JP6906658B2 - A herbicidal composition containing 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridin-2-carboxylic acid. - Google Patents

Description

Priority Claim This application is incorporated herein by reference in its entirety for each of those disclosures.
US Provisional Patent Application Nos. 61 / 675,070, filed July 24, 012, and 2013
Claims the interests of US Patent Application No. 13 / 833,923, filed March 15, 2014.

Fields In the present specification, (a) 4-amino-3-chloro-5-fluoro-6- (4-chloro-2).
A herbicide composition comprising −fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid, or an agriculturally acceptable ester or salt thereof, and (b) a synthetic auxin herbicide is provided.

In the present specification, (a) 4-amino-3-chloro-5-fluoro-6- (4-chloro-2).
Includes steps to apply a (fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid, or an agriculturally acceptable ester or ester thereof, and (b) a synthetic auxin herbicide or an agriculturally acceptable salt or ester thereof. Also provided are methods of controlling unwanted vegetation.

Background Protecting crops from weeds and other vegetation that impede crop growth is a recurring challenge in agriculture. To help address this challenge, researchers in the field of synthetic chemistry have produced a wide variety of chemicals and chemicals that are effective in controlling such unwanted growth. Many types of chemical herbicides are disclosed in the literature and many are in commercial use. However, there is still a need for effective compositions and methods for controlling unwanted vegetation.

Abstract The first embodiment of the present invention provided in the present specification is an effective herbicidal amount (a) and formula (I).
Compound

または農業上許容されるその塩もしくはエステル、および（ｂ）合成オーキシン除草剤
を含む除草組成物を含む。

Alternatively, it comprises an agriculturally acceptable salt or ester thereof, and a herbicidal composition comprising (b) a synthetic auxin herbicide.

The second embodiment is a mixture of the first embodiment, wherein the formula (I) is as follows: carboxylic acid, carboxylic acid salt, aralkyl, alkyl ester, unsubstituted benzyl, substituted benzyl,
Includes a mixture present in at least one form of C _{1-4 alkyl and / or n-butyl ester.}

The third embodiment is a mixture according to either the first or second embodiment (b).
) At least one synthetic auxin herbicide is 2,4-D, 2,4-D EHE, 2,4
-DMA, 2,4-D choline, aminocyclopyracrol, aminopyrlide, aminopyralid TIPA, clomeprop-P, clopyralid, clopyralid MEA, dicamba, dicamba DMA, dichloroprop-P, fluloxipyl, fluloxipyl MHE, MCP
A, MCPA EHE, MCPB, MCPB-ethyl ester, mecoprop-P, picloram, picloram K ⁺ salt, quinchlorac, triclopyr, triclopyr TEA, triclopyr choline, triclopyr BEE, halauxifen-methyl, halauxifen-
At least one agriculturally acceptable methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) picolinate methyl) or a potassium carboxylic acid salt thereof, or the synthetic auxin herbicide described above. Contains mixtures, which are at least one compound selected from the group consisting of salts, esters, or carboxylates thereof.

The fourth embodiment is a mixture according to any one of the first, second, or third embodiments, in which the synthetic auxin herbicide is 2,4-D, 2,4-D EHE. , 2,4-
DMA, or 2,4-D choline, gae / ha vs gai / ha or gae / h
Compounds of formula (I), given in units of a vs. gae / ha, and 2,4-D, 2,4-D.
Weight ratio to EHE, 2,4-DMA, or 2,4-D choline is 1: 128 to about 0.6
7: 1, 1:14 to about 14: 1, 1: 2, 1: 3.5, 1: 4, 1: 6, 1: 7, 1: 8
, 1:11, 1:12, 1:14, 1:16, 1:17, 1:23, 1:24, 1:28
, 1:32, 1:45, 1:48, 1:55, 1:56, 1:64, 1:96, 1:11
0, 1:16 to 1:64, 1: 3.5 to 1:28, 1: 8 to 1:64, 1: 2, to 1: 1
6, 1: 11 to 1:45, 1: 6 to 1:96, 1: 4 to 1:64, 1: 4 to 1:32, 1
: 7 to 1:55, 1: 7 to 1:28, 1:14 to 1:110, 1:28 to 1:56, 1:
It comprises a mixture selected from a range of ratios consisting of 2 to 1: 110 and a group of ratios consisting of them, or within any range defined between any set of values above.

A fifth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is aminocyclopyracrol, gae /.
The weight ratio of the compound of formula (I) to aminocyclopyrachlor given in units of ha vs. gai / ha or gae / ha vs. gae / ha is 1: 4 to about 2: 1, 1: 2 to about. 1: 1
Selected from a range of ratios consisting of 1, 1, 1: 2, 1: 4, 1: 1 to 1: 4 and a group of ratios consisting of these, or defined between any set of values above. Includes mixtures, which are within any range that has been.

A sixth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is aminopyralid or aminopyralid TIP.
The weight ratio of the compound of formula (I) to aminopyralid or aminopyralid TIPA, which is A and is given in units of gae / ha vs gai / ha or gae / ha vs gae / ha, is 1: 8 to about 6: 1. , Approximately 1.5: 1-1: 2, 1: 1, 1: 2, 1: 4, 1: 8, 3.1
, A mixture selected from a range of ratios consisting of 1: 1 to 1: 8 and a group of ratios consisting of these, or within any range defined between any set of values above. include.

A seventh embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is clomeprop-P, a compound of formula (I). Or a mixture having a weight ratio of the salt or ester to clomeprop-P or the salt or ester thereof in the range of 1: 159 to about 1: 1 or about 1: 200 to about 6: 1. include.

Eighth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is clopyralid or clopyralid MEA, gae / ha vs. gai. The weight ratio of the compound of formula (I) to clopyralid or clopyralid MEA, given in units of / ha or gae / ha to gae / ha, is approximately 1:23.
~ About 1: 4, about 1:16 ~ about 1: 6, 1: 4, 1: 5.7, 1.8, 1:16, 1: 4 ~
It comprises a mixture selected from a range of ratios consisting of 1:16 and a group of ratios consisting of these, or within any range defined between any set of values above.

A ninth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is dicamba or dicamba DMA, ga.
Formula (I) given in units of e / ha vs gai / ha or gae / ha vs gae / ha
The weight ratio of the compound of) to dicamba or dicamba DMA is about 1: 255 to about 1.2: 1.
, About 1: 31 to about 1: 7, 1: 3.3, 1: 4, 1: 6.6, 1: 8, 1:11, 1: 1
6, 1:26, 1:45, 1:53, 1:64, 1:26 to 1:53, 1: 8 to 1:64
, 1: 3.3 to 1:26, 1: 11 to 1:45, 1: 3.3 to 1:64, and a group of ratios consisting of these, or the above values. Includes mixtures, within any range defined between any set.

A tenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is dicloprop-P, gae / ha vs. gai /. The weight ratio of the compound of formula (I) given in the unit of ha or gae / ha to gae / ha and dicloprop-P is 1:16, about 1: 4 to about 1:64, 1:32. Includes mixtures selected from the range of, and the group of ratios consisting of these.

The eleventh embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is fluloxipill or fluloxipill MHE.
The weight ratio of the compound of formula (I) given in units of gae / ha to gai / ha or gae / ha to gae / ha is about 1:
127 to about 2: 1, 1:16 to about 1: 4.38, 1: 2, 1: 3.6, 1: 4, 1: 8,
1: 9, 1:14, 1:16, 1:18, 1:32, 1:35, 1: 2 to 1:32, 1:
2 to 1:16, 1: 4 to 1:35, 1:36 to 1:64, 1: 8 to 1:32, 1: 4.4
A range of ratios consisting of ~ 1: 64, 1: 2 to 1:35, and any range selected from the group of ratios consisting of these, or defined between any set of the above values. Contains the mixture in.

A twelfth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is MCPA or MCPA EHE, g.
Equation given in units of ae / ha vs gai / ha or gae / ha vs gae / ha (I)
) And MCPA or MCPA EHE have a weight ratio of about 1:64 to about 0.6: 1.
About 1:16 to about 1: 7, 1: 2, 1: 2.2, 1: 4, 1: 4.4, 1: 6.6, 1: 8
, 1: 8.8, 1:11, 1:16, 1: 17.5, 1:32, 1:35, 1: 2: 1:
16, 1: 5.7 to 1:32, 1: 8 to 1:32, 1: 2.2 to 1:35, 1: 2 to 1:
Includes a range of ratios consisting of 35, and mixtures selected from a group of ratios consisting of these, or within any range defined between any set of values above.

A thirteenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is MCPB or a salt or ester thereof, gae / ha pair. The weight ratio of the compound of formula (I) given in the unit of gai / ha or gae / ha to gae / ha and MCPB is about 1: 250 to about 3: 1, about 1: 150 to about 0.
.. Includes a range of ratios consisting of 75: 1 and mixtures that are selected from a group of ratios consisting of these or within any range defined between any set of values above.

A fourteenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is mecoprop-P, gae / ha vs. g.
The weight ratio of the compound of formula (I) given in units of ai / ha or gae / ha to gae / ha and mecoprop-P is 1:23, about 1:20 to about 1:60, about 1:40 to About 1: 1
Includes mixtures that are selected from a range of ratios consisting of 00 and a group of ratios consisting of these, or within any range defined between any set of values above.

A fifteenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is picloram or picloram K ⁺ salt.
An expression given in units of gae / ha vs gai / ha or gae / ha vs gae / ha (
The weight ratio of the compound of I) to picloram or picloram K ⁺ salt is about 1:16 to about 1.75.
1, about 0.44: 1 to about 1: 4, 1: 1.1, 1: 2, 1: 4, 1: 8, 1:16, 1
: Selected from a range of ratios consisting of 2 to 1:16, 1: 1.1 to 1:16, and a group of ratios consisting of these, or defined between any set of the above values. Includes mixtures, within any range.

The sixteenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is quinchlorac, gae / ha vs. g.
The weight ratio of the compound of formula (I) to quinchlorac, given in units of ai / ha or gae / ha vs. gae / ha, is about 1: 128 to about 1.2: 1, about 1:16 to about. 1: 6.5
1: 1.7, 1: 2, 1: 3, 1: 4, 1: 7, 1:13, 1:16, 1:18, 1:
26, 1:32, 1:35, 1:64, 1:70, 1: 128, 1: 9 to 1:70, 1:
3 to 1:128, 1:16 to 1:64, 1: 7 to 1:13, 1: 7 to 1:64, 1: 8 to
1:64, 1: 4 to 1:16, 1: 2 to 1: 128, 1: 1.7 to 1:32, 1: 1.7
Includes a mixture selected from a range of ratios consisting of ~ 1: 16 and a group of ratios consisting of these, or within any range defined between any set of values above.

The seventeenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is triclopyr, triclopyr TEA, triclopyr choline, or triclopyr BEE. The weight ratio of the compound of formula (I) to triclopyr, triclopyr TEA, triclopyr choline, or triclopyr BEE, given in units of gae / ha vs gai / ha or gae / ha vs gae / ha, is about. 1
: 64 to about 1.2: 1, about 1: 8 to about 1: 6.6, 1: 1.7, 1: 2, 1: 3.3, 1
: 4, 1: 5, 1: 5.6, 1: 6.6, 1: 8, 1:11, 1:13, 1:14, 1:
16, 1:22, 1: 17.5, 1:22, 1:26, 1:32, 1:45, 1: 5-1
: 45, 1, 11 to 1:45, 1: 2 to 1:16, 1: 2 to 1:32, 1: 4 to 1:32
Selected from a range of ratios consisting of 1, 1.7 to 1:26, 1: 1.7 to 1:13, 1: 7 to 1:45 and a group of ratios consisting of these, or of the above values. Includes mixtures, within any range defined between any set.

The eighteenth embodiment is a mixture according to any one of the first, second, or third embodiments, wherein the synthetic auxin herbicide in the mixture is halauxifene-methyl (4-amino-).
3-Chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) methyl picolinate) or a potassium carboxylic acid salt thereof, gae / ha vs. gai / ha or gae
The compound of formula (I) and halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) picolin, given in units of / ha vs. gae / ha. The weight ratio of methyl acid) or its potassium carboxylic acid salt is about 1: 2 to about 20.
1, about 2: 1 to about 5: 1, 1: 4, 1: 2, 1.2: 1, 1: 1, 2: 1, 2.4: 1
4: 1, 5: 1, 8: 1, 10: 1, 1: 2-4: 1, 1: 1-8: 1, 1.2: 1-
Selected from a range of ratios consisting of 10: 1, 1: 4 to 4: 1, 1: 4-10: 1 and a group of ratios consisting of these, or defined between any set of values above. Includes mixtures, which are within any range of.

A nineteenth embodiment is any composition according to any of the first to seventeenth embodiments, at least one in which the mixture is selected from the group consisting of an adjuvant, a carrier, or a phytotoxicity reducing agent. Contains a composition that further comprises an agriculturally acceptable agent of.

A twentieth embodiment applies or otherwise contacts vegetation and / or soil, and / or water with at least one mixture of herbicidal effective amounts according to any of the first to eighteenth embodiments. Includes methods of controlling unwanted vegetation, including steps to cause.

A twenty-first embodiment is a method according to the twentieth embodiment, in which direct-seeded rice, flooded direct-seeded rice, and / or transplanted rice, grain, wheat, barley, oat wheat, lime, sorghum, corn / corn, sugar cane, Sunflower, abrana, canola, tensai, soybean, cotton, pineapple, pasture, grassland, pasture, fallow land, lawn, tree and vineyard,
Includes methods implemented in at least one component of a group consisting of aquatic plants, plantation crops, vegetables, industrial vegetation management (IVM), or rights-of-way (ROW).

The 22nd embodiment is a method according to any of the 20th and 21st embodiments.
Includes a method in which a herbicidal effective amount mixture is applied to at least one of a crop, field, ROW, or paddy field before or after an outbreak.

The 23rd embodiment is a method according to any of the 20th to 22nd embodiments, in which the undesired vegetation is subjected to glyphosate, 5-enolpyrvir simimate-3-phosphate (EPSP) synthase inhibitor, gluhosinate. , Glutamine synthetase inhibitor, dicamba, phenoxyauxin, pyridyloxyoxin, synthetic auxin, auxin transport inhibitor, aryloxyphenoxypropionate, cyclohexanedione, phenylpyrazolin, acetyl CoA carboxylase (ACCase) inhibitor, imidazolinone, Sulfonylurea, pyrimidinylthiobenzoate, triazolopyrimidine sulfonamide, sulfonylaminocarbonyltriazolinone, acetolactate synthase (ALS)
Or acetohydroxy acid synthase (AHAS) inhibitor (iinhibitor), 4-hydroxyphenyl-pyrvate dioxygenase (HPPD) inhibitor, phytoene desaturase inhibitor, carotenoid biosynthesis inhibitor, protoporphyrinogen oxidase (PPO)
) Inhibitors, cellulose biosynthesis inhibitors, thread division inhibitors, microtube inhibitors, ultra-long chain fatty acid inhibitors, fatty acid and lipid biosynthesis inhibitors, photochemical system I inhibitors, photochemical system II inhibitors, protoporphy Includes methods that can be controlled in linogen oxidase (PPO) inhibitors, triazine, or bromoxinyl resistant crops.

A twelfth embodiment is at least one method according to any of the twentieth to twenty-third embodiments, in which a plant resistant or resistant to at least one herbicide is treated and the resistant or resistant crop is treated. Has multiple or stacked traits that confer resistance to multiple herbicides or inhibitors consisting of multiple mechanisms of action, and in some embodiments resistant to herbicides or Includes methods in which the treated plant itself exhibiting resistance is an unwanted vegetation.

A twenty-fifth embodiment is the method according to the twenty-fourth embodiment, in which resistant or resistant weeds become multiple herbicides, multiple chemical classes, multiple herbicide mechanisms of action inhibitors. Includes methods that are biotypes that are resistant or resistant to, or that are by multiple resistance mechanisms.

The 26th embodiment is at least one method according to either the 24th or 25th embodiment, in which the undesired resistant or resistant plant is an acetolactate synthase (A).
LS) inhibitor or acetohydroxy acid synthase (AHAS), photosystem II inhibitor,
Acetyl-CoA carboxylase (ACCase) inhibitor, synthetic auxin, auxin transport inhibitor, photosystem I inhibitor, 5-enolpyrvir silicate-3-phosphate (
EPSP) synthase inhibitor, microtube assembly inhibitor, fatty acid and lipid synthesis inhibitor, protoporphyrinogen oxidase (PPO) inhibitor, carotenoid biosynthesis inhibitor, very long chain fatty acid (VLCFA) inhibitor, phytoendesaturase (PDS) ) Inhibitor, Glutamine Synthetase Inhibitor, 4-Hydroxyphenyl-Pilbate-Dioxygenase (HPP)
D) Inhibitors, mitotic inhibitors, cellulose biosynthesis inhibitors, herbicides with multiple mechanisms of action, quinchlorac, arylaminopropionic acid, difenzocoat, endotar,
Alternatively, it comprises a method of being a biotype resistant or resistant to at least one agent selected from the group consisting of organoarsenic compounds.

A twenty-seventh embodiment is a method of controlling unwanted vegetation, comprising the step of applying at least one mixture according to the fourth embodiment of a herbicidal effective amount, 2,4-D, 2,4.
-D EHE, 2,4-DMA or 2,4-D choline gai / ha or gae / h
Expressed by a, about 35, 50, 52.5, 70, 105, 140, 150, 210, 240
, 280, 420, 480, 70-280, 105-420, 52.5-105, 240
A dose consisting of ~ 480, 35-70, 35-480, and any range defined between any set of values selected from the group of dose ranges consisting of these. Includes a method in which an amount of the mixture is applied at an application dose set forth in.

The 28th embodiment is a method according to either the 4th or 26th embodiment, and the plant to be controlled is ECHCG, DIGSA, ECHCO, CYPES, CYPIR, BR.
APP, LEFCH, ECHOR, CYPRO, SCPJU, SCPMA, PANDI,
ELEIN, CENMA, PANMI, POLCO, SINAR, SONAR, SORH
Includes methods that are at least one plant selected from the group consisting of A, CASOB, yet other embodiments include Barnyardgrasses (Echinochloa), Fingergrasses (Digitaria), Cyperus, Panicgrass (Brachiaria). , Panicgrass (Urochloa), Azegaya (Leptochloa), Schoenop, Schoenoplactus, Panicgrass, Polygonum, Sinapis, Son
Includes steps to control plants from the genus Sorghum, Sorghum, and Cassia.

A 29th embodiment is a method of controlling unwanted vegetation, comprising the step of applying at least one mixture of herbicidal effective amounts according to the fifth embodiment, gai / ha or gae / of aminocyclopyrachlor. Expressed in ha, about 8.75, 17.5, 8.75 ~
The mixture at a dose selected from the group consisting of a dose of 17.5 and a range of doses consisting of these, or at a dose within any range defined between any set of values above. Includes how the amount of is applied.

A thirtieth embodiment is a method according to any one of the fifth and 29th embodiments, in which the plant to be controlled is selected from the group consisting of TRFRE, SINAR, and CENMA.
Yet another embodiment comprises the method of being at least one plant, the genus Trif.
Includes steps to control plants from the genus olium), mustard (Sinapis) and Knapweed (Centaurea).

A thirty-first embodiment is a method of controlling unwanted vegetation, comprising the step of applying at least one mixture of herbicidal effective amounts according to the sixth embodiment, including aminopyralid or aminopyralid TIPA gai / ha or gae /. Expressed in ha, about 3,17.5
, 35, 17.5-35, and any range defined between any set of values selected from the group of dosage ranges consisting of these. The application dose comprises a method in which the amount of the mixture is applied.

The 32nd embodiment is a method according to either of the 6th and 31st embodiments, and the plant to be controlled is POLCO, CIRAR, BRSNN, TRFRE, SINAR,
Includes methods that are at least one plant selected from the group consisting of Sooß, yet another embodiment includes Prostrate knotweed (Polygonum), Cirsium (Cirsium), Brassica (Bras).
Includes steps to control plants from the genus consisting of sica), trifolium, mustard (Sinapis), and solidago (Solidago).

A thirty-third embodiment is a method of controlling unwanted vegetation, comprising applying a herbicidal effective amount of at least one mixture according to the seventh embodiment, Chromeprop-P.
Expressed as gai / ha or gae / ha, it is about 50 gae / ha to about 400 gae / h.
The mixture at a dose selected from the group consisting of a dose of a and a range of doses consisting of these, or at a dose within any range defined between any set of values above. Includes how the amount is applied.

A thirty-fourth embodiment is a method of controlling undesired vegetation, which comprises the step of applying at least one mixture according to the eighth embodiment of the herbicidal effective amount, and is represented by gai / ha or gae / ha. Cropyralid or clopyralid MEA is about 35, 50, 35
Amount of the mixture selected from the group consisting of a dose of 50 and a range of doses consisting of these, or at a dose within any range defined between any set of values above. Includes the method by which is applied.

The 35th embodiment is a method according to either the 8th or 34th embodiment, in which the plant to be controlled is at least one plant selected from the group consisting of AMARE, CIRAR and SOOS. Yet another embodiment, including methods, includes the genus Amaranthus,
It involves controlling plants from the genus Cirsium and Solidago.

A thirty-sixth embodiment is a method of controlling unwanted vegetation, comprising the step of applying at least one mixture of herbicidal effective amounts according to the ninth embodiment, gai / ha or gae / of dicamba or dicamba DMA. Expressed in ha, about 35, 50, 70, 140,
A dose consisting of 280, 140-280, 35-280, and any range defined between any set of values selected from the group of dose ranges consisting of these. Includes a method in which an amount of the mixture is applied at a given dose.

The 37th embodiment is a method according to either of the 9th and 36th embodiments, and the plant to be controlled is AMARE, POLCO, BRSNN, LEFCH, CYPIR, and the like.
ECHCO, ECHCG, ECHOR, SCPMA, SIDSP, SINAR, CASO
Includes the method of being at least one plant selected from the group consisting of B, yet another embodiment includes the genus Amaranthus, the genus Progonum, the genus Brassica.
From Leptochloa, Cyperus, Echinochloa, Schoenoplectus, Puruagrass, Sida, Sinapis, and Cassia Includes steps to control plants from the genus.

The 38th embodiment is a method for controlling undesired vegetation, and the tenth effective amount of weeding is used.
Includes the step of applying at least one mixture according to the embodiment of dicroprop-
Expressed as gai / ha or gae / ha of P, it is selected from the group consisting of doses consisting of about 70, 140, 280, 560 and 1,120, and a range of doses consisting of these.
Alternatively, it comprises a method in which the amount of the mixture is applied at an application rate that is within any range defined between any set of the above values.

The 39th embodiment is a method according to either the 10th or 38th embodiment.
The plant to be controlled comprises at least one plant selected from the group consisting of VIOTR, BRSNN, yet another embodiment is derived from the genus Violet (Viola) and Brassica (Brassica). Includes steps to control rapeseed.

The 40th embodiment is a method for controlling unwanted vegetation, and the eleventh effective amount of weeding is used.
Including the step of applying at least one mixture according to the embodiment of, expressed in gai / ha or gae / ha, fluloxipill or fluloxipill MHE is about 35,70,
Any dose selected from the group consisting of doses consisting of 140, 149, 280, 70-280, 35-280 and a range of doses consisting of these, or any defined between any set of values above. Includes methods in which the amount of the mixture is applied at an application dose within the range.

The 41st embodiment is a method according to either the 11th or 40th embodiment.
The plants to be controlled are CENMA, SONAR, TRFRE, SOOSS, ECHCG, E.
CHCO, CYPDI, LEFCH, ECHOR, SCPJU, AMARE, SCPMA
, VIOTR, POLCO, CIRAR, and SASKR.
Including methods that are at least one plant, yet another embodiment is the genus Knapweed (Cent).
aurea), Sow thistle (Sonchus), Trifolium, Solidago (S)
olidago), Barnyardgrass (Echinochloa), Nutsedge (Cyperus), Leptochloa (Leptoch)
loa), Scirpus (Schoenoplectus), Violet (Viola), Prostrate knotweed (Polygonum)
), Salsola, and Cirsium.

The 42nd embodiment is a method for controlling unwanted vegetation, and a 12th effective amount of weeding is used.
Including the step of applying at least one mixture according to the embodiment of MCPA or M.
Expressed as gai / ha or gae / ha of CPA EHE, it is about 50, 70, 140, 2
Selected from a group of dosages consisting of 80, 50-140, 70-140, 50-280, 70-280, and a range of dosages consisting of these, or defined between any set of values above. Includes methods in which the amount of the mixture is applied at an application rate that is within any range given.

The 43rd embodiment is a method according to either the 12th or the 42nd embodiment, and the plant to be controlled is BRAPP, DIGSA, ECHCG, ECHOR, LEFCH.
, CPJU, VIOTR, POLCO, BRSNN, comprising the method of being at least one plant selected from the group, yet another embodiment is Brachiaria.
), Digitaria, Echinochloa, Viola, Polygonum, Brassica, Leptochloa and Schoenoplectus. Includes steps to do.

The 44th embodiment is a method for controlling unwanted vegetation, and the 13th effective amount of weeding is used.
Mecoprop-P, comprising the step of applying at least one mixture according to the embodiment of.
Expressed as gai / ha or gae / ha, about 50, 100, 200, 400 and 1
The mixture at a dose selected from the group consisting of a dose of 000 and a range of doses consisting of these, or at a dose within any range defined between any set of values above. Includes how the amount of is applied.

The 45th embodiment is a method according to any one of the 13th and 44th embodiments, and includes a method in which the plant to be controlled is at least one plant selected from the group consisting of BRSNN. Yet another embodiment comprises controlling plants from the genus Brassica.

The 46th embodiment is a method for controlling unwanted vegetation, and the 14th effective amount of weeding is used.
Including the step of applying at least one mixture according to the embodiment of, picloram or picloram K ⁺ salt gai / ha or gae / ha of about 10, 35, 70, 3
With a dose selected from the group consisting of a dose consisting of 5 to 70 and a range of doses consisting of these, or within any range defined between any set of values above. Includes how the amount of mixture is applied.

The 47th embodiment is a method according to any one of the 14th and 46th embodiments, and the plant to be controlled is VIOTR, STEME, POLCO, CENMA, SINAR.
The method comprises at least one plant selected from the group consisting of, yet other embodiments include Violet (Viola), Chickweed (Stellaria), Knotweed (Polygonum), Knapweed (Centaurea), and. Includes steps to control plants from the genus Sinapis.

The 48th embodiment is a method for controlling undesired vegetation, and is a fifteenth effective amount of weeding.
Including the step of applying at least one mixture according to the embodiment of, expressed in terms of gai / ha or gae / ha of quinchlorac, about 70, 140, 280, 560, 70-2.
At a dose selected from the group consisting of doses consisting of 80, 70-560, and a range of doses consisting of these, or at a dose within any range defined between any set of values above. ,
Includes methods in which the amount of the mixture is applied.

The 49th embodiment is a method according to either of the 15th and 48th embodiments, and the plants to be controlled are AMARE, VIOTR, ECHOR, SCPMA, POLCO, and the like.
Includes a method that is at least one plant selected from the group consisting of CYPES, DIGSA, CYPIR, ECHCG, ISCRU, yet another embodiment includes the genus Amaranth.
us), violets (Viola), barnyardgrass (Echinochloa), scirpus (Schoenoplectus), purua grass (Bolboschoenus), genus Polygonum, genus Nutsedge (Cyperus)
), Digitaria, and Ischaemum.

A fiftyth embodiment is a method for controlling unwanted vegetation, wherein an effective amount of weeding is sixteenth.
Approximately 35, 50, 70, 98.3, 140, represented by gai / ha or gae / ha of triclopyr, triclopyr TEA, triclopyr choline or triclopyr BEE, comprising the step of applying at least one mixture according to the embodiment of. 196.6, 280,
Selected from the group consisting of doses consisting of 35-140, 98.3-280, 70-280, 70-140, 35-280, and a range of doses consisting of these, or any set of the above values. Includes methods in which the amount of the mixture is applied at an application rate that is within any range defined between.

The 51st embodiment is a method according to either 16th or 49th embodiment, and the plant to be controlled is BRAPP, SCPJU, DIGSA, ECHOR, ECHCG.
, SCPMA, ECHCO, LEFCH, CENMA, SONAR, CIRAR, CAS
Includes methods that are at least one plant selected from the group consisting of OB, yet other embodiments include Sow thistles (Brachiaria), Sow thistles (Schoenoplectus), Fingergrasses (Digitaria), Barnyardgrasses (Echinochloa), Purua grass (Bolboschoenus), Azegaya (Leptochloa), Knapweed (Centaurea), Sow thistle (Sonchus), Barnyard grass (Cirs)
ium), and includes steps to control plants from the genus Cassia.

The 52nd embodiment is a method for controlling unwanted vegetation, and the 17th effective amount of weeding is used.
Halauxifene-methyl (4-amino-3-chloro-6- (4-amino-3-chloro-6-), comprising the step of applying at least one mixture according to the embodiment of the above, in terms of gai / ha or gae / ha.
4-Chloro-2-fluoro-3-methoxyphenyl) methyl picolinate) or potassium carboxylic acid salt thereof is about 2.19, 3.75, 4.38, 7.5, 8.75, 15, 2.1.
Select from the group of dosages consisting of 9-4.38, 4.38-8.75, 3.75-15, 2.19-15 and a range of dosages consisting of these, or any of the above values. Includes methods in which the amount of the mixture is applied at an application rate that is within any range defined between the set.

The 53rd embodiment is a method according to either 17th or 52nd embodiment, and the plant to be controlled is LEFCH, IPOHE, CYPIR, ECHCG, ECHOR.
, CYPRO, SORHA, ELEIN and KCHSC, comprising the method of being at least one plant, yet another embodiment of the genus Leptochloa.
), Ipomoea, Cyperus, Echinochloa,
It involves controlling plants from the genus Sorghum, Eleusine, and Kochia.

The 54th embodiment is a composition according to any one of the first to third embodiments (b).
) Includes a composition in which is aminocyclopyrachlor.

The 55th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains a composition of aminopyralid or aminopyralide TIPA.

The 56th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains a composition of Chromeprop-P.

The 57th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains a composition, wherein is clopyralid or clopyralid MEA.

The 58th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains a composition, which is dicamba or dicamba DMA.

The 59th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains a composition of which is dicloprop-P.

The 60th embodiment is a composition according to any one of the 1st to 3rd embodiments (b).
) Contains a composition, which is fluloxipill or fluloxipill MHE.

The 61st embodiment is a composition according to any one of the 1st to 3rd embodiments (b).
) Contains a composition, which is MCPA or MCPA EHE.

The 62nd embodiment is a composition according to any one of the 1st to 3rd embodiments (b).
) Contains a composition, which is MCPB or MCPB ethyl ester.

The 63rd embodiment is a composition according to any one of the 1st to 3rd embodiments (b).
) Contains a composition, which is Mecoprop-P.

The 64th embodiment is a composition according to any one of the 1st to 3rd embodiments (b).
) Contains a composition in which is picloram or picloram K ^{+ salt.}

The 65th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains the composition, which is quinchlorac.

The 66th embodiment is a composition according to any one of the first to third embodiments (b).
) Is triclopyr, triclopyr TEA, triclopyr choline or triclopyr BEE
Contains the composition.

The 67th embodiment is a composition according to any one of the first to third embodiments (b).
) Contains a composition in which halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) methyl picolinate) or a potassium carboxylic acid salt thereof. ..

The 68th embodiment includes a method according to any of the 20th to 53rd embodiments, wherein the undesired vegetation is immature.

A 69th embodiment is a method according to any of the 20th to 53rd, or 68th embodiments, comprising a method in which the composition is applied to water that is part of a flooded paddy field. ..

In the present specification, the herbicidal effective amount of the compound of the formula (a) (I)

または農業上許容されるその塩もしくはエステル、および（ｂ）合成オーキシン除草剤を
含む除草組成物が提供される。本組成物は、農業上許容されるアジュバントまたは担体を
含有してもよい。

Alternatively, a herbicidal composition comprising an agriculturally acceptable salt or ester thereof and (b) a synthetic auxin herbicide is provided. The composition may contain an agriculturally acceptable adjuvant or carrier.

The present specification includes the step of applying (a) a compound of formula (I), or an agriculturally acceptable ester or ester thereof, and (b) a synthetic auxin herbicide or an agriculturally acceptable salt or ester thereof. Also provided are methods of controlling unwanted vegetation.

Detailed Description Definitions As used herein, compounds of formula (I) have the following structure:

を有する。式（Ｉ）の化合物は、４−アミノ−３−クロロ−６−（４−クロロ−２−フル
オロ−３−メトキシフェニル）−５−フルオロピリジン−２−カルボン酸という名前によ
って特定することができ、その全体が参照により本明細書に組み込まれている、米国特許
第７，３１４，８４９（Ｂ２）号において記載されている。式（Ｉ）の化合物の例示的な
使用には、複数の非作付けおよび作付け状況において、イネ科雑草、広葉雑草、およびス
ゲ雑草を含む、望ましくない植生を防除することが含まれる。

Have. The compound of formula (I) can be identified by the name 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) -5-fluoropyridin-2-carboxylic acid. , All of which are incorporated herein by reference in US Pat. No. 7,314,849 (B2). Exemplary uses of compounds of formula (I) include controlling unwanted vegetation, including grass weeds, broadleaf weeds, and sedge weeds, in multiple non-planting and planting situations.

Without being limited to any theory, synthetic auxin herbicides are generally, mimicking auxins, herbicides classified as plant growth hormone. They are often referred to as growth regulators because they upset the balance of natural hormones in plants. Exemplary synthetic auxin herbicides include, but are not limited to, 2,4-D, 2,4-DB, aminocyclopyracrol, aminopyrlide, clomeprop-P, clopyralid, dicamba, dicloprop-P, fluloxy. Pyrmeptylheptyl ester (MHE)
, MCPA, MCPB, Mecoprop-P, picloram, quinchlorac, triclopyr, and halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-).
Fluoro-3-methoxyphenyl) methyl picolinate), or agriculturally acceptable salts or esters thereof.

As used herein, 2,4-D is 2- (2,4-dichlorophenoxy) acetic acid and has the following structure:

を有する。

Have.

Illustrative use of 2,4-D is Tomlin, C. (eds.) A World Compendium The Pesticide M
anual. 15th Edition, Alton: BCPC Publications, 2009 (hereafter, "The Pesticide Manual"
, 15th edition, 2009 "). Illustrative uses of 2,4-D include, for example, in grains, corn, morokoshi, grasslands, established lawns, grass seed crops, orchards, cranberries, asparagus, sugar cane, rice forests, and non-agricultural lands. Includes use for post-outbreak control of annual and perennial broad-leaved weeds. Exemplary chemical forms of 2,4-D are salt or ester forms, such as 2-ethylhexyl 2- (2,4-dichlorophenoxy) acetate, which have the following structure:

を有する２，４−Ｄ ＥＨＥ、
Ｎ−メチルメタンアミンを有する２−（２，４−ジクロロフェノキシ）酢酸であり、以下
の構造

With 2,4-D EHE,
2- (2,4-dichlorophenoxy) acetic acid having N-methylmethaneamine and having the following structure

を有する２，４−Ｄ ＤＭＡ、
２−（２，４−ジクロロフェノキシ）酢酸２−ヒドロキシ−Ｎ，Ｎ，Ｎ−トリメチルエタ
ンアミニウムであり、以下の構造

With 2,4-D DMA,
2- (2,4-dichlorophenoxy) acetate 2-hydroxy-N, N, N-trimethylethaneaminium with the following structure

を有する２，４−Ｄコリン、
および、
２−（２，４−ジクロロフェノキシ）酪酸であり、以下の構造

With 2,4-D choline,
and,
2- (2,4-dichlorophenoxy) butyric acid with the following structure

を有する２，４−ＤＢが含まれる。

2,4-DB having

As used herein, aminocyclopyrachlor is 6-amino-5-chloro-.
2-Cyclopropyl-4-pyrimidinecarboxylic acid with the following structure

を有する。

Have.

An exemplary use of aminocyclopyracrol is described in The Pesticide Manual, 15th Edition, 2009. Exemplary uses of aminocyclopyracrol include, for example, its use for controlling broadleaf weeds and tree species in public road lands, factory lands, rangelands, perennial grass pastures, and natural areas.

As used herein, aminopyralide is 4-amino-3,6-dichloro-2-.
It is a pyridinecarboxylic acid and has the following structure.

を有する。

Have.

Illustrative use of aminopyralid is described in The Pesticide Manual, 15th Edition, 2009. Exemplary uses of aminopyralids include, for example, their use for long-term control of annual and perennial broadleaf weeds in rangelands and pastures. An exemplary chemical form of aminopyralid is, for example, a 4-amino-3,6-dichloropyridin-2-carboxylic acid compound having 1,1', 1 "-nitrilotris [2-propanol], such as: Construction

を有するアミノピラリドＴＩＰＡが含まれる。

Includes aminopyralid TIPA with.

As used herein, clomeprop-P refers to 2- (2,4-dichloro-3-methylphenoxy) -N-phenylpropanamide and has the following structure:

を有する。

Have.

An exemplary use of Chromeprop-P is described in The Pesticide Manual, 15th Edition, 2009. Exemplary uses of clomeprop include, for example, its use in paddy rice to control broad-leaved weeds and sedge weeds before or early after outbreak.

As used herein, chloride is a 3,6-dichloro-2-pyridinecarboxylic acid and has the following structure:

を有する。

Have.

Illustrative use of clopyralid is described in The Pesticide Manual, 15th Edition, 2009. Illustrative uses of clopyralid include, for example, sugar beet, feed beet, rape, corn, grain, Brassica, onions, leeks, strawberry, and flax, as well as numerous annuals and perennial lands in grasslands and non-agricultural lands. Includes use for controlling broadleaf weeds after outbreak. An exemplary chemical form of clopyralid is, for example, a 3,6-dichloro-2-pyridinecarboxylic acid having 2-aminoethanol and having the following structure:

を有する、クロピラリドＭＥＡが含まる。

Includes clopyralid MEA.

As used herein, dichloromethane is 3,6-dichloro-2-methoxybenzoic acid and has the following structure:

を有する。

Have.

Illustrative use of dicamba is described in The Pesticide Manual, 15th Edition, 2009. Illustrative uses of dicamba include, for example, perennial and perennial broadleaf weeds in grains, corn, morokoshi, sugar cane, asparagus, seed grasses, lawns, pastures, pastures, and non-agricultural lands. Includes its use to control brush species. An exemplary chemical form of dicambe includes, for example, N-
It is a 3,6-dichloro-2-methoxybenzoic acid compound having methylmethaneamine and has the following structure.

を有する、ジカンバＤＭＡが含まれる。

Includes dicamba DMA having.

Use As used herein, dichloroprop-P is (2R) -2- (2,4-).
Dichlorophenoxy) Propionic acid, which has the following structure

を有する。

Have.

An exemplary use of Dichlorprop-P is described in The Pesticide Manual, 15th Edition, 2009. Illustrative uses of dichlorprop-P include, for example, in grains.
Includes its use for controlling broadleaf weeds after outbreak.

As used herein, a fluorideyl is 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl) oxy] acetic acid and has the following structure:

を有する。

Have.

Illustrative use of furloxipills is described in The Pesticide Manual, 15th Edition, 2009. Illustrative uses of furloxipills include, for example, control of broadleaf weeds in small grain crops, Rumex spp. And Urtilc in pastures.
Includes its use for post-occurrence foliar application, controlling a dioica) and controlling white clover (Trifolium repens) in amenity grasslands. Other exemplary uses include, for example, herbaceous and woody broadleaf weeds in orchards and plantation crops, and, for example, their use for controlling broadleaf shrubs in coniferous forests. An exemplary chemical form of fluoroxypyr is, for example, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl) oxy] 1-methylheptyl acetate, which has the following structure:

を有するフルロキシピルＭＨＥが含まれる。

Includes fluloxipill MHE with.

As used herein, MCPA is 2- (4-chloro-2-methylphenoxy).
Acetic acid with the following structure

を有する。

Have.

An exemplary use of MCPA is described in The Pesticide Manual, 15th Edition, 2009. Illustrative uses of MCPA include, for example, in grains, herbaceous seed crops, flax, sake rice, pea, potatoes, asparagas, grasslands, lawns, under fruit trees, and on roadside grass edges, and banks. Includes its use for post-outbreak control of annual and perennial broad-leaved weeds. Other exemplary uses include, for example, broadleaf and woody weeds in forests, as well as their use for controlling aquatic broadleaf weeds. An exemplary chemical form of MCPA is, for example, 2-ethylhexyl 2- (4-chloro-2-methylphenoxy) acetate, which has the following structure:

を有する、ＭＣＰＡ ＥＨＥが含まれる。

Includes MCPA EHE having.

As used herein, MCPB is 4- (4-chloro-2-methylphenoxy).
Butyric acid with the following structure

を有する。

Have.

Its herbicidal activity is illustrated in The Pesticide Manual, 15th Edition, 2009. MC
PB is the control of Canadian thistles in field pea, as well as white goosefoot and red lizard species (pi).
gweed spp), Tade seed (smartweed spp.), And morning glory seed (morningglory spp.)
It can be used to control or control certain annual broadleaf weeds, including.

As used herein, MCPA-sodium is sodium 4- (4-chloro-o-tolyloxy) butanoate and has the following structure:

を有する。

Have.

Its herbicidal activity is illustrated in The Pesticide Manual, 15th Edition, 2009. MC
Exemplary uses of PB-sodium include post-occurrence control of annual and perennial broad-leaved weeds in grains, clovers, onobrychis, peas, peanuts, and grasslands, as well as control of broad-leaved and woody weeds in forests.

As used herein, MCPB-ethyl is ethyl 4- (4-chloro-2-methylphenoxy) butanoate and has the following structure:

を有する。

Have.

Its herbicidal activity is illustrated in The Pesticide Manual, 15th Edition, 2009. MC
Exemplary uses of PB-ethyl ester include control of broadleaf weeds in paddy fields.

Use Mecoprop-P, as used herein, is (2R) -2- (4-chloro-).
2-Methylphenoxy) Propionic acid, which has the following structure

を有する。

Have.

An exemplary use of Mecoprop-P is described in The Pesticide Manual, 15th Edition, 2009. Exemplary uses of Mecoprop-P include, for example, wheat, barley, oats, herbaceous seed crops, and their use for post-development control of broadleaf weeds in grasslands.

As used herein, picloram is 4-amino-3,5,6-trichloro-2.
-Pyridinecarboxylic acid with the following structure

を有する。

Have.

Illustrative use of picloram is described in The Pesticide Manual, 15th Edition, 2009. Exemplary uses of picrolam include, for example, its use in rangelands, gramineous pastures, forests, and non-agricultural and public road lands to manage unwanted vegetation. An exemplary chemical form of picloram is, for example, 4-amino-3,5,6-trichloro-2-pyridinecarboxylic acid monopotassium salt with the following structure:

を有する、ピクロラムＫ^＋塩が含まれる。

Contains picloram K ⁺ salt with.

As used herein, quincrolac is a 3,7-dichloro-8-quinoline carboxylic acid and has the following structure:

を有する。

Have.

An exemplary use of quiclorac is in The Pesticide Manual, 15th Edition, 2009.
It is described in. The use of exemplary quincrolac includes, for example, in direct-seeded and transplanted rice, its use for controlling certain grass and broadleaf weeds before and after outbreak.

As used herein, triclopyr is 2-[(3,5,6-trichloro-2-.
Pyridinyl) oxy] acetate, which has the following structure

を有する。

Have.

Illustrative use of triclopyr is described in The Pesticide Manual, 15th Edition, 2009. Exemplary uses of triclopyr include, for example, its use in controlling woody plants and broad-leaved weed species in grasslands, uncultivated lands, industrial areas, coniferous forests, rice, and plantation crops. Exemplary chemical forms of triclopyr include, for example, N, N-
It is a 2-[(3,5,6-trichloro-2-pyridinyl) oxy] acetic acid compound having diethylethaneamine and has the following structure.

を有する、トリクロピルＴＥＡ、
２−ヒドロキシ−Ｎ，Ｎ，Ｎ−トリメチルエタンアミニウム２−（（３，５，６−トリク
ロロピリジン−２−イル）オキシ）アセテートであり、以下の構造

With, triclopyr TEA,
2-Hydroxy-N, N, N-trimethylethaneaminium 2-((3,5,6-trichloropyridin-2-yl) oxy) acetate with the following structure

を有する、トリクロピルコリン、
および、
２−［（３，５，６−トリクロロ−２−ピリジニル）オキシ］酢酸２−ブトキシエチルで
あり、以下の構造

Have, triclopyrcholine,
and,
2-[(3,5,6-trichloro-2-pyridinyl) oxy] 2-butoxyethyl acetate, having the following structure

を有する、トリクロピルＢＥＥが含まれる。

Includes triclopyr BEE, which has.

As used herein, halauxifene-methyl (4-amino-3-chloro-6-)
(Methyl 4-chloro-2-fluoro-3-methoxyphenyl) picolinate) has the following structure

を有する。

Have.

Halauxifene-methyl is described in US Pat. No. 7,314,849 (B2), which is incorporated herein by reference in its entirety. Exemplary uses of halauxifene-methyl include, for example, its use for controlling broadleaf weeds in grain crops. Halauxifene-methyl has other forms, eg, the following structure:

を有する、ハラウキシフェンＫ^＋（４−アミノ−３−クロロ−６−（４−クロロ−２−フ
ルオロ−３−メトキシフェニル）ピコリン酸カリウム）として使用することができる。

It can be used as halauxifene K ⁺ (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) potassium picolinate) having.

As used herein, a herbicide means, for example, a compound that is an active ingredient that kills a plant, controls its growth, or otherwise detrimentally alters its growth.

As used herein, an effective herbicidal amount or a vegetation control amount causes detrimental alterations to the vegetation, eg, causes deviations from natural growth, kills, regulates, causes depletion, grows. The amount of active ingredient, such as causing a delay.

As used herein, controlling unwanted vegetation means preventing, reducing, killing, or otherwise detrimentally altering the growth of plants and vegetation. This specification describes a method of controlling unwanted vegetation by applying a combination or composition of certain herbicides. The method of application is adjacent to the vegetation by, but is not limited to, application to the vegetation or its habitat, for example, by hand, backpack, machine, tractor, or aerial (airplane and helicopter) application. Area application, as well as pre-embryonic, post-emergent, foliar application (wide area, direct, band, spot, mechanical, over-the-top, or rescue), and underwater application (water and) Includes underwater vegetation, wide area, spot, mechanical, underwater injection, granule wide area, granule spot, shaker bottle, or stream spray).

As used herein, plants and vegetation include, but are not limited to, germinated seeds, developing seedlings, developing plants from propagules, immature vegetation, and established vegetation.

As used herein, agriculturally acceptable salts and esters are salts and esters that exhibit herbicidal activity, or are converted to referenced herbicides in plants, water, or soil, or Refers to a salt or ester that can be converted. An exemplary agriculturally acceptable ester is a hydrolyzed, oxidized, oxidized carboxylic acid in a plant, water or soil
Metabolism, which is otherwise converted or enabled, can be present in dissociated or non-dissociated form, depending on the pH.

Exemplary salts include salts derived from alkali metals or alkaline earth metals, as well as salts derived from ammonia and amines. Illustrative cations include sodium, potassium, magnesium, and the aminium cation of the formula R ¹ R ² R ³ R ⁴ N ^+.
(In the formula, R ¹ , R ² , R ³ and R ⁴ independently represent hydrogen or C _{1 to} C ₁₂ alkyl, C _{3 to} C ₁₂ alkoxy, or C _{3 to} C ₁₂ alkynyl, which are these. each one or more hydroxy _groups, C 1 -C ₄ alkoxy groups _include, optionally substituted by C 1 -C ₄ alkylthio group or a phenyl group, with the ^proviso, R ^1, R 2, ^{R 3}
And R ⁴ is a condition that can sterically co) includes. In addition, R ¹ , R ² , R ³
And any two of R ⁴ is taken together can represent a difunctional aliphatic moiety containing 1 to 12 carbon atoms and up to two oxygen atoms or sulfur atoms. Salts include metal hydroxides such as sodium hydroxide, ammonia, trimethylamine, diethanolamine, 2-methylthiopropylamine, bisallylamine, 2-butoxyethylamine, morpholine,
It can be prepared by treatment with an amine such as cyclododecylamine or benzylamine, or tetraalkylammonium hydroxide such as tetramethylammonium hydroxide or choline hydroxide.

_{Exemplary esters include C 1-} , such as methyl alcohol, isopropyl alcohol, 1-butanol, 2-ethylhexanol, butoxyethanol, methoxypropanol, allyl alcohol, propargyl alcohol, cyclohexanol, or unsubstituted or substituted benzyl alcohol. Included are those derived from C ₁₂ alkyl alcohols, C _{3 to} C ₁₂ alkenyl alcohols, C _{3 to} C ₁₂ alkynyl alcohols or C _{7 to} C _{10 aryl substituted alkyl alcohols.} Benzyl alcohol, _halogen, C 1 -C ₄ alkyl, or _C 1 -C ₄ are independently selected from alkoxy, optionally substituted by one to three substituents. The ester couples the acid with the alcohol using any number of suitable activators, such as those used for peptide coupling, such as dicyclohexylcarbodiimide (DCC) or carbonyldiimidazole (CDI). By reacting the acid with an alkylating agent (such as alkyl halide or alkyl sulfonate) in the presence of a base (such as triethylamine or lithium carbonate); reacting the corresponding acidified of the acid with the appropriate alcohol. Thereby; in the presence of an acid catalyst, the corresponding acid can be reacted with a suitable alcohol or prepared by ester exchange.

Compositions and Methods In the present specification, effective amounts of herbicidal compounds of formula (a) and formula (I) are used.

または農業上許容されるその塩もしくはエステル、および（ｂ）合成オーキシン除草剤
を含む除草組成物が提供される。

Alternatively, a herbicidal composition comprising an agriculturally acceptable salt or ester thereof and (b) a synthetic auxin herbicide is provided.

As used herein, a method of controlling unwanted vegetation, wherein the vegetation or its habitat (ie, adjacent areas of the vegetation) is a herbicidally effective amount of a compound of formula (I) or an agriculturally acceptable salt thereof or. Also provided are methods that include the steps of contacting esters and (b) synthetic auxin herbicides or applying them to soil or water to prevent vegetation development or growth. In certain embodiments, the method uses the compositions described herein. In certain embodiments, synthetic auxin herbicides are 2,4-D, 2,4-DB, aminocyclopyracrol, aminopyrlide, clomeprop-P, clopyralid, dicamba, dicloprop-P, fluloxypyrmeptyl. Heptyl ester (MHE), MCP
A, MCPB, picloram, quinchlorac, triclopyr, and halauxifen-
Methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) methyl picolinate), or an agriculturally acceptable salt or ester thereof.

Moreover, in some embodiments, the combination of compound (I) or an agriculturally acceptable salt or ester with a synthetic auxin herbicide or an agriculturally acceptable salt or ester has a synergistic effect (eg, herbicide). When combined with active ingredients, it is more effective than when applied individually). Synergy is defined as "the interaction of two or more factors such that the combined action is greater than the expected action based on the response of each individually applied factor." .. Senseman, S. (eds.), Herbicide Handbook., 9th Edition, Lawrence: Weed Science Society of America (2007). In certain embodiments, the composition exhibits a synergistic effect as determined by Colby's formula. Colby, SR 1967, Calculat
ion of the synergistic and antagonistic response of herbicide combinations. Weed
s Volume 15: pp. 20-22.

In certain embodiments of the compositions and methods described herein, compounds of formula (I), namely carboxylic acids, are used. In certain embodiments, the carboxylic acid salt of the compound of formula (I) is used. In certain embodiments, aralkyl esters or alkyl esters are used. In certain embodiments, benzyl ester, substituted benzyl ester,
_{Alternatively,} C 1-4 alkyl esters (eg, n-butyl esters) are used. In certain embodiments, benzyl esters are used.

In some embodiments, the compound of formula (I) or a salt or ester thereof and a synthetic auxin are formulated, tank mixed, and applied simultaneously in one composition.
Or it is applied sequentially.

When the above compounds are applied directly to a plant or its habitat at any stage of growth, the compounds exhibit herbicidal activity. The effects observed are the plant species to be controlled, the growth stage of the plant, the application parameters of dilution and spray droplet size, the particle size of the solid constituents, the environmental conditions at the time of use, the specific compounds used, the specifics used. Adjuvants and carriers,
It depends on the soil type, etc., as well as the amount of chemicals applied. These and other factors can be modified to promote non-selective or selective herbicidal effects. In some embodiments, the compositions described herein are post-occurrence, pre-occurrence, or flooded paddy rice or water bodies (eg, for example, to relatively immature and unwanted vegetation. It is applied as an underwater application to ponds, lakes, and rivers) to achieve maximum weed control.

In some embodiments, the compositions and methods provided herein are, but are not limited to, direct-seeded rice, flooded direct-seeded rice, transplanted rice, grains, wheat, barley, oats,
Lime tree, morokoshi, corn / corn, sugar cane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pasture, grassland, rangeland, fallow, lawn, trees and vineyards, aquatic plants, plantation crops, vegetables, industry Plantation management (IVM),
It is also used to control weeds in crops, including public road land (ROW).

In certain embodiments, the compositions and methods provided herein are utilized to control weeds in rice. In certain embodiments, the rice is a direct-seeded rice, a flooded direct-seeded rice, or a transplanted rice.

The compositions and methods described herein include, for example, glyphosate, EPSP synthase inhibitor, glufosinate, glutamine synthase inhibitor, dicamba, phenoxyauxin, pyridyloxyoxine, synthetic auxin, auxin transport inhibitor, aryloxyphenoxy. Propionate, cyclohexanedione, phenylpyrazolin, AC
Case inhibitor, imidazolinone, sulfonylurea, pyrimidinylthiobenzoate,
Triazolopyrimidine, sulfonylaminocarbonyltriazolinone, ALS or AH
AS inhibitor, HPPD inhibitor, phytoendesaturase inhibitor, carotenoid biosynthesis inhibitor, PPO inhibitor, cellulose biosynthesis inhibitor, thread division inhibitor, microtube inhibitor, super long chain fatty acid inhibitor, fatty acid and lipid Glyphosate resistance, 5-enolpyruvyl simimate-3-phosphate (EPSP) synthase inhibitor resistance, gluhosinate resistance in combination with biosynthesis inhibitors, photochemical system I inhibitors, photochemical system II inhibitors, triazine, and bromoxinyl. , Glutamine synthetase inhibitor resistance, dicamba resistance, phenoxyoxine resistance,
Pyridyloxyoxin resistance, auxin resistance, auxin transport inhibitor resistance, aryloxyphenoxypropionate resistance, cyclohexanedione resistance, phenylpyrazolin resistance, acetyl CoA carboxylase (ACCase) inhibitor resistance, imidazolinone resistance, sulfonylurea resistance, pyrimidinyl Thiobenzoate resistance, triazolopyrimidine resistance, sulfonylaminocarbonyltriazolinone resistance, acetolactate synthase (ALS)
) Or acetohydroxy acid synthase (AHAS) inhibitor resistance, 4-hydroxyphenyl-pyrvate dioxygenase (HPPD) inhibitor resistance, phytoene desaturase inhibitor resistance, carotenoid biosynthesis inhibitor resistance, protoporphyrinogen oxidase (P)
PO) Inhibitor resistance, cellulose biosynthesis inhibitor resistance, thread splitting inhibitor resistance, microtube inhibitor resistance, ultra-long chain fatty acid inhibitor resistance, fatty acid and lipid biosynthesis inhibitor resistance, photosystem I inhibitor resistance, Not desirable in photosystem II inhibitor resistant, triazine resistant, and bromoxinyl resistant crops such as, but not limited to, soybeans, cotton, canola / abrana, rice, grains, corn, morokoshi, sunflowers, tensai, sugar cane, lawn, etc. It can be used to control vegetation. The compositions and methods are used to control unwanted vegetation in crops with multiple or multiple traits that confer resistance to multiple chemicals and / or inhibitors of multiple mechanisms of action. can do. In some embodiments, the compound of formula (I), or a salt or ester thereof, and a supplemental herbicide thereof, or a salt or ester thereof, exhibits selectivity for the crop to be treated and is used. Used in combination with herbicides that complement the spectrum of weeds controlled by these compounds at doses. In some embodiments, the compositions described herein, and other supplemental herbicides, are applied either as a combination formulation, simultaneously as a tank mix, or sequentially.

The compositions and methods include agronomic stress tolerance (but not limited to drought, cold, etc.)
Heat, salt, water, nutrients, reproduction, pH included), pest resistance (including, but not limited to, insects, fungi, and pathogens), and crop improving traits (including, but not limited to, yield;
It can be used to control unwanted vegetation in crops with protein, carbohydrate, or oil content; protein, carbohydrate, or oil composition; plant height and plant architecture). The compositions and methods provided herein are utilized to control unwanted vegetation. Unwanted vegetation includes, but is not limited to, rice, grain, wheat, barley, oat, rye, sorghum, corn / corn, sugar cane, sunflower, abrana, canola, tensai, soybean, cotton, pineapple, pasture, grassland, Includes unwanted vegetation that occurs in pastures, fallow lands, lawns, sorghum and vineyards, aquatic plants, plantation crops, vegetables, industrial vegetation management (IVM), and public road land (ROW).

In some embodiments, the methods provided herein are utilized to control unwanted vegetation in rice. In certain embodiments, the unwanted vegetation is Brachiaria platyphylla (Groseb.) Nash or Uro.
chloa platyphylla) (Nash) RD Webster (Meriken Nikubi, BRAPP), Digitaria sanguinalis (L.) Scop. (Omehishiba, DIGSA), Barnyardgrasses (Echi)
nochloa species) (ECHSS), Inubier (Echinochloa crus-galli (L.) P. Beauv.
) (Inubier, ECHCG), Echinochloa crus-pav
onis) (Kunth) Schult. (Gulf cockspur, ECHCV), Wasevier (Echinochloa colonum (L.) LINK) (Wasebie, ECHCO), Nogetainubie (E)
chinochloa oryzoides (Ard.) Fritsch) (Nogetainubier, ECHOR), Tainubier (Echinochloa oryzicola (Vasinger) Vasinger) (Tainubier, ECHPH), Echinochloa phyllopogon (Stapf) Koso-Pol
ECHPH), Echinochloa polystachya (Kunth) Hi
tchc. (creeping river grass, ECHPO), Taiwan Aiashi (Ischaemum rugosum Salisb.) (Saramollagrass), ISCR
U), Azegaya (Leptochloa chinensis (L.) Nees) (Azegaya, LEFCH), Leptochloa fascicularis (Lam.) Gray (bearded sprangletop, LEFFA), Leptochloa panicodes (Leptochloa panicoides) (Presl.) Hitchc. (Amazon Splungle Top (Amazon)
sprangletop), LEFPA), Oryza species (red rice and weed rice, OR
YSS), Panicum dichotomiflorum (L.) Michx. (Panicum dichotomiflorum (L.) Michx.)
ANDI), Dallis grass (Paspalum dilatatum Poir.) (Dallis grass, PA
SDI), Rottboellia cochinchinensis (Lour.) WD Clayton (Rottboellia cochinchinensis, ROOEX), Cyperus species (CYPSS), Cyperus difformis L. (Cyperus difformis L.) (Cyperus difformis L.) ) Rottb. (MAPDU), Cyperus escule
ntus L.) (Cyperus iria, CYPES), Cyperus iria L. (Cyperus iria, CYPIR), Cyperus rotundus L. (Nutsedge, CYPRO),
Cyperus serotinus Rottb./CB Clarke (CYPSE), Eleocharis species (E)
leocharis species) (ELOSS), Hiderico (Fimbristylis miliacea (L.) Vahl) (
Hiderico, FIMMI, Schoenoplectus species (SCPSS), Schoenoplectus juncoides Roxb. (Schoenoplectus juncoides Roxb.) (Hotarui, SCPJU), Koukiyagara (Bolboschoenus maritimus (L.) Palla) or Schoenoplectus S.
choenoplectus maritimus) L. Lye (Polar bear, SCPMA), Himekangarei (Sch
oenoplectus mucronatus L.) (Schoenoplectus mucronatus L.), Aeschyn genus (Aeschyn)
omene species) (Aeschynomene, AESSS), Alternanthera phi
loxeroides (Mart.) Griseb.) (Alligator weed, ALLPH), Sagittaria trifolia (Alis)
ma plantago-aquatica L.) (Mont water plantain, ALSPA), Amaranthaceae (A)
maranthus species) (Akaza and Amaranthus, AMASS), Hosobahimemisohagi (Ammannia coccinea Rottb.) (Hosobahimemisohagi, AMMCO), Marubatsuyukusa (AMMCO)
Commelina benghalensis L.) (Commelina benghalensis L.), American false daisy (Eclipta alba (L.) Hassk.) (American false daisy, ECLAL), American konagi (Heteranthera limosa (Sw.) Willd.) / Vahl (American konagi, HETLI) ), Heteranthera reniformis R. & P. (Roundleaf mudplantain HETREE), Ipomoea species
(Morning glory, IPOSS), American morning glory (Ipomoea hederacea (L.) Jacq.) (American morning glory, IPOHE), American morning glory (Lindernia dubia (L.) Pennell) (Azena, LIDDU), Ludwigia species (LUDSS) ), Ludwigia linifolia Poir. (Southeastern primrose-willow, LUDLI), Ludwigia o
ctovalvis (Jacq.) Raven) (Mexican Primrose-will, LUDOC), Monochoria
korsakowii Regel & Maack (monochoria, MOOKA), Konagi (Mono)
choria vaginalis) (Burm.F.) C. Presl ex Kuhth (MOOVA), Murdannia nudiflora (L.) Brenan (dovewee)
d), MUDNU), Polygonum pensylvanicum L. (Pennsylvania smartweed, POLLY), Redshank (
Polygonum persicaria L. (Redshank, POLPE), Polygonum hydropiperoides Michx. (POLHP, Mild Smart Weed (mil))
d smartweed)), Rotala indica (Willd.) Koehne) (Rotala indica, ROT
IN), Sagittaria species (Sagittaria trifolia, SAGSS), Sesbania
Exaltata (Sesbania exaltata) (Raf.) Cory / Rydb. Ex Hill (Hemp Sesbania (h)
emp sesbania), SEBEX), or Sphenoclea zeylanica Gaertn.
) (Gooseweed, SPDZE).

In some embodiments, the methods provided herein are utilized to control unwanted vegetation in grains. In certain embodiments, the unwanted vegetation is Alopecurus myosuroides Huds. (Blackgrass, A.
LOMY), Silkybent (Apera spica-venti) (L.) Beauv. (Windglass (win)
dgrass), APESV), oats (Avena fatua L.) (oats, AVEFA),
Bromes tectorum L. (Bromus tectorum L.), Bromes (BROTE), Festuca perensis (Bromus tectorum L.)
Lolium multiflorum) Lam. (Italian ryegrass, LOLMU), Paralis Minoru (Lolium multiflorum)
Phalaris minor) Retz. (Littleseed canarygrass), P
HAMI), Poa annua L. (Poa annua L.), Setaria pumila (Poir.) Roemer & JA Schultes (Setaria viridis, SETLU), Setaria viridis (L.) Beauv. Setaria viridis, S
ETVI), Amaranthus retroflexus L. (Amaranthus retroflexus L.) (Amaranthus retroflexus, AMARE)
), Brassica species (BRSSS), white goosefoot (Chenopodium album L.
) (White goosefoot, CHEAL), Thistle (Cirsium arvense (L.) Scop.) (Canada thistle, CIRAR), Cleavers (Galium aparine L.) (Galium, GAL)
AP), Kochia scoparia (L.) Schrad.) (Houkigi, KCHSC), Red deadnettle (Lamium purpureum L.) (Red deadnettle, LAMPU), Chamomile (M)
atricaria recutita L.) (Wild chamomile, MATCH), Mayweed (Matricari)
a matricarioides) (Less.) Porter (Koshikagiku, MATMT), Poppy (Papaver r)
hoeas L.) (Prickly Russian Thistle, PAPRH), Black Bindweed (Polygonum convolvulus L.) (Black Bindweed, POLCO), Salsola tragus L. (Russian thistle, SA)
SKR), Sinapis species (SINSS), Sinapis a
rvensis L.) (Noharagarashi, SINAR), Chickweed (Stellaria media (L.) Village.
) (Chickweed, STEME), Persian speedwell (Veronica persica Poir.) (Persian speedwell, VERPE), Makibasumire (Viola arvensis Murr.) (Makibasumire, VI)
OAR) or Sanshikisumire (Viola tricolor L.) (Sanshikisumire, VIOTR)
).

In some embodiments, the methods provided herein are utilized to control unwanted vegetation in ranches and pastures, fallows, IVM, and ROW. In certain embodiments, the unwanted vegetation is ragweed (Ambrosia artemisiifolia L.) (
Ragweed, AMBEL), Sicklepod (Cassia obtusifolia) (Sicklepod, CASOB)
), Centaurea maculosa auctor. Non Lam. (Spotted knapweed, CENMA), Thistle (Cirsium arve)
nse (L.) Scop.) (Canada thistle, CIRAR), Bindweed (Convolvulus arve)
nsis) L. (Convolvulaceae, CONAR), Wild carrot (Daucus carota) L. (Wild carrot, DAUCA), Euphorbia esula L. (Bindweed, E)
PHES), Prickly Lettuce (Lactuca serriola L.) / Torn. (Prickly Lettuce, LACSE),
Ribwort Plantain (Plantago lanceolata L.) (Bitter Dock, PLALA), Bitter Dock (Rumex obtusifolius L.) (Bitter Dock, RUMOB), American King Dock (S)
ida spinosa L.) (American mustard, SIDSP), Sinapis arvens
is L.) (Noharagarashi, SINAR), Taiwan Hachijouna (Sonchus arvensis) L.
(Taiwan Hachijouna, SONAR), Solidago species (Solidago species)
Aono Kirinso, SOOSS), Dandelion (Taraxacum officinale GH Webe)
r ex Wiggers) (Dandelion, TAROF), White Clover (Trifolium repens L)
.) (White clover, TRFRE), or white clover (Urtica dioica L.).
) (Nettle, URTDI).

In some embodiments, the methods provided herein are utilized to control unwanted vegetation found in row-sown crops, tree and vine crops, and perennial crops. In certain embodiments, the unwanted vegetation is Alopecurus aequalis (Alopecur).
us myosuroides Huds.) (Blackgrass, ALOMY), Oats (Avena fatua L.)
) (Oat, AVEFA), Brachiaria decumbens Stap
f. or Urochloa decumbens (Stapf) RD Webster (Surinam grass, BRADC), Brachiaria brizan
tha) (Hochst. Ex A. Rich.) Stapf. Or Urochloa brizant
ha) (Hochst. Ex A. Rich.) RD (beard grass, BRABR), Brachiaria platyphylla (Groseb.) Nash or Meriken Nikubi (U)
rochloa platyphylla (Nash) RD Webster (BRAPP), Brachiaria plantaginea (Link) Hitchc. Or Urochloa plantaginea (Link) RD Webster (Alexandergrass) BRAPL), Cenchrus echinatus L.
(Cenchrus echina, CENEC), Digitaria horizontalis Willd. (DIGHO), Miscanthus sinensis (Digitaria insularis (L.) Mez ex Ekman
) (Sourgrass, TRCIN), Digitaria sanguinalis (L.
) Scop. (Omehishiba DIGSA), Inubier (Echinochloa crus-galli (L.) P. Beau
v.) (Inubier, ECHCG), Wasevier (Echinochloa colonum (L.) LINK) (Wasebie, ECHCO), Goosegrass (Eleusine indica (L.) Gaertn.) (Ohishiba, ELEIN)
), Festuca perennial (Lolium multiflorum Lam.) (Italian ryegrass, LOLMU),
Panicum dichotomiflorum Michx. (Panicum dichot, PANDI), Millet (Panicum miliaceum L.) (Wild millet, PANMI), Setaria faberi (Setaria fa)
beri Herrm.) (Setaria viridis, SETFA), Setaria viridis (Setaria viridis)
L.) Beauv.) (Setaria viridis, SETVI), Johnsongrass (Sorghum halepense (L.)
.) Pers.) (Sorghum bicolor), Sorghum bicolor
) (L.) Moench ssp. Arundinaceum (sorghum, SORVU), Yellow Nutsedge (Cyperus esculentus L.) (Kihamasuge, CYPES), Hamasuge (C)
yperus rotundus L.) (Nutsedge, CYPRO), Velvetleaf (Abutilon theophrasti Medik)
.) (Velvetleaf, ABUTH), Amaranthus species (Amaranthus species, AMASS), Ragweed (Ambrosia artemisiifolia L.) (Ragweed, AMBEL)
), Ragweed (Ambrosia psilostachya DC.) (Ragweed, AMBPS),
Giant ragweed (Ambrosia trifida L.) (Giant ragweed, AMBTR), Giant ragweed (Anoda cristata) (L.) Schlecht.
sclepias syriaca L.) (milkweed, ASCY), black-jack (Bidens pilosa L.)
) (Cosendangsa, BIDPI), Borrelia species (BOISS)
, Hedyotis diffusa (Borreria alata (Aubl.) DC.) Or Hiroha Hedyotis diffusa (Spermacoce)
alata Aubl.) (Broadleaf buttonweed, BOILF
), Hiroha Futabamugra (Spermacose latifolia) (Broadleaf Button Weed, B
OILF), white goosefoot (Chenopodium album L.) (white goosefoot, CHEAL), thistle (Cirsium arvense (L.) Scop.) (Canada thistle, CIRAR), Commelina benghalensis (Cirsium arvense (L.) Scop.)
Commelina benghalensis L. (Commelina benghalensis L.) (Commelina benghala, COMBE), Datura stramonium L. (Datura stramonium L.) (Datura stramonium L.), Noraninjin (Daucus carota L.) Euphor
bia heterophylla L.) (Euphorbia, EPHHL), Asthma-plant (Euphorbia)
hirta L.) or Asthma-plant (Chamaesyce hirta (L.) Millsp.) (Asthma-plant, EPHHI), Euphorbia dentata Michx. Alechinogiku (Con
yza bonariensis) (L.) Cronq.) (Erigeron bonarien, ERIBO), Horseweed (E)
rigeron canadensis L.) or horseweed (Conyza canadensis (L.) Cronq.) (
Horseweed, ERICA), Erigeron sumatrensis (Retz.)
) EH Walker (Erigeron sumatren, ERIFL), sunflower (Helianthus annuus L.)
(Sunflower, HELAN), Okinawa morning glory (Jacquemontia tamnifolia (L.) Griseb.)
(Okina morning glory, IAQTA), American morning glory (Ipomoea hederacea (L.) Jacq.)
(American morning glory, IPOHE), Mameasagao (Ipomoea lacunosa L.) (Mameasagao, IPOLA), Prickly lettuce (Lactuca serriola L.) / Torn.
SE), Portulaca oleracea L. (Portulaca oleracea L.) (Portulaca oleracea L.), Neanotis hirsuta (Richardia species) (pusley, RHHSS), Feridae (S)
ida species) (Sida, SIDSS), American mustard ((Sida spinosa L.) (American mustard, SIDSP), Sinapis arvensis L. (Sinapis arvensis, SINAR), American mustard (Solanum ptychanthum Dunal) , SOLPT), Kotobukigiku (Tridax procumbens L.) (Kotobukigiku, TR
QPR) or cocklebur (Xanthium strumarium L.) (cocklebur, XANST).

In some embodiments, the methods provided herein are utilized to control unwanted vegetation on the lawn. In certain embodiments, the unwanted vegetation is daisies (Bellis perennis L.) (daisies, BELPE), yellow nutsedges (Cyperus).
esculentus L.) (Yellow Nutsedge, CYPES), Nutsedge species (Cyperus species) (
CYPSS), Digitaria ciliaris (Digitaria sanguinalis (L.) Scop.) (Omehishiba, DIG
SA), Diodia virginiana L. (Merikenmugra, DIQVI), Euphorbia species (Euphorbia species) (Euphorbia species, EPHSS), Glechoma grandis (Gle)
choma hederacea L.) (Glechoma grandis, GLEHE), Hydrocochile umberata (Hydr)
ocotyle umbellata) L. (dollarweed, HYDUM), Kyllinga species (Kyllinga, KYLSS), henbit (Lamium amplexicaule L.)
) (Henbit, LAMAM), Murdannia nudiflora
(L.) Brenan (MUDNU), Oxalis species (Oxalis species) (Oxalis, OXASS), Plantago major L. (Plantago major L.) (Plantago, P.
LAMA), Ribwort Plantain (Plantago lanceolata L.) (Ribwort Plantain (buckhorn plant)
ain) / Ribwort plantain (narrowleaf plantain), PLALA), Phyllanthus (Phyllanth)
us urinaria L.) (Phylanthus communis, PYLTE), Bitter Dock (Rumex obtusifolius)
L.) (Bitter Dock, RUMOB), Stachys floridana Sh
uttlew. (Florida betony, STAFL), chickweed (Stellaria m)
edia) (L.) Village.) (Chickweed, STEME), Dandelion (Taraxacum officin)
ale GH Weber ex Wiggers) (Dandelion, TAROF), White Clover (Trifo)
lium repens L.) (white clover, TRFRE), or Violet species (Viola spec)
ies) (Wild Violet VIOSS).

In some embodiments, the compositions and methods provided herein are grass weeds,
It is used to control unwanted vegetation consisting of broad-leaved weeds and sedge weeds. In certain embodiments, the compositions and methods provided herein are not limited to: Amaranthus, Brachiaria, Brassica, etc.
Cassia, Knapweed, Cirsium, Cyperus, Digitaria, Echinochloa, Ele
usine), Platypus (Ischaemum), Kochia, Leptochloa
), Panicgrass, Polygonum, Salsola, Sida, Sinapis, Solidago, Sonch
us), sorghum (Sorghum), scirpus (Schoenoplectus), chickweed (Stellaria)
, Trifolium, and Violet, are used to control unwanted vegetation.

In some embodiments, compound (I) or an agriculturally acceptable ester or salt thereof and 2,4-D, aminocyclopyracrol, aminopyralid, clomeprop-P, clopyralid, dicamba, dicloprop-P, full. Roxypyrmeptyl heptyl ester (
MHE), MCPA, MCPB, picloram, quinchlorac, triclopyr, and halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-).
Combinations with 3-methoxyphenyl) methyl picolinate) or their agriculturally acceptable salts or esters are Amaranthus retroflexus (L.) (Amaranthus retroflexus (L.)) (AMARE), Brachiaria platyphylla (Griseb). .) Nash or Melikennikkibi (Urochloa platyphylla) (Nash) RDWebster (Merikennikkibi,
BRAPP), Brassica napus (L.) (Volunteer rapeseed, BR
SNN), Sicklepod (Cassia obtusifolia L.) (Sicklepod, CASOB), Thistle (Cirsium arvense (L.) Scop.) (Canada thistle, CIRAR), Centaurea maculosa LAM. (Spotted napweed (knap)
weed, spotted), CENMA), Thistle (Cirsium arvense (L.) SCOP.)
(Canada thistle, CIRAR), Cyperus difformis L. (Cyperus difformis L.) (Cyperus difformis, CYPDI), Yellow nutsedge (Cyperus esculentus (L).)
PES), Cyperus iria L. (Cyperus iria L.) (Cyperus iria, CYPIR), Cyperus rotundus L. (Nutsedge, CYPRO), Digitaria sanguin
alis (L.) Scop.) (Omehishiba, DIGSA), Inubier (Echinochloa crus-galli (L.)
) Beauv.) (Inubier, ECHCG), Kohimebie (Echinochloa colona (L.) Link) (Kohimebie, ECHCO), Nogetainubie (Echinochloa oryzoides (Ard.) Fritsch) (Nogetainubie, ECHOR), Goosegrass (Eleusine ind) Gaertn.) (Goosegrass, E
LEIN), Taiwan Aiashi (Ischaemum rugosum Salisb.) (Saram)
ollagrass), ISCRU), Azegaya (Leptochloa chinensis (L.) Nees) (Azegaya,
LEFCH), Panicum dichotomiflorum Michx. (Panicum dichotomiflorum Michx.) (Panicum dichotomiflorum Michx.)
NDI), millet (Panicum miliaceum L.) (wild millet, PANMI), black Bindweed (Poly)
gonum convolvulus (L.)) (Black Bindweed, POLCO), Schoenoplectus
juncoides (Roxb.) Palla) (Scirpus juncoides, SCPJU), Purua grass (Bolboschoenus ma)
ritimus (L.) Palla) or Schoenoplectus maritimu
s) (L.) Lye (Koukiyagara, SCPMA), Johnsongrass (Sorghum halepen)
se (L.) Pers.) (Johnson grass, American mustard (Sida spinosa L.) (American mustard, SIDSP), Sinapis arvensis L.) (Sinapis arvensis L.) (Noharagarashi,
SINAR), Solidago L. spec. (Solidago L. spec.) (Solidago, SOO
SS), Taiwan Hachijouna (Sonchus arvensis L.) (Taiwan Hachijouna, SO
NAR), Johnsongrass (Sorghum halepense (L.) Pers.) (Johngrass, SO
Controls RHA, Chickweed (Stellaria media (L.) Vill.) (Chickweed, STEME), White Clover (Trifolium repens L.) (White Clover, TRFRE), and Sanshikisumire (Viola tricolor (L.)) (Sanshikisumire, VIOTR) Used to do.

A compound of formula I, or an agriculturally acceptable salt or ester thereof, can be used to control herbicide-resistant or resistant weeds. Methods using a compound of formula I or a combination of an agriculturally acceptable salt or ester thereof, and the compositions described herein can also be used to control herbicide-resistant or resistant weeds. can. Exemplary resistant or resistant weeds include, but are not limited to, acetolactate synthase (ALS) or acetolactate synthase (AHAS) inhibitors (eg, imidazolinone, sulfonylurea, pyrimidinylthiobenzoate, triazolo). Pyrimidines, sulfonylaminocarbonyltriazolinones), photochemical II inhibitors (eg, phenylcarbamate, pyridadinone, triazines, triazines, uracils, amides,
Urea-based, benzothia dinone-based, nitrile-based, phenylpyridazine-based), acetyl C
oA carboxylase (ACCase) inhibitors (eg, aryloxyphenoxypropionate, cyclohexanedione, phenylpyrazolin), synthetic auxins (eg, benzoic acid, phenoxycarboxylic acid, pyridinecarboxylic acid, quinolinecarboxylic) Acid-based), auxin transport inhibitors (eg, phthalamate-based, semicarbazone-based), photochemical-based I inhibitors (eg, bipyridylium-based), 5-enolpyruvyl simimate-3-phosphate (EPSP) synthase inhibitors (eg, Glyphosate), glutamine synthetase inhibitors (eg, gluhosinate, bialaphos), microtube assembly inhibitors (eg, benzamides, benzoic acids, dinitroanilins, phosphoramidates, pyridines), filamentous division inhibitors (eg) , Carbamate), Ultra-long chain fatty acid (VLCFA) inhibitors (eg, acetamido, chloroacetamide, oxyacetamide, tetrazolinone)
, Fatty acid and lipid biosynthesis inhibitors (eg, phosphorodithioate, thiocarbamate, benzofuran, chlorocarbonate), protoporphyrinogen oxidase (PPO)
) Inhibitors (eg, diphenyl ether, N-phenylphthalimide, oxadiazole, oxazolidinedione, phenylpyrazole, pyrimidinedione, thiadiazole, triazolinone), carotenoid biosynthesis inhibitors (eg, chromazone, amitrol) , Acronifen), phytoendesaturase (PDS) inhibitors (eg,
Amide-based, anilidex, furanone-based, phenoxybutane-amide-based, pyridiadinone-based, pyridine-based), 4-hydroxyphenyl-pyrvate-dioxygenase (HPPD)
Inhibitors (eg, calistemon, isoxazole, pyrazole, triketone)
, Cellulose biosynthesis inhibitors (eg, nitriles, benzamides, quinchloracs, triazolocarboxamides), herbicides with multiple mechanisms of action such as quinchloracs, arylaminopropionic acids, diphenzocoats, endotals, and Includes biotypes that are resistant or resistant to unclassified herbicides such as organoarsenic compounds. Exemplary resistant or resistant weeds include, but are not limited to, multiple herbicides, biotypes that are resistant or resistant to multiple chemical classes, multiple herbicidal mechanisms of action, and multiple resistances. Alternatively, biotypes having a resistance mechanism (eg, target site resistance or metabolic resistance) are included.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with 2,4-D or a carboxylic acid salt or ester thereof. NS. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to 2,4-D or a carboxylic acid salt or ester thereof is about 1: 1120 to about 4. It is in the range of 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to 2,4-D or a carboxylate or ester thereof is in the range of 1: 128 to about 1: 1. be. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to 2,4-D or a carboxylate or ester thereof is in the range of about 1: 200 to about 1: 1. It is in. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to 2,4-D or a carboxylate or ester thereof is in the range of about 1:96 to about 1: 2. It is in. In certain embodiments, the compositions provided herein are a compound of formula (I) or a benzyl ester thereof, and 2,4-D DMA, 2,4-D choline, or 2.
, 4-D EHE is included. In one embodiment, the composition is a compound of formula (I) and 2,4.
It contains −D DMA, and the weight ratio of the compound of formula (I) to 2,4-D DMA is about 1.
: 56 to about 1: 4. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and 2,4-D DMA, and the weight of the benzyl ester of the compound of formula (I) and 2,4-D DMA. The ratio is from about 1:56 to about 1: 2. In one embodiment, the composition comprises a compound of formula (I) and 2,4-D choline, the compound of formula (I) and 2
The weight ratio with 4-D choline is about 1:84 to about 1: 6.9. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and 2,4-D choline, and the weight of the benzyl ester of the compound of formula (I) and 2,4-D choline. The ratio is about 1: 96 to about 1
: 6. In one embodiment, the composition comprises a compound of formula (I) and 2,4-D EHE.
The weight ratio of the compound of formula (I) to 2,4-D EHE is about 1:56 to about 1.
: 4. In one embodiment, the composition comprises a benzyl ester of a compound of formula (I) and 2,4-D EHE, and a benzyl ester of a compound of formula (I) and 2,4-D.
The weight ratio with EHE is about 1:56 to about 1: 4. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition has an acid equivalent of about 37 grams (gae / ha) to about 2540 g per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of ae / ha. In certain embodiments, the composition comprises from about 39 grams (gae / ha) to about 5 acid equivalents per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of 15 gae / ha. In some embodiments, the method comprises the compound of formula (I) or a salt or ester thereof and 2,
The steps include contacting 4-D or a carboxylic acid salt or ester thereof, eg, sequentially or simultaneously, or applying them to soil or water to prevent vegetation development or growth. In some embodiments, 2,4-D or a carboxylic acid salt or ester thereof is applied at an application rate of about 35 gae / ha to about 480 gae / ha and is a salt or ester of the compound of formula (I). Is applied at an application rate of about 2 gae / ha to about 300 gae / ha. In some embodiments, 2,4-D or its carboxylic acid salt or ester is 2,4-DB, 2,4-D choline, 2,4-D DMA, or 2,4-DE.
HE. In some embodiments, 2,4-D or a carboxylic acid salt or ester thereof is applied at an application rate of about 17 gai / ha to about 1000 gai / ha and is a salt or ester of the compound of formula (I). Is about 0.5 g of acid equivalent per hectare (gae /
ha) ~ It is applied at an application rate of about 70 gae / ha. In some embodiments, 2,4-D or its carboxylic acid salt or ester is from about 35 gai / ha to about 480 gai / ha.
The compound of formula (I), which is a salt or ester thereof, is applied at an application rate of about 1.1 g (gae / ha) to about 35 gae / ha of acid equivalent per hectare. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester thereof, and 2,4-D DMA, 2,4-D choline, or 2,4-D EHE. In one embodiment, the method utilizes a compound of formula (I) and 2,4-D DMA and formula (I).
) Compounds have an acid equivalent of about 3.75 g (gae / ha) to about 35 gae per hectare.
It is applied at a dose of / ha and 2,4-D DMA is about 70 gai / ha to about 280.
It is applied at a gai / ha application rate. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and 2,4-D DMA, and the benzyl ester of the compound of formula (I) has an acid equivalent of about 3.75 g per hectare (1 hectare). It is applied at a dose of gae / ha) to about 35 gae / ha, and 2,4-D DMA is from about 35 gai / ha to about 280 gai /.
It is applied at a dose of ha. In one embodiment, the method comprises compounds of formula (I) and 2,4.
Utilizing -D choline, the compound of formula (I) has an acid equivalent of about 4.38 g (g) per hectare.
It is applied at a dose of ae / ha) to about 35 gae / ha, and 2,4-D choline is about 1
It is applied at a dose of 05 gai / ha to about 480 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and 2,4-D choline, formula (I).
The benzyl ester of the compound of is about 1.1 g (gae / ha) of acid equivalent per hectare.
It is applied at a dose of ~ about 35 gae / ha, and 2,4-D choline is about 50 gai / h.
It is applied at a dose of a to about 480 gai / ha. In one embodiment, the method comprises formula (I).
And 2,4-D EHE, the compound of formula (I) is applied at an acid equivalent of about 4.38 g (gae / ha) to about 35 gae / ha per hectare, and 2
, 4-D EHE is applied at a dose of about 70 gai / ha to about 280 gai / ha. In one embodiment, the method comprises a benzyl ester of a compound of formula (I) and 2,4-D.
Utilizing EHE, the benzyl ester of the compound of formula (I) is applied at an acid equivalent of about 4.38 g (gae / ha) to about 17.5 gae / ha per hectare, and 2,4
-D EHE is applied at a dose of about 70 gai / ha to about 280 gai / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with 2,4-D or a carboxylic acid salt or ester thereof may be used.
ECHCG, LEFCH, ECHOR, CYPRO, SCPJU, CENMA, SINA
R, SONAR, POLCO, PANDI, ELEIN, PANMI, DIGSA, EC
Used to control HCO, CYPES, CYPIR, SCPMA, CASOB, or BRAPP.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with aminocyclopyracrol or a carboxylic acid salt or ester thereof. .. With respect to the composition, in some embodiments,
The weight ratio of the compound of formula (I) or a salt or ester thereof, aminocyclopyrachlor or a carboxylate or ester thereof is in the range of about 1: 140 to about 34: 1.
In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to aminocyclopyracrol or a carboxylate or ester thereof is 1: 91 to about 1.
It is in the range of 2: 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to aminocyclopyracrol or a carboxylate or ester thereof is in the range of 1: 4 to about 2: 1. In certain embodiments, the composition comprises a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and aminocyclopyrachlor. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is applied at an acid equivalent of about 10 grams (gae / ha) to about 580 gae / ha per hectare relative to the total amount of active ingredient in the composition. ..
In certain embodiments, the composition is applied at an acid equivalent of about 11 grams (gae / ha) to about 300 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method applies to undesired vegetation or its habitat, formula (I
) Compounds or salts or esters thereof and aminocyclopyracrol or carboxylic acid salts or esters thereof, eg, sequentially or simultaneously, or they are applied to soil or water to prevent vegetation development or growth. Including steps. In some embodiments, the aminocyclopyrachlor or carboxylic acid salt or ester thereof is
The compound of formula (I), which is applied at a dose of about 8.8 gae / ha to about 280 gae / ha and is a salt or ester thereof, is applied at a dose of about 2 gae / ha to about 300 gae / ha. In one embodiment, aminocyclopyracrol or a carboxylic acid salt or ester thereof is applied at a dose of about 8.75 gae / ha to about 17.5 gae / ha.
And the compound of the formula (I) which is a salt or ester thereof is about 4.4 gae / ha to about 17.
It is applied at a dose of 5 gae / ha. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and aminocyclopyrachlor. In certain embodiments, the methods and compositions that utilize the compound of formula (I) or a salt or ester thereof are combined with aminocyclopyracrol or a carboxylic acid salt or ester thereof to combine TRFRE, SINAR, or CENMA. Used for control.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with aminopyralid or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to aminopyralid or carboxylic acid salt or ester thereof is in the range of about 1:60 to about 100: 1. It is in. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to aminopyralid or carboxylic acid salt or ester thereof is in the range of about 1: 8 to about 6: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to aminopyralid or carboxylic acid salt or ester thereof is in the range of about 1:16 to about 6: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to aminopyralid or carboxylic acid salt or ester thereof is in the range of about 1: 8 to about 3: 1. In certain embodiments, the compositions provided herein are of formula (I).
Compound or benzyl ester thereof, and aminopyralid or aminopyralide T
Includes IPA. In one embodiment, the composition comprises the benzyl ester and aminopyralid of the compound of formula (I), and the weight ratio of the benzyl ester of the compound of formula (I) to the aminopyralide is about 3: 1. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and an aminopyralid TIPA, and the weight ratio of the benzyl ester of the compound of formula (I) to the aminopyralide TIPA is from about 1: 8 to. It is about 1: 1. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition has an acid equivalent of about 5 grams per hectare (gae) relative to the total amount of active ingredient in the composition.
/ Ha) to about 420 gae / ha. In certain embodiments, the composition comprises approximately 7 grams (g) of acid equivalents per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of ae / ha) to about 53 gae / ha. In some embodiments, the method contacts the undesired vegetation or habitat thereof with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof, and aminopyralid or a carboxylate or ester thereof. Or it involves applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, the aminopyralide or carboxylic acid salt or ester thereof is applied at a dose of about 3 gae / ha to about 120 gae / ha, and the compound of formula (I) which is a salt or ester thereof is about 2 gae. / Ha ~ about 3
It is applied at a dose of 00 gae / ha. In some embodiments, the aminopyralid or carboxylic acid salt or ester thereof is applied at an application rate of about 1 gai / ha to about 70 gai / ha, and the compound of formula (I) which is the salt or ester thereof is 1 hectare. It is applied at an application rate of about 2 g (gae / ha) to about 45 gae / ha per acid equivalent. In some embodiments, the aminopyralid or carboxylic acid salt or ester thereof is about 3 gai / ha.
The compound of formula (I), which is applied at an application rate of ~ about 35 gai / ha and is a salt or ester thereof, has an acid equivalent of about 4.4 g (gae / ha) to about 17.5 gae / hectare.
It is applied at a dose of ha. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester thereof, and aminopyralid or aminopyralide TIPA. In one embodiment, the method utilizes the benzyl ester and aminopyralide of the compound of formula (I), the benzyl ester of the compound of formula (I) having an acid equivalent of about 8.
It is applied at a dose of 75 g (gae / ha) and aminopyralid is about 3 gai / ha.
It is applied at the dose of. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and the aminopyralid TIPA, and the benzyl ester of the compound of formula (I) is 1.
Acid equivalents per hectare are applied at a dose of about 4.4 g (gae / ha) to about 17.5 gae / ha, and aminopyralid TIPA is applied at a dose of about 3 gai / ha to about 35 gai / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with aminopyralid or a carboxylic acid salt or ester thereof are POLCO, CIRAR, BRSNN, TRFRE, SIN.
Used to control AR, SOOSS, or CENMA.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with Chromeprop-P or a salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or its salt or ester to clomeprop-P or its salt or ester is in the range of about 1: 200 to about 6: 1. It is in. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to clomeprop-P or salt or ester thereof is in the range of 1: 159 to about 1: 1. In certain embodiments, the composition comprises a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and clomeprop-P. With respect to the method, in certain embodiments, the method contacts unwanted vegetation or its habitat with the compositions described herein.
Or it includes the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, the composition is applied at an acid equivalent of about 52 grams (gae / ha) to about 700 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In certain embodiments, the composition is relative to the total amount of active ingredient in the composition.
The acid equivalent per hectare is applied at a dose of about 53 grams (gae / ha) to about 400 gae / ha. In some embodiments, the method contacts the undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof and Chromeprop-P or a salt thereof. These include the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, clomeprop-P or a salt or ester thereof is from about 50 gae / ha to about 400 gae / h.
The compound of formula (I), which is applied at the dose of a and is a salt or ester thereof, is about 2 ga.
It is applied at a dose of e / ha to about 300 gae / ha. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and clomeprop-P.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with clopyralid or a salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to clopyralid or a carboxylate or ester thereof ranges from about 1: 280 to about 9: 1. Is inside. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to clopyralid or carboxylic acid salt or ester thereof is in the range of 1:23 to about 1: 4. In certain embodiments, the formula (
The weight ratio of the compound of I) or a salt or ester thereof to clopyralid or a carboxylate or ester thereof is in the range of about 1:32 to about 1: 2. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to clopyralid or carboxylic acid salt or ester thereof is in the range of about 1:16 to about 1: 4. In certain embodiments, the compositions provided herein comprise a compound of formula (I) or a benzyl ester thereof, and clopyralid or clopyralid MEA. In one embodiment, the composition comprises a benzyl ester and a clopyralid of a compound of formula (I), wherein the formula (
The weight ratio of the benzyl ester of the compound of I) to clopyralid is about 1: 5.7. In one embodiment, the composition comprises a benzyl ester of a compound of formula (I) and clopyralid M.
The weight ratio of the benzyl ester of the compound of formula (I) to the clopyralid MEA, which contains EA, is from about 1: 4 to about 1:16. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is relative to the total amount of active ingredient in the composition.
It is applied at an acid equivalent of about 37 grams (gae / ha) to about 860 gae / ha per hectare. In certain embodiments, the composition is applied at an acid equivalent of about 38 grams (gae / ha) to about 59 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method contacts the undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof, and clopyralid or a carboxylate or ester thereof. Or, these include the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, clopyralid or its carboxylic acid salt or ester is about 35 g.
The compound of formula (I), which is applied at a dose of ae / ha to about 560 gae / ha and is a salt or ester thereof, is applied at a dose of about 2 gae / ha to about 300 gae / ha. In some embodiments, the clopyralid or carboxylic acid salt or ester thereof is about 1
The compound of formula (I), which is applied at an application rate of 7 gai / ha to about 100 gai / ha and is a salt or ester thereof, has an acid equivalent of about 1 g (gae / ha) to about 18 per hectare.
It is applied at a dose of gae / ha. In some embodiments, the clopyralid or carboxylic acid salt or ester thereof is applied at an application rate of about 35 gai / ha to about 50 gai / ha, and the compound of formula (I) which is a salt or ester thereof is 1 hectare. It is applied at an application rate of about 2.2 g (gae / ha) to about 8.75 gae / ha per acid equivalent. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester thereof, and clopyralid or clopyralid MEA. In one embodiment, the method utilizes the benzyl ester and clopyralid of the compound of formula (I), the benzyl ester of the compound of formula (I) having an acid equivalent of about 8.75 g (gae / ha) per hectare. It is applied at the dosage,
And clopyralid is applied at a dose of about 50 gai / ha. In one embodiment, the method utilizes a benzyl ester of a compound of formula (I) and a clopyralid MEA, formula (I).
The benzyl ester of the compound of is about 2.2 g (gae / ha) of acid equivalent per hectare.
It is applied at a dose of ~ about 8.8 gae / ha, and clopyralid MEA is about 35 gai.
It is applied at a dose of / ha to 50 gai / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with clopyralid or a carboxylic acid salt or ester thereof are used to control AMARE, CIRR, or SOOSS. Used for.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with dicamba or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or its salt or ester to the dicamba or its carboxylic acid salt or ester ranges from about 1: 1100 to about 8: 1. Is inside. In certain embodiments, the formula (I)
The weight ratio of the compound of) or a salt or ester thereof to dicamba or a carboxylate or ester thereof is in the range of 1: 254 to about 1: 1. In certain embodiments,
The weight ratio of the compound of formula (I) or a salt or ester thereof to dicamba or a carboxylate or ester thereof is in the range of about 1: 120 to about 1: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to the dicamba or carboxylic acid salt or ester thereof is in the range of about 1:56 to about 1: 3.3. In certain embodiments, the compositions provided herein comprise a compound of formula (I) or a benzyl ester thereof, and dicamba or dicamba DMA. In one embodiment, the composition comprises a compound of formula (I) and a dicamba, and the weight ratio of the compound of formula (I) to dicamba is from about 1:56 to about 1: 3.3. .. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and a dicamba, and the weight ratio of the benzyl ester of the compound of formula (I) to the dicamba is about 1.56: 1 to 1. It is about 1: 4. In one embodiment, the composition comprises the benzyl ester of the compound of formula (I) and dicamba DMA, and the weight ratio of the benzyl ester of the compound of formula (I) to dicamba DMA is about 1:45. 5 to about 1: 11.4. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is applied at an acid equivalent of about 36 grams (gae / ha) to about 2500 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In certain embodiments, the composition is applied at an acid equivalent of about 37 grams (gae / ha) to about 325 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method contacts the undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof, and dicamba or a carboxylate or ester thereof. Or it involves applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, the dicamba or carboxylic acid salt or ester thereof is from about 35 gae / ha to about 22.
The compound of formula (I), which is applied at a dose of 00 gae / ha and is a salt or ester thereof, is applied at a dose of about 2 gae / ha to about 300 gae / ha. In some embodiments, the dicamba or carboxylic acid salt or ester thereof is from about 17 gai / ha to about 6
The compound of formula (I), which is applied at an application rate of 00 gai / ha and is a salt or ester thereof, is applied at an acid equivalent of about 0.5 g (gae / ha) to about 100 gae / ha per hectare. NS. In some embodiments, the dicamba or carboxylic acid salt or ester thereof is applied at an application rate of about 35 gai / ha to about 280 gai / ha, and the compound of formula (I) which is the salt or ester thereof is 1 hectare. Acid equivalent per unit about 1.1g (ga)
It is applied at a dose of e / ha) to about 42.4 gae / ha. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester thereof, and dicamba or dicamba DMA. In one embodiment, the method utilizes compounds of formula (I) and dicamba, the compounds of formula (I) having an acid equivalent of about 5.3 g (gae / ha) to about 4 per hectare.
It is applied at a dose of 2.4 gae / ha, and the dicamba is about 140 gai / ha to about 2
It is applied at a dose of 80 gai / ha. In one embodiment, the method utilizes a benzyl ester of a compound of formula (I) and a dicamba, and the benzyl ester of a compound of formula (I) is:
Acid equivalents per hectare are applied at a dose of about 2.2 g (gae / ha) to about 35 gae / ha, and dicamba is applied at a dose of about 35 gai / ha to about 280 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and dicamba DMA, the benzyl ester of the compound of formula (I) having an acid equivalent of about 1.1 g (gae / ha) per hectare. ~ About 4.4 gae / ha is applied, and dicamba DMA is applied at an application rate of about 50 gai / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with dicamba or a carboxylic salt or ester thereof are LEFCH, CYPIR, ECHC.
O, ECHCG, ECHOR, SCPMA, AMARE, POLCO, BRSNN, SI
Used to control DSP, SINAR, or CASOB.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with dicloprop-P or a carboxylic acid salt or ester thereof. .. With respect to the composition, in some embodiments, the formula (I)
The weight ratio of the compound of) or a salt or ester thereof to dicloprop-P or a carboxylate or ester thereof is in the range of about 1: 5,700 to about 2: 1. In certain embodiments, the compound of formula (I) or a salt or ester thereof and a dicloprop-
The weight ratio of P or its carboxylate or ester is in the range of 1: 1000 to about 1: 3. In certain embodiments, the composition comprises a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and dicloprop-P. With respect to the method, in certain embodiments, the method contacts unwanted vegetation or its habitat with the compositions described herein, or applies them to soil or water.
Includes steps to prevent vegetation development or growth. In some embodiments, the composition has an acid equivalent of about 142 grams per hectare (gae) relative to the total amount of active ingredient in the composition.
/ Ha) to about 11,700 gae / ha. In certain embodiments,
The composition has an acid equivalent of about 144 per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of gram (gae / ha) to about 2290 gae / ha. In some embodiments, the method contacts the undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof and Dicroprop-P or a salt thereof. Or it includes the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, dicloprop-P or a carboxylic acid salt or ester thereof is applied at a dose of about 140 gae / ha to about 11,400 gae / ha and is a salt or ester of formula (I). The compound is about 2 gay / ha ~
It is applied at a dose of about 300 gae / ha. In certain embodiments, the method comprises the formula (I).
) Or its benzyl ester or n-butyl ester, and dicloprop-P.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with fluloxipill or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to fluloxypyr or a carboxylic acid salt or ester thereof ranges from about 1:112 to about 4: 1. Is inside. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to fluloxipill or carboxylic acid salt or ester thereof is in the range of 1: 127 to about 2: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to fluloxipill or carboxylic acid salt or ester thereof is in the range of about 1:70 to about 1: 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to fluloxipill or a carboxylate or ester thereof is from about 1:35 to about 1.
: It is in the range of 2. In certain embodiments, the compositions provided herein comprise a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and a fluloxipill or fluloxipill MHE. In one embodiment, the composition comprises a compound of formula (I) and fluloxypyr MHE, the compound of formula (I) and fluloxipyl M.
The weight ratio with HE is about 1:28 to about 1: 7. In one embodiment, the composition is of formula (I).
) Is contained, and the weight ratio of the benzyl ester of the compound of the formula (I) to the fluoroxypyr MHE is about 1:35 to about 1: 2. In one embodiment, the composition comprises the n-butyl ester of the compound of formula (I) and the fluloxipyl MHE, and the weight ratio of the n-butyl ester of the compound of formula (I) to the fluloxipyl MHE is about. It is 1: 17.5 to about 1: 8.2. In one embodiment, the composition comprises a benzyl ester of a compound of formula (I) and a fluoroxypill, which comprises formula (I).
The weight ratio of the benzyl ester of the compound of) to furoxypyr is about 1: 4. With respect to the method, in certain embodiments, the method involves undesired vegetation or its habitat.
Includes steps to prevent the development or growth of vegetation by contacting the compositions described herein or by applying them to soil or water. In some embodiments, the composition has an acid equivalent of about 37 grams (g) per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of ae / ha) to about 860 gae / ha. In certain embodiments, the composition is applied at an acid equivalent of about 38 grams (gae / ha) to about 315 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method contacts the undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof, and fluloxipill or a carboxylate or ester thereof. Or it involves applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, the fluoroxypill or carboxylic acid salt or ester thereof is applied at a dose of about 35 gae / ha to about 560 gae / ha, and the compound of formula (I) which is a salt or ester thereof is about 2 gae. /
It is applied at a dose of ha to about 300 gae / ha. In some embodiments, the fluloxipill or carboxylic acid salt or ester thereof is from about 17 gae / ha to about 600 gae /.
The compound of formula (I), which is applied at an application rate of ha and is a salt or ester thereof, is applied at an acid equivalent of about 1 g (gae / ha) to about 70 gae / ha per hectare. In some embodiments, the fluoroxypill or carboxylic acid salt or ester thereof is applied at a dose of about 35 gae / ha to about 280 gae / ha, and the compound of formula (I) which is a salt or ester thereof is 1 hectare. Acid equivalent per unit is about 2.2 g (gae / ha) ~
It is applied at a dose of about 35 gae / ha. In some embodiments, the fluoroxypill or carboxylic acid salt or ester thereof is applied at a dose of about 35 gae / ha to about 280 gae / ha, and the compound of formula (I) which is the salt or ester thereof is 1 hectare. It is applied at an application rate of about 2.2 g (gae / ha) to about 64 gae / ha per acid equivalent. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and a fluloxipill or fluloxipill MHE. In one embodiment, the method utilizes a compound of formula (I) and fluoroxypyr MHE to formulate (
The compound of I) has an acid equivalent of about 4.38 g (gae / ha) to about 64 ga per hectare.
It is applied at an application rate of e / ha, and furloxipill MHE is about 70 gae / ha to about 2
It is applied at a dose of 80 gae / ha. In one embodiment, the method utilizes a benzyl ester of a compound of formula (I) and a fluoroxypyr MHE, the benzyl ester of a compound of formula (I) having an acid equivalent of about 2.2 g (gae / ha) per hectare. ~ Approximately 64 gae / h
It is applied at the dose of a, and furloxipill MHE is about 35 gae / ha to about 280 g.
It is applied at a dose of ae / ha. In one embodiment, the method comprises n- of the compound of formula (I).
Utilizing butyl esters and fluoroxypyr MHE, the n-butyl ester of the compound of formula (I) is applied at an acid equivalent of about 16 g (gae / ha) to about 35 gae / ha per hectare, and fluroxypyr MHE is , About 70 gae / ha to about 280 gae
It is applied at a dose of / ha. In one embodiment, the method utilizes a benzyl ester of a compound of formula (I) and a fluloxipill, which comprises approximately 8.75 g (gae / ha) of acid equivalent per hectare of the benzyl ester of a compound of formula (I). It is applied at a dose of about 64 gae / ha, and furloxipills are applied at a dose of about 35 gae / ha to about 280 gae / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with fluloxipill or a carboxylic acid salt or ester thereof are SOOSS, CIRAR, CENMA, SONAR, TRFRE, E
CHCG, ECHCO, CYPDI, LEFCH, ECHOR, SCPJU, SCPMA
, AMARE, VIOTR, or POLCO.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with MCPA or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to MCPA or a carboxylic acid salt or ester thereof is in the range of about 1: 850 to about 10: 1. Is inside. In certain embodiments, the formula (I)
The weight ratio of the compound of) or a salt or ester thereof to MCPA or a carboxylate or ester thereof is in the range of 1: 509 to about 2: 1. In certain embodiments,
The weight ratio of the compound of formula (I) or a salt or ester thereof to MCPA or a carboxylate or ester thereof is in the range of about 1:60 to about 1: 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to MCPA or a carboxylate or ester thereof is in the range of about 1:28 to about 1: 2. In certain embodiments, the compositions provided herein are compounds of formula (I) or benzyl esters or n-butyl esters thereof, and MCPA, MCPA K ⁺ , Na ⁺ , D.
Includes MA, or MCPA EHE. In one embodiment, the composition comprises a compound of formula (I) and MCPA K ⁺ , Na ⁺ , DMA, the compound of formula (I) and MCPA K.
^{The weight ratio of +} , Na ⁺ , and DMA is about 1:28 to about 1: 2. In one embodiment, the composition comprises a benzyl ester of a compound of formula (I), and MCPA K ⁺ , Na ⁺ , DMA.
Benzyl ester of the compound of formula (I) and MCPA K ⁺ , Na ⁺ , DMA
The weight ratio with and is about 1:28 to about 1: 4. In one embodiment, the composition comprises a compound of formula (I) and MCPA EHE, and the weight ratio of the compound of formula (I) to MCPA EHE is about 1: 6.6. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and MCPA EHE, and the weight ratio of the benzyl ester of the compound of formula (I) to MCPA EHE is about 1: 8. be. In one embodiment, the composition comprises n-butyl ester of compound of formula (I) and MCPA EHE, and the weight ratio of n-butyl ester of compound of formula (I) to MCPA EHE is about. 1: 17.5-about 1:
It is 8. In one embodiment, the composition comprises the benzyl ester of the compound of formula (I) and M.
The weight ratio of the benzyl ester of the compound of formula (I) to MCPA, which contains CPA, is about 1:16. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is applied at an acid equivalent of about 32 grams (gae / ha) to about 2000 gae / ha per hectare relative to the total amount of active ingredient in the composition. ..
In certain embodiments, the composition is applied at an acid equivalent of about 33 grams (gae / ha) to about 1170 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method formulates an undesired vegetation or habitat thereof.
Steps of preventing the development or growth of vegetation by contacting the compound of I) or a salt or ester thereof, and MCPA or a carboxylate or ester thereof, for example, sequentially or simultaneously, or applying them to soil or water. including. In some embodiments, the MCPA or carboxylic acid salt or ester thereof is from about 30 gae / ha to about 170.
The compound of formula (I), which is applied at a dose of 0 gae / ha and is a salt or ester thereof, is applied at a dose of about 2 gae / ha to about 300 gae / ha. In some embodiments, the MCPA or carboxylic acid salt or ester thereof is from about 35 gai / ha to about 60.
The compound of formula (I), which is applied at an application rate of 0 gai / ha and is a salt or ester thereof, is applied at an acid equivalent of about 2 g (gae / ha) to about 90 gae / ha per hectare. In some embodiments, the MCPA or carboxylic acid salt or ester thereof is applied at an application rate of about 70 gai / ha to about 280 gai / ha, and the compound of formula (I) which is a salt or ester thereof is 1 hectare. Acid equivalent per unit is about 4.38 g (gae / h)
a) ~ It is applied at an application rate of about 42.4 gae / ha. In certain embodiments, the method comprises a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and M.
Use CPA, MCPA K ⁺ , Na ⁺ , DMA, or MCPA EHE. In one embodiment, the method utilizes a compound of formula (I) and MCPA K ⁺ , Na ⁺ , DMA, the compound of formula (I) having an acid equivalent of about 4.38 g (gae / ha) per hectare. ) ~ About 35 gae / ha, and MCPA K ⁺ , Na ⁺ , DMA is about 70
It is applied at a dose of gai / ha to about 140 gai / ha. In one embodiment, the method utilizes a benzyl ester of the compound of formula (I) and MCPA K ⁺ , Na ⁺ , DMA, and the benzyl ester of the compound of formula (I) has an acid equivalent of about 4 per hectare. .38g (
It is applied at a dose of gae / ha) to about 17.5 gae / ha, and MCPA K ⁺ , N
a ⁺ , DMA is applied at a dose of about 70 gai / ha to about 140 gai / ha. In one embodiment, the method utilizes a compound of formula (I) and MCPA EHE, formula (I).
The compounds of are applied at an acid equivalent of about 42.4 g (gae / ha) per hectare, and MCPA EHE is applied at a dose of about 280 gae / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and MCPA EHE, the benzyl ester of the compound of formula (I) having an acid equivalent of about 35 g (gae / ha) per hectare.
), And MCPA EHE is applied at a dose of about 280 gae / ha. In one embodiment, the method comprises the n-butyl ester and MCP of the compound of formula (I).
Utilizing AEHE, the n-butyl ester of the compound of formula (I) is applied at an acid equivalent of about 16 g (gae / ha) to about 35 gae / ha per hectare, and MCPA.
EHE is applied at a dose of about 280 gae / ha. In one embodiment, the method
Utilizing the benzyl ester of the compound of formula (I) and MCPA, the benzyl ester of the compound of formula (I) has an acid equivalent of about 8.75 g (gae / ha) to about 42 ga per hectare.
It is applied at an application rate of e / ha, and MCPA is about 70 gae / ha to about 280 gae /.
It is applied at a dose of ha. In one embodiment, the method utilizes a benzyl ester of the compound of formula (I) and MCPA, the benzyl ester of the compound of formula (I) being applied to an acid equivalent of about 8.75 g (gae / ha) per hectare. It is applied at a dose and MCPA is about 140
It is applied at a dose of gae / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with MCPA or a carboxylic acid salt or ester thereof are DIGSA, ECHCG, LEFCH, BRAPP.
, ECHOR, SCPJU, VIOTR, POLCO, or BRSNN.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with MCPB or a salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to MCPB or a salt or ester thereof is about 1: 2.
It is in the range of 50 to about 3: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to MCPB or salt or ester thereof is 1: 150.
It is in the range of ~ about 0.75: 1. In certain embodiments, the compositions provided herein are compounds of formula (I) or benzyl esters or n-butyl esters thereof.
And MCPB. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth.
In some embodiments, the composition is applied at an acid equivalent of about 102 grams (gae / ha) to about 2000 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In certain embodiments, the composition is 1 relative to the total amount of active ingredient in the composition.
The acid equivalent per hectare is applied at a dose of about 110 grams (gae / ha) to about 650 gae / ha. In some embodiments, the method contacts the undesired vegetation or habitat thereof with the compound of formula (I) or a salt or ester thereof, and MCPB or a salt or ester thereof, eg, sequentially or simultaneously. Or it includes the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments
MCPB or its salt or ester is about 100 gae / ha to about 1700 gae /
The compound of formula (I), which is applied at an application rate of ha and is a salt or ester thereof, is about 2 g.
It is applied at a dose of ae / ha to about 300 gae / ha. In some embodiments, MCP
B or a salt or ester thereof is applied at an application rate of about 35 gai / ha to about 500 gai / ha, and the compound of formula (I) which is the salt or ester thereof has an acid equivalent of about 2 g (gae / ha) per hectare. ) ~ Approximately 150 gae / ha. In certain embodiments, the method comprises a compound of formula (I) or a benzyl ester thereof or n-.
Butyl ester and MCPB or MCPB ethyl ester are utilized. In this embodiment, the method utilizes the n-butyl ester and MCPB ethyl ester of the compound of formula (I), the n-butyl ester of the compound of formula (I) having an acid equivalent of about 3 per hectare.
It is applied at a dose of g (gae / ha) to about 150 gae / ha, and the MCPB ethyl ester is applied at a dose of about 100 to about 500 gae / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with MCPB or a salt or ester thereof are used to control ECHCG, ECHOR and SCPJU. NS.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with mecoprop-P or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, formula (I)
The weight ratio of the compound or salt or ester thereof to mecoprop-P or its carboxylic acid salt or ester is in the range of about 1: 1680 to about 1.5: 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to mecoprop-P or a carboxylic acid salt or ester thereof is in the range of 1: 600 to about 1: 4. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to mecoprop-P or a carboxylic acid salt or ester thereof is from about 1:60 to about 1.
: It is in the range of 7. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to mecoprop-P or a carboxylic acid salt or ester thereof is in the range of about 1:30 to about 1:15. .. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to mecoprop-P or a carboxylic acid salt or ester thereof is about 1: 22.9. In certain embodiments, the compositions provided herein are a compound of formula (I) or a benzyl ester thereof, and mecoprop-P.
including. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and mecoprop-P, and the weight ratio of the benzyl ester of the compound of formula (I) to mecoprop-P is about 1: 1. It is 22.9. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is relative to the total amount of active ingredient in the composition.
It is applied at an acid equivalent of about 202 grams (gae / ha) to about 3600 gae / ha per hectare. In certain embodiments, the composition comprises an acid equivalent of about 204 grams (gae / ha) to about 1270 ga per hectare relative to the total amount of active ingredient in the composition.
It is applied at an e / ha dose. In some embodiments, the method applies compounds of formula (I) or salts or esters thereof, and mecoprop-P or carboxylic acid salts or esters thereof, eg, sequentially or simultaneously, to unwanted vegetation or habitats thereof. Includes steps to prevent vegetation development or growth by contacting or applying them to soil or water. In some embodiments, mecoprop-P or a carboxylic acid salt or ester thereof is applied at a dose of about 200 gae / ha to about 3360 gae / ha, and the compound of formula (I) which is a salt or ester thereof is a compound of formula (I). About 2 gae / ha to about 300 gae / h
It is applied at the dose of a. In some embodiments, Mecoprop-P or a carboxylic acid salt or ester thereof is applied at an application rate of about 90 gai / ha to about 500 gai / ha, and the compound of formula (I) which is a salt or ester thereof is a compound of formula (I). Acid equivalent of about 3 per hectare
It is applied at a dose of g (gae / ha) to about 24 gae / ha. In some embodiments
Mecoprop-P or its carboxylic acid salt or ester is about 180 gai / ha ~
The compound of formula (I), which is applied at an application rate of about 220 gai / ha and is a salt or ester thereof, is applied at an acid equivalent of about 6 g (gae / ha) to about 12 gae / ha per hectare. .. In some embodiments, mecoprop-P, or a carboxylic acid or ester thereof, is applied at an application rate of about 200 gai / ha, and a compound of formula (I), which is a salt or ester thereof, has an acid equivalent per hectare. It is applied at an application rate of about 8.75 g (gae / ha). In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester thereof, and mecoprop-P. In one embodiment, the method is:
Utilizing the benzyl ester of the compound of I) and mecoprop-P, the benzyl ester of the compound of formula (I) is applied at an acid equivalent of about 8.75 g (gae / ha) per hectare, and mecoprop-P. Is applied at an application rate of about 200 gai / ha. In certain embodiments, the methods and compositions that utilize the compound of formula (I) or a salt or ester thereof in combination with mecoprop-P or a carboxylic acid salt or ester thereof are used to control BRSNN. NS.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with picloram or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to picloram or a carboxylic acid salt or ester thereof is in the range of about 1: 560 to about 30: 1. Is inside. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to picloram or carboxylic acid salt or ester thereof is in the range of 1:16 to about 1: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to picloram or carboxylic acid salt or ester thereof is in the range of about 1:32 to about 2: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to picloram or carboxylic acid salt or ester thereof is in the range of about 1:16 to about 1: 1.1. In certain embodiments, the compositions provided herein comprise a compound of formula (I) or a benzyl ester thereof, and picloram or picloram K ⁺ . In one embodiment, the composition comprises a benzyl ester and picloram of a compound of formula (I) and is of formula (I).
The weight ratio of the benzyl ester of the compound of) to picloram is about 1:16 to about 1: 2. In one embodiment, the composition comprises at ⁺ benzyl ester and picloram K of the compounds of formula (I), the weight ratio of benzyl ester and the picloram K ⁺ of the compound of formula (I) is about 1: It is 1.1. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth.
In some embodiments, the composition is applied at an acid equivalent of about 12 grams (gae / ha) to about 1420 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In certain embodiments, the composition is applied at an application rate of about 13 grams (gae / ha) to about 88 gae / ha of acid equivalent per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method contacts undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof, and picrolam or a carboxylate or ester thereof. Or, these include the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, picrolam or a carboxylic acid salt or ester thereof is applied at an application rate of about 10 gae / ha to about 1120 gae / ha, and a compound of formula (I) which is a salt or ester thereof is about 2 gae. It is applied at a dose of / ha to about 300 gae / ha. In some embodiments, picloram or a carboxylic acid salt or ester thereof is about 4 gai / ha ~.
The compound of formula (I), which is applied at an application rate of about 140 gai / ha and is a salt or ester thereof, is applied at an acid equivalent of about 2 g (gae / ha) to about 45 gae / ha per hectare. .. In some embodiments, picrolam or a carboxylic acid salt or ester thereof is applied at an application rate of about 10 gai / ha to about 70 gai / ha, and the compound of formula (I) which is a salt or ester thereof is 1 hectare. Acid equivalent per unit is about 4.4 g (gae)
/ Ha) to about 17.5 gae / ha. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and picloram or picloram K ^+. In one embodiment, the method utilizes the benzyl ester and picrolam of the compound of formula (I), which comprises approximately 4.4 g (gae / ha) of acid equivalent per hectare of the benzyl ester of the compound of formula (I). Approximately 17.5 gae / h
It is applied at a dose of a and picloram is applied at a dose of about 10 gai / ha to about 70 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and picrolam K ⁺ , the benzyl ester of the compound of formula (I) having an acid equivalent of about 8.75 g per hectare (gae / ha). And picrolam K ⁺ is applied at a dose of about 10 gai / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with picloram or a carboxylic acid salt or ester thereof are CENMA, SINAR, VIOTR, ST.
Used to control EME, or POLCO.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with quinchlorac or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to quinchlorac or a carboxylic acid salt or ester thereof is about 1: 280 to about 4: 1. It is within the range. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to quinchlorac or a carboxylate or ester thereof is in the range of 1: 127 to about 1: 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to quinchlorac or a carboxylate or ester thereof is in the range of about 1: 130 to about 1: 3. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to quinchlorac or a carboxylate or ester thereof is from about 1:64 to about 1.
: It is in the range of 6.6. In certain embodiments, the compositions provided herein comprise a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and quinchlorac. In one embodiment, the composition comprises a compound of formula (I) and quinchlorac, and the weight ratio of the compound of formula (I) to quinchlorac is from about 1:64 to about 1.
: 6.6. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and quinchlorac, and the weight ratio of the benzyl ester of the compound of formula (I) to quinchlorac is about 1.56 :. It is 1 to about 1: 8. In one embodiment, the composition is represented by the formula (
It contains n-butyl ester and quinchlorac of the compound of I), and the weight ratio of the n-butyl ester of the compound of formula (I) to quinchlorac is about 1:16 to about 1: 8.
With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is applied at an acid equivalent of about 72 grams (gae / ha) to about 860 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In certain embodiments, the composition comprises approximately 7 acid equivalents per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of 4 grams (gae / ha) to about 645 gae / ha. In some embodiments, the method contacts the undesired vegetation or habitat thereof with the compound of formula (I) or a salt or ester thereof, and quinchlorac or a carboxylate or ester thereof, eg, sequentially or simultaneously. Includes steps to prevent vegetation development or growth by letting or applying them to soil or water. In some embodiments, the quinchlorac or carboxylic acid salt or ester thereof is from about 70 gae / ha to about 560 gae /.
The compound of formula (I), which is applied at an application rate of ha and is a salt or ester thereof, is about 2 g.
It is applied at a dose of ae / ha to about 300 gae / ha. In some embodiments, the quinchlorac or carboxylic acid salt or ester thereof is from about 35 gai / ha to about 1100.
The compound of formula (I), which is applied at a gai / ha application and is a salt or ester thereof, is applied at an acid equivalent of about 2 g (gae / ha) to about 170 gae / ha per hectare. In some embodiments, quinchlorac or a carboxylic acid salt or ester thereof is applied at an application rate of about 70 gai / ha to about 560 gai / ha, and the compound of formula (I) which is a salt or ester thereof is 1 Acid equivalent per hectare is about 4.38g (ga)
It is applied at a dose of e / ha) to about 84.8 gae / ha. In certain embodiments, the method utilizes a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and quinchlorac. In one embodiment, the method utilizes a compound of formula (I) and quinchlorac, the compound of formula (I) having an acid equivalent of about 4.38 g per hectare (1 hectare).
It is applied at a dose of gae / ha) to about 84.8 gae / ha, and quincrolac is used.
It is applied at a dose of about 70 gai / ha to about 560 gai / ha. In one embodiment, the method utilizes a benzyl ester and quinchlorac of a compound of formula (I) and formula (I).
The benzyl ester of the compound of is about 4.38 g (gae / ha) of acid equivalent per hectare.
) ~ About 35 gae / ha, and Kincrolac is about 70 gai / h
It is applied at a dose of a to about 560 gai / ha. In one embodiment, the method comprises formula (I).
Using the n-butyl ester of the compound of the above and quinchlorac, the n- of the compound of the formula (I)
Butyl ester has an acid equivalent of about 35 g (gae / ha) to about 70 gae per hectare.
It is applied at a dose of / ha and Kincrolac is applied at a dose of about 560 gai / ha. In certain embodiments, the methods and compositions that utilize a compound of formula (I) or a salt or ester thereof in combination with quinchlorac or a carboxylic acid salt or ester thereof are CYPES, DIGSA, ECHCG, CYPIR ISCRU, EC
Used to control HOR, SCPMA, AMARE, VIOTR, or POLCO.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is used in combination with triclopyr or a carboxylic acid salt or ester thereof. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to triclopyr or a carboxylic acid salt or ester thereof is in the range of about 1:112 to about 4: 1. Is inside. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to triclopyr or a carboxylate or ester thereof is in the range of 1:64 to about 1: 1. In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to triclopyr or a carboxylate or ester thereof is in the range of about 1: 100 to about 1: 1.
In certain embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to triclopyr or a carboxylate or ester thereof is in the range of about 1:44 to about 1: 1.7. In certain embodiments, the compositions provided herein are the compound of formula (I) or a benzyl ester or n-butyl ester thereof, and triclopyr T.
Includes EA, triclopyrcholine, or triclopyr BEE. In one embodiment, the composition comprises a compound of formula (I) and triclopyr TEA, the weight ratio of the compound of formula (I) to triclopyr TEA being from about 1:44 to about 1: 2. .. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and triclopyr TEA, and the weight ratio of the benzyl ester of the compound of formula (I) to triclopyr TEA is about 1.44 :. 1
~ About 1: 4. In one embodiment, the composition comprises n-butyl ester of compound of formula (I) and triclopyr TEA, and the weight ratio of n-butyl ester of compound of formula (I) to triclopyr TEA is about. It is 1: 17.5. In one embodiment, the composition is
It contains the compound of formula (I) and triclopyrcholine, and the weight ratio of the compound of formula (I) to triclopyrcholine is from about 1:28 to about 1: 1.7. In one embodiment, the composition comprises the benzyl ester of the compound of formula (I) and triclopyrcholine, the formula (
The weight ratio of the benzyl ester of the compound I) to triclopyrcholine is about 1:28 to about 1.
: 4. In one embodiment, the composition comprises a benzyl ester of the compound of formula (I) and triclopyr BEE, and the weight ratio of the benzyl ester of the compound of formula (I) to triclopyr BEE is from about 1:16. It is about 1: 2. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition has an acid equivalent of about 37 grams (gae / ha) to about 2540 g per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of ae / ha. In certain embodiments, the composition comprises from about 40 grams (gae / ha) to about 3 acid equivalents per hectare relative to the total amount of active ingredient in the composition.
It is applied at a dose of 25 gae / ha. In some embodiments, the method contacts the undesired vegetation or its habitat with, for example, sequentially or simultaneously with the compound of formula (I) or a salt or ester thereof, and triclopil or a carboxylate or ester thereof. Or, these include the steps of applying them to soil or water to prevent the development or growth of vegetation. In some embodiments, triclopyr or a carboxylic acid salt or ester thereof is applied at a dose of about 35 gae / ha to about 2240 gae / ha, and the compound of formula (I) which is a salt or ester thereof is about 2 gae. / Ha ~ about 300 gae / ha
It is applied at the dose of. In some embodiments, the triclopyr salt or ester thereof is triclopyr TEA, triclopyr DMA, or triclopyr choline salt. In some embodiments, triclopyr or a carboxylic acid salt or ester thereof is about 17 gai /.
Formulas that are applied at a dose of ha to about 600 gai / ha and are salts or esters thereof (
The compound of I) has an acid equivalent of about 2 g (gae / ha) to about 100 gae / hectare.
It is applied at a dose of ha. In some embodiments, triclopyr or a carboxylic acid salt or ester thereof is applied at a dose of about 35 gai / ha to about 280 gai / ha.
The compound of formula (I), which is a salt or ester thereof, has an acid equivalent of about 4.
It is applied at a dose of 38 g (gae / ha) to about 42.4 gae / ha. In certain embodiments, the method comprises a compound of formula (I) or a benzyl ester or n-butyl ester thereof, and triclopyr TEA, triclopyr choline, or triclopyr BEE.
To use. In one embodiment, the method utilizes a compound of formula (I) and triclopyr TEA, the compound of formula (I) having an acid equivalent of about 4.38 g (gae / ha) per hectare.
It is applied at a dose of ~ about 42.4 gae / ha, and triclopyr TEA is about 70 ga.
It is applied at a dose of i / ha to about 280 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and triclopyr TEA, the benzyl ester of the compound of formula (I) having an acid equivalent of about 4.38 g (gae / ha) per hectare. It is applied at a dose of ~ about 17.5 gae / ha, and triclopyr TEA is about 70 gai /
It is applied at a dose of ha to about 280 gai / ha. In one embodiment, the method comprises the formula (I).
The n-butyl ester of the compound of) and triclopyr TEA are utilized, and the n-butyl ester of the compound of formula (I) is applied at an acid equivalent of about 16 g (gae / ha) per hectare, and triclopyr TEA. Is applied at an application rate of about 280 gai / ha.
In one embodiment, the method utilizes the compound of formula (I) and triclopyrcholine to formulate (
The compound of I) has an acid equivalent of about 4.38 g (gae / ha) to about 42.4 per hectare.
It is applied at a dose of gae / ha, and triclopyrcholine is applied at a dose of about 35 gai / ha to about 140 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and triclopyrcholine, the benzyl ester of the compound of formula (I) having an acid equivalent of about 4.38 g (gae / ha) per hectare. ) ~ Approximately 17.5 ga
It is applied at an e / ha dose and triclopyrcholine is about 35 gai / ha to about 14
It is applied at a dose of 0 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and triclopyr BEE, the benzyl ester of the compound of formula (I) having an acid equivalent of about 4.4 g (gae / ha) per hectare. ~ Approximately 17.5 gae / h
It is applied at the dose of a, and triclopyr BEE is about 35 gai / ha to about 70 gai.
It is applied at a dose of / ha. In certain embodiments, the methods and compositions that utilize the compound of formula (I) or a salt or ester thereof in combination with triclopyr or a carboxylic acid salt or ester thereof are BRAPP, DIGSA, ECHCG, ECHCO,
LEFCH, SCPJU, SCPMA, ECHOR, CYPRO, FIMMI, CENM
Used to control A, SONAR, CIRAR, or CASOB.

In certain embodiments of the compositions and methods described herein, the compound of formula (I) or a salt or ester thereof is halauxifene-methyl (4-amino-3-chloro-6- (4-amino-3-chloro-6-). 4-Chloro-2-fluoro-3-methoxyphenyl) methyl picolinate), or its carboxylic acid or carboxylic acid salt, or used in combination with other esters. With respect to the composition, in some embodiments, the weight ratio of the compound of formula (I) or a salt or ester thereof to halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is: It is in the range of about 1: 17.5 to about 600: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is from 1: 4 to about. It is in the range of 20: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is from about 1: 4 to. It is in the range of about 20: 1. In certain embodiments, the weight ratio of the compound of formula (I) or salt or ester thereof to halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is approximately 1: 2 to. It is in the range of about 9.6: 1. In certain embodiments, the compositions provided herein comprise a compound of formula (I) or a benzyl ester thereof, and halauxifene-methyl or halauxifene K ⁺ . In one embodiment, the composition comprises a compound of formula (I) and halauxifen-methyl, and the weight ratio of the compound of formula (I) to halauxifen-methyl is about 1: 1 to 1. It is about 9.6: 1. In one embodiment, the composition comprises the benzyl ester of the compound of formula (I) and halauxifen-methyl, and the weight ratio of the benzyl ester of the compound of formula (I) to halauxifen-methyl is , About 1: 2 to about 8: 1. In one embodiment, the composition comprises at ⁺ benzyl ester and Halau carboxymethyl Fen K of the compound of formula (I), the weight ratio of benzyl ester and Halau carboxymethyl Fen K ⁺ of the compound of formula (I) , About 1: 2 to about 2: 1. With respect to the method, in certain embodiments, the method involves contacting unwanted vegetation or its habitat with the compositions described herein, or applying them to soil or water. Includes steps to prevent vegetation development or growth. In some embodiments, the composition is applied at an acid equivalent of about 2.5 grams (gae / ha) to about 335 gae / ha per hectare relative to the total amount of active ingredient in the composition. Will be done. In certain embodiments, the composition is applied at an acid equivalent of about 6 grams (gae / ha) to about 57 gae / ha per hectare relative to the total amount of active ingredient in the composition. .. In some embodiments, the method presents undesired vegetation or habitats thereof with a compound of formula (I) or a salt or ester thereof, and halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or the like. Esters are, for example, sequentially or simultaneously contacted, or they are applied to soil or water to prevent the development or growth of vegetation. In some embodiments, halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is applied at an application rate of from about 0.5 gae / ha to about 35 gae / ha and is a salt or salt thereof. The compound of formula (I), which is an ester, is applied at an application rate of about 2 gae / ha to about 300 gae / ha. In some embodiments, halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is about 1 ga.
The compound of formula (I), which is applied at an application rate of i / ha to about 30 gai / ha and is a salt or ester thereof, has an acid equivalent of about 1 g (gae / ha) to about 100 gae per hectare.
It is applied at a dose of / ha. In some embodiments, halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other ester is about 2.19 gai / h.
Formula (I), which is applied at an application rate of a to about 15 gai / ha and is a salt or ester thereof.
Compounds have an acid equivalent of about 3.75 g (gae / ha) to about 42.4 ga per hectare.
It is applied at an e / ha dose. In certain embodiments, the method comprises a compound of formula (I) or a benzyl ester thereof, and halauxifene-methyl or halauxifene K.
^{Use +} . In one embodiment, the method comprises the compound of formula (I) and halauxifene-.
Utilizing methyl, the compound of formula (I) has an acid equivalent of about 4.38 g (gae) per hectare.
/ Ha) to about 42.4 gae / ha, and halauxifene-methyl is applied at a dose of about 2.19 gai / ha to about 8.75 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and halauxifene-methyl, the benzyl ester of the compound of formula (I) having an acid equivalent of about 3.
It is applied at a dose of 75 g (gae / ha) to about 17.5 gae / ha, and halauxifene-methyl is applied at a dose of about 2.19 gai / ha to about 15 gai / ha. In one embodiment, the method utilizes the benzyl ester of the compound of formula (I) and halauxifen K ⁺ , the benzyl ester of the compound of formula (I) having an acid equivalent of about 3.75 g per hectare (gae). / Ha) to about 42 gae / ha, and ^{halauxifen K +} is applied at a dose of about 3.75 gai / ha to about 15 gai / ha.
In certain embodiments, the methods and compositions utilizing the compounds of formula (I) or salts or esters thereof are combined with halauxifene-methyl, or a carboxylic acid or carboxylic acid salt thereof, or other esters. , LEFCH, IPOHE, CYPIR, E
Used to control CHCG, ECHOR, CYPRO, ELEIN, or SORHA.

The components of the mixtures described herein can be applied either individually or as part of a multipart herbicide system.

The mixtures described herein can be applied in combination with one or more other herbicides to control a wider variety of unwanted vegetation. When used in combination with other herbicides, the composition may be formulated with other herbicides (s), tank mixed with other herbicides (s), or other herbicides (s). ) And can be applied sequentially. Some of the herbicides that can be used in combination with the compositions and methods described herein include, but are not limited to, 4-CPA; 4-CPB; 4-CPP; 3,4-DA; 3,4-DB;
2,4-DEB; 2,4-DEP; 3,4-DP; 2,3,6-TBA; 2,4,5-T
2,4,5-TB; acetochlor, asifluolphen, acronifen, acrolein, alacrol, aridchlor, alloxydim, allyl alcohol, allolac, ametridion, ametrine, ambazine, amiccarbazone, amidosulfone, amiprophos-methyl, amitrol, ammonium sul. Famate, Anilophos, Anislon, Aslam, Atraton, Atrazine, Azaphenidine, Azim Sulflon, Adiprotrin,
Burban, BCPC, beflubutamide, benazoline, bencarbazone, benfluralin,
Benfresate, Bensulflon-Methyl, Benthlide, Benthiocarb, Ventazone-
Sodium, benzadox, benzfendizone, benziplum, benzobicyclon, benzophenap, benzofluol, benzoylprop, benzthiazuron, bialaphos, bicyclopyrone, biphenox, bialaphos, bispyribak-sodium, borax, bromacil, bromobonyl, bromobutide, bromophenoxime, Bromoxinyl, bromacilazone, butachlor, butaphenacyl, butamiphos, butenachlor, butydazole, butiuron, butraline, butoroxydim, buturon, butyrate, cacodylic acid, cafentrol, calcium chlorate, calcium cyanamide, cambendichlor, calvaslam, carbetamid, carboxazolechlorprocarb , Calfentrazone-Ethyl,
CDEA, CEPC, clomethoxyphene, chloramben, chloranokryl, chlorradihop, chlorazine, chlorbromron, chlorbufam, chlorleturon, chlorphenac, chlorphenprop, chlorfurlazole, chlorflurenol, chloridazone, chlorlimron, chlornitrofen, chloropon Chloroxynyl, chlorpropham, chlorsulfuron, chlortal, chlortiamide, cinidone-ethyl, symmethyrine, sinosulfuron, cisanilide, cretogym, cryogenate, chlordinahop-propargyl, crohop, chromazone, cloprop, cloproxilim, chlorathrum-methyl, CMA, sulfuric acid. Copper, CPMF, CPPC, credazine, cresol, cumyllon, cyanatrin, cyanazine, cycloate, cyclopyrimolate, cyclosulfamron, cycloxidim, cyclulon, cihalohop-butyl,
Cipelcoat, cyprazine, cyprazole, cypromid, dimulon, dalapon, dazomet, delacrol, desmedifam, desmethrin, di-alate, diclobenil, dichloralurea, dichlormate, dicrohop-methyl, dicroslam, dietumcoat, dietatyl, diphenopenten, diphenocene diphenocene Diflufenzopill, dimeflon, dimepiperate, dimethaclor, dimetamethrin, dimethenamide, dimethenamide-P, dimexano, dimidazone, dinitramine, dinophenate, dinoprop, dinosam, dinoceb, dinoterub, diphenamide, dipropetrin , DSMA, E
BEP, Eglinadin, Endotar, Apronaz, EPTC, Elle-Bon, Esprocarb, Etalfurlarin, ethbenzamide, Etamethosulfron, Echidimron, Ethiolate, ethobenzamid, etob
enzamid), etofumesate, ethoxyphen, ethoxysulfone, etinophen, etonipromid, etobenzanide, EXD, phenaslam, phenoprop, phenoxaprop, phenoxaprop-P-ethyl, phenoxaprop-P-ethyl + isoxadiphen-ethyl, phenoki Sasulfon, Fenteracol, Fentiaprop, Fentrazamide, Phenuron, Ferrous Sulfate, Fulham Prop, Fulham Prop-M, Frazasulfuron, Floraslam, Fluazihop, Fluazihop-P-Butyl, Fluazolate, Flucarbazone, Flucetosulfone, Fluchloraline , Flufenacet, Fluphenican, Flufenpil-Ethyl, Flumethoslam, Flumedin, Flumicrolac-
Pentyl, flumioxazine, flumipropin, fluomethurone, fluorodiphen, fluoroglycophen, fluoromidine, fluoronitrophen, fluorothyurone, flupoxam, flupropasyl, flupropanate, flupyrsulfuron, fluridone, flulocrolidone, flulutamon, fluthiaset, homesaphen, Horamsulfuron, hosamine, fumicrolac, fryloxyphene, glufosinate, glufosinate-ammonium, glufosinate-P-ammonium, glyphosate, halosafene, halosulfuron-methyl, haloxidine, haloxihop-methyl, haloxihop-P-methyl, hexachloroacetone, Hexaflulate, Hexadinone, Imazametabens, Imazamox, Imazapic, Imazapill, Imazaquin, Imazosulfone, Imazetapill, Indanophan, Indazifram, Iodobonyl, Iodomethane, Iodosulflon, Iodosulfone-Ethyl-Sodium, Iofencelfuron Zone, iprimidum, isocarbamide, isosyl, isomethiodine, isonorlone, isopolynate, isopropalin, isoproturone, isouron, isoxaben, isoxachlortol, isoxaflutol, isoxapyrihop, carbutyrate,
Ketospiradox, Lactophene, Lenacil, Linuron, MAA, MAMA, MCPB,
Medinoterub, mephenacet, mefluidide, mesoprazine, mesosulfuron, mesotrione, metam, metamihop, metamitron, metazachlor, metazosulfuron, metoflurazone, metabenzthiazulone, metalpropalin, metazol, methionenecarb, methiozoline, methiulone, methiozoline , Methyl isothiocyanate, Methyldimron, Metobenzlone, Metobromron, Metrachlor, Methoslam, Metoxron, Metribdin, Methosulfone, Methosulfron-methyl, Molinate, Monalide, Monisouron, Monochloroacetic acid, Monolinuron, Monuron, Morphumcoat, MSMA, Naproanid Nebron, Nicosulfuron, Nipyraclophen, Nitralin, Nitrofen, Nitrofluorphen, Norflurazone, Norlon, OCH, Orbencarb, Ortho-dichlorobenzene, Orthosulfamron, Oryzarin, Oxaziargyl, Oxaziazone, Oxapyrazone, Oxalphlone, Oxadichromephone, Oxyfluorphen, Paraflufen-ethyl, paraflulon, paraquat, pebrate, pelargonic acid, pendimethalin, penoxyslam,
Pentachlorophenol, pentanochlor, pentoxazone, perfluidone, petoxamide, phenisoam, fenmedifam, phenmedifam-ethyl, phenobenzlone, phenylmercury acetate, picolinaphen, pinoxaden, piperophos, potassium arsenate,
Potassium azide, potassium cyanate, pretilachlor, primisulfuron-methyl, procyanidin, prodiamine, profluazole, proflularin, prohoxydim, proglinazine, prohexadione-calcium, promethone, promethrin, pronamide,
Propachlor, Propanil, Propaquiza Hop, Propazine, Profem, Propisochlor, Propoxycarbazone, Propyrisulfuron, Propyzamide, Prosulfalin,
Prosulfocarb, prosulfone, proxan, prinachlor, pidanone, pyracronyl, pyraflufen-ethyl, pyrasulfotor, pyrazodyl, pyrazolinete, pyrazosulfone-ethyl, pyrazoxifene, pyribenzoxim, pyribuchicarb, pyrichlor, pyridaform, pyridate, pyriphthalide, pyriminobac, pyrimisulfan , Pyrthiobac-sodium, Pyroxasulfone, Pyroxyslam, Kinmerak, Kinoclamine, Kinonamide, Kizarohop, Kizarohop-P-Ethyl, Rhodetanyl, Lisulflon, Saflufenacyl, S-methaclor, Sebutyrazin, Sekbumeton, Setoxydim, Cyduron, Simadine, Simetone , SMA, sodium phosphite, sodium azide, sodium chlorate, sulcotrione, sulfalate, sulfentrazone, sulfomethurone, sulfosate, sulfosulfone, sulfuric acid, sulglycapine, swep, SYN-523, TCA, tebutum, Tebutyuron, Tefriltrion, Tembotrion, Tepraloxidim, Telbasil, Telbucarb, Telbuchlor, Telbumethone, Telbutyrazin, Telbutrin, Tetraflulon, Tenylchlor, Thiazaflulon, Thiazopill, Thidiadimin, Thidiazulone, Thiencarbazone-Methyl, Thifensulfuron,
Tiffenslefurun-methyl, thiobencarb, thiocarbazyl, thiochlorim, topramison, tralcoxydim, triafamon, tri-alate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, tricamba, tridiphan, trifluralin, trifluralin, trifluralin , Trihop,
Includes trihopsime, trihydroxytriazine, trimethurone, tripropindan, tritac tritosulfone, vernolate, xylachlor, and salts, esters, optically active isomers, and mixtures thereof.

The compositions and methods described herein further include glyphosate resistance, 5-enolpyrvir silicate-3-phosphate (EPSP) synthase inhibitor resistance, glufosinate resistance, glutamine synthetase inhibitor resistance, dicamba resistance, Phenoxyoxin resistance, pyridyloxyoxin resistance, auxin resistance, auxin transport inhibitor resistance,
Aryloxyphenoxypropionate resistance, cyclohexanedione resistance, phenylpyrazolin resistance, acetyl CoA carboxylase (ACCase) inhibitor resistance, imidazolinone resistance, sulfonylurea resistance, pyrimidinylthiobenzoate resistance, triazolopyrimidine resistance, sulfonylaminocarbonyltriazoli Non-resistant, acetolactate synthase (ALS) or acetoxylate synthase (AHAS) resistance, 4-hydroxyphenyl-pyrvate dioxygenase (HPPD) resistance, phytoendesaturase inhibitor resistance, carotenoid biosynthesis inhibitor resistance, protoporphyrinogen Oxidase (PPO)
) Resistance, cellulose biosynthesis inhibitor resistance, auxin division inhibitor resistance, microtube inhibitor resistance, ultra-long chain fatty acid inhibitor resistance, fatty acid and lipid biosynthesis inhibitor resistance, photochemical system I inhibitor resistance, photochemical system II With inhibitor-tolerant, triazine-tolerant, bromoxinyl-tolerant crops, and multiple or multiple traits that confer resistance to multiple chemicals and / or multiple mechanisms of action by single and / or multiple resistance mechanisms. Glyphosate, EPSP synthase inhibitor, gluhosinate, glutamine synthase inhibitor, dicamba, phenoxyoxine, pyridyloxyoxine, synthetic auxin, auxin transport inhibitor, aryloxyphenoxypropionate, cyclohexanedione, phenylpyrazolin ,
ACCase, imidazolinone, sulfonylurea, pyrimidinylthiobenzoate, triazolopyrimidine, sulfonylaminocarbonyltriazolinone, ALS or AHA
S inhibitor, HPPD inhibitor, phytoendesaturase inhibitor, carotenoid biosynthesis inhibitor, PPO inhibitor, cellulose biosynthesis inhibitor, thread division inhibitor, microtube inhibitor, super long chain fatty acid inhibitor, fatty acid and lipid Biosynthesis inhibitor, photochemical system I inhibitor, photochemical system II inhibitor,
It can be used in combination with triazine and bromoxynil. In some embodiments, the formula (
The compounds of I), or salts or esters thereof, and their complementary herbicides, or salts or esters thereof, are selective for the crop being treated and are controlled by these compounds at the dosages used. Used in combination with herbicides that complement the weed spectrum. In some embodiments, the compositions described herein, and other supplemental herbicides, are applied simultaneously, either as a combination formulation or as a tank mix.

In some embodiments, the compositions described herein are AD-67 (MON4660), benoxalol, benthiocarb, brassinolides, to enhance their selectivity.
Croquintoset (mexil), siometrinyl, dimulon, dichlormid, dicyclonone, dimepiperate, disulfoton, phenchlorazole-ethyl, fenchlorim,
Flurazole, fluxophenim, frylazole, harpin protein, isoxadiphen-ethyl, jiecaowan, jiecaoxi, mephenpil-
Diethyl, mephenate, naphthalic anhydride (NA), oxabetrinyl, R29148
, And one or more herbicides such as N-Phenyl-sulfonyl benzoic acid amides used in combination with herbicide safeners. In some embodiments, the phytotoxicity reducing agent is used in a rice, grain, corn, or corn environment. In some embodiments, the phytotoxicity reducing agent is a cloquintoset, or a salt or ester thereof. In certain embodiments, crokinto sets are utilized to offset the adverse effects of the composition on rice and grains. In some embodiments, the phytotoxicity reducing agent is cloquintoset (mexil).
Is.

In some embodiments, the compositions described herein are 2,3,5-tri-iodobenzoic acid, IAA, IBA, naphthalene acetamide, α-naphthalene acetate, benzyladenine, 4-hydroxyphenetyl. Alcohol, kinetin, zeatin, endtal, ethephon, pentachlorophenol, tidiazulone, tribuphos, abigricin, etephone, hydrazide maleate, gibberellic acid, gibberellic acid, abscisic acid, ansimidol,
Hoamine, glyphosine, isopyrimol, jasmonic acid, hydrazide maleate, mepicort, 2,3,5-tri-iodobenzoic acid, morphactin, dichloroflurenol, fluluprimidol, mefluidide, paclobutrazol, tetcyclasis, uniconazole, brassinolide , Brassinolide-Ethyl, Cycloheximide, Ethylene, Metasulfocarb, Prohexadione, Triapentenol, and Trinexapack and are used in combination with one or more plant growth regulators.

In some embodiments, the plant growth regulators are rice, grain crops, corn, corn, broadleaf crops, oilseed rape / canola, lawn, pineapple, sugar cane, sunflower, grass, grassland, grazing land, fallow, lawn, trees. And used in one or more crops or environments such as vineyards, plantation crops, vegetables, and non-crop (foliage plant) environments. In some embodiments, the plant growth regulator is mixed with a compound of formula (I) or with a compound of formula (I) and a synthetic auxin so as to cause a preferentially favorable effect on the plant. Be mixed.

In some embodiments, the compositions provided herein further comprise at least one agriculturally acceptable adjuvant or carrier. Appropriate adjuvants or carriers should be phytotoxic to high value crops in the presence of crops, especially at the concentrations used when applying the composition to selectively control weeds. And should not chemically react with herbicidal constituents or other compositional ingredients. Such mixtures can be designed to be applied directly to weeds or their habitats, or can be concentrated or formulations that are usually diluted with additional carriers and adjuvants prior to application. They can be, for example, solids such as powders, granules, granule wettable powders, or wettable powders, or liquids such as emulsions, liquids, emulsions, or suspensions. They can also be provided as premixtures or tank mixtures.

Suitable agricultural adjuvants and carriers include, but are not limited to, crop oil concentrates; nonoxynols ethoxylates; benzyl cocoalkyldimethyl quaternary ammonium salts; petroleum hydrocarbons, alkyl esters, organic acids, and anionic surfactants. Blend of agents; C ₉
~ C ₁₁ alkyl polyglycoside; phosphorylated alcohol ethoxylate; natural primary alcohol (C ₁₂ ~ C ₁₆ ) ethoxylate; di-sec-butylphenol EO-PO block copolymer; polysiloxane-methylcap; nonoxyphenol ethoxylate +
Includes ammonium urea nitrate; emulsified methylated seed oil; tridecyl alcohol (synthetic) ethoxylate (8EO); tallow amine ethoxylate (15 EO); PEG (400) dioleate-99.

Liquid carriers that can be used include water and organic solvents. Organic solvents are, but are not limited to, petroleum distillates or hydrocarbons (eg mineral oils, aromatic solvents, paraffin oils, etc.); vegetable oils (eg soybean oil, rapeseed oil, olive oil, sunflower oil, sunflower seed oil, etc.)
Palm oil, coconut oil, cottonseed oil, flaxseed oil, palm oil, lacquer oil, Benibana oil, sesame oil, millet oil, etc.); Esters of the above vegetable oils; monoalcohol or divalent, trivalent, or other lower polyalcohols (4 to Esters of 6 hydroxy esters (eg 2-ethylhexyl stearate, n-butyl oleate, isopropyl myristate, propylene glycol dioleate, di-octyl succinate, di-butyl adipate, di-phthalate)
Octyl, etc.); includes esters of mono, di and polycarboxylic acids, etc. Specific organic solvents include, but are not limited to, toluene, xylene, petroleum naphtha, crop oil, acetone, methyl ethyl ketone, cyclohexanone, trichloroethylene, perchloroethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol monomethyl ether and Diethylene glycol monomethyl ether, methyl alcohol, ethyl alcohol, isopropyl alcohol, amyl alcohol, ethylene glycol, propylene glycol, glycerin, N-methyl-2-pyrrolidinone, N, N-dimethylalkylamide, dimethyl sulfoxide, liquid fertilizer and the like are included. In certain embodiments, the diluting carrier for the concentrated formulation is water.

Suitable solid carriers include, but are not limited to, talc, pyrophyllite clay, silica, attapargas clay, kaolin clay, keelgur, choke, diatomaceous earth, lime, calcium carbonate, bentonite clay, fuller soil, cotton husks, flour. , Soybean flour, limestone, wood flour, walnut shell flour, lignin, cellulose, etc.

In some embodiments, the compositions described herein further comprise one or more surfactants. In some embodiments, such surfactants are used in both solid and liquid compositions, and in certain embodiments, they are designed to be diluted with a carrier prior to application. Surfactants can be anionic, cationic, or nonionic in nature and can be used as emulsifiers, wetting agents, suspending agents, or for other purposes. Surfactants that can also be used in the formulations of the present invention are, among others, "McCutcheon".
's Detergents and Emulsifiers Annual' MC Publishing Corp., Ridgewood, New Jerse
y, 1998 and "Encyclopedia of Surfactants" Volumes I-III, Chemical Publishing Co., N
ew York, 1980-81. The surfactants include, but are not limited to, (and ammonium lauryl sulfate diethanol) alkyl sulfates, (such as calcium dodecylbenzenesulfonate) alkyl aryl sulfonates; alkylphenol - alkylene oxide addition products (nonylphenol -C ₁₈ ethoxy Rate etc.); Alcohol-alkylene oxide addition product (tridecyl alcohol-C ₁₆ ethoxylate etc.); Secken (sodium stearate etc.); Alkylnaphthalene-sulfonate (sodium dibutylnaphthalene sulfonate etc.); Dialkyl ester (di (2)
-Ethylhexyl) sodium sulfosuccinate, etc.); sorbitol ester (sorbitol oleate, etc.); quaternary amine (lauryltrimethylammonium chloride, etc.); fatty acid polyethylene glycol ester (polyethylene glycol stearate, etc.); block copolymer of ethylene oxide and propylene oxide; Salts of mono and dialkyl phosphates; vegetable or seed oils (eg soybean oil, rapeseed / canola oil, olive oil, sunflower oil, sunflower seed oil, palm oil, corn oil, cottonseed oil, flaxseed oil, palm oil, lacquer oil, Benibana Oils, sesame oil, millet oil, etc.); and esters of the above vegetable oils, and in certain embodiments, methyl esthetics.

In some embodiments, these substances, such as vegetable or seed oils and their esters, can be used interchangeably as an agricultural adjuvant, as a liquid carrier, or as a surfactant.

Other exemplary additives for use in the compositions provided herein include:
Not limited to, but not limited to, compatibilizers, defoamers, metal ion blockers, neutralizers and buffers, corrosion inhibitors, pigments, odorants, spreading agents, penetrating aids, fixing agents, dispersants. , Thickeners, freezing point depression agents, antimicrobial agents, etc. are included. The composition may also contain other compatible constituents such as other herbicides, plant growth regulators, fungicides, pesticides, etc., with liquid fertilizers, or with ammonium nitrate, urea, etc. It can be formulated with a carrier of solid fine particle fertilizer.

In some embodiments, the concentration of active ingredient in the compositions described herein is about 0.
It is 0005 to 98% by weight. In some embodiments, the concentration is from about 0.0006 to 90% by weight.
Is. In compositions designed for use as concentrated formulations, in certain embodiments, the active ingredient is from about 0.1-98% by weight, and in certain embodiments, from about 0.5-90% by weight. Present in concentration. In certain embodiments, such compositions are diluted with an inert carrier, such as water, prior to application. Diluted compositions commonly applied to weeds or weed habitats are:
In certain embodiments, it contains from about 0.0006 to 3.0% by weight of the active ingredient, and in certain embodiments it contains from about 0.01 to 1.0% by weight.

The compositions of the present invention can be prepared by the use of conventional soil or aerial dusters, sprayers, and granulators, by addition to irrigation or field water, and other conventional means known to those of skill in the art. Can be applied to weeds or their growing areas.

The embodiments described and the examples below are for purposes of illustration only and are not intended to limit the scope of the claims. Other modifications, uses or combinations relating to the compositions described herein will be apparent to those skilled in the art without departing from the spirit and scope of the claimed subject matter.

The results of Examples I, II, III, IV, and V are the results of the greenhouse test.

Example I Evaluation of post-occurrence foliar-applied weeding mixture for weed control in direct-seeded rice Loam soil or sandy loam soil (eg, 28.6% silt, 18.8% clay, and 52.6 sand) %, The pH is about 5.8 and the organic content is about 1.8%) and the soil matrix prepared by mixing the calcareous gravel in a ratio of 80:20 to the seeds of the desired test plant species or Small silts were planted. The soil matrix was contained in a plastic pot with a volume of 1 quart and a surface area of 83.6 square centimeters (cm ^2).
Antifungal and / or other chemical or physical treatments were applied as necessary to ensure good germination and healthy plants. Plants are about 29 ° C during the day and 26 ° C at night
It was cultivated for 8 to 22 days in a greenhouse with a photoperiod of about 14 hours, maintained in. Nutrients (P
Ethers Excel® 15-5-15 5-Ca 2-Mg and chelated iron) were applied in the irrigation solution as needed and water was added periodically. 100 if necessary
A 0 watt overhead metal halide lamp was used to provide supplementary lighting. When these plants reached the 1st to 4th true leaf stages, they were used in the test.

Treatment was 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) pyridin-2-carboxylic acid, each of which was formulated as SC (suspended preparation). It consisted of an acid or ester of (Compound A) and various herbicidal components alone and in combination. The form of Compound A was applied on an acid equivalent basis.

In the form of compound A (compound of formula I) tested,

が含まれる。

Is included.

Other herbicidal constituents are applied on an acid equivalent or active ingredient basis and are 2,4-D dimethylammonium (DMA) salts (formulated as Weedar® 64), 2,4-D.
Choline salt (formulated as liquid (SL)), 2,4-D2-ethylhexyl ester (EH)
E) (formulated as SL), MCPA K ⁺ / Na ⁺ / DMA salt (formulated as Agritox® 50), MCPA ethylhexyl ester (MCPA2®)
Formulated as), Fluroxypyrmethyl heptyl ester (MHE) (Starane (
Formulated as Registered Trademark) or Starane® Ultra), Triclopyrtriethylamine (TEA) Salt (Formulated as Grandstand® R),
Triclopyrcholine salt (formulated as SL), triclopyrbutothyl ester (formulated as EC), dicambadimethylammonium (DMA) salt (Banvel® 4)
Formulated as S), Kincrolac (formulated as Facet® 75DF),
And halauxifene-methyl (formulated as SC (suspension)).

The treatment requirements are the dosage to be tested, the concentration or acid equivalent of the active ingredient in the formulation, and 187 L.
Calculated based on a 12 mL application volume at a / ha application rate.

For treatments consisting of formulated compounds, the measured amounts of compound are individually placed in 25 mL glass vials and diluted to a volume of 1.25% (v / v) of Agri-Dex® concentrated crop oil. Then, a 12 × preservation solution was obtained. If the test compound did not dissolve easily, the mixture was warmed and / or sonicated. The application solution is an appropriate amount of each storage solution (eg, 1) so that the final spray solution contains 1.25 +/- 0.05% (v / v) of the crop oil concentrate.
mL) was added and 10 mL of an aqueous mixture of 1.25% (v / v) crop oil concentrate was added to dilute to the appropriate final concentration.

For treatments consisting of industrial compounds, the weighed ones were individually placed in 25 mL glass vials and dissolved in a volume of acetone / DMSO97: 3v / v to give a 12x storage solution. If the test compound does not dissolve easily, the mixture can be warmed and / or sonicated. For the application solution, add an appropriate amount of each storage solution (for example, 1 mL) so that the final spray solution contains 1.25% (v / v) of the crop oil concentrate, and 1.5% (v / v) of the crop oil concentrate. v
) By adding 10 mL of the aqueous mixture to a suitable final concentration.
Can be prepared. When using industrial substances, the final acetone and DMS of the application solution
This concentrated storage solution can be added to the spray solution so that the O concentration is 16.2% and 0.5%, respectively.

For treatments consisting of formulated compounds and industrial compounds, 25 mL of the weighed industrial material
Put individually in glass vials and dissolve in a volume of acetone / DMSO97: 3v / v to obtain a 12x storage solution, and also place the measured amount of the formulated compound individually in 25mL glass vials to produce the crop. Dilute the oil concentrate or water to a volume of 1.5% (v / v), 12 ×
A storage solution can be obtained. If the test compound does not dissolve easily, the mixture can be warmed and / or sonicated. For the application solution, add an appropriate amount of each storage solution (for example, 1 mL) so that the final spray solution contains 1.25% (v / v) of the crop oil concentrate, and add an appropriate amount of the crop oil concentrate of 1.5% (v / v). It can be prepared by diluting to a suitable final concentration by adding an aqueous mixture of v / v). If necessary, add additional water and / or acetone / DMSO 97: 3 v / v to the individual application solutions to bring the final concentrations of acetone and DMSO in the application solutions to be compared to 8.1% and 0.25%, respectively. be able to.

All storage and application solutions were visually inspected for compound compatibility prior to application. Overhead Mandel truck spray with 8002E nozzle calibrated to deliver 187 L / ha over the entire ^{application area of 0.503 m 2} at a spray height 18-20 inches (46-50 cm) above the average canopy height of the plant. The spray solution was applied to the vegetable material using a track sprayer. Control plants were sprayed with solvent blanks in the same manner.

Treated and control plants were placed in the greenhouse above and watered by underground irrigation to prevent the test compounds from being washed away. After about 3 weeks, the condition of the test plant compared to that of the untreated plant was visually determined and scaled from 0 to 100 percent (0 corresponds to no harm or growth inhibition, 100 corresponds to complete death). Scored based on.

Colby's equation was used to determine the expected herbicidal effect from the mixture (Colby, S).
. R. 1967, Calculation of the synergistic and antagonistic response of herbicid
e combinations. Weeds Volume 15: pp. 20-22. ).

The following formula was used to calculate the expected activity of the mixture containing the two active ingredients A and B.
Expected value = A + B- (A × B / 100)
A = Observed potency of active ingredient A at the same concentration as used in the mixture.
B = Observed potency of active ingredient B at the same concentration as used in the mixture.

The test compounds, dosages used, plant species tested, and results are shown in Tables 1-26.

Example II Evaluation of the herbicidal mixture applied underwater in the case of weed control in transplanted paddy crushed non-sterile mineral soil (silt 50.5%, clay 25.5%, and sand 24%,
Weeds of the desired test plant species were added to the flooded soil (mud) prepared by mixing water at a volume ratio of 1: 1 with pH of about 7.6 and organic matter content of about 2.9%). Seeds or nucules were planted. Non-perforated 16 with a surface area of 86.59 square centimeters (cm ²⁾
In ounce (oz.) Plastic pots, 3 cm (cm) in each pot
) Was provided, and the above-prepared mud was distributed and charged in a fixed amount of 365 mL. Allowed to dry overnight before planting or transplanting. In the plastic plug tray, Sun Gr
o MetroMix® 306 seeding mixture (usually having a pH of 6.0-6.8 and an organic matter content of about 30%) was planted with rice seeds. Four days prior to application of the herbicide, a non-perforated 32 oz. With ^{a surface area of 86.59 cm 2.} 840 mL of mud in a plastic pot was transplanted with seedlings in the second or third leaf growing stage. Rice fields were prepared by filling the headspaces of these pots with water 2.5 to 3 cm. Antifungal and / or other chemical or physical treatments were applied as necessary to ensure good germination and healthy plants. The plants were cultivated for 4-22 days in a greenhouse with a photoperiod of about 14 hours, maintained at about 29 ° C during the day and 26 ° C at night. Nutrients are Osm
16oz as ocote® (19: 6: 12, N: P: K + micronutrients)
.. 2 g per pot, and 32 oz. 4 g was added per pot of. Water was added regularly to maintain the flooding of the rice fields and, if necessary, supplementary lighting was provided using 1000 watt overhead metal halide lamps. When these plants reached the 1st to 4th true leaf stages, they were used in the test.

The treatment was 4-amino-3-chloro-5-fluoro-6- (4-amino-3-chloro-5-fluoro-6-, each of which was formulated as SC.
It consisted of an acid or ester of 4-chloro-2-fluoro-3-methoxy-phenyl) pyridin-2-carboxylic acid (Compound A), alone or in combination with various herbicidal constituents. The form of Compound A was applied on an acid equivalent basis.

In the form of compound A (compound of formula I) tested,

が含まれる。

Is included.

Other herbicidal constituents are applied on an acid equivalent or active ingredient basis and are 2,4-D dimethylammonium (DMA) salts (formulated as Weedar® 64), 2,4-
D choline salt (formulated as liquid (SL)), 2,4-D2-ethylhexyl ester (E)
HE) (formulated as SL), MCPA K ⁺ / Na ⁺ / DMA salt (Agritox50)
Formulated as MCPA Ethylhexyl Ester (Formulated as MCPA2), Fluroxypyrmethylhexyl Ester (EHE) (Starane® or Sta
lane (registered trademark) Ultra (formulated as Ultra), triclopyrcholine salt (formulated as SL), triclopyrbutothyl ester (formulated as EC), triclopiltriethylamine (TEA) salt (formulated as Grandstand® R) (Formulation), dicambadimethylammonium (DMA) salt (formulated as Banvel® 4S), quinchlorac (formulated as Facate® 75DF), and halauxifene-methyl (formulated as SC). Inclusive.

The treatment requirements for each compound or herbicidal component are the dosage to be tested, the concentration or acid equivalent of the active ingredient in the formulation, the application volume of 2 mL per component per pot, and the application area of ^{86.59 cm 2 per pot.} Calculated based on.

For the formulated compounds, the measured doses are placed in individual 100 mL or 200 mL glass vials and dissolved in a volume of 1.25% (v / v) of Agri-Dex® crop oil concentrate. An application solution was obtained. If the test compound did not dissolve easily, the mixture was warmed and / or sonicated.

For industrial grade compounds, the weighed ones can be placed in individual 100 mL to 200 mL glass vials and dissolved in a volume of acetone to give a concentrated storage solution. If the test compound does not dissolve easily, the mixture can be warmed and / or sonicated. The resulting concentrated storage solution is an aqueous mixture containing 2.5% (v / v) of crop oil concentrate so that the final application solution contains 1.25% (v / v) crop oil concentrate. Can be diluted using equal volumes.

The application was performed by individually and sequentially injecting an appropriate amount of the application solution into the aqueous layer of the rice field using a pipettor. Control plants were treated in the same manner with solvent blanks. All treated plant materials were applied to give the same concentration of acetone and crop oil concentrate.

The treated and control plants were placed in the above greenhouse and water was added as needed to maintain the flooding of the rice fields. After about 3 weeks, the condition of the test plant compared to that of the untreated plant was visually determined and scaled from 0 to 100 percent (0 corresponds to no harm or growth inhibition, 100 corresponds to complete death). Scored based on.

Colby's equation was used to determine the expected herbicidal effect from the mixture (Colby, S).
.R. 1967, Calculation of the synergistic and antagonistic response of herbi
cide combinations. Weeds Volume 15: pp. 20-22. ).

The following formula was used to calculate the expected activity of the mixture containing the two active ingredients A and B.
Expected value = A + B- (A × B / 100)
A = Observed potency of active ingredient A at the same concentration as used in the mixture.
B = Observed potency of active ingredient B at the same concentration as used in the mixture.

Some of the test compounds, the dosages used, the plant species tested, and the results are shown in Tables 27-53.

Example III Evaluation of herbicide mixture applied foliar after outbreak to control weeds common to row-sown crops such as corn and soybean Loam soil or sandy loam soil (eg 28.6% silt, clay) Soil prepared by mixing 18.8% and 52.6% sand, pH about 5.8, organic content about 1.8%) and calcareous gravel in a ratio of 80:20. The matrix was planted with seeds or small silts of the desired test plant species. The soil matrix was contained in a plastic pot with a surface area of 84.6 square centimeters (cm ² ) and a volume of 560 cubic centimeters (cm ^3). Antifungal and / or other chemical or physical treatments were applied as necessary to ensure good germination and healthy plants. These plants were cultivated for 7-31 days (d) in a greenhouse with a photoperiod of about 15 hours (h), maintained at about 23-29 ° C during the day and 22-28 ° C at night. Nutrients (Peters Excel® 15-5-15 5-Ca 2-Mg) and water are added regularly and, if necessary, 1
A 000 watt overhead metal halide lamp was used to provide supplementary lighting. When these plants reached the 1st, 2nd, or 3rd true leaf stage, they were used in the test.

The conditions of treatment are the application dose to be tested, the concentration or acid equivalent of the active ingredient in the formulation, and 187.
Calculated based on an application volume of 12 mL at an application rate of L / ha.

The treatment was 4-amino-3-chloro-5-fluoro-6-, each of which was formulated as SC.
It consisted of an acid or ester of (4-chloro-2-fluoro-3-methoxy-phenyl) pyridine-2-carboxylic acid (Compound A), and various herbicidal constituents alone or in combination. The form of Compound A was applied on an acid equivalent basis.

In the form of compound A (compound of formula I) tested,

が含まれる。

Is included.

A synthetic auxin herbicide, 2,4-D, to which other herbicidal components are applied on an acid equivalent basis.
It contained a dimethylamine salt (formulated as Weedar® 64) and a halauxifen K ⁺ salt (formulated as a liquid (SL)). For treatments consisting of formulated compounds, the measured amounts of compound are individually placed in 25 mL glass vials and diluted to a volume of 1.5% (v / v) of Agri-Dex® concentrated crop oil. Then, 6 × preservation solution was obtained.
If the test compound did not dissolve easily, the mixture was warmed and / or sonicated. For the application solution, add an appropriate amount of each storage solution (usually 2 mL) so that the final spray solution contains 1.25 +/- 0.05% (v / v) of the crop oil concentrate, and add an appropriate amount of the crop oil concentrate. 1.5%
Prepared by diluting to the appropriate final concentration by adding an aqueous mixture of (v / v) and water.

For treatments consisting of industrial compounds, the weighed ones were individually placed in 25 mL glass vials and dissolved in a volume of acetone / DMSO97: 3v / v to give a 6x storage solution. If the test compound does not dissolve easily, the mixture can be warmed and / or sonicated. For the application solution, add an appropriate amount of each storage solution (for example, 2 mL) so that the final spray solution contains 1.25% (v / v) of the crop oil concentrate, and 1.5% of the appropriate amount of the crop oil concentrate (for example, 2 mL). v
It can be prepared by diluting to the appropriate final concentration by adding / v) and water. When industrial materials are used, concentrated storage solutions can be added to the spray solution so that the final acetone and DMSO concentrations of the application solution are 16.2% and 0.5%, respectively.

For treatments consisting of formulated compounds and industrial compounds, 25 mL of the weighed industrial material
Individually placed in glass vials and dissolved in a volume of acetone / DMSO97: 3v / v to give a 6 × storage solution, and the measured amounts of the formulated compound are individually placed in 25 mL glass vials. It was added and diluted with water to a volume of 1.5% (v / v) of the crop oil concentrate to obtain a 6 × storage solution. If the test compound did not dissolve easily, the mixture was warmed and / or sonicated. As for the application solution, the final spray solution contains 1.25% of the crop oil concentrate.
Appropriate by adding an appropriate amount of each storage solution (eg, 2 mL) to contain (v / v) and adding an appropriate amount of crop oil concentrate 1.5% (v / v) and an aqueous mixture of water. It can be prepared by diluting to the final concentration. If necessary, add additional water and / or acetone / DMSO 97: 3 v / v to the individual application solutions to bring the final acetone and DMSO concentrations of the application solutions to be compared to 16.2% and 0.5%, respectively. be able to.

All storage and application solutions were visually inspected for compound compatibility prior to application. The requirements for the compound are 12 mL application volume at a dose of 187 liters (L / ha) per hectare.
Was used as the standard. Equipped with an 8002E nozzle calibrated to deliver 187 L / ha over the entire ^{application area of 0.503 square meters (m 2} ) at a spray height of 18-20 inches (46-50 cm) above the average canopy height of the plant. The formulated compound was applied to the plant material using an overhead Mandel truck sprayer. Control plants were sprayed with solvent blanks in the same manner.

Treated and control plants were placed in the greenhouse above and watered by underground irrigation to prevent the test compounds from being washed away. After about 2 weeks, the condition of the test plant compared to that of the untreated plant was visually determined and scaled from 0 to 100 percent (0 corresponds to no harm or growth inhibition, 100 corresponds to complete death). ) Was scored.

Colby's equation was used to determine the expected herbicidal effect from the mixture (Colby, S).
.R. 1967, Calculation of the synergistic and antagonistic response of herbi
cide combinations. Weeds Volume 15: pp. 20-22. ).

The following formula was used to calculate the expected activity of the mixture containing the two active ingredients A and B.
Expected value = A + B- (AxB / 100)
A = Observed potency of active ingredient A at the same concentration as used in the mixture.
B = Observed potency of active ingredient B at the same concentration as used in the mixture.

Some of the test compounds, the dosages used, the plant species tested, and the results are shown in Tables 54-56.

Example IV Evaluation of a herbicide mixture applied to the foliage after outbreak to control weeds in grain crops in a greenhouse.
S in a plastic pot with a surface area of 103.2 square centimeters (cm ²⁾
un Gro MetroMix® 306 seeding mixture (usually pH 6.0-
Seeds of the desired test plant species were planted at 6.8 and having an organic matter content of about 30 percent). Antifungal and / or other chemical or physical treatments were applied as necessary to ensure good germination and healthy plants. These plants have a temperature of about 18 ° C during the day.
And at night, it was cultivated for 7-36 days in a greenhouse with a photoperiod of about 14 hours, maintained at 17 ° C. Nutrients and water were added on a regular basis and, if necessary, supplementary lighting was provided using a 1000 watt overhead metal halide lamp. When these plants reached the second or third true leaf stage, they were used for testing.

Treatment was 4-amino-3-chloro-5-fluoro-6- (4-) formulated as SC.
Chloro-2-fluoro-3-methoxy-phenyl) Pyridine-2-carboxylic acid (Compound A)
) Benzyl ester, and a second grain herbicide alone and in combination.

In the form of compound A (compound of formula I) tested,

が含まれる。

Is included.

25 ml of benzyl ester of 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) pyridin-2-carboxylic acid (Compound A) measured in a certain amount. (ML) was placed in a glass vial and diluted to a volume of 1.25% (v / v) of Agri-Dex concentrated crop oil to obtain a storage solution. Compound requirements were based on an application volume of 12 mL at a dose of 187 liters (L / ha) per hectare.
A spray solution of a mixture of the second grain herbicide and the experimental compound is prepared by adding this preservation solution to an appropriate amount of the dilution solution and contains the active ingredient in the binary and ternary combinations 1
A 2 mL spray solution was formed. Overhead Mandel truck sprayer equipped with 8002E nozzle calibrated to deliver 187 L / ha over an entire ^{application area of 0.503 square meters (m 2} ) at a spray height of 18 inches (46 cm) above the average canopy of the plant. The formulated compound was applied to a plant material using a (track sprayer). Control plants were sprayed with solvent blanks in the same manner.

Treated and control plants were placed in the greenhouse above and watered by underground irrigation to prevent the test compounds from being washed away. After 20-22 days, the condition of the test plant compared to that of the control plant was visually determined and scaled to 0-100 percent (0 corresponds to harmless, 100 corresponds to complete death). Scored based on.

Colby's equation was used to determine the expected herbicidal effect of the mixture (Colby, S).
. R. 1967, Calculation of the synergistic and antagonistic response of herbici
de combinations. Weeds Volume 15: pp. 20-22. ).

The following formula was used to calculate the predicted activity of the mixture containing the two active ingredients A and B.
Predicted value = A + B- (A × B / 100)
A = Observed potency of active ingredient A at the same concentration as used in the mixture.
B = Observed potency of active ingredient B at the same concentration as used in the mixture.

The test compounds, dosages used, test plant species, and results are shown in Tables 57-66.

Example V Evaluation of post-occurrence herbicidal activity of the mixture in forage crops S in a plastic pot with a ^{surface area of 126.6 square centimeters (cm 2)}
un Gro MetroMix® 306 seeding mixture (usually pH 6.0-
Seeds or roots of the desired test plant species were planted at 6.8 and having an organic matter content of about 30 percent. Antifungal and / or other chemical or physical treatments were applied as necessary to ensure good germination and healthy plants. These plants are maintained at about 28 ° C during the day and 24 ° C at night, from 14 to 14 in a greenhouse with a photoperiod of about 14 hours.
Cultivated for 60 days. Nutrients and water were added on a regular basis and, if necessary, supplementary lighting was provided using a 1000 watt overhead metal halide lamp. When these plants reached the BBCH13-BBCH23 leaf stage, they were used in the test.

Treatment was 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) pyridin-2-carboxylic acid (Compound A) formulated as SC.
Benzyl ester, and a second herbicide alone and in combination.

In the form of compound A (compound of formula I) tested,

が含まれる。

Is included.

Place the measured constant amount of Compound A in a 25 ml (mL) glass vial and add Ag.
The ri-Dex® concentrated crop oil was diluted to a volume of 1.25% (v / v) to give a preservation solution. Compound requirements were based on an application volume of 12 mL at a dose of 187 liters (L / ha) per hectare. A spray solution of a mixture of the second herbicide or experimental compound was prepared by adding this storage solution to an appropriate amount of dilution solution to form a 12 mL spray solution containing the active ingredient in the binary combination. 18 inches (4) from the average canopy of the plant
At a spray height above 6 cm), on the entire surface ^{of the application area 0.503 square meters (m 2)}
Overhead M equipped with 8002E nozzle calibrated to deliver 187L / ha
The formulated compound was applied to the plant material using an andel truck sprayer. Control plants were sprayed with solvent blanks in the same manner.

Treated and control plants were placed in the greenhouse above and watered by underground irrigation to prevent the test compounds from being washed away. Approximately 21 days later, the condition of the test plant compared to that of the control plant was visually determined and based on a scale of 0-100 percent (0 corresponds to harmless and 100 corresponds to complete death). Was scored.

Colby's equation was used to determine the expected herbicidal effect of the mixture (Colby, S).
. R. 1967, Calculation of the synergistic and antagonistic response of herbici
de combinations. Weeds Volume 15: pp. 20-22. ).

The following formula was used to calculate the predicted activity of the mixture containing the two active ingredients A and B.
Predicted value = A + B- (A × B / 100)
A = Observed potency of active ingredient A at the same concentration as used in the mixture.
B = Observed potency of active ingredient B at the same concentration as used in the mixture.

The test compounds, dosages used, test plant species, and results are shown in Tables 67-75.

Example VI Assessment of herbicidal activity after development of the mixture in a Canadian grain field test.
Post-occurrence field testing was performed in Warner (Alberta, Canada) under commercial field conditions. The test site was located in a commercial field of direct-seeded durum wheat (Macaroni wheat (Triticum durum)) using standard herbicide subtest plot study methodologies. The test plot size varied by 2 meters (m) x 8 m (width x length) in 4 repeated tests per treatment. Grain crops were cultivated using routine cultivation management operations for fertilization, sowing and management to ensure good crop growth and weed growth.

All treatments during the field test after the outbreak were calibrated to apply a spray volume of 100 L / ha at a nozzle pressure of about 276 kPa, a flat fan air attracting nozzle (110 °).
) Was applied using a backpack-type compressed CO _{2 atomizer.} Treatment is SC (suspension preparation)
Benzyl ester of 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) pyridin-2-carboxylic acid (Compound A) formulated as, and various It consisted of herbicidal components alone and in combination.

In the form of compound A (compound of formula I) tested,

が含まれる。

Is included.

Fluroxypill-MHE (STARANE II, emulsion (emulsifiable concentrate f)
ormulation), 333gae / L) commercial products, and halauxifen-ME (GF-
The formulation of 2645, granule wettable powder, 200 gae / kg) is mixed in water at the appropriate dosage of the formulated product and the unit area of application (hectare) to achieve the desired dosage shown.
The desired dosage was achieved based on. Treatment was scored 28-54 days after application (DAA) compared to untreated control plants. Visual weed control was scored on a scale of 0 to 100 percent, where 0 corresponds to no harm and 100 corresponds to complete death.

For both single products and mixtures, all treatment results are the average of 4 repeated tests. The test site had a spontaneous population of weeds. The weed spectrum included, but not limited to, salsola and Russian thistle.

Colby's equation was used to determine the expected herbicidal effect of the mixture (Colby, S).
. R. 1967, Calculation of the synergistic and antagonistic response of herbici
de combinations. Weeds Volume 15: pp. 20-22. ).

The following formula was used to calculate the predicted activity of the mixture containing the two active ingredients A and B.
Predicted value = A + B- (A × B / 100)
A = Observed potency of active ingredient A at the same concentration as used in the mixture.
B = Observed potency of active ingredient B at the same concentration as used in the mixture.

The test compounds, dosages used, test plant species, and results from in-crop field tests are shown in Tables 76 and 77.

Examples of the invention of the present application based on the above description include the following.
[1] Effective amount of herbicidal compound of formula (a) (I)

Alternatively, a synergistic herbicidal composition comprising an agriculturally acceptable salt or ester thereof and (b) a synthetic auxin herbicide.
[2] (a) is a compound of formula (I), C of a compound of formula (I). _1-4 The composition according to [1], which is an alkyl ester or a benzyl ester of a compound of the formula (I).
[3] (b) is 2,4-D, 2,4-D EHE, 2,4-DMA, 2,4-D choline, aminocyclopyracrol, aminopyralid, aminopyralid TIPA, clomeprop-P, clopyralid, Clopyralid MEA, dicamba, dicamba DMA, dichloroprop-P, fluloxipill, fluoroxypill MHE, MCPA, MCPA EHE, MCPB, MCPB-ethyl ester, mecoprop-P, picloram, picloram K ^＋ Salt, quinchlorac, triclopyl, triclopyl TEA, triclopyrcholine, triclopyl BEE, halauxifene-methyl, and halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3) -Methyl methoxyphenyl) picolinate) or at least one compound selected from the group consisting of potassium carboxylic acid salts thereof, or agriculturally acceptable salts thereof, carboxylic acids, carboxylic acid salts or esters [1]. To the composition according to any one of [2].
[4] The composition according to any one of [1] to [3], further comprising an agriculturally acceptable adjuvant or carrier.
[5] The composition according to any one of [1] to [4], further comprising a herbicide and a phytotoxicity reducing agent.
[6] A method for controlling undesired vegetation, in which an effective amount of the compound of formula (a) (I) is applied to the vegetation or its growing place.

Alternatively, it comprises the steps of superficially contacting the agriculturally acceptable salt or ester and (b) a synthetic auxin herbicide, or applying them to soil or water to prevent vegetation development or growth. ,Method.
[7] (a) is a compound of formula (I), C of a compound of formula (I). _1-4 The method according to [6], which is an alkyl ester or a benzyl ester of a compound of formula (I).
[8] (b) is 2,4-D, 2,4-D EHE, 2,4-DMA, 2,4-D choline, aminocyclopyracrol, aminopyralid, aminopyralid TIPA, clomeprop-P, clopyralid, Clopyralid MEA, dicamba, dicamba DMA, dichloroprop-P, fluloxipill, fluoroxypill MHE, MCPA, MCPA EHE, MCPB, MCPB-ethyl ester, mecoprop-P, picloram, picloram K ^＋ Salt, quinchlorac, triclopyl, triclopyl TEA, triclopyrcholine, triclopyl BEE, halauxifene-methyl, and halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3) -Methyl methoxyphenyl) picolinate) or at least one compound selected from the group consisting of potassium carboxylic acid salts thereof, or agriculturally acceptable salts thereof, carboxylic acids, carboxylic acid salts or esters, [6]. To the method according to any one of [7].
[9] Direct-sown rice, flooded rice and transplanted rice, grain, wheat, barley, oat wheat, rye, sorghum, corn / corn (maize), sugar cane, sunflower, abrana, canola, tensai, soybean, cotton, pineapple, grass , Grasslands, pastures, fallow lands, lawns, trees and vineyards, aquatic plants, industrial vegetation management (IVM), or public road lands (ROW) to control unwanted vegetation, [6] to [8] The method described in either.
[10] The method according to any one of [6] to [9], wherein (a) and (b) are applied to weeds or crops before outbreak.
[11] Glyphosate, 5-enolpyruvyl simimate-3-phosphate (EPSP) synthase inhibitor, gluhosinate, glutamine synthase inhibitor, dicamba, phenoxyoxine, pyridyloxyoxine, synthetic oxine, oxine transport inhibitor, aryloxyphenoxy Propionate, cyclohexanedione, phenylpyrazolin, acetyl CoA carboxylase (ACCase) inhibitor, imidazolinone, sulfonylurea, pyrimidinylthiobenzoate, triazolopyrimidine, sulfonylaminocarbonyltriazolinone, acetolactic synthase (ALS) or acethydroxy Acid synthase (AHAS) inhibitor, 4-hydroxyphenyl-pyrvate dioxygenase (HPPD) inhibitor, phytoendesaturase inhibitor, carotenoid biosynthesis inhibitor, protoporphyrinogen oxidase (PPO) inhibitor, cellulose biosynthesis inhibitor Undesirable vegetation in filamentous division inhibitors, microtube inhibitors, ultra-long chain fatty acid inhibitors, fatty acid and lipid biosynthesis inhibitors, photochemical system I inhibitors, photochemical system II inhibitors, triazine, or bromoxinyl resistant crops The method according to any one of [6] to [10], wherein is controlled.
[12] The method of [11], wherein the resistant crop has a plurality of or multiple traits that confer resistance to a plurality of herbicides or multiple mechanisms of action.
[13] The method according to any of [6] to [12], wherein the unwanted vegetation comprises herbicide-resistant or resistant weeds.

Claims (11)

Effective amount of herbicidal compound of formula (a) (I)

A synergistic herbicidal composition comprising the benzyl ester of (b) and a synthetic auxin herbicide .
(B) is 2,4-D, 2,4-D EHE, 2,4-D DMA, 2,4-D choline, 2,4-DB, aminocyclopyracrol, aminopyrlide, aminopyrlide TIPA, triclopyride, Clopyralid MEA, dicamba, dicamba DMA, dichlorprop-P, furloxipill, furloxipill ME, furloxipill MHE, MCPA, MCPA EHE, mecoprop-P, picloram, picloram K ⁺ salt, quinchlorac, triclopyr, triclopyr TEA, triclopyr choline, Triclopyr BEE, triclopyr butothyl ester, halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) methyl picolinate), and halauxifene potassium salt At least one compound selected from the group consisting of
A composition in which the combination of (a) and (b) exhibits a synergistic effect between the herbicidal effect of (a) and the herbicidal effect of (b) . (B) is 2,4-D, and the ratio between (a) and (b) is 1: 2 to 1: 96.
(B) is 2,4-D EHE, and the ratio between (a) and (b) is 1: 4 to 1:56.
(B) is 2,4-D DMA, and the ratio between (a) and (b) is 1: 2 to 1: 63.9.
(B) is 2,4-D choline, and the ratio between (a) and (b) is 1: 6 to 1:96.
(B) is 2,4-DB, and the ratio between (a) and (b) is 1:17.
(B) is aminocyclopyrachlor, and the ratio between (a) and (b) is 2: 1 to 1: 4.
(B) is aminopyralid, and the ratio between (a) and (b) is 1: 3 to 1: 8.
(B) is aminopyralid TIPA, and the ratio between (a) and (b) is 1: 1 to 1: 8.
(B) is clopyralid, and the ratio between (a) and (b) is 1: 4 to 1:16.
(B) is clopyralid MEA, and the ratio between (a) and (b) is 1: 4 to 1:16.
(B) is dicamba, and the ratio between (a) and (b) is 1: 3.3 to 1:56.
(B) is dicamba DMA, and the ratio between (a) and (b) is 1: 3.3 to 1:56.
(B) is dichloroprop-P, and the ratio between (a) and (b) is 1:16.
(B) is a furloxipill, and the ratio between (a) and (b) is 1: 2 to 1:35.
(B) is furloxipyl MHE, and the ratio between (a) and (b) is 1: 2 to 1:35.
(B) is furloxipill ME, and the ratio between (a) and (b) is 1: 2 to 1:35.
(B) is MCPA, and the ratio between (a) and (b) is 1: 2 to 1:28.
(B) is MCPA EHE, and the ratio between (a) and (b) is 1: 2 to 1:28.
(B) is mecoprop-P, and the ratio between (a) and (b) is 1:15 to 1:30.
(B) is picloram, and the ratio between (a) and (b) is 1: 1.1 to 1:16.
(B) is a potassium potassium salt of picrolam, and the ratio between (a) and (b) is 1: 2 to 1:16.
(B) is quinchlorac, and the ratio between (a) and (b) is 1: 6.6 to 1:64.
(B) is triclopyr, and the ratio between (a) and (b) is 1: 1.7 to 1:44.
(B) is triclopyr TEA, and the ratio between (a) and (b) is 1: 2 to 1:44.
(B) is triclopyrcholine, and the ratio between (a) and (b) is 1: 1.7 to 1:28.
(B) is triclopyr BEE, and the ratio between (a) and (b) is 1: 2 to 1:16.
(B) is a triclopyrbutothyl ester, and the ratio between (a) and (b) is 1: 2 to 1:32.
(B) is halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2)
-Methyl fluoro-3-methoxyphenyl) picolinate), and the ratio between (a) and (b) is 9.6: 1-1: 2, or
The composition according to claim 1, wherein (b) is a potassium halauxifene salt and the ratio between (a) and (b) is 2: 1 to 1: 2. The composition according to claim 1 or 2 , further comprising an agriculturally acceptable adjuvant or carrier. Herbicide further comprising a safener, the compositions according to any one of claims 1-3. A method for controlling undesired vegetation, which is a plant or a place where it grows, or soil or water which enables the growth of the undesired vegetation, and a compound of formula (a) (I).

Look including the benzyl ester, and (b) absence step contacting the herbicidally effective amount of a composition comprising a synthetic auxin herbicides,
(B) is 2,4-D, 2,4-D EHE, 2,4-D DMA, 2,4-D choline, 2,4-DB, aminocyclopyracrol, aminopyrlide, aminopyrlide TIPA, triclopyride, Clopyralid MEA, dicamba, dicamba DMA, dichlorprop-P, furloxipill, furloxipill ME, furloxipill MHE, MCPA, MCPA EHE, mecoprop-P, picloram, picloram K ⁺ salt, quinchlorac, triclopyr, triclopyr TEA, triclopyr choline, Triclopyr BEE, triclopyr butothyl ester, halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) methyl picolinate), and halauxifene potassium salt At least one compound selected from the group consisting of
A method in which the combination of (a) and (b) exhibits a synergistic effect between the herbicidal effect of (a) and the herbicidal effect of (b) . (B) is 2,4-D, and the ratio between (a) and (b) is 1: 2 to 1: 96.
(B) is 2,4-D EHE, and the ratio between (a) and (b) is 1: 4 to 1:56.
(B) is 2,4-D DMA, and the ratio between (a) and (b) is 1: 2 to 1: 63.9.
(B) is 2,4-D choline, and the ratio between (a) and (b) is 1: 6 to 1:96.
(B) is 2,4-DB, and the ratio between (a) and (b) is 1:17.
(B) is aminocyclopyrachlor, and the ratio between (a) and (b) is 2: 1 to 1: 4.
(B) is aminopyralid, and the ratio between (a) and (b) is 1: 3 to 1: 8.
(B) is aminopyralid TIPA, and the ratio between (a) and (b) is 1: 1 to 1: 8.
(B) is clopyralid, and the ratio between (a) and (b) is 1: 4 to 1:16.
(B) is clopyralid MEA, and the ratio between (a) and (b) is 1: 4 to 1:16.
(B) is dicamba, and the ratio between (a) and (b) is 1: 3.3 to 1:56.
(B) is dicamba DMA, and the ratio between (a) and (b) is 1: 3.3 to 1:56.
(B) is dichloroprop-P, and the ratio between (a) and (b) is 1:16.
(B) is a furloxipill, and the ratio between (a) and (b) is 1: 2 to 1:35.
(B) is furloxipyl MHE, and the ratio between (a) and (b) is 1: 2 to 1:35.
(B) is furloxipill ME, and the ratio between (a) and (b) is 1: 2 to 1:35.
(B) is MCPA, and the ratio between (a) and (b) is 1: 2 to 1:28.
(B) is MCPA EHE, and the ratio between (a) and (b) is 1: 2 to 1:28.
(B) is mecoprop-P, and the ratio between (a) and (b) is 1:15 to 1:30.
(B) is picloram, and the ratio between (a) and (b) is 1: 1.1 to 1:16.
(B) is a potassium potassium salt of picrolam, and the ratio between (a) and (b) is 1: 2 to 1:16.
(B) is quinchlorac, and the ratio between (a) and (b) is 1: 6.6 to 1:64.
(B) is triclopyr, and the ratio between (a) and (b) is 1: 1.7 to 1:44.
(B) is triclopyr TEA, and the ratio between (a) and (b) is 1: 2 to 1:44.
(B) is triclopyrcholine, and the ratio between (a) and (b) is 1: 1.7 to 1:28.
(B) is triclopyr BEE, and the ratio between (a) and (b) is 1: 2 to 1:16.
(B) is a triclopyrbutothyl ester, and the ratio between (a) and (b) is 1: 2 to 1:32.
(B) is halauxifene-methyl (4-amino-3-chloro-6- (4-chloro-2)
-Methyl fluoro-3-methoxyphenyl) picolinate), and the ratio between (a) and (b) is 9.6: 1-1: 2, or
The method according to claim 5, wherein (b) is a potassium halauxifene salt and the ratio between (a) and (b) is 2: 1 to 1: 2. Direct seeding rice, submerged direct seeding rice and transplanted rice, grain, wheat, barley, oats, rye, sorghum, corn, sugar cane, sunflower, rapeseed, canola, sugar beet, soybean, cotton, pineapple, pasture, grassland, grazing land, holiday arable, lawns, trees and vineyards, aquatic plants, industrial vegetation management (IVM), or in right-of-way (ROW), the undesired vegetation is controlled, the method according to any one of claims 5-7 .. (A) and (b) it is applied before generation of said plant The method according to any one of claims 5-7. Glyphosate- tolerant crops , 5-enolpyrvir simimate-3-phosphate (EPSP) synthase inhibitor- tolerant crops , gluhosinate- tolerant crops , glutamine synthase inhibitor-tolerant crops , dicamba- tolerant crops , phenoxyoxine- tolerant crops , pyridyloxyoxine- tolerant crops , Synthetic auxin resistant crops , auxin transport inhibitor resistant crops , aryloxyphenoxypropionate resistant crops , cyclohexanedione resistant crops , phenylpyrazolin resistant crops , acetyl CoA carboxylase (ACCase) inhibitor resistant crops , imidazolinone resistant crops , sulfonylurea Resistant crops , pyrimidinylthiobenzoate resistant crops , triazolopyrimidine resistant crops , sulfonylaminocarbonyltriazolinone resistant crops , acetolactic synthase (ALS) or acetohydroxyate synthase (AHAS) inhibitor resistant crops , 4-hydroxyphenyl-pilbate Dioxygenase (HPPD) inhibitor resistant crops , phytoendesaturase inhibitor resistant crops , carotenoid biosynthesis inhibitor resistant crops , protoporphyrinogen oxidase (PPO) inhibitor resistant crops , cellulose biosynthesis inhibitor resistant crops , thread division inhibition Agent- resistant crops , microtube inhibitor- resistant crops , ultra-long-chain fatty acid inhibitor- resistant crops , fatty acid and lipid biosynthesis inhibitor- resistant crops , photochemical I inhibitor- resistant crops , photochemical II inhibitor- resistant crops , triazine- resistant crops , or the bromoxynil tolerant crops, the undesired vegetation is controlled, the method according to any one of claims 5-8. The method of claim 9 , wherein the resistant crop has a plurality of or multiple traits that confer resistance to a plurality of herbicides or resistance to a plurality of herbicide mechanisms of action. The undesired vegetation, including plants that are herbicide-resistant or herbicide resistance, the method according to any one of claims 5-10.