JP7457549B2 - Method for producing a new salt composition - Google Patents
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- JP7457549B2 JP7457549B2 JP2020053797A JP2020053797A JP7457549B2 JP 7457549 B2 JP7457549 B2 JP 7457549B2 JP 2020053797 A JP2020053797 A JP 2020053797A JP 2020053797 A JP2020053797 A JP 2020053797A JP 7457549 B2 JP7457549 B2 JP 7457549B2
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- 150000003839 salts Chemical class 0.000 title claims description 67
- 239000000203 mixture Substances 0.000 title claims description 44
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 150000004676 glycans Chemical class 0.000 claims description 28
- 229920001282 polysaccharide Polymers 0.000 claims description 28
- 239000005017 polysaccharide Substances 0.000 claims description 28
- 239000007864 aqueous solution Substances 0.000 claims description 20
- 230000008719 thickening Effects 0.000 claims description 14
- 235000004298 Tamarindus indica Nutrition 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 7
- 244000215068 Acacia senegal Species 0.000 claims description 6
- 229920000084 Gum arabic Polymers 0.000 claims description 6
- 235000010489 acacia gum Nutrition 0.000 claims description 6
- 239000000205 acacia gum Substances 0.000 claims description 6
- 240000004584 Tamarindus indica Species 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 94
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 55
- 239000011780 sodium chloride Substances 0.000 description 34
- 235000019643 salty taste Nutrition 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000002562 thickening agent Substances 0.000 description 14
- 238000011156 evaluation Methods 0.000 description 11
- 229920000591 gum Polymers 0.000 description 9
- 235000014347 soups Nutrition 0.000 description 9
- 241000596504 Tamarindus Species 0.000 description 8
- 238000001291 vacuum drying Methods 0.000 description 8
- 238000001694 spray drying Methods 0.000 description 6
- 210000001779 taste bud Anatomy 0.000 description 6
- 238000007602 hot air drying Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019640 taste Nutrition 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000015598 salt intake Nutrition 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- 229920002261 Corn starch Polymers 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 235000019658 bitter taste Nutrition 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 235000021056 liquid food Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000019600 saltiness Nutrition 0.000 description 2
- 235000011888 snacks Nutrition 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- AUHDWARTFSKSAC-HEIFUQTGSA-N (2S,3R,4S,5R)-3,4-dihydroxy-5-(hydroxymethyl)-2-(6-oxo-1H-purin-9-yl)oxolane-2-carboxylic acid Chemical compound [C@]1([C@H](O)[C@H](O)[C@@H](CO)O1)(N1C=NC=2C(O)=NC=NC12)C(=O)O AUHDWARTFSKSAC-HEIFUQTGSA-N 0.000 description 1
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229920002558 Curdlan Polymers 0.000 description 1
- 239000001879 Curdlan Substances 0.000 description 1
- 229920000926 Galactomannan Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GRSZFWQUAKGDAV-UHFFFAOYSA-N Inosinic acid Natural products OC1C(O)C(COP(O)(O)=O)OC1N1C(NC=NC2=O)=C2N=C1 GRSZFWQUAKGDAV-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 244000090599 Plantago psyllium Species 0.000 description 1
- 235000010451 Plantago psyllium Nutrition 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 235000019316 curdlan Nutrition 0.000 description 1
- 229940078035 curdlan Drugs 0.000 description 1
- 235000018823 dietary intake Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000504 effect on taste Effects 0.000 description 1
- -1 etc.) Polymers 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004245 inosinic acid Substances 0.000 description 1
- 235000013902 inosinic acid Nutrition 0.000 description 1
- 229940028843 inosinic acid Drugs 0.000 description 1
- 235000014109 instant soup Nutrition 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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- Seasonings (AREA)
- Jellies, Jams, And Syrups (AREA)
Description
本発明は、スープなどの用途において、塩味を強く持続可能な食塩組成物の製造方法に関するものである。 The present invention relates to a method for producing a salt composition that has a strong and sustainable salty taste for use in soups and the like.
近年、ナトリウムの過剰摂取による高血圧を予防するため、塩化ナトリウム含量を低減した、いわゆる減塩商品が多数上市されている。厚生労働省の「日本人の食事摂取基準」2010年度版では、一日の食塩摂取目標値が成人男性で9g未満、成人女性で7.5g未満であったのに対し、2015年度版では、一日の食塩摂取目標値が成人男性で8g未満、成人女性で7g未満とそれぞれ一日の食塩摂取目標値が減少していることからも、今後もさらに減塩志向が高まっていくと考えられる。 In recent years, in order to prevent high blood pressure caused by excessive intake of sodium, many so-called low-salt products with reduced sodium chloride content have been put on the market. In the 2010 edition of the Ministry of Health, Labor and Welfare's Dietary Intake Standards for Japanese, the daily target salt intake was less than 9g for adult men and less than 7.5g for adult women, but in the 2015 edition, Given that the daily salt intake target value for adult men is less than 8g and that for adult women is less than 7g, it is thought that the desire to reduce salt intake will continue to increase in the future.
例えば、塩味料粉末の溶解性等を改善するために、塩化ナトリウムと塩化カリウムとからなる水溶液を噴霧乾燥して粉末状の塩味料粉末を製造する方法が開示されている(特許文献1)。また、これに類似した方法として、食塩組成物の表面積を広げて塩味を強化するために、食塩と有機物質とからなる水溶液を噴霧乾燥して中空状の食塩組成物を製造する方法が開示されている(特許文献2)。 For example, in order to improve the solubility and the like of salty seasoning powder, a method has been disclosed in which a powdery salty seasoning powder is produced by spray drying an aqueous solution consisting of sodium chloride and potassium chloride (Patent Document 1). In addition, as a similar method, a method is disclosed in which a hollow salt composition is produced by spray-drying an aqueous solution consisting of common salt and an organic substance in order to expand the surface area of the salt composition and enhance the salty taste. (Patent Document 2).
しかしながら、これらの発明は、スナック菓子など固形のまま喫食される食品の塩味を強化するのには有効であるものの、即席スープのように、お湯で溶いて液状で喫食される食品に対しては、ほとんど塩味を強化する効果がなかった。 However, although these inventions are effective in enhancing the salty taste of foods that are eaten in solid form, such as snacks, they are not effective for enhancing the salty taste of foods that are eaten in liquid form by dissolving them in hot water, such as instant soup. There was almost no effect of enhancing the salty taste.
本発明は、スープ等の液状食品において、塩味を強化することが可能な食塩組成物を提供することを目的とするものである。 An object of the present invention is to provide a salt composition that can enhance the salty taste of liquid foods such as soups.
本発明者らは、食塩と増粘多糖類とを含む食塩組成物の製造方法であって、食塩と増粘多糖類とを含む水溶液を調整する工程と、該水溶液を真空乾燥する工程とを含むことを特徴とする食塩組成物の製造方法によって、上記課題を解決できることを見出した。 The present inventors have found that the above-mentioned problems can be solved by a method for producing a salt composition containing salt and a thickening polysaccharide, the method comprising the steps of preparing an aqueous solution containing salt and a thickening polysaccharide, and vacuum drying the aqueous solution.
本発明の完成により、スープ等の液状食品において、塩味を強化することが可能な食塩組成物を提供することができる。 By completing the present invention, it is possible to provide a salt composition that can enhance the salty taste in liquid foods such as soups.
本発明は、塩と増粘多糖類とを含む食塩組成物の製造方法であって、食塩と増粘多糖類とを含む水溶液を調整する工程と、該水溶液を真空乾燥する工程とを含むことを特徴とする食塩組成物の製造方法に関するものである。以下詳細に説明する。 The present invention is a method for producing a salt composition containing salt and a polysaccharide thickener, which includes the steps of preparing an aqueous solution containing salt and a polysaccharide thickener, and vacuum drying the aqueous solution. The present invention relates to a method for producing a salt composition characterized by the following. This will be explained in detail below.
原料
1-1.食塩
本発明における食塩とは、塩化ナトリウムを主成分とする食用の塩である。したがって、塩化ナトリウムを主成分とする海塩、岩塩なども本発明における食塩に含まれる。
Raw materials 1-1. Common Salt In the present invention, common salt is edible salt containing sodium chloride as a main component. Therefore, sea salt, rock salt, and the like containing sodium chloride as a main component are also included in the salt in the present invention.
また、食塩は、塩化ナトリウム以外にも無機塩を含んでいてもよい。具体的には、硫酸ナトリウム、硫酸マグネシウム等の硫酸塩、塩化カリウム、塩化マグネシウム等の塩化物塩、臭化ナトリウム、臭化カリウム等の臭化物塩、炭酸ナトリウム、および炭酸マグネシウム等の炭酸塩が含まれてもよい。 Moreover, common salt may contain inorganic salts other than sodium chloride. Specifically, it includes sulfates such as sodium sulfate and magnesium sulfate, chloride salts such as potassium chloride and magnesium chloride, bromide salts such as sodium bromide and potassium bromide, and carbonates such as sodium carbonate and magnesium carbonate. You may be
1-2.増粘多糖類
増粘多糖類を加えることにより、食塩粒子を繋ぎ合せ、造粒することが可能になる。増粘多糖類としては、アラビアガム、キサンタンガム、ジェランガム、タマリンドガム、サイリウムシードガム、ガラクトマンナン((例)ローカストビーンガム、グァーガム等)、グルコマンナン、カラギーナン、ペクチン、プルラン、カードラン寒天、ゼラチン等を挙げることができる。
1-2. polysaccharide thickener
The addition of polysaccharide thickeners allows the salt particles to be tied together and granulated. Thickening polysaccharides include gum arabic, xanthan gum, gellan gum, tamarind gum, psyllium seed gum, galactomannan (e.g. locust bean gum, guar gum, etc.), glucomannan, carrageenan, pectin, pullulan, curdlan agar, gelatin, etc. can be mentioned.
なかでも、エグ味や苦味などが弱く、風味への影響の小さいタマリンドガム又はアラビアガムが好ましい。 Among these, tamarind gum or gum arabic is preferred because it has a weak harsh taste or bitter taste and has little effect on flavor.
1-3.その他成分
本発明では、食塩、その他塩味成分および増粘多糖類以外の成分を含んでいて良い。具体的には、グルコース、スクロース、オリゴ糖等の乳糖以外の糖類、グルタミン酸やイノシン酸等の旨味成分、および香辛料などを風味や保存性が低下しない範囲で適宜加えることができる。ただし、その他材料が多すぎると塩味が低下したり、造粒しにくくなるため、食塩および増粘多糖類の総量に対して10重量%以下に留めることが好ましい。
1-3. Other Components The present invention may contain components other than common salt, other salty components, and polysaccharide thickeners. Specifically, sugars other than lactose such as glucose, sucrose, and oligosaccharides, flavor components such as glutamic acid and inosinic acid, and spices can be added as appropriate to the extent that flavor and preservability are not deteriorated. However, if the amount of other materials is too large, the salty taste will deteriorate or it will become difficult to granulate, so it is preferable to limit the amount to 10% by weight or less based on the total amount of salt and polysaccharide thickener.
2.水溶液の調整
真空乾燥を実施するために、食塩および増粘多糖類を含む水溶液を調整する。この際、溶媒として水以外にエタノール等の揮発性溶媒を併用しても良いが、溶解性の観点から水を主成分(溶媒全量分以上)とする必要がある。
2. Preparation of aqueous solution In order to carry out vacuum drying, an aqueous solution containing salt and a thickening polysaccharide is prepared. In this case, a volatile solvent such as ethanol may be used in addition to water as a solvent, but water must be the main component (at least the total amount of the solvent) from the viewpoint of solubility.
食塩100重量部に対して、増粘多糖類を3~10重量部添加することが好ましく、4~8重量部がより好ましい。増粘多糖類の添加量をこの範囲とすることで、食塩組成物の形状を保持するとともに、異味を抑え塩味への影響を最小限に抑えることができる。 The polysaccharide thickener is preferably added in an amount of 3 to 10 parts by weight, more preferably 4 to 8 parts by weight, per 100 parts by weight of common salt. By adjusting the amount of polysaccharide thickener added within this range, the shape of the salt composition can be maintained, off-taste can be suppressed, and the influence on salty taste can be minimized.
また、生産性の観点から、水溶液の食塩濃度はできる限り高濃度とすることが好ましい。具体的には、食塩濃度の下限は10重量%とすることが好ましい。なお、食塩濃度の上限は、食塩の水への溶解度に依存する。 Further, from the viewpoint of productivity, it is preferable that the salt concentration of the aqueous solution is as high as possible. Specifically, the lower limit of the salt concentration is preferably 10% by weight. Note that the upper limit of the salt concentration depends on the solubility of salt in water.
3.乾燥方法
本発明は、食塩組成物の製造に際して、真空乾燥を用いることが特徴である。先ず、塩化ナトリウム量を減らしても塩味の強さを維持できる理由、及びスープなどの用途でも塩味を持続できる理由について説明する。
3. Drying method The present invention is characterized in that vacuum drying is used in producing the salt composition. First, we will explain why the strength of the salty taste can be maintained even if the amount of sodium chloride is reduced, and why the salty taste can be maintained even when used in soups and the like.
一般的な食塩の場合は、主成分が塩化ナトリウム結晶であるため、食塩の表面には塩化ナトリウムが連続的に並んでいる。そして、この塩化ナトリウムが味蕾に作用することで塩味を感じる。ところが、味蕾は、塩化ナトリウムを定量するという点においては精度の高いセンサーではないため、容易に錯覚を起こすことができる。たとえば、結晶の中央部にある塩化ナトリウムは、味蕾に何ら作用しないため、中空状にして表面積を増やすことで塩味を強く感じさせることができる。これは、背景技術において説明した通りである。 In the case of common table salt, the main component is sodium chloride crystals, so sodium chloride is continuously arranged on the surface of the table salt. This sodium chloride then acts on the taste buds, giving it a salty taste. However, taste buds are not highly accurate sensors when it comes to quantifying sodium chloride, so they can easily create illusions. For example, the sodium chloride in the center of the crystal has no effect on taste buds, so making it hollow to increase the surface area can make the crystal taste more salty. This is as explained in the background art.
しかしながら、塩味を強めることができるのは、スナック菓子などの食塩組成物を固体で用いることのできる用途に限定される。中空状の食塩組成物は、表面積が多いため溶解するのも早い。したがって、スープなどの用途で中空状の食塩組成物を用いたとしても、塩味を持続させる効果はほとんどなかった。 However, the ability to enhance the salty taste is limited to applications where the salt composition can be used in solid form, such as snack foods. Since the hollow salt composition has a large surface area, it dissolves quickly. Therefore, even if a hollow salt composition was used for purposes such as soup, it had little effect on sustaining the salty taste.
味蕾を錯覚させる方法は他にも存在する。具体的には、塩味の強い(塩化ナトリウム濃度の高い)領域と、塩味の弱い(塩化ナトリウム濃度の低い)領域とが一定間隔で交互に存在する場合には、味蕾は塩味の強い領域に誘引されて塩味を強く感じやすい。発明者らは、このメカニズムを利用し、スープなどの用途で塩味を持続することが可能な食塩組成物を開発することを試みた。 There are other ways to fool the taste buds. Specifically, when regions with a strong salty taste (high sodium chloride concentration) and regions with a weak salty taste (low sodium chloride concentration) exist alternately at regular intervals, taste buds are attracted to the salty region. It tends to have a strong salty taste. The inventors attempted to utilize this mechanism to develop a salt composition that can maintain a salty taste when used in soups and the like.
次に、本発明の特徴である真空乾燥について、従来の乾燥法と比較しつつ説明する。 Next, vacuum drying, which is a feature of the present invention, will be explained in comparison with conventional drying methods.
自然乾燥、熱風乾燥
自然乾燥や熱風乾燥(以下「熱風乾燥等」という)の場合には、液体が滞留しながら徐々に乾燥するため素材ごとに析出してくるタイミングが異なる。本発明のように溶解度の低い塩化ナトリウムの濃度が高い場合には、塩化ナトリウムが優先して析出し、その後増粘多糖類が析出するため、塩化ナトリウムと増粘多糖類がそれぞれ偏在する。したがって、熱風乾燥等を用いる方法は、塩化ナトリウムと増粘多糖類を単に混合するのとほとんど変わらず、塩味を持続させる効果はない。
Natural drying, hot air drying <br/>In the case of natural drying or hot air drying (hereinafter referred to as "hot air drying, etc."), the liquid dries gradually while remaining in the liquid, so the timing of precipitation varies for each material. When the concentration of sodium chloride, which has low solubility, is high as in the present invention, sodium chloride precipitates first, followed by the thickening polysaccharides, so that sodium chloride and the thickening polysaccharides are unevenly distributed. Therefore, methods that use hot air drying, etc. are almost the same as simply mixing sodium chloride and thickening polysaccharides, and have no effect on sustaining the salty taste.
噴霧乾燥
前記の通り、噴霧乾燥の場合には、微小な液滴を散布して一気に粉末化させるため、熱風乾燥等とは異なり、食塩と増粘多糖類の偏在は起こりにくい。したがって、塩化ナトリウムが均一に分布した粒子径の細かい食塩組成物が形成される。しかしながら、噴霧乾燥で製造した食塩組成物は、中空状であり、表面積が大きいためお湯に速やかに溶解し、均一化してしまうため、スープなどの用途には向いていない。
Spray Drying As mentioned above, in the case of spray drying, minute droplets are dispersed and powdered at once, so unlike hot air drying etc., uneven distribution of common salt and thickening polysaccharide is less likely to occur. Therefore, a salt composition with fine particle size in which sodium chloride is uniformly distributed is formed. However, the salt composition produced by spray drying is hollow and has a large surface area, so it dissolves quickly in hot water and becomes uniform, so it is not suitable for uses such as soups.
真空乾燥
真空乾燥では、水の昇華により乾燥が進むため、水溶液に溶けている塩化ナトリウムや増粘多糖類は乾燥中ほとんど動かず、水の存在していた位置に無数の孔が形成される。この孔は非常に小さいためお湯(水)が入り込む余地がなく、食塩組成物の内部まではお湯が到達しにくい。このため、真空乾燥で製造した食塩組成物は、嵩高く、且つお湯に溶けにくいという特徴を有する。そして、スープ全体としての塩味が弱い(塩化ナトリウム濃度が低い)としても、食塩組成物周辺の塩味が強く(塩化ナトリウム濃度が高く)なることで、味蕾に塩味が強いと錯覚させることができる。
Vacuum drying In vacuum drying, drying progresses due to sublimation of water, so the sodium chloride and polysaccharide thickener dissolved in the aqueous solution hardly move during drying, leaving countless pores where water used to be. It is formed. These pores are so small that there is no room for hot water (water) to enter, making it difficult for hot water to reach the interior of the salt composition. For this reason, the salt composition produced by vacuum drying has the characteristics of being bulky and difficult to dissolve in hot water. Even if the soup as a whole has a weak salty taste (low sodium chloride concentration), the strong salty taste (high sodium chloride concentration) around the salt composition can trick the taste buds into thinking that the salty taste is strong.
次に実施例を示して、本発明を詳細に説明するが、本発明はこれらの実施例により何ら制限されるものではない。なお、特に断らない限り単位は重量部である。 EXAMPLES Next, the present invention will be explained in detail with reference to Examples, but the present invention is not limited to these Examples in any way. In addition, unless otherwise specified, the units are parts by weight.
(水溶液の調整)
1000重量部の水に、食塩100重量部、タマリンドガム1重量部に溶解させて水溶液1を調整した。また、タマリンドガムの配合量を変更して水溶液2~7を調整した。
(Preparation of aqueous solution)
Aqueous solution 1 was prepared by dissolving 100 parts by weight of salt and 1 part by weight of tamarind gum in 1000 parts by weight of water. Aqueous solutions 2 to 7 were also prepared by changing the amount of tamarind gum added.
水溶液5におけるタマリンドガムを、アラビアガム、キサンタンガム、グァーガム、セルロース又はコーンスターチに変更して水溶液8~12を調整した。なお、以下の記載においてタマリンドガム、アラビアガム、キサンタンガム、グァーガム、セルロース又はコーンスターチを「増粘多糖類等」と称する場合がある。 Aqueous solutions 8 to 12 were prepared by replacing the tamarind gum in aqueous solution 5 with gum arabic, xanthan gum, guar gum, cellulose, or corn starch. In the following description, tamarind gum, gum arabic, xanthan gum, guar gum, cellulose, or corn starch may be referred to as "thickening polysaccharide etc."
(凍結乾燥)
水溶液200mlを、ステンレス製の角型ポット(内寸法(縦×横×深さ)=200mm×100mm×50mm)に入れて、-20℃の冷凍庫で予備乾燥した。これを、凍結乾燥機(TFD-5LF4-H、東洋技研社製)を用いて凍結乾燥し、完全に乾燥した後に濾過(メッシュ10M)して食塩組成物1~12を製造した。
(freeze drying)
200 ml of the aqueous solution was placed in a stainless steel rectangular pot (inner dimensions (length x width x depth) = 200 mm x 100 mm x 50 mm) and pre-dried in a -20°C freezer. This was freeze-dried using a freeze dryer (TFD-5LF 4 -H, manufactured by Toyo Giken Co., Ltd.), and after being completely dried, it was filtered (mesh 10M) to produce salt compositions 1 to 12.
また、特表2016-527890号公報の記載に従って、水溶液5、8を噴霧乾燥し、中空状の食塩組成物R5、R8を製造した。 Further, according to the description in Japanese Patent Publication No. 2016-527890, aqueous solutions 5 and 8 were spray-dried to produce hollow salt compositions R5 and R8.
(塩味評価)
食塩組成物ごとに以下の3つの評価用サンプル(標準、比較1、比較2)を調整した。
(1)標準
80℃のお湯100重量部に、食塩組成物を加えて攪拌して5分間静置した。食塩組成物の添加量は、食塩の添加量が0.7重量部になるように調整した。例えば、食塩組成物5の評価に際しては、食塩組成物5を0.735重量部(食塩0.7重量部含有)添加した。
(2)比較1
80℃のお湯100重量部に、食塩0.7重量部を加えて攪拌して5分間静置した。
(3)比較2
80℃のお湯100重量部に、食塩0.7重量部と増粘多糖類等を加えて攪拌して5分静置した。増粘多糖類等の添加量は、食塩組成物に含まれる増粘多糖類等の量に従った。例えば、食塩組成物5の評価に際しては、タマリンドガムを0.35重量部添加した。
(Saltiness evaluation)
The following three evaluation samples (standard, comparison 1, and comparison 2) were prepared for each salt composition.
(1) A salt composition was added to 100 parts by weight of standard 80°C hot water, stirred, and allowed to stand for 5 minutes. The amount of the salt composition added was adjusted so that the amount of salt added was 0.7 parts by weight. For example, when evaluating the salt composition 5, 0.735 parts by weight of the salt composition 5 (containing 0.7 parts by weight of salt) was added.
(2) Comparison 1
0.7 parts by weight of common salt was added to 100 parts by weight of 80°C hot water, stirred, and allowed to stand for 5 minutes.
(3) Comparison 2
0.7 parts by weight of common salt, polysaccharide thickener, etc. were added to 100 parts by weight of 80°C hot water, stirred, and allowed to stand for 5 minutes. The amount of polysaccharide thickener etc. added was in accordance with the amount of polysaccharide thickener etc. contained in the salt composition. For example, when evaluating salt composition 5, 0.35 parts by weight of tamarind gum was added.
上記の評価用サンプルを用いて、熟練したパネラー20名が塩味を評価した。表2中の人数は、最も塩味が強いと評価したパネラーの人数である。 Twenty experienced panelists evaluated the salty taste using the above evaluation samples. The number of people in Table 2 is the number of panelists who rated the salty taste as the strongest.
(異味評価)
上記の評価用サンプル(標準、比較1)を用いて、熟練したパネラー20名が食塩組成物ごとに異味(エグ味、苦味)を評価した。評価基準は以下の通りである。
○:食塩のみのサンプル(比較1)と比べて、異味が強いと評価したパネラーが2名以下
△:食塩のみのサンプル(比較1)と比べて、異味が強いと評価したパネラーが3名以上、10名以下
×:食塩のみのサンプル(比較1)と比べて、異味が強いと評価したパネラーが11名以上
(Off taste evaluation)
Using the above evaluation samples (standard, comparison 1), 20 experienced panelists evaluated the off-taste (aggressive taste, bitterness) for each salt composition. The evaluation criteria are as follows.
○: Less than 2 panelists rated the sample as having a stronger off-taste compared to the salt-only sample (Comparison 1) △: 3 or more panelists rated the off-taste as strong compared to the salt-only sample (Comparison 1) , 10 or less ×: 11 or more panelists rated the sample as having a stronger off-taste compared to the salt-only sample (comparison 1)
なお、表3では塩味の評価を以下のように簡略化して表記した。
○:食塩組成物を用いた評価用サンプル(標準)が最も塩味が強いと評価したパネラーが16名以上
△:食塩組成物を用いた評価用サンプル(標準)が最も塩味が強いと評価したパネラーが11名以上、15名以下
×:食塩組成物を用いた評価用サンプル(標準)が最も塩味が強いと評価したパネラーが10名以下
In addition, in Table 3, the evaluation of salty taste is simplified as follows.
○: 16 or more panelists evaluated that the evaluation sample (standard) using the salt composition was the saltiest. △: Panelists evaluated that the evaluation sample (standard) using the salt composition was the saltiest. 11 or more, 15 or less ×: 10 or less panelists evaluated that the evaluation sample (standard) using the salt composition was the saltiest.
食塩組成物5、8と、食塩組成物R5、R8について、熟練したパネラー20名が塩味を比較することにより、製法の違いによる塩味の変化を評価した。塩味評価用の水溶液は、前記の「標準:80℃のお湯100重量部に、食塩組成物を加えて攪拌して5分間静置」と同じ条件で調整した。 Twenty experienced panelists compared the salty tastes of Salt Compositions 5 and 8 and Salt Compositions R5 and R8 to evaluate changes in salty taste due to differences in manufacturing methods. The aqueous solution for saltiness evaluation was prepared under the same conditions as the above-mentioned "Standard: Add the salt composition to 100 parts by weight of 80°C hot water, stir and let stand for 5 minutes."
食塩組成物5、11.12を比較することで、塩味を強化するには増粘多糖類が必須であることがわかる。 By comparing salt compositions 5 and 11.12, it can be seen that polysaccharide thickener is essential to enhance the salty taste.
また、食塩組成物1~7を比較することにより、塩味を強化するには増粘多糖類を少なくとも3重量%以上添加する必要があり、4重量%以上が好ましいことがわかる。また、増粘多糖類を10重量%以上加えると異味が強まってしまうこともわかる。 Further, by comparing the salt compositions 1 to 7, it can be seen that in order to enhance the salty taste, it is necessary to add at least 3% by weight of polysaccharide thickener, and 4% by weight or more is preferable. It can also be seen that adding 10% by weight or more of thickening polysaccharide intensifies the off-taste.
また、食塩組成物5、8~10を比較することで、タマリンドガムとアラビアガムの異味が弱く、より好適であることがわかる。 Furthermore, by comparing salt compositions 5, 8 to 10, it can be seen that the off-flavors of tamarind gum and gum arabic are weaker and are more suitable.
食塩組成物5、8とR5,R8を比較すること、噴霧乾燥により得られる食塩組成物では、スープのような用途で塩味を強化することはできないことがわかる。 Comparing salt compositions 5 and 8 with R5 and R8, it can be seen that the salt compositions obtained by spray drying cannot enhance the salty taste in applications such as soups.
Claims (1)
食塩と増粘多糖類とを含む水溶液を調整する工程と、
該水溶液を真空乾燥する工程と、を含み、
増粘多糖類がタマリンドガム又はアラビアガムであって、
食塩100重量部に対して、増粘多糖類を3~10重量部含むことを特徴とする食塩組成物の製造方法。 A method for producing a salt composition containing salt and a thickening polysaccharide, comprising:
preparing an aqueous solution containing salt and a thickening polysaccharide;
and drying the aqueous solution under vacuum.
The thickening polysaccharide is tamarind gum or gum arabic,
A method for producing a salt composition, comprising the steps of: (a) preparing a salt composition comprising 3 to 10 parts by weight of a thickening polysaccharide per 100 parts by weight of salt;
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