JP7389592B2 - Beer-taste beverage and its manufacturing method - Google Patents

Description

The present invention relates to a beer-taste beverage, a method for producing the same, and the like.

Beer-taste beverages are beverages that have beer-like flavor and bitterness (beer-like flavor and flavor), and are beer-taste alcoholic beverages that belong to beer, low-malt beer, other brewed liquors, and liqueurs as defined by the Liquor Tax Act. However, in recent years, non-alcoholic beer-flavored drinks have also been sold.

Furthermore, Patent Document 1 discloses a beer-taste beverage containing 0.3 to 5 ppm of quacin and/or 0.5 to 5 ppm of quinine as a beer-taste beverage having beer-like bitterness and aftertaste, and hops. Also disclosed are configurations that are substantially free of iso-α-acids derived from.

Japanese Patent Application Publication No. 2017-006077

In addition, the present inventors have developed a beer-taste beverage containing berberine, which is a raw material capable of imparting a refreshing bitterness and bitterness sharpness. Berberine is excellent in that it can impart a refreshing bitterness and sharp bitterness to beverages without using hops, but it also contains some unique aromas that are undesirable for beer-taste beverages. There is room for further improvement in terms of use in beverages.

The present invention has been made in view of the above points, and aims to provide a beer-taste beverage that has beer-like flavor and bitterness without using hops, and a method for producing the same.

In order to solve the above-mentioned problems, the present inventor made extensive studies and created a beer-taste beverage that contains berberine and 0.50 mg/L or more of ethyl acetate, thereby providing a beer-like flavor without using hops. The present inventors have discovered that a beer-taste beverage with a bitter taste can be obtained, and have completed the present invention.

That is, the present invention has the following (1) to (6).
(1) A beer-taste beverage containing berberine and 0.50 mg/L or more of ethyl acetate.
(2) The beer-taste beverage according to (1), wherein the berberine content is 1.2 mg/L or more and 14 mg/L or less.
(3) The beer-taste beverage according to (1) or (2), containing the ethyl acetate in an amount of 4.0 mg/L or more and 50 mg/L or less.
(4) The beer-taste beverage according to any one of (1) to (3), which has a bitterness value (BU) of less than 5.
(5) A method for producing a beer-taste beverage, comprising the steps of containing berberine, containing ethyl acetate, and controlling the content of ethyl acetate to 0.50 mg/L or more.
(6) A method for improving beer-like flavor and bitterness in a beer-taste beverage, which comprises containing berberine and ethyl acetate, and making the content of ethyl acetate 0.50 mg/L or more.

According to the present invention, a beer-taste beverage having beer-like flavor and bitterness can be provided without using hops.

The present invention will be explained.
The present invention relates to a beer-taste beverage containing berberine and 0.50 mg/L or more of ethyl acetate (hereinafter also referred to as "beer-taste beverage of the present invention"), a step of incorporating berberine, and acetic acid. A method for producing a beer-taste beverage (hereinafter referred to as "the method for producing a beer-taste beverage according to the present invention") comprising a step of incorporating ethyl and a step of adjusting the content of ethyl acetate to 0.50 mg/L or more. ) etc.

First, the beer-taste beverage of the present invention will be explained in detail.
In the present invention, the term "beer-taste beverage" refers to a beverage that has a beer-like flavor and bitterness, that is, a beer-like flavor and flavor. Therefore, the "beer-taste beverage" of the present invention includes beer-like beverages that belong to the sparkling alcoholic beverages (beer, low-malt beer, other brewed liquors, and liqueurs) defined by the Liquor Tax Act (Act No. 6 of 1950). Alcoholic beverages that do not belong to the sparkling alcoholic beverages defined by the Liquor Tax Law mentioned above but have a beer-like flavor and flavor (e.g. non-sparkling alcoholic beverages), and alcoholic beverages that have a beer-like flavor and flavor. Soft drinks (for example, non-alcoholic beer-taste drinks), etc. are included. Furthermore, the beer-taste beverage of the present invention may be a fermented beverage produced through a fermentation process using yeast or the like (a process in which yeast or the like generates metabolites such as alcohol from organic substances such as sugars), or may be a fermented beverage produced through a fermentation process using yeast or the like (a process in which yeast or the like produces metabolites such as alcohol from organic substances such as sugars), or may be a fermented beverage produced through this fermentation process. It may also be a non-fermented beverage produced without any process.

The beer-taste beverage of the present invention contains berberine (C ₂₀ H ₁₈ NO ₄ ⁺ ). Berberine is a compound represented by the following formula (1), and is a bitter component contained in yellowfin tuna. Note that Phellodendron amurense is a deciduous tree of the Rutaceae family, Phellodendron amurense, also called Phellodendron amurense.
Berberine can be contained using yellowfin tuna (dried and pulverized bark, etc.), yellowfin tuna extract, berberine preparations (including preparations of berberine salts), and the like. Here, the yellowfin tuna extract is an extract obtained by extracting yellowfin tuna (for example, bark, etc.) using one or more solvents selected from the group consisting of water, hot water, and ethanol, and this solvent Also included are concentrates and dried products from which at least a portion of the organic matter has been removed, and diluted products diluted with the above-mentioned solvents. Furthermore, this yellowfin tuna or yellowfin tuna extract may be a commercially available product (for example, a food additive).
By containing berberine, the beer-taste beverage of the present invention has a refreshing bitterness and sharp bitterness even without using hops.

Further, the beer-taste beverage of the present invention contains 0.50 mg/L or more of ethyl acetate (C ₄ H ₈ O ₂ ) in addition to the above-mentioned berberine. Ethyl acetate is a compound formed by an ester bond of acetic acid and ethanol, and is one of the aroma components. In the beer-taste beverage of the present invention, by setting the content of ethyl acetate to 0.50 mg/L or more based on the total amount of the beer-taste beverage, the flavor and bitterness typical of beer can be maintained, but it is not desirable as a beer-taste beverage. It is possible to suppress the pine-like scent.
Note that this ethyl acetate may be contained using a commercially available preparation, or may be contained using ethyl acetate-containing raw materials (for example, distilled spirits, fragrances, etc.), or it may be contained using a product produced by fermentation. It may be something.

In the beer-taste beverage of the present invention, the content of ethyl acetate is preferably 0.80 mg/L or more, more preferably 1.0 mg/L or more, and 2.0 mg/L or more. It is more preferably 3.0 mg/L or more, even more preferably 4.0 mg/L or more, even more preferably 4.5 mg/L or more, and even more preferably 5.0 mg/L. It is more preferably at least 8.0 mg/L, even more preferably at least 10 mg/L. As a result, in the beer-taste beverage of the present invention containing berberine, the pine-like aroma that is undesirable as a beer-taste beverage is further suppressed, and the beer-taste beverage has a more beer-like flavor.

Further, in the beer-taste beverage of the present invention, the content of ethyl acetate is preferably 60 mg/L or less, more preferably 50 mg/L or less, still more preferably 45 mg/L or less, even more preferably 40 mg/L or less, More preferably, when the concentration is adjusted to 35 mg/L or less, and even more preferably 30 mg/L or less, the pine-like aroma that is undesirable as a beer-taste beverage is suppressed, and a more beer-like flavor and pleasant bitterness (beer-taste beverage It is very suitable because it can provide a beer-taste beverage with a pleasant bitterness that increases drinkability.
For example, an example of a suitable range for the ethyl acetate content in the beer-taste beverage of the present invention is a range of 4.0 mg/L or more and 50 mg/L or less.

Furthermore, in the beer-taste beverage of the present invention, the content of the above-mentioned berberine is preferably 0.6 mg/L or more, more preferably 1.0 mg/L or more, and even more preferably 1.2 mg/L, based on the total amount of the beer-taste beverage. L or more, more preferably 2.0 mg/L% or more, still more preferably 3.0 mg/L or more, even more preferably 4.0 mg/L or more, and/or the content is preferably 20 mg /L or less, more preferably 14 mg/L or less, further preferably 12 mg/L or less, still more preferably 10 mg/L or less, still more preferably 8.0 mg/L or less. When the content of berberine is within this range, the beer-like flavor and pleasant bitterness of the beer-taste beverage of the present invention can be further improved.
For example, an example of a suitable range for the berberine content in the beer-taste beverage of the present invention is a range of 1.2 mg/L or more and 14 mg/L or less.

The ratio of the berberine content and the ethyl acetate content in the beer-taste beverage of the present invention is 1:1 to 25. The ratio is preferably 1:1.2 to 15, more preferably 1:1.5 to 10. This is because the beer-like flavor and pleasant bitterness can be improved in a well-balanced manner.

Here, the content of ethyl acetate in the beer-taste beverage of the present invention is determined by the revised BCOJ beer analysis method (published by the Brewing Association of Japan, edited by the Beer Brewers Association International Technical Committee [Analysis Committee], expanded and revised in 2013). This value is measured by the method described in "8.22 Low boiling point aroma components".
Further, the berberine content in the beer-taste beverage of the present invention is a value measured based on the 17th edition of the Japanese Pharmacopoeia.

The beer-taste beverage of the present invention may contain a hop-derived component, but is characterized by having beer-like flavor and bitterness even if it does not contain a hop-derived component. For example, the beer-taste beverage of the present invention may have a bitterness value (BU) of less than 5, 4.5 or less, 4.0 or less, or 3.5 or less. 3.0 or less, 2.5 or less, 2.0 or less, 1.5 or less, 1.0 or less It may be 0.5 or less. This bitterness value can be adjusted by adjusting the amount of hops used, variety, type, timing of addition, etc. Here, this bitterness value (BU) is the "8.15 Bitterness" of the Revised BCOJ Beer Analysis Method (published by the Brewing Association of Japan, edited by the Beer Brewers Association International Technical Committee [Analysis Committee], expanded and revised in 2013). This is the value measured by the method described in "Value".

When using hops in the beer-taste beverage of the present invention, examples of the types include dried hops, hop pellets, hop extracts, and the like. The hops used may be processed hop products such as low hops, hexahops, tetrahops, and isolized hop extracts. These may be used alone or in combination of two or more, and are not particularly limited.
Furthermore, in addition to berberine, the beer-taste beverage of the present invention includes, for example, gentian and/or gentian extract, caffeine, quacin, chrysanthemum extract, peptides, theobromine, naringin, bittern extract, bittern wormwood extract, Other materials that can be substituted for hops, such as cinchona extract, and other bitter materials such as bitter amino acids (one or more selected from the group consisting of Val, Met, Ile, Leu, and His) may also be used. can.

In addition to the above-mentioned ethyl acetate and berberine, the beer-taste beverage of the present invention can optionally use wheat or processed wheat products, rice, corn, beans, fruits, spices, etc. as raw materials. Furthermore, when producing fermented beverages, saccharides may be used as raw materials to promote fermentation and the like. Note that this "raw material" refers to materials other than water and hops among all the raw materials used for producing the beer-taste beverage of the present invention.
Here, examples of the above-mentioned wheat include barley, wheat, rye, oats, oats, pigeons, and oats. In addition, examples of processed wheat products include wheat extract, malt, and malt extract. This barley extract is obtained by extracting an extract containing sugar and nitrogen from barley. Malt is obtained by germinating wheat. Malt extract is obtained by extracting an extract containing sugar and nitrogen from malt.

Furthermore, the beer-taste beverage of the present invention includes acidulants, coloring agents, sweeteners, high-intensity sweeteners, antioxidants, flavoring agents, and other additives that can be normally incorporated into beverages within a range that does not affect the effects of the present invention. It may also contain salts and the like. Examples of the acidulant include phosphoric acid, lactic acid, sodium lactate, DL-malic acid, sodium DL-malate, citric acid, trisodium citrate, adipic acid, glucono delta-lactone, gluconic acid, potassium gluconate, and glucone. Sodium succinate, monosodium succinate, disodium succinate, sodium acetate, DL-tartaric acid, L-tartaric acid, sodium DL-tartrate, sodium L-tartrate, glacial acetic acid, fumaric acid, monosodium fumarate, etc. It will be done. Examples of the coloring agent include caramel color, gardenia color, fruit juice color, vegetable color, and synthetic color. Examples of sweeteners include high-fructose corn syrup, glucose, galactose, mannose, fructose, lactose, sucrose, maltose, glycogen, and starch. Examples of high-intensity sweeteners include neotame, acesulfame K, sucralose, saccharin, sodium saccharin, disodium lythyrrhizinate, cyclamate, dultin, stevia, glycyrrhizin, thaumatin, monellin, aspartame, alitame, and the like. Examples of antioxidants include vitamin C, vitamin E, and polyphenols. Examples of the salts include common salt (sodium chloride), acidic potassium phosphate, acidic calcium phosphate, ammonium phosphate, magnesium sulfate, calcium sulfate, potassium metabisulfite, calcium chloride, magnesium chloride, potassium nitrate, ammonium sulfate, and the like.

Furthermore, the beer-taste beverage of the present invention may be a beer-taste alcoholic beverage. The alcohol content in that case is not particularly limited, but as an example, the lower limit is 1 v/v% or more, more preferably 2 v/v% or more, even more preferably 3 v/v% or more, even more preferably 4 v/v% or more, More preferably, it is 5v/v% or more, and the upper limit is preferably 20v/v% or less, more preferably 15v/v% or less, still more preferably 10v/v% or less, still more preferably 9v/v% or less, and Preferably it is 8v/v% or less, more preferably 7v/v% or less, still more preferably 6v/v% or less.
Alternatively, the beer-taste beverage of the present invention has an alcohol content of less than 1 v/v%, more preferably less than 0.5 v/v%, even more preferably less than 0.1 v/v%, even more preferably less than 0.005 v/v%. It may be a non-alcoholic beer-taste beverage.

Here, in the present invention, "alcohol content (v/v%)" refers to the revised BCOJ beer analysis method (published by the Brewing Association of Japan, edited by the Beer Brewers Association International Technical Committee [Analysis Committee], expanded in 2013). This is the value measured by the method described in "8.3 Alcohol" (8.3.6 Alcoholizer method) of the revised version. In the present invention, "alcohol" means ethanol.

The alcohol content of the beer-taste beverage of the present invention is determined by the method of controlling fermentation conditions in the manufacturing process, the raw material liquid (process liquid that is the basis of the beer-taste beverage in the manufacturing process of the beer-taste beverage of the present invention) It can be adjusted by blending distilled spirits such as shochu, brandy, various spirits (vodka, etc.), and alcohol for raw materials.

Furthermore, it is preferable that the beer-taste beverage of the present invention is effervescent, since the beer-like flavor and bitterness are more likely to be felt when drinking the beer-taste beverage. Here, in the present invention, "foaming property" means that the carbon dioxide pressure at 20° C. is 0.049 MPa (0.5 kg/cm ² ) or more. The carbon dioxide pressure may be set to 0.294 MPa (3.0 kg/cm ² ) or less. Note that the carbon dioxide gas may be generated by fermentation, or may be provided by carbonated water or a carbonation (carbon dioxide gas injection) process. This carbonation step may be performed in a batch manner or continuously in an in-line manner in which a carbon dioxide gas injection system (carbonator) is installed in the piping. Further, this carbonation step is preferably carried out at a liquid temperature of 10° C. or lower (more preferably 4° C. or lower) in order to avoid the occurrence of foaming.
The beer-taste beverage of the present invention may be a non-sparkling beer-taste beverage having a carbon dioxide gas pressure of less than 0.049 MPa (0.5 kg/cm ² ) at 20°C.

Furthermore, the beer-taste beverage of the present invention may further contain any components other than those mentioned above, within a range that does not affect the effects of the present invention.

Next, the method for producing a beer-taste beverage according to the present invention will be described in detail.
The method for producing a beer-taste beverage according to the present invention includes a step of incorporating berberine, a step of incorporating ethyl acetate, and a step of adjusting the content of ethyl acetate to 0.50 mg/L or more with respect to the total amount of the beer-taste beverage. Including this, the other steps may be carried out according to conventional methods and are not particularly limited. Note that the step of incorporating ethyl acetate may include a fermentation step of producing ethyl acetate using microorganisms such as yeast. In addition to the above steps, the method may include a step of adjusting the content of berberine to a predetermined range, and a step of further adjusting the content of ethyl acetate to a predetermined range. Moreover, each of the above-mentioned steps may be performed in combination of two or more steps in one step, or each step may be performed separately into two or more steps.

In addition, in the method for producing a beer-taste beverage according to the present invention, a beer-taste beverage having beer-like flavor and bitterness can be produced by including each of the above-mentioned steps, and therefore a step of adding hops is not required. You can. In other words, the method for producing a beer-taste beverage according to the present invention may have a configuration that does not include the step of adding hops.
Alternatively, even if the method for producing a beer-taste beverage according to the present invention includes a step of adding hops, it may also include a step of making the bitterness value (BU) less than 5.

As an example of the method for producing a beer-taste beverage according to the present invention, first, a liquid mixture containing berberine and a predetermined amount of ethyl acetate is prepared, and if necessary, hops or the like is added to this liquid mixture. Accordingly, the alcohol content is adjusted by adding spirits, etc., the carbon dioxide pressure is adjusted by adding carbonated water, carbonation, etc., and the product is made into a product by performing filtration, sterilization, etc. Further, a container filling step may be performed in which the product is filled into a container made of metal such as aluminum or steel, a glass container, a plastic bottle container, a paper container, a pouch (plastic pouch) container, or the like and sealed. In particular, it is more preferable to fill a metal container and seal it, since it has high barrier properties against gas, moisture, light, etc., and can maintain quality at room temperature for a long period of time.

Further, as an example of the method for producing the beer-taste fermented beverage according to the present invention, first, in the brewing process, wort is prepared by a conventional method using raw materials containing malt, barley, etc. Or, add yellowfin tuna extract and hops if necessary to this wort and perform a boiling process, then remove the precipitate, add beer yeast to the pre-fermentation liquid, and ferment under specified conditions. A method is presented for carrying out a process to produce a predetermined amount of ethyl acetate. After fermentation, the fermented liquor undergoes storage (aging process) and filtration processes to produce the product. If necessary, the alcohol content may be adjusted by adding spirits or removing alcohol, or carbonation may be performed in any step. Alternatively, the product may be similarly filled into a metal container and sealed.

In all of the above-mentioned production methods, berberine is added not only to the process of preparing the blended liquid and pre-fermentation liquid, but also to the boiling process, fermentation process, adjustment process of alcohol content and carbon dioxide gas pressure, and aging process. , filtration process, sterilization process, etc. In addition to producing ethyl acetate in the fermentation process, preparations or raw materials containing ethyl acetate may be added in any process. The same applies to the adjustment of the berberine content and the adjustment of the ethyl acetate content.

The present invention provides a method for improving beer-like flavor and bitterness in a beer-taste beverage, which includes berberine and ethyl acetate, and the content of ethyl acetate is 0.50 mg/L or more. It can also be said that it is something that is provided. In this method, in the beer-taste beverage, for example, by setting the berberine content to 1.2 mg/L or more and 14 mg/L or less, or by setting the ethyl acetate content to 4.0 mg/L or more and 50 mg/L or less, It is also possible to provide a method for suppressing pine-like aroma and improving beer-like flavor and pleasant bitterness in beer-taste beverages.

Examples of the present invention will be described below, but the present invention is not limited to the following examples, and various modifications can be made within the technical idea of the present invention.

First, caramel color was added to the base pure water so that the content of the final sample was 0.04 w/v%, and the ethyl acetate preparation was added to the dissolved liquid so that the ethyl acetate content of the final sample was 15 mg/L. Furthermore, yellowfin tuna extract (water extract) was added so that the berberine content of the final sample was as shown in the upper part of Table 1 below. Then, the carbon dioxide pressure was adjusted to 2.2 kg/cm ² using carbonated water. In this way, non-alcoholic beer-taste beverages of Samples 1-1 to 1-6 having an ethyl acetate content of 15 mg/L and different berberine contents were prepared. As a control, Sample 1-0 was also prepared in the same manner as above except that it did not contain berberine.

Separately, caramel color was added to the base pure water so that the content of the final sample was 0.04 w/v%, and yellowfin tuna extract (water extract) was added to the dissolved liquid for the final sample. was added so that the berberine content was 4.0 mg/L, and an ethyl acetate preparation was added so that the ethyl acetate content of the final sample was as shown in the upper part of Table 1 below. Then, the carbon dioxide pressure was adjusted to 2.2 kg/cm ² using carbonated water. In this way, non-alcoholic beer-taste drinks of Samples 2-1 to 2-6 having a berberine content of 4.0 mg/L and different ethyl acetate contents were prepared. As a control, sample 2-0 was also prepared in the same manner as above except that it did not contain ethyl acetate.

Furthermore, apart from these, caramel coloring was added to the base pure water so that the content of the final sample was 0.04 w/v%, and the ethyl acetate preparation was added to the dissolved liquid. was added so that the berberine content of the final sample was 15 mg/L, and yellowfin tuna extract (water extract) was added so that the berberine content of the final sample was 4.0 mg/L, and the alcohol content of the final sample was approximately 5.0 mg/L. Spirits were added to give a concentration of 0v/v%. A beer-taste alcoholic beverage (sample 3-1) was also prepared in which the carbon dioxide pressure was adjusted to 2.2 kg/cm ² using carbonated water.

Then, each sample and control were trained for pleasant bitterness (pleasant bitterness that increases drinkability) and pine-like aroma derived from yellowfin tuna extract (unfavorable aroma for beer-taste beverages). A comparative sensory evaluation was conducted by five panelists with sensory discrimination abilities using the evaluation criteria shown below.

[Evaluation criteria for pleasant bitterness]
The pleasant bitterness in Sample 1-0 is set as 1 (almost not felt), and as a comparison with this sample 1-0, it is rated as 5 (very noticeable), 4 (feelable), 3 (slightly bitter), and 2 (slightly felt). ), 1 (almost not felt: equivalent to sample 1-0), and a comparative sensory evaluation was performed.
[Evaluation criteria for pine scent]
The pine-like scent in sample 1-0 was rated 5 (almost not felt), and in comparison with this sample 1-0, 5 (almost not felt: same as sample 1-0), 4 (slightly felt), 3 ( Comparative sensory evaluation was performed using five levels: 2 (slightly felt), 2 (slightly felt), and 1 (strongly felt).

The sensory evaluation results (average evaluation of five panelists) are shown in the lower part of Table 1 below. From this result, it was revealed that by containing a predetermined amount or more of ethyl acetate in a beer-taste beverage containing berberine, the pine-like aroma, which is an undesirable aroma for a beer-taste beverage, is suppressed. In particular, by setting the ethyl acetate content to 1 to 60 mg/L, more preferably 7 to 30 mg/L, and the berberine content to 1.2 to 14 mg/L, the pine-like aroma can be suppressed. In addition, it has been revealed that the beer-taste beverage has a pleasant bitterness that is pleasant to the mouth, and has an improved beer-like flavor and bitterness.

Claims (4)

A beer-taste beverage having a bitterness value (BU) of less than 5, containing berberine of 1.2 mg/L or more and 14 mg/L or less , and further containing ethyl acetate of 1.0 mg/L or more and 60 mg/L or less . The beer-taste beverage according to claim 1 , containing the ethyl acetate in an amount of 4.0 mg/L or more and 50 mg/L or less. a step of containing berberine, a step of containing ethyl acetate, a step of making the content of berberine 1.2 mg/L or more and 14 mg/L or less, and a step of making the content of ethyl acetate 1.0 mg/L or more and 60 mg or less. /L or less , a method for producing a beer-taste beverage having a bitterness value (BU) of less than 5 . A beer-taste beverage with a bitterness value (BU) of less than 5 , containing berberine and ethyl acetate, and the content of berberine is 1.2 mg/L or more and 14 mg/L or less, and the content of ethyl acetate is A method for improving beer-like flavor and bitterness in a beer-taste beverage with a bitterness value (BU) of less than 5, in which the bitterness value (BU) is set to 1.0 mg/L or more and 60 mg/L or less .