JP7238216B1 - absorbent article - Google Patents

Abstract

The present invention provides a fluff pulp pulp sheet capable of producing an absorbent article in which the amount of backflow of water-absorbing liquid is reduced and rashes on the skin are suppressed. A pulp sheet for fluff pulp according to one aspect of the present invention contains hardwood kraft kraft pulp and softwood kraft pulp, and the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is 15/85 or more. It is 50/50 or less, and the content of the acacia wood in the raw material wood of the bleached hardwood kraft pulp is 20% by mass or more and 100% by mass or less. The kappa number of the bleached hardwood kraft pulp is preferably 0.3 or less. [Selection figure] None

Description

The present invention relates to a pulp sheet for fluff pulp.
This application claims priority based on Japanese Application No. 2020-215691 filed on December 24, 2020, and incorporates all the content described in the above Japanese Application.

Fluff pulp is produced by defibrating wood pulp by mechanical treatment, and is used as an absorbent member of absorbent articles such as disposable diapers.

As a fluff pulp pulp used in such absorbent articles, wood pulp derived from coniferous trees, which has good bulkiness, water absorption and fibrillating properties, is widely used (see Patent Document 1).

JP 2012-211411 A

On the other hand, hardwood-derived wood pulp is relatively inexpensive compared to softwood-derived pulp. If wood pulp derived from broad-leaved trees is used for the material, the liquid absorption rate may be likely to decrease. In addition, absorbent articles are required to improve not only the water absorption performance but also the effect of suppressing rashes on the skin.

The present invention was made based on the above circumstances, and provides a pulp sheet for fluff pulp that can produce absorbent articles that achieve both absorption speed and reversion property and suppress skin rashes. With the goal.

The pulp sheet for fluff pulp according to one aspect of the present invention contains bleached hardwood kraft pulp and bleached softwood kraft pulp, and the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is 15/85 or more and 50/50 or less. and the content of the acacia wood in the raw material wood of the bleached hardwood kraft pulp is 20% by mass or more and 100% by mass or less.

According to the present invention, it is possible to provide a fluff pulp pulp sheet that can reduce the backflow amount of water-absorbing liquid and can produce an absorbent article that suppresses rashes on the skin.

[Description of the embodiment of the present invention]
The pulp sheet for fluff pulp according to one aspect of the present invention contains bleached hardwood kraft pulp and bleached softwood kraft pulp, and the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is 15/85 or more and 50/50 or less. and the content of the acacia wood in the raw material wood of the bleached hardwood kraft pulp is 20% by mass or more and 100% by mass or less.

The pulp sheet for fluff pulp is made by blending bleached hardwood kraft pulp and bleached softwood kraft pulp in a well-balanced manner at a specific mass ratio, thereby imparting bulkiness and liquid absorbency to the absorbent article due to the bleached softwood kraft pulp. , broad-leaved bleached kraft pulp can impart surface density, an effect of reducing the backflow of water-absorbing liquid, and an effect of suppressing skin rashes. In addition, since the content of acacia material in the raw material wood of the broad-leaved bleached kraft pulp is 20% by mass or more and 100% by mass or less, a certain amount or single acacia material with a large fiber width can be blended, so that uniform pulp Since sufficient voids can be secured between fibers, it is possible to further achieve both absorption speed and reversion property in the absorbent article. Therefore, the fluff pulp pulp sheet reduces the backflow amount of water-absorbing liquid and provides a fluff pulp pulp sheet capable of producing an absorbent article that suppresses rashes on the skin.

The kappa number of the bleached hardwood kraft pulp is preferably 0.3 or less. When the kappa number of the bleached hardwood kraft pulp is 0.3 or less, the effect of suppressing skin irritation can be improved. The kappa number is measured according to JIS-P8211 (2011).

[Details of the embodiment of the present invention]
Hereinafter, a pulp sheet for fluff pulp according to one embodiment of the present invention will be described in detail. Unless otherwise specified, the amount of each material to be added to the pulp sheet base material (absolute dry internal addition amount) refers to the mass ratio to the absolute dry mass of the pulp of the pulp sheet base material.

<Pulp sheet for fluff pulp>
The pulp sheet for fluff pulp can be obtained by papermaking a slurry containing the raw material pulp.

(raw material pulp)
Virgin pulp, for example, can be used as raw material pulp. Chemical pulp is preferable as raw material pulp for use in the pulp sheet for fluff pulp. As the chemical pulp, a combination of softwood bleached kraft pulp (NBKP) and hardwood bleached kraft pulp (LBKP) is preferable. When the pulp sheet for fluff pulp contains softwood bleached kraft pulp, the bulkiness and liquid absorbency of the absorbent article can be improved. In addition, since the pulp sheet for fluff pulp contains bleached hardwood kraft pulp, the density of the surface of the absorbent article is increased, and the effect of reducing the amount of water-absorbing liquid flowing back into the absorbent article and the effect of suppressing skin rashes are improved. can.

(Bleached hardwood kraft pulp)
The bleached hardwood kraft pulp is preferably a bleached hardwood kraft pulp made from acacia wood or eucalyptus wood.

Acacia wood shrinks little when dried, is resistant to impact, and is strong and hard. The pulp obtained from acacia wood inherits its original properties, and is a useful raw material pulp with high water absorption and drying properties. is. Eucalyptus wood belongs to the genus Eucalyptus, and Eucalyptus globulus, Eucalyptus grandis, Eucalyptus europhylla, Eucalyptus nitens, Eucalyptus regnans, etc. have been widely used as raw material pulp materials for paper manufacturing for a long time. The fiber lumen (lumen) is hard to collapse and is rigid, and by blending this pulp fiber, a bulky and low-density pulp sheet for fluff pulp can be obtained. As for bleached hardwood kraft pulp, acacia wood has a larger fiber width than eucalyptus wood, so it is bulky. preferable.

(Content of acacia wood in raw material wood for hardwood kraft pulp)
The lower limit of the acacia content in the raw material wood for the hardwood kraft pulp is preferably 20% by mass, more preferably 50% by mass. The upper limit of the acacia material content is preferably 100% by mass, more preferably 80% by mass. The content of acacia in the raw material wood of the hardwood kraft pulp of the pulp sheet for fluff pulp is in the above range, so that the fiber length is shorter than that of the bleached softwood kraft pulp, and the fibers tend to be tightly clogged. Even if the fibers are oriented in any direction (for example, the length direction, width direction, or thickness direction of the absorbent article), the gaps between the fibers can be uniformly secured particularly well. It is possible to achieve both the absorption speed and the reversion property required for the pulp sheet for fluff pulp. If the ratio of rigid eucalyptus wood is increased, for example, if the ratio of rigid eucalyptus wood is increased, the number of voids due to rigidity increases, but the voids tend to vary depending on the direction in which the fibers are oriented. Absorption speed and reversibility are likely to be uneven in the article, and as a result, these properties are likely to be lowered, which is not preferable.

The lower limit of the average fiber width of hardwood unbleached kraft pulp is preferably 16.7 μm, more preferably 16.9 μm. If the average fiber width is less than the lower limit, the voids between the fibers in the absorbent article become dense, and the absorption speed decreases, which may easily cause rashes. On the other hand, the upper limit of the average fiber width is preferably 18.2 µm, more preferably 17.7 µm. If the average fiber width exceeds the upper limit, the contact area between the pulp fibers in the fluff pulp pulp sheet becomes too large, the bonding force between the fibers increases, and the pulverizability during the manufacturing process may decrease. . If the pulverizability is too low, excessive pulverization occurs during the manufacturing process of the absorbent article, producing fine fibers, which may reduce the absorption speed of the absorbent article. Here, "average fiber width" means weight average fiber width. The weight-average fiber width is measured by JAPAN TAPPI paper pulp test method No. 1 using a fiber length measuring machine "FiberLab" manufactured by Metso Automation. 52 "Pulp and Paper--Fiber Length Test Method--Automatic Optical Measurement", measure fibers with a fiber length of 0.1 mm or more.

The lower limit of the weight average fiber length (hereinafter also referred to as the average fiber length) of unbleached hardwood kraft pulp is preferably 0.76 mm, more preferably 0.80 mm. If the average fiber length is less than the lower limit, the bulkiness of the pulp sheet for fluff pulp tends to be low, and the pulverizability during the manufacturing process may be low. On the other hand, the upper limit of the average fiber length is preferably 0.92 mm, more preferably 0.86 mm. If the average fiber length exceeds the upper limit, the voids are likely to vary depending on the direction in which the fibers are oriented in the absorbent article, which may reduce the absorption rate and reversion property. The weight-average fiber length is determined according to JAPAN TAPPI paper pulp test method No. 1 using a fiber length measuring device "FiberLab" manufactured by Metso Automation. 52 "Pulp and Paper--Fiber Length Test Method--Automatic Optical Measurement", measure fibers with a fiber length of 0.1 mm or more.

The kappa number of the bleached hardwood kraft pulp is preferably 0.3 or less. If the kappa number exceeds the upper limit, the lignin in the fiber cannot be sufficiently removed, the water absorbency of the pulp fiber becomes low, and the reversion amount decreases, which may easily cause rash.

The lower limit of the sulfidity of white liquor for cooking hardwood kraft pulp is preferably 25%, more preferably 28%. If the sulfidity is less than 25%, the pulp fibers are likely to be damaged and the absorbent article becomes dense, resulting in a decrease in the absorption speed, which may cause rashes. On the other hand, the upper limit of the sulfidity is preferably 32%, more preferably 30%. If the sulfidity exceeds the above upper limit, the pulp fibers are hard to be damaged and remain rigid, the voids of the absorbent body become uneven, the amount of backflow tends to decrease, and rashes may occur. The above sulfidity is calculated according to the following formula as the ratio of sodium sulfide to the total of sodium sulfide and caustic soda.
Sulfidity (%) = ( _Na2S /(NaOH+ _Na2S )) x 100

(Freeness of unbeaten hardwood bleached kraft pulp)
The Canadian Standard Freeness (CSF) of the unbeaten hardwood bleached kraft pulp is preferably adjusted to 520 ml or more and 580 ml or less. If the freeness of the unbeaten pulp of the bleached hardwood kraft pulp is less than 520 ml, the dewatering property deteriorates during pulp sheet production. Not only is the bond between them stronger, but also the bulkiness of the pulp sheet is reduced, which may reduce the grindability during production. On the other hand, if the Canadian standard freeness of the unbeaten pulp exceeds 580 ml, the pulp sheet will have too many voids between the fibers, which tends to cause uneven pulverization during pulverization, and in the absorbent article, reversion will decrease and rash will occur. It may occur more easily.

The lower limit of the content of bleached hardwood kraft pulp in the pulp sheet for fluff pulp is preferably 15% by mass, more preferably 20% by mass. On the other hand, the upper limit of the content of the hardwood bleached kraft pulp is preferably 50% by mass, more preferably 40% by mass. The above-mentioned "content of bleached hardwood kraft pulp in the pulp sheet for fluff pulp" is the same when pulp other than bleached hardwood kraft pulp and bleached softwood kraft pulp is contained. When the content of the bleached hardwood kraft pulp is in the above range, even if the bleached hardwood kraft pulp has a short fiber length and tends to be tightly clogged with each other when mixed with the bleached softwood kraft pulp, the fibers can be particularly well formed. Since the space between the sheets can be secured, it is possible to satisfy both the absorption speed and reversion property required for the pulp sheet for fluff pulp.

(Conifer bleached kraft pulp)
In the pulp sheet for fluff pulp, pine trees represented by radiata pine and various cedars are suitably used as raw material wood for softwood bleached kraft pulp.

(Pulp blend ratio)
The lower limit of the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp in the pulp used in the pulp sheet for fluff pulp is 15/85, preferably 20/80. If the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is less than 15/85, the gaps between the fibers in the absorbent article are likely to be uneven, and the absorbent article may tend to revert and cause rashes. On the other hand, the upper limit of the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is 50/50, preferably 40/60. When the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp exceeds 50/50, the absorbent article becomes dense, the absorption speed decreases, and rashes may occur easily.
When the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is within the above range, even if the bleached softwood kraft pulp is mixed with the bleached hardwood kraft pulp, which has a short fiber length and tends to be tightly clogged with each other. , regardless of which direction the broad-leaved tree bleached kraft pulp fibers are oriented, it is possible to ensure even and uniform gaps between the fibers. Therefore, the absorption speed required for the pulp sheet for fluff pulp and the effect of suppressing reversion and rash required for the absorbent article can be improved.

(other pulp)
The pulp sheet for fluff pulp may contain pulp other than the bleached hardwood kraft pulp and the bleached softwood kraft pulp. Examples of other pulps include soda pulp, sulfite pulp, chemithermomechanical pulp, chemrefiner mechanical pulp, and thermochemimechanical pulp. However, if the lignin in the fibers is not sufficiently removed, the water absorbency of the pulp fibers becomes low, the amount of reversion is reduced, and rashes are likely to occur, so bleached pulp from which lignin has been sufficiently removed is preferable. When the other pulp is contained, the content of the other pulp is preferably 10% by mass or less with respect to the entire pulp raw material.

(Other additives)
If necessary, other additives can be added internally to the pulp sheet for fluff pulp. Additives include, for example, fillers, pigments, sizing agents, coagulants, oil resistance agents, aluminum sulfate, retention aids, drainage improvers, dry paper strength agents, wet paper strength agents, coloring pigments, and water resistance agents. etc., can be used singly or in combination.

[Physical properties of pulp sheet for fluff pulp]
(basis weight)
Basis weight is measured in accordance with “Paper and paperboard—Method for measuring basis weight” described in JIS-P8124 (2011). The basis weight of the fluff pulp pulp sheet can be, for example, 300.0 g/cm ² or more and 1500.0 g/cm ² or less.

(density)
Density is measured according to "Paper and paperboard-Testing methods for thickness, density and specific volume" described in JIS-P8118 (2014). The lower limit of the density of the pulp sheet for fluff pulp is preferably 0.52 g/cm ³ , more preferably 0.53 g/cm ³ . The upper limit of the density of the fluff pulp pulp sheet is preferably 0.60 g/cm ³ , more preferably 0.59 g/cm ³ . When the density of the fluff pulp pulp sheet is within the above range, the fluff pulp pulp sheet obtained by mixing the hardwood bleached kraft pulp and the softwood bleached kraft pulp can improve the pulverizability during the manufacturing process, and can be evenly and uniformly. It is possible to obtain an absorbent article in which it is easy to secure voids between fibers. Therefore, it is possible to achieve a balance between the absorption speed and the amount of water-absorbent liquid returning, which are contradictory performances of the absorbent article, and to obtain an absorbent article that satisfactorily achieves both.
The density is measured in an atmosphere of 23±1° C. and 50±2% RH as described in JIS-P8111 (1998) “Paper, paperboard and pulp—standard conditions for humidity conditioning and testing”. .

(Ratio burst strength)
The specific bursting strength is a value obtained by dividing the bursting strength of paper in kilopascals (kPa) measured according to JIS-P8131 (2009) by the basis weight. The lower limit of the specific burst strength is preferably 1.20 kPa·m ² /g, more preferably 1.22 kPa·m ² /g. If the above-mentioned specific bursting strength of the pulp sheet for fluff pulp is less than 1.20 kPa·m ² /g, the fibers are likely to be cut due to over-pulverization, so that the absorbent article becomes dense, the absorption speed decreases, and rashes occur. It may become easier. On the other hand, the upper limit of the specific bursting strength of the pulp sheet for fluff pulp is preferably 1.58 kPa·m ² /g, more preferably 1.44 kPa·m ² /g. When the specific bursting strength of the fluff pulp pulp sheet exceeds 1.58 kPa m ² /g, the pulverizability during the manufacturing process is poor, and the resulting absorbent article has many voids, which causes the water-absorbing liquid to return. As it becomes easier to wear, there is a risk that rashes may occur more easily. Since the relative bursting degree of the fluff pulp pulp sheet is within the above range, the fluff pulp pulp sheet obtained by mixing the hardwood bleached kraft pulp and the softwood bleached kraft pulp can improve the grindability during the manufacturing process. In the absorbent article, since it becomes easier to ensure even and uniform voids between fibers, it is possible to achieve a good balance between the absorption rate of the absorbent article and the amount of water-absorbing liquid returning, which are contradictory performances.
In addition, the relative burst rate measurement is performed under an atmosphere of 23 ± 1 ° C. and 50 ± 2% RH, as described in JIS-P8111 (1998) "Paper, paperboard and pulp - standard conditions for humidity conditioning and testing". Measure in

[Manufacturing method of pulp sheet for fluff pulp]
The method for producing the pulp sheet for fluff pulp is not particularly limited, but for example, a cooking step of cooking raw wood to obtain unbleached pulp, a delignification step of performing delignification, and bleaching to obtain bleached pulp. a beating step of beating the bleached pulp to a desired freeness; and a step of making paper from the pulp slurry. In addition, a dehydration washing step can be appropriately provided between the above steps.

(Cooking process)
In the cooking step, raw material wood is cooked to obtain unbleached pulp. The white liquor and raw wood chips (hardwood or softwood) are charged to the digester and cooked, and the resulting (unwashed) pulp slurry mixed with black liquor is removed from the bottom of the continuous digester. The cooking method can be arbitrarily selected from commercially available kraft improvement methods such as MCC, EMCC, ITC, Lo-Solids, KobudoMari, Compact method, etc. The digester may be either a continuous digester or a batch method. Also, the cooking conditions (cooking temperature, H factor obtained by multiplying the degree of influence of the cooking temperature and the cooking time and combined into one factor, the content of active alkali or effective alkali, etc.) are not particularly limited.

(Delignification process)
In the delignification step, the unbleached pulp is delignified. Alkaline chemicals and oxygen are added to the unbleached pulp, and the lignin is decomposed at high temperature and pressure and eluted into the alkaline chemicals. The delignification process may be of low consistency (pulp density: 3% to 8%), medium consistency (pulp density: 8% to 15%), or high consistency (pulp density: 20% to 30%).

(Washing process)
In the washing process, the unbleached pulp is washed by a combination of displacement, dilution or dewatering. The washing method is not particularly limited, and washing can be performed using a known washing machine. For example, a displacement cleaning method, a dilution/dehydration method, a press cleaning method, or a cleaning method combining these methods is used. Diffusion washers, pressurized diffusion washers, belt-type washers, and the like are used as displacement wash-type washers. A vacuum filter washer, a pressure filter washer, and the like are used as the dilution/dehydration type washer. As the press cleaning method, a screw type press cleaning machine, a disc type press cleaning machine, a roll type press cleaning machine, or the like is used.

In the present invention, since it is preferable to remove lignin and reduce the kappa number, it is preferable to use a press washing machine that easily removes lignin. The pulp concentration after washing by the press washing method is preferably 30% or more, more preferably 32% or more, and even more preferably 35% or more. In the dehydration by the press washing method, the moisture inside the fibers can also be squeezed out and removed, so compared to other washing methods, it is easy to sufficiently remove the lignin released inside the pulp fibers.

(Bleaching process)
In the bleaching step, the delignified unbleached pulp is bleached to obtain bleached pulp. The bleaching method is not particularly limited, and can be bleached by a known bleaching method. For example, acid treatment, ozone bleaching, chlorine dioxide bleaching, hydrogen peroxide bleaching, alkali extraction with these, alkali extraction with oxygen added, alkali extraction with oxygen and hydrogen peroxide added, etc., can be performed singly or in combination. can do.

In the bleaching step, it is preferable to use ozone bleaching, which can adjust the water absorption and reversion properties of pulp fibers by damaging the pulp fibers. The method of ozone bleaching is not particularly limited, and can be performed at any of high concentration (30% to 40%), medium concentration (8% to 15%), and low concentration (1% to 3%), but more fibers are used. A sensitive high concentration method is preferred.
A known device can be used as the ozone generator. The generated ozone may be mixed with the pulp as it is, or dissolved in water and then mixed with the pulp.

In ozone bleaching, a lower pH promotes delignification and less damage to fibers, so it is preferable to adjust the pH according to the required quality of the fluff pulp pulp sheet. The pH in the ozone bleaching of the pulp sheet for fluff pulp is preferably 6 or less, more preferably 4 or less, and still more preferably 2-3. It is preferable that the pH of the fluff pulp pulp sheet in the ozone bleaching is within the above range because it is easy to achieve both the absorption rate and the reversion property required for the fluff pulp pulp sheet.

(Preparation process)
If necessary, the preparation step beats the bleached pulp to the desired freeness. After that, the slurry obtained by dispersing the pulp fibers in water is mixed with an additive corresponding to each paper layer as necessary to prepare the stock for each paper layer.

(Papermaking process)
Next, using these raw material slurries, paper is made by a paper machine in a neutral range so that the pH is 6 or more and 8 or less. In the papermaking process, the raw material pulp is made into paper using a papermaking machine that makes paper from the pulp raw material jetted onto the running wire. The paper machine is not particularly limited, and a known paper machine such as a fourdrinier paper machine, a cylinder paper machine, a hybrid former, a gap former, or the like can be used. be. The pulp sheet for fluff pulp can be produced by combining a single layer or a plurality of layers, but a single layer is preferable because the density in the layer can be easily made uniform.

According to the pulp sheet for fluff pulp, it is possible to produce an absorbent article that satisfies both absorption speed and reversion property and suppresses skin irritation.

[Fluff pulp]
The fluff pulp can be obtained by defibrating the fluff pulp pulp sheet into fibers by mechanical treatment. The pulp sheet for fluff pulp used for the fluffed pulp in the present invention may be in the form of either a veil or a roll, but a roll is preferred because it tends to improve the productivity of absorbent articles.

In the present invention, the equipment used for the mechanical treatment for fluffing, i.e. defibrating, is not particularly limited. A known defibrator used in the production of absorbent articles such as disposable diapers can be used, and a defibrator that utilizes frictional force or shear force as a mechanical treatment can be preferably used. Examples of the method of defibrator used for fluffing include a hammer pulverizer, an impact pulverizer, a roll pulverizer, and a jet pulverizer.

[Absorbent article]
The absorbent article is an absorbent article using the pulp sheet for fluff pulp. Since the absorbent article uses the pulp sheet for fluff pulp, both absorption speed and reversion property can be achieved, and skin rash can be suppressed. Examples of the absorbent article include, but are not particularly limited to, disposable diapers, incontinence pads, light incontinence pads, and sanitary napkins.

The manufacturing method of the absorbent article is not particularly limited, and it can be manufactured by a known method. For example, paper diapers can be manufactured by using manufacturing machines manufactured by Zuiko, Toa Kiko, and Erhardt Leimer, for example, by panel type, leg hole type, vertical flow type, horizontal flow type, and the like.

<Other embodiments>
The present invention is not limited to the above-described embodiments, and can be implemented in various modified and improved modes in addition to the above-described modes.

EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to the following examples.

[Examples 1 to 14 and Comparative Examples 1 to 4, Reference Example 1]
Pulp sheets for fluff pulp of Examples 1 to 14 and Comparative Examples 1 to 4 were produced by the following procedure.

(Cooking process)
(1) Hardwood Acacia and eucalyptus are mixed so as to have a predetermined mass ratio, white liquor having a predetermined sulfidity is added, and the liquid ratio is 6.0 (L / kg), the maximum temperature is 170 ° C. and the rotary autoclave is used. Cooking was carried out to obtain an unbleached kraft pulp with a kappa number of about 16.
(2) Softwood Add white liquor having a predetermined sulfidity to cedar, cook with a rotary autoclave at a liquor ratio of 6.0 (L / kg) and a maximum temperature of 170 ° C, and unbleached kraft with a kappa number of about 30 A pulp was obtained.

(Washing process)
After diluting the unbleached pulp to about 2% pulp consistency, the Buchner funnel was filled with a No. 2 Filter paper (manufactured by ADVANTEC) was laid and dewatered to a pulp concentration of about 12%. After that, in the case of press dehydration shown in Table 1, the unbleached pulp was sandwiched between square filter papers (manufactured by ADVANTEC), pressure was applied with a press, and dewatered to a pulp concentration of 33%. This washing step was performed twice with and without press dewatering.

(Bleaching process)
(1) Hardwood (1-1) Acid treatment Unbleached kraft pulp was adjusted to a pulp concentration of 10% and pH 3.0, and subjected to acid treatment at 90°C for 3 hours.
(1-2) Ozone Bleaching The acid-treated pulp was ozone bleached at 45° C. with ozone gas of 8.1% concentration for about 2 minutes. For ozone bleaching, ozone gas from a laboratory ozone generator of PSA Ozonizer SGA-01A-PSA4 manufactured by Sumitomo Precision Products Co., Ltd. was used.
(1-3) Chlorine dioxide bleaching The pulp after ozone bleaching is subjected to chlorine dioxide bleaching at a chlorine dioxide addition rate of 1.5%, a pulp concentration of 10% by mass, and 70 ° C., and the hardwood bleached kraft with the kappa value shown in Table 1. A pulp was obtained.
Between each bleaching step, after diluting the pulp to a concentration of about 2%, a Buchner funnel with No. 2 Filter paper (manufactured by ADVANTEC) was laid, and a dilution washing step of dehydrating to a pulp concentration of about 12% was performed twice.
(2) Softwood Unbleached kraft pulp was subjected to chlorine dioxide bleaching at a chlorine dioxide addition rate of 1.5% and a pulp concentration of 10 mass% at 70°C for 30 minutes. Subsequently, alkaline hydrogen peroxide bleaching was carried out at 1% alkali addition rate, 0.3% hydrogen peroxide addition rate, pulp concentration 10% by mass, and 70° C. for 120 minutes. Subsequently, alkaline treatment was performed at 70° C. for 120 minutes at a pulp concentration of 10% by mass at a sodium hydroxide addition rate of 0.2%. Subsequently, chlorine dioxide bleaching was performed at a chlorine dioxide addition rate of 0.3% and a pulp concentration of 10% by mass at 70° C. for 150 minutes to obtain softwood bleached kraft pulp.
Between each bleaching step, after diluting the pulp to a concentration of about 2%, a Buchner funnel with No. 2 Filter paper (manufactured by ADVANTEC) was laid, and a dilution washing step of dehydrating to a pulp concentration of about 12% was performed twice.

(Papermaking process)
The obtained bleached kraft pulp is diluted to a concentration of about 2% without beating, and then hand-made into a sheet with a basis weight of 800 g/m ² using a semi-automatic sheet machine (manufactured by Kumagai Riki Kogyo Co., Ltd.). It was created. Thus, pulp sheets for fluff pulp of Examples 1 to 14 and Comparative Examples 1 to 4 were obtained.

Various evaluations were performed on the pulp sheet for fluff pulp obtained as described above.

(Weight average fiber length and weight average fiber width of pulp fiber)
The weight average fiber length and weight average fiber width of hardwood unbleached kraft pulp (kappa number of about 16) of Examples 1 to 14 and Comparative Examples 1 to 4 after the cooking and washing steps were measured. The weight average fiber length and the weight average fiber width were determined by JAPAN TAPPI paper pulp test method No. 1 using a fiber length measuring machine "FiberLab" manufactured by Metso Automation. 52 "Pulp and Paper--Fiber Length Test Method--Automatic Optical Measurement", fibers with a fiber length of 0.1 mm or more were measured. The fiber analyzer "FiberLab" can measure the length and width of pulp fibers with high accuracy by image analysis when the diluted pulp fibers pass through the measuring cell inside the fiber analyzer.

(Density of pulp sheet for fluff pulp)
The density of each fluff pulp pulp sheet was measured according to “Paper and paperboard—Testing methods for thickness, density and specific volume” described in JIS-P8118 (2014).

(Specific bursting strength of pulp sheet for fluff pulp)
The specific bursting strength of each fluff pulp pulp sheet was obtained by dividing the paper bursting strength in kilopascals (kPa) measured according to JIS-P8131 (2009) by the basis weight.

(Grindability of pulp sheet for fluff pulp)
For the crushability of each fluff pulp pulp sheet, 5 g of fluff pulp cut to 10 mm×10 mm is placed in a laboratory mixer and the pulp is crushed. Then, the state of the pulp was checked every 10 seconds, and the time until lumps of pulp disappeared was measured. If the pulverizability is poor, the absorbent may have uneven liquid absorbability and regurgitation properties, and both properties may be reduced. Evaluation was carried out according to the following four grades based on Reference Example 1 of 100% coniferous wood. When the evaluations are A and B, the pulverizability of the fluff pulp pulp sheet is good.
A: It can be dealt with in defibration time equivalent to that of the fluff pulp of Reference Example 1.
B: The time required for fibrillation is slightly longer than that of the fluff pulp of Reference Example 1, but it is practically usable.
C: The fluff pulp of Reference Example 1 requires longer time to defibrate, but is practically usable.
D: The time required for fibrillation is clearly longer than that of the fluff pulp of Reference Example 1, and practical use is impossible.

(Absorption speed of fluff pulp)
As a procedure for measuring the absorption speed of each fluff pulp, 5 g of fluff pulp cut into 10 mm×10 mm was first placed in a laboratory mixer and pulverized. Next, 0.5 g of the pulverized pulp prepared in the above pulverization test was compressed into a disk shape to prepare a sample, and then dropped on the water surface to measure the time until it settled below the water surface. Evaluation was carried out according to the following four grades based on Reference Example 1 of 100% coniferous wood. When the evaluations are A and B, the absorption rate in fluff pulp is good.
A: Equivalent to the fluff pulp of Reference Example 1, it settles quickly.
B: It takes a little longer to settle than the fluff pulp of Reference Example 1, but is practically usable.
C: More time is required for sedimentation than the fluff pulp of Reference Example 1, but practical use is possible.
D: The time to sedimentation is obviously slower than that of the fluff pulp of Reference Example 1, and practically unusable.

(Return amount of water-absorbing liquid in absorbent article)
The amount of backflow indicates the amount of backflow of the liquid absorbed by the absorber and released when pressure is applied to the absorber. The backflow amount of the water-absorbing liquid was obtained by making paper diapers using the fluff pulp pulp sheets of Examples 1 to 14 and Comparative Examples 1 to 4, and then applying artificial urine several times to the absorber at intervals. Absorb. A filter paper was placed on the absorber, a load was applied, and the weight of the artificial urine absorbed by the filter paper was measured. Evaluation was carried out according to the following four grades based on Reference Example 1 of 100% coniferous wood. When the evaluations are A, B, and C, the effect of suppressing backflow of water-absorbing liquid in the absorbent article is good.
A: The amount of reversion is smaller than that of the fluff pulp of Reference Example 1.
B: The amount of reversion is equivalent to that of the fluff pulp of Reference Example 1.
C: The amount of reversion is slightly larger than that of the fluff pulp of Reference Example 1, but it is practically usable.
D: The amount of reversion is larger than that of the fluff pulp of Reference Example 1, and practical use is impossible.

(Skin Rash on Absorbent Articles)
After making paper diapers using the pulp sheets for fluff pulp of Examples 1 to 14, Comparative Examples 1 to 4, and Reference Example 1, 50 monitors were asked to use 10 sheets each. The number of sheets generated was evaluated as a percentage. Evaluation was carried out according to the following four grades based on Example 1. When the evaluations are A, B, and C, the effect of suppressing skin rashes is good.
A: Better than Reference Example 1 in rash occurrence rate.
B: Slightly superior to Reference Example 1 in fog generation rate.
C: The rash occurrence rate is equivalent to that of Reference Example 1, and practical use is possible.
D: The rash occurrence rate is higher than that of Reference Example 1, and practically unusable.

Table 2 shows the evaluation results of each example and comparative example.

As shown in Table 2, the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is 15/85 or more and 50/50 or less, and the content of acacia wood in the raw material wood of the bleached hardwood kraft pulp is 20 mass. % or more and 100% by mass or less of Examples 1 to 14 show the crushability of the fluff pulp pulp sheet, the absorption speed of the fluff pulp, and the amount of backflow of the water-absorbing liquid in the absorbent article and the effect of suppressing skin rash. Good results were obtained in all cases.

On the other hand, Comparative Example 1, in which the content of acacia wood in the raw material wood of the bleached broadleaf kraft pulp was less than 20% by mass, was inferior in the absorption rate in the fluff pulp and in the effect of suppressing skin irritation in the absorbent article. In Comparative Example 2, in which the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is less than 15/85, the pulp sheet for fluff pulp is inferior in grindability, and the absorbent article has a large amount of backflow of water-absorbing liquid. The inhibitory effect on skin rashes was inferior. This is because when a large amount of water-absorbing liquid flows back into the absorbent article, even after urine is absorbed, pressure is applied by body movements, and urine returns to the surface of the absorbent article and touches the skin, causing a rash. presumably because it makes it easier. Comparative Example 3, in which the mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is more than 50/50, and the mass ratio is very high, shows the crushability and absorption rate in the pulp sheet for fluff pulp, and in the absorbent article The inhibitory effect on skin rashes was inferior. This is presumably because the absorption rate of the fluff pulp pulp sheet is slowed down, and excretions such as urine are in contact with the skin for a longer period of time when the absorbent article is worn, making rashes more likely to occur. In Comparative Example 4, in which the mass ratio of the broadleaf tree bleached kraft pulp slightly exceeded 50/50, the effect of suppressing skin rashes was inferior.

As a result, it was shown that the absorbent article using the fluff pulp pulp sheet has a good effect of reducing the backflow amount of the water-absorbent liquid and a good effect of suppressing skin irritation.
The pulp sheet for fluff pulp of the present invention is suitable for absorbent articles.

Claims (2)

An absorbent article using a pulp sheet for fluff pulp,
The pulp sheet for fluff pulp contains bleached hardwood kraft pulp and bleached softwood kraft pulp,
The mass ratio of the bleached hardwood kraft pulp to the bleached softwood kraft pulp is 15/85 or more and 50/50 or less,
The absorbent article, wherein the content of acacia wood in the raw material wood of the bleached hardwood kraft pulp is 20% by mass or more and 100% by mass or less. 2. The absorbent article according to claim 1, wherein the hardwood bleached kraft pulp has a kappa number of 0.3 or less.