
(実施例)
PCTFEE/変性poe/pvoce/lニートシー
ル層の構成を有する積層フィルムを作成しその防湿度を
透湿度で測定し、PCTFE層単独、PVDCIm/ヒ
ートシール層のそれぞれの透湿度と比較した。結果は本
発明品の方が低温側i0i温側とも低透湿度を示し、防
湿性の良いものであった。(Example) A laminated film having a PCTFEE/modified poe/pvoce/l neat seal layer structure was created, and its moisture resistance was measured by moisture permeability, and compared with the moisture permeability of the PCTFEE layer alone and the PVDCIm/heat seal layer. did. The results showed that the product of the present invention exhibited lower moisture permeability on both the low temperature side and the i0i temperature side, and had better moisture resistance.
(発明の効果)
以上説明の様に、この発明は、従来の防湿フィルムより
も高防湿性を有するものである。(Effects of the Invention) As explained above, the present invention has higher moisture-proofing properties than conventional moisture-proofing films.
第1図はPVDC及びPCTFEの透湿度と温度との関
係を示す参考図である。FIG. 1 is a reference diagram showing the relationship between moisture permeability and temperature of PVDC and PCTFE.
Claims (1)
ン樹脂層とを積層してなる高防湿積層フィルム。A highly moisture-proof laminated film made by laminating a vinylidene chloride resin layer and a polychlorotrifluoroethylene resin layer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26833987A JPH01110953A (en) | 1987-10-26 | 1987-10-26 | High moistureproof laminated film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26833987A JPH01110953A (en) | 1987-10-26 | 1987-10-26 | High moistureproof laminated film |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01110953A true JPH01110953A (en) | 1989-04-27 |
Family
ID=17457170
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP26833987A Pending JPH01110953A (en) | 1987-10-26 | 1987-10-26 | High moistureproof laminated film |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01110953A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0398312A2 (en) * | 1989-05-18 | 1990-11-22 | M & FC HOLDING COMPANY, INC. | Moisture resistant laminated cover, its production and its use in an electronic utility meter |
DE102008056123A1 (en) * | 2008-11-06 | 2010-05-12 | Klöckner Pentaplast GmbH & Co. KG | Multilayer film |
CN106313834A (en) * | 2016-08-25 | 2017-01-11 | 四川汇利实业有限公司 | Moisture resistance packaging film |
US11858241B2 (en) | 2018-05-29 | 2024-01-02 | Klöckner Pentaplast Gmbh | Transparent polymer film with discolouration compensation |
US11891479B2 (en) | 2020-11-18 | 2024-02-06 | Klöckner Pentaplast Of America, Inc. | Thermoformed packaging and methods of forming the same |
-
1987
- 1987-10-26 JP JP26833987A patent/JPH01110953A/en active Pending
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0398312A2 (en) * | 1989-05-18 | 1990-11-22 | M & FC HOLDING COMPANY, INC. | Moisture resistant laminated cover, its production and its use in an electronic utility meter |
DE102008056123A1 (en) * | 2008-11-06 | 2010-05-12 | Klöckner Pentaplast GmbH & Co. KG | Multilayer film |
JP2012507410A (en) * | 2008-11-06 | 2012-03-29 | クレックナー ペンタプラスト ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト | Multilayer film |
DE102008056123B4 (en) * | 2008-11-06 | 2017-11-16 | Klöckner Pentaplast Gmbh | Multilayer film and blister packaging |
EP2344401B1 (en) * | 2008-11-06 | 2018-10-24 | Klöckner Pentaplast GmbH | Multi-layer film |
CN106313834A (en) * | 2016-08-25 | 2017-01-11 | 四川汇利实业有限公司 | Moisture resistance packaging film |
US11858241B2 (en) | 2018-05-29 | 2024-01-02 | Klöckner Pentaplast Gmbh | Transparent polymer film with discolouration compensation |
US11891479B2 (en) | 2020-11-18 | 2024-02-06 | Klöckner Pentaplast Of America, Inc. | Thermoformed packaging and methods of forming the same |
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