JP7526805B2 - Flavor inhalation device and flavor inhalation system - Google Patents
Flavor inhalation device and flavor inhalation system Download PDFInfo
- Publication number
- JP7526805B2 JP7526805B2 JP2022556855A JP2022556855A JP7526805B2 JP 7526805 B2 JP7526805 B2 JP 7526805B2 JP 2022556855 A JP2022556855 A JP 2022556855A JP 2022556855 A JP2022556855 A JP 2022556855A JP 7526805 B2 JP7526805 B2 JP 7526805B2
- Authority
- JP
- Japan
- Prior art keywords
- flavor
- inhalation device
- wrapper
- mass
- nonwoven fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 235000019634 flavors Nutrition 0.000 title claims description 259
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- 238000002485 combustion reaction Methods 0.000 claims description 40
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- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- 229940095045 isopulegol Drugs 0.000 description 1
- 150000002540 isothiocyanates Chemical class 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000001475 levisticum officinale koch root oil Substances 0.000 description 1
- 229940010454 licorice Drugs 0.000 description 1
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- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 239000001683 mentha spicata herb oil Substances 0.000 description 1
- DILOFCBIBDMHAY-UHFFFAOYSA-N methyl 2-(3,4-dimethoxyphenyl)acetate Chemical compound COC(=O)CC1=CC=C(OC)C(OC)=C1 DILOFCBIBDMHAY-UHFFFAOYSA-N 0.000 description 1
- 229940102398 methyl anthranilate Drugs 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000001627 myristica fragrans houtt. fruit oil Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- FPJRGEOLQICYQZ-UHFFFAOYSA-N n-[4-(cyanomethyl)phenyl]-5-methyl-2-propan-2-ylcyclohexane-1-carboxamide Chemical compound CC(C)C1CCC(C)CC1C(=O)NC1=CC=C(CC#N)C=C1 FPJRGEOLQICYQZ-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- ZYTMANIQRDEHIO-UHFFFAOYSA-N neo-Isopulegol Natural products CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
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- 239000010502 orange oil Substances 0.000 description 1
- LMXFTMYMHGYJEI-UHFFFAOYSA-N p-menthane-3,8-diol Chemical compound CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 description 1
- 229930006948 p-menthane-3,8-diol Natural products 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000008379 phenol ethers Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940081310 piperonal Drugs 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
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- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- NJGBTKGETPDVIK-UHFFFAOYSA-N raspberry ketone Chemical compound CC(=O)CCC1=CC=C(O)C=C1 NJGBTKGETPDVIK-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
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- 230000004044 response Effects 0.000 description 1
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- 235000013533 rum Nutrition 0.000 description 1
- 229940112950 sage extract Drugs 0.000 description 1
- 235000020752 sage extract Nutrition 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
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- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229930000308 sinensal Natural products 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- VQTLGLGPQXZERV-UHFFFAOYSA-M sodium;4-hydroxyundecanoate Chemical compound [Na+].CCCCCCCC(O)CCC([O-])=O VQTLGLGPQXZERV-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- UNYNVICDCJHOPO-UHFFFAOYSA-N sotolone Chemical compound CC1OC(=O)C(O)=C1C UNYNVICDCJHOPO-UHFFFAOYSA-N 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000010676 star anise oil Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- PINIEAOMWQJGBW-FYZOBXCZSA-N tenofovir hydrate Chemical compound O.N1=CN=C2N(C[C@@H](C)OCP(O)(O)=O)C=NC2=C1N PINIEAOMWQJGBW-FYZOBXCZSA-N 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
- 239000001917 trigonella foenum graecum l. absolute Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000001846 viola odorata l. leaf absolute Substances 0.000 description 1
- KPQMCAKZRXOZLB-AATRIKPKSA-N vomifoliol Chemical compound CC(O)\C=C\C1(O)C(C)=CC(=O)CC1(C)C KPQMCAKZRXOZLB-AATRIKPKSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Description
本発明は、香味吸引器具及び香味吸引システムに関する。 The present invention relates to a flavor inhalation device and a flavor inhalation system.
香味成分を含むたばこ等を備える香味吸引器具用のフィルターとしては、通常、濾過材としての酢酸セルロース繊維をトリアセチン等の可塑剤で結着し、筒状のラッパー内に充填したアセテートフィルターが用いられる。一方、酢酸セルロース繊維等の化学合成繊維ではなく、天然繊維を使用したフィルターとしては、例えば植物パルプからなる紙を濾過材として含むフィルター、植物パルプからなる不織布を濾過材として含むフィルター等が挙げられる(例えば特許文献1~3)。As a filter for a flavor inhalation device equipped with tobacco containing flavor components, acetate filters are usually used in which cellulose acetate fibers as a filtering material are bound with a plasticizer such as triacetin and packed into a cylindrical wrapper. On the other hand, as a filter using natural fibers instead of chemically synthesized fibers such as cellulose acetate fibers, there are, for example, filters containing paper made of plant pulp as a filtering material and filters containing nonwoven fabric made of plant pulp as a filtering material (for example, Patent Documents 1 to 3).
たばこの中には様々な香味成分が内因されていて、使用時にたばこが加熱されて香味成分が揮発、または、香味成分の熱分解成分が揮発して使用者に供給される。また、良好な香味付与の観点から、メンソール等の揮発性香料成分が別途添加された香味吸引器具が知られている(例えば特許文献4及び5)。該香味吸引器具では、使用時に揮発性香料成分が揮発して、たばこ由来の揮発した香味成分等と共に使用者に供給される。Tobacco contains various flavor components, and when the tobacco is heated during use, the flavor components volatilize, or the thermally decomposed components of the flavor components volatilize and are supplied to the user. From the perspective of providing a good flavor, flavor inhalation devices are known in which volatile flavor components such as menthol are added separately (e.g., Patent Documents 4 and 5). In these flavor inhalation devices, the volatile flavor components volatilize during use and are supplied to the user together with the volatilized flavor components derived from the tobacco.
しかしながら、前記たばこに含まれる香味成分、もしくは、前記別途添加される揮発性香料成分を含む香味吸引器具では、蔵置中に香味吸引器具を収容するパック内で前記香味成分もしくは前記揮発性香料成分が揮発し、前記香味成分もしくは前記揮発性香料成分と親和性が高い材料の内部に収着する場合がある。前記香味成分もしくは前記揮発性香料成分は親油性であることが多いため、前記香味吸引器具がアセテートフィルターを備える場合、蔵置中に親油性である酢酸セルロース繊維やトリアセチン等の可塑剤の内部に収着される場合がある。繊維内部や可塑剤内部に一度収着された香味成分もしくは揮発性香料成分は、使用時に主煙流中に供給されず収着されたままとなるため、香味成分もしくは揮発性香料成分の供給効率が低下する。However, in a flavor inhalation device containing a flavor component contained in the tobacco or a volatile flavor component added separately, the flavor component or the volatile flavor component may volatilize in a pack that contains the flavor inhalation device during storage and may be sorbed inside a material that has a high affinity for the flavor component or the volatile flavor component. Since the flavor component or the volatile flavor component is often lipophilic, when the flavor inhalation device is equipped with an acetate filter, the flavor component or the volatile flavor component may be sorbed inside a plasticizer such as cellulose acetate fiber or triacetin, which is lipophilic, during storage. The flavor component or the volatile flavor component once sorbed inside the fiber or plasticizer remains sorbed without being supplied to the main smoke flow during use, resulting in a decrease in the supply efficiency of the flavor component or the volatile flavor component.
本発明は、蔵置中における香味成分もしくは揮発性香料成分の収着が低減された香味吸引器具及び該香味吸引器具を備える香味吸引システムを提供することを目的とする。The present invention aims to provide a flavor inhalation device in which sorption of flavor components or volatile fragrance components during storage is reduced, and a flavor inhalation system equipped with the flavor inhalation device.
本発明は以下の実施態様を含む。 The present invention includes the following embodiments:
本実施形態に係る香味吸引器具は、
筒状の第一のラッパーと、前記第一のラッパー内部に充填されたたばこを含む充填物と、を含む香味生成セグメントと、
筒状の第二のラッパーと、前記第二のラッパー内部に充填された不織布と、を含むフィルターセグメントと、
を含む香味吸引器具であって、
前記不織布が、植物パルプを含む繊維が水溶性バインダーで結合して形成されている。
The flavor inhalation device according to this embodiment is
a flavor generating segment including a cylindrical first wrapper and a filler including tobacco filled inside the first wrapper;
A filter segment including a cylindrical second wrapper and a nonwoven fabric filled inside the second wrapper;
A flavor inhalation device comprising:
The nonwoven fabric is formed by binding fibers containing plant pulp with a water-soluble binder.
本実施形態に係る香味吸引システムは、本実施形態に係る香味吸引器具と、前記香味吸引器具を加熱する加熱装置と、を備える。The flavor inhalation system of this embodiment comprises a flavor inhalation device of this embodiment and a heating device that heats the flavor inhalation device.
本発明によれば、蔵置中における香味成分もしくは揮発性香料成分の収着が低減された香味吸引器具及び該香味吸引器具を備える香味吸引システムを提供することができる。According to the present invention, it is possible to provide a flavor inhalation device in which sorption of flavor components or volatile fragrance components during storage is reduced, and a flavor inhalation system equipped with the flavor inhalation device.
[香味吸引器具]
本実施形態に係る香味吸引器具は、筒状の第一のラッパーと、前記第一のラッパー内部に充填されたたばこを含む充填物と、を含む香味生成セグメントと、筒状の第二のラッパーと、前記第二のラッパー内部に充填された不織布と、を含むフィルターセグメントと、を含む。ここで、前記不織布は、植物パルプを含む繊維が水溶性バインダーで結合して形成されている。前記充填物は、前記たばこに加えて、さらに揮発性香料成分を含むことが好ましい。
[Flavor inhalation device]
The flavor inhalation device according to the present embodiment includes a flavor generating segment including a cylindrical first wrapper and a filling including tobacco filled inside the first wrapper, and a filter segment including a cylindrical second wrapper and a nonwoven fabric filled inside the second wrapper. Here, the nonwoven fabric is formed by binding fibers including plant pulp with a water-soluble binder. The filling preferably further includes a volatile flavor component in addition to the tobacco.
本実施形態に係る香味吸引器具では、アセテートフィルターの代わりに、植物パルプを含む繊維が水溶性バインダーで結合して形成された不織布が第二のラッパー内部に充填されたフィルターセグメントを備える。植物パルプの主成分であるセルロース及び水溶性バインダーは親水性であるため、親油性の香味成分及び揮発性香料成分を収着しにくい。したがって、本実施形態に係る香味吸引器具では蔵置中における香味成分もしくは揮発性香料成分の収着を低減でき、使用時における香味成分もしくは揮発性香料成分の供給効率を向上させることができる。また、植物パルプは天然繊維であるため、自然環境において分散性や分解性が高く、本実施形態に係る香味吸引器具は自然環境への負荷を低減することができる。なお、本明細書において、「香味成分」とは、たばこに含まれる成分であり、加熱により揮発して使用者に供給されることで、使用者に香味を付与可能な成分である。一方、「揮発性香料成分」とは、たばこ以外に別途添加される香料成分であり、「香味成分」と同様に、加熱により揮発して使用者に供給されることで、使用者に香味をさらに付与可能な成分である。In the flavor inhalation device according to the present embodiment, instead of an acetate filter, a filter segment is provided in which a nonwoven fabric formed by binding fibers containing plant pulp with a water-soluble binder is filled inside the second wrapper. Cellulose, which is the main component of plant pulp, and the water-soluble binder are hydrophilic, and therefore do not easily adsorb lipophilic flavor components and volatile flavor components. Therefore, the flavor inhalation device according to the present embodiment can reduce the sorption of flavor components or volatile flavor components during storage, and can improve the supply efficiency of flavor components or volatile flavor components during use. In addition, since plant pulp is a natural fiber, it has high dispersibility and decomposition in the natural environment, and the flavor inhalation device according to the present embodiment can reduce the burden on the natural environment. In this specification, the term "flavor component" refers to a component contained in tobacco, which is a component that can impart a flavor to the user by volatilizing when heated and being supplied to the user. On the other hand, the term "volatile flavor component" refers to a flavor component that is added separately to tobacco, and is a component that can impart a flavor to the user by volatilizing when heated and being supplied to the user, similar to the "flavor component".
本実施形態に係る香味吸引器具としては、燃焼型香味吸引器具(紙巻きたばこ、シガレット、シガリロ等)、非燃焼加熱型香味吸引器具が挙げられる。本実施形態に係る香味吸引器具は、前記香味生成セグメント及び前記フィルターセグメント以外にも、他のセグメントをさらに含んでもよい。以下、本実施形態について詳細に説明するが、本実施形態はこれらに限定されない。 Examples of the flavor inhalation device according to this embodiment include a combustion type flavor inhalation device (such as cigarettes, cigarettes, and cigarillos) and a non-combustion heating type flavor inhalation device. The flavor inhalation device according to this embodiment may further include other segments in addition to the flavor generation segment and the filter segment. The present embodiment will be described in detail below, but is not limited thereto.
(フィルターセグメント)
本実施形態に係るフィルターセグメントは、筒状の第二のラッパーと、前記第二のラッパー内部に充填された不織布と、を含む。該不織布は、植物パルプを含む繊維が水溶性バインダーで結合して形成されている。フィルターセグメントは、香味生成セグメントの下流側(吸口端側)に配置され、最も吸口端側に配置されることができる。
(Filter Segment)
The filter segment according to the present embodiment includes a cylindrical second wrapper and a nonwoven fabric filled inside the second wrapper. The nonwoven fabric is formed by binding fibers containing plant pulp with a water-soluble binder. The filter segment is disposed downstream (mouth end side) of the flavor generating segment, and may be disposed closest to the mouth end side.
第二のラッパーの材料としては、紙、ポリマーフィルム(セロハンフィルム、ポリオレフィンフィルム、ポリエステルフィルム等)等が挙げられる。第二のラッパーは、第二のラッパーの一方の端部と、第二のラッパーの他方の端部とが、親水性ポリマーを基材とする水溶性糊によって接着され、筒状になっていることが好ましい。糊として前記水溶性糊を用いることで、香味成分もしくは揮発性香料成分の収着をより抑制することができる。前記水溶性糊としては、例えばポリビニルアルコール、ポリ酢酸ビニル、エチレン酢酸ビニルコポリマー、デンプン等が好ましい。これらの水溶性糊は一種を用いてもよく、二種以上を併用してもよい。 Materials for the second wrapper include paper, polymer film (cellophane film, polyolefin film, polyester film, etc.), etc. The second wrapper is preferably formed into a cylindrical shape by bonding one end of the second wrapper to the other end of the second wrapper with a water-soluble glue based on a hydrophilic polymer. By using the water-soluble glue as the glue, the sorption of flavor components or volatile flavor components can be further suppressed. As the water-soluble glue, for example, polyvinyl alcohol, polyvinyl acetate, ethylene-vinyl acetate copolymer, starch, etc. are preferable. These water-soluble glues may be used alone or in combination of two or more.
また、前記第二のラッパーは、前記親水性ポリマーを基材とする水溶性糊により不織布に接着されていることが、前記第二のラッパーと不織布とを固定し、位置ずれしにくくすることができ、また香味成分もしくは揮発性香料成分の収着をより抑制することができるため好ましい。前記水溶性糊としては、前記と同様のものを用いることができる。これらの水溶性糊は一種を用いてもよく、二種以上を併用してもよい。It is also preferable that the second wrapper is adhered to the nonwoven fabric by a water-soluble glue based on the hydrophilic polymer, since this fixes the second wrapper and the nonwoven fabric, making them less likely to shift, and further suppresses the sorption of flavor components or volatile flavor components. The water-soluble glue may be the same as that described above. These water-soluble glues may be used alone or in combination of two or more.
前記不織布は、植物パルプを含む繊維で構成され、植物パルプからなる繊維で構成されることが好ましい。不織布の坪量は、フィルター硬度およびフィルター生産性の観点から、25~70g/m2であることが好ましく、30~60g/m2であることがより好ましく、40~55g/m2がさらに好ましい。前記繊維は水溶性バインダーで結合されている。本実施形態において「水溶性バインダー」とは、水揮散型バインダーを指す。水揮散型バインダーは、溶剤としての水が揮散することによってバインダーが固化し接着強さを発揮する。水揮散型バインダーは、水溶液バインダー、水分散バインダーに分類分けできる。水揮散型バインダーは、有機溶剤揮散型バインダーと比較して、バインダーが水に溶解する、もしくは水中にエマルジョン分散する必要性が有るため、バインダーとしては水との親和性が高いものが使用される。水溶液バインダーとしては、ポリビニルアルコール(PVA)、にかわ、でんぷん、修飾でんぷん、カルボキシメチルセルロース(CMC)等の修飾セルロース等を例示することができる。水分散バインダーとしては、ポリ酢酸ビニル(PVAc)、酢酸ビニルアクリルコポリマー、エチレン酢酸ビニルコポリマー、増粘多糖類、ガム類、アクリル樹脂等を例示できる。水揮散型バインダーの定義は「接着・粘着の事典、監修:山口章三郎、発行:株式会社朝倉書店」を参照できる。水溶性バインダーのハンセンの溶解度パラメータ(HSP)は、σD=17.59~19.30、σP=4.91~10.40、σH=8.50~26.50で表すこともできる。 The nonwoven fabric is preferably made of fibers containing plant pulp, and is preferably made of fibers made of plant pulp. The basis weight of the nonwoven fabric is preferably 25 to 70 g/m 2 , more preferably 30 to 60 g/m 2 , and even more preferably 40 to 55 g/m 2 , from the viewpoint of filter hardness and filter productivity. The fibers are bound by a water-soluble binder. In this embodiment, the term "water-soluble binder" refers to a water-volatile binder. The water-volatile binder solidifies as the water as a solvent evaporates, and exerts adhesive strength. The water-volatile binder can be classified into an aqueous solution binder and a water-dispersed binder. Compared with an organic solvent-volatile binder, the water-volatile binder needs to be dissolved in water or emulsion-dispersed in water, so a binder with high affinity to water is used. Examples of aqueous binders include polyvinyl alcohol (PVA), glue, starch, modified starch, and modified cellulose such as carboxymethyl cellulose (CMC). Examples of aqueous binders include polyvinyl acetate (PVAc), vinyl acetate acrylic copolymer, ethylene vinyl acetate copolymer, thickening polysaccharides, gums, and acrylic resins. For the definition of water-volatile binders, see "Encyclopedia of Adhesives and Cohesives, Supervised by Shozaburo Yamaguchi, Published by Asakura Publishing Co., Ltd." The Hansen solubility parameters (HSP) of water-soluble binders can also be expressed as σD = 17.59 to 19.30, σP = 4.91 to 10.40, and σH = 8.50 to 26.50.
前記水溶性バインダーは、香味成分もしくは揮発性香料成分の収着をより抑制することができる観点から、デンプン、修飾デンプン、修飾セルロース、ポリビニルアルコール(PVA)、ポリ酢酸ビニル(PVAc)、酢酸ビニルアクリルコポリマー、エチレン酢酸ビニルコポリマー、増粘多糖類、及びガム類からなる群から選択される少なくとも一種のバインダーであることが好ましく、ポリビニルアルコール及び酢酸ビニルアクリルコポリマーの混合物であることがより好ましい。前記不織布は、香味吸引器具用のフィルターとして第二のラッパーで円柱状に巻装される際に、製造装置の表面を高速で搬送される。酢酸ビニルアクリルコポリマーを水溶性バインダーの一つとして選定すると高速搬送時の装置表面との摩擦で発生する熱による不織布の劣化を防止することができる。前記水溶性バインダーがポリビニルアルコール及び酢酸ビニルアクリルコポリマーの混合物である場合、ポリビニルアルコール及び酢酸ビニルアクリルコポリマーの合計100質量%に対する、ポリビニルアルコールの割合は、17質量%以上100質量%未満であることが好ましく、17質量%以上70質量%以下であることがより好ましく、17質量%以上40質量%未満であることがさらに好ましく、17質量%以上30質量%以下であることが特に好ましい。特に、該割合が17質量%以上40質量%未満である場合、香味成分もしくは揮発性香料成分の収着を十分に抑制しつつ、使用時に唾液により不織布が溶解することを十分に防ぐことができる。From the viewpoint of suppressing the sorption of flavor components or volatile flavor components, the water-soluble binder is preferably at least one binder selected from the group consisting of starch, modified starch, modified cellulose, polyvinyl alcohol (PVA), polyvinyl acetate (PVAc), vinyl acetate acrylic copolymer, ethylene vinyl acetate copolymer, thickening polysaccharides, and gums, and more preferably a mixture of polyvinyl alcohol and vinyl acetate acrylic copolymer. When the nonwoven fabric is wrapped in a cylindrical shape with a second wrapper as a filter for a flavor inhaler, the nonwoven fabric is transported at high speed on the surface of a manufacturing device. Selecting a vinyl acetate acrylic copolymer as one of the water-soluble binders can prevent deterioration of the nonwoven fabric due to heat generated by friction with the surface of the device during high-speed transport. When the water-soluble binder is a mixture of polyvinyl alcohol and vinyl acetate acrylic copolymer, the proportion of polyvinyl alcohol relative to the total of polyvinyl alcohol and vinyl acetate acrylic copolymer (100% by mass) is preferably 17% by mass or more and less than 100% by mass, more preferably 17% by mass or more and less than 70% by mass, even more preferably 17% by mass or more and less than 40% by mass, and particularly preferably 17% by mass or more and less than 30% by mass. In particular, when the proportion is 17% by mass or more and less than 40% by mass, it is possible to sufficiently prevent the nonwoven fabric from being dissolved by saliva during use while sufficiently suppressing the sorption of flavor components or volatile flavor components.
また、前記水溶性バインダーの、ハンセンの溶解度パラメータ(HSP)は、σD=17.59~18.16、σP=4.91~6.74、σH=8.50~14.50であることが好ましく、σD=17.69~17.78、σP=5.21~5.52、σH=9.50~10.50であることがより好ましい。また、前記水溶性バインダーの、ハンセンの溶解度パラメータ(HSP)は、σD=17.59~18.92、σP=4.91~9.18、σH=8.50~22.50であることもできる。HSPの値が前記範囲内であることにより、香味成分もしくは揮発性香料成分の収着を十分に抑制しつつ、使用時に唾液により不織布が溶解することを十分に防ぐことができる。なお、HSPの値はHSPiPのデータベースにおける値を用いることができ、複数成分の混合物におけるHSPの値は、各成分の体積分率で表される。The water-soluble binder preferably has a Hansen solubility parameter (HSP) of σD = 17.59 to 18.16, σP = 4.91 to 6.74, and σH = 8.50 to 14.50, and more preferably has a Hansen solubility parameter (HSP) of σD = 17.69 to 17.78, σP = 5.21 to 5.52, and σH = 9.50 to 10.50. The water-soluble binder may also have a Hansen solubility parameter (HSP) of σD = 17.59 to 18.92, σP = 4.91 to 9.18, and σH = 8.50 to 22.50. By having the HSP value within the above range, it is possible to sufficiently prevent the nonwoven fabric from being dissolved by saliva during use while sufficiently suppressing the sorption of flavor components or volatile flavor components. The HSP value can be the value in the HSPiP database, and the HSP value in a mixture of multiple components is expressed as the volume fraction of each component.
不織布100質量%中の水溶性バインダーの含有量は、10~25質量%であることが好ましく、15~20質量%であることがより好ましい。該含有量が10質量%以上であることにより、繊維同士を十分に結着することができる。また、該含有量が25質量%以下であることにより、不織布中の繊維含有量を増加させることができ、また香味成分もしくは揮発性香料成分の収着を十分に抑制することができる。The content of the water-soluble binder in 100% by mass of the nonwoven fabric is preferably 10 to 25% by mass, and more preferably 15 to 20% by mass. When the content is 10% by mass or more, the fibers can be sufficiently bound together. Furthermore, when the content is 25% by mass or less, the fiber content in the nonwoven fabric can be increased, and the sorption of flavor components or volatile fragrance components can be sufficiently suppressed.
第二のラッパー内部への不織布の充填方法は特に限定されないが、シート状の不織布を複数枚重ね、S字状形状に折りたたんで筒状の第二のラッパー内部に充填することが好ましい。このように不織布が充填されていることにより、フィルターセグメントの端面において不織布間に間隙が視認されにくくなり、外観が良好となる。また、適度な通気抵抗が得られる。Although there are no particular limitations on the method of filling the second wrapper with nonwoven fabric, it is preferable to stack multiple sheets of nonwoven fabric, fold them into an S-shape, and fill the inside of the cylindrical second wrapper. By filling the nonwoven fabric in this way, gaps between the nonwoven fabrics are less visible on the end faces of the filter segments, resulting in a good appearance. In addition, an appropriate airflow resistance is obtained.
(香味生成セグメント)
本実施形態に係る香味生成セグメントは、筒状の第一のラッパーと、前記第一のラッパー内部に充填されたたばこを含む充填物と、を含む。本発明の効果がより得られる観点から、該充填物は、さらに揮発性香料成分を含むことが好ましい。また、香味生成セグメントが非燃焼加熱型香味吸引器具用の香味生成セグメントである場合、該充填物はさらにエアロゾル生成基材を含むことができる。香味生成セグメントは、フィルターセグメントの上流側(吸口端とは反対側)に配置される。第一のラッパーの材料としては、第二のラッパーの材料と同様であることができる。
(Flavor Generation Segment)
The flavor generating segment according to this embodiment includes a cylindrical first wrapper and a filling material including tobacco filled inside the first wrapper. From the viewpoint of obtaining the effect of the present invention more effectively, it is preferable that the filling material further includes a volatile flavor component. In addition, when the flavor generating segment is a flavor generating segment for a non-combustion heating type flavor inhalation device, the filling material may further include an aerosol-generating base material. The flavor generating segment is disposed on the upstream side (opposite the mouth end) of the filter segment. The material of the first wrapper may be the same as that of the second wrapper.
たばこの種類としては特に限定されないが、例えば黄色種、バーレー種、オリエント種、在来種、その他のニコチアナ・タバカム系品種やニコチアナ・ルスチカ系品種を、目的とする味となるように適宜ブレンドして用いることができる。たばこの種類の詳細は、例えば「たばこの事典、たばこ総合研究センター、2009.3.31」にその詳細が開示されている。たばこ内には様々な香味成分が含まれている。これらのたばこに含まれる香味成分の中には揮発性の香味成分が存在する。本実施形態の構成により、これらたばこに内在する揮発性の香味成分のフィルターへの収着が抑制される。たばこに内在する揮発性の香味成分としては、例えばリモネン、スチレン、イソプレン等が挙げられる。The type of tobacco is not particularly limited, but for example, flue-cured, burley, orient, native, other Nicotiana tabacum or Nicotiana rustica varieties can be appropriately blended to achieve the desired flavor. Details of the types of tobacco are disclosed in, for example, "Encyclopedia of Tobacco, Tobacco Research Center, March 31, 2009." Tobacco contains various flavor components. Among the flavor components contained in these tobaccos, there are volatile flavor components. The configuration of this embodiment suppresses the sorption of these volatile flavor components inherent in tobacco to the filter. Examples of volatile flavor components inherent in tobacco include limonene, styrene, and isoprene.
揮発性香料成分としては、例えば、「周知・慣用技術集(香料)」(2007年3月14日、特許庁発行)、「最新 香料の事典(普及版)」(2012年2月25日、荒井綜一・小林彰夫・矢島泉・川崎通昭 編、朝倉書店)、および「Tobacco Flavoring for Smoking Products」(1972年6月、R.J.REYNOLDS TOBACCO COMPANY)に記載されているような広範な種類の揮発性香料成分を使用することができる。当該揮発性香料成分としては、例えば、イソチオシアネート類、インドールおよびその誘導体、エーテル類、エステル類、ケトン類、脂肪酸類、脂肪族高級アルコール類、脂肪族高級アルデヒド類、脂肪族高級炭化水素類、チオエーテル類、チオール類、テルペン系炭化水素類、フェノールエーテル類、フェノール類、フルフラールおよびその誘導体、芳香族アルコール類、芳香族アルデヒド類、ラクトン類などから選ばれる揮発性香料成分を単独、あるいは組み合わせてなるものが挙げられる。揮発性香料成分は、冷感/温感刺激をもたらす成分であっても良い。As the volatile flavoring ingredient, a wide variety of volatile flavoring ingredients can be used, for example, as described in "Collection of Well-Known and Commonly Used Technology (Fragrances)" (March 14, 2007, published by the Japan Patent Office), "Latest Encyclopedia of Flavors (Popular Edition)" (February 25, 2012, edited by Soichi Arai, Akio Kobayashi, Izumi Yajima, and Michiaki Kawasaki, Asakura Publishing), and "Tobacco Flavoring for Smoking Products" (June 1972, R. J. Reynolds Tobacco Company). Examples of the volatile fragrance component include volatile fragrance components selected from isothiocyanates, indole and its derivatives, ethers, esters, ketones, fatty acids, higher aliphatic alcohols, higher aliphatic aldehydes, higher aliphatic hydrocarbons, thioethers, thiols, terpene hydrocarbons, phenol ethers, phenols, furfural and its derivatives, aromatic alcohols, aromatic aldehydes, lactones, etc., used alone or in combination. The volatile fragrance component may be a component that provides a cooling/warming sensation.
当該揮発性香料成分としては、より具体的には、アセトアニソール、アセトフェノン、アセチルピラジン、2-アセチルチアゾール、アルファルファエキストラクト、アミルアルコール、酪酸アミル、トランス-アネトール、スターアニス油、リンゴ果汁、ペルーバルサム油、ミツロウアブソリュート、ベンズアルデヒド、ベンゾインレジノイド、ベンジルアルコール、安息香酸ベンジル、フェニル酢酸ベンジル、プロピオン酸ベンジル、2,3-ブタンジオン、2-ブタノール、酪酸ブチル、酪酸、カラメル、カルダモン油、キャロブアブソリュート、β-カロテン、ニンジンジュース、L-カルボン、β-カリオフィレン、カシア樹皮油、シダーウッド油、セロリーシード油、カモミール油、シンナムアルデヒド、ケイ皮酸、シンナミルアルコール、ケイ皮酸シンナミル、シトロネラ油、DL-シトロネロール、クラリセージエキストラクト、コーヒー、コニャック油、コリアンダー油、クミンアルデヒド、ダバナ油、δ-デカラクトン、γ-デカラクトン、デカン酸、ディルハーブ油、3,4-ジメチル-1,2-シクロペンタンジオン、4,5-ジメチル-3-ヒドロキシ-2,5-ジヒドロフラン-2-オン、3,7-ジメチル-6-オクテン酸、2,3-ジメチルピラジン、2,5-ジメチルピラジン、2,6-ジメチルピラジン、2-メチル酪酸エチル、酢酸エチル、酪酸エチル、ヘキサン酸エチル、イソ吉草酸エチル、乳酸エチル、ラウリン酸エチル、レブリン酸エチル、エチルマルトール、オクタン酸エチル、オレイン酸エチル、パルミチン酸エチル、フェニル酢酸エチル、プロピオン酸エチル、ステアリン酸エチル、吉草酸エチル、エチルバニリン、エチルバニリングルコシド、2-エチル-3,(5または6)-ジメチルピラジン、5-エチル-3-ヒドロキシ-4-メチル-2(5H)-フラノン、2-エチル-3-メチルピラジン、ユ-カリプトール、フェネグリークアブソリュート、ジェネアブソリュート、リンドウ根インフュージョン、ゲラニオ-ル、酢酸ゲラニル、ブドウ果汁、グアヤコール、グァバエキストラクト、γ-ヘプタラクトン、γ-ヘキサラクトン、ヘキサン酸、シス-3-ヘキセン-1-オール、酢酸ヘキシル、ヘキシルアルコール、フェニル酢酸ヘキシル、ハチミツ、4-ヒドロキシ-3-ペンテン酸ラクトン、4-ヒドロキシ-4-(3-ヒドロキシ-1-ブテニル)-3,5,5-トリメチル-2-シクロヘキセン-1-オン、4-(パラ-ヒドロキシフェニル)-2-ブタノン、4-ヒドロキシウンデカン酸ナトリウム、インモルテルアブソリュート、β-イオノン、酢酸イソアミル、酪酸イソアミル、フェニル酢酸イソアミル、酢酸イソブチル、フェニル酢酸イソブチル、ジャスミンアブソリュート、コーラナッツティンクチャー、ラブダナム油、レモンテルペンレス油、カンゾウエキストラクト、リナロール、酢酸リナリル、ロベージ根油、メープルシロップ、メンソール、リモネン、cis-3-ヘキサノール、メントン、酢酸L-メンチル、パラメトキシベンズアルデヒド、メチル-2-ピロリルケトン、アントラニル酸メチル、フェニル酢酸メチル、サリチル酸メチル、4’-メチルアセトフェノン、メチルシクロペンテノロン、3-メチル吉草酸、ミモザアブソリュート、トウミツ、ミリスチン酸、ネロール、ネロリドール、γ-ノナラクトン、ナツメグ油、δ-オクタラクトン、オクタナール、オクタン酸、オレンジフラワー油、オレンジ油、オリス根油、パルミチン酸、ω-ペンタデカラクトン、ペパーミント油、プチグレインパラグアイ油、フェネチルアルコール、フェニル酢酸フェネチル、フェニル酢酸、ピペロナール、プラムエキストラクト、プロペニルグアエトール、酢酸プロピル、3-プロピリデンフタリド、プルーン果汁、ピルビン酸、レーズンエキストラクト、ローズ油、ラム酒、セージ油、サンダルウッド油、スペアミント油、スチラックスアブソリュート、マリーゴールド油、ティーディスティレート、α-テルピネオール、酢酸テルピニル、5,6,7,8-テトラヒドロキノキサリン、1,5,5,9-テトラメチル-13-オキサシクロ(8.3.0.0(4.9))トリデカン、2,3,5,6-テトラメチルピラジン、タイム油、トマトエキストラクト、2-トリデカノン、クエン酸トリエチル、4-(2,6,6-トリメチル-1-シクロヘキセニル)2-ブテン-4-オン、2,6,6-トリメチル-2-シクロヘキセン-1,4-ジオン、4-(2,6,6-トリメチル-1,3-シクロヘキサジエニル)2-ブテン-4-オン、2,3,5-トリメチルピラジン、γ-ウンデカラクトン、γ-バレロラクトン、バニラエキストラクト、バニリン、ベラトルアルデヒド、バイオレットリーフアブソリュート、シトラール、マンダリン油、4-(アセトキシメチル)トルエン、2-メチル-1-ブタノール、10-ウンデセン酸エチル、ヘキサン酸イソアミル、1-フェニルエチル酢酸、ラウリン酸、8-メルカプトメントン、シネンサール、酪酸ヘキシル、植物粉末(ハーブ粉末、フラワー粉末、スパイス粉末、茶粉末:ココア粉末、キャロブ粉末、コリアンダー粉末、リコリス粉末、オレンジピール粉末、ローズピップ粉末、カモミールフラワ粉末、レモンバーベナ粉末、ペパーミント粉末、リーフ粉末、スペアミント粉末、紅茶粉末など)、カンファー、イソプレゴール、シネオール、ハッカオイル、ユーカリプタスオイル、2-l-メントキシエタノール(COOLACT(登録商標)5)、3-l-メントキシプロパン-1,2-ジオール(COOLACT(登録商標)10)、l-メンチル-3-ヒドロキシブチレート(COOLACT(登録商標)20)、p-メンタン-3,8-ジオール(COOLACT(登録商標)38D)、N-(2-ヒドロキシ-2-フェニルエチル)-2-イソプロピル-5,5-ジメチルシクロヘキサン-1-カルボキサミド(COOLACT(登録商標)370)、N-(4-(シアノメチル)フェニル)-2-イソプロピル-5,5-ジメチルシクロヘキサンカルボキサミド(COOLACT(登録商標)400)、N-(3-ヒドロキシ-4-メトキシフェニル)-2-イソプロピル-5,5-ジメチルシクロヘキサンカルボキサミド、N-エチル-p-メンタン-3-カルボアミド(WS-3)、エチル-2-(p-メンタン-3-カルボキサミド)アセテート(WS-5)、N-(4-メトキシフェニル)-p-メンタンカルボキサミド(WS-12)、2-イソプロピル-N,2,3-トリメチルブチラミド(WS-23)、3-l-メントキシ-2-メチルプロパン-1,2-ジオール、2-l-メントキシエタン-1-オール、3-l-メントキシプロパン-1-オール、4-l-メントキシブタン-1-オール、メンチルラクテート(FEMA3748)、メントングリセリンアセタール(Frescolat MGA、FEMA3807、FEMA3808)、2-(2-l-メンチルオキシエチル)エタノール、グリオキシル酸メンチル、2-ピロリドン-5-カルボン酸メンチル、コハク酸メンチル(FEMA3810)、N-(2-(ピリジン-2-イル)-エチル)-3-p-メンタンカルボキサミド(FEMA4549)、N-(エトキシカルボニルメチル)-p-メンタン-3-カルボキサミド、N-(4-シアノメチルフェニル)-p-メンタンカルボキサミド、およびN-(4-アミノカルボニルフェニル)-p-メンタンなどが挙げられる。これらの中でも揮発性香料成分としては、本発明の効果が得られやすい観点から親油性の高い成分が好ましく、例えばメンソール、リモネン、cis-3-ヘキサノール、メントンが好ましい。これらの揮発性香料成分は一種を用いてもよく、二種以上を併用してもよい。More specifically, the volatile fragrance components include acetanisole, acetophenone, acetylpyrazine, 2-acetylthiazole, alfalfa extract, amyl alcohol, amyl butyrate, trans-anethole, star anise oil, apple juice, balsam of Peru oil, beeswax absolute, benzaldehyde, benzoin resinoid, benzyl alcohol, benzyl benzoate, benzyl phenylacetate, benzyl propionate, 2,3-butanedione, 2-butanol, butyl butyrate, butyric acid, caramel, cardamom oil, carob absolute, β-carotene, carrot juice, L-carvone, β-caryophyllene, cassia bark oil, cedarwood oil, celery seed oil, chamomile oil, cinnamaldehyde, cinnamic acid, cinnamyl alcohol, cinnamyl cinnamate, citronella oil, DL- Citronellol, Clary Sage Extract, Coffee, Cognac Oil, Coriander Oil, Cuminaldehyde, Davana Oil, δ-Decalactone, γ-Decalactone, Decanoic Acid, Dill Herb Oil, 3,4-Dimethyl-1,2-Cyclopentanedione, 4,5-Dimethyl-3-Hydroxy-2,5-Dihydrofuran-2-one, 3,7-Dimethyl-6-Octenoic Acid, 2,3-Dimethylpyrazine, 2,5-Dimethylpyrazine, 2,6-Dimethylpyrazine, Ethyl 2-Methylbutyrate, Ethyl Acetate, Ethyl Butyrate, Ethyl Hexanoate, Ethyl Isovalerate, Ethyl Lactate, Ethyl Laurate, Ethyl Levulinate, Ethyl Maltol, Ethyl Octanoate, Ethyl Oleate, Ethyl Palmitate, Ethyl Phenylacetate, Ethyl Propionate, Ethyl Stearate, Ethyl Valerate, Ethyl Vanillin, Ethyl Vanillin Glucosyl , 2-ethyl-3,(5 or 6)-dimethylpyrazine, 5-ethyl-3-hydroxy-4-methyl-2(5H)-furanone, 2-ethyl-3-methylpyrazine, eucalyptol, fenugreek absolute, gene absolute, gentian root infusion, geraniol, geranyl acetate, grape juice, guaiacol, guava extract, gamma-heptalactone, gamma-hexalactone, hexanoic acid, cis-3-hexen-1-ol, hexyl acetate, hexyl alcohol, phenylhexyl acetate, honey, 4-hydroxy-3-pentenoic acid lactone, 4-hydroxy-4-(3-hydroxy-1-butenyl)-3,5,5-trimethyl-2-cyclohexen-1-one, 4-(para-hydroxyphenyl)-2-butanone, sodium 4-hydroxyundecanoate, immortell Absolute, β-Ionone, Isoamyl acetate, Isoamyl butyrate, Isoamyl phenylacetate, Isobutyl acetate, Isobutyl phenylacetate, Jasmine absolute, Cola nut tincture, Labdanum oil, Lemon terpeneless oil, Licorice extract, Linalool, Linalyl acetate, Lovage root oil, Maple syrup, Menthol, Limonene, Cis-3-hexanol, Menthone, L-menthyl acetate, Paramethoxybenzaldehyde, Methyl 2-pyrrolyl ketone, Methyl anthranilate, Methyl phenylacetate, Methyl salicylate, 4'-Methylacetophenone, Methylcyclopentenolone, 3-Methylvaleric acid, Mimosa absolute, Honey beet, Myristic acid, Nerol, Nerolidol, γ-Nonalactone, Nutmeg oil, δ-Octalactone, Octanal, Octanoic acid, Orange fruit Rose oil, orange oil, orris root oil, palmitic acid, omega-pentadecalactone, peppermint oil, petitgrain Paraguay oil, phenethyl alcohol, phenethyl phenylacetate, phenylacetic acid, piperonal, plum extract, propenyl guaethol, propyl acetate, 3-propylidenephthalide, prune juice, pyruvic acid, raisin extract, rose oil, rum, sage oil, sandalwood oil, spearmint oil, styrax absolute, marigold oil, tea distillate, alpha-terpineol, terpinyl acetate, 5,6,7,8-tetrahydroquinoxaline, 1,5,5,9-tetramethyl-13-oxacyclo(8.3.0.0(4.9))tridecane, 2,3,5,6-tetramethylpyrazine, thyme oil, tomato extract, 2-tridecanone, citric acid Triethyl, 4-(2,6,6-trimethyl-1-cyclohexenyl)2-buten-4-one, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, 4-(2,6,6-trimethyl-1,3-cyclohexadienyl)2-buten-4-one, 2,3,5-trimethylpyrazine, gamma-undecalactone, gamma-valerolactone, vanilla extract, vanillin, veratraldehyde, violet leaf absolute, citral, mandarin oil, 4-(acetoxymethyl)toluene, 2-methyl-1-butanol, ethyl 10-undecenoate, isoamyl hexanoate, 1-phenylethyl acetate, lauric acid, 8-mercaptomenthone, sinensal, hexyl butyrate, plant powders (herb powders, flower powders, spice powders, tea powders: cocoa powder, carob powder, coriander powder, licorice powder, orange peel powder, rose pip powder, chamomile flower powder, lemon verbena powder, peppermint powder, leaf powder, spearmint powder, black tea powder, etc.), camphor, isopulegol, cineole, peppermint oil, eucalyptus oil, 2-l-menthoxyethanol (COOLACT® 5), 3-l-menthoxypropane-1,2-diol (COOLACT® 10), l-menthyl-3-hydroxybutyrate (COOLACT® 20), p-menthane-3,8-diol (COOLACT® 38D), N-(2-hydroxy-2-phenylethyl)-2-isopropyl-5,5-dimethylcyclohexane-1-carboxamide (COOLACT® 370), N-(4-(cyanomethyl)phenyl)-2-isopropyl- 5,5-Dimethylcyclohexanecarboxamide (COOLACT® 400), N-(3-hydroxy-4-methoxyphenyl)-2-isopropyl-5,5-dimethylcyclohexanecarboxamide, N-ethyl-p-menthane-3-carboxamide (WS-3), ethyl-2-(p-menthane-3-carboxamide) acetate (WS-5), N-(4-methoxyphenyl)-p-menthane Menthyl carboxamide (WS-12), 2-isopropyl-N,2,3-trimethylbutyramide (WS-23), 3-l-menthoxy-2-methylpropane-1,2-diol, 2-l-menthoxyethan-1-ol, 3-l-menthoxypropan-1-ol, 4-l-menthoxybutan-1-ol, menthyl lactate (FEMA3748), menthone glycerin acetal (Frescolat MGA, FEMA3807, FEMA3808), 2-(2-l-menthyloxyethyl)ethanol, menthyl glyoxylate, menthyl 2-pyrrolidone-5-carboxylate, menthyl succinate (FEMA3810), N-(2-(pyridin-2-yl)-ethyl)-3-p-menthanecarboxamide (FEMA4549), N-(ethoxycarbonylmethyl)-p-menthane-3-carboxamide, N-(4-cyanomethylphenyl)-p-menthanecarboxamide, and N-(4-aminocarbonylphenyl)-p-menthane. Among these, as the volatile flavor component, a component having high lipophilicity is preferred from the viewpoint of easily achieving the effects of the present invention, and for example, menthol, limonene, cis-3-hexanol, and menthone are preferred. These volatile flavor components may be used alone or in combination of two or more.
前記充填物が揮発性香料成分を含む場合、揮発性香料成分は、前記充填物100質量%に対して0.1~10質量%添加されていることが好ましく、0.3~8質量%添加されていることがより好ましく、0.5~5質量%添加されていることがさらに好ましい。揮発性香料成分が前記充填物100質量%に対して0.1質量%以上添加されていることにより、揮発性香料成分の収着の課題がより生じやすく、本発明の効果がより得られやすい。また、揮発性香料成分が前記充填物100質量%に対して10質量%以下添加されていることにより、前記充填物中のたばこの含有量を増やすことができ、使用時に十分なたばこの香味を提供できる。When the filling contains a volatile flavor component, the volatile flavor component is preferably added in an amount of 0.1 to 10% by mass, more preferably 0.3 to 8% by mass, and even more preferably 0.5 to 5% by mass, relative to 100% by mass of the filling. By adding 0.1% or more by mass of the volatile flavor component relative to 100% by mass of the filling, the problem of sorption of the volatile flavor component is more likely to occur, and the effects of the present invention are more likely to be obtained. Furthermore, by adding 10% or less by mass of the volatile flavor component relative to 100% by mass of the filling, the tobacco content in the filling can be increased, and a sufficient tobacco flavor can be provided during use.
エアロゾル生成基材は加熱によりエアロゾルを生成し得る材料であり、グリセリン又はプロピレングリコールであることが好ましい。グリセリン及びプロピレングリコールは保湿剤であり、蔵置中に水分を吸収する。非燃焼加熱型香味吸引器具では使用前の加熱時に、該水分が蒸発して水蒸気となり、使用時の1パフ目に該水蒸気がほぼ全て主流煙として使用者の口内に供給される。そのため、煙が熱い場合があるが、本実施形態ではフィルターセグメントが、植物パルプを含む繊維が水溶性バインダーで結合して形成された不織布を含むため、該水蒸気を吸着、濾過できる。これにより、1パフ目の煙の体感温度を低下させることができる。香味吸引器具が非燃焼加熱型香味吸引器具である場合、エアロゾル生成基材は、前記充填物100質量%に対して5~50質量%添加されていることができる。The aerosol-generating substrate is a material capable of generating an aerosol by heating, and is preferably glycerin or propylene glycol. Glycerin and propylene glycol are humectants that absorb moisture during storage. In a non-combustion heating type flavor inhalation device, when heated before use, the moisture evaporates to form water vapor, and almost all of the water vapor is supplied to the user's mouth as mainstream smoke at the first puff during use. Therefore, the smoke may be hot, but in this embodiment, the filter segment includes a nonwoven fabric formed by binding fibers containing plant pulp with a water-soluble binder, so that the water vapor can be adsorbed and filtered. This makes it possible to reduce the perceived temperature of the smoke at the first puff. When the flavor inhalation device is a non-combustion heating type flavor inhalation device, the aerosol-generating substrate can be added in an amount of 5 to 50% by mass relative to 100% by mass of the filling.
(燃焼型香味吸引器具)
本実施形態に係る燃焼型香味吸引器具の一例を図1に示す。図1に示されるように、燃焼型香味吸引器具8は、香味生成セグメント1と、香味生成セグメント1に隣接して設けられたフィルターセグメント2とを含む。香味生成セグメント1は、たばこを含む充填物3と、充填物3の周囲を巻いた第一のラッパー4とを含む。フィルターセグメント2は、不織布5と、不織布5の周囲を巻いた第二のラッパー6とを含む。香味生成セグメント1とフィルターセグメント2とは、香味生成セグメント1及びフィルターセグメント2上に巻かれたチップペーパー部材7によって連結されている。チップペーパー部材7は、その外周の一部に通気孔を有していてもよい。通気孔の数は1つでも複数でもよく、例えば10~40個形成されていることができる。通気孔の数が複数の場合、通気孔は例えばチップペーパー部材7の外周部に一列に並んで環状に配置されることができる。複数の通気孔は、略一定の間隔で配置されることができる。通気孔を設けることによって、吸引時に通気孔からフィルターセグメント2内に空気が取り込まれる。主流煙を通気孔からの外気によって薄めることで、所望のタール値の製品設計を行うことができる。
(Combustion-type flavor inhalation device)
An example of a combustion type flavor inhalation device according to the present embodiment is shown in FIG. 1. As shown in FIG. 1, the combustion type flavor inhalation device 8 includes a flavor generating segment 1 and a filter segment 2 provided adjacent to the flavor generating segment 1. The flavor generating segment 1 includes a filler 3 containing tobacco and a first wrapper 4 wrapped around the filler 3. The filter segment 2 includes a nonwoven fabric 5 and a second wrapper 6 wrapped around the nonwoven fabric 5. The flavor generating segment 1 and the filter segment 2 are connected by a tipping paper member 7 wrapped around the flavor generating segment 1 and the filter segment 2. The tipping paper member 7 may have an air hole in a part of its outer periphery. The number of the air holes may be one or more, and for example, 10 to 40 holes may be formed. When the number of the air holes is more than one, the air holes may be arranged in a line in a ring shape on the outer periphery of the tipping paper member 7. The multiple air holes may be arranged at approximately regular intervals. By providing the air holes, air is taken into the filter segment 2 through the air holes during inhalation. By diluting the mainstream smoke with outside air from the ventilation holes, products can be designed to achieve the desired tar level.
使用者は、香味生成セグメント1の先端に着火して、フィルターセグメント2の吸口端を口でくわえて吸引することで、たばこの香味を楽しむことができる。本実施形態に係る燃焼型香味吸引器具8では、蔵置中において香味成分もしくは揮発性香料成分の収着が低減されているため、使用時に十分な量の香味成分もしくは揮発性香料成分が使用者へ供給される。A user can enjoy the flavor of tobacco by lighting the tip of the flavor generating segment 1 and inhaling by holding the mouth end of the filter segment 2 in the mouth. In the combustion type flavor inhalation device 8 according to this embodiment, the sorption of flavor components or volatile flavor components is reduced during storage, so that a sufficient amount of flavor components or volatile flavor components is supplied to the user when used.
本実施形態に係る燃焼型香味吸引器具は、本実施形態に係る香味生成セグメント及びフィルターセグメントに加えて、少なくとも一つ以上の他のセグメントをさらに有してもよい。他のセグメントとしては、例えばアセテートやポリ乳酸等の化学合成繊維が充填されたフィルターセグメント、アセテートやポリ乳酸等のフィルムが充填されたセグメント、または、中空構造を有するセグメント等が挙げられる。また、フィルターセグメントの中に活性炭、シリカゲル、またはゼオライトのような吸着剤を含ませることもできるし、液体香料、固体香料または担持体に担持した香料を含ませることもできる。液体香料をゼラチン、多糖類または樹脂等のシェルで包みコアシェル構造とした香料カプセルをセグメントに含ませることもできる。例えば、図2に示される燃焼型香味吸引器具11は、香味生成セグメント1と、フィルターセグメント2との間に、他のフィルターセグメント9を有する。フィルターセグメント2と他のフィルターセグメント9とはフィルタープラグラッパー10により接続されている。他のフィルターセグメント9には本実施形態に係るフィルターセグメント2とは異なる機能を持たせることができるため、フィルターに対して複数の機能を付与することができる。The combustion type flavor inhalation device according to the present embodiment may further have at least one or more other segments in addition to the flavor generating segment and the filter segment according to the present embodiment. Examples of the other segments include a filter segment filled with chemically synthetic fibers such as acetate or polylactic acid, a segment filled with a film such as acetate or polylactic acid, or a segment having a hollow structure. The filter segment may also contain an adsorbent such as activated carbon, silica gel, or zeolite, or may contain a liquid flavor, a solid flavor, or a flavor supported on a carrier. The segment may also contain a flavor capsule having a core-shell structure in which a liquid flavor is wrapped in a shell such as gelatin, polysaccharide, or resin. For example, the combustion type flavor inhalation device 11 shown in FIG. 2 has another filter segment 9 between the flavor generating segment 1 and the filter segment 2. The filter segment 2 and the other filter segment 9 are connected by a filter plug wrapper 10. The other filter segment 9 can have a function different from that of the filter segment 2 according to the present embodiment, so that the filter can be given multiple functions.
(非燃焼加熱型香味吸引器具)
本実施形態に係る非燃焼加熱型香味吸引器具の一例を図3に示す。図3に示される非燃焼加熱型香味吸引器具12は、本実施形態に係る香味生成セグメント1と、マウスピースセグメント13とを備える。マウスピースセグメント13は、冷却セグメント14と、センターホールセグメント15と、本実施形態に係るフィルターセグメント2とを備える。吸引時、香味生成セグメント1が加熱され、香味生成セグメント1に含まれる香味成分、エアロゾル生成基材及び水が気化し、吸引によりこれらはマウスピースセグメント13へ移行し、フィルターセグメント2の端部より吸引が行われる。
(Non-combustion heating type flavor inhalation device)
An example of a non-combustion heating type flavor inhalation device according to this embodiment is shown in Fig. 3. The non-combustion heating type flavor inhalation device 12 shown in Fig. 3 comprises a flavor generating segment 1 according to this embodiment and a mouthpiece segment 13. The mouthpiece segment 13 comprises a cooling segment 14, a center hole segment 15, and a filter segment 2 according to this embodiment. When inhaling, the flavor generating segment 1 is heated, and the flavor components, aerosol generating base material, and water contained in the flavor generating segment 1 are vaporized, and these are transferred to the mouthpiece segment 13 by inhalation, and inhalation is performed from the end of the filter segment 2.
冷却セグメント14は筒状部材16で構成される。筒状部材16は例えば厚紙を円筒状に加工した紙管であることができる。筒状部材16及び後述するマウスピースライニングペーパー21には、両者を貫通する穿孔17が設けられている。穿孔17の存在により、吸引時に外気が冷却セグメント14内に導入される。これにより、香味生成セグメント1が加熱されることで生成したエアロゾル気化成分が外気と接触し、その温度が低下するため液化し、エアロゾルが形成される。穿孔17の径(差し渡し長さ)は特に限定されないが、例えば0.5~1.5mmであることができる。穿孔17の数は特に限定されず、1つでも2つ以上でもよい。例えば穿孔17は冷却セグメント14の周上に複数設けられていてもよい。The cooling segment 14 is composed of a cylindrical member 16. The cylindrical member 16 can be, for example, a paper tube made by processing cardboard into a cylindrical shape. The cylindrical member 16 and the mouthpiece lining paper 21 described later are provided with perforations 17 penetrating both. Due to the presence of the perforations 17, outside air is introduced into the cooling segment 14 during inhalation. As a result, the aerosol vaporized components generated by heating the flavor generating segment 1 come into contact with the outside air, and as their temperature drops, they are liquefied to form an aerosol. The diameter (distance across) of the perforations 17 is not particularly limited, but can be, for example, 0.5 to 1.5 mm. The number of perforations 17 is not particularly limited, and may be one or more than two. For example, a plurality of perforations 17 may be provided on the circumference of the cooling segment 14.
センターホールセグメント15は、中空部を有する充填層18と、充填層18を覆うインナープラグラッパー19とで構成される。センターホールセグメント15は、マウスピースセグメント13の強度を高める機能を有する。充填層18は、例えば酢酸セルロース繊維が高密度で充填され、トリアセチンを含む可塑剤が酢酸セルロース質量に対して6~20質量%添加されて硬化された、内径φ5.0~φ1.0mmのロッドであることができる。充填層18は繊維の充填密度が高いため、吸引時は空気やエアロゾルは中空部のみを流れることになり、充填層18内はほとんど流れない。フィルターセグメント2でのエアロゾル成分の濾過による減少を少なくしたいときに、フィルターセグメント2の長さを短くし、センターホールセグメント15で置き換えることは、エアロゾル成分のデリバリー量を増大させるために有効である。センターホールセグメント15内部の充填層18は繊維充填層であることから、使用時の外側からの触り心地は良好である。なお、図4(a)に示されるように、センターホールセグメントを設けずに、代わりにフィルターセグメント2を延長してもよい。また、図4(b)に示されるように、センターホールセグメントを設けずに、代わりに冷却セグメント14を延長してもよい。 The center hole segment 15 is composed of a filling layer 18 having a hollow portion and an inner plug wrapper 19 that covers the filling layer 18. The center hole segment 15 has the function of increasing the strength of the mouthpiece segment 13. The filling layer 18 can be, for example, a rod with an inner diameter of φ5.0 to φ1.0 mm, in which cellulose acetate fibers are densely packed and a plasticizer containing triacetin is added at 6 to 20% by mass relative to the mass of cellulose acetate and hardened. Since the filling layer 18 has a high fiber packing density, air and aerosol flow only through the hollow portion during inhalation and hardly flow inside the filling layer 18. When it is desired to reduce the loss of aerosol components due to filtration in the filter segment 2, shortening the length of the filter segment 2 and replacing it with the center hole segment 15 is effective in increasing the delivery amount of the aerosol components. Since the filling layer 18 inside the center hole segment 15 is a fiber packed layer, it feels good to the touch from the outside during use. As shown in FIG. 4(a), the filter segment 2 may be extended instead of providing a center hole segment. Also, as shown in FIG. 4(b), the center hole segment may be omitted and instead the cooling segment 14 may be extended.
センターホールセグメント15と、フィルターセグメント2とはアウタープラグラッパー20で接続されている。アウタープラグラッパー20は、例えば円筒状の紙であることができる。また、香味生成セグメント1と、冷却セグメント14と、接続済みのセンターホールセグメント15及びフィルターセグメント2とは、マウスピースライニングペーパー21により接続されている。これらの接続は、例えばマウスピースライニングペーパー21の内側面に前述した親水性ポリマーを基材とする水溶性糊を塗り、前記3つのセグメントを入れて巻くことで接続することができる。The center hole segment 15 and the filter segment 2 are connected by an outer plug wrapper 20. The outer plug wrapper 20 can be, for example, a cylindrical paper. The flavor generating segment 1, the cooling segment 14, and the connected center hole segment 15 and filter segment 2 are connected by a mouthpiece lining paper 21. These connections can be made, for example, by applying a water-soluble glue based on the hydrophilic polymer described above to the inner surface of the mouthpiece lining paper 21, and then inserting and rolling the three segments.
本実施形態に係る非燃焼加熱型香味吸引器具の軸方向、すなわち図3における水平方向の長さは特に限定されないが、40~90mmであることが好ましく、50~75mmであることがより好ましく、50~60mmであることがさらに好ましい。また、非燃焼加熱型香味吸引器具の周の長さは16~25mmであることが好ましく、20~24mmであることがより好ましく、21~23mmであることがさらに好ましい。例えば、香味生成セグメント1の長さは20mm、冷却セグメント14の長さは20mm、センターホールセグメント15の長さは8mm、フィルターセグメント2の長さは7mmである態様を挙げることができる。これら個々のセグメント長さは、製造適性、要求品質等に応じて、適宜変更できる。本実施形態に係る非燃焼加熱型香味吸引器具では、蔵置中において揮発性香料成分の収着が低減されているため、使用時に十分な量の揮発性香料成分が使用者へ供給される。 The axial length of the non-combustion heating type flavor inhalation device according to this embodiment, i.e., the horizontal length in FIG. 3, is not particularly limited, but is preferably 40 to 90 mm, more preferably 50 to 75 mm, and even more preferably 50 to 60 mm. The circumferential length of the non-combustion heating type flavor inhalation device is preferably 16 to 25 mm, more preferably 20 to 24 mm, and even more preferably 21 to 23 mm. For example, the length of the flavor generating segment 1 may be 20 mm, the length of the cooling segment 14 may be 20 mm, the length of the center hole segment 15 may be 8 mm, and the length of the filter segment 2 may be 7 mm. These individual segment lengths may be appropriately changed depending on the manufacturing suitability, the required quality, and the like. In the non-combustion heating type flavor inhalation device according to this embodiment, the sorption of the volatile flavor component is reduced during storage, so that a sufficient amount of the volatile flavor component is supplied to the user when used.
[香味吸引システム]
本実施形態に係る香味吸引システムは、本実施形態に係る非燃焼加熱型香味吸引器具と、該非燃焼加熱型香味吸引器具を加熱する加熱装置と、を備えることが好ましい。本実施形態に係る香味吸引システムは、本実施形態に係る非燃焼加熱型香味吸引器具及び前記加熱装置以外の他の構成を有していてもよい。
[Flavor Inhalation System]
The flavor inhalation system according to the present embodiment preferably includes a non-combustion heating type flavor inhalation device according to the present embodiment and a heating device for heating the non-combustion heating type flavor inhalation device. The flavor inhalation system according to the present embodiment may have a configuration other than the non-combustion heating type flavor inhalation device according to the present embodiment and the heating device.
本実施形態に係る香味吸引システムの一例を図5に示す。図5に示される香味吸引システムは、本実施形態に係る非燃焼加熱型香味吸引器具12と、非燃焼加熱型香味吸引器具12の香味生成セグメントを外側から加熱する加熱装置22とを備える。図5(a)は非燃焼加熱型香味吸引器具12を加熱装置22に挿入する前の状態を示し、図5(b)は非燃焼加熱型香味吸引器具12を加熱装置22に挿入して加熱する状態を示す。図5に示される加熱装置22は、ボディ23と、ヒーター24と、金属管25と、電池ユニット26と、制御ユニット27とを備える。ボディ23は筒状の凹部28を有し、凹部28の内側側面であって、凹部28に挿入される非燃焼加熱型香味吸引器具12の香味生成セグメントと対応する位置に、ヒーター24及び金属管25が配置されている。ヒーター24は電気抵抗によるヒーターであることができ、温度制御を行う制御ユニット27からの指示により電池ユニット26より電力が供給され、ヒーター24の加熱が行われる。ヒーター24から発せられた熱は、熱伝導度の高い金属管25を通じて非燃焼加熱型香味吸引器具12の香味生成セグメントへ伝えられる。An example of the flavor inhalation system according to the present embodiment is shown in FIG. 5. The flavor inhalation system shown in FIG. 5 includes the non-combustion heating type flavor inhalation tool 12 according to the present embodiment and a heating device 22 that heats the flavor generation segment of the non-combustion heating type flavor inhalation tool 12 from the outside. FIG. 5(a) shows the state before the non-combustion heating type flavor inhalation tool 12 is inserted into the heating device 22, and FIG. 5(b) shows the state in which the non-combustion heating type flavor inhalation tool 12 is inserted into the heating device 22 and heated. The heating device 22 shown in FIG. 5 includes a body 23, a heater 24, a metal tube 25, a battery unit 26, and a control unit 27. The body 23 has a cylindrical recess 28, and the heater 24 and the metal tube 25 are arranged on the inner side of the recess 28 at a position corresponding to the flavor generation segment of the non-combustion heating type flavor inhalation tool 12 inserted into the recess 28. The heater 24 can be a heater using electric resistance, and is heated by being supplied with power from a battery unit 26 in response to an instruction from a control unit 27 that controls temperature. The heat generated by the heater 24 is transferred to the flavor generating segment of the non-combustion heating type flavor inhalation device 12 through a metal tube 25 having high thermal conductivity.
図5(b)においては模式的に図示しているため、非燃焼加熱型香味吸引器具12の外周と金属管25の内周との間に隙間があるが、実際は、熱を効率的に伝達する目的で非燃焼加熱型香味吸引器具12の外周と金属管25の内周との間に隙間は無い方が望ましい。また、加熱装置22は非燃焼加熱型香味吸引器具12の香味生成セグメントを外側から加熱するが、内側から加熱するものであってもよい。内側から加熱するものである場合、金属管25を用いずに、剛直性のある板状、ブレード状、柱状ヒーターを用いることが好ましい。係るヒーターとしては、例えばセラミック基材の上にモリブデンやタングステン等を付与したセラミックヒーターが挙げられる。5(b) is a schematic illustration, so there is a gap between the outer periphery of the non-combustion heating type flavor inhalation device 12 and the inner periphery of the metal tube 25, but in reality, it is preferable that there is no gap between the outer periphery of the non-combustion heating type flavor inhalation device 12 and the inner periphery of the metal tube 25 for the purpose of efficient heat transfer. In addition, the heating device 22 heats the flavor generation segment of the non-combustion heating type flavor inhalation device 12 from the outside, but it may also heat from the inside. If it heats from the inside, it is preferable to use a rigid plate-shaped, blade-shaped, or columnar heater without using the metal tube 25. Examples of such heaters include ceramic heaters in which molybdenum, tungsten, or the like is applied to a ceramic substrate.
加熱装置による加熱温度は、160℃以上であることが好ましく、160℃以上400℃以下であることがより好ましく、200℃以上350℃以下であることがさらに好ましい。非燃焼加熱型香味吸引器具の加熱により、フィルターセグメントが160℃以上となることがあるが、本実施形態ではフィルターセグメントの不織布を構成する繊維が植物パルプを含むため、160℃以上の温度に十分に耐えることができる。なお、通常のアセテートフィルターを構成する酢酸セルロース繊維は、ガラス転移温度が160~180℃であるため、加熱により分子構造が乱れる場合があり、耐熱性が低い。なお、加熱温度とは加熱装置のヒーターの温度を示す。The heating temperature by the heating device is preferably 160°C or higher, more preferably 160°C to 400°C, and even more preferably 200°C to 350°C. When heated by a non-combustion heating type flavor inhalation device, the filter segment may reach 160°C or higher, but in this embodiment, the fibers constituting the nonwoven fabric of the filter segment contain plant pulp, so they can fully withstand temperatures of 160°C or higher. Note that the cellulose acetate fibers constituting a typical acetate filter have a glass transition temperature of 160 to 180°C, so that their molecular structure may be disrupted by heating, and their heat resistance is low. Note that the heating temperature refers to the temperature of the heater in the heating device.
以下、本発明を実施例により詳細に説明するが、本発明はこれらの実施例に限定されない。The present invention will now be described in more detail with reference to examples, but the present invention is not limited to these examples.
[実施例1]
(フィルターセグメントの作製)
(1)不織布の製造
原料となる木材パルプを粗砕機および解繊機で単繊維化した後、ウエブ形成装置からパルプを無端金網の吸収面上に落下させ、ウエブを形成ししつ移送した。このウエブに水溶性バインダー(PVAと酢酸ビニルアクリルコポリマーとを質量比17:83で混合したもの)を水中に溶解させたものを噴霧し、乾燥し、さらに前記と同じバインダーを噴霧し乾燥して、幅240cmの不織布を得た。得られた不織布を巻取装置で巻き取りジャンボロールとした。ジャンボロールから不織布を繰り出して幅13cmにスリット加工し、巻き取った。原料となる木材パルプには、粗度が0.22mg/mである木材パルプ(Weyerhaueser社製 品名:NB416)を用いた。不織布の坪量は45g/m2、厚さは1.2mmであった。不織布100質量%中の水溶性バインダーの含有量は18質量%であった。
[Example 1]
(Preparation of Filter Segments)
(1) Production of nonwoven fabric After the raw material wood pulp was broken into single fibers using a coarse grinder and a fiberizer, the pulp was dropped from the web forming device onto the absorbent surface of an endless wire netting to form a web and transport it. A water-soluble binder (a mixture of PVA and vinyl acetate acrylic copolymer in a mass ratio of 17:83) dissolved in water was sprayed onto this web, dried, and then the same binder as above was sprayed and dried to obtain a nonwoven fabric with a width of 240 cm. The obtained nonwoven fabric was wound up into a jumbo roll by a winding device. The nonwoven fabric was unwound from the jumbo roll, slit to a width of 13 cm, and wound up. The raw material wood pulp used was wood pulp with a roughness of 0.22 mg/m (Weyerhauser, product name: NB416). The basis weight of the nonwoven fabric was 45 g/ m2 and the thickness was 1.2 mm. The content of the water-soluble binder in 100% by mass of the nonwoven fabric was 18% by mass.
(2)フィルターセグメントの製造
フィルターセグメントを、たばこ用フィルター製造装置を用いて製造した。すなわち、(1)に記載の方法で製造された不織布を、スリッターで4枚に切り裂き、4枚を重ねて切り口がS字状の円筒状に圧縮して成形した。次に、円筒状の不織布をラッパーで包み、ラップ部を糊付けした後に、所定の長さにカッターで切断して、フィルターセグメントを得た。ラッパー端部同士の接着、及びラッパーと不織布との接着にはポリ酢酸ビニルを用いた。不織布はスリット前の幅が13cmであり、これが等間隔で4枚にスリットされることで1枚の幅が32mmとなる。スリット時にわずかにロスが発生する。
(2) Manufacturing of filter segments Filter segments were manufactured using a cigarette filter manufacturing device. That is, the nonwoven fabric manufactured by the method described in (1) was cut into four pieces by a slitter, and the four pieces were stacked and compressed into a cylindrical shape with an S-shaped cut edge. Next, the cylindrical nonwoven fabric was wrapped in a wrapper, the wrapper was glued, and then cut to a predetermined length by a cutter to obtain a filter segment. Polyvinyl acetate was used to bond the wrapper ends together and to bond the wrapper and the nonwoven fabric. The nonwoven fabric had a width of 13 cm before slitting, and was slit into four pieces at equal intervals, resulting in a width of 32 mm for each piece. A small loss occurred during slitting.
(香味生成セグメントおよび香味吸引器具の作製)
前記フィルターセグメントを用いて、図1に示される燃焼型香味吸引器具を作製した。たばこ含有セグメントとしては、軸方向長さが57.0mm、円周が24.5mm、たばこ含有量が675mgのたばこ含有セグメントを用いた。たばこ含有セグメントの充填物は、たばこに加えて、揮発性香料成分としてのl-メンソールを4.6mg含む。充填物100質量%に対するl-メンソールの含有率は0.68質量%である。たばこ含有セグメントと、フィルターセグメントとを、長さ32.0mmのチップペーパー部材7により接続し、香味吸引器具を作製した。チップペーパー部材にはタール値調整用の通気孔は設けなかった。チップペーパー部材7の接着にはポリ酢酸ビニルエマルジョン糊を用いた。
(Preparation of Flavor-Generating Segment and Flavor-Inhaling Device)
The filter segment was used to prepare a combustion-type flavor inhalation device as shown in FIG. 1. The tobacco-containing segment used had an axial length of 57.0 mm, a circumference of 24.5 mm, and a tobacco content of 675 mg. The filling of the tobacco-containing segment contained 4.6 mg of l-menthol as a volatile flavor component in addition to tobacco. The content of l-menthol relative to 100% by mass of the filling was 0.68% by mass. The tobacco-containing segment and the filter segment were connected by a tipping paper member 7 having a length of 32.0 mm to prepare a flavor inhalation device. No vent holes for adjusting the tar value were provided in the tipping paper member. Polyvinyl acetate emulsion glue was used to adhere the tipping paper member 7.
(香味吸引器具の小箱包装)
作製した香味吸引器具20本を、内包紙であるアルミ張り合わせ紙で包み、縦22mm、横56mm、高さ89mmの紙製の小箱内に入れた。その後に、該小箱の外側をPP製フィルムで覆って密封した。
(Small box packaging for flavor inhalation devices)
The twenty flavor inhalation devices thus prepared were wrapped in an aluminum-laminated paper inner wrapping, and placed in a small paper box measuring 22 mm in length, 56 mm in width, and 89 mm in height. The outside of the small box was then covered with a PP film and sealed.
(蔵置によるフィルターセグメントへの移香評価)
前記小箱包装形態のまま、前記小箱を22℃環境下に一か月間置き、蔵置影響を評価した。蔵置開始時、すなわち香味吸引器具作製時(初期)と、蔵置一か月後のl-メンソール量の測定を行った。l-メンソール量の測定は下記手順で行った。
i)小箱を開封し、香味吸引器具20本を取り出した。
ii)香味生成セグメントとフィルターセグメントとをカッターで切断した。香味生成セグメントとフィルターセグメントとを別々に10mlのメタノールを入れたバイアル瓶に入れて、30分振とうさせた。この操作を香味吸引器具10本について行った。
iii)振とう後にバイアル瓶中のメタノールをガスクロマトグラフィー(アジレント製、検出器:FID)で測定し、各セグメントに含まれているl-メンソール量を測定した。
iv)香味生成セグメント10本分とフィルターセグメント10本分のデータをそれぞれ平均して、各セグメントに含まれるl-メンソール量とした。
結果を表1に示す。
(Evaluation of odor transfer to filter segments after storage)
The small box was left in the small box packaging form in an environment of 22°C for one month to evaluate the storage effect. The amount of l-menthol was measured at the start of storage, i.e., when the flavor inhalation device was produced (initial stage), and after one month of storage. The amount of l-menthol was measured according to the following procedure.
i) The small box was opened and 20 flavor inhalation devices were taken out.
ii) The flavor generating segment and the filter segment were cut with a cutter. The flavor generating segment and the filter segment were separately placed in a vial containing 10 ml of methanol and shaken for 30 minutes. This operation was performed for 10 flavor inhalation devices.
iii) After shaking, the methanol in the vial was measured by gas chromatography (manufactured by Agilent, detector: FID) to measure the amount of 1-menthol contained in each segment.
iv) The data for the 10 flavor generating segments and the 10 filter segments were each averaged to determine the amount of 1-menthol contained in each segment.
The results are shown in Table 1.
[実施例2]
フィルターセグメントの不織布の作製において、水溶性バインダーとしてPVAと酢酸ビニルアクリルコポリマーの混合物を用いる代わりに、PVAを単独で用いた以外は、実施例1と同様に香味吸引器具を作製し、評価した。結果を表1に示す。なお、前記水溶性バインダーのHSPはσD=19.30、σP=10.40、σH=26.50であった。
[Example 2]
A flavor inhaler was prepared and evaluated in the same manner as in Example 1, except that in the preparation of the nonwoven fabric for the filter segment, instead of using a mixture of PVA and vinyl acetate acrylic copolymer as the water-soluble binder, PVA alone was used. The results are shown in Table 1. The HSP of the water-soluble binder was σD=19.30, σP=10.40, and σH=26.50.
[比較例1]
フィルターセグメントとして、酢酸セルロース繊維束(ダイセル製、フィラメントデニール:3.5g/9000m、トータルデニール:35000g/9000mm)が、トリアセチン(酢酸セルロース繊維束の質量に対して6質量%添加)により結合されたアセテートフィルターを用いた以外は、実施例1と同様に香味吸引器具を作製し、評価した。結果を表1に示す。
[Comparative Example 1]
A flavor inhalation device was produced and evaluated in the same manner as in Example 1, except that an acetate filter in which a cellulose acetate fiber bundle (manufactured by Daicel, filament denier: 3.5 g/9000 m, total denier: 35000 g/9000 mm) was bonded with triacetin (added at 6% by mass relative to the mass of the cellulose acetate fiber bundle) was used as the filter segment. The results are shown in Table 1.
表1に示されるように、フィルターセグメントが、植物パルプを含む繊維が水溶性バインダーで結合して形成された不織布を備える実施例1及び2では、香味生成セグメントに含まれるメンソールのフィルターセグメントへの経時による移香が抑制された。したがって、実施例1及び2では、蔵置中における揮発性香料成分の収着が低減されることが確認された。一方、フィルターセグメントとしてアセテートフィルターを用いた比較例1では、蔵置中にメンソールがアセテートフィルターへ移香する割合が高く、蔵置中に揮発性香料成分が収着することが確認された。また、実際の使用では、実施例1の香味吸引器具は、実施例2の香味吸引器具よりも唾液によるフィルターの溶解が十分に抑制され、より好適に使用できることが確認された。
本発明は以下の実施態様を含む。
[1]筒状の第一のラッパーと、前記第一のラッパー内部に充填されたたばこを含む充填物と、を含む香味生成セグメントと、
筒状の第二のラッパーと、前記第二のラッパー内部に充填された不織布と、を含むフィルターセグメントと、
を含む香味吸引器具であって、
前記不織布が、植物パルプを含む繊維が水溶性バインダーで結合して形成されている、香味吸引器具。
[2]前記充填物が揮発性香料成分をさらに含む[1]に記載の香味吸引器具。
[3]前記水溶性バインダーが、デンプン、修飾デンプン、修飾セルロース、ポリビニルアルコール、ポリ酢酸ビニル、酢酸ビニルアクリルコポリマー、エチレン酢酸ビニルコポリマー、増粘多糖類、及びガム類からなる群から選択される少なくとも一種のバインダーである[1]又は[2]に記載の香味吸引器具。
[4]前記水溶性バインダーが、ポリビニルアルコール及び酢酸ビニルアクリルコポリマーの混合物である[3]に記載の香味吸引器具。
[5]前記ポリビニルアルコール及び前記酢酸ビニルアクリルコポリマーの合計100質量%に対する、前記ポリビニルアルコールの割合が17質量%以上100質量%未満である[4]に記載の香味吸引器具。
[6]前記ポリビニルアルコール及び前記酢酸ビニルアクリルコポリマーの合計100質量%に対する、前記ポリビニルアルコールの割合が17質量%以上40質量%未満である[5]に記載の香味吸引器具。
[7]前記水溶性バインダーの、ハンセンの溶解度パラメータ(HSP)が、σD=17.59~18.92、σP=4.91~9.18、σH=8.50~22.50である[1]から[6]のいずれかに記載の香味吸引器具。
[8]前記不織布100質量%中の前記水溶性バインダーの含有量が、10~25質量%である[1]から[7]のいずれかに記載の香味吸引器具。
[9]前記不織布の坪量が25~70g/m
2
である[1]から[8]のいずれかに記載の香味吸引器具。
[10]シート状の前記不織布が複数枚重ねられ、S字状形状に折りたたまれて前記第二のラッパー内部に充填されている[1]から[9]のいずれかに記載の香味吸引器具。
[11]前記第二のラッパーが、ポリビニルアルコール、ポリ酢酸ビニル、エチレン酢酸ビニルコポリマー、及びデンプンからなる群から選択される少なくとも一種の糊により前記不織布に接着されている[1]から[10]のいずれかに記載の香味吸引器具。
[12]ポリビニルアルコール、ポリ酢酸ビニル、エチレン酢酸ビニルコポリマー、及びデンプンからなる群から選択される少なくとも一種の糊により、前記第二のラッパーの一方の端部と、前記第二のラッパーの他方の端部とが接着され、前記第二のラッパーが筒状になっている[1]から[11]のいずれかに記載の香味吸引器具。
[13]前記揮発性香料成分が、メンソール、リモネン、cis-3-ヘキサノール、及びメントンからなる群から選択される少なくとも一種の成分である[2]に記載の香味吸引器具。
[14]前記揮発性香料成分が、前記充填物100質量%に対して0.1~10質量%添加されている[2]又は[13]に記載の香味吸引器具。
[15]燃焼型香味吸引器具である[1]から[14]のいずれかに記載の香味吸引器具。
[16]非燃焼加熱型香味吸引器具である[1]から[14]のいずれかに記載の香味吸引器具。
[17]前記香味生成セグメントがエアロゾル生成基材をさらに含む[16]に記載の香味吸引器具。
[18]前記エアロゾル生成基材がグリセリン又はプロピレングリコールである[17]に記載の香味吸引器具。
[19][16]から[18]のいずれかに記載の香味吸引器具と、
前記香味吸引器具を加熱する加熱装置と、
を備える香味吸引システム。
[20]前記加熱装置による加熱温度が160℃以上である[19]に記載の香味吸引システム。
As shown in Table 1, in Examples 1 and 2 in which the filter segment comprises a nonwoven fabric formed by binding fibers containing plant pulp with a water-soluble binder, the transfer of menthol contained in the flavor generating segment to the filter segment over time was suppressed. Thus, it was confirmed that the sorption of volatile flavor components during storage was reduced in Examples 1 and 2. On the other hand, in Comparative Example 1 in which an acetate filter was used as the filter segment, the rate at which menthol transferred to the acetate filter during storage was high, and it was confirmed that volatile flavor components were sorbed during storage. In addition, in actual use, it was confirmed that the flavor inhalation device of Example 1 was more sufficiently suppressed from dissolving the filter by saliva than the flavor inhalation device of Example 2, and could be used more suitably.
The present invention includes the following embodiments.
[1] A flavor generating segment including a cylindrical first wrapper and a filler including tobacco filled inside the first wrapper;
A filter segment including a cylindrical second wrapper and a nonwoven fabric filled inside the second wrapper;
A flavor inhalation device comprising:
The flavor inhalation device, wherein the nonwoven fabric is formed by binding fibers containing plant pulp with a water-soluble binder.
[2] The flavor inhaler according to [1], wherein the filling further contains a volatile flavor component.
[3] The flavor inhaler according to [1] or [2], wherein the water-soluble binder is at least one binder selected from the group consisting of starch, modified starch, modified cellulose, polyvinyl alcohol, polyvinyl acetate, vinyl acetate acrylic copolymer, ethylene vinyl acetate copolymer, thickening polysaccharides, and gums.
[4] The flavor inhalation device according to [3], wherein the water-soluble binder is a mixture of polyvinyl alcohol and vinyl acetate acrylic copolymer.
[5] The flavor inhalation device described in [4], wherein the ratio of the polyvinyl alcohol to the total of the polyvinyl alcohol and the vinyl acetate acrylic copolymer (100% by mass) is 17% by mass or more and less than 100% by mass.
[6] The flavor inhalation device described in [5], wherein the ratio of the polyvinyl alcohol to the total of the polyvinyl alcohol and the vinyl acetate acrylic copolymer (100% by mass) is 17% by mass or more and less than 40% by mass.
[7] The flavor inhaler according to any one of [1] to [6], wherein the water-soluble binder has a Hansen solubility parameter (HSP) of σD = 17.59 to 18.92, σP = 4.91 to 9.18, and σH = 8.50 to 22.50.
[8] The flavor inhaler according to any one of [1] to [7], wherein the content of the water-soluble binder in 100% by mass of the nonwoven fabric is 10 to 25% by mass.
[9] The flavor inhaler according to any one of [1] to [8], wherein the nonwoven fabric has a basis weight of 25 to 70 g/m2 .
[10] The flavor inhalation device according to any one of [1] to [9], wherein a plurality of sheets of the nonwoven fabric are stacked, folded into an S-shape, and filled inside the second wrapper.
[11] The flavor inhaler described in any one of [1] to [10], wherein the second wrapper is adhered to the nonwoven fabric by at least one glue selected from the group consisting of polyvinyl alcohol, polyvinyl acetate, ethylene-vinyl acetate copolymer, and starch.
[12] The flavor inhalation device according to any one of [1] to [11], wherein one end of the second wrapper and the other end of the second wrapper are bonded together with at least one glue selected from the group consisting of polyvinyl alcohol, polyvinyl acetate, ethylene-vinyl acetate copolymer, and starch, and the second wrapper is cylindrical.
[13] The flavor inhaler according to [2], wherein the volatile flavor component is at least one component selected from the group consisting of menthol, limonene, cis-3-hexanol, and menthone.
[14] The flavor inhaler according to [2] or [13], wherein the volatile flavor component is added in an amount of 0.1 to 10% by mass relative to 100% by mass of the filling.
[15] The flavor inhalation device according to any one of [1] to [14], which is a combustion type flavor inhalation device.
[16] The flavor inhalation device according to any one of [1] to [14], which is a non-combustion heating type flavor inhalation device.
[17] The flavor inhalation device according to [16], wherein the flavor generating segment further comprises an aerosol generating substrate.
[18] The flavor inhalation device described in [17], wherein the aerosol-generating base material is glycerin or propylene glycol.
[19] A flavor inhalation device according to any one of [16] to [18],
A heating device for heating the flavor inhalation device;
A flavor suction system comprising:
[20] The flavor inhalation system described in [19], wherein the heating temperature by the heating device is 160°C or higher.
1 香味生成セグメント
2 フィルターセグメント
3 充填物
4 第一のラッパー
5 不織布
6 第二のラッパー
1 Flavor generating segment 2 Filter segment 3 Filler 4 First wrapper 5 Nonwoven fabric 6 Second wrapper
Claims (22)
筒状の第二のラッパーと、前記第二のラッパー内部に充填された不織布と、を含むフィルターセグメントと、
を含む香味吸引器具であって、
前記不織布が、植物パルプからなる繊維が水溶性バインダーで結合して形成されており、
前記第二のラッパーは、親水性ポリマーを基材とする水溶性糊により前記不織布に接着され、前記第二のラッパーと前記不織布とが固定されている、香味吸引器具。 a flavor generating segment including a cylindrical first wrapper and a filler including tobacco filled inside the first wrapper;
A filter segment including a cylindrical second wrapper and a nonwoven fabric filled inside the second wrapper;
A flavor inhalation device comprising:
The nonwoven fabric is formed by bonding fibers made of vegetable pulp with a water-soluble binder,
The flavor inhalation device, wherein the second wrapper is adhered to the nonwoven fabric by a water-soluble glue based on a hydrophilic polymer , thereby fixing the second wrapper and the nonwoven fabric together .
筒状の第二のラッパーと、前記第二のラッパー内部に充填された不織布と、を含むフィルターセグメントと、A filter segment including a cylindrical second wrapper and a nonwoven fabric filled inside the second wrapper;
を含む香味吸引器具であって、A flavor inhalation device comprising:
前記不織布が、植物パルプを含む繊維が水溶性バインダーで結合して形成されており、The nonwoven fabric is formed by binding fibers containing plant pulp with a water-soluble binder,
前記水溶性バインダーが、ポリビニルアルコール及び酢酸ビニルアクリルコポリマーの混合物であり、the water-soluble binder is a mixture of polyvinyl alcohol and vinyl acetate acrylic copolymer;
前記ポリビニルアルコール及び前記酢酸ビニルアクリルコポリマーの合計100質量%に対する、前記ポリビニルアルコールの割合が17質量%以上100質量%未満である、香味吸引器具。A flavor inhalation device, wherein a ratio of the polyvinyl alcohol to a total of 100% by mass of the polyvinyl alcohol and the vinyl acetate acrylic copolymer is 17% by mass or more and less than 100% by mass.
前記香味吸引器具を加熱する加熱装置と、
を備える香味吸引システム。 A flavor inhalation device according to any one of claims 17 to 20 ,
A heating device for heating the flavor inhalation device;
A flavor suction system comprising:
The flavor inhalation system according to claim 21 , wherein the heating temperature by the heating device is 160°C or higher.
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- 2020-10-20 EP EP20958625.4A patent/EP4233577A4/en active Pending
- 2020-10-20 JP JP2022556855A patent/JP7526805B2/en active Active
- 2020-10-20 WO PCT/JP2020/039394 patent/WO2022085072A1/en unknown
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2021
- 2021-03-26 TW TW110111144A patent/TW202215988A/en unknown
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JP2015507937A (en) | 2012-02-23 | 2015-03-16 | エッセントラ フィルター プロダクツ ディベロップメント カンパニープライベート リミティド | Cigarette smoke filter |
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JP2020114206A (en) | 2018-12-20 | 2020-07-30 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Aerosol-generating article with light hollow segment |
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Also Published As
Publication number | Publication date |
---|---|
EP4233577A4 (en) | 2024-09-11 |
WO2022085072A1 (en) | 2022-04-28 |
JPWO2022085072A1 (en) | 2022-04-28 |
EP4233577A1 (en) | 2023-08-30 |
TW202215988A (en) | 2022-05-01 |
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