JP7396745B1 - Heating device and heating method equipped with exothermic laminate - Google Patents

Heating device and heating method equipped with exothermic laminate Download PDF

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JP7396745B1
JP7396745B1 JP2023031841A JP2023031841A JP7396745B1 JP 7396745 B1 JP7396745 B1 JP 7396745B1 JP 2023031841 A JP2023031841 A JP 2023031841A JP 2023031841 A JP2023031841 A JP 2023031841A JP 7396745 B1 JP7396745 B1 JP 7396745B1
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光男 吉澤
いずみ 吉澤
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株式会社ヨシザワ
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【課題】発熱剤と水との反応を利用して熱エネルギーを発生させる化学発熱性積層体であって、発熱を引き起こす操作が容易かつ確実となる積層体及びその積層体を内部に備えた加熱装置を用いる加熱対象物の加熱方法を提供する。【解決手段】四角い皿状の箱体に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋4とが、重ねられた状態で支持板に固定されており、さらに、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、箱体の前方から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた加熱装置であり、水袋と発熱剤袋の引き裂き用の紐体の前方の部分を引っ張って箱体の前方に引き出し、水袋と発熱剤袋とを引き裂くことにより、発熱を起こさせて加熱対象物を加熱する。【選択図】図3[Problem] A chemical exothermic laminate that generates thermal energy by using a reaction between an exothermic agent and water, the laminate having an easy and reliable operation for generating heat, and a heating device equipped with the laminate inside. A method of heating an object using an apparatus is provided. [Solution] A water bag formed by storing water in a rectangular dish-shaped box body and a heat generating agent bag 4 in which a bag-like container houses a chemical heat generating agent that generates heat upon contact with water are supported in a stacked state. It is fixed to the board, and is further wrapped around the front and back of both the upper and lower surfaces of the water bag, and the front and back of both the upper and lower surfaces of the exothermic agent bag, and then wrapped around the box body. This is a heating device equipped with a heat generating laminate to which a string for tearing the water bag and heat generating agent bag is attached which is pulled out from the front. By pulling the part and pulling it out to the front of the box body and tearing the water bag and the exothermic agent bag, heat is generated and the object to be heated is heated. [Selection diagram] Figure 3

Description

本発明は、新規な発熱性積層体或いは加熱装置を用いる加熱対象物の加熱方法に関する。本発明はまた、改良が進められた発熱性積層体及び加熱装置にも関する。さらに詳しく言えば、本発明は、本発明者両名が先に完成させた新規な発熱性積層体及び加熱装置の発明を開示した二件の特許出願(特願2022-124769号出願及び特願2022-156316号出願、なお前者の特願2022-124769号出願は、補正後の特許請求の範囲の記載に基づき既に特許査定が発行されている)にて開示した発熱性積層体或いは加熱装置を用いる加熱対象物の加熱方法、そしてそれらの特許出願に開示した発熱性積層体或いは加熱装置の改良にも関する。 The present invention relates to a method of heating an object to be heated using a novel exothermic laminate or heating device. The present invention also relates to improved exothermic laminates and heating devices. More specifically, the present invention is based on two patent applications (Japanese Patent Application No. 2022-124769 and Japanese Patent Application No. 2022-124769 and Patent Application No. Application No. 2022-156316, your patent application No. 2022-124769 has already been granted a patent based on the amended claims). The present invention also relates to methods for heating objects to be heated, and improvements to the exothermic laminates or heating devices disclosed in those patent applications.

近年、弁当、調理済み食品、非常食、日本酒、乳児用ミルク調製用温水等の各種の食品および飲料の加熱もしくは加温のために、粒状もしくは粉末状の発熱剤と水との化学反応により発熱状態を生起させる発熱システムの利用が進められている。すなわち、旅行中、災害発生時などのような、可燃性ガスや電気エネルギーを利用する加熱器具を用いることが困難な状況であって、弁当、調理済み食品、非常食等の食品や乳児用ミルクの調製用温水等の飲料を加熱もしくは加温したい場合に、予め水と生石灰などの水と接触することにより発熱する発熱剤とを別々に袋体に収容して皿状などの耐水性容器内にそれぞれを近接配置した加熱装置を用意しておき、必要となった時に、加熱装置の上に加熱対象の調理済み食品などを載置した上で、加熱装置にセットされた発熱剤と水とを互いに接触させる操作を行うことにより熱エネルギーを生成させ、その熱エネルギーを利用して所望の加熱や加温を実現させる発熱システムである。 In recent years, heat generation has been developed due to the chemical reaction between granular or powdered exothermic agents and water to heat or warm various foods and beverages such as bento boxes, cooked foods, emergency rations, Japanese sake, and hot water for preparing infant milk. Progress is being made in the use of heat generation systems to generate conditions. In other words, in situations where it is difficult to use heating equipment that uses flammable gas or electrical energy, such as while traveling or in the event of a disaster, food items such as bento boxes, pre-cooked foods, emergency rations, and infant milk may be used. When you want to heat or heat a beverage, such as hot water, you can store water and a heat-generating agent, such as quicklime, that generates heat when it comes into contact with water, separately in a bag and place it in a water-resistant container such as a dish. Prepare a heating device with each placed close to each other, and when necessary, place the cooked food to be heated on top of the heating device, and then heat the exothermic agent and water set in the heating device. This is a heat generating system that generates thermal energy by bringing the two into contact with each other, and uses that thermal energy to achieve desired heating.

上記の発熱システムの実現に利用できる加熱装置や発熱性組成物については、これまでに様々なタイプのものが考えられている。
その例を挙げると、まず特許文献1には、発熱剤を収容した発熱剤袋、水を収容した水袋、そして支持板(プレート)とを重ね合わせて構成した積層体に、発熱袋と水袋の双方を破断し、開裂させるための紐体(破断用紐)を組み合わせて一体のセットとした、このセットを容器内に収容した加熱容器が開示されている。この加熱容器を用いて弁当や調理済食品などを加熱する場合には、発熱装置の上に弁当や調理済食品などの加熱処理を必要とする物品(加熱対象物)を置き、所望の時に破断用紐を引くことにより、発熱袋と水袋の双方をほぼ同時に破断して開裂させ、この開裂操作により、発熱剤と水とを物理的に接触させて、発熱反応を起こさせるシステムである。
この特許文献1には、発熱剤や水を収容する袋の素材の例として、ポリエチレン等の合成樹脂を材料としたフィルムが記載されている。
Various types of heating devices and exothermic compositions that can be used to realize the above exothermic system have been considered so far.
To give an example, first of all, Patent Document 1 discloses that a heat-generating bag containing a heat-generating agent, a water bag containing water, and a support plate (plate) are stacked on top of each other. A heating container is disclosed in which strings (breaking strings) for breaking and tearing both sides of the bag are combined to form an integrated set, and this set is housed in the container. When heating bento boxes, cooked foods, etc. using this heating container, place the item (object to be heated) that requires heat treatment, such as the bento box or cooked foods, on top of the heating device, and break it at the desired time. By pulling the string, both the exothermic bag and the water bag are ruptured almost simultaneously, and this tearing operation brings the exothermic agent and water into physical contact, causing an exothermic reaction.
This Patent Document 1 describes a film made of synthetic resin such as polyethylene as an example of a material for a bag that contains a heat generating agent and water.

特許文献2にも、特許文献1に開示の加熱装置と類似の構成の加熱装置が開示されており、発熱剤袋として、不織布製の袋に発熱剤を充填した発熱剤パックの使用が記載されている。 Patent Document 2 also discloses a heating device having a similar configuration to the heating device disclosed in Patent Document 1, and describes the use of a heat generating agent pack in which a nonwoven fabric bag is filled with a heat generating agent as the heat generating agent bag. ing.

特許文献3にも、特許文献1に開示の加熱装置と類似の構成を持ち、同様の化学反応を利用する加熱装置が開示されている。なお、この加熱装置では、発熱剤袋の破断と開裂により飛散し、発熱剤と水との反応により発生する水蒸気と共に上昇して、上方に配置された食材の汚染を引き起こしやすい発熱剤残渣の食材との接触を防ぐために、発熱装置の容器の上面に保護シートが配置されている。 Patent Document 3 also discloses a heating device that has a similar configuration to the heating device disclosed in Patent Document 1 and utilizes a similar chemical reaction. In addition, in this heating device, food products with heat-generating agent residues tend to scatter when the heat-generating agent bag breaks and ruptures, and rise together with water vapor generated by the reaction between the heat-generating agent and water, causing contamination of the food items placed above. A protective sheet is placed on the top of the heat generating device container to prevent contact with the heat generating device.

特許文献4には、特許文献1に開示の加熱装置を改良した発熱性積層体として、発熱剤袋を、発熱剤を透水性袋体に内包させた発熱剤内袋と、支持板に固定された辺に沿って一方の側に該発熱剤内袋を偏在させた状態で収容する耐湿性外袋から構成し、破断用の紐による発熱剤袋の切断位置が耐湿性外袋内の発熱剤内袋の位置とは重なることのないように設定されている構成のものが開示されている。 Patent Document 4 describes a heat generating laminate that is an improved heating device disclosed in Patent Document 1, and includes a heat generating agent bag, a heat generating agent inner bag in which a heat generating agent is encapsulated in a water permeable bag body, and a heat generating agent bag fixed to a support plate. It consists of a moisture-resistant outer bag that accommodates the exothermic agent inner bag unevenly distributed along one side, and the position where the exothermic agent bag is cut by the tearing string is the exothermic agent inside the moisture-resistant outer bag. A configuration is disclosed in which the position is set so as not to overlap with the position of the inner bag.

特開平11-292155JP 11-292155 特開2007-275170JP2007-275170 特開2010-68846JP2010-68846 特開2018-42605JP2018-42605

上記の先行技術文献の記載内容と、これまでの説明から分かるように、公知の化学反応による発熱を利用する加熱装置の多くは、水袋、袋状容器に粒状または粉末状の発熱剤を収容した発熱剤袋、そして支持板が任意の順に積層され、さらに発熱剤袋と水袋のそれぞれの上面と下面とにかけて掛け渡された一本の破断用紐体を含む構成の発熱性積層体が、上面が開口した四角い皿状の箱体に収容された構造を持つ。また、水袋と発熱剤袋の破断(開裂)が容易にできるように、それぞれの袋の一辺が共に支持板に対して固定された積層体とすることも一般的であった。 As can be seen from the descriptions of the above-mentioned prior art documents and the previous explanations, most of the heating devices that utilize heat generated by a known chemical reaction contain a granular or powdery exothermic agent in a water bag or bag-like container. A heat-generating laminate is constructed in which a heat-generating agent bag and a support plate are laminated in an arbitrary order, and a breaking string is strung across the upper and lower surfaces of each of the heat-generating agent bag and the water bag. It has a structure housed in a square dish-shaped box with an open top. Further, in order to easily break (cleave) the water bag and the exothermic agent bag, it has also been common to form a laminate in which one side of each bag is fixed to a support plate.

但し、これまでに知られている各種の発熱性積層体を利用する加熱装置には、次に述べるような問題があることが知られている。
特許文献1に記載されているように粉末状もしくは粒状の生石灰などの発熱剤を合成樹脂製フィルムの袋に内包した発熱剤袋では通常の合成樹脂製のフィルムの袋が透湿性を示す持つため、その袋に内包した発熱剤の吸湿による失活が早い時期に進行し、通常の発熱剤袋では、その発熱機能を維持できる保存期間が一ヶ月程度と短期となる。このため、非常時に使用するという目的で保管する加熱装置としては活性の維持が不充分となり易い。また、紐体の引っ張りにより、水袋と発熱剤袋とを同時に破断し、開裂させる際に、水袋と発熱剤袋のそれぞれの袋を形成するフィルム状シートを破断開裂させるための力(引っ張り力)に加えて、発熱剤袋に詰められて、吸湿等により塊状になっているいる粉末あるいは粒状の発熱剤の塊を解きほぐすための力も必要となり、強い腕力を持たない年配者や子供などにとって破断用紐体の確実な引っ張り作業が難しくなりやすいという問題がある。
However, it is known that the heating devices that utilize various heat generating laminates that have been known so far have the following problems.
As described in Patent Document 1, in a heat generating agent bag in which a heat generating agent such as powdered or granular quicklime is encapsulated in a synthetic resin film bag, a normal synthetic resin film bag exhibits moisture permeability. The exothermic agent contained in the bag quickly loses its activity due to moisture absorption, and a typical exothermic agent bag can only maintain its exothermic function for a short storage period of about one month. Therefore, as a heating device stored for the purpose of use in an emergency, maintenance of activity is likely to be insufficient. In addition, when the water bag and the exothermic agent bag are simultaneously broken and torn by pulling the string, the force (pulling In addition to this, force is also required to loosen the lumps of powder or granular heat-generating agent packed in the heat-generating bag and clumped together due to moisture absorption, etc., which is difficult for elderly people, children, etc. who do not have strong physical strength. There is a problem in that it tends to be difficult to reliably pull the breaking string.

特許文献2に記載されている発熱剤を不織布製の袋に収容した発熱剤パックも同様な傾向があり、特許文献3に記載の発熱装置も類似の問題点がある。 The exothermic agent pack described in Patent Document 2, in which the exothermic agent is housed in a bag made of nonwoven fabric, has a similar tendency, and the heat generating device described in Patent Document 3 also has similar problems.

特許文献4に記載の加熱装置は、特許文献1~3に記載されている加熱装置の改良装置として提供されたものあるが、実用上の操作工程に関する本発明の発明者の詳細な検討によると、特許文献4に記載されている透水性の内袋に発熱剤を内包させて、この発熱剤内袋を耐湿性の外袋に収容した構成では、発熱剤の保存性は向上するものの、発熱剤内袋が耐湿性の外袋内で一方の側に偏在させているため、発熱剤袋と水袋のそれぞれの上面と下面とに掛け渡された一本の破断用紐体の掛け渡し位置が制限され、このため破断用紐体を用いる発熱剤袋と水袋との同時期の破断操作が容易ではないという問題が発生することが判明した。 The heating device described in Patent Document 4 was provided as an improved device of the heating devices described in Patent Documents 1 to 3, but according to the detailed study of the inventor of the present invention regarding the practical operation process. In the configuration described in Patent Document 4, in which a heat-generating agent is encapsulated in a water-permeable inner bag and the heat-generating agent inner bag is housed in a moisture-resistant outer bag, although the storage stability of the heat-generating agent is improved, Since the inner agent bag is unevenly distributed on one side of the moisture-resistant outer bag, the position of the single breaking string that is stretched between the upper and lower surfaces of the exothermic agent bag and the water bag, respectively. It has been found that a problem arises in that it is difficult to simultaneously break the heating agent bag and the water bag using the breaking string.

本発明の発明者は、公知の加熱装置に関する上述の種々の問題全体の解決を目的として研究を継続した結果、なかでも優れた実用性能を示す特許文献4に記載された構成の発熱性積層体と加熱装置において現れる不充分な点を改良した発熱性積層体そして加熱装置として、以下に記載する構成の発熱性積層体そして加熱装置を利用することで、多くの点が顕著に改善されることを先に見出している。
そして、この発明について、発明者は、2022年8月4日に出願手続と早期審査申請手続を行った。この出願は特願2022-124769として審査された結果、まず一回の拒絶理由通知が発行され、次いで、出願人からの特許請求の範囲の補正手続が行われた。その後、補正後の特許請求の範囲の記載に基づき、特許査定が発行された。
As a result of continuing research aimed at solving all of the above-mentioned problems related to known heating devices, the inventor of the present invention discovered a heat-generating laminate having the structure described in Patent Document 4, which exhibits particularly excellent practical performance. By using the exothermic laminate and heating device having the configurations described below, many points can be significantly improved. is discovered first.
Regarding this invention, the inventor filed an application and filed an application for accelerated examination on August 4, 2022. As a result of this application being examined as Japanese Patent Application No. 2022-124769, a notice of reasons for refusal was first issued, and then procedures for amending the scope of claims were carried out by the applicant. Thereafter, a grant of patent was issued based on the amended claims.

上記の特願2022-124769として出願した発明(補正前の特許請求の範囲の独立請求項に記載の発明)は、下記の加熱装置と発熱性積層体の発明です。
(1)加熱装置
上面が開口した四角い皿状の箱体の内部に、水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して重ねられた状態で支持板に固定されていて、さらに、一方の端部が支持体(=支持板)に固定され、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、上記箱体の前方から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた加熱装置であって、
化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製の容器であり、その金属フィルム製の袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、そして水袋と発熱剤袋の引き裂き用の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されていることを特徴とする加熱装置。
The invention filed as the above patent application No. 2022-124769 (the invention stated in the independent claim of the claims before amendment) is the invention of the following heating device and exothermic laminate.
(1) Heating device
Inside a square dish-shaped box with an open top, a water bag is made of a water-impermeable, easily tearable bag containing water, and a chemical exothermic agent that generates heat when it comes into contact with water is housed in a bag-like container. The exothermic agent bags are stacked and fixed to the support plate with a support plate having an opening interposed between the bags, and one end is fixed to the support plate (= support plate). ), and the other end is wrapped around both the upper and lower surfaces of the water bag, and around both the upper and lower surfaces of the heating agent bag, and then A heating device comprising a heat-generating laminate to which a water bag pulled out from the front of a box body and a string for tearing a heat-generating agent bag are attached,
The bag-like container for the chemical heat generating agent is a water-impermeable and easily tearable metal film container, and the chemical heat generating agent is divided into left and right sides through a blank area inside the metal film bag-like container. and a string for tearing the water bag and the exothermic agent bag is wound so as to straddle the upper and lower sides of the blank area. heating device.

(2)発熱性積層体
水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して重ねられた状態で支持体に固定されていて、さらに、一方の端部が支持板に固定されていて、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、支持板の一方の側から引き出されている水袋と発熱剤袋の引き裂き用の紐体を備えた発熱性積層体であって、
化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製の容器であり、その金属フィルム製の袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、そして水袋と発熱剤袋の引き裂き用の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されていることを特徴とする発熱性積層体。
(2) A water bag made of a water-generating laminate containing water in a water-impermeable and easily tearable bag, and a heat-generating agent bag containing a chemical exothermic agent that generates heat upon contact with water in a bag-like container, The bags are fixed to a support in an overlapping state via a support plate having an opening interposed between the bags, and further, one end is fixed to the support plate and the other end is fixed to the support body. , wrapped around the front and back of both the upper and lower surfaces of the water bag, and the front and back of both the upper and lower surfaces of the heating agent bag, and then pulled out from one side of the support plate. A heat generating laminate comprising a string for tearing a water bag and a heat generating agent bag,
The bag-like container for the chemical heat generating agent is a water-impermeable and easily tearable metal film container, and the chemical heat generating agent is divided into left and right sides through a blank area inside the metal film bag-like container. and a string for tearing the water bag and the exothermic agent bag is wound so as to straddle the upper and lower sides of the blank area. Exothermic laminate.

なお、上述の特願2022-124769にて補正手続がなされた後に、特許査定が出された補正後の特許請求の範囲の各請求項(従属請求項については、主請求項を上記請求項として記載した)に記載の発明は、下記の通りです。 In addition, after the amendment procedure was carried out in the above-mentioned patent application 2022-124769, each claim in the amended scope of claims for which a grant of patent was issued (for dependent claims, the main claim should be considered as the above claim) The inventions described in ) are as follows.

(請求項1)
上面が開口した四角い皿状の箱体の内部に水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して、上から順に重ねられた状態で支持板に固定されており、さらに、一方の端部が該支持板に固定され、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、上記箱体の前方から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた加熱装置であって、
化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製もしくは表面に金属層が形成された合成樹脂フィルム製の容器であり、その袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、該袋状容器の内部で左右に分割配置されている化学発熱剤のそれぞれが水透過性あるいは水溶解性の内袋に収容されていること、そして水袋と発熱剤袋の引き裂き用の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されていることを特徴とする加熱装置。
(請求項2)化学発熱剤を収容する内袋のいずれもが不織布製である上記請求項1に記載の加熱装置。
(請求項3)化学発熱剤を収容している発熱剤袋がアルミ箔製である上記請求項1に記載の加熱装置。
(請求項4)化学発熱剤が生石灰と金属アルミニウム粉末との混合物である上記請求項1に記載の加熱装置。
(請求項5)水を収容している水袋が、表面に金属が蒸着されたプラスチックフィルム製である上記請求項1に記載の加熱装置。
(請求項6)皿状箱体がプラスチック製である上記請求項1に記載の加熱装置。
(請求項7)水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して、上から順に重ねられた状態で支持板に固定されており、さらに、一方の端部が該支持板に固定され、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、支持板の一方の側から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた発熱性積層体であって、化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製もしくは表面に金属層が形成された合成樹脂フィルム製の容器であり、その袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、該袋状容器の内部で左右に分割配置されている化学発熱剤のそれぞれが水透過性あるいは水溶解性の内袋に収容されていること、そして水袋と発熱剤袋の引き裂き用の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されていることを特徴とする発熱性積層体。
(請求項8)化学発熱剤を収容する内袋のいずれもが不織布製である上記請求項7に記載の発熱性積層体。
(請求項9)化学発熱剤が生石灰と金属アルミニウム粉末との混合物である上記請求項7に記載の発熱性積層体。
(請求項10)化学発熱剤を収容している発熱剤袋がアルミ箔製である上記請求項7に記載の発熱性積層体。
(請求項11)水を収容している水袋が、表面に金属が蒸着されたプラスチックフィルム製である上記請求項7に記載の発熱性積層体。
(Claim 1)
A water bag is formed by storing water in a water-impermeable and easily tearable bag inside a square dish-shaped box with an open top, and a chemical exothermic agent that generates heat when it comes into contact with water is stored in the bag-like container. The exothermic agent bags are fixed to the support plate in a stacked state from above through a support plate having an opening interposed between the bags, and further, one end is fixed to the support plate in a stacked state from above. and the other end is wrapped around the front and back of both the upper and lower surfaces of the water bag and the front and back of both the upper and lower surfaces of the heating agent bag, and then A heating device comprising a heat generating laminate to which a string for tearing a water bag pulled out from the front of the body and a heat generating agent bag is attached,
The bag-like container for the chemical heating agent is made of a water-impermeable and easily tearable metal film or a synthetic resin film with a metal layer formed on the surface, and the chemical heating agent is inside the bag-like container. The chemical exothermic agent divided left and right inside the bag-like container is housed in a state where it is divided into left and right sides through a blank area, and each of the chemical exothermic agents divided left and right inside the bag-like container is placed in a water-permeable or water-soluble inner bag. and a string for tearing the water bag and the heating agent bag is wound so as to straddle the upper and lower sides of the blank area.
(Claim 2) The heating device according to the above-mentioned Item 1, wherein both of the inner bags containing the chemical exothermic agent are made of nonwoven fabric.
(Claim 3) The heating device according to Claim 1, wherein the exothermic bag containing the chemical exothermic agent is made of aluminum foil.
(Claim 4) The heating device according to Claim 1, wherein the chemical exothermic agent is a mixture of quicklime and metal aluminum powder.
(Claim 5) The heating device according to Claim 1, wherein the water bag containing water is made of a plastic film with metal vapor-deposited on the surface.
(Claim 6) The heating device according to Claim 1, wherein the dish-shaped box is made of plastic.
(Claim 7) A water bag comprising water contained in a water-impermeable and easily tearable bag and a heat generating agent bag comprising a chemical exothermic agent that generates heat upon contact with water contained in a bag-like container. They are fixed to the support plate in a stacked state from above through a support plate with an opening interposed between the bags, and one end is fixed to the support plate and the other end is fixed to the support plate in a stacked state from above. is wrapped around both the upper and lower surfaces of the water bag, and around both the upper and lower surfaces of the heating agent bag, and then pulled out from one side of the support plate. A heat-generating laminate comprising a water bag and a string for tearing the heat-generating agent bag, the bag-like container for the chemical heat-generating agent being water-impermeable and easily tearable. It is a container made of a metal film or a synthetic resin film with a metal layer formed on the surface, and the chemical exothermic agent is housed inside the bag-like container divided into left and right sides with a blank area. In particular, each of the chemical exothermic agents divided left and right inside the bag-like container is housed in a water-permeable or water-soluble inner bag, and there is a separate inner bag for tearing the water bag and the exothermic agent bag. A heat generating laminate characterized in that a string is wound so as to straddle the upper and lower sides of the blank area.
(Claim 8) The heat-generating laminate according to the above-mentioned Item 7, wherein each of the inner bags containing the chemical heating agent is made of non-woven fabric.
(Claim 9) The exothermic laminate according to Item 7, wherein the chemical exothermic agent is a mixture of quicklime and metal aluminum powder.
(Claim 10) The exothermic laminate according to Item 7, wherein the exothermic bag containing the chemical exothermic agent is made of aluminum foil.
(Claim 11) The exothermic laminate according to Item 7, wherein the water bag containing water is made of a plastic film with metal vapor-deposited on the surface.

本出願で提出するのは、特願2022-124769において補正手続の後に特許査定が出された補正後の特許請求の範囲の各請求項に記載の加熱装置あるいは発熱性積層体を用いる以下に記載の加熱対象物の加熱方法の発明である。 What is submitted in this application is the following description using the heating device or exothermic laminate described in each claim of the amended claims for which a patent was granted after the amendment procedure in Japanese Patent Application No. 2022-124769. This is an invention of a method for heating an object to be heated.

(1)上面が開口した四角い皿状の箱体の内部に水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して、上から順に重ねられた状態で支持板に固定されており、さらに、一方の端部が該支持板に固定され、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、上記箱体の前方から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた加熱装置を用意し、
化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製もしくは表面に金属層が形成された合成樹脂フィルム製の容器であり、その袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、該袋状容器の内部で左右に分割配置されている化学発熱剤のそれぞれが水透過性あるいは水溶解性の内袋に収容されていること、そして水袋と発熱剤袋の引き裂き用の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されている加熱装置の箱体の上面に加熱対象物を載置し、その後、上記の水袋と発熱剤袋の引き裂き用のの紐体の前方の部分を引っ張って箱体の前方に引き出し、水袋と発熱剤袋とを引き裂くことにより、発熱を起こさせて加熱対象物を加熱することを特徴とする加熱対象物の加熱方法。
(2)化学発熱剤を収容する内袋のいずれもが不織布製である上記加熱装置を用いる加熱方法。
(3)化学発熱剤を収容している発熱剤袋がアルミ箔製である上記加熱装置を用いる加熱方法。
(4)化学発熱剤が生石灰と金属アルミニウム粉末との混合物である上記加熱装置を用いる加熱方法。
(5)水を収容している水袋が、表面に金属が蒸着されたプラスチックフィルム製である上記加熱装置を用いる加熱方法。
(6)皿状箱体がプラスチック製である上記加熱装置を用いる加熱方法。
(7)水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して、上から順に重ねられた状態で支持板に固定されており、さらに、一方の端部が該支持板に固定され、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、支持板の一方の側から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた発熱性積層体であって、化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製もしくは表面に金属層が形成された合成樹脂フィルム製の容器であり、その袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、該袋状容器の内部で左右に分割配置されている化学発熱剤のそれぞれが水透過性あるいは水溶解性の内袋に収容されていること、そして水袋と発熱剤袋の引き裂き用の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されている発熱性積層体上面に加熱対象物を載置し、その後、上記の水袋と発熱剤袋の引き裂き用の紐体の前方の部分を引っ張って積層体の前方に引き出し(矢印参照)、水袋と発熱剤袋とを引き裂くことにより、発熱を起こさせて加熱対象物を加熱することを特徴とする加熱対象物の加熱方法。。
(8)化学発熱剤を収容する内袋のいずれもが不織布製である上記の発熱性積層体を用いる加熱方法。
(9)化学発熱剤が生石灰と金属アルミニウム粉末との混合物である発熱性積層体を用いる加熱方法。
(10)化学発熱剤を収容している発熱剤袋がアルミ箔製である発熱性積層体を用いる加熱方法。
(11)水を収容している水袋が、表面に金属が蒸着されたプラスチックフィルム製である発熱性積層体を用いる加熱方法。
(1) A bag-shaped container containing a chemical exothermic agent that generates heat when it comes into contact with a water bag made of a water-impermeable and easily tearable bag containing water inside a square dish-shaped box with an open top. The heat generating agent bags housed in It is fixed to the support plate, and the other end is wound around both the upper and lower surfaces of the water bag, and around both the upper and lower surfaces of the exothermic agent bag, and then , preparing a heating device equipped with a heat-generating laminate to which a string for tearing the water bag and the heat-generating agent bag pulled out from the front of the box body is attached;
The bag-like container for the chemical heating agent is made of a water-impermeable and easily tearable metal film or a synthetic resin film with a metal layer formed on the surface, and the chemical heating agent is inside the bag-like container. The chemical exothermic agent divided left and right inside the bag-like container is housed in a state where it is divided into left and right sides through a blank area, and each of the chemical exothermic agents divided left and right inside the bag-like container is placed in a water-permeable or water-soluble inner bag. The string for tearing the water bag and heat generating agent bag is wrapped around the upper and lower sides of the blank area. Place the object, then pull the front part of the string for tearing the water bag and exothermic agent bag, pull it out to the front of the box, and tear the water bag and exothermic agent bag. A method for heating an object to be heated, characterized by heating the object by causing heat generation.
(2) A heating method using the heating device described above, in which both inner bags containing the chemical heating agent are made of nonwoven fabric.
(3) A heating method using the heating device described above, in which the exothermic bag containing the chemical exothermic agent is made of aluminum foil.
(4) A heating method using the heating device described above, in which the chemical exothermic agent is a mixture of quicklime and metal aluminum powder.
(5) A heating method using the heating device described above, in which the water bag containing water is made of a plastic film with metal vapor-deposited on its surface.
(6) A heating method using the above heating device in which the dish-shaped box is made of plastic.
(7) A water bag made of a water-impermeable and easily tearable bag containing water, and a heat-generating bag made of a bag-like container containing a chemical heat-generating agent that generates heat upon contact with water. They are fixed to the support plate in a stacked state from above through a support plate with an opening interposed therebetween, and further, one end is fixed to the support plate, and the other end is The water is wrapped around the front and rear sides of both the top and bottom surfaces of the water bag and the front and back around both the top and bottom surfaces of the exothermic bag, and is drawn out from one side of the support plate. A heat-generating laminate comprising a heat-generating laminate to which a bag and a string for tearing the heat-generating agent bag are attached; It is a container made of film or synthetic resin film with a metal layer formed on the surface, and the chemical exothermic agent is housed inside the bag-like container divided into left and right sides with a blank area, Each of the chemical exothermic agents divided into left and right parts inside the bag-like container is housed in a water-permeable or water-soluble inner bag, and a string for tearing the water bag and the exothermic agent bag is provided. The object to be heated is placed on the top surface of the heat-generating laminate that is wound so as to straddle the upper and lower sides of the blank area, and then a A heating object that is characterized by generating heat and heating the object by pulling the front part of the string and pulling it out to the front of the laminate (see arrow) and tearing the water bag and the exothermic agent bag. How to heat things. .
(8) A heating method using the above exothermic laminate, in which both of the inner bags containing the chemical exothermic agent are made of nonwoven fabric.
(9) A heating method using an exothermic laminate in which the chemical exothermic agent is a mixture of quicklime and metal aluminum powder.
(10) A heating method using an exothermic laminate in which the exothermic bag containing the chemical exothermic agent is made of aluminum foil.
(11) A heating method using a heat-generating laminate in which the water bag containing water is made of a plastic film with metal vapor-deposited on the surface.

なお、前述したように、本発明の発明者は、上記の特願2022-124769に記載の加熱装置と発熱性積層体の実用性について、さらに検討を重ねた結果、上記の加熱装置と発熱性積層体の実用性については、特段の問題はないものの、それらを用いての熱発生操作や保存性については問題となる場合があって、改良の余地があるケースが存在することを見出した。 As mentioned above, the inventor of the present invention has further studied the practicality of the heating device and the heat-generating laminate described in the above-mentioned Japanese Patent Application No. 2022-124769. Although there are no particular problems with the practicality of the laminates, it has been found that there are cases in which there are problems with heat generation operations and storage stability, and there are cases where there is room for improvement.

その一例としては、紐体の引き出しによる水袋と発熱剤袋との引き裂きが操作が容易とは云えない場合があること。 For example, it may not be easy to tear apart the water bag and heat generating agent bag by pulling out the string.

また別の例としては、紐体の引き出しにより自由に流れ出すようになった水とほぼ同時に発熱剤袋内の表面で露出した接触により発生する発熱の速度のコントロールが容易ではないこと。 Another example is that it is not easy to control the rate of heat generation that occurs due to contact with exposed surfaces within the exothermic agent bag at about the same time as the water is allowed to flow freely due to withdrawal of the string.

さらに別の例としては、紐体の引き出しにより起こる発熱とその発熱により生成する高温の水蒸気の箱体の上面からの放散速度のコントロールが容易ではないこと。 Another example is that it is not easy to control the heat generated by pulling out the cord and the rate at which the high-temperature water vapor generated by the heat dissipates from the top surface of the box.

本発明の発明者は、上記の追加的な問題点の改良として、下記の対策のいずれか一つ、あるいは全てを改善することが有効であることを見出した。 The inventors of the present invention have found that it is effective to improve any one or all of the following measures as an additional improvement to the above-mentioned problems.

(1)水袋と発熱剤袋の少なくとも一方の引き裂き予定位置に、引き裂きを容易にする切れ目あるいはV字型のノッチを設ける。
(2)加熱装置については、箱体の上面に多孔性のプラスチックシートを貼りつけて箱体上面からの高温水蒸気の放散速度のコントロールを可能にする。
(1) At least one of the water bag and the exothermic agent bag is provided with a cut or a V-shaped notch at the intended tearing position to facilitate tearing.
(2) Regarding the heating device, a porous plastic sheet is attached to the top of the box to enable control of the rate of dissipation of high-temperature water vapor from the top of the box.

本発明の発熱性積層体或いは加熱装置を用いる加熱対象物の加熱操作は、これまでに知られていた発熱性積層体や加熱装置に比べて発熱を引き起こすための操作が容易である上に、各種の利便性の向上等の実用上において極めて有利な改良が実現する。 The operation of heating an object to be heated using the exothermic laminate or heating device of the present invention is easier than the conventional exothermic laminates or heating devices, and the operation for generating heat is easier. Improvements that are extremely advantageous in practical terms, such as improvements in various types of convenience, are realized.

本発明の発熱性積層体を備えた加熱装置の平面図(上面図)である。発熱性積層体の層構成の理解を容易にするために、加熱装置の上面に貼られた多孔性フィルムの一部を削除した平面図として描いている。また、煩雑を避けるため、水袋と発熱剤袋の引き裂き用の紐体の一部の記入は省略した。FIG. 1 is a plan view (top view) of a heating device equipped with a heat generating laminate of the present invention. In order to facilitate understanding of the layer structure of the heat-generating laminate, the diagram is drawn as a plan view with a portion of the porous film attached to the top surface of the heating device removed. In addition, to avoid complexity, a part of the string for tearing the water bag and heat generating agent bag has been omitted. 図1に示した加熱装置の右側側面から見た断面図である。左側側面から見た断面も略同形となる。FIG. 2 is a sectional view of the heating device shown in FIG. 1 viewed from the right side. The cross section seen from the left side also has approximately the same shape. 図1に示した加熱装置の発熱剤袋に収容されている分割された領域に配置された発熱剤を内包する内袋の所在を明らかにする平面図(上面図)である。なお、この平面図は、発熱剤袋を一部切り取った状態で描いてある。FIG. 2 is a plan view (top view) illustrating the location of the inner bag containing the exothermic agent, which is arranged in divided areas and accommodated in the exothermic agent bag of the heating device shown in FIG. 1; Note that this plan view is drawn with the exothermic agent bag partially cut away.

次に、添付図面を参照しながら、本発明の発熱性積層体と加熱装置を用いる加熱対象物の加熱用法をさらに詳しく説明する。 Next, a method for heating an object to be heated using the exothermic laminate and heating device of the present invention will be described in more detail with reference to the accompanying drawings.

図1は、本発明の発熱性積層体を備えた加熱装置の平面図(上面図)である。 FIG. 1 is a plan view (top view) of a heating device equipped with a heat generating laminate according to the present invention.

本発明で用いる加熱装置1の基本構成は、これまでに知られている化学発熱剤を用いる加熱装置と同様な、上面が開口した四角い皿状の箱体2の内部に、水不透過性で易引き裂き性の袋に水を収容してなる水袋3と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋4とが、それらの袋の間に介在する開口を備えた支持板5を介して重ねられた状態で支持板5に配置されており、一方の端部が支持板5に固定され、他方の端部が、水袋3の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、箱体2の前面側から引き出されている水袋と発熱剤袋の引き裂き用の紐体5が取り付けられている発熱性積層体を備えた加熱装置である。なお、皿状箱体2の上面は通常、内側に収容した水袋3と発熱剤袋4の脱落防止、そして発熱反応により発生した熱エネルギーを効率良く上昇させるために有効な多孔性のプラスチックフィルムにより覆われていることが好ましい。 The basic configuration of the heating device 1 used in the present invention is similar to the heating devices using chemical exothermic agents known up to now. A water bag 3, which is an easily tearable bag containing water, and a heat generating agent bag 4, which is a bag-shaped container containing a chemical exothermic agent that generates heat when it comes into contact with water, open an opening between the bags. They are arranged on the support plate 5 in an overlapping state via the support plate 5 provided, one end is fixed to the support plate 5, and the other end is attached to the upper and lower surfaces of the water bag 3. It is wrapped around both sides of the water bag and the exothermic agent bag, and is wound around the front and back of both the upper and lower surfaces of the exothermic agent bag, and is pulled out from the front side of the box body 2 for tearing the water bag and the exothermic agent bag. This heating device includes a heat generating laminate to which a string 5 is attached. Note that the upper surface of the dish-shaped box 2 is usually covered with a porous plastic film that is effective for preventing the water bag 3 and exothermic agent bag 4 housed inside from falling off, and for efficiently increasing the thermal energy generated by the exothermic reaction. Preferably, it is covered by

本発明の発熱性積層体を収容する上面が開口した四角い皿状の箱体2は従来の同種の加熱装置で一般的に用いられている合成樹脂製の耐水性容器であることが好ましい。ただし、皿状の箱体と云っても、その深さについては特に限定は無い。また、耐水性を高めた厚紙あるいは段ボールなども使用できる。
そして、箱体2の開口面に沿った縁部には、ひも(破断用紐体)6を外部に引き出すための切り欠き部が形成されていることが好ましい。ただし、この切り欠き部は必ずしも必要とせず、切り欠き部の代わりに、箱体2の前側の側面(側壁)に孔部を設けても良い。
The rectangular dish-shaped box 2 with an open top that houses the exothermic laminate of the present invention is preferably a water-resistant container made of synthetic resin that is commonly used in conventional heating devices of the same type. However, even though it is a dish-shaped box, there is no particular limitation on its depth. Additionally, cardboard or cardboard with increased water resistance can also be used.
Further, it is preferable that a cutout portion for pulling out the string (breaking string) 6 to the outside is preferably formed at the edge along the opening surface of the box body 2. However, this notch is not necessarily required, and instead of the notch, a hole may be provided on the front side surface (side wall) of the box body 2.

四角い皿状の箱体2の底面には、水袋の破断により箱体の底面側に拡散する水を底面に集めるために凹部あるいはV字状の陥没部を設けることが好ましい。 It is preferable to provide a recess or a V-shaped depression on the bottom of the rectangular dish-shaped box 2 in order to collect water that diffuses to the bottom of the box when the water bag breaks.

水袋3と発熱剤袋4とは、それらの袋の間に介在する開口を備えた支持板5を介して重ねられた状態で支持板5に固定されている。この水袋3と発熱剤袋4の固定は、水袋3の後側の縁部と発熱袋の後ろ側縁部とを支持板の後ろ側縁部を挟んで接合固定する方法を利用して行うことが好ましい。 The water bag 3 and the exothermic agent bag 4 are fixed to the support plate 5 in an overlapping state with a support plate 5 having an opening interposed between the bags. The water bag 3 and the exothermic agent bag 4 are fixed by joining and fixing the rear edge of the water bag 3 and the rear edge of the exothermic bag by sandwiching the rear edge of the support plate. It is preferable to do so.

水袋3に収容される水は、通常の水道水や工業用水でもよいが、水に食塩やエチレングリコールなど凍結防止剤を添加しておくことが好ましい。凍結防止剤の添加量は、発熱性積層体や加熱装置の冷却条件を考慮して適宜決めることができる。一例を挙げれば、水に対する凍結防止剤の添加量を5~30重量%の範囲内の量、特に10~20重量%の範囲内の量とすることができる。必要なのは、予定している冷却保存温度や冷却保存期間などの冷却保存条件にて、水の流動性が大きく妨げられないことである。 The water contained in the water bag 3 may be ordinary tap water or industrial water, but it is preferable to add an antifreeze agent such as salt or ethylene glycol to the water. The amount of the antifreeze agent added can be appropriately determined in consideration of the cooling conditions of the exothermic laminate and the heating device. By way of example, the amount of antifreeze added to the water can be in the range from 5 to 30% by weight, especially in the range from 10 to 20% by weight. What is required is that the fluidity of the water is not significantly impeded under the planned chilled storage conditions, such as the planned chilled storage temperature and chilled storage period.

発熱剤としては、公知の生石灰、あるいは生石灰に金属アルミニウム粉末など発熱強化剤を添加した強発熱性の発熱剤を用いることが好ましい。発熱剤は通常、公知の粉末状あるいは粒状のものが用いられるが、破片状あるいは板状の成形体であっても良い。 As the exothermic agent, it is preferable to use known quicklime or a strongly exothermic exothermic agent prepared by adding a heat generating enhancer such as metal aluminum powder to quicklime. The exothermic agent is usually in the form of a known powder or granules, but it may also be in the form of pieces or plates.

本発明で用いる加熱装置あるいは発熱性積層体の主要な構成上の特徴は、イ)化学発熱剤の袋状容器を、水不透過性で易引き裂き性の金属フィルム製の容器としたこと、そして、ロ)その金属フィルム製の袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、そしてハ)水袋と発熱剤袋の引き裂き用の紐体が、上記の空白領域の上側と下側とを跨がるように巻き回されていることにある。
上記の空白領域は、化学発熱剤が袋状容器内のおおよそ中央に相当するような位置に設けられる。
The main structural features of the heating device or exothermic laminate used in the present invention are: a) the bag-like container for the chemical exothermic agent is made of a water-impermeable and easily tearable metal film container; , b) The chemical exothermic agent is housed inside the metal film bag-like container divided into left and right sides with a blank area, and c) A container for tearing the water bag and the exothermic agent bag. The string is wound so as to straddle the upper and lower sides of the blank area.
The above-mentioned blank area is provided at a position where the chemical exothermic agent corresponds approximately to the center within the bag-like container.

発熱剤を収容する水不透過性で易引き裂き性の金属フィルム製の容器としては通常、二枚のシート状のアルミ箔の四辺の縁部のそれぞれを接合して作成した袋体が用いられる。そして、発熱性積層体に組み込む化学発熱剤を予め略等分して、それぞれを不織布製などの水透過性の内袋に詰めたうえで、化学発熱剤の水不透過性で易引き裂き性の金属フィルム製の袋(外袋)の内部の左右の位置に収容配置する。なお、この場合の「左右」の配置とは、加熱装置にセットされている紐体と重ならないように紐体の左側と右側となる位置関係であって、紐体の引っ張り方向を基準とした配置である。また、左右の配置は、紐体の引っ張り方向と厳密に一致する必要は無い。 As a water-impermeable, easily tearable metal film container containing a heat generating agent, a bag made by joining each of the four edges of two sheets of aluminum foil is usually used. The chemical exothermic agent to be incorporated into the exothermic laminate is divided into approximately equal parts in advance, each portion is packed in a water-permeable inner bag made of non-woven fabric, etc., and the chemical exothermic agent is water-impermeable and easily tearable. It is housed in the left and right positions inside the metal film bag (outer bag). In addition, the "left and right" arrangement in this case refers to the positional relationship between the left and right sides of the string so that they do not overlap with the string set in the heating device, and is based on the direction in which the string is pulled. It is the arrangement. Further, the left and right arrangement does not need to strictly match the pulling direction of the string.

図3は、発熱剤が二枚の内袋(4a、4b)のそれぞれに詰められて金属フィルム製の外袋4の内部に空白領域を設けた上で左右に分けて配置された代表的な位置関係を示す平面図である。 FIG. 3 shows a typical example in which the exothermic agent is packed into each of two inner bags (4a, 4b) and separated left and right with a blank area provided inside the outer bag 4 made of metal film. FIG. 3 is a plan view showing the positional relationship.

発熱性積層体1は通常、図1と図2とから理解できるように、皿状(深さには特に限定はなく、材料も合成樹脂や厚紙などが用いられる)の耐水性容器2に収容される。 As can be understood from FIGS. 1 and 2, the heat-generating laminate 1 is usually housed in a dish-shaped (there is no particular limit to the depth, and materials such as synthetic resin or cardboard can be used) a water-resistant container 2. be done.

この皿状の耐水性容器2に収容された発熱性積層体1では、耐水性容器の前方側への紐体6の引き出し、あるいは引き抜きによって発生する、水袋と発熱剤袋の破断・開裂により、水袋から容器内には水が流れ出し、同様な破断・開裂により発熱剤袋内で露出した発熱剤と接触して発熱、即ち熱エネルギーの発生が始まり、その後における継続的な発熱が実現する。 In the heat-generating laminate 1 housed in the dish-shaped water-resistant container 2, the water bag and the heat-generating agent bag are broken or torn, which occurs when the string 6 is pulled out or pulled out to the front side of the water-resistant container. , Water flows out from the water bag into the container, contacts the exothermic agent exposed in the exothermic agent bag due to similar breakage and rupture, and begins to generate heat, that is, thermal energy, and then continuous heat generation is realized. .

上記のように、本発明の発熱性積層体に使用する発熱剤袋では、発熱剤を不織布などの透水性袋体に発熱剤を内包させた透水性内袋(なお、発熱剤を不織布のような透水性袋体に内包させた発熱剤パック自体は発熱性積層体の構成部材として、あるいは他の目的に用いるための発熱剤パックとして市販されている)を用意し、この発熱剤内袋を別に用意した発熱剤内袋よりサイズの大きな耐湿性外袋(水蒸気の透過が顕著に抑制された袋体であって、例えば、金属フィルムもしくは合成樹脂フィルムの表面に蒸着などの手段により金属層が形成された構成を持つ)の内側に左右略等分に配置する。なお、破断用紐体による発熱剤袋の切断位置が、耐湿性外袋内に配置されたいずれの発熱剤内袋の位置とも重なることのないように設定することが好ましい。 As mentioned above, the exothermic agent bag used in the exothermic laminate of the present invention is a water permeable inner bag in which the exothermic agent is encapsulated in a water permeable bag body such as a non-woven fabric. The heat-generating agent pack itself enclosed in a water-permeable bag is commercially available as a component of a heat-generating laminate or as a heat-generating pack for other purposes. A moisture-resistant outer bag that is larger in size than a separately prepared heat-generating agent inner bag (a bag body in which water vapor transmission is significantly suppressed; for example, a metal layer is formed on the surface of a metal film or synthetic resin film by means such as vapor deposition). (having a formed configuration) are placed approximately equally on the left and right sides. Note that it is preferable to set the cutting position of the exothermic agent bag by the breaking string so that it does not overlap with the position of any of the exothermic agent inner bags arranged in the moisture-resistant outer bag.

発熱性積層体1の発熱剤袋を図1乃至3に示した構成とすることによって、破断用紐体6を引っ張ることで実現する水袋と発熱剤袋の耐湿性外袋の破断と開裂とが比較的弱い引っ張り力であっても容易かつ確実に実現する。また、左右に分割配置した発熱剤のそれぞれが不織布などで形成させた内袋に詰められていると、発熱剤袋(外袋4)の破断・開裂によっても、透水性袋体に発熱剤を内包している発熱剤内袋の破断や開裂は発生することなく、発熱剤は透水性袋体に内包された状態を維持されるため、発熱剤の透水性袋体の外部への飛散や水蒸気の上昇に伴っての上昇は発生しにくい。このため、従来の加熱装置で問題となりがちな発熱剤残渣による加熱対象の食品の汚染が効果的に防止される。 By configuring the exothermic agent bag of the exothermic laminate 1 as shown in FIGS. 1 to 3, the water bag and the moisture-resistant outer bag of the exothermic agent bag can be broken and torn by pulling the breaking string 6. can be easily and reliably realized even with a relatively weak tensile force. In addition, if the exothermic agents arranged on the left and right are each packed in an inner bag made of non-woven fabric, even if the exothermic agent bag (outer bag 4) breaks or rips, the exothermic agent will be transferred to the water-permeable bag. The exothermic agent inner bag does not break or rupture, and the exothermic agent remains encapsulated in the water-permeable bag, preventing the exothermic agent from scattering to the outside of the water-permeable bag or causing water vapor. It is unlikely that a rise will occur as a result of a rise in . Therefore, contamination of the food to be heated due to exothermic agent residue, which tends to be a problem with conventional heating devices, is effectively prevented.

1 発熱性積層体
2 上面が開口した四角い皿状の箱体
3 水袋
4 発熱剤袋(外袋)
4a 発熱剤内袋
4b 発熱剤内袋
5 支持板
6 破断用紐体
矢印(→) 破断用紐体の引っ張り方向
1 Heat-generating laminate 2 Square dish-shaped box with an open top 3 Water bag 4 Heat-generating agent bag (outer bag)
4a Heat generating agent inner bag 4b Heat generating agent inner bag 5 Support plate 6 Breaking string arrow (→) Pulling direction of breaking string

Claims (2)

上面が開口した四角い皿状の箱体の内部に水不透過性かつ易引き裂き性の袋に水を収容してなる水袋と水との接触により発熱する化学発熱剤を袋状容器に収容した発熱剤袋とが、それらの袋の間に介在する開口を備えた支持板を介して、上から順に重ねられた状態で支持板に固定されており、さらに、一方の端部が該支持板に固定され、他方の端部が、水袋の上表面と下表面の両面の周囲の前後そして発熱剤袋の上表面と下表面の両面の周囲の前後を巻き回された上で、上記箱体の前方から引き出されている水袋と発熱剤袋の引き裂き用の紐体が取り付けられている発熱性積層体を備えた加熱装置であって、
化学発熱剤の袋状容器が、水不透過性かつ易引き裂き性の金属フィルム製もしくは表面に金属層が形成された合成樹脂フィルム製の容器であり、その袋状容器の内部に化学発熱剤が空白領域を介して左右に分割されている状態で収容されていること、該袋状容器の内部で左右に分割配置されている化学発熱剤のそれぞれが水透過性あるいは水溶解性の内袋に収容されていること、そして水袋と発熱剤袋の引き裂き用の前記の紐体が、上記空白領域の上側と下側とを跨がるように巻き回されているおり、さらに箱体の上面には多孔性のプラスチックシートが貼り付けられている加熱装置
A water bag is formed by storing water in a water-impermeable and easily tearable bag inside a square dish-shaped box with an open top, and a chemical exothermic agent that generates heat when it comes into contact with water is stored in the bag-like container. The exothermic agent bags are fixed to the support plate in a stacked state from above through a support plate having an opening interposed between the bags, and further, one end is fixed to the support plate in a stacked state from above. and the other end is wrapped around the front and back of both the upper and lower surfaces of the water bag and the front and back of both the upper and lower surfaces of the heating agent bag, and then A heating device comprising a heat generating laminate to which a string for tearing a water bag pulled out from the front of the body and a heat generating agent bag is attached,
The bag-like container for the chemical heating agent is made of a water-impermeable and easily tearable metal film or a synthetic resin film with a metal layer formed on the surface, and the chemical heating agent is inside the bag-like container. The chemical exothermic agent divided left and right inside the bag-like container is housed in a state where it is divided into left and right sides through a blank area, and each of the chemical exothermic agents divided left and right inside the bag-like container is placed in a water-permeable or water-soluble inner bag. The above-mentioned string for tearing the water bag and exothermic bag is wound so as to span the upper and lower sides of the blank area , and is further wrapped around the upper and lower sides of the blank area. A heating device has a porous plastic sheet attached to it .
請求項1に記載の加熱装置の箱体の上面に加熱対象物を載置し、その後、水袋と発熱剤袋の引き裂き用の紐体の前方の部分を引っ張って箱体の前方に引き出し、水袋と発熱剤袋とを引き裂くことにより発熱反応を起こさせて加熱対象物を加熱することを特徴とする加熱対象物の加熱方法。
Place the object to be heated on the top surface of the box of the heating device according to claim 1, and then pull the front part of the string for tearing the water bag and the exothermic bag to the front of the box, A method for heating an object to be heated, characterized in that the object to be heated is heated by causing an exothermic reaction by tearing a water bag and a heating agent bag .
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JP2008089214A (en) 2006-09-29 2008-04-17 Yoshizawa:Kk Heat generating implement and food heating container comprising the same
JP2010068846A (en) 2008-09-16 2010-04-02 Yoshizawa:Kk Heat-generating device using chemical heat-generating agent, and portable food container with the heat-generating device using chemical heat-generating agent
JP2018042605A (en) 2016-09-12 2018-03-22 株式会社ヨシザワ Exothermic laminate enabling long-term storage
JP7240051B1 (en) 2022-08-04 2023-03-15 株式会社ヨシザワ Heat-generating laminate and heating device
JP7306763B1 (en) 2022-09-29 2023-07-11 株式会社ヨシザワ Heat-generating laminate suitable for cold storage and heating device

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