JPH01101398A - Solid detergent - Google Patents
Solid detergentInfo
- Publication number
- JPH01101398A JPH01101398A JP25938287A JP25938287A JPH01101398A JP H01101398 A JPH01101398 A JP H01101398A JP 25938287 A JP25938287 A JP 25938287A JP 25938287 A JP25938287 A JP 25938287A JP H01101398 A JPH01101398 A JP H01101398A
- Authority
- JP
- Japan
- Prior art keywords
- solid detergent
- present
- water
- solid
- clay mineral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013042 solid detergent Substances 0.000 title claims abstract description 19
- 239000002734 clay mineral Substances 0.000 claims abstract description 12
- 238000000465 moulding Methods 0.000 abstract description 7
- 230000000704 physical effect Effects 0.000 abstract description 4
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 abstract description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000271 hectorite Inorganic materials 0.000 abstract description 2
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 abstract description 2
- 229910052901 montmorillonite Inorganic materials 0.000 abstract description 2
- 229910000273 nontronite Inorganic materials 0.000 abstract description 2
- 229910052604 silicate mineral Inorganic materials 0.000 abstract description 2
- 229910021647 smectite Inorganic materials 0.000 abstract description 2
- 239000003599 detergent Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000003578 releasing effect Effects 0.000 abstract 1
- 229910000275 saponite Inorganic materials 0.000 abstract 1
- 239000000344 soap Substances 0.000 description 8
- -1 sabonite Inorganic materials 0.000 description 7
- 230000008961 swelling Effects 0.000 description 5
- 230000002950 deficient Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical class CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002522 swelling effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Chemical class 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- UTEKWVTZAYINIU-UHFFFAOYSA-N [F].[Si].[Si].[Si].[Si] Chemical compound [F].[Si].[Si].[Si].[Si] UTEKWVTZAYINIU-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229940035289 tobi Drugs 0.000 description 1
- NLVFBUXFDBBNBW-PBSUHMDJSA-N tobramycin Chemical compound N[C@@H]1C[C@H](O)[C@@H](CN)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O[C@@H]2[C@@H]([C@@H](N)[C@H](O)[C@@H](CO)O2)O)[C@H](N)C[C@@H]1N NLVFBUXFDBBNBW-PBSUHMDJSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/18—Water-insoluble compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、水ｌ１ｉｉｔｚ性粘土鉱物を配合した固型洗
浄料に関する。更に詳しくは、水膨潤性粘土鉱物を配合
することにより、離型性に優れた固型洗浄料を提供する
ものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a solid detergent containing a hydrophilic clay mineral. More specifically, by incorporating water-swellable clay minerals, a solid detergent with excellent mold release properties is provided.
［従来の技術］
固型洗浄料は、大別すると枠線りタイプと、機械練りタ
イプとに分けられる。これら固型洗浄料は、付加価値を
高めるために金型で各種形状に成型する技術は従来から
知られている。固型洗浄料は、各種の形状にするために
成型され、同時に刻印やマークを石鹸表面に打ち込んで
いる。しかしながら、固型洗浄料の物性にも左右される
が、はとんどの固型洗浄料は、成型時において金型から
の離型性が悪く、そのためカスの打ち込みが生じたり、
圧力があまりかけられない場合には、のびが不十分にな
り仕上りの外観に問題が生じたりしていた。また、離型
性が悪いとそれを良くするために作業中に洗浄したり、
あるいは溶剤を噴霧したりするため作業性が悪く時間が
かかるといった問題があった。[Prior Art] Solid detergents can be roughly divided into border type and mechanically kneaded type. Techniques for molding these solid detergents into various shapes using molds in order to increase their added value are conventionally known. Solid detergents are molded into various shapes, and at the same time stamps or marks are etched into the soap surface. However, although it depends on the physical properties of the solid detergent, most solid detergents have poor releasability from the mold during molding, resulting in dregs being driven into the mold.
If too little pressure is applied, the spread will be insufficient and problems will arise in the finished appearance. Also, if the mold release property is poor, you may need to wash it during work to improve it.
In addition, since the method involves spraying a solvent, there is a problem that the workability is poor and it takes a long time.
［発明が解決しようとする問題点］
本発明者らは、固型洗浄料の物性を変えることなく、固
型洗浄料の成型時における型離れに優れるものはないか
と鋭意研究した結果、水膨潤性粘土鉱物を配合すると、
この問題点が解決できることを見出し、本発明を完成す
るに至った。[Problems to be Solved by the Invention] As a result of intensive research into whether there is a method that can improve mold release during molding of solid detergents without changing the physical properties of the solid detergents, the present inventors found that water swelling When mixed with natural clay minerals,
The inventors have discovered that this problem can be solved and have completed the present invention.
［問題点を解決するための手段１
即ち、本発明は、水膨潤性粘土鉱物を配合することを特
徴とする固型洗浄料である。[Means for Solving the Problems 1] That is, the present invention is a solid detergent characterized by incorporating a water-swellable clay mineral.
以下本発明の構成について詳述する。The configuration of the present invention will be explained in detail below.
本発明に用いる水膨潤性粘土鉱物は、スメクタイト属に
属する層状ケイ酸塩鉱物であり、一般にはモンモリロナ
イト、バイデライト、ノントロナイト、サボナイト及び
ヘクトライト等があり、これらは天然又は合成品のいず
れであってもよい。The water-swellable clay mineral used in the present invention is a layered silicate mineral belonging to the genus smectite, and generally includes montmorillonite, beidellite, nontronite, sabonite, and hectorite, and these may be natural or synthetic. There may be.
市販品では、クニビア、スメタトン（いずれもクニミネ
工業）、ビーガム（パンダービルト社）、ラポナイト（
ラボルテ社）、フッ素四ケイ素雲母（トビ−工業）等が
利用できる。本発明の実施にあたっては、これらの水膨
潤性粘土鉱物のうちから、一種または二種以上が任意に
選択される。Commercially available products include Knivia, Smetatone (all manufactured by Kunimine Industries), Veegum (Panderbilt), and Laponite (
Laborte), fluorine tetrasilicon mica (Tobi Industries), etc. can be used. In carrying out the present invention, one or more kinds of these water-swellable clay minerals are arbitrarily selected.
本発明に用いられる水膨潤性粘土鉱物の配合量は、固型
洗浄料金量中０．１〜２０重量％が好ましく、さらに好
ましくは０．６〜１０重量％である。The amount of the water-swellable clay mineral used in the present invention is preferably 0.1 to 20% by weight, more preferably 0.6 to 10% by weight, based on the amount of solid cleaning material.
本発明に用いられる水膨潤性粘土鉱物は、原料そのまま
、もしくはボールミルあるいはアトマイザ−等により、
２〜１００μｍ程度に粉砕したものを用いる。The water-swellable clay mineral used in the present invention can be prepared as a raw material or by using a ball mill, an atomizer, etc.
Use one that has been pulverized to about 2 to 100 μm.
一般に固型洗浄料は、枠線り石けんと、機械練り石けん
に大別され、枠線り石けんにおいては透明、半透明、不
透明タイプに分類きれる。一方機械練り石けんは、石け
ん及び合成活性剤タイプに分類される。本発明の固型洗
浄料は、これらすべてのタイプに適用されるものである
。In general, solid detergents are broadly classified into borderline soaps and machine-mixed soaps, and borderline soaps can be classified into transparent, translucent, and opaque types. Machine-made soaps, on the other hand, are classified into soap and synthetic activator types. The solid cleaning agent of the present invention is applicable to all of these types.
本発明の固型洗浄料の基剤としては一般に使用される界
面活性剤、すなわち高級脂肪酸塩、アルキル硫酸塩、ア
シルイセチオン酸塩、Ｎ−アシル酸性アミノ酸塩、シ：
Ｉ糖脂肪酸エステル糖等が用いられ、これらは、一種又
は二種以上が任意に選択され用いられる。Commonly used surfactants as bases for the solid detergent of the present invention include higher fatty acid salts, alkyl sulfates, acyl isethionates, N-acyl acidic amino acid salts, and
I-saccharide fatty acid ester sugars and the like are used, and one or more of these may be arbitrarily selected and used.
ざらに、高級アルコール、スクワラン、ラノリン誘導体
、流動パラフィン糖の油性成分、プロピレングリコール
、グリセリン、ポリエチレングリコール、砂糖などの多
糖類糖の保湿剤、水溶性高分子物質（アニオン性、非イ
オン性、カチオン性のものも含む。）、ビタミン等の薬
剤、防腐剤、殺菌剤、紫外線吸収剤、酸化防止剤、動物
、植物抽出物あるいはその誘導体、色素、香料、ポリマ
ー微粉末等を本発明の効果を損なわない範囲で配合する
ことができる。Zara, higher alcohol, squalane, lanolin derivatives, oily components of liquid paraffin sugar, propylene glycol, glycerin, polyethylene glycol, humectants of polysaccharide sugars such as sugar, water-soluble polymer substances (anionic, nonionic, cationic) ), drugs such as vitamins, preservatives, disinfectants, ultraviolet absorbers, antioxidants, animal and plant extracts or their derivatives, pigments, fragrances, polymer fine powders, etc. can be used to achieve the effects of the present invention. It can be blended as long as it does not cause any damage.
［発明の効果１
本発明の水膨潤性粘土鉱物を配合してなる固型洗浄料は
、従来の物性をそのまま保ち、しかも成型時の離型性に
優れるため、カスの打ち込みや、仕上りの外観等に全く
問題のないものである。[Effect of the invention 1] The solid detergent compounded with the water-swellable clay mineral of the present invention maintains the conventional physical properties and has excellent mold releasability during molding, so there is no problem with the implantation of scum and the appearance of the finished product. etc., there is no problem at all.
［実施例］
次に実施例によって本発明を更に詳細に説明する。本発
明はこれにより限定されるものではない。[Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby.
実施例１〜６、比較例１〜３
表−１に記載の配合成分よりなる固型洗浄料を常法によ
り調整し、以下の評価方法で、成型時の型離れ及び膨潤
性について調べた。なお、水膨潤性粘土鉱物は、ボール
ミルにより粒径２〜１００μ゛ｍに粉砕したものを用い
た。また、枠線り石鹸については冷却固化後、切断し、
約５０日乾燥したものを磨いて成型を行なった。Examples 1 to 6, Comparative Examples 1 to 3 Solid detergents consisting of the ingredients listed in Table 1 were prepared by a conventional method, and mold release and swelling properties during molding were examined using the following evaluation methods. The water-swellable clay mineral used was ground to a particle size of 2 to 100 μm using a ball mill. In addition, for framed soap, after cooling and solidifying, cut it,
After drying for about 50 days, it was polished and molded.
離型性
石けん１００個を成型し、不良個数を割りだし、その割
合から以下のような基準で評価した。100 pieces of releasable soap were molded, the number of defective pieces was determined, and the percentage was evaluated using the following criteria.
○・・・不良個数が５個未満
Δ・・・不良個数が６個以上、５０個未満×・・・不良
個数が５０個以上
膨潤性
あらかじめ重量を測定した試料を針金につるして２０℃
に保たれた２００ｄの水道水に浸す。２時間後に取りだ
し、重量を測定し、次の式を用いて膨潤度（吸水％）を
求めた。○...Number of defective pieces is less than 5 Δ...Number of defective pieces is 6 or more, less than 50 x...Number of defective pieces is 50 or more Swellability A sample whose weight has been measured in advance is hung on a wire at 20°C.
Soak in 200 d of tap water maintained at After 2 hours, it was taken out, the weight was measured, and the degree of swelling (% water absorption) was determined using the following formula.
膨潤度＝ ｂ−（ａ−ｃ）／ａ−ｃ Ｘ １００ただ
し、ａ：浸漬前の重量（ｇ）
ｂ：浸漬後の重ｆｆｉ（ｇ）
Ｃ：水中に溶けだした重量（ｇ）
０・・・良好（膨潤度２１％未満）
Δ・・・普通（膨潤度２１％以上、２５％未満）×・・
・悪いＣｌ１ｆｆｉ度２５％以上）表−１
表−１より明らかなように、本発明は枠線りタイプ、機
械練りタイプのどちらにおいても優れた効果があること
が見出された。。Swelling degree = b-(ac)/ac-c・Good (degree of swelling less than 21%) Δ... Average (degree of swelling 21% or more, less than 25%) ×...
- Bad Cl1ffi degree of 25% or more) Table 1 As is clear from Table 1, it was found that the present invention has excellent effects in both the border type and mechanical kneading type. .
実施例７〜１２
表−２に記載の配合成分よりなる固型洗浄料を常法によ
り調整し、膨潤性および成型時の型離れについて調べた
。Examples 7 to 12 Solid detergents consisting of the ingredients listed in Table 2 were prepared by a conventional method, and their swelling properties and release from the mold during molding were investigated.
表−２
表−２より明らかなように、本発明は優れた効果がある
ことが見出きれた。Table 2 As is clear from Table 2, it has been found that the present invention has excellent effects.
特許出願人 株式会社 資生堂
手続補正ＩＦ（方式）
％式％
１、 事件の表示
昭和６２年特許願第ンη８ｕ号
２、発明の名称
固・−メーン克シ杆十
３、補正をする者
事件との関係 特許出願人
住 所 東京都中央区銀座７丁目５番５号昭和６３年１
月２／１日 ・イ゛ζ明細書第１頁
第ｇ行目と第７行目の間に「３゜以上Patent Applicant: Shiseido Co., Ltd. Procedural Amendment IF (Method) % Formula % 1. Indication of the case 1985 Patent Application No. Relationship Patent applicant address: 1, 1986, 7-5-5, Ginza, Chuo-ku, Tokyo
Month 2/1 ・I
Claims (1)
浄料。A solid detergent characterized by containing water-swellable clay minerals.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25938287A JPH01101398A (en) | 1987-10-14 | 1987-10-14 | Solid detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25938287A JPH01101398A (en) | 1987-10-14 | 1987-10-14 | Solid detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01101398A true JPH01101398A (en) | 1989-04-19 |
Family
ID=17333357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25938287A Pending JPH01101398A (en) | 1987-10-14 | 1987-10-14 | Solid detergent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01101398A (en) |
-
1987
- 1987-10-14 JP JP25938287A patent/JPH01101398A/en active Pending
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