JPH01102002A - Germicidal disinfectant composition - Google Patents
Germicidal disinfectant compositionInfo
- Publication number
- JPH01102002A JPH01102002A JP26136487A JP26136487A JPH01102002A JP H01102002 A JPH01102002 A JP H01102002A JP 26136487 A JP26136487 A JP 26136487A JP 26136487 A JP26136487 A JP 26136487A JP H01102002 A JPH01102002 A JP H01102002A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- disinfectant
- alkenyl
- compound expressed
- sterilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000645 desinfectant Substances 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 230000002070 germicidal effect Effects 0.000 title abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 239000003623 enhancer Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 150000001450 anions Chemical class 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 244000144977 poultry Species 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 239000002023 wood Substances 0.000 abstract description 2
- 238000004321 preservation Methods 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 description 18
- 238000009472 formulation Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000001580 bacterial effect Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000249 desinfective effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000003206 sterilizing agent Substances 0.000 description 3
- 241000228212 Aspergillus Species 0.000 description 2
- 241000275031 Nica Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 241000222290 Cladosporium Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- REAYFGLASQTHKB-UHFFFAOYSA-N [2-[3-(1H-pyrazol-4-yl)phenoxy]-6-(trifluoromethyl)pyridin-4-yl]methanamine Chemical compound N1N=CC(=C1)C=1C=C(OC2=NC(=CC(=C2)CN)C(F)(F)F)C=CC=1 REAYFGLASQTHKB-UHFFFAOYSA-N 0.000 description 1
- SAHIZENKTPRYSN-UHFFFAOYSA-N [2-[3-(phenoxymethyl)phenoxy]-6-(trifluoromethyl)pyridin-4-yl]methanamine Chemical compound O(C1=CC=CC=C1)CC=1C=C(OC2=NC(=CC(=C2)CN)C(F)(F)F)C=CC=1 SAHIZENKTPRYSN-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000005757 colony formation Effects 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940088679 drug related substance Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- -1 flowables Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は殺菌消毒剤組成物に関し、詳しくは、食品工場
、畜舎、豚舎、鶏舎などの建物、環境の殺菌消毒、木材
の防腐、製紙工程での防腐など各種産業分野での防腐に
優れた効力を発揮し、或いは家庭など常時湿気を帯びた
トイレ、風呂場、台所などで繁殖しやすいカビなどに対
しても優れた殺菌消毒活性を発揮する、殺菌消毒剤組成
物に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a sterilizing disinfectant composition, and more specifically, it is used for sterilizing and disinfecting buildings such as food factories, livestock houses, pig houses, poultry houses, environments, preservatives of wood, and paper manufacturing processes. It exhibits excellent antiseptic effects in various industrial fields such as antiseptics, and also exhibits excellent sterilizing and disinfecting activity against mold that tends to grow in constantly humid rooms such as toilets, bathrooms, and kitchens. The present invention relates to a germicidal disinfectant composition.
殺菌消毒剤は、乳剤、水和剤、フロワブル剤、粉剤、く
ん煙剤などの剤型にて使用され“Ｃいる。Bactericidal disinfectants are used in the form of emulsions, wettable powders, flowables, powders, fumes, etc.
その際、原体の活性を十分に引き出すために製剤物性上
、種々の工夫がなされているが、殺菌消毒剤の効力を更
に増強させるまでには到っていない。At this time, various efforts have been made to improve the physical properties of the formulation in order to fully bring out the activity of the drug substance, but this has not yet led to further enhancement of the efficacy of the sterilizing agent.
よって、殺菌消毒剤の開発が一層困難な状況にある現在
、特に、既存殺菌消毒剤の活性を一層増強させることは
大いに意味のあることである。Therefore, it is of great significance to further enhance the activity of existing sterilizing disinfectants, especially as the development of sterilizing disinfectants is becoming increasingly difficult.
本発明者らは鋭意検討を積み重ねた結果、特定の化合物
が殺菌消毒剤に対して効力を顕著に増強させることを見
出し、本発明を完成した。As a result of extensive studies, the present inventors have discovered that a specific compound significantly enhances the efficacy of disinfectants, and have completed the present invention.
即ち本発明は、一般式（Ｉ）で表される化合物と一般式
（ＩＩ）で表される化合物とを重量比で１：１〜２０：
１の割合で含有することを特徴とする殺菌消毒剤組成物
を提供するものである。That is, the present invention provides a compound represented by general formula (I) and a compound represented by general formula (II) in a weight ratio of 1:1 to 20:
The present invention provides a sterilizing disinfectant composition characterized in that the composition contains 1 part of the sterilizing agent.
Ｒ，−Ｎ→０ ・・・（Ｉ）Ｒ５
〔式（Ｉ）中、ＲＩは炭素数１０〜１４のアルキル基又
はアルケニル基、Ｒ，、Ｒ，はそれぞれＣＨ３、ＣＨ２
ＣＨ３又は（ＣＨ２Ｃ）１２０） 、Ｈ（ｐは１〜１５
の整数）である。〕〔式（ｎ）中、Ｒ４、Ｒ５はメチル
基、エチル基、炭素数１０〜１４のアルキル基又はアル
ケニル基で、少なくとも一方は炭素数１０〜１４のアル
キル基又一般式（ＩＩ）における対アニオンＸは特に限
定されないが、好ましいものとして、ＣＨ，ＳＯ，、ハ
ロゲン原子（ＣＩ、 ［］ｒ、 Ｉ）、Ｃ，Ｈ５ＳＯ４
、ＨＯ（ＣＨ２） ｑＣＯＯ（ｑは１〜５の整数）等が
例示される。R, -N→0...(I)R5 [In formula (I), RI is an alkyl group or alkenyl group having 10 to 14 carbon atoms, R, , R, are CH3 and CH2, respectively
CH3 or (CH2C)120), H (p is 1-15
). [In formula (n), R4 and R5 are a methyl group, an ethyl group, an alkyl group having 10 to 14 carbon atoms, or an alkenyl group, and at least one of them is an alkyl group having 10 to 14 carbon atoms or a pair in general formula (II). The anion X is not particularly limited, but preferable ones include CH, SO, halogen atom (CI, []r, I), C, H5SO4
, HO(CH2) qCOO (q is an integer from 1 to 5), and the like.
なお、本発明に係る前記一般式（Ｉ）又は（ＩＩ）で表
される化合物は公知の方法で製造される。The compound represented by the general formula (I) or (II) according to the present invention is produced by a known method.
本発明に係る一般式（Ｉ）で表される化合物は殺菌消毒
剤の効力増強剤として用いられるものであり、中でも下
記の式（ＩＩＩ）又は（ＴＶ）で表される化合物が好適
である。The compound represented by the general formula (I) according to the present invention is used as an efficacy enhancer of a disinfectant, and among them, the compound represented by the following formula (III) or (TV) is suitable.
ＣＨ。CH.
ＣＨ，−（ＣＨ２）ｌｌ−１１→０ ・・
・（ＩＩＩ）ＣＨ。CH,-(CH2)ll-11→0...
・(III) CH.
〔式（ＩＩＩ）中、ｎは９〜１３の、整数である。〕（
ＣＨ，ＣＨ２０）、 Ｈ
■
ＣＨ３−（Ｃ）Ｉ２） 、、−Ｎ→ロ
・・・ （ｒＶ）（ＣＩＩ２［：ＬＤ
Ｌ Ｈ
〔式（ＩＶ）中、ｎは９〜１３、Ｘ、ｙはそれぞれ１〜
１５の整数である。[In formula (III), n is an integer of 9 to 13. 〕(
CH, CH20), H ■ CH3-(C)I2) , -N→Ro
... (rV) (CII2[:LD
L H [In formula (IV), n is 9 to 13, X and y are each 1 to
It is an integer of 15.
本発明に係る一般式（Ｉｆ）で表される化合物は殺菌消
毒剤として用いられるものであり、中でも下記の式（Ｖ
）〜（ＩＸ）で表される化合物が好適である。The compound represented by the general formula (If) according to the present invention is used as a sterilizing disinfectant, and among them, the compound represented by the following formula (V
) to (IX) are preferred.
（式中、ｎ＝９〜１３であり、ＸはＣＩ、 Ｏｒ又はＩ
である。）
（式中、ｎ＋ｍ ＝ ６〜ｌＯであり、ＸはＣ１、Ｂｒ
又はＩである。）
（式中、ｎ＋ｍ ＝１８〜２６であり、ＸはＣｌ５Ｄｒ
又は■である。）
（式中、ｎ＋ｍ ＝ ６〜１０であり、ＸはＣＩ、 Ｓ
ｒ又はＩである。）
（式中、ｎ＋ｍ ＝ ６〜１０であり、ＸはＣＩ、Ｏｒ
又はＩである。）
本発明の殺菌消毒剤組成物は、薬害なく効力を、前記一
般式（ＩＩ）で表される殺菌消毒剤単独の場合と比較し
て５〜１０倍増大させることができる。(In the formula, n = 9 to 13, and X is CI, Or or I
It is. ) (where n+m = 6~1O, X is C1, Br
Or I. ) (In the formula, n+m = 18 to 26, and X is Cl5Dr
Or ■. ) (where n+m = 6 to 10, X is CI, S
r or I. ) (where n+m = 6 to 10, X is CI, Or
Or I. ) The sterilizing disinfectant composition of the present invention can increase the efficacy by 5 to 10 times as compared to the case of the sterilizing disinfectant represented by the general formula (II) alone without causing chemical harm.
本発明に係る前記一般式（Ｉ）で表される効力増強剤の
使用量は、通常、前記一般式（ｎ）で表される殺菌消毒
剤に対し重量比で１：１〜１：２０が好ましい。The amount of the efficacy enhancer represented by the general formula (I) according to the present invention to be used is usually 1:1 to 1:20 by weight to the sterilizing agent represented by the general formula (n). preferable.
本発明の殺菌消毒剤組成物は、乳剤、フロワブル剤、水
和剤、粉剤、くん煙剤等、いずれの製剤型でも用いるこ
とができ、型は問わない。The sterilizing disinfectant composition of the present invention can be used in any formulation form, such as an emulsion, a flowable agent, a wettable powder, a powder, a smoke agent, etc., and the type does not matter.
従って、その製剤型に応じ、他の添加剤、例えば乳化剤
、分散剤、担体等を加えることができる。Therefore, depending on the formulation type, other additives such as emulsifiers, dispersants, carriers, etc. can be added.
本発明殺菌消毒剤組成物の使用に当たっては、上記各種
剤型中に入れて処方化する場合と、希釈使用時に別添に
て使用する方法があるが、どちらの方法にても本発明の
殺菌消毒剤組成物は効力増強効果が得られる。When using the sterilizing disinfectant composition of the present invention, there are two methods: formulating it by putting it into the various dosage forms mentioned above, and using it as a separate attachment when diluted. Disinfectant compositions can provide efficacy enhancement effects.
本発明の殺菌消毒剤組成物が、いかにしてこの様な顕著
な効力増強作用を呈するかについて。How the germicidal disinfectant composition of the present invention exhibits such a remarkable potency-enhancing effect.
の機作は必ずしも明らかではないが、本発明に係る前記
一般式（Ｉ）で表される効力増強剤が菌体表面の細胞膜
や脂質に作用し、前記一般式（ＩＩ）で表される殺菌消
毒剤の菌体内への浸透を促すものと推察される。Although the mechanism is not necessarily clear, the efficacy enhancer represented by the general formula (I) according to the present invention acts on cell membranes and lipids on the surface of bacterial cells, resulting in the bactericidal effect represented by the general formula (II). It is presumed that this promotes the penetration of the disinfectant into the bacterial cells.
次に具体例を挙げて本発明の殺菌消毒剤組成物を説明す
るが、本発明はこれらの実施例に限定されるものではな
い。Next, the sterilizing and disinfecting composition of the present invention will be explained by giving specific examples, but the present invention is not limited to these examples.
尚、以下に実施例で用いた本発明に係る効力増強剤（化
合物１〜４）と使用した殺菌消毒剤原体の構造、及び殺
菌消毒剤処方例を示す。In addition, the structures of the efficacy enhancers (compounds 1 to 4) according to the present invention used in Examples and the sterilizing disinfectant raw materials used, and examples of sterilizing disinfectant formulations are shown below.
■
ＣＩＪ２ｓ Ｎ→０
ＣＨｏ
督
Ｃ，、Ｈ，、−Ｎ−０
ｗＨｓ
Ｃｌ０８２１ Ｎ−０（×＋ｙは８）（Ｃｔｌ、ＣＨ
２０Ｌ Ｈ
■
Ｃ１□Ｈ２，−Ｎ→０
ＣＨ２Ｃｌ１．０）！
使用した殺菌消毒剤原体
く処 方 例〉
処方例１
化合物１ ４％
水 ９４ ％処方例２
殺菌消毒剤原体 ２％
化合物２ ４％
水 ９４ ％処方例３
殺菌消毒剤原体 ２％
化合物３ ４％
水 ９４ ％処方例４
殺菌消毒剤原体 ２％
化合物４ ４％
水 ９６ ％比較処方
例１
殺菌消毒剤原体 ６％
水 ９４ ％比較処方
例２
化合物１ ６％
水 ９４ ％実施例１
本発明の効力増強剤を用いた処方例１〜４、及び比較処
方例１〜２の殺菌消毒剤組成物を各種濃度に調整し、そ
の後、予め液体培地にて培養した大腸菌（Ｂｓｃｈｅｒ
ｉｃｈｉａ ｃｏｌｉ）、枯草菌（Ｂａ−ｃｉｌｌｕｓ
５ｕｂｔｉｌｉｓ）を５分間接触させ、その後集菌し
、新しい培地に植えつぎ、一定時間放置後、これらの菌
の生育状態を下記の基準にて評価した。■ CIJ2s N→0 CHo Kan C,, H,, -N-0 wHs Cl0821 N-0 (x+y is 8) (Ctl, CH
20L H ■ C1□H2, -N→0 CH2Cl1.0)! Examples of active disinfectant formulations used Prescription example 1 Compound 1 4% Water 94% Formulation example 2 Active disinfectant 2% Compound 2 4% Water 94% Formulation example 3 Active disinfectant 2% Compound 3 4% Water 94% Formulation Example 4 Disinfectant active ingredient 2% Compound 4 4% Water 96% Comparative Prescription Example 1 Sterilizing disinfectant active ingredient 6% Water 94% Comparative Formulation Example 2 Compound 1 6% Water 94% Example 1. The sterilizing disinfectant compositions of Prescription Examples 1 to 4 and Comparative Prescription Examples 1 to 2 using the efficacy enhancer of the present invention were adjusted to various concentrations, and then E. coli (Bscher
ichia coli), Bacillus subtilis
5ubtilis) for 5 minutes, and then the bacteria were collected, planted in a new medium, and left to stand for a certain period of time, and the growth status of these bacteria was evaluated based on the following criteria.
結果を表−１に示す。The results are shown in Table-1.
〈評 価〉
−生育せず（コロニーの形成なし）
± 僅かに生育（コロニー５個まで）
十 生育を示す（コロニー５個以上）
表−１
実施例２
正確に秤量した処方例１〜４及び比較処方例１〜２の殺
菌消毒剤組成物を水に溶解し、各種濃度に調整し、その
１−を９ｃｍのシャーレに流した。加温溶解した寒天培
地を９１ｒｄ！分注し、均一に混合して固化した。<Evaluation> - No growth (no colony formation) ± Slight growth (up to 5 colonies) 10 Showing growth (5 or more colonies) Table 1 Example 2 Accurately weighed formulation examples 1 to 4 and The disinfectant compositions of Comparative Formulation Examples 1 and 2 were dissolved in water, adjusted to various concentrations, and poured into a 9 cm petri dish. 91rd using heated and dissolved agar medium! The mixture was dispensed, mixed uniformly, and solidified.
各平板にアスペルギルス・ニカ−（Ａｓｐｅｒｇｉｌ
ｌｕｓｎｉｇｅｒ）、ボトリティス・シネリア（Ｂｏｔ
ｏｒｉｔｉｓｃｉｎｅｒｅａ） 、タラトスポリウム・
バーバリウム（Ｃｌａｄｏｓｐｏｒｉｕｍ ｈｅｒｂａ
ｒｉｕｍ）の試験菌を接種して、一定条件で培養後、発
育を完全に阻止する最小濃度（ｍｉｎｉｍｕｍ １ｎｈ
ｉｂｉｔｏｒｙ ｃｏｎｃｅｎｔｒａｔｉｏｎ ＭＩＣ
μｇ／−） を求めた。Aspergillus nica (Aspergillus nica) on each plate
lusniger), Botrytis cinerea (Bot
oritiscinerea), Talatosporium
Barbarium (Cladosporium herba)
After inoculating the test bacteria of M.rium and culturing under certain conditions, the minimum concentration that completely inhibits the growth (minimum 1nh
ibitory concentration MIC
μg/-) was determined.
その結果を表−２に示す。The results are shown in Table-2.
□□□□□□□□
表−２
実施例３
グロープシコース法に準じて、まず実験者の手にゴム手
袋をはめ、手袋内にサンプリング液を入れ、その上から
マツサージを行い、回収液を培養し、初期菌数値を求め
る。□□□□□□□□ Table-2 Example 3 According to the globe sicose method, first put rubber gloves on the experimenter's hands, put the sampling liquid into the gloves, perform pine surge over it, and collect the collected liquid. Culture and determine the initial bacterial count.
次に、処方例１〜４及び比較処方例１〜２の殺菌消毒剤
組成物を５００ｐｐｍに調整した液にて手指消毒−、ゴ
ム手袋をはめ、直後並びに３０分後、１時間後、２時間
後に初期菌数値測定と同様の操作で手指に残存する菌を
回収し、菌数値を求め、以下の式で滅菌率を求めた。Next, the hands were disinfected with a solution containing the sterilizing disinfectant compositions of Prescription Examples 1 to 4 and Comparative Prescription Examples 1 to 2 adjusted to 500 ppm, and rubber gloves were put on, immediately after, 30 minutes later, 1 hour later, and 2 hours later. Afterwards, the remaining bacteria on the hands and fingers were collected using the same procedure as the initial bacterial count measurement, the bacterial count was determined, and the sterilization rate was determined using the following formula.
その結果を表−３に示す。The results are shown in Table-3.
表−３ 出願人代理人 古 谷 馨Table-3 Applicant's agent Kaoru Furutani
Claims (1)
れる化合物とを重量比で１：１〜２０：１の割合で含有
することを特徴とする殺菌消毒剤組成物。 ▲数式、化学式、表等があります▼・・・（ I ） 〔式（ I ）中、Ｒ＿１は炭素数１０〜１４のアルキル
基又はアルケニル基、Ｒ＿２、Ｒ＿３はそれぞれＣＨ＿
３、ＣＨ＿２ＣＨ＿３又は（ＣＨ＿２ＣＨ＿２Ｏ）＿ｐ
Ｈ（ｐは１〜１５の整数）である。〕▲数式、化学式、
表等があります▼・・・（II） 〔式（II）中、Ｒ＿４、Ｒ＿５はメチル基、エチル基、
炭素数１０〜１４のアルキル基又はアルケニル基で、少
なくとも一方は炭素数１０〜１４のアルキル基又はアル
ケニル基、Ｒ＿５はＣＨ＿３、ＣＨ＿２ＣＨ＿３、▲数
式、化学式、表等があります▼又は▲数式、化学式、表
等があります▼、Ｒ＿７はＣＨ＿３又はＣＨ＿２ＣＨ＿
３、Ｘ＾■は対アニオンである。〕[Claims] A sterilizer characterized by containing a compound represented by general formula (I) and a compound represented by general formula (II) in a weight ratio of 1:1 to 20:1. Disinfectant composition. ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(I) [In formula (I), R_1 is an alkyl group or alkenyl group having 10 to 14 carbon atoms, and R_2 and R_3 are each CH_
3, CH_2CH_3 or (CH_2CH_2O)_p
H (p is an integer of 1 to 15). 〕▲Mathematical formula, chemical formula,
There are tables etc.▼...(II) [In formula (II), R_4 and R_5 are methyl group, ethyl group,
An alkyl group or alkenyl group having 10 to 14 carbon atoms, at least one of which is an alkyl group or alkenyl group having 10 to 14 carbon atoms, R_5 is CH_3, CH_2CH_3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Numerical formulas, chemical formulas, There are tables etc. ▼, R_7 is CH_3 or CH_2CH_
3. X^■ is a counter-anion. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26136487A JPH01102002A (en) | 1987-10-16 | 1987-10-16 | Germicidal disinfectant composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26136487A JPH01102002A (en) | 1987-10-16 | 1987-10-16 | Germicidal disinfectant composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01102002A true JPH01102002A (en) | 1989-04-19 |
Family
ID=17360815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26136487A Pending JPH01102002A (en) | 1987-10-16 | 1987-10-16 | Germicidal disinfectant composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01102002A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6172117B1 (en) | 1998-02-27 | 2001-01-09 | Akzo Nobel N.V. | Biocidal preservatives |
| WO2000059696A3 (en) * | 1999-04-08 | 2001-01-11 | Lonza Ag | Methods for enhancing penetration of wood preservatives |
| WO2010091280A1 (en) * | 2009-02-06 | 2010-08-12 | Alcon Research, Ltd. | N-halogenated amino acid formulations comprising phosphine or amine oxides |
| US8945655B2 (en) | 2007-07-10 | 2015-02-03 | Conopco, Inc. | Stable and consumable compositions |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3528209A1 (en) * | 1984-08-07 | 1986-04-24 | Fresenius AG, 6380 Bad Homburg | Disinfectant |
-
1987
- 1987-10-16 JP JP26136487A patent/JPH01102002A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3528209A1 (en) * | 1984-08-07 | 1986-04-24 | Fresenius AG, 6380 Bad Homburg | Disinfectant |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6172117B1 (en) | 1998-02-27 | 2001-01-09 | Akzo Nobel N.V. | Biocidal preservatives |
| WO2000059696A3 (en) * | 1999-04-08 | 2001-01-11 | Lonza Ag | Methods for enhancing penetration of wood preservatives |
| US6485790B2 (en) | 1999-04-08 | 2002-11-26 | Lonza Inc. | Methods for enhancing penetration of wood preservatives |
| EP1721713A1 (en) * | 1999-04-08 | 2006-11-15 | Lonza, Inc. | Methods and product for enhancing penetration of wood preservatives |
| US8945655B2 (en) | 2007-07-10 | 2015-02-03 | Conopco, Inc. | Stable and consumable compositions |
| WO2010091280A1 (en) * | 2009-02-06 | 2010-08-12 | Alcon Research, Ltd. | N-halogenated amino acid formulations comprising phosphine or amine oxides |
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