JP7489861B2 - Soup for frozen food, its manufacturing method, and frozen food using said soup for frozen food - Google Patents

Soup for frozen food, its manufacturing method, and frozen food using said soup for frozen food Download PDF

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JP7489861B2
JP7489861B2 JP2020137912A JP2020137912A JP7489861B2 JP 7489861 B2 JP7489861 B2 JP 7489861B2 JP 2020137912 A JP2020137912 A JP 2020137912A JP 2020137912 A JP2020137912 A JP 2020137912A JP 7489861 B2 JP7489861 B2 JP 7489861B2
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soup
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frozen food
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明日香 大関
森 藤山
武志 宮本
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Nissin Foods Holdings Co Ltd
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Description

本発明は、冷凍食品用スープ及びその製造方法並びに該冷凍食品用スープを用いた冷凍食品に関する。 The present invention relates to soup for frozen foods, a method for producing the same, and frozen foods using the soup for frozen foods.

近年、電子レンジを用いて簡単に調理できる冷凍食品が多数上市されており、スープやソースを使用するものとしては、冷凍うどんや冷凍ラーメン、冷凍パスタなどの冷凍食品が挙げられる。この内、冷凍パスタは、ソースの添加量が少なく、ソースの色が麺に色移りしても問題が少ないため、主にソースが麺に直充填されており、電子レンジ調理のみで喫食できる。それに対し、冷凍うどんや冷凍ラーメンは、主に濃縮スープが別添されており、麺や具材を電子レンジ調理した後、予め別添スープを熱湯で溶かして用意したスープに麺や具材を入れて調理するか、麺や具材を鍋炊きで調理した後、別添スープを添加する方法が一般的である。 In recent years, many frozen foods that can be easily cooked in a microwave oven have been released onto the market, and examples of frozen foods that use soup or sauce include frozen udon, frozen ramen, and frozen pasta. Of these, frozen pasta mainly contains sauce directly in the noodles, as only a small amount of sauce is added and there are few problems if the color of the sauce transfers to the noodles, and it can be eaten by cooking only in a microwave. In contrast, frozen udon and frozen ramen mainly contain concentrated soup separately, and the general method is to cook the noodles and ingredients in a microwave oven, and then add the noodles and ingredients to the soup prepared in advance by dissolving the soup separately in hot water, or to cook the noodles and ingredients in a pot and then add the soup separately provided.

近年、調理方法の簡便化だけでなく、環境面からも別添スープの包材を減らし、スープを直充填することが試みられている。冷凍うどんや冷凍ラーメンなどの冷凍食品は、鍋炊き調理する場合は、濃縮スープではなくストレートスープごと麺と凍結することが可能であるが、電子レンジ調理する場合は、ストレートスープごと麺と凍結すると解凍に時間がかかりすぎる問題がある。また、濃縮スープを麺に直充填すると製造中や保存中、電子レンジなどの調理中に主食材である麺にスープの色が移る問題がある。 In recent years, attempts have been made to reduce the amount of packaging used for soup separately, not only to simplify cooking methods but also from an environmental perspective, and to fill the soup directly instead. When cooking in a pot, frozen foods such as frozen udon and ramen can be frozen with the noodles in straight soup rather than concentrated soup, but when cooking in a microwave, freezing the noodles in straight soup can take too long to thaw. In addition, when concentrated soup is directly filled into the noodles, there is the problem that the color of the soup can transfer to the noodles, the main ingredient, during production, storage, and cooking in a microwave oven, etc.

これらの問題に対する方法として、特許文献1の方法が開示されている。特許文献1には、容器内に、調味液の上に主食の順に配置され、該調味液の70℃における粘度がC型粘度計で1000~8000cPであり、調味液と主食が全面でなく一部で接触して凍結されている冷凍食品が記載されており、調味液から主食である麺や米飯への水分移行を少なくし、喫食時の手間を省き、包材コストを減らすことができる旨が記載されている。 As a method to solve these problems, the method disclosed in Patent Document 1 is described. Patent Document 1 describes a frozen food in which the seasoning liquid is placed on top of the staple food in a container, the viscosity of the seasoning liquid at 70°C being 1000-8000 cP measured with a C-type viscometer, and the seasoning liquid and the staple food are frozen in contact with each other only partially rather than entirely, and it is described that this reduces the transfer of moisture from the seasoning liquid to the staple food (noodles or rice), saves the effort of eating, and reduces packaging costs.

また、スープを二層とする技術については、特許文献2~4の技術が知られている。特許文献2には、解凍・加熱調理を電子レンジ等で行うのに適した冷凍調味液塊並びに調味液付き冷凍食品及びその製造方法として、凍結させてなる主食材塊の上に、凍結させてなる第一成分を含む第一層と凍結させてなる第二成分を含む第二層とが積層された冷凍調味液塊が配置されてなる調味液付き冷凍食品であって、前記冷凍調味液塊は、第二層を下にして配置され、さらに、60℃における流動性が、第二成分よりも第一成分の方が低く、平面視において前記冷凍調味液塊の全外周が、前記主食材塊の外周より内に収まるように配置され、前記冷凍調味液塊の底部が前記主食材塊に埋没しているとともに、前記冷凍調味液塊の少なくとも第二層の一部を含む上部が前記主食材塊の周縁上面より突出していることを特徴とする調味液付き冷凍食品が記載されている。しかしながら、二層は積層状態であって、本件発明のような内側の内層スープを外側の外層スープが包含する構造ではなく、また、流動性の高い第二層が主食材塊と接触する必要があり、主食材に直充填できず、スープを事前に凍結して充填する必要がある。 Also, the techniques of forming a two-layer soup are known from Patent Documents 2 to 4. Patent Document 2 describes a frozen seasoning liquid block and a frozen food with seasoning liquid suitable for thawing and cooking in a microwave oven or the like, and a method for producing the same, which is a frozen food with seasoning liquid comprising a frozen seasoning liquid block having a first layer containing a frozen first component and a second layer containing a frozen second component stacked on top of a frozen main ingredient block, the frozen seasoning liquid block being placed with the second layer underneath, the first component having a lower fluidity at 60°C than the second component, the frozen seasoning liquid block being placed such that the entire outer periphery of the frozen seasoning liquid block is contained within the outer periphery of the main ingredient block in a plan view, the bottom of the frozen seasoning liquid block being embedded in the main ingredient block, and the upper part of the frozen seasoning liquid block including at least a part of the second layer protruding from the peripheral upper surface of the main ingredient block. However, the two layers are laminated, and the structure of the present invention is not one in which the inner soup layer is enclosed by the outer soup layer, and the second layer, which has high fluidity, needs to come into contact with the main ingredient mass, so the soup cannot be directly poured into the main ingredient and must be frozen beforehand before being poured.

特許文献3には、ソースと茹麺を一緒にして包装してもソースから茹麺への水分移行が抑制された包装冷凍麺類として、ブリックス度が一番高い冷凍ソース層を表層として、ブリックス度の異なる冷凍ソース層を複数層重層して構成された冷凍ソースのブリックス度の一番高い冷凍ソース層面と、この冷凍ソースとは別に凍結して得られた冷凍麺塊面とが直接接触する状態で包装されていることを特徴とする、包装冷凍麺類が記載されている。しかしながら、ブリックスが高いスープは、凝固点効果によって、運搬時や冷凍保存時に溶解しやすく、色素などが含まれている場合には容易に麺に色移りが起きやすい。また、特許文献3に記載された技術は、冷凍麺とソースを別々に凍結する必要があり、直充填できず、ソースの上に冷凍麺塊を置く必要がある。 Patent Document 3 describes packaged frozen noodles in which moisture transfer from the sauce to the boiled noodles is suppressed even when the sauce and boiled noodles are packaged together, and which are characterized in that the frozen sauce layer with the highest Brix degree of the frozen sauce, which is composed of multiple layers of frozen sauce layers with different Brix degrees, with the frozen sauce layer with the highest Brix degree as the outer layer, is in direct contact with the frozen noodle block surface obtained by freezing the frozen sauce separately. However, soup with a high Brix is easily dissolved during transportation or frozen storage due to the freezing point effect, and if it contains colorants, color transfer to the noodles is likely to occur. Furthermore, the technology described in Patent Document 3 requires the frozen noodles and sauce to be frozen separately, and direct filling is not possible, so the frozen noodle block must be placed on top of the sauce.

特許文献4には、保存性が高く、かつ固形状態のまま常温保存することができるゲル状ソースとして、ゲル状ソースであって、ゲル状の第一ソースと、これに被覆される第二ソースとを含み、該第一ソースが、pH7.0以下で、Awが0.80より高く0.90以下かつ該第二ソースのAwよりも高く、該第二ソースが、pH3.5~7.0で、Awが0.80以上0.86未満である、ゲル状ソースが記載されている。しかしながら、第一ソースを常温でゲル化する必要があり、また、加熱調理により溶解し、粘度の低いゾルとなるため、加熱調理時に麺に色移りしたり、麺に水分移行したりして食感が不均質となる可能性がある。 Patent Document 4 describes a gelled sauce that has high storage stability and can be stored in a solid state at room temperature, the gelled sauce comprising a first gelled sauce and a second sauce coated thereon, the first sauce having a pH of 7.0 or less and an Aw of more than 0.80 and not more than 0.90 and higher than the Aw of the second sauce, and the second sauce having a pH of 3.5 to 7.0 and an Aw of 0.80 or more and less than 0.86. However, the first sauce needs to be gelled at room temperature, and it dissolves when cooked with heat to become a low-viscosity sol, so there is a possibility that color transfer to the noodles or moisture transfer to the noodles during cooking, resulting in an uneven texture.

特許第4654772号公報Patent No. 4654772 特許第4197671号公報Patent No. 4197671 特許第4091535号公報Patent No. 4091535 特開2019-205357号公報JP 2019-205357 A

本発明は、濃縮スープであっても冷凍食品の主食材に直充填でき、包材が削減でき、簡便な調理が可能な冷凍食品用スープ及び該冷凍食品用スープを含む冷凍食品を提供することを目的とする。また、醤油ラーメンのような有色の濃縮スープを冷凍食品の主食材に直充填する場合であっても、冷凍保存時や電子レンジなどの調理時に食品へのスープの色移りが少ない冷凍食品用スープ及び該冷凍食品用スープを含む冷凍食品を提供することを目的とする。 The present invention aims to provide a soup for frozen foods that can be directly packed into the main ingredient of a frozen food even if it is a concentrated soup, reducing packaging materials and allowing for simple cooking, and a frozen food containing said soup for frozen foods. In addition, the present invention aims to provide a soup for frozen foods that causes little color transfer to the food during freezing or cooking in a microwave oven, even when a colored concentrated soup such as soy sauce ramen is directly packed into the main ingredient of the frozen food, and a frozen food containing said soup for frozen foods.

発明者は、醤油ラーメンのような有色スープを有する冷凍食品において、主食材である麺に濃縮スープを直充填し、包材を削減し、調理を簡便化できる方法を検討したが、通常の濃縮スープを麺に直充填しただけでは、濃縮スープが麺を凍結するための冷凍用容器の底に溜まり、冷凍保存中や電子レンジ調理時に麺線にスープの色が移り、見た目が悪く、また、電子レンジ調理時に濃縮スープが焦げるなどの課題があった。そこで鋭意研究した結果、濃縮スープであっても主食材に直充填でき、冷凍保存時や調理時に主食材への色移りを抑制できる冷凍食品用スープを見出し本発明に至った。 The inventors have investigated a method for filling noodles, the main ingredient, with concentrated soup directly in frozen foods with colored soup such as soy sauce ramen, to reduce packaging materials and simplify cooking. However, simply filling noodles directly with regular concentrated soup results in the concentrated soup pooling at the bottom of the freezer container used to freeze the noodles, and the color of the soup transfers to the noodle strings during freezing or cooking in a microwave, making for a poor appearance. In addition, the concentrated soup burns when cooking in a microwave. As a result of extensive research, the inventors have discovered a soup for frozen foods that can be filled directly into the main ingredient, even if it is concentrated soup, and that prevents color transfer to the main ingredient during freezing or cooking, which led to the present invention.

すなわち、二層構造を有する冷凍食品用スープであって、前記二層構造は、内側の内層スープを、外側の外層スープが包含する構造であり、充填時の前記外層スープの粘度が270Pa・s以上であり、60℃の前記外層スープの粘度が250Pa・s以上であることを特徴とする冷凍食品用スープである。 That is, it is a soup for frozen foods that has a two-layer structure, in which an inner layer soup is enclosed by an outer layer soup, and the viscosity of the outer layer soup when filled is 270 Pa·s or more, and the viscosity of the outer layer soup at 60°C is 250 Pa·s or more.

また、外層スープが、ゼラチン、澱粉または増粘多糖類の少なくとも何れか一つを含むことが好ましい。 It is also preferable that the outer layer soup contains at least one of gelatin, starch, or thickening polysaccharides.

また、外層スープは少なくとも澱粉を含み、澱粉の種類としては、リン酸架橋澱粉、ヒドロキシプロピルリン酸架橋澱粉またはアセチル化リン酸架橋澱粉の少なくとも何れか一つを含むことが好ましい。 In addition, the outer layer soup contains at least starch, and the type of starch preferably contains at least one of phosphate cross-linked starch, hydroxypropyl phosphate cross-linked starch, or acetylated phosphate cross-linked starch.

また、冷凍食品用スープ中の外層スープの重量は、内層スープの重量の2倍以上であることが好ましい。 In addition, it is preferable that the weight of the outer layer soup in the frozen food soup is at least twice the weight of the inner layer soup.

また、内層スープが外層スープよりも主食材に色移りする色素成分多く含むことが好ましい。 It is also preferable that the inner soup layer contains more pigment components that will transfer color to the main ingredient than the outer soup layer.

また、冷凍食品用スープは、冷凍食品に直充填されることが好ましい。 Frozen food soup is preferably filled directly into the frozen food.

また、本発明に係る二層構造を有する冷凍食品用スープは、冷凍食品に使用され、特に冷凍食品としては冷凍麺類に使用されることが好ましい。 The soup for frozen foods having a two-layer structure according to the present invention is preferably used in frozen foods, and more preferably in frozen noodles.

また、本発明に係る二重構造を有する冷凍食品スープを冷凍食品に使用する場合、冷凍食品中に耐熱性アミラーゼを含むことが好ましい。 When the frozen food soup having a double structure according to the present invention is used in a frozen food, it is preferable that the frozen food contains a heat-resistant amylase.

また、本発明に係る二重構造を有する冷凍食品スープの製造方法としては、外層スープの充填時の粘度が270Pa・s以上であり、60℃の粘度が250Pa・s以上であり、二液充填ノズルを用いて製造することが好ましい。 In addition, in the method for producing the frozen soup food having a double structure according to the present invention, it is preferable that the viscosity of the outer layer soup when filled is 270 Pa·s or more, and the viscosity at 60°C is 250 Pa·s or more, and that the soup is produced using a two-liquid filling nozzle.

本発明により、食品に直接濃縮スープを直充填でき、包材が削減でき、簡便な調理が可能な冷凍食品用スープ及び該冷凍食品用スープを含む冷凍食品を提供することができる。また、醤油ラーメンのような有色の濃縮スープを冷凍食品に直充填する場合であっても、冷凍保存時や電子レンジなどの調理時に食品へのスープの色移りが少ない冷凍食品用スープ及び該冷凍食品用スープを含む冷凍食品を提供することができる。 The present invention makes it possible to provide a soup for frozen foods that allows concentrated soup to be directly packed into food, reducing packaging materials and enabling simple cooking, and a frozen food that contains the soup for frozen foods. Furthermore, even when colored concentrated soup such as soy sauce ramen is directly packed into frozen foods, it is possible to provide a soup for frozen foods and a frozen food that contains the soup for frozen foods that causes little transfer of soup color to the food during storage in the freezer or cooking in a microwave oven, etc.

本発明の実施形態に係る冷凍食品用スープAの上面図である。FIG. 2 is a top view of soup A for frozen foods according to an embodiment of the present invention. 本発明の実施形態に係る冷凍食品用スープAのα-α’線断面図である。This is a cross-sectional view of soup A for frozen foods according to an embodiment of the present invention taken along line α-α'. 本発明の実施形態に係る冷凍食品Bの上面図である。FIG. 2 is a top view of frozen food B according to an embodiment of the present invention. 本発明の実施形態に係る冷凍食品Bのβ-β’線断面図である。This is a β-β' cross-sectional view of frozen food B according to an embodiment of the present invention. 本発明に実施形態に係る冷凍食品の変形例である冷凍食品用スープA’及び冷凍食品B’の上面図である。1 is a top view of soup A' for frozen food and frozen food B', which are modified examples of the frozen food according to an embodiment of the present invention. FIG. 本発明に実施形態に係る冷凍食品の変形例である冷凍食品用スープA’及び冷凍食品B’のγ-γ’線断面図である。7 is a cross-sectional view of frozen food soup A' and frozen food B', which are modified examples of frozen foods according to an embodiment of the present invention, taken along line γ-γ'. FIG. 本発明に実施形態に係る冷凍食品の変形例である冷凍食品B”の上面図である。FIG. 2 is a top view of frozen food B″, which is a modified example of the frozen food according to the embodiment of the present invention. 本発明に実施形態に係る冷凍食品の変形例である冷凍食品B”の下面図である。FIG. 2 is a bottom view of frozen food B″, which is a modified example of the frozen food according to the embodiment of the present invention. 本発明に実施形態に係る冷凍食品の変形例である冷凍食品B”のΔ-Δ’線断面図である。FIG. 2 is a cross-sectional view taken along line Δ-Δ′ of frozen food B″, which is a modified example of the frozen food according to the embodiment of the present invention. 本発明に実施形態に係る冷凍食品の変形例のである冷凍食品B’の作製例を示した説明図である。FIG. 2 is an explanatory diagram showing an example of preparation of frozen food B', which is a modified example of the frozen food according to the embodiment of the present invention. 本発明に実施形態に係る冷凍食品の変形例のである冷凍食品B”の作製例を示した説明図である。FIG. 1 is an explanatory diagram showing an example of preparation of frozen food B″, which is a modified example of the frozen food according to the embodiment of the present invention. 実施例3の冷凍食品サンプルの上面写真、虐待処理後の底面写真、虐待処理サンプルの電子レンジ調理後の上面写真、虐待処理サンプルの給湯後の麺の写真である。These are a top view photograph of a frozen food sample of Example 3, a bottom view photograph after the abuse treatment, a top view photograph of the abuse-treated sample after cooking in a microwave, and a photograph of the noodles of the abuse-treated sample after being heated to boiling water. 比較例1の冷凍食品サンプルの上面写真、虐待処理後の底面写真、虐待処理サンプルの給湯後の麺の写真である。This is a photograph of the top surface of a frozen food sample of Comparative Example 1, a photograph of the bottom surface after abuse treatment, and a photograph of the noodles of the abuse-treated sample after being heated to boiling water. 比較例3の冷凍食品サンプルの上面写真、虐待処理後の底面写真、虐待処理サンプルの電子レンジ調理後の上面写真、虐待処理サンプルの給湯後の麺の写真である。These are a top view photograph of a frozen food sample of Comparative Example 3, a bottom view photograph after the abuse treatment, a top view photograph of the abuse-treated sample after cooking in a microwave, and a photograph of the noodles of the abuse-treated sample after being heated to boiling water.

1 内層スープ
2 外層スープ
3 主食品
4 耐熱性アミラーゼを含む氷層
5 冷凍用容器
6 内層スープノズル
7 外層スープノズル
8 二液充填ノズル
9 耐熱性アミラーゼ水溶液
A 冷凍食品用スープ
B 冷凍食品
1 Inner layer soup 2 Outer layer soup 3 Main food 4 Ice layer containing heat-resistant amylase 5 Freezing container 6 Inner layer soup nozzle 7 Outer layer soup nozzle 8 Two-liquid filling nozzle 9 Aqueous solution of heat-resistant amylase A Soup for frozen food B Frozen food

以下、本発明について詳細に説明する。ただし、本発明は以下の記載に限定されるものではない。 The present invention will be described in detail below. However, the present invention is not limited to the following description.

(1)冷凍食品用スープ
本発明に係る冷凍食品用スープは、図1及び2で示す冷凍食品用スープAや図7及び図9で示す冷凍食品用スープA’のように内層スープ1と、これを包含する外層スープ2を有する二層構造となっている。
(1) Soup for frozen foods The soup for frozen foods according to the present invention has a two-layer structure having an inner layer soup 1 and an outer layer soup 2 that encompasses it, such as soup A for frozen foods shown in Figures 1 and 2 and soup A' for frozen foods shown in Figures 7 and 9.

本発明に係る外層スープ2は、充填時の粘度として270Pa・s以上が好ましい。粘度が270Pa・s未満であると内層スープ1の粘度が低い場合、内層スープ1を包含することが難しいだけでなく、主食材3上に直充填する場合には、冷凍食品用スープが主食材3の上に留まることが難しくなる。逆に高すぎるとノズルから充填しにくくなる。好ましくは550~1610Pa・sである。粘度の測定方法は、各充填時の温度においてB型粘度計で測定する。ローターや回転速度については、ローター4番で回転数0.3rpmで測定すればよい。 The outer layer soup 2 of the present invention preferably has a viscosity of 270 Pa·s or more when filled. If the viscosity is less than 270 Pa·s, not only is it difficult to contain the inner layer soup 1 when the inner layer soup 1 has a low viscosity, but when filled directly onto the main ingredient 3, it is difficult for the frozen food soup to remain on top of the main ingredient 3. Conversely, if the viscosity is too high, it becomes difficult to fill from the nozzle. The viscosity is preferably 550 to 1610 Pa·s. The viscosity is measured using a B-type viscometer at each temperature when filling. The rotor and rotation speed can be measured using rotor number 4 at a rotation speed of 0.3 rpm.

本発明に係る外層スープ2は、60℃における粘度が250Pa・s以上であることが好ましい。250Pa・s未満であると、電子レンジなどの調理時に、融解した外層スープ2が主食品3の隙間から落下して内層スープ1が主食品3と接触したり、沸騰して主食品3に色移りする。また、内層スープ1が落下することで内層スープ1が焦げたりする。逆に粘度が高すぎると、外層スープ2が熱湯に溶解しにくくなったり、均質に混ぜにくくなったりする。好ましくは520~1140Pa・sである。粘度の測定方法は、60℃に調整した外層2スープをB型粘度計で測定する。ローターや回転速度については、ローター4番で回転数0.3rpmで測定すればよい。 The outer layer soup 2 of the present invention preferably has a viscosity of 250 Pa·s or more at 60°C. If it is less than 250 Pa·s, the molten outer layer soup 2 may fall through gaps in the main food 3 during cooking in a microwave oven or the like, causing the inner layer soup 1 to come into contact with the main food 3, or may boil and stain the main food 3. Furthermore, the inner layer soup 1 may burn as it falls. Conversely, if the viscosity is too high, the outer layer soup 2 may be difficult to dissolve in hot water or difficult to mix homogeneously. A viscosity of 520 to 1140 Pa·s is preferable. The viscosity is measured by measuring the outer layer 2 soup adjusted to 60°C with a B-type viscometer. The rotor and rotation speed may be measured with rotor number 4 at a rotation speed of 0.3 rpm.

本発明に係る外層スープ2は、ゼラチン、澱粉または増粘多糖類の少なくとも何れか一つにより、粘度を調整することが好ましい。本発明に係る冷凍食品用スープを直充填するためには、高粘度とする必要があり、また、電子レンジ調理などの加熱後においても粘性を保ち、主食材3の上に留まり、必要により熱湯などに溶解可能であることが好ましいことから、高温でも粘度を維持しやすく、熱湯に溶解しやすい澱粉をベースに粘度を調整することが好ましい。 The viscosity of the outer layer soup 2 according to the present invention is preferably adjusted by at least one of gelatin, starch, and thickening polysaccharides. In order to directly fill the frozen food soup according to the present invention, it is necessary to have a high viscosity, and it is preferable that the soup maintains its viscosity even after heating, such as in a microwave oven, remains on top of the main ingredient 3, and is soluble in hot water if necessary. Therefore, it is preferable to adjust the viscosity based on starch, which is easy to maintain its viscosity even at high temperatures and is easily soluble in hot water.

本発明に係る外層スープ2の粘度調整に澱粉を使用する場合、澱粉の種類は、特に限定はなく、馬鈴薯澱粉、タピオカ澱粉、コーンスターチ 、ワキシーコーンスターチ、サゴ澱粉、緑豆澱粉、小麦澱粉、米澱粉などの澱粉及びこれらにエーテル化、エステル化、リン酸化、酸化処理などの処理を施した加工澱粉などが例示され、これら澱粉から一または二以上を選択して使用することができる。なお、本発明で使用する澱粉として、冷凍耐性のある澱粉が好ましく、リン酸架橋澱粉、ヒドロキシプロピル化リン酸架橋澱粉、アセチル化リン酸架橋澱粉が好ましい。澱粉の添加量としては、外層スープの粘度にもよるが、5~15重量%が好ましい。5重量%未満だと十分な粘度が発現できず、15重量%よりも多いと粘度が高くなりすぎ、ノズルによる充填が困難となる。 When starch is used to adjust the viscosity of the outer layer soup 2 according to the present invention, the type of starch is not particularly limited, and examples include potato starch, tapioca starch, corn starch, waxy corn starch, sago starch, mung bean starch, wheat starch, rice starch, and processed starches obtained by subjecting these to etherification, esterification, phosphorylation, oxidation, and the like. One or more of these starches can be selected and used. The starch used in the present invention is preferably a starch that is resistant to freezing, and phosphate cross-linked starch, hydroxypropylated phosphate cross-linked starch, and acetylated phosphate cross-linked starch are preferred. The amount of starch added depends on the viscosity of the outer layer soup, but is preferably 5 to 15% by weight. If it is less than 5% by weight, sufficient viscosity cannot be expressed, and if it is more than 15% by weight, the viscosity becomes too high, making it difficult to fill the soup with a nozzle.

本発明に係る外層スープ2は、ゼラチンや増粘多糖類を用いて粘度を調整することもできる。澱粉だけでなくゼラチンや増粘多糖類を用いることで、冷凍食品用スープの充填適性を改善することができるだけでなく、澱粉だけでは表現できない調理後のスープ粘度を調整することができる。増粘多糖類の種類としては、グアガム、キサンタンガム、タラガム、タマリンドシードガム、スクシノグリカンなどが挙げられる。ゼラチンとしては、板ゼラチン、粉ゼラチン、顆粒ゼラチンなど何れのゼラチンも使用することができる。また、豚由来、牛由来、魚由来の何れのゼラチンも使用できる。増粘剤の添加量としては、求める冷凍麺類のスープの粘度や増粘剤の種類によるが、外層スープ中に0.1~3重量%程度添加することができる。 The viscosity of the outer layer soup 2 of the present invention can also be adjusted using gelatin or thickening polysaccharides. By using gelatin or thickening polysaccharides in addition to starch, it is possible to improve the filling suitability of the soup for frozen foods, and also to adjust the viscosity of the soup after cooking, which cannot be achieved with starch alone. Examples of thickening polysaccharides include guar gum, xanthan gum, tara gum, tamarind seed gum, and succinoglycan. As for gelatin, any type of gelatin can be used, such as sheet gelatin, powdered gelatin, or granular gelatin. In addition, any type of gelatin derived from pork, beef, or fish can also be used. The amount of thickener added depends on the desired viscosity of the soup for frozen noodles and the type of thickener, but it can be added to the outer layer soup in an amount of about 0.1 to 3% by weight.

本発明に係る外層スープ2のその他の素材としては、通常の目的とする冷凍食品のスープやソースに使用する素材を使用できる。例えば、食塩、砂糖、グルタミン酸ナトリウム、コハク酸ナトリウム、核酸、蛋白加水分解物、アミノ酸、クエン酸、酢酸などの酸味料、醤油、酒、みりん、油脂、動植物粉末、動植物エキス、香辛料、色素、香料などが挙げられる。また、肉ミンチやカット野菜などの固形分を含んでもよい。ただし、外層スープ2は、直接冷凍食品の主食品3と接するため、主食材3に接したときに色移りするような濃口醤油や色素などの成分の添加はできるだけ少なくし、内層スープ1に多く配合することが好ましい。そうすることで、冷凍保存中の温度上昇によりスープが融解した場合でも、外層スープ2から主食材3への色移りを防ぐことができる。また、冷凍食品であっても、冷凍保存中に風味が劣化していくため、風味が劣化する成分は、出来るだけ内層スープ1に多く配合することが好ましい。具体的には、食塩、砂糖などの結晶物と澱粉やゼラチン、増粘剤などの粘度を出す素材を含むことが好ましい。 Other ingredients of the outer layer soup 2 according to the present invention can be ingredients used in soups and sauces for ordinary frozen foods. Examples include salt, sugar, sodium glutamate, sodium succinate, nucleic acid, protein hydrolysates, amino acids, citric acid, acidulants such as acetic acid, soy sauce, sake, mirin, oils and fats, animal and vegetable powders, animal and vegetable extracts, spices, colorings, and flavorings. It may also contain solids such as minced meat and cut vegetables. However, since the outer layer soup 2 comes into direct contact with the main food 3 of the frozen food, it is preferable to add as little ingredients such as dark soy sauce and colorings that may transfer color when in contact with the main food 3 as possible and to mix them in large amounts in the inner layer soup 1. By doing so, even if the soup melts due to a rise in temperature during frozen storage, color transfer from the outer layer soup 2 to the main food 3 can be prevented. In addition, even in frozen foods, the flavor deteriorates during frozen storage, so it is preferable to mix as many ingredients that deteriorate flavor as possible in the inner layer soup 1. Specifically, it is preferable for the mixture to contain crystalline substances such as salt and sugar, as well as viscosity-imparting materials such as starch, gelatin, and thickeners.

本発明に係る内層スープ1の粘度は、特に限定はなく、粘性が無くても、粘性があっても外層スープ2に包含されれば問題ないが、多少粘性がある方が充填時や冷凍保存時に内層スープ1が外層スープ2と混ざったり、外層スープ1の外側へ出て広がることが少なく好ましい。好ましい粘度としては、充填時において0.2Pa・s~1250Pa・s程度である。 The viscosity of the inner layer soup 1 according to the present invention is not particularly limited, and it does not matter if it is viscous or not, as long as it is contained in the outer layer soup 2. However, it is preferable for the inner layer soup 1 to have some viscosity, as this reduces the possibility of the inner layer soup 1 mixing with the outer layer soup 2 during filling or freezing and spreading outside the outer layer soup 1. The preferred viscosity is about 0.2 Pa·s to 1250 Pa·s when filling.

本発明に係る内層スープ1に使用される素材としては、外層スープ2と同様に、澱粉、ゼラチン、増粘剤を使用できる他に、通常の目的とする冷凍食品の濃縮スープに使用する素材を使用できる。例えば、食塩、砂糖、グルタミン酸ナトリウム、コハク酸ナトリウム、核酸、蛋白加水分解物、アミノ酸、クエン酸、酢酸などの酸味料、醤油、酒、みりん、油脂、動植物粉末、動植物エキス、香辛料、色素、香料などが挙げられる。また、肉ミンチやカット野菜などの固形分を含んでもよい。ただし、内層スープ1は、外層スープ2よりも色移りするような濃口醤油や色素などを多く含むことが好ましい。そうすることで、冷凍保存中の温度上昇によりスープが融解した場合でも、外層スープ2から主食材3への色移りを防ぐことができる。また、内層スープ1には、冷凍保存中に風味が劣化する成分や、電子レンジ調理による加熱により風味が悪くなったり、揮発してしまうような成分を多く含むことが好ましい。具体的には、醤油ラーメンの場合は、濃口醤油やカラメル色素の色素成分、香辛料、香料、動植物エキスなどの風味素材は外層スープ1よりも内層スープ2に含まれることが好ましい。 The ingredients used in the inner layer soup 1 according to the present invention can be starch, gelatin, thickeners, as in the outer layer soup 2, or ingredients used in concentrated soups for ordinary frozen foods. Examples include salt, sugar, sodium glutamate, sodium succinate, nucleic acid, protein hydrolysates, amino acids, acidulants such as citric acid and acetic acid, soy sauce, sake, mirin, oils and fats, animal and vegetable powders, animal and vegetable extracts, spices, colorings, and flavorings. Solids such as minced meat and cut vegetables may also be included. However, it is preferable that the inner layer soup 1 contains more dark soy sauce and colorings that may transfer color than the outer layer soup 2. This can prevent color transfer from the outer layer soup 2 to the main ingredient 3 even if the soup melts due to a rise in temperature during frozen storage. It is also preferable that the inner layer soup 1 contains many ingredients whose flavor deteriorates during frozen storage, or whose flavor deteriorates or evaporates when heated in a microwave oven. Specifically, in the case of soy sauce ramen, it is preferable that flavoring ingredients such as dark soy sauce and caramel coloring, spices, flavorings, and animal and plant extracts are contained in the inner soup layer 2 rather than the outer soup layer 1.

本発明に係る冷凍食品用スープは内層スープ1及び外層スープ2合わせて、本発明に係る冷凍食品1食あたり、50~150g添加することが好ましい。添加量が少なくなると濃縮スープの場合、スープの濃縮が困難であり、多すぎると解凍に時間がかかる。また、外層スープ2の重量は、内層スープ1の重量に対して2~10倍程度が好ましい。外層スープ2の量が少なすぎると内層スープ1が外層スープ2の外に出てしまう可能性が高く、また、図5及び図6で示した冷凍食品B’のように、冷凍食品用スープA’を主食材3に直充填した場合には、外層スープ2が主食材3の隙間から垂れることにより内層スープ1が主食材3と部分的に接触してしまう可能性が高くなる。逆に外層スープ2の量が多すぎると調理時の解凍や熱湯でスープを溶解するのに時間がかかり好ましくない。 It is preferable to add 50 to 150 g of the inner layer soup 1 and the outer layer soup 2 to one meal of the frozen food according to the present invention. If the amount added is small, it is difficult to concentrate the soup in the case of a concentrated soup, and if the amount added is too large, it takes a long time to thaw. The weight of the outer layer soup 2 is preferably about 2 to 10 times the weight of the inner layer soup 1. If the amount of the outer layer soup 2 is too small, there is a high possibility that the inner layer soup 1 will fall out of the outer layer soup 2. Also, when the frozen food soup A' is directly filled into the main ingredient 3 as in the frozen food B' shown in Figures 5 and 6, there is a high possibility that the outer layer soup 2 will drip from the gap in the main ingredient 3, causing the inner layer soup 1 to partially come into contact with the main ingredient 3. Conversely, if the amount of the outer layer soup 2 is too large, it is not preferable because it takes a long time to thaw during cooking or to dissolve the soup in hot water.

本発明に係る冷凍食品用スープは、図1及び図2で示すような冷凍食品用スープAのように冷凍食品用スープのみを凍結してから、図3で示すように主食材3に添加して使用してもよく、図5及び図6で示す冷凍食品用スープA’のように主食材3に直充填して使用してもよい。冷凍食品用スープAのように冷凍食品用スープのみを凍結する場合には、凍結用の型枠に入れて、ワゴンフリーザーやスパイラルフリーザーなどで凍結してもよく、また型枠に入れずにコンベア上に冷凍食品用スープを充填し、スパイラルフリーザーやトンネルフリーザー等により凍結してもよい。凍結温度は特に限定はないが、少なくとも外層スープがしっかりと凍結するまで凍結すればよい。 The frozen food soup according to the present invention may be used by freezing only the soup for frozen foods as in the case of frozen food soup A shown in Figures 1 and 2 and then adding it to the main food ingredient 3 as shown in Figure 3, or by directly filling the main food ingredient 3 as in the case of frozen food soup A' shown in Figures 5 and 6. When only the soup for frozen foods is frozen as in the case of frozen food soup A, it may be placed in a freezing form and frozen in a wagon freezer or spiral freezer, or the soup for frozen foods may be filled on a conveyor without being placed in a form and frozen in a spiral freezer or tunnel freezer. There are no particular limitations on the freezing temperature, but it is sufficient to freeze until at least the outer layer of the soup is firmly frozen.

また、本発明に係る冷凍食品用スープは、ラーメン、うどん、そばなどの濃縮スープとして電子レンジ調理後に熱湯をかけて溶解することにより喫食できるものや、水を入れて鍋炊き調理してスープを溶解し喫食でもよく、また、あんかけラーメン、パスタなどのストレートスープ(またはソース)として電子レンジ調理などによりそのまま喫食できるものでもよい。ラーメン、うどん、そばなどの場合は、外層スープの粘度を主に澱粉で発現させ、熱湯をかける際や鍋炊き調理時に耐熱性アミラーゼを作用させることによって、喫食時のスープの粘度を低下させることができる。 The frozen food soup according to the present invention may be a concentrated soup for ramen, udon, soba, etc. that can be eaten by pouring boiling water over it after cooking in a microwave oven, or it may be a soup that can be eaten by adding water and cooking in a pot to dissolve the soup, or it may be a straight soup (or sauce) for ramen with thickened sauce, pasta, etc. that can be eaten as is after cooking in a microwave oven. In the case of ramen, udon, soba, etc., the viscosity of the outer layer soup is expressed mainly by starch, and the viscosity of the soup at the time of eating can be reduced by pouring boiling water over it or cooking in a pot.

本発明に係る冷凍食品用スープの製造方法としては、特に限定はなく、外層スープを容器に充填した後、中央を凹ませて内層スープを充填し、包含するように更に上から外層スープを載せて作製してもよく、容器に充填した外層スープの中央にノズルを差し込み内層スープを充填した後、ノズル孔を外層スープで塞いで作製してもよく、後述する二液充填ノズルにより作製してもよい。 There are no particular limitations on the method for producing the frozen food soup according to the present invention. The method may involve filling a container with the outer layer soup, then creating a depression in the center and filling it with the inner layer soup, and then placing the outer layer soup on top to enclose it, or it may involve inserting a nozzle into the center of the outer layer soup filled in the container, filling it with the inner layer soup, and then blocking the nozzle hole with the outer layer soup, or it may be produced using a two-liquid filling nozzle, which will be described later.

なお、本発明における包含とは、内層スープが完全に外層スープ内に含まれるものだけではなく、内層スープの大部分が外層スープに包まれていることをいい、充填時や凍結時の膨張により意図せずに内層スープの一部が外層スープ外に出てしまうものも含む。これらの場合の多くが冷凍食品用スープの上面側でおこるため、部分的に内層が外層外に漏れ出ても主食材3と直接接しないため、大きな問題はない。 In this invention, "encompassing" does not only mean that the inner layer soup is completely contained within the outer layer soup, but also that most of the inner layer soup is enveloped in the outer layer soup, and also includes cases where part of the inner layer soup unintentionally leaks out of the outer layer soup due to expansion during filling or freezing. In most cases, this occurs on the top surface side of the soup for frozen foods, so even if part of the inner layer leaks out of the outer layer, it does not come into direct contact with the main ingredient 3, and so there is no major problem.

(2)冷凍食品
本発明に係る冷凍食品は、図4、図6及び図9の冷凍食品B、冷凍食品B’、冷凍食品B”で示すように、本発明に係る冷凍食品用スープAや冷凍食品用スープA’と主食材3を含む食品であれば特に限定はなく、例えば、冷凍うどん、冷凍そば、冷凍中華麺、冷凍パスタ、冷凍あんかけ焼きそば、冷凍あんかけラーメン、冷凍あんかけチャーパンが挙げられる。この内、喫食時のスープが粘度の少なく、濃縮スープを使用するような、冷凍うどん、冷凍そば、冷凍ラーメンなどの冷凍麺類は、濃縮スープを直充填する場合に主食材3への色移りが問題となることが多く、本発明に係る冷凍食品用スープを使用する冷凍食品として適している。つまり、主食材3への色移りを防ぐべく、主食材3と直接接する外層スープ2に色移りする成分を少なくし、内層スープ1に色移りする成分を多く配合することで、冷凍保存時や電子レンジなどの調理時に色素成分が麺へ移行することを防ぐことができる。
(2) Frozen Foods The frozen foods of the present invention are not particularly limited as long as they contain soup A for frozen foods or soup A' for frozen foods of the present invention and main food ingredient 3, as shown by frozen foods B, B', and B" in Figs. 4, 6, and 9, and examples thereof include frozen udon, frozen soba, frozen Chinese noodles, frozen pasta, frozen fried noodles with thickened sauce, frozen ramen with thickened sauce, and frozen fried bread with thickened sauce. Of these, frozen noodles such as frozen udon, frozen soba, and frozen ramen, which have a low viscosity soup when eaten and use concentrated soup, often pose a problem of color transfer to the main food ingredient 3 when concentrated soup is directly filled, and are therefore suitable as frozen foods that use the soup for frozen foods of the present invention. In other words, in order to prevent color transfer to the main food ingredient 3, the amount of components that transfer color to the outer layer soup 2 that is in direct contact with the main food ingredient 3 is reduced, and a large amount of components that transfer color to the inner layer soup 1 is blended, thereby preventing the transfer of color components to the noodles during frozen storage or cooking in a microwave oven, etc.

主食材3としては、そば、うどん、ラーメン、マカロニ、スパゲティ、パスタ、春雨、ビーフン、冷麺などの麺類やチャーハンなどの米飯類が挙げられ、常法により加熱調理したものを冷凍食品1食当たり150~250gで充填することが好ましい。 The main ingredient 3 may be noodles such as soba, udon, ramen, macaroni, spaghetti, pasta, glass noodles, rice vermicelli, hiyashi noodles, or cooked rice such as fried rice. It is preferable to fill 150 to 250 g of the main ingredient 3 per serving of frozen food after heating and cooking it in the usual manner.

例えば、本発明に係る冷凍食品の主食材3が麺類の場合は、常法の製法で作製した生麺や乾麺を使用することができる。生麺や乾麺を茹で処理や蒸し処理することによりα化する。本発明に係る冷凍食品は、喫食時に加熱調理されるため、完全に喫食できる程度まで麺を茹で処理や蒸し処理するのではなく、時間を短くするなどにより、一部不完全な状態にすることが好ましい。例えば、茹で温度が95~100℃程度、茹で時間については、ラーメンであれば通常20秒~5分程度、うどんであれば4分~20分程度で加熱処理すればよい。蒸煮の方法としては、飽和水蒸気による加熱だけでなく、過熱水蒸気により加熱することもでき、シャワーや浸漬などの水分補給工程を組み合わせることもできる。調理された麺は必要により、水洗冷却や調味液浸漬を行うこともできる。加熱調理した麺は、冷凍用容器5に充填し、凍結処理する。 For example, when the main ingredient 3 of the frozen food according to the present invention is noodles, raw noodles or dried noodles produced by a conventional manufacturing method can be used. Raw noodles or dried noodles are gelatinized by boiling or steaming. Since the frozen food according to the present invention is cooked when eaten, it is preferable to make the noodles partially incomplete by shortening the time rather than boiling or steaming them to a level that allows them to be completely eaten. For example, the boiling temperature is about 95 to 100°C, and the boiling time is usually about 20 seconds to 5 minutes for ramen and about 4 to 20 minutes for udon. As a method of steaming, heating with not only saturated steam but also superheated steam can be used, and a hydration step such as showering or soaking can be combined. The cooked noodles can be washed and cooled or soaked in seasoning liquid as necessary. The cooked noodles are filled into a freezing container 5 and frozen.

本発明に係る冷凍食品の主食材3が米飯類の場合は、常法により炊飯した米飯を冷凍用容器5に充填して凍結してもよいが、常法によりバラ凍結し作製した冷凍米飯を冷凍用容器5に充填して凍結してもよい。 When the main ingredient 3 of the frozen food according to the present invention is cooked rice, cooked rice may be packed into the freezing container 5 in a conventional manner and frozen, or frozen cooked rice prepared by bulk freezing in a conventional manner may be packed into the freezing container 5 and frozen.

主食材3の厚みとしては、凍結後の厚みが20mm以上であることが好ましい。20mm以下となると電子レンジ調理時に溶解した冷凍食品用スープが底に落下し、焦げる可能性がある。好ましくは25mm以上、より好ましくは30mm以上である。また、逆に主食材3の厚みが厚くなりすぎると、調理時間が長くなり調理ムラが発生するため、50mm以下が好ましい。 The thickness of the main ingredient 3 after freezing is preferably 20 mm or more. If it is less than 20 mm, the frozen food soup that melts during microwave cooking may fall to the bottom and burn. It is preferably 25 mm or more, and more preferably 30 mm or more. Conversely, if the main ingredient 3 is too thick, the cooking time will be longer and uneven cooking will occur, so it is preferably 50 mm or less.

また、本発明に係る主食材3の充填密度としては、あまりに密度が低いと冷凍食品用スープが主食材3の上面に留まらず、また、電子レンジ調理した際に冷凍食品用スープが垂れ落ちるため、0.3g/cm以上が好ましい。より好ましくは0.4g/cm以上である。また、あまり高密度すぎても電子レンジ調理に時間がかかるため0.6g/cm以下が好ましい。麺塊密度については、冷凍麺塊の平坦面を10~20mm角の正方形に切断し、切断面の四辺の長さ(高さ)の平均をサンプルの高さとして、切断サンプルの体積として算出すればよい。 Furthermore, if the density is too low, the soup for the frozen food will not remain on the upper surface of the main food ingredient 3 and will drip off during microwave cooking, so the packing density of the main food ingredient 3 in the present invention is preferably at least 0.3 g/ cm3 . More preferably, it is at least 0.4 g/ cm3 . Furthermore, if the density is too high, microwave cooking will take a long time, so a packing density of 0.6 g/ cm3 or less is preferable. The noodle block density can be calculated by cutting the flat surface of the frozen noodle block into a square with sides of 10 to 20 mm, taking the average length (height) of the four sides of the cut surface as the height of the sample, and calculating the volume of the cut sample.

本発明に係る冷凍食品の主食材3の形状は、特に限定はなく、円錐台状や四角錘台状、円柱状や四角柱状でもよい。また、図7、図8及び図9で示すように主食材の底面の中央に窪みを設けてもよい。窪みを設けることで、電子レンジ調理ムラを低減することができ、電子レンジ調理時間を短縮できる。窪みの深さとしては、主食材3の厚みにもよるが、5mm以上が好ましく、主食材3の厚みの10~70%となるように設けることが好ましい。 The shape of the main ingredient 3 of the frozen food according to the present invention is not particularly limited, and may be a truncated cone, a truncated square pyramid, a cylindrical shape, or a square prism shape. In addition, as shown in Figures 7, 8, and 9, a depression may be provided in the center of the bottom surface of the main ingredient. By providing a depression, unevenness in microwave cooking can be reduced, and the microwave cooking time can be shortened. The depth of the depression depends on the thickness of the main ingredient 3, but is preferably 5 mm or more, and is preferably 10 to 70% of the thickness of the main ingredient 3.

本発明に係る冷凍食品は、図3及び図4で示す冷凍食品Bのように別途作製した冷凍食品用スープAを主食材3に添加し、凍結するか、または、別途作製した冷凍食品用スープAを凍結した主食材3に添加して作製してもよい。 The frozen food of the present invention may be prepared by adding a separately prepared soup A for frozen food to a main ingredient 3 and freezing it, as in the case of frozen food B shown in Figures 3 and 4, or by adding a separately prepared soup A for frozen food to a frozen main ingredient 3.

また、本発明に係る冷凍食品は、図5及び図6で示す冷凍食品B’のように主食材3の上に冷凍食品用スープA’を直充填したものでもよい。冷凍食品B’の作製方法としては、図10(b)のように冷凍用容器5に主食材3を充填し、次いで図10(c)、(d)のように二液充填ノズル8の外層ノズル7から外層スープ2を充填しつつ、遅れて内層スープ1を内層ノズル6から充填し、図10(e)のように内層ノズル6から内層スープ1の充填を止め、次いで図10(f)のように外層ノズル7から外層スープ2の充填を止めることで、外層スープ2に内層スープ1が包含された冷凍食品用スープA’を主食材3の上に直充填できる。冷凍食品用スープA’を主食材3の上に直充填した冷凍用容器5を図10(g)で示すように凍結庫などで冷凍する。このとき、完全に凍結するまでに時間がかかるが、その間に冷凍食品用スープA’が主食材3から垂れ落ちないことが好ましい。完全に凍結した後、図10(h)のように冷凍用容器5から取り出すことで冷凍食品B’を作製することができる。 The frozen food according to the present invention may also be one in which the soup A' for frozen food is directly filled on the main ingredient 3, as in the frozen food B' shown in Figs. 5 and 6. The method of producing the frozen food B' is as follows: the main ingredient 3 is filled in the freezing container 5 as shown in Fig. 10(b), then the outer layer soup 2 is filled from the outer layer nozzle 7 of the two-liquid filling nozzle 8 as shown in Figs. 10(c) and (d), while the inner layer soup 1 is filled from the inner layer nozzle 6 after a delay, as shown in Figs. 10(c) and (d), the filling of the inner layer soup 1 from the inner layer nozzle 6 is stopped as shown in Fig. 10(e), and then the filling of the outer layer soup 2 from the outer layer nozzle 7 is stopped as shown in Fig. 10(f), thereby directly filling the soup A' for frozen food, in which the inner layer soup 1 is contained in the outer layer soup 2, on the main ingredient 3. The freezing container 5 in which the soup A' for frozen food is directly filled on the main ingredient 3 is frozen in a freezer or the like as shown in Fig. 10(g). At this time, it takes time to completely freeze, but it is preferable that the soup A' for frozen food does not drip from the main ingredient 3 during that time. Once completely frozen, frozen food B' can be produced by removing it from the freezing container 5 as shown in FIG. 10(h).

また、本発明に係る冷凍食品は、図7、図8及び図9で示す冷凍食品B”のように主食材3に耐熱性アミラーゼの表層4を付着させることができる。耐熱性アミラーゼを冷凍食品B”に添加することで、冷凍食品用スープA’の外層スープ2の粘度が澱粉をベースに付けられている場合、熱湯を注ぐことで主食材3に付着した耐熱性アミラーゼが外層スープ2の澱粉を分解し、喫食時のスープの粘度を低下させることができ、うどんやそば、ラーメンなどの低粘度のスープを有する食品とすることができる。 Furthermore, the frozen food according to the present invention can have a surface layer 4 of heat-resistant amylase attached to the main ingredient 3, as in the case of frozen food B" shown in Figures 7, 8 and 9. By adding heat-resistant amylase to frozen food B", if the viscosity of the outer layer soup 2 of frozen food soup A' is based on starch, pouring hot water over it will cause the heat-resistant amylase attached to the main ingredient 3 to break down the starch in the outer layer soup 2, lowering the viscosity of the soup when eaten, allowing it to become a food with a low-viscosity soup, such as udon, soba or ramen.

本発明にいう耐熱性アミラーゼとは、至適温度が概ね70℃以上のアミラーゼをいう。通常の酵素では、至適温度が30℃~50℃程度であり、これと比較して高温度帯において至適温度を有する。また、耐熱性のアミラーゼであれば、特に種類は限定されない。すなわち、αアミラーゼ、βアミラーゼのいずれでも使用可能であるが、αアミラーゼの方が澱粉の分解速度が速いため好ましい。また、これらのアミラーゼは細菌や植物 、動物等の生物から抽出したものや遺伝子工学的手法を用いて大量生産して製造されたものでもよい。具体的な製品としては、天野エンザイム株式会社のクライスターゼ(登録商標)T10S、クライスターゼ(登録商標)SD8、コクゲンSD―TC3等が挙げられる。尚、本発明に利用できる耐熱性アミラーゼは、固形の粉末状態のタイプや液体のタイプのいずれも用いることができる。 The term "thermostable amylase" as used herein refers to an amylase with an optimum temperature of approximately 70°C or higher. The optimum temperature of ordinary enzymes is approximately 30°C to 50°C, and the optimum temperature of the thermostable amylase is in a higher temperature range. There is no particular limitation on the type of thermostable amylase. In other words, either α-amylase or β-amylase can be used, but α-amylase is preferred because it has a faster starch decomposition rate. These amylases may be extracted from organisms such as bacteria, plants, and animals, or mass-produced using genetic engineering techniques. Specific examples of such products include Clystase (registered trademark) T10S, Clystase (registered trademark) SD8, and Kokugen SD-TC3, all of which are manufactured by Amano Enzyme Co., Ltd. The thermostable amylase that can be used in the present invention may be in the form of a solid powder or liquid.

本発明に係る耐熱性アミラーゼを含む表層4中の耐熱性アミラーゼの量としては、喫食時のスープ量は250g~350gである場合、喫食時のスープ中に概ね15U以上の耐熱性アミラーゼを含むように添加すればよい。15U以上含まれれば、本発明に係る冷凍食品用スープに含まれる澱粉を分解することができる。上限は、特に限定はないが、200U以上添加すると麺の食感に影響が出ることがある。具体的には、耐熱性アミラーゼを1.5U/g~20U/g含む水溶液を本発明に係る冷凍食品1食あたり、5~50g程度添加することが好ましい。 The amount of thermostable amylase in the surface layer 4 containing the thermostable amylase according to the present invention is such that, when the amount of soup at the time of consumption is 250g to 350g, the thermostable amylase is added so that the soup at the time of consumption contains approximately 15U or more. If 15U or more is contained, the starch contained in the soup for frozen foods according to the present invention can be decomposed. There is no particular upper limit, but adding more than 200U may affect the texture of the noodles. Specifically, it is preferable to add about 5 to 50g of an aqueous solution containing 1.5U/g to 20U/g of thermostable amylase per serving of the frozen food according to the present invention.

本発明に係る冷凍食品B”の作製方法としては、図11(a)に記載したような底面の中央が凸上に盛り上がった冷凍用容器5に図11(b)で記載したように主食材3を充填し、図11(c)~(f)で示すように冷凍食品用スープA’を直充填した後、図11(f)で示すように耐熱性アミラーゼ水溶液9を冷凍用容器5の側面に充填し、図11(g)で示すように凍結することで耐熱性アミラーゼを含む氷層4を作製し、図11(h)で示すように冷凍用容器5から取り外すことで冷凍用食品B”を作製できる。耐熱性アミラーゼ水溶液の充填は、主食材3の充填前に行っても、主食材3の充填後、冷凍食品用スープA’の充填前に行ってもよい。また、冷凍用容器5は、底面の中央が凸上に盛り上がっているが、図10に記載された冷凍用容器5のように底面の中央が平坦のものであってもよい。 In the method of producing frozen food B" according to the present invention, a freezing container 5 with a convex bottom center as shown in FIG. 11(a) is filled with a main ingredient 3 as shown in FIG. 11(b), and then directly filled with soup A' for frozen food as shown in FIGS. 11(c) to (f). Then, a thermostable amylase aqueous solution 9 is filled on the side of the freezing container 5 as shown in FIG. 11(f), and an ice layer 4 containing thermostable amylase is produced by freezing as shown in FIG. 11(g). Then, the container is removed from the freezing container 5 as shown in FIG. 11(h), thereby producing frozen food B". The thermostable amylase aqueous solution may be filled before filling with the main ingredient 3, or after filling with the main ingredient 3 and before filling with soup A' for frozen food. Although the freezing container 5 has a convex bottom center, the freezing container 5 may have a flat bottom center as shown in FIG. 10.

その他の食材として、チャーシュー、メンマ、ホウレンソウ、天ぷら、油揚げ、揚げ玉などの具材を本発明に係る冷凍食品に添加することができる。添加方法としては、予め凍結した具材を凍結した冷凍食品に添加してもよく、主食材3を凍結する際に添加させ一緒に凍結させてもよい。 Other ingredients such as roasted pork fillets, bamboo shoots, spinach, tempura, deep-fried tofu, and fried tempura bits can be added to the frozen food of the present invention. The ingredients may be added by adding pre-frozen ingredients to the frozen food, or by adding the ingredients when freezing the main ingredient 3 and freezing them together.

凍結した冷凍食品は、電子レンジ調理する場合は、電子レンジ調理可能な袋や容器に入れ包装し、市販することができる。鍋炊き調理の場合は、耐冷性のあるプラスチック製のフィルムに包装したり、直火調理可能なアルミ皿に本発明に係る冷凍食品を入れ、耐冷凍性のあるプラスチックフィルムで包装することで市販するができる。 If the frozen food is to be cooked in a microwave oven, it can be packaged in a microwaveable bag or container and sold commercially. If it is to be cooked in a pot, it can be packaged in a cold-resistant plastic film, or the frozen food of the present invention can be placed in an aluminum dish that can be cooked over an open flame and then packaged in a freezing-resistant plastic film and sold commercially.

(3)調理
本発明に係る冷凍食品の調理方法としては、特に限定はなく、電子レンジ調理や鍋炊き調理で喫食することができる。冷凍食品が米飯類やパスタ、あんかけ焼きそば、焼きそば、焼うどんなどを電子レンジ調理する場合は、電子レンジ調理後そのまま喫食可能であり、うどん、そば、ラーメンを電子レンジ調理する場合は、電子レンジ調理後、どんぶりに移して熱湯を注ぎ撹拌することで簡便に喫食できる。また、うどん、そば、ラーメンを鍋炊き調理する場合は、鍋やアルミ皿に水や熱湯を注ぎ、加熱することで喫食することができる。
(3) Cooking The cooking method of the frozen food according to the present invention is not particularly limited, and it can be eaten by cooking in a microwave oven or cooking in a pot. When the frozen food is cooked in a microwave oven, such as rice, pasta, fried noodles with thickened sauce, fried noodles, or fried udon, it can be eaten as is after cooking in the microwave oven. When udon, soba, or ramen is cooked in a microwave oven, it can be easily eaten by transferring it to a bowl, pouring hot water over it, and stirring it. When udon, soba, or ramen is cooked in a pot, it can be eaten by pouring water or hot water into a pot or aluminum dish and heating it.

このとき、本発明に係る冷凍食品用スープは、電子レンジ調理によって加熱されても60℃における粘度が250Pa・s以上と高いため、図12で示すように、加熱されても冷凍食品用スープが主食材3の上に落下せずに留まり、また、内層スープ1が外層スープ2の外へ溶出してしまうことがない。そのため、冷凍食品スープが焦げることもなく、また、色移りするような成分を内層スープ1に多く配合することにより、調理時に冷凍食品用スープから主食材3に色移りを防ぐことができる。 At this time, the frozen food soup according to the present invention has a high viscosity of 250 Pa·s or more at 60°C even when heated by microwave cooking, so as shown in FIG. 12, the frozen food soup does not fall onto the main ingredient 3 even when heated, and the inner layer soup 1 does not dissolve out of the outer layer soup 2. Therefore, the frozen food soup does not burn, and by incorporating a large amount of ingredients that may transfer color into the inner layer soup 1, color transfer from the frozen food soup to the main ingredient 3 during cooking can be prevented.

また、本発明に係る冷凍食品B”のように耐熱性アミラーゼを含む場合、電子レンジ調理などによる加熱調理の後に熱湯を注ぐことで冷凍食品用スープの外層スープ2に含まれる澱粉が溶解するため、喫食時のスープ粘度が低くすることができる。 In addition, when the frozen food B" according to the present invention contains a heat-resistant amylase, the starch contained in the outer layer soup 2 of the frozen food soup is dissolved by pouring boiling water after cooking with heat such as in a microwave oven, so that the viscosity of the soup at the time of eating can be reduced.

以上のように、冷凍食品用スープを内側の内層スープを、外側の外層スープが包含するような二層構造とし、充填時の外層スープの粘度を270Pa・s以上とし、60℃における外層スープの粘度を250Pa・s以上とすることにより、冷凍食品の主食材に直接濃縮スープを直充填でき、包材が削減でき、簡便な調理が可能な冷凍食品用スープ及び該冷凍食品用スープを含む冷凍食品を提供することができる。また、醤油ラーメンのような有色の濃縮スープを冷凍食品に直充填する場合であっても、冷凍保存時や調理時の食品へのスープの色移りが少ない冷凍食品用スープ及び該冷凍食品用スープを含む冷凍食品を提供することができる。 As described above, by making the soup for frozen foods have a two-layer structure in which the inner layer soup is enclosed by the outer layer soup, making the viscosity of the outer layer soup at the time of filling 270 Pa·s or more, and making the viscosity of the outer layer soup at 60°C 250 Pa·s or more, it is possible to fill the concentrated soup directly into the main ingredient of the frozen food, reducing packaging materials and providing a frozen food soup that allows for simple cooking, and a frozen food that contains the said soup for frozen foods. Furthermore, even when colored concentrated soup such as soy sauce ramen is directly filled into the frozen food, it is possible to provide a soup for frozen foods and a frozen food that contains the said soup for frozen foods that causes little transfer of the soup color to the food during freezing and cooking.

以下に実施例を挙げて本実施形態をさらに詳細に説明する。 The following examples will explain this embodiment in more detail.

(各試験区の冷凍食品用スープの作製)
下記表1に記載された各試験区の配合のスープ用の資材を、水、粉体物、液体物の順にタンクに投入し良く撹拌した。次いで、タンクを加熱しながら良く撹拌した後、90℃達温後10分間温度を維持しながら撹拌し、35℃まで冷却した。このとき、35℃におけるスープ(二層スープの場合は、各層スープ)の粘度を測定した。また、60℃におけるスープ(二層スープの場合は、各層スープ)の粘度を測定した。粘度についてはB型粘度計で測定し、ヒドロキシプロピルリン酸架橋澱粉の重量が3重量%についてはローター1番で12rpm、その他のサンプルについてはローター4番で回転数0.3rpmで測定した。
(Preparation of frozen food soup for each test group)
The ingredients for soup in each test batch shown in Table 1 below were placed in a tank in the order of water, powder, and liquid, and thoroughly stirred. The tank was then heated and thoroughly stirred, and after reaching a temperature of 90°C, the temperature was maintained while stirring for 10 minutes, and then cooled to 35°C. The viscosity of the soup (each layer soup in the case of a two-layer soup) at 35°C was measured. The viscosity of the soup (each layer soup in the case of a two-layer soup) at 60°C was also measured. The viscosity was measured with a B-type viscometer, and for samples containing 3% by weight of hydroxypropyl phosphate cross-linked starch, the measurement was performed with rotor No. 1 at 12 rpm, and for the other samples, the measurement was performed with rotor No. 4 at 0.3 rpm.

Figure 0007489861000001
Figure 0007489861000001

(実施例1)
小麦粉950gと澱粉50gを混合した原料粉に、食塩10gとかんすい製剤(炭酸ナトリウム50:炭酸カリウム45:重合リン酸塩5)10gを350mlの水に溶かした練り水を加え、ミキサーで15分間混練し麺生地を作製した。これをロールで圧延して厚さ1.5mmの麺帯とし、20番の切刃(角刃)で切出して生麺線とした。次に、得られた生麺線を、1食分25~30cm(重量116g/食)にカットし、沸騰水にて30秒間茹で、冷水で1分間水洗後、氷水に30秒間浸漬、冷却し、水切し、調理済み麺(ラーメン)とした。
Example 1
A mixing solution of 10 g of salt and 10 g of kansui preparation (sodium carbonate 50: potassium carbonate 45: polymerized phosphate 5) dissolved in 350 ml of water was added to a raw material flour made by mixing 950 g of wheat flour and 50 g of starch, and the mixture was kneaded in a mixer for 15 minutes to prepare a noodle dough. This was rolled out with a roll to produce a noodle band with a thickness of 1.5 mm, and cut out with a cutting blade (square blade) of No. 20 to produce raw noodle strands. The obtained raw noodle strands were then cut into one serving of 25-30 cm (weight 116 g/serving), boiled in boiling water for 30 seconds, washed in cold water for 1 minute, immersed in ice water for 30 seconds, cooled, and drained to produce cooked noodles (ramen).

次いで、冷凍用容器(容器口径:150mm,容器底面径:140mm,容器高さ:54mm,容器凸部口径:108mm,容器凸部底面径:96.5mm,容器凸部高さ:8mm)に調理済み麺を170g充填した後、充填した調理済み麺の上に二液ノズルを用いて表1の実施例1に記載された内層スープが外層スープに包含するように麺塊上面の中央に充填した(麺密度0.46g/cm、麺塊厚み30mm)。次いで耐熱性アミラーゼとしてクライスターゼ(登録商標)T10S(1700U/g)を0.3重量%となるように溶解した溶液を10g冷凍用容器に充填し、-35℃のエアブラスト式急速凍結機に入れ45分間、冷凍処理し、トレーから取り出し、図7、図8及び図9で示したような冷凍食品(醤油ラーメン)を作製した。作製した冷凍食品は、電子レンジ調理用の袋にいれて試験サンプルとした。 Next, 170 g of cooked noodles were packed into a freezing container (container opening diameter: 150 mm, container bottom diameter: 140 mm, container height: 54 mm, container convex opening diameter: 108 mm, container convex bottom diameter: 96.5 mm, container convex height: 8 mm), and then a two-fluid nozzle was used to pack the cooked noodles into the center of the top surface of the noodle block so that the inner layer soup described in Example 1 of Table 1 was encompassed by the outer layer soup (noodle density: 0.46 g/cm 3 , noodle block thickness: 30 mm). Next, 10 g of a solution in which Kleistase (registered trademark) T10S (1700 U/g) was dissolved to a concentration of 0.3 wt % as a heat-resistant amylase was packed into the freezing container, and the solution was placed in an air blast type quick freezer at -35°C for 45 minutes and then removed from the tray to produce a frozen food (soy sauce ramen) as shown in Figures 7, 8 and 9. The frozen food thus prepared was placed in a bag for microwave cooking to prepare a test sample.

(実施例2)
表1の実施例2に記載された内層スープ、外層スープを充填する以外は実施例1の方法に従って試験サンプルを作製した。
Example 2
Test samples were prepared according to the method of Example 1, except that the inner layer soup and outer layer soup described in Example 2 in Table 1 were filled.

(実施例3)
表1の実施例3に記載された内層スープ、外層スープを充填する以外は実施例1の方法に従って試験サンプルを作製した。
Example 3
Test samples were prepared according to the method of Example 1, except that the inner layer soup and outer layer soup described in Example 3 of Table 1 were filled.

(実施例4)
表1の実施例4に記載された内層スープ、外層スープを充填する以外は実施例1の方法に従って試験サンプルを作製した。
Example 4
Test samples were prepared according to the method of Example 1, except that the inner layer soup and outer layer soup shown in Example 4 in Table 1 were filled.

(実施例5)
表1の実施例5に記載された内層スープ、外層スープを充填する以外は実施例1の方法に従って試験サンプルを作製した。
Example 5
Test samples were prepared according to the method of Example 1, except that the inner layer soup and outer layer soup shown in Example 5 in Table 1 were filled.

(実施例6)
表1の実施例6に記載された内層スープ、外層スープを充填する以外は実施例1の方法に従って試験サンプルを作製した。
(比較例1)
表1の比較例1に記載された濃縮スープを二液ノズルの内層ノズルから充填し、耐熱性アミラーゼ溶液を添加しない以外は、実施例1方法に従って試験サンプルを作製した。
Example 6
Test samples were prepared according to the method of Example 1, except that the inner layer soup and outer layer soup described in Example 6 in Table 1 were filled.
(Comparative Example 1)
A test sample was prepared according to the method of Example 1, except that the concentrated soup described in Comparative Example 1 in Table 1 was filled from the inner layer nozzle of the two-liquid nozzle and no heat-resistant amylase solution was added.

(比較例2)
表1の比較例2、3に記載された濃縮スープを二液ノズルの内層ノズルから充填する以外は、比較例1の方法に従って試験サンプルを作製した。
(Comparative Example 2)
Test samples were prepared according to the method of Comparative Example 1, except that the concentrated soups shown in Comparative Examples 2 and 3 in Table 1 were filled from the inner layer nozzle of the two-liquid nozzle.

(比較例3)
表1の比較例2、3に記載された濃縮スープを二液ノズルの内層ノズルから充填する以外は、実施例1方法に従って試験サンプルを作製した。
(Comparative Example 3)
Test samples were prepared according to the method of Example 1, except that the concentrated soups shown in Comparative Examples 2 and 3 in Table 1 were filled from the inner nozzle of the two-liquid nozzle.

(比較例4)
表1の比較例4に記載された内層スープ、外層スープを充填する以外は実施例1の方法に従って試験サンプルを作製した。
(Comparative Example 4)
A test sample was prepared in the same manner as in Example 1, except that the inner layer soup and outer layer soup shown in Comparative Example 4 in Table 1 were filled.

各試験例の冷凍麺類サンプルを調理し評価を行った。調理方法は、試験例サンプルを電子レンジにて500Wで5分30秒間調理して行い、どんぶりに移した後に、熱湯を250g注ぎスープと麺を撹拌して行った。評価については、充填時のスープの垂れ落ち、二層スープに関しては内層スープの包含性、調理時の麺への色移り、スープの垂れ落ち、スープの溶解性・粘度について行った。また、各サンプルは、虐待処理したものについても調理を行い、調理後の色移りについて評価を行った。虐待処理は、-18℃の冷蔵庫に14日間保存し、1回30分かけて庫内温度が5℃まで昇温し、30分かけて-18℃まで降温する処理を6時間ごとに行った。 Each test example frozen noodle sample was cooked and evaluated. The cooking method was to cook the test example sample in a microwave oven at 500W for 5 minutes and 30 seconds, then transfer it to a bowl, pour in 250g of boiling water, and stir the soup and noodles. Evaluations were performed on dripping of soup when filled, the containment of the inner layer of soup for the two-layer soup, color transfer to the noodles during cooking, dripping of soup, and the solubility and viscosity of the soup. Each sample was also cooked after being abused, and color transfer after cooking was evaluated. Abuse treatment involved storing the samples in a refrigerator at -18°C for 14 days, with the temperature inside the refrigerator being raised to 5°C over 30 minutes and then lowered to -18°C over 30 minutes, with this treatment performed every 6 hours.

評価方法は、4段階評価で行った。充填時のスープの垂れ落ちについては、麺塊内部への垂れ落ちがほとんどないものを◎、麺塊の内部に垂れ落ちはあるが軽微である(内層スープが麺塊と接触していない)ものを○、電子レンジ用包材までは垂れ落ちがないが麺塊内部深くまで垂れ落ちがある(内層スープが麺塊と接触している)ものを△、電子レンジ用包材まで垂れ落ちがあるものを×とした。 The evaluation method was a four-point scale. Regarding dripping of soup during filling, those that hardly dripped into the inside of the noodle block were rated as ◎, those that dripped into the inside of the noodle block but only slightly (the inner layer of soup was not in contact with the noodle block) were rated as ○, those that did not drip onto the microwave packaging but dripped deep into the noodle block (the inner layer of soup was in contact with the noodle block) were rated as △, and those that dripped onto the microwave packaging were rated as ×.

二層スープについては、内層の包含性について評価を行った。内層スープが外層スープ内部に非常に良好に包含されているものを◎、内層スープが外層スープ内部に包含されているものを○、内層スープが外層スープの一部が出てしまっているものを△、内層スープが外層スープから大部分が出てしまっているものを×とした。 The two-layer soup was evaluated for the inclusion of the inner layer. The inner layer soup was very well included in the outer layer soup, and was marked with an ◎. The inner layer soup was included in the outer layer soup, and was marked with an ○. The inner layer soup was partially leaking out of the outer layer soup, and the inner layer soup was mostly leaking out of the outer layer soup, and was marked with an ×.

調理時の色移りについては、麺線の色移りが全くないものを◎、麺線の色移りはほとんどなく薄く軽微なものを○、麺への色移りが部分的にあり気づくものを△、麺への色移りが著しく、目立つものを×とした。 Regarding color transfer during cooking, the following criteria were given: ◎: no color transfer to the noodle strings at all; ○: very little or only slight color transfer to the noodle strings; △: some color transfer to the noodles that was noticeable; ×: significant and noticeable color transfer to the noodles.

調理時のスープの垂れ落ちについては、電子レンジ調理後にスープの麺塊内部への垂れ落ちがほとんどないものを◎、麺塊の内部に垂れ落ちはあるが麺塊の底面までは垂れ落ちていないものを○、僅かに麺塊の底面まで垂れ落ちがあるが電子レンジ用包材までは垂れ落ちがないものを△、電子レンジ用包材まで垂れ落ちがあるものを×とした。 Regarding dripping of soup during cooking, those that barely dripped into the noodle block after microwave cooking were marked with an ◎, those that dripped into the noodle block but did not drip onto the bottom of the noodle block were marked with an ○, those that dripped slightly onto the bottom of the noodle block but did not drip onto the microwave packaging were marked with a △, and those that dripped onto the microwave packaging were marked with an ×.

調理時のスープの粘度・溶解性については、お湯に溶解し、別添スープで調理した際のスープの粘度とほとんど変わらないものを◎、お湯に溶解し、僅かに別添スープで調理した際のスープの粘度より高いが概ね良好なものを○、お湯に溶解しづらく、別添スープで調理した際のスープの粘度が高く劣るものを△、お湯に溶解させることが困難で、別添スープで調理した際のスープの粘度が著しく高く不可なものを×とした。 Regarding the viscosity and solubility of the soup during cooking, those that dissolved in hot water and had almost the same viscosity as the soup when cooked with the soup provided separately were rated as ◎, those that dissolved in hot water and had a slightly higher viscosity than the soup when cooked with the soup provided separately but were generally good were rated ○, those that were difficult to dissolve in hot water and had a high and inferior viscosity when cooked with the soup provided separately were rated △, and those that were difficult to dissolve in hot water and had a significantly higher viscosity when cooked with the soup provided separately and were unacceptable were rated ×.

また、各試験サンプルを虐待処理したサンプルを同様に調理を行い、調理時の色移りについて評価を行った。 In addition, samples that had been subjected to abusive treatment were cooked in the same manner and the color transfer during cooking was evaluated.

各試験例の官能評価結果について下記表2に示す。 The sensory evaluation results for each test example are shown in Table 2 below.

Figure 0007489861000002
Figure 0007489861000002

比較例1で示すように、通常の濃縮スープをそのまま充填する場合には、充填時からスープが麺塊から垂れ落ち、調理時に麺に色移りするだけでなく、スープが焦げて風味が悪いものとなった。また、図13で示すように、虐待処理によりさらに麺にスープの色が移った。 As shown in Comparative Example 1, when ordinary concentrated soup was filled as is, the soup dripped from the noodle block when it was filled, and not only did the color transfer to the noodles during cooking, but the soup also burned, resulting in a poor flavor. Furthermore, as shown in Figure 13, the mistreatment process caused the color of the soup to transfer even more to the noodles.

比較例2で示すように、主に澱粉によりスープに粘性を持たせることにより、充填時にスープが垂れ落ちず、調理時もスープが垂れ落ちることがないため、ある程度麺線への色移りや焦げによる風味劣化を抑制することができた。しかしながら、スープをお湯で溶かしたときのスープの溶解性が悪く、澱粉によりスープの粘度が増加した。 As shown in Comparative Example 2, by imparting viscosity to the soup mainly through starch, the soup does not drip when filled or when cooked, and this helps to prevent color transfer to the noodle strings and flavor deterioration due to burning. However, the soup has poor solubility when dissolved in hot water, and the viscosity of the soup increases due to the starch.

比較例3で示すように、耐熱性アミラーゼの氷層を麺塊に付着させることにより、比較例2と比較し、調理時のスープの溶解性が向上し、スープ中の澱粉が分解されるため粘度がほとんど発生しなくなった。しかしながら、図14で示すように、虐待処理を行うと麺塊と濃口醤油やカラメル色素を含むスープが直接接触しているため、品温の上昇に伴いスープが溶解し色移りが発生したことから冷凍保存中の色移りが起きると考える。 As shown in Comparative Example 3, by attaching an ice layer of heat-resistant amylase to the noodle block, the solubility of the soup during cooking was improved compared to Comparative Example 2, and the starch in the soup was broken down, resulting in almost no viscosity. However, as shown in Figure 14, when the noodle block was subjected to abuse treatment, the noodle block was in direct contact with the soup containing dark soy sauce and caramel coloring, and as the product temperature rose, the soup dissolved and color transfer occurred, which is thought to be why color transfer occurs during frozen storage.

それに対し、実施例1~6で示すように、冷凍食品用スープを二層化し、色移りしやすい濃口醤油やカラメル色素を内層に充填することで、調理時の色移りだけでなく、図12で示すように虐待時の色移りも防ぐことができることから、冷凍保存中の色移りも防ぐことができると考える。 In response to this, as shown in Examples 1 to 6, by making the soup for frozen foods into two layers and filling the inner layer with dark soy sauce or caramel coloring, which are prone to color transfer, it is possible to prevent color transfer not only during cooking but also during abuse, as shown in Figure 12, and therefore it is believed that color transfer during frozen storage can also be prevented.

しかしながら、比較例4で示すように、外層スープの澱粉添加量が低く、粘度が低い場合には、充填時に内層スープを外層スープが包含することが難しく、また、スープが麺塊内部に落下してしまうため、調理時の色移りが発生するだけでなく、虐待処理により麺にスープの色が移った。したがって、外層スープの充填時の粘度としては、270Pa・s以上、より好ましくは、550Pa・s以上が好ましいと考える。また、澱粉の含量としては、5重量%以上、より好ましくは7重量%以上が好ましいと考える。逆に、実施例5で示すように、外層スープの澱粉添加量が多く、粘度が高い場合は、熱湯の溶解性が悪く耐熱性アミラーゼによる分解に時間がかかり、スープの粘度が高めとなった。また、充填も難しくなるため澱粉含量としては15重量%以下、より好ましくは12重量%以下、充填時の粘度としては、2000pa・s以下、より好ましくは1610Pa・s以下が好ましいと考える。 However, as shown in Comparative Example 4, when the amount of starch added to the outer layer soup is low and the viscosity is low, it is difficult for the outer layer soup to contain the inner layer soup when filling, and the soup falls into the inside of the noodle block, which not only causes color transfer during cooking, but also transfers the color of the soup to the noodles when the noodle is mistreated. Therefore, it is considered that the viscosity of the outer layer soup when filling is 270 Pa·s or more, more preferably 550 Pa·s or more. It is also considered that the starch content is 5% by weight or more, more preferably 7% by weight or more. Conversely, as shown in Example 5, when the amount of starch added to the outer layer soup is high and the viscosity is high, the solubility in boiling water is poor and it takes a long time to decompose with heat-resistant amylase, resulting in a high viscosity of the soup. It is also difficult to fill, so it is considered that the starch content is 15% by weight or less, more preferably 12% by weight or less, and the viscosity when filling is 2000 Pa·s or less, more preferably 1610 Pa·s or less.

実施例6で示すように、内層スープの重量に対して外層スープの重量が少なくなると充填時の包含性が悪くなり、内層スープが麺塊と接触しやすくなり、色移りが発生しやすくなった。よって、内層スープを包含する外層スープの量としては2倍以上が好ましいと考える。しかしながら、外層スープの量を増やせば増やすほど、冷凍食品用スープの重量が重くなり、解凍に時間がかかるだけでなく、澱粉を分解するためにより多くの酵素が必要となるため、実質的に10倍以下が好ましいと考える。 As shown in Example 6, when the weight of the outer layer soup is small relative to the weight of the inner layer soup, the inclusion during filling is poor, the inner layer soup is more likely to come into contact with the noodle block, and color transfer is more likely to occur. Therefore, it is considered preferable that the amount of outer layer soup encompasses the inner layer soup by at least two times. However, the more the amount of outer layer soup is increased, the heavier the soup for frozen foods becomes, which not only takes longer to thaw, but also requires more enzymes to break down the starch, so it is considered preferable that the amount is substantially 10 times or less.

Claims (10)

主食材とスープとを含む冷凍食品に用いられる二層構造を有する冷凍食品用スープであって、
前記二層構造は、内側の内層スープを、外側の外層スープが包含する構造であり、
充填時の前記外層スープの粘度が270Pa・s以上であり、
60℃の前記外層スープの粘度が250Pa・s以上であり、
前記外層スープは、粘度調整のための原料として少なくとも澱粉を含むことを特徴とする冷凍食品用スープ
A soup for frozen food having a two-layer structure used for frozen food including a main ingredient and soup ,
The two-layer structure is a structure in which an inner layer soup is enclosed by an outer layer soup,
the viscosity of the outer layer soup at the time of filling is 270 Pa s or more,
The viscosity of the outer layer soup at 60°C is 250 Pa s or more,
The outer layer soup contains at least starch as an ingredient for adjusting viscosity .
前記澱粉がリン酸架橋澱粉、ヒドロキシプロピルリン酸架橋澱粉またはアセチル化リン酸架橋澱粉の少なくとも一つを含むことを特徴とする請求項1記載の冷凍食品用スープ。2. The soup for frozen food according to claim 1, wherein the starch comprises at least one of phosphate cross-linked starch, hydroxypropyl phosphate cross-linked starch, or acetylated phosphate cross-linked starch. 前記澱粉の添加量が外層スープの重量に対して5~15重量%であることを特徴とする請求項1または2記載の冷凍食品用スープ。3. A soup for frozen foods according to claim 1 or 2, characterized in that the amount of said starch added is 5 to 15% by weight based on the weight of the outer layer soup. 前記冷凍食品用スープ中の前記外層スープの重量は、前記内層スープの重量の2倍以上であることを特徴とする請求項1~3何れか一項記載の冷凍食品用スープ。 The soup for frozen foods according to any one of claims 1 to 3, characterized in that the weight of the outer layer soup in the soup for frozen foods is at least twice the weight of the inner layer soup. 前記内層スープの方が前記外層スープよりも色素成分を多く含むこと特徴とする請求項1~4何れか一項記載の冷凍食品用スープ。 The soup for frozen food according to any one of claims 1 to 4, characterized in that the inner layer soup contains more pigment components than the outer layer soup. 前記冷凍食品用スープが前記主食材の上に直充填されることを特徴とする請求項1~5何れか一項記載の冷凍食品用スープ。 6. The soup for frozen foods according to claim 1, wherein the soup for frozen foods is filled directly on top of the main ingredient. 請求項1~6何れか一項記載の冷凍食品用スープと主食材を含むことを特徴とする冷凍食品。 A frozen food comprising the soup for frozen food according to any one of claims 1 to 6 and a main ingredient . 前記主食材麺類または米飯類であることを特徴とする請求項7記載の冷凍食品。
The frozen food according to claim 7, characterized in that the main ingredient is noodles or rice .
前記冷凍食品中に耐熱性アミラーゼを含むことを特徴とする請求項7または8記載の冷凍食品。 The frozen food according to claim 7 or 8, characterized in that the frozen food contains a heat-resistant amylase. 主食材とスープとを含む冷凍食品に用いられる冷凍食品用スープの製造方法であって、
前記冷凍食品用スープは、内側の内層スープを、外側の外層スープが包含する二層構造となるように、二液充填ノズルを使用して製造され、
前記外層スープは、充填時の粘度が270Pa・s以上であり、60℃の粘度が250Pa・s以上であり、
前記外層スープは、粘度調整のための原料として少なくとも澱粉を含むことを特徴とする冷凍食品用スープの製造方法。
A method for producing soup for frozen food used in frozen food including a main ingredient and soup , comprising:
The soup for frozen food is produced using a two-liquid filling nozzle so that the soup has a two-layer structure in which an inner layer soup is enclosed by an outer layer soup,
the outer layer soup has a viscosity of 270 Pa s or more when filled and a viscosity of 250 Pa s or more at 60° C.,
2. A method for producing soup for frozen foods , wherein the outer layer soup contains at least starch as a raw material for adjusting viscosity .
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JP2005176803A (en) 2003-12-24 2005-07-07 Nisshin Foods Kk Packaged frozen noodle
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JP2006061113A (en) 2004-08-30 2006-03-09 Nissin Food Prod Co Ltd Frozen seasoning liquid lump, frozen food with seasoning liquid and method for producing the same
JP2011115055A (en) 2009-12-01 2011-06-16 Nisshin Foods Kk Frozen sauce having microwave oven resistance, and frozen food including the same
JP2015188382A (en) 2014-03-28 2015-11-02 日清食品ホールディングス株式会社 Food product containing noodle and soup
JP2019135945A (en) 2018-02-07 2019-08-22 キユーピー株式会社 Frozen spherical food and frozen spherical food production method
JP2019205357A (en) 2018-05-28 2019-12-05 日清フーズ株式会社 Gel-like sauce

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JP2005176803A (en) 2003-12-24 2005-07-07 Nisshin Foods Kk Packaged frozen noodle
JP2006020630A (en) 2004-06-11 2006-01-26 Ajinomoto Co Inc Frozen food having seasoning liquid
JP2006061113A (en) 2004-08-30 2006-03-09 Nissin Food Prod Co Ltd Frozen seasoning liquid lump, frozen food with seasoning liquid and method for producing the same
JP2011115055A (en) 2009-12-01 2011-06-16 Nisshin Foods Kk Frozen sauce having microwave oven resistance, and frozen food including the same
JP2015188382A (en) 2014-03-28 2015-11-02 日清食品ホールディングス株式会社 Food product containing noodle and soup
JP2019135945A (en) 2018-02-07 2019-08-22 キユーピー株式会社 Frozen spherical food and frozen spherical food production method
JP2019205357A (en) 2018-05-28 2019-12-05 日清フーズ株式会社 Gel-like sauce

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