JP7843894B2 - Preform for double-walled container molding - Google Patents
Preform for double-walled container moldingInfo
- Publication number
- JP7843894B2 JP7843894B2 JP2025083829A JP2025083829A JP7843894B2 JP 7843894 B2 JP7843894 B2 JP 7843894B2 JP 2025083829 A JP2025083829 A JP 2025083829A JP 2025083829 A JP2025083829 A JP 2025083829A JP 7843894 B2 JP7843894 B2 JP 7843894B2
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- JP
- Japan
- Prior art keywords
- preform
- container
- circumferential surface
- opening
- double
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/14—Making preforms characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/06—Injection blow-moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/071—Preforms or parisons characterised by their configuration, e.g. geometry, dimensions or physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/22—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C2049/023—Combined blow-moulding and manufacture of the preform or the parison using inherent heat of the preform, i.e. 1 step blow moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/076—Preforms or parisons characterised by their configuration characterised by the shape
- B29C2949/0768—Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform
- B29C2949/0778—Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the flange
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/22—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at neck portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/24—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at flange portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3016—Preforms or parisons made of several components at body portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/302—Preforms or parisons made of several components at bottom portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3086—Interaction between two or more components, e.g. type of or lack of bonding
- B29C2949/3094—Interaction between two or more components, e.g. type of or lack of bonding preform having at least partially loose components, e.g. at least partially loose layers
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Geometry (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Description
本発明は、二重容器成形用プリフォームに関する。 This invention relates to a preform for double-walled container molding.
収容される内容物の減少に伴い減容変形する内容器と、内容器が内装されるとともに、内容物の減少に伴い、内容器との間に外気を導入する外気導入孔が形成された外容器と、を備える二重容器を成形するためのプリフォームは、内容器を成形するための有底筒状の内プリフォームと、外容器を成形するための有底筒状の外プリフォームと、を備えている。
この種の二重容器成形用プリフォームとして、例えば下記特許文献1に示されるような、外プリフォーム内に内プリフォームが嵌合され、外プリフォームの内周面と、内プリフォームの外周面と、の間に剥離剤層が設けられた構成が知られている。
このプリフォームで形成された二重容器では、内容物の減少に伴い、外気が外気導入孔を通して内容器と外容器との間に導入されたときに、内容器の外周面を、外容器の内周面から剥離しやすくすることができる。
A preform for forming a double-walled container comprising an inner container that deforms in volume as the contents it contains decrease, and an outer container that houses the inner container and has an air intake hole formed between it and the inner container to introduce outside air as the contents decrease, comprises a bottomed cylindrical inner preform for forming the inner container and a bottomed cylindrical outer preform for forming the outer container.
As a preform for this type of double-walled container molding, a configuration is known in which an inner preform is fitted inside an outer preform, and a release agent layer is provided between the inner circumferential surface of the outer preform and the outer circumferential surface of the inner preform, as shown in Patent Document 1 below.
In a double-walled container formed with this preform, as the contents decrease, outside air is introduced between the inner and outer containers through the outside air intake holes, making it easier to separate the outer surface of the inner container from the inner surface of the outer container.
しかしながら、前記従来の二重容器成形用プリフォームでは、外プリフォームの内周面と、内プリフォームの外周面と、の間に剥離剤層が設けられていたので、製造が困難であるという問題があった。 However, the conventional double-walled container molding preform had a release agent layer between the inner surface of the outer preform and the outer surface of the inner preform, which presented a manufacturing difficulty.
本発明は、前述した事情に鑑みてなされたものであって、剥離剤層を設けなくても、内容物の減少に伴い、内容器の外周面を外容器の内周面から剥離しやすくすることができる二重容器成形用プリフォームを提供することを目的とする。 This invention has been made in view of the circumstances described above, and aims to provide a preform for molding double-walled containers that allows the outer surface of the inner container to be easily separated from the inner surface of the outer container as the contents decrease, even without providing a release agent layer.
本発明は、上記課題を解決するために以下のような手段を採用した。すなわち、本発明の二重容器成形用プリフォームは、収容される内容物の減少に伴い減容変形する内容器と、前記内容器が内装されるとともに、前記内容物の減少に伴い、前記内容器との間に外気を導入する外気導入孔が形成された外容器と、を備える二重容器を成形するためのプリフォームであって、前記内容器を成形するための有底筒状の内プリフォームと、前記外容器を成形するための有底筒状の外プリフォームと、を備えるとともに、前記外プリフォームの口部内に、前記内プリフォームの口部が嵌合された状態で、前記外プリフォーム内に前記内プリフォームが挿入され、前記外プリフォームの口部の内周面に、前記外プリフォームの上端開口縁から下方に向けて延びる縦溝が形成され、前記縦溝に前記外気導入孔が開口し、前記内プリフォームの口部には、周方向の全長にわたって連続して延びるとともに、前記外プリフォームの上端開口縁に当接して、前記縦溝の上端開口を閉塞したフランジ部が設けられ、前記外気導入孔は、前記外プリフォームの上端開口縁から下方に離れ、前記外プリフォームの口部の内周面、および前記内プリフォームの口部の外周面が、前記縦溝を除く全域にわたって互いに当接している。 The present invention employs the following means to solve the above problems. That is, the present invention provides a preform for forming a double-walled container comprising: an inner container that deforms in volume as the contents it contains decrease; and an outer container in which the inner container is housed, and in which an air intake hole is formed to introduce outside air between the inner container and the outer container as the contents decrease, the preform comprises a bottomed cylindrical inner preform for forming the inner container and a bottomed cylindrical outer preform for forming the outer container, and the inner preform is placed inside the outer preform with the opening of the inner preform fitted into the opening of the outer preform A frame is inserted, and a vertical groove is formed on the inner circumferential surface of the mouth of the outer preform, extending downward from the upper opening edge of the outer preform. The outside air intake hole opens in the vertical groove. The mouth of the inner preform is provided with a flange portion that extends continuously along its entire circumferential length and abuts against the upper opening edge of the outer preform, closing the upper opening of the vertical groove. The outside air intake hole is separated downward from the upper opening edge of the outer preform, and the inner circumferential surface of the mouth of the outer preform and the outer circumferential surface of the mouth of the inner preform are in contact with each other over the entire area except for the vertical groove.
本発明では、外プリフォームの口部の内周面に、外プリフォームの上端開口縁から下方に向けて延びる縦溝が形成され、縦溝に外気導入孔が開口しているので、外プリフォームの口部内に、内プリフォームの口部が嵌合されて、外プリフォームおよび内プリフォームの相対移動が抑止された状態であっても、外気が外気導入孔を通して内容器と外容器との間に導入されたときに、縦溝を通過することとなり、剥離剤層を設けなくても、内容物の減少に伴い、内容器の外周面を外容器の内周面から剥離しやすくすることができる。
縦溝が、外プリフォームの上端開口縁から下方に向けて延びているので、成形金型の構造を複雑にせずに、外プリフォームの内周面に縦溝を容易に設けることができる。
内プリフォームの口部に、周方向の全長にわたって連続して延び、外プリフォームの上端開口縁に当接したフランジ部が設けられているので、外プリフォームおよび内プリフォームの相対移動を確実に抑止することができる。
フランジ部が、縦溝の上端開口を閉塞しているので、内容物の減少に伴い、外気が内容器と外容器との間に進入する部分を外気導入孔に限定することができる。これにより、外気が内容器と外容器との間に進入するときの勢いを維持しやすくなり、内容器の外周面を外容器の内周面から確実に剥離しやすくすることができるとともに、内容器の縮小変形形状を所期した形状にしやすくすることが可能になり、内容物の残量を抑えることができる。
In this invention, a vertical groove is formed on the inner circumferential surface of the mouth of the outer preform, extending downward from the upper opening edge of the outer preform, and an outside air introduction hole is opened in the vertical groove. Therefore, even when the mouth of the inner preform is fitted into the mouth of the outer preform and relative movement between the outer and inner preforms is suppressed, when outside air is introduced between the inner container and the outer container through the outside air introduction hole, it passes through the vertical groove. This makes it easier to separate the outer circumferential surface of the inner container from the inner circumferential surface of the outer container as the contents decrease, even without providing a release agent layer.
Since the longitudinal grooves extend downward from the upper opening edge of the outer preform, the longitudinal grooves can be easily provided on the inner circumferential surface of the outer preform without complicating the structure of the molding die.
Since the inner preform is provided with a flange portion that extends continuously along its entire circumferential length and abuts against the upper opening edge of the outer preform, relative movement between the outer and inner preforms can be reliably suppressed.
Since the flange portion closes the upper end opening of the vertical groove, as the contents decrease, the portion in which outside air enters between the inner container and the outer container can be limited to the outside air intake hole. This makes it easier to maintain the momentum of the outside air when it enters between the inner and outer containers, making it easier to reliably separate the outer surface of the inner container from the inner surface of the outer container, and also makes it easier to reduce the size of the inner container as intended, thereby minimizing the amount of remaining contents.
前記内プリフォームの口部における内周面および外周面は、前記内プリフォームの中心軸線に沿う縦断面視で、前記中心軸線に沿って延びてもよい。 The inner and outer circumferential surfaces of the opening of the inner preform may extend along the central axis in a longitudinal cross-sectional view along the central axis of the inner preform.
この場合、内プリフォームの口部における内周面および外周面が、内プリフォームの中心軸線に沿う縦断面視で、前記中心軸線に沿って延びているので、外プリフォームおよび内プリフォームの相対移動を確実に抑止することができる。 In this case, since the inner and outer circumferential surfaces at the opening of the inner preform extend along the central axis in a longitudinal cross-sectional view along the central axis of the inner preform, relative movement between the outer and inner preforms can be reliably suppressed.
前記内プリフォームの口部における外周面に、径方向の外側に向けて突出し、周方向の全長にわたって連続して延びるとともに、前記外プリフォームの口部の内周面に圧接する突条部が設けられてもよい。 The outer circumferential surface of the opening of the inner preform may be provided with a projection that extends radially outward, continuously along its entire circumferential length, and presses against the inner circumferential surface of the opening of the outer preform.
この場合、内プリフォームの口部における外周面に、外プリフォームの口部の内周面に圧接する突条部が設けられているので、外プリフォームおよび内プリフォームの相対移動を確実に抑止することができる。 In this case, since the outer circumferential surface of the opening of the inner preform is provided with a protrusion that presses against the inner circumferential surface of the opening of the outer preform, relative movement between the outer and inner preforms can be reliably suppressed.
前記内プリフォームの外周面における前記フランジ部の下面との接続部分と、前記外プリフォームにおける内周面と上端開口縁との接続部分と、の間に、周方向の全長にわたって連続して延びる拡散隙間が設けられてもよい。 A diffusion gap extending continuously along the entire length in the circumferential direction may be provided between the connection portion between the outer circumferential surface of the inner preform and the lower surface of the flange portion, and the connection portion between the inner circumferential surface of the outer preform and the upper end opening edge.
この場合、内プリフォームの外周面におけるフランジ部の下面との接続部分と、外プリフォームにおける内周面と上端開口縁との接続部分と、の間に、拡散隙間が設けられているので、内容物の減少に伴い、外気導入孔を通して内容器と外容器との間に導入された外気を、拡散隙間を流通させることで、二重容器の口部における周方向の全長にわたって行き渡らせやすくなり、内容器の縮小変形形状を所期した形状にしやすくすることができる。 In this case, a diffusion gap is provided between the connection point between the lower surface of the flange on the outer circumferential surface of the inner preform and the connection point between the inner circumferential surface and the upper opening edge of the outer preform. Therefore, as the contents decrease, the outside air introduced between the inner and outer containers through the outside air intake holes can circulate through the diffusion gap, making it easier to distribute the air throughout the entire circumferential length of the mouth of the double-walled container. This facilitates the reduction and deformation of the inner container to the desired shape.
この発明によれば、剥離剤層を設けなくても、内容物の減少に伴い、内容器の外周面を外容器の内周面から剥離しやすくすることができる。 According to this invention, even without providing a release agent layer, the outer surface of the inner container can be easily separated from the inner surface of the outer container as the contents decrease.
以下、図面を参照し、第1実施形態に係る二重容器成形用プリフォームを説明する。
二重容器成形用プリフォーム1は、図1から図4に示されるように、収容される内容物の減少に伴い減容変形する内容器X1と、内容器X1が内装されるとともに、内容物の減少に伴い、内容器X1との間に外気を導入する外気導入孔13が形成された外容器X2と、を備える二重容器Xを成形するために用いられる。
二重容器Xは、二重容器成形用プリフォーム1をブロー成形することで形成される。二重容器Xでは、内容器X1は、可撓性に富み、外容器X2の内面に離間可能に設けられる。
The preform for molding a double-walled container according to the first embodiment will be described below with reference to the drawings.
The double-walled container molding preform 1 is used to mold a double-walled container X, as shown in Figures 1 to 4, which comprises an inner container X1 that deforms in volume as the contents it contains decrease, and an outer container X2 in which the inner container X1 is housed, and which has an air intake hole 13 formed between it and the inner container X1 to introduce outside air as the contents decrease.
The double-walled container X is formed by blow molding a preform 1 for double-walled container molding. In the double-walled container X, the inner container X1 is highly flexible and is spaced apart on the inner surface of the outer container X2.
二重容器成形用プリフォーム1は、内容器X1を成形するための有底筒状の内プリフォーム11と、外容器X2を成形するための有底筒状の外プリフォーム12と、を備えている。図1において、内プリフォーム11にはハッチングを付してある。
図2に示されるように、外プリフォーム12の口部(以下、外口部という)22内に、内プリフォーム11の口部(以下、内口部という)21が挿入され、外プリフォーム12の底部(以下、外底部という)24内に、内プリフォーム11の底部(以下、内底部という)23が挿入されている。
The double-walled container molding preform 1 comprises a bottomed cylindrical inner preform 11 for molding the inner container X1 and a bottomed cylindrical outer preform 12 for molding the outer container X2. In Figure 1, the inner preform 11 is hatched.
As shown in Figure 2, the opening 21 of the inner preform 11 (hereinafter referred to as the inner opening) is inserted into the opening 22 of the outer preform 12 (hereinafter referred to as the outer opening), and the bottom 23 of the inner preform 11 (hereinafter referred to as the inner bottom) is inserted into the bottom 24 of the outer preform 12 (hereinafter referred to as the outer bottom).
内プリフォーム11および外プリフォーム12は、共通軸と同軸に配設されている。
以下、この共通軸を中心軸線Oといい、中心軸線Oに沿う内口部21側および外口部22側を上側といい、中心軸線Oに沿う内底部23側および外底部24側を下側という。上下方向から見て、中心軸線Oに交差する方向を径方向といい、中心軸線O回りに周回する方向を周方向という。
The inner preform 11 and the outer preform 12 are arranged coaxially with the common axis.
Hereinafter, this common axis will be referred to as the central axis O, the inner opening 21 side and the outer opening 22 side along the central axis O will be referred to as the upper side, and the inner bottom 23 side and the outer bottom 24 side along the central axis O will be referred to as the lower side. When viewed from above or below, the direction intersecting the central axis O will be referred to as the radial direction, and the direction revolving around the central axis O will be referred to as the circumferential direction.
内プリフォーム11および外プリフォーム12の材質は合成樹脂材料とされ、互いに同材質でも構わないし異材質でも構わない。合成樹脂材料の一例としては、例えば、PET(ポリエチレンテレフタレート)、PP(ポリプロピレン)、PE(ポリエチレン)、ナイロン(ポリアミド)、およびEVOH(エチレン-ビニルアルコール共重合体)等が挙げられる。 The inner preform 11 and outer preform 12 are made of synthetic resin materials, and may be made of the same material or different materials. Examples of synthetic resin materials include PET (polyethylene terephthalate), PP (polypropylene), PE (polyethylene), nylon (polyamide), and EVOH (ethylene-vinyl alcohol copolymer).
図4に示されるように、内口部21が、外口部22の内側に嵌合されている。内口部21の外周面が、上下方向の全長にわたって外口部22の内周面に当接している。
図2に示されるように、内プリフォーム11の外周面と、外プリフォーム12の内周面と、の間において、内口部21および外口部22より下方に位置する部分に、上下方向の全長にわたって隙間が設けられている。
As shown in Figure 4, the inner opening 21 is fitted inside the outer opening 22. The outer circumferential surface of the inner opening 21 abuts against the inner circumferential surface of the outer opening 22 along its entire length in the vertical direction.
As shown in Figure 2, a gap is provided between the outer circumferential surface of the inner preform 11 and the inner circumferential surface of the outer preform 12, in the portion located below the inner opening 21 and the outer opening 22, along the entire length in the vertical direction.
外口部22の外周面に、図示されないキャップが螺着される雄ねじ部22aと、図示されないキャップの周壁部が外嵌される被シール突部22bと、ネックリング22cと、が上方から下方に向けてこの順に形成されている。
なお、キャップは、外口部22にアンダーカット嵌合されてもよい。
On the outer circumferential surface of the outer opening 22, a male threaded portion 22a to which a cap (not shown) is screwed, a sealing projection 22b to which the peripheral wall portion of the cap (not shown) is fitted, and a neck ring 22c are formed in this order from top to bottom.
The cap may also be fitted onto the outer opening 22 with an undercut.
被シール突部22b、およびネックリング22cは、外口部22から径方向の外側に向けて突出し、周方向の全長にわたって連続して延びている。被シール突部22bの外周面と、図示されないキャップの周壁部の内周面と、の間は、気密にシールされる。ネックリング22cの外径は、被シール突部22bの外径より大きくなっている。ネックリング22cは、図示されないキャップの周壁部より下方に位置する。 The sealed projection 22b and the neck ring 22c project radially outward from the outer opening 22 and extend continuously along the entire circumferential length. The outer surface of the sealed projection 22b and the inner surface of the circumferential wall of the cap (not shown) are airtightly sealed. The outer diameter of the neck ring 22c is larger than the outer diameter of the sealed projection 22b. The neck ring 22c is located below the circumferential wall of the cap (not shown).
外口部22に、前述の外気導入孔13が形成されている。外気導入孔13は、被シール突部22bのうち、最も径方向の外側に位置して、周方向の全長にわたって連続して延びるシール面より上方に位置している。外気導入孔13、および雄ねじ部22aの下部それぞれの上下方向の位置が互いに同じになっている。ここで、雄ねじ部22aは、周方向に間欠的に延びており、この雄ねじ部22aにおける周方向の間欠部分に、外気導入孔13が設けられている。
外口部22の内周面に、外プリフォーム12の上端開口縁15から下方に向けて延びる縦溝16が形成されている。縦溝16に外気導入孔13が開口している。縦溝16の下端部は、ネックリング22cより下方に位置している。
The aforementioned outside air intake hole 13 is formed in the outer opening portion 22. The outside air intake hole 13 is located radially on the outermost side of the sealed projection 22b and is positioned above the sealing surface that extends continuously along its entire circumferential length. The vertical positions of the outside air intake hole 13 and the lower part of the male threaded portion 22a are the same. Here, the male threaded portion 22a extends intermittently in the circumferential direction, and the outside air intake hole 13 is provided in the intermittent circumferential portion of this male threaded portion 22a.
A vertical groove 16 is formed on the inner circumferential surface of the outer opening portion 22, extending downward from the upper end opening edge 15 of the outer preform 12. An outside air intake hole 13 is opened in the vertical groove 16. The lower end of the vertical groove 16 is located below the neck ring 22c.
図1に示されるように、外気導入孔13および縦溝16はそれぞれ、周方向に同等の間隔をあけて複数設けられている。図示の例では、縦溝16は、上下方向から見て中心軸線Oを中心に90°間隔で4箇所設けられている。4つの縦溝16のうち、径方向で互いに対向する2つの縦溝16に外気導入孔13が一つずつ開口している。なお、全ての縦溝16に外気導入孔13が開口してもよく、1つの縦溝16に複数の外気導入孔13が開口してもよい。 As shown in Figure 1, multiple air intake holes 13 and vertical grooves 16 are provided at equal intervals in the circumferential direction. In the illustrated example, four vertical grooves 16 are provided at 90° intervals around the central axis O when viewed from above and below. Of the four vertical grooves 16, one air intake hole 13 is opened in each of the two vertical grooves 16 that are radially opposite to each other. Note that air intake holes 13 may be opened in all vertical grooves 16, or multiple air intake holes 13 may be opened in a single vertical groove 16.
内口部21には、周方向の全長にわたって連続して延びるとともに、外プリフォーム12の上端開口縁15に当接したフランジ部25が設けられている。図3に示されるように、フランジ部25は、縦溝16の上端開口を閉塞している。 The inner opening 21 is provided with a flange portion 25 that extends continuously along its entire circumferential length and abuts against the upper end opening edge 15 of the outer preform 12. As shown in Figure 3, the flange portion 25 closes the upper end opening of the vertical groove 16.
図4に示されるように、内口部21における外周面に、径方向の外側に向けて突出し、周方向の全長にわたって連続して延びるとともに、外口部22の内周面に圧接した突条部26が設けられている。突条部26は、上下方向に間隔をあけて複数設けられている。図3に示されるように、突条部26は、外口部22の外気導入孔13より上方に位置している。なお、突条部26を設けなくてもよい。 As shown in Figure 4, the outer circumferential surface of the inner opening 21 is provided with a projection 26 that protrudes radially outward, extends continuously along its entire circumferential length, and is pressed against the inner circumferential surface of the outer opening 22. Multiple projections 26 are provided at intervals in the vertical direction. As shown in Figure 3, the projections 26 are located above the outside air intake hole 13 of the outer opening 22. Note that the projections 26 are not required.
内口部21における内周面および外周面は、中心軸線Oに沿う縦断面視で、中心軸線Oに沿って延びている。内口部21における内周面および外周面のうち、少なくとも内周面は、中心軸線Oと平行に延びている。図示の例では、内口部21における内周面および外周面が、中心軸線Oと平行に延びている。ここで言う「平行」とは、成形金型からの抜き勾配を含むものとする。 The inner and outer circumferential surfaces of the inner opening 21 extend along the central axis O in a longitudinal cross-sectional view along the central axis O. Of the inner and outer circumferential surfaces of the inner opening 21, at least the inner circumferential surface extends parallel to the central axis O. In the illustrated example, the inner and outer circumferential surfaces of the inner opening 21 extend parallel to the central axis O. Here, "parallel" includes the draft angle from the molding die.
内口部21は、内プリフォーム11のうち、外プリフォーム12におけるネックリング22cの下面に対して、上下方向の同じ位置を含み、かつ上方に位置する部分となっている。二重容器成形用プリフォーム1において、ネックリング22cの下面に対して、上下方向の同じ位置を含み、かつ上方に位置する部分は、ブロー成形の前後で形状が変化しない部分となっている。 The inner opening portion 21 is the part of the inner preform 11 that includes the same position in the vertical direction relative to the lower surface of the neck ring 22c of the outer preform 12, and is located above it. In the double-walled container molding preform 1, the portion that includes the same position in the vertical direction relative to the lower surface of the neck ring 22c, and is located above it, is a portion whose shape does not change before and after blow molding.
内プリフォーム11の外周面において、内口部21の下端に連なる部分に、径方向の外側に向けて突出し、外プリフォーム12の内周面に近接するリブ11aが、周方向に間隔をあけて複数形成されている。リブ11aは、二重容器Xにおいて、内容器X1の外周面と外容器X2の内周面との間の上下方向の連通状態を維持する。
なお、リブ11aは、ブロー成形の前後で形状が変化しない部分であってもよいし、ブロー成形後に外プリフォーム12により形成される外容器X2の内周面に当接する部分であってもよい。
On the outer circumferential surface of the inner preform 11, multiple ribs 11a are formed at circumferential intervals in the portion connected to the lower end of the inner opening 21, projecting radially outward and close to the inner circumferential surface of the outer preform 12. The ribs 11a maintain vertical communication between the outer circumferential surface of the inner container X1 and the inner circumferential surface of the outer container X2 in the double-walled container X.
The rib 11a may be a part whose shape does not change before and after blow molding, or it may be a part that abuts against the inner circumferential surface of the outer container X2 formed by the outer preform 12 after blow molding.
内プリフォーム11の外周面におけるフランジ部25の下面との接続部分と、外プリフォーム12における内周面と上端開口縁15との接続部分と、の間に、周方向の全長にわたって連続して延びる拡散隙間Aが設けられている。拡散隙間Aは、縦溝16に開口している。
内プリフォーム11の外周面におけるフランジ部25の下面との接続部分は、径方向の内側に向けて窪む曲面状に形成されている。外プリフォーム12における内周面と上端開口縁15との接続部分は、径方向の内側に向けて突の曲面状に形成されている。
A diffusion gap A is provided between the connection portion between the outer circumferential surface of the inner preform 11 and the lower surface of the flange portion 25, and the connection portion between the inner circumferential surface of the outer preform 12 and the upper end opening edge 15, extending continuously along the entire length in the circumferential direction. The diffusion gap A opens into the vertical groove 16.
The connection portion between the outer circumferential surface of the inner preform 11 and the lower surface of the flange portion 25 is formed as a curved surface that is recessed radially inward. The connection portion between the inner circumferential surface of the outer preform 12 and the upper end opening edge 15 is formed as a curved surface that protrudes radially inward.
以上説明したように、本実施形態による二重容器成形用プリフォーム1によれば、外口部22の内周面に、外プリフォーム12の上端開口縁15から下方に向けて延びる縦溝16が形成され、縦溝16に外気導入孔13が開口しているので、外口部22内に、内口部21が嵌合されて、外プリフォーム12および内プリフォーム11の相対移動が抑止された状態であっても、外気が外気導入孔13を通して内容器X1と外容器X2との間に導入されたときに、縦溝16を通過することとなり、剥離剤層を設けなくても、内容物の減少に伴い、内容器X1の外周面を外容器X2の内周面から剥離しやすくすることができる。 As described above, according to the double-walled container molding preform 1 of this embodiment, a vertical groove 16 is formed on the inner circumferential surface of the outer opening 22, extending downward from the upper opening edge 15 of the outer preform 12. Since an outside air inlet 13 is opened in the vertical groove 16, even when the inner opening 21 is fitted into the outer opening 22 and relative movement between the outer preform 12 and the inner preform 11 is suppressed, when outside air is introduced between the inner container X1 and the outer container X2 through the outside air inlet 13, it passes through the vertical groove 16. Therefore, even without providing a release agent layer, the outer circumferential surface of the inner container X1 can be easily separated from the inner circumferential surface of the outer container X2 as the contents decrease.
縦溝16が、外プリフォーム12の上端開口縁15から下方に向けて延びているので、成形金型の構造を複雑にせずに、外プリフォーム12の内周面に縦溝16を容易に設けることができる。
内口部21に、周方向の全長にわたって連続して延び、外プリフォーム12の上端開口縁15に当接したフランジ部25が設けられているので、外プリフォーム12および内プリフォーム11の相対移動を確実に抑止することができる。
Since the vertical grooves 16 extend downward from the upper opening edge 15 of the outer preform 12, the vertical grooves 16 can be easily provided on the inner circumferential surface of the outer preform 12 without complicating the structure of the molding die.
Since the inner opening portion 21 is provided with a flange portion 25 that extends continuously along the entire length in the circumferential direction and abuts against the upper end opening edge 15 of the outer preform 12, relative movement between the outer preform 12 and the inner preform 11 can be reliably suppressed.
フランジ部25が、縦溝16の上端開口を閉塞しているので、内容物の減少に伴い、外気が内容器X1と外容器X2との間に進入する部分を外気導入孔13に限定することができる。これにより、外気が内容器X1と外容器X2との間に進入するときの勢いを維持しやすくなり、内容器X1の外周面を外容器X2の内周面から確実に剥離しやすくすることができるとともに、内容器X1の縮小変形形状を所期した形状にしやすくすることが可能になり、内容物の残量を抑えることができる。 Since the flange portion 25 closes the upper end opening of the vertical groove 16, as the contents decrease, the portion of outside air entering between the inner container X1 and the outer container X2 can be limited to the outside air intake hole 13. This makes it easier to maintain the momentum of the outside air entering between the inner container X1 and the outer container X2, ensuring that the outer surface of the inner container X1 is reliably separated from the inner surface of the outer container X2. Furthermore, it becomes easier to achieve the desired shape of the reduced deformation of the inner container X1, thereby minimizing the amount of remaining contents.
内口部21における内周面および外周面が、中心軸線Oに沿う縦断面視で、中心軸線Oに沿って延びているので、外プリフォーム12および内プリフォーム11の相対移動を確実に抑止することができる。 Since the inner and outer circumferential surfaces of the inner opening 21 extend along the central axis O in a longitudinal cross-sectional view along the central axis O, relative movement between the outer preform 12 and the inner preform 11 can be reliably suppressed.
内口部21における外周面に、外口部22の内周面に圧接する突条部26が設けられているので、外プリフォーム12および内プリフォーム11の相対移動を確実に抑止することができる。 Since the outer circumferential surface of the inner opening 21 is provided with a protruding portion 26 that presses against the inner circumferential surface of the outer opening 22, relative movement between the outer preform 12 and the inner preform 11 can be reliably suppressed.
内プリフォーム11の外周面におけるフランジ部25の下面との接続部分と、外プリフォーム12における内周面と上端開口縁15との接続部分と、の間に、拡散隙間Aが設けられているので、内容物の減少に伴い、外気導入孔13を通して内容器X1と外容器X2との間に導入された外気を、拡散隙間Aを流通させることで、二重容器Xの口部における周方向の全長にわたって行き渡らせやすくなり、内容器X1の縮小変形形状を所期した形状にしやすくすることができる。 Since a diffusion gap A is provided between the connection portion between the lower surface of the flange portion 25 on the outer circumferential surface of the inner preform 11 and the connection portion between the inner circumferential surface of the outer preform 12 and the upper end opening edge 15, as the contents decrease, the outside air introduced between the inner container X1 and the outer container X2 through the outside air introduction hole 13 can be circulated through the diffusion gap A, making it easier to distribute the outside air over the entire circumferential length of the mouth of the double container X, and thus making it easier to achieve the desired shape when the inner container X1 shrinks and deforms.
次に、第2実施形態に係る二重容器成形用プリフォーム2を、図5および図6を参照しながら説明する。
なお、第2実施形態においては、第1実施形態における構成要素と同一の部分については同一の符号を付し、その説明を省略し、異なる点についてのみ説明する。
Next, the double-walled container molding preform 2 according to the second embodiment will be described with reference to Figures 5 and 6.
In the second embodiment, the same reference numerals are used for parts that are the same as those in the first embodiment, and their descriptions are omitted. Only the differences will be described.
本実施形態では、リブ11aが、外プリフォーム12の内周面に当接している。リブ11aの上端部、および縦溝16の下端部それぞれの上下方向の位置が互いに同じになっている。リブ11aの下端部は、縦溝16より下方に位置している。
二重容器成形用プリフォーム2において、ブロー成形の前後で形状が変化しない部分と、ブロー成形時に延伸される部分と、の境界には、リブ11aのうち、外プリフォーム12の内周面に当接している当接部分が位置している。
なお、二重容器成形用プリフォーム2において、内口部21、およびリブ11aの前記当接部分と上下方向の位置が同じ部分を、ブロー成形の前後で形状が変化しない部分とし、リブ11aの前記当接部分より下方に位置する部分を、ブロー成形時に延伸される部分としてもよい。
In this embodiment, the rib 11a is in contact with the inner circumferential surface of the outer preform 12. The upper end of the rib 11a and the lower end of the longitudinal groove 16 are at the same vertical position. The lower end of the rib 11a is located below the longitudinal groove 16.
In the double-walled container molding preform 2, the boundary between the portion whose shape does not change before and after blow molding and the portion that is stretched during blow molding is located at the contact portion of the rib 11a that is in contact with the inner circumferential surface of the outer preform 12.
In addition, in the double-walled container molding preform 2, the portion of the inner opening 21 and the portion of the rib 11a that is in the same vertical position as the contact portion may be designated as a portion whose shape does not change before and after blow molding, while the portion of the rib 11a located below the contact portion may be designated as a portion that is stretched during blow molding.
以上説明したように、本実施形態による二重容器成形用プリフォーム2によれば、二重容器成形用プリフォーム1と同様に、剥離剤層を設けなくても、内容物の減少に伴い、内容器X1の外周面を外容器X2の内周面から剥離しやすくすること等ができる。 As described above, the double-walled container molding preform 2 according to this embodiment, similar to the double-walled container molding preform 1, makes it possible to easily separate the outer surface of the inner container X1 from the inner surface of the outer container X2 as the contents decrease, even without providing a release agent layer.
なお、本発明の技術範囲は、前述した実施形態に限定されるものではなく、本発明の趣旨を逸脱しない範囲において種々の変更を加えることが可能である。 Furthermore, the technical scope of the present invention is not limited to the embodiments described above, and various modifications can be made without departing from the spirit of the invention.
内プリフォーム11の外周面におけるフランジ部25の下面との接続部分と、外プリフォーム12における内周面と上端開口縁15との接続部分と、の間に、拡散隙間Aを設けなくてもよい。 A diffusion gap A does not need to be provided between the connection portion between the lower surface of the flange portion 25 on the outer circumferential surface of the inner preform 11 and the connection portion between the inner circumferential surface of the outer preform 12 and the upper end opening edge 15.
その他、本発明の趣旨を逸脱しない範囲で、前記実施形態における構成要素を周知の構成要素に置き換えることは適宜可能であり、また、前記実施形態および前記変形例を適宜組み合わせてもよい。 Furthermore, without departing from the spirit of the present invention, the components in the above embodiments may be replaced with well-known components as appropriate, and the above embodiments and modifications may be combined as appropriate.
1、2 二重容器成形用プリフォーム
11 内プリフォーム
12 外プリフォーム
13 外気導入孔
15 上端開口縁
16 縦溝
21 内口部(内プリフォームの口部)
22 外口部(外プリフォームの口部)
25 フランジ部
26 突条部
A 拡散隙間
O 中心軸線
X 二重容器
X1 内容器
X2 外容器
1, 2 Preforms for double-walled container molding 11 Inner preform 12 Outer preform 13 Air intake hole 15 Upper opening edge 16 Vertical groove 21 Inner opening (opening of inner preform)
22. Outer opening (opening of the outer preform)
25 Flange section 26 Protruding section A Diffusion gap O Central axis X Double container X1 Inner container X2 Outer container
Claims (4)
前記内容器が内装されるとともに、前記内容物の減少に伴い、前記内容器との間に外気を導入する外気導入孔が形成された外容器と、を備える二重容器を成形するためのプリフォームであって、
前記内容器を成形するための有底筒状の内プリフォームと、前記外容器を成形するための有底筒状の外プリフォームと、を備えるとともに、
前記外プリフォームの口部内に、前記内プリフォームの口部が嵌合された状態で、前記外プリフォーム内に前記内プリフォームが挿入され、
前記外プリフォームの口部の内周面に、前記外プリフォームの上端開口縁から下方に向けて延びる縦溝が形成され、
前記縦溝に前記外気導入孔が開口し、
前記内プリフォームの口部には、周方向の全長にわたって連続して延びるとともに、前記外プリフォームの上端開口縁に当接して、前記縦溝の上端開口を閉塞したフランジ部が設けられ、
前記外気導入孔は、前記外プリフォームの上端開口縁から下方に離れ、
前記外プリフォームの口部の内周面、および前記内プリフォームの口部の外周面が、前記縦溝を除く全域にわたって互いに当接している、二重容器成形用プリフォーム。 The inner container deforms and decreases in volume as the contents it holds decrease,
A preform for forming a double container comprising: an inner container in which the inner container is housed, and an outer container having an air intake hole formed between it and the inner container for introducing outside air as the contents decrease,
It comprises a bottomed cylindrical inner preform for forming the inner container and a bottomed cylindrical outer preform for forming the outer container,
With the opening of the inner preform fitted into the opening of the outer preform, the inner preform is inserted into the outer preform.
A longitudinal groove is formed on the inner circumferential surface of the opening of the outer preform, extending downward from the upper opening edge of the outer preform.
The aforementioned vertical groove has an opening for the outside air intake,
The opening of the inner preform is provided with a flange portion that extends continuously along its entire circumferential length and abuts against the upper end opening edge of the outer preform, thereby closing the upper end opening of the vertical groove.
The aforementioned outside air intake hole is located away from the upper opening edge of the outer preform,
A preform for double-walled container molding, wherein the inner circumferential surface of the mouth of the outer preform and the outer circumferential surface of the mouth of the inner preform are in contact with each other over the entire area except for the longitudinal groove.
前記外プリフォームにおける内周面と上端開口縁との接続部分と、
の間に、周方向の全長にわたって連続して延びる拡散隙間が設けられている、請求項1から3のいずれか1項に記載の二重容器成形用プリフォーム。 The connection portion between the outer circumferential surface of the inner preform and the lower surface of the flange portion,
The connection portion between the inner circumferential surface and the upper opening edge of the outer preform,
A preform for double-walled container molding according to any one of claims 1 to 3, wherein a diffusion gap is provided between them, extending continuously along the entire length in the circumferential direction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2025083829A JP7843894B2 (en) | 2021-04-26 | 2025-05-20 | Preform for double-walled container molding |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021073768A JP2022168374A (en) | 2021-04-26 | 2021-04-26 | Preform for molding double container |
| JP2025083829A JP7843894B2 (en) | 2021-04-26 | 2025-05-20 | Preform for double-walled container molding |
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| JP2021073768A Division JP2022168374A (en) | 2021-04-26 | 2021-04-26 | Preform for molding double container |
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| JP2025109904A JP2025109904A (en) | 2025-07-25 |
| JP7843894B2 true JP7843894B2 (en) | 2026-04-10 |
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| JP2025083829A Active JP7843894B2 (en) | 2021-04-26 | 2025-05-20 | Preform for double-walled container molding |
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| JP2021073768A Pending JP2022168374A (en) | 2021-04-26 | 2021-04-26 | Preform for molding double container |
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| US (1) | US20240217159A1 (en) |
| JP (2) | JP2022168374A (en) |
| CA (1) | CA3216615A1 (en) |
| WO (1) | WO2022230868A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011509219A (en) | 2008-01-08 | 2011-03-24 | ディスペンシング テクノロジーズ ビー.ブイ. | Composite container and manufacturing method thereof |
| JP2019081604A (en) | 2017-10-31 | 2019-05-30 | 株式会社吉野工業所 | Double container |
| JP2019151352A (en) | 2018-02-28 | 2019-09-12 | 株式会社吉野工業所 | Discharge container and preform assembly |
| JP2021028153A (en) | 2019-08-09 | 2021-02-25 | 株式会社吉野工業所 | Preform, synthetic resin container, and method for manufacturing synthetic resin container |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3796595B2 (en) * | 1996-12-20 | 2006-07-12 | 株式会社吉野工業所 | Molding method of the housing |
| US20080257847A1 (en) * | 2007-04-19 | 2008-10-23 | Inbev S.A. | Integrally blow-moulded bag-in-container having a bag anchoring point; process for the production thereof; and tool therefor |
| JP7072975B2 (en) * | 2018-02-28 | 2022-05-23 | 株式会社吉野工業所 | Double container |
| JP7308050B2 (en) * | 2019-02-27 | 2023-07-13 | 株式会社吉野工業所 | Double container evaluation method |
| JP7311318B2 (en) * | 2019-06-19 | 2023-07-19 | 東洋製罐グループホールディングス株式会社 | Stack preform used for molding double structure containers |
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2021
- 2021-04-26 JP JP2021073768A patent/JP2022168374A/en active Pending
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2022
- 2022-04-26 CA CA3216615A patent/CA3216615A1/en active Pending
- 2022-04-26 US US18/288,260 patent/US20240217159A1/en active Pending
- 2022-04-26 WO PCT/JP2022/018867 patent/WO2022230868A1/en not_active Ceased
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011509219A (en) | 2008-01-08 | 2011-03-24 | ディスペンシング テクノロジーズ ビー.ブイ. | Composite container and manufacturing method thereof |
| US20140299565A1 (en) | 2008-01-08 | 2014-10-09 | Dispensing Technologies B.V. | Composite container and method for manufacturing same ("multi-layer preform") |
| JP2019081604A (en) | 2017-10-31 | 2019-05-30 | 株式会社吉野工業所 | Double container |
| JP2019151352A (en) | 2018-02-28 | 2019-09-12 | 株式会社吉野工業所 | Discharge container and preform assembly |
| JP2021028153A (en) | 2019-08-09 | 2021-02-25 | 株式会社吉野工業所 | Preform, synthetic resin container, and method for manufacturing synthetic resin container |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2022168374A (en) | 2022-11-08 |
| CA3216615A1 (en) | 2022-11-03 |
| US20240217159A1 (en) | 2024-07-04 |
| WO2022230868A1 (en) | 2022-11-03 |
| JP2025109904A (en) | 2025-07-25 |
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