JPH01104887A - Dyeing of bloended fiber - Google Patents
Dyeing of bloended fiberInfo
- Publication number
- JPH01104887A JPH01104887A JP62069932A JP6993287A JPH01104887A JP H01104887 A JPH01104887 A JP H01104887A JP 62069932 A JP62069932 A JP 62069932A JP 6993287 A JP6993287 A JP 6993287A JP H01104887 A JPH01104887 A JP H01104887A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- dyeing
- group
- bath
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 35
- 239000000835 fiber Substances 0.000 title claims abstract description 22
- 239000000975 dye Substances 0.000 claims abstract description 30
- 229920000728 polyester Polymers 0.000 claims abstract description 19
- 239000000985 reactive dye Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000000986 disperse dye Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 10
- 239000001913 cellulose Substances 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 4
- 239000002253 acid Substances 0.000 claims description 7
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 238000010016 exhaust dyeing Methods 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 abstract description 8
- -1 (substituted) phenylene Chemical group 0.000 abstract description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000460 chlorine Substances 0.000 abstract description 6
- 229910052736 halogen Inorganic materials 0.000 abstract description 2
- 150000002367 halogens Chemical group 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000006172 buffering agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- 241001185311 Lyticum Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- LVWZTYCIRDMTEY-UHFFFAOYSA-N metamizole Chemical compound O=C1C(N(CS(O)(=O)=O)C)=C(C)N(C)N1C1=CC=CC=C1 LVWZTYCIRDMTEY-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
- C09B62/507—Azo dyes
- C09B62/513—Disazo or polyazo dyes
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は混合繊維の染色法に関するもので、詳シくは、
セルロースとポリエステルを含有する混合繊維を反応染
料と分散染料とを用いて、ｐＨ７〜ＩＯで、７００〜１
５０℃の温度にて一浴で吸尽染色する方法に関するもの
である。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for dyeing mixed fibers.
Mixed fibers containing cellulose and polyester are treated with reactive dyes and disperse dyes at pH 7-IO to 700-1
This invention relates to a method of exhaust dyeing in one bath at a temperature of 50°C.
（従来の技術）
近年、ポリエステル／セルロース混合繊維を分散染料と
反応染料を併用して、従来、ポリエステル繊維の染色条
件として採用されているｐＨ７〜ＩＯで、しかも１００
〜／ｊＯ℃の高温において、−浴一段で染色する研究が
なされているが、−船釣に反応染料はｐＨ／ｘ以上では
セルロース繊維に対して良好カ染色性を示すものの、〆
（７０以下の低ｐＨ域では染色性が不良であシ、また１
００℃以上の高温では構造的に不安定なものも多い。(Prior art) In recent years, polyester/cellulose mixed fibers have been dyed using a combination of disperse dyes and reactive dyes to dye them at pH 7 to IO, which has conventionally been used as the dyeing condition for polyester fibers, and at pH 100.
Research has been conducted to dye cellulose fibers in a single step at high temperatures of ~/jO℃; The stainability is poor in the low pH range of
Many of them are structurally unstable at high temperatures of 00°C or higher.
そこで、最近、このような染色法に適する反応染料がい
くつか提案されており、例えば、下記構造式ＣＡ：ｌ、
［：Ｂ〕で示される染料が知られている。Therefore, recently, several reactive dyes suitable for such dyeing methods have been proposed. For example, the following structural formula CA: l,
Dyes represented by [:B] are known.
・・・・・・・・・［Ａ）
（ａ、Ｘ、リアクティブ ブラックｊ）しかしながら、
上記構造式〔Ａ〕で示される反応染料は、化合物中に反
応基となるビニル基を、２個有しているにもかかわらず
、上述した高温の染色条件下では反応率が十分とは言え
ず、また、耐塩素堅牢度が不良である等の問題点を有し
ている。・・・・・・・・・[A) (a, X, Reactive Black j) However,
Although the reactive dye represented by the above structural formula [A] has two vinyl groups that serve as reactive groups in the compound, the reaction rate is not sufficient under the above-mentioned high-temperature dyeing conditions. Moreover, it also has problems such as poor chlorine fastness.
一方、上記構造式ＣＢ〕で示される反応染料は、上記構
造式ＣＡ）で示される染料に比較して耐塩素堅牢度は優
れているものの、反応率が低いことに起因する染着性不
良、更にはビルドアツプ性不良等の問題点を有している
。On the other hand, although the reactive dye represented by the above structural formula CB has superior chlorine fastness compared to the dye represented by the above structural formula CA), it has poor dyeability due to a low reaction rate. Furthermore, there are other problems such as poor build-up performance.
（発明が解決しようとする問題点）
本発明者等は上記実情に鑑み、公知の反応染料の中でも
、特定の構造を有する、高温、低〆１域の染色条件下で
染色性が極めて良好な反応染料を用いて、混合繊維中の
セルロースを、従来、ポリエステルの染色条件として採
用されている高温で、且つ、低…域でも良好に染色する
ことのできる染色法を提供しようとするものである。(Problems to be Solved by the Invention) In view of the above-mentioned circumstances, the present inventors have discovered that, among known reactive dyes, they have a specific structure and have extremely good dyeability under dyeing conditions of high temperature and low dyeing range 1. The purpose of the present invention is to provide a dyeing method that uses reactive dyes to dye cellulose in mixed fibers well at high temperatures and low... .
（問題点を解決するための手段）
すなわち、本発明の要旨は、セルロース及びポリエステ
ルを含有する混合繊維を反応染料と分散染料を用いて、
ｐＨｓ〜／θで、１００〜１５０℃の温度にて一浴で吸
尽染色する方法において、反応染料として遊離酸の形で
下記−最大〔■〕
ＢＯ３Ｈ”Ｌ’８”
〔式中、Ａは置換基を有していてもよいフェニレン基を
示し Ｒ１は水素原子または低級アルキル基を示し、ｎ
けθまたは／を示し、Ｘはハロゲンぶ子を示し、Ｙは−
５ｏ２ａＨ＝ ＯＨ，基５、または−８ｐ２Ｃ２Ｈ４Ｗ
基（ここで、Ｗはアルカリの作用によって脱離する基を
示す）を示す〕
で表わされる水溶性テトラアゾ染料を用いることを特徴
とする混合繊維の染色法に存する。(Means for Solving the Problems) That is, the gist of the present invention is to produce a mixed fiber containing cellulose and polyester using a reactive dye and a disperse dye.
In the method of exhaust dyeing in one bath at a temperature of 100 to 150 °C at pHs ~ / θ, the following - maximum [■] BO3H"L'8" [in the formula, A is Represents a phenylene group which may have a substituent, R1 represents a hydrogen atom or a lower alkyl group, and n
ke θ or /, X represents a halogen button, Y represents -
5o2aH= OH, group 5, or -8p2C2H4W
group (wherein W represents a group that is eliminated by the action of an alkali)] A method for dyeing mixed fibers characterized by using a water-soluble tetraazo dye represented by the following.
以下、本発明の詳細な説明するに１本発明で反応染料と
して用いる前示一般式ＩＩＩ）で示される水溶性テトラ
アゾ化合物において、Ａで表わされる置換基を有してい
てもよいフェニレン基としては、フェニレン基または例
えば、炭素数ｌ〜ダの低級アルキル基、低級アに；キシ
基あるいは塩素原子、弗素原子などのハロゲン原子で置
換されたフェニレン基が挙げられ、これらの具体例とし
ては、次のものが挙げられる。In the following, the present invention will be described in detail. In the water-soluble tetraazo compound represented by the general formula III) used as a reactive dye in the present invention, the phenylene group which may have a substituent represented by A is , a phenylene group or, for example, a lower alkyl group having 1 to 2 carbon atoms, a phenylene group in which the lower atom is substituted with an xy group or a halogen atom such as a chlorine atom or a fluorine atom. Specific examples of these include the following: Examples include:
ＬＪＩ、Ｉ４８
Ｒ１で表わされる低級アルキル基としては、例えば、メ
チル基、エチル基、プロピル基などの炭素数／〜グのア
ルキル基が挙げられる。Ｘで表わされるハロゲン原子と
しては、例えば塩素原子、フッ素原子または臭素原子が
挙げられる。Examples of the lower alkyl group represented by LJI, I48 R1 include alkyl groups having a carbon number of 1 to 3, such as a methyl group, an ethyl group, and a propyl group. Examples of the halogen atom represented by X include a chlorine atom, a fluorine atom, and a bromine atom.
更に、Ｗで表わされるアルカリの作用で脱離する基とし
ては通常、硫酸エステル基、チオ硫酸エステル基、リン
酸エステル基、酢酸エステル基、又はハロゲン原子など
が挙げられ、特に好ましくは硫酸エステル基が挙げられ
る。Further, the group represented by W which is eliminated by the action of an alkali usually includes a sulfate ester group, a thiosulfate ester group, a phosphate ester group, an acetate ester group, or a halogen atom, and particularly preferably a sulfate ester group. can be mentioned.
前示一般式ＣＩ）のテトラアゾ染料は遊離酸の形で、ま
たはその塩の形で存在するが、塩としては通常、アルカ
リ金属およびアルカリ土類金属塩で必シ、特にリチクム
塩、ナトリウム塩、カリウム塩が好ましい。The tetraazo dyes of general formula CI) are present in the free acid form or in the form of their salts, but the salts are usually alkali metal and alkaline earth metal salts, in particular lyticum salts, sodium salts, Potassium salts are preferred.
前示一般式ＣＩ）で表わされるテトラアゾ化合物は次の
ようにして製造することができる０例えば、下記式［■
）
（式中、ＡおよびＹは前記定義に同じ）で示されるモノ
アゾ化合物２モル割合に、下記式〔■〕
（式中、Ｒ’、ｎおよびＸは前記定義を示す。）で示さ
れるジアミノ化合物１モル割合をテトラゾ化した後、ア
ルカリ性でカップリングさせることによりＭ造すること
ができる。なお、反応液から目的物を伯るには通常の塩
析法が用いられるが、反応液をそのままスプレー乾燥す
るととＫよることも出来る。The tetraazo compound represented by the general formula CI) can be produced as follows.For example, the tetraazo compound represented by the following formula [■
) (wherein A and Y are the same as defined above) to 2 molar proportions of the monoazo compound represented by the following formula [■] (wherein R', n and X are as defined above): M can be produced by tetrazotizing 1 molar proportion of the compound and then coupling in alkaline conditions. Although the usual salting-out method is used to extract the target product from the reaction solution, it is also possible to spray dry the reaction solution as it is.
一方、本発明で用いるポリエステルを染色するための分
散染料としては、特に限定されるものでなく、例えば、
Ｏｏ’１ｏｕｒ Ｘｎｄｅｘ （第３版）Ｋ記載され
るような、ベンゼン系、ピリドン系、ピラゾロン系、チ
アゾール系あるいはベンゾチアゾール系などのモノアゾ
染料又はジスアゾ染料等が利用し得る。これらの分散染
料の使用割合は混合繊維中のポリエステルの割合によっ
て連室決定される。また、分散染料の使用に当りては、
常法に従って、分散剤及びその他助剤により分散染料組
成物を１４製する。On the other hand, the disperse dye for dyeing polyester used in the present invention is not particularly limited, and for example,
Monoazo dyes or disazo dyes such as benzene-based, pyridone-based, pyrazolone-based, thiazole-based or benzothiazole-based dyes as described in Oo'1our Xndex (3rd edition) K can be used. The proportion of these disperse dyes used is determined by the proportion of polyester in the mixed fiber. In addition, when using disperse dyes,
A disperse dye composition is prepared using a dispersant and other auxiliary agents according to a conventional method.
本発明で対象となるセルロース繊維としては、通常、木
綿、ビスコースレーヨン、キュプラアンモニウムレーヨ
ン、麻などである。また、ポリエステル繊維としては、
ポリエチレンテレフタレート、ポリブチレンテレフタレ
ートが代表的に挙げられる。セルｐ−スとポリエステル
を含有する混合繊維の形態は、通常、混紡布、混繊編物
又は不織布などである。Cellulose fibers targeted by the present invention are usually cotton, viscose rayon, cuproammonium rayon, hemp, and the like. In addition, as polyester fiber,
Typical examples include polyethylene terephthalate and polybutylene terephthalate. The form of the mixed fiber containing cellp-seed and polyester is usually a blended fabric, a blended knitted fabric, or a nonwoven fabric.
本発明において混合繊維を染色するには、前示一般式［
１〕のテトラアゾ染料及び分散染料組成物と一調整のた
めの（例えば、炭酸、リン酸、酢酸、クエン酸等の酸と
それらの酸のナトリウム塩またはカリウム塩の単一また
は混合物で通常ｏ、ｔ−ｒ、ｏｔ７を程度）、そして、
必要に応じて電解質（塩化ナトリウムまたは硫酸ナトリ
ウム等）を通常／−７７０９／を程度、特に好ま１、
（ハｕ Ｏ−Ｉ Ｏｆ ／ ｔを加えた染浴をＬ’１５
１１Ｌ、この染浴に混合繊維を加えて染色することがで
きる。In order to dye mixed fibers in the present invention, the general formula [
1) and the tetraazo dye and disperse dye composition (for example, acids such as carbonic acid, phosphoric acid, acetic acid, citric acid, and sodium salts or potassium salts of these acids, singly or in mixtures, usually o, tr, ot7 degree), and
If necessary, add an electrolyte (sodium chloride or sodium sulfate, etc.) usually to a level of -7709/, particularly preferably 1,
(L'15 dye bath with addition of O-I Of/t
11L, mixed fibers can be added to this dye bath for dyeing.
この染色浴の−は！〜１０．好ましくは７〜りに保持さ
れる。また、染色温度は７００〜７５０℃、好ましくは
／コＱ〜１４ｔｏ℃であり、染色時間は通常、３０〜！
θ分程度である。What is this dye bath? ~10. Preferably, it is maintained at 7 to 7. Further, the dyeing temperature is 700 to 750°C, preferably 14 to 14°C, and the dyeing time is usually 30 to 750°C.
It is about θ minutes.
本発明ではこのような染色条件においても、セルロース
繊維を前示一般式〔１〕のテトラアゾ染料によって良好
に染色することができる。このテトラアゾ染料の場合に
は、むしろ、１０〜６０℃の染色温度に比べ１００〜／
夕Ｑ℃の染色温度の方が、よシ優れた染色ができ、濃厚
な。In the present invention, even under such dyeing conditions, cellulose fibers can be favorably dyed with the tetraazo dye of the general formula [1]. In the case of this tetrazo dye, rather than the dyeing temperature of 10-60℃,
The dyeing temperature of evening Q℃ allows for better dyeing and thicker dyeing.
染色物を（Ｉることができる。したがって、本発明方法
によれば、セルロースとポリエステルの肉繊維を一浴一
段で良好に染色することができるので望ましい方法であ
る。Therefore, according to the method of the present invention, cellulose and polyester meat fibers can be dyed satisfactorily in one bath and in one step, so it is a desirable method.
（実施例）
以下、本発明の方法を実施例をあげて、さらに具体的に
説明するが、本発明は、以下の実施例等に限定されるも
のではない。(Examples) Hereinafter, the method of the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the following Examples.
実施例１
下記の構造式
で表わされるモノアゾ化合物−モル割合に、下記の構造
式
で表わされるジアミノ化合物／−１ニル割合を常法に従
いテトラゾ化した後、水媒中、θ′〜！℃の温度でｐＨ
２〜ｒの条件下、カップリングさせた。Example 1 After tetrazotizing a monoazo compound represented by the following structural formula to a molar ratio of a diamino compound represented by the following structural formula/-1 nyl according to a conventional method, θ'~! pH at temperature in °C
Coupling was carried out under conditions of 2 to r.
カップリング終了後、塩化カリウムで塩析、濾過、乾燥
して、下記の構造式（遊離酸の形で示す。）および最大
吸収波長を有するテトラアゾ染料を得た。After the coupling was completed, the mixture was salted out with potassium chloride, filtered, and dried to obtain a tetraazo dye having the following structural formula (shown in free acid form) and maximum absorption wavelength.
（λｍａＸ ｊり４ｔｎｍ（水））
上記のようにして得られたテトラアゾ染料θ、２ｆ１芒
硝／ ｊ ？、緩衝剤としてＮａ２ＨＰＯ４−コＨ２０
θ、４ｔｙおよびｘａ２ｐｏ４θ、／ ｆを水２０θｄ
に加えて一一７に調装した染浴に未シルケット綿メリヤ
ス１０ｔを入れ３０分を要して／２０℃迄昇温し、同温
度でｄＯ分間染色した後、水洗、ンービング、水洗、乾
燥を行いネービーブルー色の染色物を得た。本染料は染
着ｙｒｏ％と非常に良好で、苅られ先染色物は極めて濃
厚であシ耐光堅牢度クー！級、耐塩素堅牢度（Ｊ工Ｓ
Ｌ＃Ｊ”４ｔ ／θＩ！ＩＩ）４を級と良好であった。(λmaX j = 4tnm (water)) Tetraazo dye θ obtained as above, 2f1 Glauber's salt/j ? , Na2HPO4-coH20 as buffering agent
θ, 4ty and xa2po4θ,/f water 20θd
In addition, 10 tons of unmercerized cotton knitted fabric was added to the dye bath prepared in 117, and the temperature was raised to 20℃ over 30 minutes. After dyeing at the same temperature for dO minutes, washing, annealing, washing, and drying. A navy blue dyed product was obtained. This dye has a very good dyeing rate of yro%, and the dyed product is extremely thick and has a light fastness of 100%. class, chlorine fastness (J Engineering S
L#J"4t/θI!II) It was good with a grade of 4.
実施例コ
実施例／に記載のテトラアゾ染料０．２ｆおよび
で示される公知のポリエステル用モノアゾ染料０．２
ｆ 、芒硝／コｔ、緩衝剤としてＮａ２ＨＰＯ４＃４Ｈ
２０θ、４ｔｙおよびＫＨ，ＰＯ４０，／ ｆを水コθ
０ｄに加えて調装した染浴にポリエステル／木綿＝！θ
：！０の混紡布１０９を入れ３０分を要して／３０℃迄
昇湛し、同温度で５θ分間染色した後、水洗、ンーピン
ク、水洗、乾燥を行い同色性良好なネービーブルー色の
染色物をイｑた。Example 0.2f of the tetraazo dye described in Example 1 and 0.2 of the known monoazo dye for polyester shown in
f, mirabilite/cot, Na2HPO4#4H as a buffering agent
20θ, 4ty and KH, PO40, / f to water θ
In addition to 0d, polyester/cotton =! θ
:! 0 mixed fabric 109 was added and heated to 30°C for 30 minutes, dyed at the same temperature for 5θ minutes, washed with water, dyed with dark pink, washed with water, and dried to obtain a dyed navy blue color with good same color property. I was ready.
本染色浴は染色の前、後においてｐＨ７，７であった。This dyeing bath had a pH of 7.7 before and after dyeing.
また、染着性は非常に良好で得られた染色物は極めて濃
厚であシ耐光堅牢度、耐塩素堅牢度はいずれも良好であ
った。Furthermore, the dyeing property was very good, and the dyed product obtained was extremely dense, and both light fastness and chlorine fastness were good.
実施例３
第１表に示すテトラアゾ染料（遊離酸の形で示す。）を
実施例／の方法に準じて合成し、実施例／と同様の方法
で綿布を染色したところ、各々、良好な染色ができ、各
染布の染着率は２０％以上で、耐塩素堅牢度はグ級とい
ずれも良好であった。Example 3 The tetraazo dyes shown in Table 1 (shown in the form of free acids) were synthesized according to the method in Example/and cotton cloth was dyed in the same manner as in Example/. The dyeing rate of each dyed fabric was 20% or more, and the fastness to chlorine was good as grade 1.
すなわち、この結果よシ、本発明で特定する反応染料で
あるテトラアゾ染料は、従来、ポリエステルの染色条件
として採用されている条件においても、良好な染色性を
示すことが明らかであシ、このことからセルロースとポ
リエステルの混合繊維％−一浴一段染色した場合でも、
同様な好結果が有られると言うことが判る。In other words, from this result, it is clear that the tetraazo dye, which is the reactive dye specified in the present invention, exhibits good dyeing properties even under the conditions conventionally employed for dyeing polyester. Mixed fibers of cellulose and polyester from % - Even when dyed in one bath and one step,
It can be seen that similar good results can be obtained.
実施例ダ
実施例＝において、緩衝剤として炭酸水素ナトリウム０
．−２ｆ （染色浴−は、ｒ、４ｔに保持されることと
なる）を用いた以外は実施例２詫記載通シに行なった結
果、実施例−と同様に良好な染色ができ、得られた染色
物は極めて濃厚なものであった。In example d, sodium bicarbonate was used as a buffering agent.
．． As a result of carrying out the procedure as described in Example 2 except for using -2f (the dyeing bath was maintained at r and 4t), good dyeing was obtained in the same manner as in Example -. The dyed product was extremely deep.
実施例！
第−表に示すテトラアゾ染料（遊離酸の形で示す）を実
施例／の方法に準じて合成し、実施例ダと同様の方法で
ポリエステル／木綿＋！Ｏ：！０混紡布を染色したとこ
ろ、各々良好な染色ができた。Example! The tetraazo dyes shown in Table 1 (shown in free acid form) were synthesized according to the method of Example 1, and the polyester/cotton +! O:! When the 0 blend fabric was dyed, good dyeing was achieved in each case.
（発明の効果）
本発明で特定する反応染料であるテトラアゾ染料は従来
の高畠、低ｐＨ域のポリエステルの染色条件（１００〜
１５０℃、ｐＨｊ〜１０）でも良好な染色性を示すので
、本発明によれば、セルロースとポリエステルの混合繊
維を反応染料と分散染料を用いて、−浴一段で良好に染
色することができる。(Effects of the invention) The tetraazo dye, which is a reactive dye specified in the present invention, can be used under conventional Takahata, low pH dyeing conditions for polyester (100~
Since it shows good dyeability even at 150° C. and pH of 10), according to the present invention, mixed fibers of cellulose and polyester can be dyed well in a single bath using a reactive dye and a disperse dye.
特許出願人 三菱化成工業株式会社 代 理 人 弁理士 長谷用 − （ほか７名）Patent applicant: Mitsubishi Chemical Industries, Ltd. Representative Patent Attorney Hase - (7 others)
Claims (1)
を反応染料と分散染料とを用いて、ｐＨ５〜１０で１０
０〜１５０℃の温度にて一浴で吸尽染色する方法におい
て、反応染料として、遊離酸の形で下記一般式〔 I 〕 ▲数式、化学式、表等があります▼・・・・・・・・・
〔 I 〕 〔式中、Ａは置換基を有していてもよいフェニレン基を
示し、Ｒ＾１は水素原子または低級アルキル基を示し、
ｎは０または１を示し、Ｘはハロゲン原子を示し、Ｙは
−ＳＯ＿２ＣＨ＝ＣＨ＿２基または−ＳＯ＿２Ｃ＿２Ｈ
＿４Ｗ基（ここで、Ｗはアルカリの作用によって脱離す
る基を示す）を示す〕で表わされる水溶性テトラアゾ染
料を用いることを特徴とする混合繊維の染色法。(1) Mixed fibers containing cellulose and polyester are treated with reactive dyes and disperse dyes at pH 5 to 10.
In the method of exhaust dyeing in one bath at a temperature of 0 to 150℃, the following general formula [I] ▲Mathematical formula, chemical formula, table, etc. are used as a reactive dye in the form of a free acid▼・・・・・・・・・・・・
[I] [In the formula, A represents a phenylene group which may have a substituent, R^1 represents a hydrogen atom or a lower alkyl group,
n represents 0 or 1, X represents a halogen atom, Y represents -SO_2CH=CH_2 group or -SO_2C_2H
A method for dyeing mixed fibers, characterized by using a water-soluble tetraazo dye represented by _4W group (where W represents a group that is eliminated by the action of an alkali).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62069932A JPH0753953B2 (en) | 1986-05-23 | 1987-03-24 | Dyeing method for mixed fibers |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61-118593 | 1986-05-23 | ||
| JP11859386 | 1986-05-23 | ||
| JP62069932A JPH0753953B2 (en) | 1986-05-23 | 1987-03-24 | Dyeing method for mixed fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01104887A true JPH01104887A (en) | 1989-04-21 |
| JPH0753953B2 JPH0753953B2 (en) | 1995-06-07 |
Family
ID=26411104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62069932A Expired - Lifetime JPH0753953B2 (en) | 1986-05-23 | 1987-03-24 | Dyeing method for mixed fibers |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0753953B2 (en) |
-
1987
- 1987-03-24 JP JP62069932A patent/JPH0753953B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0753953B2 (en) | 1995-06-07 |
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