JP7456835B2 - Aqueous stripper composition - Google Patents
Aqueous stripper composition Download PDFInfo
- Publication number
- JP7456835B2 JP7456835B2 JP2020066368A JP2020066368A JP7456835B2 JP 7456835 B2 JP7456835 B2 JP 7456835B2 JP 2020066368 A JP2020066368 A JP 2020066368A JP 2020066368 A JP2020066368 A JP 2020066368A JP 7456835 B2 JP7456835 B2 JP 7456835B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- weight
- carbon atoms
- aliphatic
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 43
- 125000001931 aliphatic group Chemical group 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 8
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 8
- YRHYCMZPEVDGFQ-UHFFFAOYSA-N methyl decanoate Chemical compound CCCCCCCCCC(=O)OC YRHYCMZPEVDGFQ-UHFFFAOYSA-N 0.000 claims description 6
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 4
- 239000005640 Methyl decanoate Substances 0.000 claims description 3
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 3
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 3
- 229940073769 methyl oleate Drugs 0.000 claims description 3
- -1 sulfate ester salts Chemical class 0.000 description 57
- 239000003973 paint Substances 0.000 description 26
- 230000000694 effects Effects 0.000 description 15
- 229920006395 saturated elastomer Polymers 0.000 description 15
- 238000000576 coating method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- 239000001993 wax Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000011054 acetic acid Nutrition 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 3
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 3
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical class OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 3
- 235000019445 benzyl alcohol Nutrition 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000001913 cellulose Chemical class 0.000 description 3
- 229920002678 cellulose Chemical class 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical class OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- YUFFSWGQGVEMMI-JLNKQSITSA-N (7Z,10Z,13Z,16Z,19Z)-docosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCCCC(O)=O YUFFSWGQGVEMMI-JLNKQSITSA-N 0.000 description 2
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 2
- QYGBYAQGBVHMDD-XQRVVYSFSA-N (z)-2-cyano-3-thiophen-2-ylprop-2-enoic acid Chemical compound OC(=O)C(\C#N)=C/C1=CC=CS1 QYGBYAQGBVHMDD-XQRVVYSFSA-N 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- PKBSGDQYUYBUDY-UHFFFAOYSA-N 1-nonacosanol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCO PKBSGDQYUYBUDY-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 2
- PFNHSEQQEPMLNI-UHFFFAOYSA-N 2-methyl-1-pentanol Chemical compound CCCC(C)CO PFNHSEQQEPMLNI-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- IWTBVKIGCDZRPL-UHFFFAOYSA-N 3-methylpentanol Chemical compound CCC(C)CCO IWTBVKIGCDZRPL-UHFFFAOYSA-N 0.000 description 2
- FCOUHTHQYOMLJT-UHFFFAOYSA-N 6-methylheptan-2-ol Chemical compound CC(C)CCCC(C)O FCOUHTHQYOMLJT-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 235000021294 Docosapentaenoic acid Nutrition 0.000 description 2
- 235000021292 Docosatetraenoic acid Nutrition 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- MBMBGCFOFBJSGT-KUBAVDMBSA-N all-cis-docosa-4,7,10,13,16,19-hexaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCC(O)=O MBMBGCFOFBJSGT-KUBAVDMBSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- HOWGUJZVBDQJKV-UHFFFAOYSA-N docosane Chemical compound CCCCCCCCCCCCCCCCCCCCCC HOWGUJZVBDQJKV-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- CKDDRHZIAZRDBW-UHFFFAOYSA-N henicosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCC(O)=O CKDDRHZIAZRDBW-UHFFFAOYSA-N 0.000 description 2
- ULCZGKYHRYJXAU-UHFFFAOYSA-N heptacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCO ULCZGKYHRYJXAU-UHFFFAOYSA-N 0.000 description 2
- BJQWYEJQWHSSCJ-UHFFFAOYSA-N heptacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCC BJQWYEJQWHSSCJ-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- NDJKXXJCMXVBJW-UHFFFAOYSA-N heptadecane Chemical compound CCCCCCCCCCCCCCCCC NDJKXXJCMXVBJW-UHFFFAOYSA-N 0.000 description 2
- HOZOFMIVACKJMX-UHFFFAOYSA-N heptadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCC(O)O HOZOFMIVACKJMX-UHFFFAOYSA-N 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 2
- HMSWAIKSFDFLKN-UHFFFAOYSA-N hexacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC HMSWAIKSFDFLKN-UHFFFAOYSA-N 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 229960002163 hydrogen peroxide Drugs 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- SIOLDWZBFABPJU-UHFFFAOYSA-N isotridecanoic acid Chemical compound CC(C)CCCCCCCCCC(O)=O SIOLDWZBFABPJU-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- QHKIWQPIFXRUOW-UHFFFAOYSA-N tetracosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCN QHKIWQPIFXRUOW-UHFFFAOYSA-N 0.000 description 1
- ZAYKUYSGARCXKQ-UHFFFAOYSA-N tetracosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(N)=O ZAYKUYSGARCXKQ-UHFFFAOYSA-N 0.000 description 1
- PMBKSTOGTODXJZ-UHFFFAOYSA-N tetracosane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(O)O PMBKSTOGTODXJZ-UHFFFAOYSA-N 0.000 description 1
- QZZGJDVWLFXDLK-UHFFFAOYSA-N tetracosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(O)=O QZZGJDVWLFXDLK-UHFFFAOYSA-N 0.000 description 1
- ARZGWBJFLJBOTR-UHFFFAOYSA-N tetradecanamide Chemical compound CCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCC(N)=O ARZGWBJFLJBOTR-UHFFFAOYSA-N 0.000 description 1
- CQTBQILMJBCTRS-UHFFFAOYSA-N tetradecane-1,1-diol Chemical compound CCCCCCCCCCCCCC(O)O CQTBQILMJBCTRS-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- HOGWBMWOBRRKCD-BUHFOSPRSA-N trans-2-pentadecenoic acid Chemical compound CCCCCCCCCCCC\C=C\C(O)=O HOGWBMWOBRRKCD-BUHFOSPRSA-N 0.000 description 1
- UWHZIFQPPBDJPM-BQYQJAHWSA-N trans-vaccenic acid Chemical compound CCCCCC\C=C\CCCCCCCCCC(O)=O UWHZIFQPPBDJPM-BQYQJAHWSA-N 0.000 description 1
- WFLJHDLVVWUGGZ-UHFFFAOYSA-N triacontan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCN WFLJHDLVVWUGGZ-UHFFFAOYSA-N 0.000 description 1
- OLTHARGIAFTREU-UHFFFAOYSA-N triacontane Natural products CCCCCCCCCCCCCCCCCCCCC(C)CCCCCCCC OLTHARGIAFTREU-UHFFFAOYSA-N 0.000 description 1
- ZUDWINGCBFUXNG-UHFFFAOYSA-N tridecane-1,1-diol Chemical compound CCCCCCCCCCCCC(O)O ZUDWINGCBFUXNG-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- GRXOWOKLKIZFNP-UHFFFAOYSA-N undecane-1,1-diol Chemical compound CCCCCCCCCCC(O)O GRXOWOKLKIZFNP-UHFFFAOYSA-N 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Description
本発明は、環境負荷が小さく、優れた剥離効果及び剥離効果の持続性に優れた水性剥離剤組成物に関する。 TECHNICAL FIELD The present invention relates to an aqueous stripping agent composition that has a small environmental impact and has excellent peeling effects and long-lasting peeling effects.
建築物、土木構造物等の表面に形成された塗膜(旧塗膜)を塗り替える方法として、旧塗膜の上に新しい塗料を塗装する方法、または、旧塗膜を一旦剥離し新しい塗料を塗装する方法等が挙げられる。従来コストや工期短縮等の面から旧塗膜に上に新しい塗料を塗装する方法で塗り替える場合が多く、現在旧塗膜の上に2回ないし3回以上塗り重ねた建築物、土木構造物は数多く存在する。 As a method of repainting the paint film (old paint film) formed on the surface of buildings, civil engineering structures, etc., there is a method of painting a new paint on top of the old paint film, or a method of removing the old paint film and applying a new paint. Examples include a method of painting. Conventionally, in order to reduce cost and construction time, new paint is often applied on top of the old paint film, and currently buildings and civil engineering structures that have been painted over the old paint film two or three times or more are There are many.
しかし、既に劣化した旧塗膜の上に新しい塗料を何重にも塗り重ねると、塗膜自体が重くなり基材に負荷を与える恐れがある。また塗膜自体の厚みが厚くなりすぎ空間を圧迫してしまう場合もある。さらに近年では高機能性塗膜が登場し、塗膜の上に新しい塗料を塗装すること自体が難しい場合もある。 However, if multiple layers of new paint are applied over an old paint film that has already deteriorated, the paint film itself becomes heavy and there is a risk of putting a load on the base material. Moreover, the thickness of the coating film itself may become too thick, compressing the space. Furthermore, in recent years, highly functional paint films have appeared, and it may be difficult to apply new paint on top of the paint film itself.
このような問題から、最近では旧塗膜を一旦剥離する方法が多くなってきている。
旧塗膜を剥離する方法としては、サンダー処理、ブラスト処理、高圧水噴射、タガネハツリ等の物理的手法、薬剤、溶剤を利用した化学的手法等が挙げられるが、最近では、下地損傷、粉塵飛散等の問題、環境配慮等の観点から、水性剥離剤を利用した化学的手法が用いられるようになっている。(例えば、特許文献1等)
Due to these problems, recently there has been an increase in the number of methods in which the old paint film is temporarily peeled off.
Methods for removing old paint include physical methods such as sanding, blasting, high-pressure water jetting, and chisel chisel, and chemical methods using chemicals and solvents. Chemical methods using water-based stripping agents have come to be used from the viewpoint of environmental considerations and other problems. (For example, Patent Document 1, etc.)
このような水性剥離剤は、水、ベンジルアルコールを基本組成とし、さらに、溶剤や乳化剤を含有させることにより、水とベンジルアルコールを効率よく相溶、分散させることにより、優れた剥離性能を得ることができる。
例えば特許文献1では、水、ベンジルアルコールにさらに極性非プロトン溶剤を加えて可溶化させる方法が記載されている。
しかし、特許文献1の方法では、剥離効果、剥離効果の持続性に劣る場合があり、改善の余地がある。
Such a water-based stripping agent has a basic composition of water and benzyl alcohol, and further contains a solvent and an emulsifier to efficiently dissolve and disperse water and benzyl alcohol, thereby obtaining excellent stripping performance. Can be done.
For example, Patent Document 1 describes a method of solubilizing water and benzyl alcohol by further adding a polar aprotic solvent.
However, in the method of Patent Document 1, the peeling effect and the sustainability of the peeling effect may be poor, and there is room for improvement.
本発明はこのような課題に鑑みなされたもので、(A)水、(B)芳香族アルコールに、さらに、(C)炭素数6以上30以下のアルキル基とオキシアルキレン単位を有する界面活性剤と、(D)芳香族溶媒及び/または(E)炭素数6以上30以下の脂肪族溶媒を含有することにより、剥離効果及び剥離効果の持続性に優れていることを見出し、本発明の完成に至った。 The present invention was made in view of these problems, and includes (A) water, (B) an aromatic alcohol, and (C) a surfactant having an alkyl group having 6 to 30 carbon atoms and an oxyalkylene unit. and (D) an aromatic solvent and/or (E) an aliphatic solvent having 6 to 30 carbon atoms, it has been found that the peeling effect and the sustainability of the peeling effect are excellent, and the present invention has been completed. reached.
すなわち、本発明は、以下の特徴を有するものである。
1.(A)水25重量%以上70重量%以下、
(B)芳香族アルコール20重量%以上70重量%以下、
を含む水性剥離剤組成物であって、さらに、
(C)炭素数6以上30以下のアルキル基とオキシアルキレン単位を有する界面活性剤0.1重量%以上10重量%以下、
(D)芳香族溶媒0.1重量%以上10重量%以下及び(E)炭素数6以上30以下の脂肪族溶媒0.5重量%以上10重量%以下、
を含有し、
該(E)炭素数6以上30以下の脂肪族溶媒が、ノナン、オクタデカノール、エルカ酸アミド、ヘキサデカノール、オクタノール、デカン酸メチル、オレイン酸メチルから選ばれる1種以上を含有する、
ことを特徴とする水性剥離剤組成物。
That is, the present invention has the following features.
1. (A) Water 25% by weight or more and 70% by weight or less ,
(B) aromatic alcohol 20% by weight or more and 70% by weight or less ,
An aqueous stripper composition comprising:
(C) a surfactant having an alkyl group having 6 to 30 carbon atoms and an oxyalkylene unit from 0.1% by weight to 10% by weight ;
(D) aromatic solvent 0.1% to 10% by weight; (E) aliphatic solvent having 6 to 30 carbon atoms 0.5% to 10% by weight ;
Contains
(E) the aliphatic solvent having 6 to 30 carbon atoms contains one or more selected from nonane, octadecanol, erucic acid amide, hexadecanol, octanol, methyl decanoate, and methyl oleate;
An aqueous stripping agent composition characterized by:
本発明の水性剥離剤組成物は、環境負荷が小さく、優れた剥離効果及び剥離効果の持続性に優れている。 The aqueous stripping agent composition of the present invention has a small environmental impact, and has excellent stripping effect and durability of the stripping effect.
以下、本発明を実施するための形態について説明する。 EMBODIMENT OF THE INVENTION Hereinafter, the form for implementing this invention is demonstrated.
本発明の水性剥離剤組成物は、(A)水(以下、「(A)成分」ともいう。)、(B)芳香族アルコール(以下、「(B)成分」ともいう。)とともに、(C)炭素数6以上30以下のアルキル基とオキシアルキレン単位を有する界面活性剤(以下、「(C)成分」ともいう。)と、(D)芳香族溶媒(以下、「(D)成分」ともいう。)及び/または(E)炭素数6以上30以下の脂肪族溶媒(以下、「(E)成分」ともいう。)を含むことを特徴とするものである。 The aqueous stripping agent composition of the present invention contains (A) water (hereinafter also referred to as "component (A)"), (B) aromatic alcohol (hereinafter also referred to as "component (B)"), ( C) a surfactant having an alkyl group having 6 to 30 carbon atoms and an oxyalkylene unit (hereinafter also referred to as "component (C)"), and (D) an aromatic solvent (hereinafter "component (D)") ) and/or (E) an aliphatic solvent having 6 to 30 carbon atoms (hereinafter also referred to as "component (E)").
本発明で用いる(B)成分は、例えば、ベンジルアルコール、フェニルエチルアルコール、ナフトール等が挙げられる。本発明では特に、ベンジルアルコールを用いることが好ましい。
このような(B)成分と(A)成分を混合することで、優れた水性の剥離剤を得ることができる。
Examples of the component (B) used in the present invention include benzyl alcohol, phenylethyl alcohol, and naphthol. In the present invention, it is particularly preferable to use benzyl alcohol.
By mixing such components (B) and (A), an excellent aqueous release agent can be obtained.
本発明で用いる(C)成分は、炭素数6以上30以下(好ましくは炭素数8以上24以下)のアルキル基とオキシアルキレン単位を有する界面活性剤で、例えば、ポリオキシアルキレンアルキルエーテルあるいは、その硫酸塩、硫酸エステル塩、スルホン酸塩、スルホン酸エステル塩、コハク酸塩、コハク酸エステル塩等が挙げられ、これらのうち1種または2種以上を使用できる。
また、ポリオキシアルキレンアルキルエーテルの具体例としては、ポリオキシエチレンノニルフェニルエーテル、ポリオキシエチレンオクチルフェニルエーテル、ポリオキシエチレンジステアレート、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンフェニルエーテル、ポリオキシエチレントリデシルエーテル、ポリオキシエチレンデシルエーテル、ポリオキシエチレンオクチルドデシルエーテル等が挙げられる。また、オキシアルキレン単位としては、オキシエチレン単位、オキシプロピレン単位等が挙げられ、繰り返し単位が6以上50以下、好ましくは8以上30以下であること好ましい。
このような(C)成分は、(A)成分と(B)成分の乳化分散体を形成し、(B)成分の分散安定性を高めることができる。また後述する(D)成分、(E)成分とともに混合することで、剥離効果、剥離効果の持続性に優れた剥離剤を得ることができる。
The component (C) used in the present invention is a surfactant having an alkyl group having 6 to 30 carbon atoms (preferably having 8 to 24 carbon atoms) and an oxyalkylene unit, and examples thereof include polyoxyalkylene alkyl ethers, or their sulfates, sulfate ester salts, sulfonates, sulfonate ester salts, succinates, and succinate ester salts, and one or more of these may be used.
Specific examples of polyoxyalkylene alkyl ethers include polyoxyethylene nonylphenyl ether, polyoxyethylene octylphenyl ether, polyoxyethylene distearate, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene alkyl ether, polyoxyethylene phenyl ether, polyoxyethylene tridecyl ether, polyoxyethylene decyl ether, polyoxyethylene octyldodecyl ether, etc. Examples of oxyalkylene units include oxyethylene units and oxypropylene units, and the number of repeating units is preferably 6 to 50, and more preferably 8 to 30.
Such component (C) can form an emulsion dispersion of components (A) and (B) and can enhance the dispersion stability of component (B). By mixing component (C) with components (D) and (E) described below, a release agent having excellent release effect and durability of the release effect can be obtained.
本発明で用いる(D)成分は、例えば、トルエン、キシレン、ベンゼン、エチルベンゼン、クメン、トリメチルベンゼン、ナフタレン、クロロベンゼン、ジクロロベンゼン、ベンジルフェニルエーテル、ベンジルメチルエーテル、ジベンジルエーテル、ジフェニルエーテル等が挙げられ、これらのうち1種または2種以上を使用できる。
このような(D)成分は、特に剥離効果の向上が期待できる成分である。また(D)成分は、特に(B)成分と相溶しやすく、(B)成分と(D)成分の相乗効果により、より優れた剥離効果を得ることができる。
Component (D) used in the present invention includes, for example, toluene, xylene, benzene, ethylbenzene, cumene, trimethylbenzene, naphthalene, chlorobenzene, dichlorobenzene, benzyl phenyl ether, benzyl methyl ether, dibenzyl ether, diphenyl ether, etc. One or more of these can be used.
Such component (D) is a component that can be expected to particularly improve the peeling effect. In addition, component (D) is particularly easily compatible with component (B), and the synergistic effect of component (B) and component (D) can provide a better peeling effect.
本発明で用いる(E)成分は、炭素数6以上30以下(好ましくは炭素数8以上24以下、より好ましくは炭素数10以上22以下、さらに好ましくは炭素数12以上20以下)の脂肪族溶媒で、特に剥離効果の持続性の向上が期待できる成分である。また(E)成分は、特に(C)成分と相溶しやすく、上記(B)成分(または(D)成分)の分散安定性を高める効果も有する。
(E)成分としては、例えば、次に例示するもの等が挙げられ、これらのうち1種または2種以上を使用できる。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族炭化水素
例えば、ヘキサン、オクタン、ノナン、デカン、ウンデカン、ドデカン、トリデカン、ペンタデカン、テトラデカン、ヘキサデカン、ヘプタデカン、オクタデカン、ノナデカン、エイコサン、ドコサン、トリコサン、テトラコサン、ペンタコサン、ヘキサコサン、ヘプタコサン、オクタコサン、ノナコサン、トリアコンタン等が挙げられ、特に、直鎖状の飽和脂肪族炭化水素等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族モノアルコール
第一級、第二級、第三級等特に限定されないが、例えば、ヘキサノール、ヘプタノール、オクタノール、ノナノール、デカノール、ウンデカノール、ドデカノール、トリデカノール、テトラデカノール、ペンタデカノール、ヘキサデカノール、ヘプタデカノール、オクタデカノール、ノナデカノール、エイコサノール、ヘンイコサノール、ドコサノール、トリコサノール、テトラコサノール、ペンタコサノール、ヘキサコサノール、ヘプタコサノール、オクタコサノール、ノナコサノール、トリアコンタノール、オレイルアルコール、リノレイルアルコール、パルミトレイルアルコール 、エライジルアルコール、エライドリノレイルアルコール、リノレニルアルコール、エライドリノレニルアルコール、エルシルアルコール、イソヘキサノール、2-メチル-1-ペンタノール、3-メチル-1-ペンタノール、2-エチル-1-ブタノール、3,3-ジメチル-1-ブタノール、イソヘプタノール、4-メチル-1-ヘキサノール、3-メチル-1-ヘキサノール、2-エチル-2-メチル-1-ブタノール、イソオクタノール、2-エチルヘキサノール、6-メチル-2-ヘプタノール、イソノナノール、3,5,5-トリメチルヘキサノール、イソデカノール、イソウンデカノール、イソドデカノール、2-ブチルオクタノール、イソトリデカノール、イソテトラデカノール、イソペンタデカノール、2-ヘキシルデカノール、イソヘキサデカノール、2-ヘキシルデカノール、イソヘプタデカノール、イソオクタデカノール、2-イソヘプチルイソウンデカノール、イソノナデカノール、イソエイコサノール、2-オクチルドデカノール、イソヘンエイコサノール、18-メチルエイコサノール、イソドコサノール、イソトリコサノール、イソテトラコサノール、2-デシルテトラデカノール、イソペンタコサノール、イソヘキサコサノール、イソヘプタコサノール、イソオクタコサノール、イソノナコサノール、イソトリアコンタノール等が挙げられ、特に、直鎖状の第一級飽和脂肪族脂肪族モノアルコール等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族ジアルコール
例えば、ヘキサンジオール、ヘプタンジオール、オクタンジオール、ノナンジオール、デカンジオール、ウンデカンジオール、ドデカンジオール、トリデカンジオール、テトラデカンジオール、ペンタデカンジオール、ヘキサデカンジオール、ヘプタデカンジオール、オクタデカンジオール、ノナデカンジオール、エイコサンジオール、ヘンイコサンジオール、ドコサンジオール、トリコサンジオール、テトラコサンジオール、ペンタコサンジオール、ヘキサコサンジオール、ヘプタコサンジオール、オクタコサンジオール、ノナコサンジオール、トリアコサンジオール、リシノレイルアルコール等が挙げられ、特に、直鎖状の飽和脂肪族ジアルコール等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族モノカルボン酸
例えば、ヘキサン酸、ヘプタン酸、オクタン酸、デカン酸、ウンデカン酸、ドデカン酸、トリデカン酸、テトラデカン酸、ペンタデカン酸、ヘキサデカン酸、ヘプタデカン酸 、オクタデカン酸、ノナデカン酸、イコサン酸、ヘンイコサン酸、ドコサン酸、トリコサン酸、テトラコサン酸、ペンタコサン酸、ヘキサコサン酸、ヘプタコサン酸、オクタコサン酸、ノナコサン酸、トリアコンタン酸、サピエン酸、オレイン酸、エイコセン酸、エルカ酸、ネルボン酸、パルミトレイン酸、バクセン酸、パウリン酸、ミード酸、リノール酸、γ-リノレン酸、ピノレン酸、エイコサジエン酸、ジホモ-γ-リノレン酸、アラキドン酸、ドコサジエン酸、ドコサテトラエン酸、アドレン酸、ドコサペンタエン酸、オズボンド酸、α-リノレン酸、ステアリドン酸、エイコサトリエン酸、エイコサテトラエン酸、エイコサペンタエン酸、ドコサペンタエン酸、ドコサヘキサエン酸、テトラコサペンタエン酸、テトラコサヘキサエン酸、リシノール酸、ミリストレイン酸、ペンタデセン酸、ヘプタデセン酸、ペトロセリン酸、エレオステアリン酸、ボセオペンタエン酸、ガドレイン酸、エチルヘキサン酸、ネオデカン酸、イソトリデカン酸、イソテトラデカン酸、イソペンタデカン酸、イソヘキサデカン酸、2-ヘキシルデカン酸、イソヘプタデカン酸、イソオクタデカン酸、イソノナデカン酸、イソエイコサン酸、2-オクチルドデカン酸、2-デシルテトラデカン酸等が挙げられ、特に、直鎖状の飽和あるいは不飽和脂肪族モノカルボン酸等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族ジカルボン酸
例えば、ヘキサン二酸、ヘプタン二酸、オクタン二酸、ノナン二酸、デカン二酸等が挙げられ、特に直鎖状の飽和脂肪族ジカルボン酸等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族モノエステル
例えば、上記炭素数6以上30以下の脂肪族モノカルボン酸とアルコールの反応生成物である脂肪族モノエステル、あるいは、上記炭素数6以上30以下の脂肪族モノアルコールとカルボン酸の反応生成物である脂肪族モノエステル等が挙げられる。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族ジエステル
例えば、上記炭素数6以上30以下の脂肪族ジカルボン酸とアルコールの反応生成物である脂肪族ジエステル、あるいは、上記炭素数6以上30以下の脂肪族ジアルコールとカルボン酸の反応生成物である脂肪族ジエステル等が挙げられる。
なお、脂肪族モノエステル、脂肪族ジエステルの生成で使用されるアルコールとしては、上記脂肪族モノアルコール、あるいはメタノール、エタノール、プロパノール、ブタノール、ペンタノールから選ばれる1種以上が挙げられる。また、カルボン酸としては、上記脂肪族モノカルボン酸、あるいはメタン酸、エタン酸、プロパン酸、ブタン酸、ペンタン酸から選ばれる1種以上が挙げられる。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族エーテル
例えば、ヘプチルエーテル、オクチルエーテル、テトラデシルエーテル、ヘキサデシルエーテル等が挙げられ、特に、直鎖状の飽和脂肪族エーテル等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族ケトン
例えば、メチルイソブチルケトン、ジイソブチルケトン、ヘプタノン、シクロヘキサノン、シクロヘプタノン、シクロオクタノン、イソホロン等が挙げられ、特に、直鎖状の飽和脂肪族ケトン等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族モノアミン
例えば、ヘキシルアミン、ヘプチルアミン、オクチルアミン、エチルヘキシルアミン、デシルアミン、ドデシルアミン、テトラデシルアミン、ヘキサデシルアミン、オクタデシルアミン、イコシルアミン、ドコシルアミン、テトラコシルアミン、ペンタコシルアミン、ヘキサコシルアミン、ヘプタコシルアミン、オクタコシルアミン、ノナコシルアミン、トリアコンチルアミン、オレイルアミン、リノレイルアミン、エルカアミン、リシノレイルアミン等が挙げられ、特に、直鎖状の飽和脂肪族モノアミン等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族ジアミン
例えば、ヘキシルジアミン、ヘプチルジアミン、オクタンジアミン、デカンジアミン、ドデカンジアミン等が挙げられ、特に、直鎖状の飽和脂肪族ジアミン等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族モノアミド
例えば、ヘキサンアミド、ヘプタンアミド、オクタンアミド、デカンアミド、ドデカンアミド、テトラデカンアミド、ヘキサデカンアミド、オクタデカンアミド、イコサンアミド、ドコサンアミド、テトラコサンアミド、オレイン酸アミド、リノール酸アミド、リノレン酸アミド、アラキドン酸アミド、エルカ酸アミド等、また、上記炭素数6以上30以下の脂肪族モノカルボン酸とアミンの反応生成物である脂肪族モノアミド等が挙げられ、特に、直鎖状の飽和脂肪族モノアミド等が好ましい。
・炭素数6以上30以下の直鎖状、分岐状の飽和、不飽和脂肪族ジアミド
例えば、上記炭素数6以上30以下の脂肪族ジカルボン酸とアミンの反応生成物である脂肪族ジアミド等が挙げられ、特に、直鎖状の飽和脂肪族ジアミド等が好ましい。
なお、脂肪族モノアミド、脂肪族ジアミドの生成で使用されるアミンとしては、例えば、上記脂肪族モノアミン、あるいは、メチルアミン、エチルアミン、プロピルアミン、ブチルアミン、ペンチルアミンから選ばれる1種以上が挙げられる。
Component (E) used in the present invention is an aliphatic solvent having 6 to 30 carbon atoms (preferably 8 to 24 carbon atoms, more preferably 10 to 22 carbon atoms, even more preferably 12 to 20 carbon atoms). In particular, it is a component that can be expected to improve the sustainability of the peeling effect. In addition, component (E) is particularly easily compatible with component (C), and also has the effect of increasing the dispersion stability of component (B) (or component (D)).
Examples of the component (E) include those listed below, and one or more of these can be used.
- Straight chain, branched, saturated or unsaturated aliphatic hydrocarbons having 6 to 30 carbon atoms, such as hexane, octane, nonane, decane, undecane, dodecane, tridecane, pentadecane, tetradecane, hexadecane, heptadecane, octadecane, nonadecane , eicosane, docosane, tricosane, tetracosane, pentacosane, hexacosane, heptacosane, octacosane, nonacosane, triacontane, etc., and linear saturated aliphatic hydrocarbons are particularly preferred.
- Linear, branched, saturated, unsaturated aliphatic monoalcohols having 6 to 30 carbon atoms, including but not limited to primary, secondary, and tertiary alcohols, such as hexanol, heptanol, octanol, nonanol, Decanol, undecanol, dodecanol, tridecanol, tetradecanol, pentadecanol, hexadecanol, heptadecanol, octadecanol, nonadecanol, eicosanol, heniicosanol, docosanol, tricosanol, tetracosanol, pentacosanol, hexacosanol, Heptacosanol, octacosanol, nonacosanol, triacontanol, oleyl alcohol, linoleyl alcohol, palmitrail alcohol, elaidyl alcohol, elaidlinoleyl alcohol, linolenyl alcohol, elaidrinolenyl alcohol, erucyl alcohol, isohexanol, 2 -Methyl-1-pentanol, 3-methyl-1-pentanol, 2-ethyl-1-butanol, 3,3-dimethyl-1-butanol, isoheptanol, 4-methyl-1-hexanol, 3-methyl -1-hexanol, 2-ethyl-2-methyl-1-butanol, isooctanol, 2-ethylhexanol, 6-methyl-2-heptanol, isononanol, 3,5,5-trimethylhexanol, isodecanol, isoundecanol , isododecanol, 2-butyloctanol, isotridecanol, isotetradecanol, isopentadecanol, 2-hexyldecanol, isohexadecanol, 2-hexyldecanol, isoheptadecanol, isooctadecanol, 2- Isoheptyl isoundecanol, isononadecanol, isoeicosanol, 2-octyldodecanol, isoheneeicosanol, 18-methyleicosanol, isodocosanol, isotricosanol, isotetracosanol, Examples include 2-decyltetradecanol, isopentacosanol, isohexacosanol, isoheptacosanol, isooctacosanol, isononacosanol, isotriacontanol, etc. In particular, linear primary saturated aliphatic Aliphatic monoalcohols and the like are preferred.
- Linear, branched, saturated or unsaturated aliphatic dialcohols having 6 to 30 carbon atoms, such as hexanediol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol, Tetradecanediol, pentadecanediol, hexadecanediol, heptadecanediol, octadecanediol, nonadecanediol, eicosanediol, henicosanediol, docosanediol, tricosanediol, tetracosanediol, pentacosanediol, hexacosanediol, heptadecanediol Examples include cosanediol, octacosanediol, nonacosanediol, triacosanediol, ricinoleyl alcohol, and particularly preferred are linear saturated aliphatic dialcohols.
- Linear, branched, saturated or unsaturated aliphatic monocarboxylic acids having 6 to 30 carbon atoms, such as hexanoic acid, heptanoic acid, octanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, Pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, icosanoic acid, henicosanoic acid, docosanoic acid, tricosanoic acid, tetracosanoic acid, pentacosanoic acid, hexacosanoic acid, heptacanoic acid, octacosanoic acid, nonacosanoic acid, triacontanoic acid, sapien Acid, oleic acid, eicosenoic acid, erucic acid, nervonic acid, palmitoleic acid, vaccenic acid, paulic acid, mead acid, linoleic acid, γ-linolenic acid, pinolenic acid, eicosadienoic acid, dihomo-γ-linolenic acid, arachidonic acid, docosadienoic acid, docosatetraenoic acid, adrenic acid, docosapentaenoic acid, ozbond acid, α-linolenic acid, stearidonic acid, eicosatrienoic acid, eicosatetraenoic acid, eicosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, Tetracosapentaenoic acid, tetracosahexaenoic acid, ricinoleic acid, myristoleic acid, pentadecenoic acid, heptadenoic acid, petroselic acid, eleostearic acid, boseopentaenoic acid, gadoleic acid, ethylhexanoic acid, neodecanoic acid, isotridecanoic acid, iso Tetradecanoic acid, isopentadecanoic acid, isohexadecanoic acid, 2-hexyldecanoic acid, isoheptadecanoic acid, isooctadecanoic acid, isononadecanoic acid, isoeicosanoic acid, 2-octyldodecanoic acid, 2-decyltetradecanoic acid, etc., and especially linear Preferred are saturated or unsaturated aliphatic monocarboxylic acids.
- Linear or branched saturated or unsaturated aliphatic dicarboxylic acids having 6 to 30 carbon atoms Examples include hexanedioic acid, heptanedioic acid, octanedioic acid, nonanedioic acid, decanedioic acid, etc., especially Straight chain saturated aliphatic dicarboxylic acids and the like are preferred.
- Straight-chain, branched, saturated or unsaturated aliphatic monoesters having 6 to 30 carbon atoms For example, aliphatic monoesters that are reaction products of the above aliphatic monocarboxylic acids having 6 to 30 carbon atoms and alcohols. Alternatively, an aliphatic monoester, which is a reaction product of the above aliphatic monoalcohol having 6 to 30 carbon atoms and a carboxylic acid, may be mentioned.
- Linear, branched, saturated or unsaturated aliphatic diesters having 6 or more carbon atoms and 30 or less carbon atoms For example, aliphatic diesters that are the reaction products of the above aliphatic dicarboxylic acids having 6 or more carbon atoms and 30 or less carbon atoms, or Examples include aliphatic diesters which are reaction products of the above-mentioned aliphatic dialcohol having 6 to 30 carbon atoms and carboxylic acid.
The alcohol used in the production of the aliphatic monoester and aliphatic diester includes the aliphatic monoalcohols mentioned above, and one or more selected from methanol, ethanol, propanol, butanol, and pentanol. Further, examples of the carboxylic acid include the above-mentioned aliphatic monocarboxylic acids, or one or more selected from methanoic acid, ethanoic acid, propanoic acid, butanoic acid, and pentanoic acid.
- Linear, branched, saturated or unsaturated aliphatic ethers having 6 to 30 carbon atoms Examples include heptyl ether, octyl ether, tetradecyl ether, hexadecyl ether, etc. In particular, linear saturated aliphatic ethers Group ethers are preferred.
- Linear or branched saturated or unsaturated aliphatic ketones having 6 to 30 carbon atoms Examples include methyl isobutyl ketone, diisobutyl ketone, heptanone, cyclohexanone, cycloheptanone, cyclooctanone, isophorone, etc. , linear saturated aliphatic ketones, etc. are preferred.
- Straight chain, branched, saturated or unsaturated aliphatic monoamines having 6 to 30 carbon atoms, such as hexylamine, heptylamine, octylamine, ethylhexylamine, decylamine, dodecylamine, tetradecylamine, hexadecylamine, octadecyl Examples include amine, icosylamine, docosylamine, tetracosylamine, pentacosylamine, hexacosylamine, heptacosylamine, octacosylamine, nonacosylamine, triacontylamine, oleylamine, linoleylamine, erucamine, ricinoleylamine, etc. , linear saturated aliphatic monoamines, etc. are preferred.
- Linear, branched, saturated, unsaturated aliphatic diamines having 6 to 30 carbon atoms Examples include hexyldiamine, heptyldiamine, octanediamine, decanediamine, dodecanediamine, etc. In particular, linear saturated Aliphatic diamines and the like are preferred.
- Straight chain, branched, saturated or unsaturated aliphatic monoamides having 6 to 30 carbon atoms, such as hexaneamide, heptaneamide, octaneamide, decanamide, dodecanamide, tetradecanamide, hexadecaneamide, octadecaneamide, icosanamide, docosanamide , tetracosanamide, oleic acid amide, linoleic acid amide, linolenic acid amide, arachidonic acid amide, erucic acid amide, etc. Also, fats that are reaction products of the above aliphatic monocarboxylic acids having 6 to 30 carbon atoms and amines. Among them, linear saturated aliphatic monoamides are particularly preferred.
- Linear, branched, saturated or unsaturated aliphatic diamides having 6 or more carbon atoms and 30 or less carbon atoms Examples include aliphatic diamides that are reaction products of the above-mentioned aliphatic dicarboxylic acids having 6 or more carbon atoms and 30 or less carbon atoms, and amines. In particular, linear saturated aliphatic diamides are preferred.
The amines used in the production of aliphatic monoamides and aliphatic diamides include, for example, the aliphatic monoamines mentioned above, or one or more selected from methylamine, ethylamine, propylamine, butylamine, and pentylamine.
本発明では特に(E)成分として、炭素数6以上12以下(好ましくは炭素数8以上12以下)の脂肪族溶媒と、炭素数13以上30以下(好ましくは炭素数14以上24以下)の脂肪族溶媒を併用したものを用いることが好ましい。
また(E)成分として、脂肪族炭化水素、脂肪族モノアルコール、脂肪族モノエステル、脂肪族ジエステル、脂肪族モノアミド、脂肪族ジアミドから選ばれる1種以上を用いることが好ましく、特に、脂肪族炭化水素と、脂肪族モノエステル及び/または脂肪族ジエステルを併用したものを用いることが好ましい。
In the present invention, in particular, as component (E), an aliphatic solvent having 6 to 12 carbon atoms (preferably 8 to 12 carbon atoms) and a fat having 13 to 30 carbon atoms (preferably 14 to 24 carbon atoms) It is preferable to use a group solvent in combination.
In addition, as component (E), it is preferable to use one or more selected from aliphatic hydrocarbons, aliphatic monoalcohols, aliphatic monoesters, aliphatic diesters, aliphatic monoamides, and aliphatic diamides, particularly aliphatic carbonized It is preferable to use a combination of hydrogen and an aliphatic monoester and/or an aliphatic diester.
このような(A)成分、(B)成分、(C)成分、(D)成分、(E)成分の混合量は、特に限定されないが、剥離剤全量に対し、
(A)成分25重量%以上70重量%以下(好ましくは30重量%以上60重量%以下、より好ましくは35重量%以上50重量%以下)、
(B)成分20重量%以上70重量%以下(好ましくは25重量%以上65重量%以下、より好ましくは30重量%以上60重量%以下)、
(C)成分0.1重量%以上10重量%以下(好ましくは0.5重量%以上8重量%以下、より好ましくは1.0重量%以上6重量%以下)、
(D)成分0.1重量%以上10重量%以下(好ましくは0.5重量%以上5重量%以下)、
(E)成分0.5重量%以上10重量%以下(好ましくは1.5重量%以上8重量%以下)、
であることが好ましい。
The mixing amounts of such components (A), (B), (C), (D), and (E) are not particularly limited, but based on the total amount of the release agent,
(A) component 25% to 70% by weight (preferably 30% to 60% by weight, more preferably 35% to 50% by weight),
(B) component 20% by weight or more and 70% by weight or less (preferably 25% by weight or more and 65% by weight or less, more preferably 30% by weight or more and 60% by weight or less),
(C) component 0.1% to 10% by weight (preferably 0.5% to 8% by weight, more preferably 1.0% to 6% by weight),
(D) component 0.1% by weight or more and 10% by weight or less (preferably 0.5% by weight or more and 5% by weight or less),
(E) component 0.5% by weight or more and 10% by weight or less (preferably 1.5% by weight or more and 8% by weight or less),
It is preferable that
本発明の剥離剤組成物は、上記(A)成分、(B)成分、(C)成分、(D)成分、(E)成分の他に、例えば、増粘剤、酸化剤、還元剤、樹脂、ワックス、揮発防止剤、芳香剤、着色剤、染料等の添加剤を用いることもできる。 In addition to the components (A), (B), (C), (D), and (E), the release agent composition of the present invention includes, for example, a thickener, an oxidizing agent, a reducing agent, Additives such as resins, waxes, volatilization inhibitors, fragrances, colorants, dyes, and the like can also be used.
増粘剤としては、例えば、セピオライト、パリゴルスカイト、ベントナイト、モンモリロナイト、ヘクトライト、バイデライト、サポナイト、ノントロナイト、ボルコンスコアイト、ソーコナイト、スティーブンサイト、フルオロヘクトライト、ラポナイト、レクトナイト、バーミキュライト、イライト、マカタイト、カネマイト、イリエライト、マガディアイト、ケニヤアイト等の粘土鉱物、膨潤性シリカ、セルロースまたはセルロース誘導体、ポリアクリル酸重合体等を用いることができる。
増粘剤は、組成物全量に対し、0.1重量%以上20重量%以下、さらには0.5重量%以上15重量%以下含有することが好ましい。
Examples of thickeners include sepiolite, palygorskite, bentonite, montmorillonite, hectorite, beidellite, saponite, nontronite, volkonscoreite, sauconite, stevensite, fluorohectolite, laponite, rectonite, vermiculite, illite, and macatite. , clay minerals such as kanemite, illierite, magadiite, and kenyaite, swellable silica, cellulose or cellulose derivatives, polyacrylic acid polymers, and the like can be used.
The content of the thickener is preferably 0.1% by weight or more and 20% by weight or less, more preferably 0.5% by weight or more and 15% by weight or less, based on the total amount of the composition.
酸化剤としては、例えば、蟻酸、酢酸、酪酸、アクリル酸、シュウ酸、マロン酸、コハク酸、グルタル酸、フタル酸、マレイン酸、フマル酸、安息香酸、サリチル酸、ケイ皮酸、乳酸、リンゴ酸、クエン酸、酒石酸、アスコルビン酸、アスパラギン酸、アミノ安息香酸、アルギン酸、グリコール酸、グルコン酸、グルタミン酸、トルエンスルホン酸、ニコチン酸、尿酸、ハロゲン置換酢酸、ベンゼンスルホン酸、過酸化水素、過塩素酸塩、過ホウ酸塩等が挙げられる。 Examples of oxidizing agents include formic acid, acetic acid, butyric acid, acrylic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, phthalic acid, maleic acid, fumaric acid, benzoic acid, salicylic acid, cinnamic acid, lactic acid, and malic acid. , citric acid, tartaric acid, ascorbic acid, aspartic acid, aminobenzoic acid, alginic acid, glycolic acid, gluconic acid, glutamic acid, toluenesulfonic acid, nicotinic acid, uric acid, halogen-substituted acetic acid, benzenesulfonic acid, hydrogen peroxide, perchloric acid Examples include salts, perborates, and the like.
還元剤としては、例えば、水酸化ナトリウム、ポリリン酸ナトリウム、炭酸ナトリウム、水酸化カリウム、水酸化リチウム、水酸化カルシウム等が挙げられる。 Examples of the reducing agent include sodium hydroxide, sodium polyphosphate, sodium carbonate, potassium hydroxide, lithium hydroxide, and calcium hydroxide.
酸化剤、還元剤の混合量は、特に限定されないが、組成物全量に対し、その合計量が0.1重量%以上10重量%以下、さらには0.5重量%以上5重量%以下であることが好ましい。 The amount of the oxidizing agent and reducing agent mixed is not particularly limited, but the total amount is 0.1% by weight or more and 10% by weight or less, more preferably 0.5% by weight or more and 5% by weight or less, based on the total amount of the composition. It is preferable.
樹脂としては、例えば、酢酸ビニル樹脂、アクリル樹脂、ウレタン樹脂、ポリエステル樹脂等が挙げられ、本発明では特に酢酸ビニル樹脂、アクリル樹脂等の熱可塑性樹脂を用いることが好ましい。また、樹脂形態は、水可溶型、水分散型、溶剤可溶型、NAD型、自己乳化型、粉末型等特に限定されないが、水分散型、自己乳化型、粉末型等であることが好ましい。 Examples of the resin include vinyl acetate resin, acrylic resin, urethane resin, polyester resin, etc. In the present invention, it is particularly preferable to use thermoplastic resins such as vinyl acetate resin and acrylic resin. Further, the resin form is not particularly limited, such as water-soluble type, water-dispersible type, solvent-soluble type, NAD type, self-emulsifying type, powder type, etc., but may be water-dispersible type, self-emulsifying type, powder type, etc. preferable.
ワックスとしては、例えば、ポリエチレンワックス及びその誘導体、モンタンワックス及びその誘導体、パラフィンワックス及びその誘導体、マイクロクリスタリンワックス及びその誘導体、ペトロラタム、カルナバワックス、キャンデリラワックス、ライスワックス、木ロウ、ラノリン、みつろう、フィッシャー・トロプシュワックス等が挙げられ、液状または固形状特に限定されず、1種または2種以上を用いることができる。本発明では特に、ポリエチレンワックス、パラフィンワックスを用いることが好ましい。 Examples of the wax include polyethylene wax and its derivatives, montan wax and its derivatives, paraffin wax and its derivatives, microcrystalline wax and its derivatives, petrolatum, carnauba wax, candelilla wax, rice wax, wood wax, lanolin, beeswax, Examples include Fischer-Tropsch wax, and the wax is not particularly limited to liquid or solid form, and one or more types can be used. In the present invention, it is particularly preferable to use polyethylene wax and paraffin wax.
揮発防止剤としては、例えば、グリセリン、ブタントリオール、2-メチル-プロパントリオール、ペンタントリオール、2-メチル-ブタントリオール、トリメチロールエタン、ヘキサントリオール、2-エチル-ブタントリオール、トリメチロールプロパン、トリエタノールアミン、トリイソプロパノールアミン、ペンタエリスリトール、ペンタンテトロール、ヘキサンテトロール、ジグリセリン、ジトリメチロールプロパン、ソルビトール、アドニトール、アラビトール、キシリトール、トリグリセリン、ジペンタエリスリトール、ソルビトール、マンニトール、イジトール、イノシトール、ダルシトール、タロース、アロース、トリペンタエリスリトール、
トリメリット酸、ヘミメリット酸等のベンゼントリカルボン酸、ピロメリット酸等のベンゼンテトラカルボン酸、メリット酸等のベンゼンヘキサカルボン酸、シクロヘキサントリカルボン酸、
トリアミノトリエチルアミン、トリエチレンテトラミン、
ヘキサメチルリン酸トリアミド、
等が挙げられ、これらのうち1種または2種以上を使用できる。
Examples of the volatilization inhibitor include glycerin, butanetriol, 2-methyl-propanetriol, pentanetriol, 2-methyl-butanetriol, trimethylolethane, hexanetriol, 2-ethyl-butanetriol, trimethylolpropane, and triethanol. Amine, triisopropanolamine, pentaerythritol, pentantetrol, hexanetetrol, diglycerin, ditrimethylolpropane, sorbitol, adonitol, arabitol, xylitol, triglycerin, dipentaerythritol, sorbitol, mannitol, iditol, inositol, dulcitol, talose , allose, tripentaerythritol,
Benzenetricarboxylic acids such as trimellitic acid and hemimellitic acid, benzenetetracarboxylic acids such as pyromellitic acid, benzenehexacarboxylic acids such as mellitic acid, cyclohexanetricarboxylic acids,
triaminotriethylamine, triethylenetetramine,
hexamethyl phosphate triamide,
etc., and one or more types of these can be used.
また、上記(E)成分、(D)成分以外の溶媒として、例えば、エチレングリコール、ジエチレングリコール、プロピレングリコール、エチレングリコールモノn-ブチルエーテル、エチレングリコールモノtert-ブチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、ジエチレングリコールモノブチルエーテル、エチレングリコールジアセテート、プロピレングリコールモノブチルエーテル、ジプロピレングリコールモノメチルエーテル、プロピレングリコールモノn-ブチルエーテル、ジプロピレングリコールモノプロピルエーテル、エチレングリコールモノ-2-エチルヘキシルエーテル、エチレングリコールジブチルエーテル、ジエチレングリコールエチルメチルエーテル、ジエチレングリコールジメチルエーテル、ジエチレングリコールエチルメチルエーテル、ジエチレングリコールジエチルエーテル、ジエチレングリコールジブチルエーテル、ジプロピレングリコールジメチルエーテル、トリエチレングリコールジメチルエーテル、ジエチレングリコールモノエチルエーテルアセテート、エチレングリコールモノエチルエーテルアセテート、エチレングリコールモノブチルエーテルアセテート、ジエチレングリコールモノエチルエーテルアセテート、ジエチレングリコールモノブチルエーテルアセテート等のグリコール、酢酸エチル、酢酸ブチル、ジメチルスルホキシド、ヘキサメチルリン酸トリアミド、N-メチルピロリドン、スルホラン、クロロブタン、ブロムヘキサン、ジクロロメタン、1,2−ジクロロエタン、1,1−ジクロロエタン、クロロホルム、塩素化ポリエチレン、塩素化ポリプロピレン、トリグリセリド、シクロヘキサノール、フルフリルアルコール等を使用することもできる。 In addition, examples of solvents other than the above components (E) and (D) include ethylene glycol, diethylene glycol, propylene glycol, ethylene glycol mono-n-butyl ether, ethylene glycol mono-tert-butyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, Diethylene glycol monobutyl ether, ethylene glycol diacetate, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, propylene glycol mono-n-butyl ether, dipropylene glycol monopropyl ether, ethylene glycol mono-2-ethylhexyl ether, ethylene glycol dibutyl ether, diethylene glycol ethyl Methyl ether, diethylene glycol dimethyl ether, diethylene glycol ethyl methyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, dipropylene glycol dimethyl ether, triethylene glycol dimethyl ether, diethylene glycol monoethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, diethylene glycol mono Glycols such as ethyl ether acetate, diethylene glycol monobutyl ether acetate, ethyl acetate, butyl acetate, dimethyl sulfoxide, hexamethyl phosphoric acid triamide, N-methylpyrrolidone, sulfolane, chlorobutane, bromhexane, dichloromethane, 1,2−dichloroethane, 1 , 1−dichloroethane, chloroform, chlorinated polyethylene, chlorinated polypropylene, triglyceride, cyclohexanol, furfuryl alcohol, etc. can also be used.
本発明の剥離剤組成物は、建築物、土木構造物等の表面に形成された塗膜を剥離するもので、適用できる塗膜としては、特に限定されないが、例えば、JIS K5621「一般用さび止めペイント」、JIS K5651「アミノアルキド樹脂塗料」、JIS K5658「建築用耐候性上塗り塗料」、JIS K5659「鋼構造物用耐候性塗料」、JIS K5660「つや有合成樹脂エマルションペイント」、JIS K5663「合成樹脂エマルションペイント」、JIS K5668「合成樹脂エマルション模様塗料」、JIS K5670「アクリル樹脂系非水分散形塗料」、JIS A6909「建築用仕上塗材」等が挙げられる。 The stripping agent composition of the present invention is used to strip coating films formed on the surfaces of buildings, civil engineering structures, etc. Applicable coatings are not particularly limited, but include, for example, JIS K5621 "General Purpose Rust". JIS K5651 "Amino alkyd resin paint", JIS K5658 "Weather resistant top coat for construction", JIS K5659 "Weather resistant paint for steel structures", JIS K5660 "Glossy synthetic resin emulsion paint", JIS K5663 " Examples include "synthetic resin emulsion paint", JIS K5668 "synthetic resin emulsion pattern paint", JIS K5670 "acrylic resin non-aqueous dispersion paint", and JIS A6909 "architectural finishing coating material".
本発明の剥離剤組成物は、このような塗膜の上に、好ましくは0.2kg/m2以上5.0kg/m2以下、より好ましくは0.3kg/m2以上3.0kg/m2以下で塗付すればよい。塗装器具としては特に限定されず、例えば、ローラー、刷毛、鏝、ヘラ、スプレー、ガン等を用いて塗装すればよい。 The release agent composition of the present invention is applied onto such a coating film at a weight of preferably 0.2 kg/m 2 or more and 5.0 kg/m 2 or less, more preferably 0.3 kg/m 2 or more and 3.0 kg/m 2 or less. It is sufficient to apply with 2 or less. The coating device is not particularly limited, and for example, a roller, brush, trowel, spatula, spray, gun, or the like may be used for coating.
また本発明の剥離剤組成物は、30分から2時間程度で軟化し剥離を開始することができ、さらに24時間から48時間経過後も軟化が持続している。そのため、翌日など、施工者のタイミングにあわせて剥離が可能である。剥離器具としては特に限定されず、例えば、鏝、ヘラ、スクレーパー等を用いて剥離すればよい。 Further, the stripping agent composition of the present invention can soften and start stripping in about 30 minutes to 2 hours, and continues to soften even after 24 to 48 hours have passed. Therefore, it is possible to remove the material at a time that suits the builder, such as the next day. The peeling device is not particularly limited, and for example, a trowel, spatula, scraper, or the like may be used for peeling.
以下に実施例を示し、本発明の特徴をより明確にする。 Examples are shown below to clarify the features of the present invention.
表1に示す重量割合にて下記原料を均一に混合した剥離剤組成物1~16を用意した。
A:水
B:ベンジルアルコール
C1:ポリオキシエチレン(20)ラウリルエーテル硫酸ナトリウム
C2:ポリオキシエチレン(20)ステアリルエーテル
C3:ポリオキシエチレン(3)ラウリルエーテル硫酸ナトリウム
C4:ポリオキシエチレンポリオキシプロピレングリコール
D:キシレン
E1:ノナン
E2:オクタデカノール
E3:エルカ酸アミド
E4:ヘキサデカノール
E5:オクタノール
E6:ブタノール
E7:デカン酸メチル
E8:オレイン酸メチル
E9:プロピオン酸メチル
揮発抑制剤:グリセリン
増粘剤:セルロース系増粘剤
酸化剤:過酸化水素
Release agent compositions 1 to 16 were prepared by uniformly mixing the following raw materials in the weight proportions shown in Table 1.
A: Water B: Benzyl alcohol C1: Polyoxyethylene (20) Sodium lauryl ether sulfate C2: Polyoxyethylene (20) Stearyl ether C3: Polyoxyethylene (3) Sodium lauryl ether sulfate C4: Polyoxyethylene polyoxypropylene glycol
D: Xylene E1: Nonane E2: Octadecanol E3: Erucic acid amide E4: Hexadecanol E5: Octanol E6: Butanol E7: Methyl decanoate E8: Methyl oleate E9: Methyl propionate Volatization inhibitor: Glycerin thickener : Cellulose thickener Oxidizing agent: Hydrogen peroxide
(試験)
下記に示す塗膜面が垂直となるように設置し、表1に示す剥離用組成物を下記に示す所要量でローラー塗りし、下記の試験を実施した。
塗膜面:スレート板(300×150×6mm)の片面に、アクリルシリコン樹脂、酸化チタンを主成分とするアクリルシリコン樹脂塗料を吹付け、塗膜厚0.3mmの塗膜を形成させ、これを促進耐候性試験機「アイスーパーUVテスター」(岩崎電気株式会社製)にて400時間曝露させたものを塗膜面とした。剥離用組成物所要量0.5kg/m2。
(test)
It was installed so that the coating surface shown below was perpendicular, and the peeling composition shown in Table 1 was applied with a roller in the required amount shown below, and the following test was conducted.
Coating surface: Spray acrylic silicone resin paint containing acrylic silicone resin and titanium oxide as main components on one side of a slate board (300 x 150 x 6 mm) to form a coating film with a thickness of 0.3 mm. The coated surface was exposed for 400 hours using an accelerated weathering tester "I-Super UV Tester" (manufactured by Iwasaki Electric Co., Ltd.). Required amount of stripping composition: 0.5 kg/m 2 .
(試験1)塗着性
塗付直後の剥離用組成物の塗着度合いを目視にて観察した。度合いの評価は、「5」(垂直面でも問題無く優れた塗着性を示した。)から「1」(剥離用組成物が一部垂れ落ちてしまった。)の5段階で評価した。結果は表1に示す。
(Test 1) Adhesion The degree of adhesion of the release composition immediately after application was visually observed. The degree was evaluated on a five-point scale from "5" (excellent adhesion was exhibited even on vertical surfaces without any problems) to "1" (part of the stripping composition dripped down). The results are shown in Table 1.
(試験2)剥離性
塗付後24時間後、ヘラを用いて塗膜剥離を行い、その度合いを、「5」(問題無くスムーズに剥離でき、優れた塗膜軟化性を示した。)から「1」(剥離が困難であり、塗膜軟化性に劣っていた。)の5段階で評価した。結果は表1に示す。
(Test 2) Peelability 24 hours after application, the paint film was peeled off using a spatula, and the degree of peeling was evaluated from ``5'' (smooth peeling with no problems and excellent paint film softening properties). Evaluation was made on a five-point scale of "1" (difficult to peel and poor coating softening properties). The results are shown in Table 1.
(試験3)剥離効果の持続性
塗付後48時間後、ヘラを用いて塗膜剥離を行い、その度合いを評価した。評価は試験2と同様である。結果は表1に示す。
(Test 3) Persistence of Peeling Effect 48 hours after application, the coating was peeled off using a spatula, and the degree of peeling was evaluated. The evaluation is the same as Test 2. The results are shown in Table 1.
Claims (1)
(B)芳香族アルコール20重量%以上70重量%以下、
を含む水性剥離剤組成物であって、さらに、
(C)炭素数6以上30以下のアルキル基とオキシアルキレン単位を有する界面活性剤0.1重量%以上10重量%以下、
(D)芳香族溶媒0.1重量%以上10重量%以下及び(E)炭素数6以上30以下の脂肪族溶媒0.5重量%以上10重量%以下、
を含有し、
該(E)炭素数6以上30以下の脂肪族溶媒が、ノナン、オクタデカノール、エルカ酸アミド、ヘキサデカノール、オクタノール、デカン酸メチル、オレイン酸メチルから選ばれる1種以上を含有する、
ことを特徴とする水性剥離剤組成物。
(A) Water 25% by weight or more and 70% by weight or less ,
(B) aromatic alcohol 20% by weight or more and 70% by weight or less ,
An aqueous stripper composition comprising:
(C) a surfactant having an alkyl group having 6 to 30 carbon atoms and an oxyalkylene unit from 0.1% by weight to 10% by weight ;
(D) aromatic solvent 0.1% to 10% by weight; (E) aliphatic solvent having 6 to 30 carbon atoms 0.5% to 10% by weight ;
Contains
(E) the aliphatic solvent having 6 to 30 carbon atoms contains one or more selected from nonane, octadecanol, erucic acid amide, hexadecanol, octanol, methyl decanoate, and methyl oleate;
An aqueous stripping agent composition characterized by:
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JP2009155590A (en) | 2007-12-28 | 2009-07-16 | Yokohama Yushi Kogyo Kk | Stripping agent and stripping method for solid lubricant type cured coating |
JP2014151581A (en) | 2013-02-12 | 2014-08-25 | Nicca Chemical Co Ltd | Resin coating film removal method and method of producing recycled polypropylene-based resin molded body |
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JP2009155590A (en) | 2007-12-28 | 2009-07-16 | Yokohama Yushi Kogyo Kk | Stripping agent and stripping method for solid lubricant type cured coating |
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