JP7099572B2 - Airless bottle with excellent regular shrinkage of inner bag container - Google Patents

Description

The present invention relates to an airless bottle including an outer container and an inner bag container inserted and held in the outer container.

Conventionally, among the double-structured containers having a double-structured structure consisting of an inner bag container and an outer container, an airless bottle has been put into practical use as a container for storing a seasoning liquid such as soy sauce. Such an airless bottle is used in combination with a cap with a check valve, and the contents filled in the inner bag container by squeezing and denting the body wall of the bottle, which is the outer container, from the outside. When the liquid is discharged from the pouring path formed in the cap and the discharge of the content liquid is terminated by stopping the pressing of the body wall of the bottle, the air is introduced into the inner bag container by the action of the check valve. Instead, it will be introduced into the space between the inner bag container and the outer container through a flow path different from the pouring path of the cap. As a result, the inner bag container shrinks by the amount that the content liquid is discharged, and each time the content liquid is discharged, the inner bag container shrinks. In an airless bottle in which the content liquid is discharged by such a method, the content liquid can be dispensed and the intrusion of air into the inner bag container filled with the content liquid is effectively prevented, so that the content liquid is oxidatively deteriorated. There is an advantage that the freshness of the content liquid can be maintained for a long period of time.

As a method for manufacturing an airless bottle (hereinafter, can be referred to as a double-structured container) as described above, a resin for molding an outer container and a resin for molding an inner bag container, which do not have adhesiveness to each other, are used. The direct blow method, in which the resin is selected and shaped into the shape of the container by direct blow molding using these resins, has been the mainstream. That is, in this method, a pipe having a double structure is formed by melt extrusion using the above resin, the lower end of the pipe is pinched off, and then a blow fluid is blown into the pipe to shape it into a bottle. It is a method. However, this method has a problem that it is difficult to take a large number of pieces and the productivity is low because the process from melt extrusion molding to bottle molding is performed at once. There is also a problem that the strength of the outer container is low.

Therefore, recently, a method of manufacturing a double-structured container by stretch blow molding has been studied.
The preform-in-bottle method and the stack preform method are widely known as this method.

In the preform-in-bottle method, an outer container is formed in advance by a known stretch blow molding, a test tube-shaped inner bag preform is inserted into the outer container, and an inner bag preform is inserted in this state. It is a method of performing blow molding by supplying a blow fluid inside. In this method, the outer container functions as a blow type, and the inner bag preform is shaped into a bag-shaped container shape. That is, in this method, stretch blow molding of the outer container and stretch blow molding of the inner bag container are sequentially performed.

In the stack preform method, the preform for outer container molding and the preform for inner bag are molded by injection molding, and the preform for inner bag is inserted into the preform for outer container molding to form the preform for outer container molding. And the preform for the inner bag form a stacked preform in which the preform for the inner bag is overlapped, the stack preform is held in the blow mold, and the blow fluid is supplied into the preform for the inner bag inside the stack preform to perform stretch blow molding. It is a method of doing. That is, in this method, the preform for forming the outer container is shaped into the shape of the container by the expansion of the preform for the inner bag, and the outer container is stretch blow molded and the inner bag container is stretch blow molded. Are done at the same time.

However, in a double-structured container consisting of an inner bag container and an outer container, the inner bag container is irregularly deformed as the container contents liquid contained in the inner bag container is discharged, and the contents are, for example, to some extent. When the liquid is discharged, the bottom of the inner bag container rises from the bottom of the outer container and becomes crumpled, the discharge flow path of the content liquid is crushed, and there is a problem that the discharge of the content liquid becomes difficult. Such a problem also occurs when the double-structured container is manufactured by any of the direct blow method, the preform-in-bottle method and the stack preform method.

For example, Patent Document 1 discloses that the preform for an inner bag container used in the preform-in-bottle method is provided with a gap forming rib on the outer surface of the body portion. In a double-structured container using such a preform for an inner bag container, a gap is formed between the inner surface of the outer container and the outer surface of the inner bag. Since the bag preform quickly separates from the inner surface of the outer container and shrinks (excellent in initial delamination), the content liquid can be quickly discharged. However, in such a double-structured container, since the inner bag container shrinks irregularly due to the discharge of the content liquid, the problem that the content liquid becomes difficult to be discharged while the content liquid is discharged is solved. Not.
Further, in Patent Document 1, it is also proposed to provide a rib for forming a gap on the inner surface of the preform for an outer container, but even in this case, the above problem is not solved.

Further, Patent Document 2 discloses that the preform for an inner bag container used in the stack preform method is provided with a large number of ridges on the outer surface of the body portion. The double-structured container obtained by using such a preform for an inner bag also has a gap formed between the inner surface of the outer container and the outer surface of the inner bag, but the inner bag container with the discharge of the content liquid is used. Since the shrinkage is irregular, the problem that the content liquid becomes difficult to be discharged while the content liquid is discharged has not been solved.

Further, in Patent Document 3, when a double-structured container is manufactured by the stack preform method, a protrusion and an engaging claw are provided on the bottom of the preform for the inner bag container, and this claw is used as the bottom of the preform for the outer container. A means has been proposed in which two preforms are connected by being inserted into a hole and engaged with each other, and simultaneous stretch blow molding is performed in this form.
In such a means, since the bottom of the inner bag container is connected to the bottom of the outer container, the shrinkage of the inner bag container due to the discharge of the content liquid is restricted, and the content liquid is discharged while the content liquid is discharged. The problem of difficulty in discharging the liquid has been effectively solved. However, in such a means, it is necessary to form a claw at the bottom of the inner bag preform, and further, the outer container preform needs to be provided with a hole for engaging with the claw. The mold for manufacturing becomes complicated, and further, the claws formed in the inner bag preform are inserted into the holes formed in the outer container preform and engaged with each other. There is a big problem that the productivity is low because the troublesome operation is required.

Japanese Unexamined Patent Publication No. 2005-53513 Japanese Patent No. 4281454 Japanese Unexamined Patent Publication No. 2014-69875

Therefore, an object of the present invention is a double-structured container (airless bottle) in which the problem that the shrinkage of the inner bag container is regulated and the content liquid becomes difficult to be discharged while the content liquid is discharged is effectively solved. ) Is to be provided.

As a result of conducting many experiments and examining the stack preform method known as a method for manufacturing a double-structured container, the present inventors have conducted and examined many experiments. We obtained the unexpected finding that it is possible to form deep grooves that are locally thinned, and by performing simultaneous stretch blow molding using such deep grooves, the contents of the inner bag container can be obtained. A thin-walled portion that can regulate the shrinkage associated with the discharge of the liquid is formed, and in the double-structured container thus obtained, the problem that the content liquid becomes difficult to discharge while the content liquid is discharged is effectively solved. This has led to the completion of the present invention.

According to the present invention, in an airless bottle composed of an inner bag container and an outer container,
The body of the inner bag container is non-adhesive to the body of the outer container, and the body of the inner bag container is spaced in the circumferential direction at a plurality of locations in an axial strip shape. An airless bottle is provided characterized by being provided with an extended shrink control thin wall portion.

In the airless bottle of the present invention,
When viewed in a plan section, the minimum thickness t'of the shrinkage-regulating thin-walled portion is in the range of 70% or less of the thickness T'of the portion other than the thin-walled portion.
Suitable.

The airless bottle of the present invention can be manufactured, for example, by using the following preform for an inner bag container.

This preform for an inner bag container is used for manufacturing a double-structured container (airless bottle) by the stack preform method. That is, the stack preform in which the inner bag container preform is inserted and held inside the outer container preform is assembled, the stack preform is placed in the blow mold, and in this state, it is appropriately stretched. The rod is inserted into the inner bag container preform and stretched in a uniaxial direction, and further, a blow fluid (for example, compressed air) is supplied into the inner bag container preform to expand it in the circumferential direction (that is,). By simultaneous blow stretching), the preform for the inner bag container is thinned by expansion while being in close contact with the inner surface of the preform for the outer container and shaped into the form of the inner bag container, and the preform for the outer container is the preform for the outer container. As the preform for the inner bag container, which is in close contact with the inner surface, expands and becomes thinner, it is shaped into the form of the outer container by the blow mold, so that the inner container is housed and held in the outer container and the outer container. A double-structured container composed of a bag container can be obtained.
In the following description, the double-structured container means an airless bottle.

Both the inner bag container preform and the outer container preform have a test tube shape as a whole, and the inner bag container preform is inserted and held in the outer container preform. The non-stretched molded portion of the outer container preform has a neck portion located in a certain mouth portion, a body portion connected to the neck portion, and a bottom portion in which the body portion is closed. That is, the body portion and the bottom portion are stretch-molded in the simultaneous stretch blow molding with the preform for the outer container. In the preform for an inner bag container having such a basic shape, in the present invention, the body portion, which is a stretch-molded portion, extends linearly at a plurality of locations at intervals in the circumferential direction in the axial direction. It has an important feature in that a shrinkage control groove is formed.
When the above-mentioned simultaneous stretch blow molding is performed using the preform for the inner bag container in which the shrinkage control groove is formed, the groove portion is thinner than the other portions. In the inner bag container obtained by thinning, a shrinkage-regulating thin-walled portion in which the shrinkage-regulating groove is thinned is formed.
That is, a plurality of shrinkage-regulating thin-walled portions formed in the inner bag container are formed at intervals in the circumferential direction, but all of them extend in the axial direction of the container and are not such thin-walled portions. It is considerably thinner than that. Therefore, the shrinkage of the inner bag container caused by the discharge of the content liquid contained in the inner bag container is deformed starting from the shrinkage-regulating thin-walled portion extending in the axial direction, and as a result, the content liquid is deformed. Irregular shrinkage deformation that causes the bottom of the inner bag container to rise greatly and become wrinkled is suppressed due to the shrinkage that accompanies the discharge of the content liquid, and the flow path of the content liquid is not blocked, so that the content liquid is stable. Can be discharged.

What is important here is that the thin-walled portion for shrinkage regulation formed in the inner bag as described above can be realized only by adopting the stack preform method, and can be formed by the preform-in-bottle method. It means that it cannot be done.
That is, since the thin-walled portion for regulating shrinkage is the starting point of deformation at the time of shrinkage, it is necessary that the thickness difference from other portions is considerably large. This is because if this thickness difference is small, when the inner bag container is contracted and deformed due to the discharge of the content liquid, the other parts are also deformed almost at the same time, and the function of regulating the contraction is not exhibited. Therefore, in order to form a thin-walled portion having such a thickness difference, a thin-walled portion is formed on the stretch-molded portion (body portion) of the preform for the inner bag container used for molding the inner bag container. Specifically, it is necessary to form a groove, and it is also necessary to set a large difference in thickness between this groove and other portions. When a preform for an inner bag container having a groove having such a large difference in thickness is independently stretch-blow molded as in the preform-in-bottle method, the groove having a significantly thin thickness is greatly stretched and thus broken. It causes molding defects such as. That is, since the thickness of the groove is limited, it is not possible to form a thin-walled portion for restricting shrinkage.
On the other hand, in the stack preform method, when a double-structured container is manufactured by simultaneous stretch blow molding, the stretch-molded portion (body portion) of the inner bag container preform is in close contact with the inner surface of the outer container preform. Moreover, it is stretched by the expansion integrated with the preform for the outer container. Therefore, even if the inner bag container preform has a groove having a large difference in thickness from other parts, the inner surface of the body of the outer container preform relaxes the stretching of the groove portion alone, and the groove is formed. The portion expands and becomes thinner in the same manner as the portion other than the groove, and as a result, molding defects such as breakage are effectively suppressed. In other words, it is possible to form a groove having a large difference in thickness that can form a shrinkage-restricted thin-walled portion on the body portion (stretched molded portion) of the preform for the inner bag container.

Instead of the linear groove extending in the axial direction, it is conceivable to provide a ridge on the body of the preform for the inner bag container, particularly on the outer surface. In this case, a thick portion is formed in the inner bag container obtained by blow molding so as to correspond to the ridge, and such a thick portion is formed between the outer container and the inner bag container. It helps to form gaps between them, but does not show the function of regulating contraction. That is, this part is a part that is hard to be deformed, and the shrinkage deformation due to the discharge of the content liquid occurs from a part other than the thick part existing in a large area, so that the shrinkage deformation inevitably occurs irregularly. Become.

As described above, in the double-structured container obtained by the stack preform method using the preform for the inner bag container of the present invention, the shrinkage deformation of the inner bag container due to the discharge of the content liquid is effectively regulated and irregular. Since the deformation is prevented, the inconvenience that the discharge flow path of the content liquid is blocked is effectively avoided, and the content liquid can be discharged stably.
Further, in the present invention, a double-structured container is formed by a conventionally known stack preform method, except that a preform for an inner bag container in which a groove is formed in a stretch-molded portion (body portion) is used. It does not use a special form of preform with claws, holes, etc., and it is also necessary to perform troublesome operations such as engagement between the claws and holes when assembling the stack preform. Therefore, the present invention is extremely advantageous in terms of productivity, manufacturing cost, and the like.

FIG. 1 is a diagram showing a schematic side cross section of a preform for an inner bag container, a preform for an outer container, and a stack preform assembled from these preforms used in the production of the double-structured container of the present invention. a) is a preform for an inner bag container, FIG. 1 (b) is a preform for an outer container, and FIG. 1 (c) is a diagram showing a stack preform. FIG. 3 is a cross-sectional view taken along the line AA of the preform for an inner bag container of FIG. The figure which shows the schematic side cross section of the double structure container of this invention obtained by simultaneous stretch blow molding by a stack preform method. The figure which shows the BB plan cross section of the inner bag container in FIG. It is a figure which shows the form of shrinkage deformation of the inner bag container with the discharge of the content liquid with respect to a double structure container, and FIG. It is a schematic side view which shows the form of the contraction deformation at the time, and FIG. 5 (b) is a schematic plan sectional view thereof. It is a schematic side view which shows the form of shrinkage deformation when the thin-walled part for shrinkage regulation is not formed in the inner bag container. FIG. 3 is a schematic plan sectional view showing an example of another arrangement pattern of a plurality of shrink-regulating thin-walled portions formed in the inner bag container of FIG. 3 and a modified form of the inner bag container formed according to this pattern.

With reference to FIG. 1, the double-structured container of the present invention uses a preform 1 for an inner bag container (see FIG. 1 (a)) and a preform 3 for an outer container (see FIG. 1 (b)). It is obtained by all the stack preform methods. That is, the inner bag container preform 1 (hereinafter, may be simply referred to as an inner preform) is inserted into the outer container preform 3 (hereinafter, may be simply referred to as an outer preform) and stacked. By forming the reform 20 (see FIG. 1 (c)) and stretching blow molding using this stack preform, the inner preform 1 and the outer preform 3 are stretch blow molded at the same time. The double-structured container shown is manufactured.

As can be understood from FIG. 1, both the inner preform 1 and the outer preform 3 have a test tube shape as a whole and are molded by injection molding.

In the present invention, the inner preform 1 has a neck portion 5, a body portion 7 connected to the neck portion 5, and a bottom portion in which the lower ends of the body portion 7 are closed. On the other hand, the outer preform 3 in which the inner preform 1 is housed is composed of a mouth portion 11, a body portion 13 connected to the mouth portion 11, and a bottom portion 15 closing the lower end of the body portion 13, and the mouth portion 11 is extended. It is a fixed portion (non-stretched molded portion) that is not molded, and is a portion in which the body portion 13 and the bottom portion 15 are stretch-molded.

In the inner preform 1 as described above, the neck portion 5 is a portion located in the mouth portion 11 which is not stretch blow molded when the stack preform 20 is used. Therefore, in this inner preform 1, the body portion 7 and the bottom portion connected to the neck portion 5 are stretch-molded regions, but when the stack preform 20 is used, between the outer surface of the neck portion 5 and the inner surface of the mouth portion 11. When a gap is formed, it may be stretch-molded from the portion where such a gap exists.
In FIG. 1, both the inner preform 1 and the outer preform 3 of the non-stretched molded portion are shown by hatching.

Further, the upper portion of the neck portion 5 of the inner preform 1 is firmly fitted and fixed in the mouth portion 11 of the outer preform 3 when the stack preform 20 is used, but the upper end portion thereof spreads outward. A peripheral flange 5a is formed, and by engaging the peripheral flange 5a with the upper end of the mouth portion 11, the inner preform 1 is positioned so as not to be inserted deeper than necessary.

Further, a screw 11a for attaching a cap with a check valve is provided on the outer surface of the mouth portion 11 of the outer preform 3 which is a non-stretched molded portion, and a screw 11a is provided on the upper side of the screw 11a. An air introduction port 11b is formed, and air is introduced between the inner bag container and the outer container of the double-structured container finally formed through the air introduction port 11b, and the inner bag container is filled. The contents liquid can be discharged quickly.
Further, a support ring 11c is provided on the lower side of the above-mentioned screw 11a, and is used as a gripping member when the outer preform 3 and the stack preform 20 are conveyed. Further, when a cap with a check valve is attached, the cap abuts on the upper surface of the support ring 11c, so that air does not leak and the double-structured container is finally formed through the air introduction port 11b. Air can be introduced between the inner bag container and the outer container.

In the inner preform 1 and the outer preform 3 as described above, the neck portion 5 of the inner preform 1 may be formed to protrude from the mouth portion 11 of the outer preform 3, and the protruding portion may be formed. A screw 11a for engaging with the check valve cap can be provided on the outer surface of the neck 5, and the check valve cap is of a type that is fixed by fitting and fixing regardless of screw engagement. In some cases, it is possible to omit the screw 11a as described above.

Further, the outer surface of the body portion 7 of the inner preform 1 has a tapered portion 7a whose diameter is reduced as it goes downward from the upper end portion (a portion connected to the neck portion 5), and the tapered portion 7a has a tapered portion 7a. , It is connected to the straight body portion 7b below. With such a form, the inner preform 1 can be quickly inserted into the outer preform 3 and fitted and fixed at the upper portion of the neck portion 5.

The stack preform 20 formed by inserting the inner preform 1 described above into the outer preform 3 and fitting and fixing the inner preform 20 is held in the blow mold, and the temperature at which blow molding is possible (forms the preform). Heat to the temperature above the glass transition point temperature of the resin and below the melting point), insert a stretch rod into the inner preform 1 as appropriate, stretch it in the uniaxial direction, and then apply blow fluid such as compressed air to the inner preform 1. The desired double-structured container can be obtained by supplying the glass to the room, expanding it in the circumferential direction, and stretching it.
That is, the stretch-molded portion (body portion 7 and bottom portion 9) of the inner preform 1 is stretch-molded while being in close contact with the inner surface of the stretch-molded portion (body portion 13 and bottom portion 15) of the outer preform 3, and the outer preform 3 is formed. Is expanded and stretched by the inner preform 1, and shaped into the shape of a container by a blow mold. At this time, the inner preform 1 is shaped into the shape of a bag container using the inner surface of the outer preform 3 as a mold. It will be shaped.

In such an inner preform 1, in the present invention, a plurality of shrinkage regulating grooves 10 are formed on the inner surface of the body portion 7 which is a stretch molding portion. That is, with reference to the plan sectional view of FIG. 2, the inner surface of the body portion 7, particularly the straight body portion 7b, has two contraction-regulating properties extending in the axial direction so as to face each other in the radial direction. Grooves 10 and 10 are formed. In addition, in FIG. 1, the portion where the groove 10 is formed is shown by the region surrounded by the alternate long and short dash line in the drawing.
Such a shrinkage regulating groove 10 has a large difference in thickness from a portion other than the groove, whereby the inner bag container is formed on the body of the inner bag container obtained by stretching and blow molding the inner preform 1. It is possible to form a thin-walled portion that regularly regulates shrinkage deformation due to discharge of the content liquid filled in the container. The form of such a thin portion and the shrinkage deformation will be described in detail later.

For example, in the present invention, the minimum thickness t of the shrinkage regulating groove 10 is 80% or less, particularly 70% or less of the thickness T of the portion other than the groove 10, and thus the thickness difference from the other portions. Is large and thin. When the minimum thickness t of the groove 10 is thicker than the above range with respect to the thickness T of other portions, it is difficult to form a shrinkage regulating thin-walled portion that regularly regulates shrinkage deformation in the inner bag container. Will be.
What is important here is that the shrinkage control groove 10 having a large thickness difference from other parts as described above is only when the inner preform 1 and the outer preform 3 are simultaneously stretched and blow molded by the stack preform method. It means that the shrinkage-regulating thin-walled portion can be formed in the inner bag container, and it is not possible to form such a shrinkage-regulating thin-walled portion in the inner bag container by other methods. This is because the inner preform 1 is broken at the portion of the groove 10 during stretch blow molding. In the stack preform method, when the inner preform 1 is expanded and deformed by stretch blow molding, the inner surface of the body 13 of the outer preform 3 is always in close contact with the outer surface of the body 7 of the inner preform 1. Therefore, breakage at the portion of the groove 10 is effectively prevented, and as a result, a thin-walled portion for shrinkage regulation can be formed in the inner bag container.

If the minimum thickness t of the groove 10 is excessively thin, breakage is likely to occur during stretch blow molding. Therefore, it is desirable that the minimum thickness t has a thickness of 200 μm or more, particularly 500 μm or more.

Further, in the present invention, it is preferable that the width w of the shrinkage control groove 10 is in the range of 0.2 to 8 mm, respectively, when viewed in the plan cross section of the body portion. That is, in both cases where the width W is too large or too small, the width of the shrinkage-regulating thin-walled portion derived from the groove 10 and formed in the inner bag container becomes larger or smaller. It tends to be difficult to regularly regulate the shrinkage deformation due to the discharge of the content liquid.

The axial length L of the shrinkage regulating groove 10 is not particularly limited, but generally, when the height H of the body portion 7 which is the stretch molding portion, that is, the stack preform 20 is used, the outer preform 3 is used. Having a length of 30% or more, particularly 50% or more with respect to the length of the portion located below the lower end of the mouth portion 11, causes the shrinkage due to the discharge of the content liquid as a whole. Suitable for regular regulation.
Further, such a shrinkage regulating groove 10 is preferably located on the side close to the bottom portion 9, and is formed in a portion of the straight body portion 7b as shown in FIG. 1, for example. Is desirable. As a result, it is possible to more reliably prevent irregular deformation such as the bottom of the bag-shaped container floating upward at the time of shrinkage deformation due to the discharge of the content liquid.

Further, in the example of FIG. 1, the shrinkage regulating groove 10 is formed on the inner surface of the body portion 7, but of course, it can also be formed on the outer surface of the body portion 7. However, when the depth of the groove 10 is made deeper and a large thickness difference is formed between the groove 10 and the other portion, the inner surface of the body portion 7 is formed from the viewpoint of injection moldability of the preform 1. It is preferable to provide the groove 10. Further, from the viewpoint of effectively preventing breakage at the portion of the groove 10 during stretch blow molding, it is more preferable to provide the groove 10 on the inner surface.
Further, in the examples of FIGS. 1 and 2, shrinkage control grooves 10 are provided at two locations facing each other in the radial direction, but such shrinkage control grooves 10 are provided in a number larger than 2. You can also. From the viewpoint of more regularly regulating the shrinkage deformation due to the discharge of the content liquid, it is preferable that the large number of shrinkage control grooves 10 are provided at positions that are point-symmetrical when viewed in a plan cross section. In the present invention, it is optimal that the shrinkage control grooves 10 are distributed point-symmetrically in the circumferential direction, particularly in the number of 2 to 4.

The double-structured container of the present invention, which is shown in FIG. 30 as a whole with reference to FIGS. 3 and 4, stretch blow-molds a stack preform 20 composed of the above-mentioned inner preform 1 and outer preform 3. This is obtained by the above, and is composed of an inner bag container 31 obtained from the inner preform 1 and an outer container 41 obtained from the outer preform 3.

In these containers 31 and 41, since the neck portion 5 of the inner preform 1 and the mouth portion 11 of the outer preform 3 are portions that are not substantially stretch-molded, these portions are provided as they are.
For example, the inner bag container 31 has a neck portion 5, a deformable body portion 33 and a bottom portion 35, and the body portion 33 and the bottom portion 35 are formed by stretch blow molding.
Further, the outer container 41 has a mouth portion 11, a body portion 43 and a bottom portion 45, and the body portion 43 and the bottom portion 45 are formed by stretch blow molding. Further, from the viewpoint of the independence of the container and the like, generally, a raised bottom portion 45a is formed in the central portion of the bottom portion 45, and the peripheral portion of the bottom portion 45 serves as a ground contact portion. In the initial state immediately after blow molding, the body 33 and the bottom 35 of the inner bag container 31 are held in close contact with the inner surface of the outer container 41.

In such a double-structured container 30, in the present invention, two thin-walled portions 50 for shrinkage regulation are formed on the body portion 33 of the inner bag container 31 so as to face each other in the radial direction. In FIG. 3, the portion where the thin-walled portion 50 is formed is shown by a region surrounded by the alternate long and short dash line in the drawing.
That is, the shrinkage regulating thin-walled portion 50 is formed by stretching the shrinkage regulating groove 10 provided in the inner preform 1 of FIG. 1, and therefore, two facing each other in the radial direction. A thin-walled portion 50 for shrinkage regulation is formed at the place, and these thin-walled portions 50 extend in a strip shape in the axial direction.

In the present invention, the shrinkage-regulating thin-walled portion 50 is a portion having a large difference in thickness from other portions, and is extremely thin. Therefore, as already described, such shrinkage regulation is performed only by using the inner bag container preform 1 having the shrinkage regulation groove 10 having a thickness difference and performing simultaneous stretch blow molding by the stack preform method. The thin-walled portion 50 cannot be formed.

That is, in the double-structured container 30 of the present invention, the inner bag container 31 is filled with the content liquid, and by pressing the body 43 of the outer container 41, the body 33 of the inner bag 31 is also pressed. As a result, the content liquid is discharged. Next, when this pressing is stopped, the body portion 43 of the outer container 41 returns to its original shape, but at this time, the pressure between the body portion 33 of the bag-shaped container 31 and the body portion 43 of the outer container 41 is a negative pressure. Therefore, the air introduction port 11b flows from the valve of the cap with the check valve between the two, and the air does not flow into the inner bag container 31, so that the oxidative deterioration of the content liquid is effectively prevented. , The quality of the content liquid can be effectively maintained. As described above, the inner bag container 31 contracts with the discharge of the content liquid, and then the content liquid is discharged again by pressing the body portion 43 of the outer container 41.

When the content liquid is discharged as described above, the body portion 33 of the inner bag container 31 contracts accordingly, but in the present invention, the thin-walled portion 50 for shrinkage regulation is formed. The deformation due to this shrinkage is regulated to be regular, and inconveniences such as the flow path of the content liquid being crushed due to this shrinkage deformation can be effectively avoided.
For example, with reference to FIG. 5, which shows the form of contraction deformation of the body portion 33, in the present invention, the contraction-regulating thin-walled portion 50 formed so as to face in the radial direction is contracted and deformed as a ridge line, so that the portion is exactly straight. It is regularly deformed into a form that can be folded into a shape, and as a result, a space Z that serves as a discharge flow path for the content liquid is secured in the central portion of the deformed body portion 33.
On the other hand, as shown in FIG. 6, when the shrinkage regulating thin-walled portion 50 is not formed, the entire body portion 33 is deformed at once. Therefore, for example, the body portion 33 is the bottom portion of the outer container 41. It rises greatly from 45 and contracts into a remarkably irregular form, and as a result, the flow path of the content liquid is crushed, and it becomes difficult to discharge the content liquid.

In the present invention described above, the shrinkage regulating thin-walled portion 50 and the shrinkage-regulating groove 10 formed in the inner preform 1 for forming the thin-walled portion 50 are formed at two locations facing each other in the radial direction. Although an example is shown, as described in the section of the shrinkage control groove 10, such a groove 10 and a thin wall portion 50 can be provided in a number of 3 or more, and more regularly deformed shrinkage. It is preferable that these are arranged in the circumferential direction in a point symmetry.

FIG. 7 shows an outline of the pattern of the thin-walled portion 50 formed when the three and four shrinkage control grooves 10 are arranged point-symmetrically and the shrinkage-deformed form.
As can be understood from this figure, in each case, the thin-walled part 50 for shrinkage, which is significantly deformed as compared with other parts, is contracted and deformed as a ridgeline, so that the central portion thereof serves as a discharge flow path for the content liquid. The space Z is maintained, and the content liquid can be smoothly discharged.

By the way, as described above, in order to secure regular shrinkage deformation as described above, it is necessary that the thickness difference between the thin-walled portion 50 and the other portion is large, and for this reason, A deep groove (shrinkage regulating groove 10) having a thickness difference of a certain degree or more is formed in the body portion 7 of the inner preform 1 described above, and the minimum thickness t of the shrinkage regulating groove 10 is the other portion. The thickness is set to 80% or less of the thickness T, particularly 70% or less, and the portion of the shrinkage regulating groove 10 is stretched and blow molded and stretched to extend in a strip shape in the axial direction. A thin-walled portion 50 for shrinkage regulation is formed. For example, the minimum thickness t'of such a thin-walled portion 50 for shrinkage regulation is in the range of 70% or less, particularly 60% or less with respect to the thickness T'of the other portion, and the thickness difference from the other portion is large. As a result, it is possible to regulate the shrinkage deformation due to the discharge of the content liquid so as to be regular.

The ratio of the thin-walled portion 50 to the thickness T'of the other portion of the minimum thickness t'is shifted to a range slightly smaller than the ratio of the minimum thickness t of the shrinkage regulating groove 10 to the thickness T of the other portion. This is because the portion of the shrinkage regulating groove 10 is made thinner by stretching blow than the other portions. Similarly, the width W'of the thin-walled portion 50 is wider than the width W of the shrinkage regulating groove 10 by the amount of thinning according to the stretching ratio in the circumferential direction. Therefore, the conditions for stretching blow (circumferential stretching ratio) are set so that the width W'does not become larger than necessary. For example, the width W'is contracted so as to be in the range of about 3 to 30 mm. The circumferential stretching ratio is set according to the width W of the groove 10.

The above-mentioned double-structured container of the present invention is used by filling the inner bag container 31 with the content liquid and then attaching a cap with a check valve known per se.

In the present invention, the inner bag container preform 1 for forming the inner bag container 31 and the outer container preform 3 for forming the outer container 41 are various thermoplastic resins as long as they can be blow molded. Can be formed with.
Examples of such a thermoplastic resin include the following.
Olefin-based resins such as low-density polyethylene, high-density polyethylene, polypropylene, poly1-butene, poly4-methyl-1-pentene or α-olefins such as ethylene, propylene, 1-butene and 4-methyl-1-pentene. Random or block copolymers, cyclic olefin copolymers, etc.;
Ethylene-vinyl acetate copolymers, for example, ethylene-vinyl acetate copolymers, ethylene-vinyl alcohol copolymers, ethylene-vinyl chloride copolymers, etc.;
Styrene-based resins such as polystyrene, acrylonitrile / styrene copolymer, ABS, α-methylstyrene / styrene copolymer, etc.;
Vinyl-based resins such as polyvinyl chloride, polyvinylidene chloride, vinyl chloride / vinylidene chloride copolymer, methyl polyacrylate, polymethyl methacrylate, etc.;
Polyamide resin, for example, nylon 6, nylon 6-6, nylon 6-10, nylon 11, nylon 12, etc .;
Polyester resins such as polyethylene terephthalate (PET), polybutylene terephthalate, polyethylene naphthalate, and copolymerized polyesters thereof and the like;
Polycarbonate resin;
Polyphenylene oxide resin;
Biodegradable resins such as polylactic acid;
Of course, a blend of these thermoplastic resins can also be used as the base resin as long as the moldability is not impaired.
In the present invention, the thermoplastic resin particularly preferably used is a polyester resin and an olefin resin, and further, for the purpose of use, air flows between the inner bag container 31 and the outer container 41, so that the outside is used. The outer preform 3 for forming the container 41 does not necessarily have to have water and gas barrier properties, and polylactic acid having low water and gas barrier properties can also be preferably used.

Further, in order to impart gas barrier properties to the inner bag container 31 and the outer container 41 to be molded, the inner preform 1 and the outer preform 3 for forming these may have a multi-layer structure.
For example, an ethylene vinyl alcohol copolymer (ethylene vinyl acetate copolymer saken product) or aromatic polyamide is used as an intermediate layer between the inner and outer layers formed of the polyester resin or olefin resin (or polylactic acid) described above. It is preferable to provide a gas barrier layer formed by using a gas barrier resin such as, and it is most preferable to provide a gas barrier layer made of an ethylene vinyl alcohol copolymer. That is, oxygen barrier properties can be imparted by providing a gas barrier layer as an intermediate layer, and in particular, ethylene vinyl alcohol copolymer exhibits particularly excellent oxygen barrier properties, so that the contents may be oxidatively deteriorated due to oxygen permeation. It can be effectively suppressed and excellent storage stability of the contents can be ensured.

Further, when the gas barrier layer as described above is provided, an adhesive resin layer can be provided in order to enhance the adhesiveness with the inner and outer layers and prevent delamination, whereby the gas barrier layer of the intermediate layer can be provided. It can be firmly adhered and fixed to the inner and outer layers. The adhesive resin used for forming such an adhesive resin layer is known by itself, and for example, a resin having a carbonyl group (> C = O) in the main chain or the side chain is 1 to 100 meq / 100 g, particularly 10 to 100 meq / 100 g. A resin contained in the amount of the resin, specifically, an olefin resin graft-modified with a carboxylic acid such as maleic acid, itaconic acid, fumaric acid or an anhydride thereof, an amide, an ester, etc.; an ethylene-acrylic acid copolymer; Ion-crosslinked olefin-based copolymers; ethylene-vinyl acetate copolymers; and the like are used as adhesive resins.

The above-mentioned double-structured container of the present invention is excellent in productivity because it does not use a mold having a complicated structure and the stack preform can be easily assembled. In addition, the content liquid can be continuously and smoothly discharged, and not only can the content liquid be effectively suppressed from remaining in the inner bag container, but also high freshness can be maintained for a long period of time, and the content can be maintained. Since the liquid can be dispensed, it is extremely useful as a container for seasoning liquids such as soy sauce.

The excellent effect of the present invention will be described with reference to the following experimental examples.

Commercially available PET resin for bottles (inherent viscosity: 0.84 dl / g) that has been sufficiently dried in a dehumidifying dryer is supplied to the hopper of the injection molding machine, and a test tube-shaped outer container molding preform and a test tube-shaped preform are used. A preform for molding an inner bag container was obtained. The inner bag container molding preform is provided with a plurality of shrinkage control grooves on the inner surface side so as to be axially symmetrical. Table 1 shows the shape and number of grooves.

The inner bag container molding preform was inserted into the above outer container molding preform to obtain a stack preform. Further, the stack preform was heated by a quartz heater and an iron core for heating and blow-molded to obtain a cylindrical bottle having an internal capacity of about 400 ml. The draw ratio was 2.5 times in the vertical direction and 2.5 times in the circumferential direction with respect to the preform for the outer layer, 2.7 times in the vertical direction and 4.2 times in the circumferential direction with respect to the preform for the inner layer. rice field.
In the inner bag of the obtained double-structured container, a shrinkage-regulating thin-walled portion was formed according to the shape and number of shrinkage-regulating grooves provided in the inner bag container molding preform. Table 1 shows the thickness and width of the thin-walled portion for shrinkage regulation. In addition, Table 1 also shows whether or not shrinkage regulation is applied when the obtained double-structured container is squeeze and the contents are discharged while shrinking the inner bag, and the shrinkage regulation shape.

When the shrinkage control groove is small as in shape 2, the inner bag shrinks all at once as in the case where no groove is provided, and the inner bag is completely randomly folded to block the flow path of the content liquid. ..

When a large shrinkage control groove is provided as in shapes 1 and 3 to 5, the shrinkage control thin-walled portion after bottle molding becomes the starting point of folding, and the inner bag shrinks with the shrinkage control thin-walled portion as a ridgeline. No blockage of the flow path of the contents liquid occurred.

1: Preform for inner bag container (inner preform)
3: Preform for outer container (outer preform)
5: Inner preform and inner bag container neck 7: Inner preform body 10: Shrinkage control groove 11: Outer preform and outer container mouth 11b: Air inlet 20: Stack preform 30: Double Structural container 31: Inner bag container 33: Inner bag container body 35: Inner bag container bottom 41: Outer container 43: Outer container body 45: Outer container bottom 50: Shrinkage control thin-walled part

Claims (2)

In an airless bottle consisting of an inner bag container and an outer container
The body of the inner bag container is non-adhesive to the inner surface of the body of the outer container, and the body of the inner bag container has a band shape in the axial direction at a plurality of locations at intervals in the circumferential direction. An airless bottle characterized by being provided with a thin-walled part for shrinkage regulation that extends to. The airless bottle according to claim 1, wherein the minimum thickness t'of the shrinkage-regulating thin-walled portion in a plan section is 70% or less of the thickness T'of the portion other than the thin-walled portion.

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