JP6886899B2 - Fuel cell structure - Google Patents

Description

Embodiments of the present invention relate to the configuration of a fuel cell structure.
Regarding.

The fuel cell power generation system is a system in which a fuel such as hydrogen and an oxidizing agent such as air are electrochemically reacted to directly convert the chemical energy of the fuel into electric energy and take it out to the outside. This fuel cell power generation system is generally characterized by being relatively small, highly efficient, and environmentally friendly. In addition, it can be applied as a cogeneration system by recovering the heat generated by power generation as hot water or steam.

The fuel cell body of such a fuel cell system is classified into various types according to the difference in electrolytes and the like. In particular, a polymer electrolyte fuel cell using a polymer electrolyte membrane as an electrolyte is excellent in low temperature operability and has a high output density. Therefore, it is suitable for use as a power source for small cogeneration systems for general households and fuel cell vehicles, and the market scale is expected to expand rapidly in the future.

This solid polymer fuel cell power generation system includes, for example, a reformer that produces hydrogen-containing gas from hydrocarbon fuels such as city gas and LPG, hydrogen-containing gas produced by the reformer, and the atmosphere. A fuel cell stack that generates electromotive power by supplying the air to the fuel electrode and the oxidant electrode, respectively, an electric control device that supplies the electrical energy generated by the fuel cell stack to an external load, and heat that recovers the heat generated by power generation. It has a usage system, etc. Further, as an index showing the performance of the fuel cell power generation system, the power generation efficiency defined as the power generation amount with respect to the fuel supply amount is used. That is, the higher the power generation efficiency, the more the fuel consumption can be reduced. Therefore, it is desired to improve the power generation efficiency of the fuel cell stack.

The fuel cell stack includes, for example, a plurality of fuel cell cells composed of an electrolyte membrane / electrode assembly (MEA: Membrane Electrode Assembly) formed by arranging a fuel electrode and an oxidizing agent electrode across an electrolyte membrane, and a separator. It has a laminated cell laminate. The cell laminate is tightened by a tightening plate so as to have a predetermined surface pressure. As a result, the contact resistance between the laminated bodies of the cell laminated body is reduced, and the sealing function of the laminated body is maintained. Further, in order to increase the power generation efficiency of the cell laminate, it is necessary to keep the surface pressure in the plane of the cell laminate uniform. Further, in order to reduce the size of the fuel cell power generation system, it is required to reduce the thickness and weight of the tightening plate.

Japanese Unexamined Patent Publication No. 2012-256540

However, if the tightening plate is made thinner and lighter, bending may occur when the tightening plate is fastened to the connector, and the surface pressure of the cell laminate may become non-uniform.

The problem to be solved by the present invention is to provide a fuel cell structure capable of equalizing the surface pressure of the cell laminate even if bending occurs when the tightening plate is fastened to the connector. is there.

According to the present embodiment, the fuel cell structure includes a cell laminate in which a plurality of fuel cell cells are laminated, and a cell laminate.
Two tightening plates for tightening the cell laminate from both end faces in the stacking direction of the cell laminate are provided, and each of the two tightening plates faces both end faces in the stacking direction of the cell laminate. A convex portion that is arranged and presses the cell laminate in the stacking direction and a protrusion that protrudes toward the surface of the pressing portion opposite to the surface facing the cell laminate and extends along the surface of the pressing portion. The central portion of the pressing portion on the surface side facing the cell laminate, which has a shaped beam portion, is more cell-laminated than the edge portion of the pressing portion on the surface side facing the cell laminate. It protrudes toward the body, and the pressing portion and the beam portion are integrally molded.

According to the present invention, even if bending occurs when the tightening plate is fastened to the connecting tool, the surface pressure inside the cell stack can be made uniform.

The perspective view of the fuel cell structure which concerns on 1st Embodiment. The figure which shows the fuel cell structure in the state which attached the manifold. Perspective view of the tightening plate. The figure which shows the tightening plate of the comparative example 1. FIG. The figure which shows the tightening plate of the comparative example 2. The figure which summarized the strength and shape change of the evaluated tightening plate. The figure which summarized the thickness of the base material, the strength of the tightening plate, and the shape change. The perspective view of the tightening plate which concerns on a modification. The perspective view of the tightening plate which concerns on 2nd Embodiment. A side view of the tightening plate as viewed from the A direction. A side view of the tightening plate as viewed from the B direction. 12 (a) is an enlarged view of the portion of the tightening plate shown in FIG. 3 corresponding to the partial area C of FIG. 9, and FIG. 12 (b) is an enlarged view of the partial area C of FIG. The figure which summarized the strength and shape change of the tightening plate which concerns on 1st Embodiment and the tightening plate which concerns on 2nd Embodiment. The figure which shows the tightening plate and the current terminal. The figure which shows typically the sectional view of the fuel cell structure. The figure which shows the side view of the tightening plate which concerns on 3rd embodiment. The figure which shows the region which measured the surface pressure at the boundary surface of a current collector plate and a laminated body. The figure which summarized the relationship between the step distance and the standard deviation of a surface pressure. The figure of the graph which shows the standard deviation of the surface pressure distribution in a cell laminated body. The figure which shows the power generation characteristic of a cell laminated body. The figure which shows the structure of the back surface of the tightening plate which concerns on 4th Embodiment, that is, the surface side which faces the cell laminated body. The figure which shows the process sequence of fastening a tightening plate to a connector.

Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the drawings attached to the present specification, the scale, aspect ratio, etc. are appropriately changed from those of the actual product and exaggerated for the convenience of illustration and comprehension.

(First Embodiment)
FIG. 1 is a perspective view of the fuel cell structure 1 according to the first embodiment. As shown in FIG. 1, the fuel cell structure 1 is a structure that generates electricity by an electrochemical reaction in a fuel cell. That is, the fuel cell structure 1 includes a cell laminate 10, two current collector plates 20, two insulating plates 25, and a fuel cell tightening structure 30. The cell laminate 10 is a stack of a plurality of fuel cell cells. Fuel cell cells generate electricity through an electrochemical reaction between a fuel gas containing hydrogen and air containing oxygen. That is, in the fuel cell, for example, gas is supplied to the electrolyte membrane / electrode assembly formed by arranging the fuel electrode and the oxidant electrode with the electrolyte membrane interposed therebetween, and the fuel and the oxidizer are oxidized. It has a separator having a function of separating the agent. The separator is made of, for example, a conductive porous plate having fine pores. Further, the separator has a cooling water flow path. The cooling water flow path evaporates the supplied cooling water from its surface to humidify the fuel cell. A separator having no cooling water channel may be used.

Two current collector plates 20 are arranged on both sides of the cell laminate 10 in the stacking direction. The two current collector plates 20 are plate-shaped conductors and are arranged on both end faces of the cell laminate 10. The two insulating plates 25 are plate-shaped insulators, and are arranged between the two current collecting plates 20 and the two tightening plates 100, respectively. In this way, two current collector plates 20 and two insulating plates 25 are sequentially arranged on both sides of the cell laminated body 10 in the stacking direction, and these are integrally arranged from both sides in the stacking direction. By tightening with 100, the fuel cell structure 1 can be obtained.

The fuel cell tightening structure 30 is a structure that applies surface pressure to the cell laminate 10, and is configured to include two tightening plates 100 and a plurality of connecting tools 200. The two tightening plates 100 are members that tighten the cell laminate 10 from both sides in the stacking direction of the cell laminate 10 in which a plurality of fuel cell cells are laminated. The tightening plate 100 has a pressing portion 110 and a beam portion 120. The pressing portion 110 and the beam portion 120 are integrally formed. The detailed structure of the tightening plate 100 will be described later.

The connector 200 is a member that connects the two tightening plates 100. That is, the connector 200 in the present embodiment has a tie rod 202, two washers 204, and two nuts 206. As shown in FIG. 1, the nut 206 is tightened via the washer 204 with the tie rod 202 passed through the opposing holes provided in the two tightening plates 100, and the two tightening plates 100 are connected. ing.

A manifold is mounted around the cell laminate 10 in the fuel cell structure 1 of FIG. 1. A manifold is a member provided with flow paths for fuel gas, air, and cooling water.

FIG. 2 is a diagram showing a fuel cell structure 1 with a manifold attached. The fuel cell structure 1 shown in FIG. 2 further includes a first manifold 40, a second manifold 42, a third manifold 44, and a fourth manifold 46.

The first manifold 40 has a cooling water manifold and an air gas manifold. The second manifold 42 is a fuel gas manifold. The third manifold 44 has a cooling water manifold and an air gas manifold. The fourth manifold 46 is a fuel gas manifold. The cooling water introduced from the cooling water inlet 40A is supplied from the side surface of the separator and discharged from the cooling water outlet 44A through the flow channel of the separator. On the other hand, the air gas is introduced from the air gas inlet 40B, and the air gas not consumed by the electrochemical reaction in the cell laminate 10 is discharged from the air gas outlet 40C. Further, the fuel gas is introduced from the fuel gas inlet 46A, and the fuel gas not consumed by the electrochemical reaction in the cell laminate 10 is discharged from the fuel gas outlet 46A.

The shape of the tightening plate 100 will be described with reference to FIGS. 1 and 2. FIG. 3 is a perspective view of the tightening plate 100. As shown in FIGS. 1 and 2, the pressing portion 110 is arranged to face the cell laminated body 10 and presses the cell laminated body 10 in the stacking direction. Actually, since the current collector plate 20 and the insulator 25 are arranged on both sides of the cell laminate 10 in the stacking direction, the pressing portion 110 is the cell laminate via the insulator 25 and the current collector plate 20. The body 10 will be pressed from both sides. As shown in FIG. 3, the pressing portion 110 includes partial pressing portions 110A, 110B, 110C, 110D, 110E and folded portions 112A, 112B, 112C, 112D bent in a direction intersecting the surface direction of the pressing portion 110. have. Of these, the partial pressing portion 110E is arranged on the central side of the pressing portion 110, and the partial pressing portions 110A, 110B, 110C, and 110D are arranged around the partial pressing portion 110E. The folded portions 112A, 112B, 112C, and 112D are formed by bending the edge sides of the partial pressing portions 110A, 110B, 110C, and 110D, respectively. As shown in FIG. 2, a fourth manifold 46, a first manifold 40, a second manifold 42, and a third manifold 44 are attached to the folded portions 112A, 112B, 112C, and 112D, respectively.

As shown in FIG. 3, the beam portion 120 is a convex beam that protrudes from the pressing portion 110 to the opposite side of the cell laminate 10 and extends along the surface of the pressing portion 110. The beam portion 120 has a plurality of fastening portions 122A, 122B, 122C, and 122D for fixing the plurality of connecting members 200. These plurality of fastening portions 122A, 122B, 122C, and 122D are arranged on the edge side of the beam portion 120. As can be seen from these, the two tightening plates 100 press the cell laminate 10 in the stacking direction by fixing the plurality of connecting members 200 to the plurality of fastening portions 122A, 122B, 122C, and 122D.

Further, the beam portion 120 has a plurality of convex portions 124A, 124B, 124C, 124D connecting two adjacent fastening portions among the plurality of fastening portions 122A, 122B, 122C, and 122D, and the convex portion 124A. , 124B, 124C, 124D, the convex size on the central side is formed smaller than the convex size on the fastening portion 122A, 122B, 122C, 122D side of the convex portions 124A, 124B, 124C, 124D. For example, the convex height on the central side of the convex portions 124A, 124B, 124C, 124D is lower than the convex height on the fastening portions 122A, 122B, 122C, 122D of the convex portions 124A, 124B, 124C, 124D. It is formed.

Furthermore, the convex heights are formed so as to continuously change from the fastening portion on one end side to the fastening portion on the other end side of the convex portions 124A, 124B, 124C, 124D. With such a shape, there is no possibility that the wall thickness on the central side of the convex portions 124A, 124B, 124C, and 124D becomes thin. Assuming that the convex sizes of the convex portions 124A, 124B, 124C, and 124D are the same over the entire length in the longitudinal direction, these four convex portions are closer to each other on the central side in the longitudinal direction, and thus are on the central side. The wall thickness size of is apt to be thinner than the wall thickness size on the fastening part side. When the wall thickness size is reduced, cracks are likely to occur, and the in-plane pressure for pressing the cell laminate 10 is also likely to be non-uniform. On the other hand, if the convex height on the central side is made lower than the convex height on the fastening portion side as in the present embodiment, the wall thickness size on the central side is not reduced and cracks are less likely to occur. , The in-plane pressure that presses the cell stack 10 can also be made uniform. Further, by making the convex height on the central side of the convex portions 124A, 124B, 124C, 124D lower than the convex height on the fastening portion side, the plate as a whole of the convex portions 124A, 124B, 124C, 124D. The amount of material used can be reduced and the weight can be reduced.

The convex portions 124A, 124B, 124C, and 124D are arranged outside the partial pressing portion 110E arranged in the central portion of the pressing portion 110. Further, the convex portions 124A, 124B, 124C, and 124D are arranged point-symmetrically with respect to the center position of the pressing portion 110 in the plane of the pressing portion 110. As a result, the pressing force of the cell laminate 10 is made uniform in the plane. Further, the beam portion 120 has collar portions 126A, 126B, 126C, 126D flush with the pressing portion 110 in the vicinity of the plurality of fastening portions 122A, 122B, 122C, 122D. By providing the collar portions 126A, 126B, 126C, and 126D, the contact area with the insulator 25 can be increased.

The tightening plate 100 according to the present embodiment is formed, for example, using a high-strength steel (tensile strength 400 MPa) having a thickness of 2.0 mm as a base material and undergoing a plurality of pressure pressing steps using a die. To.

As described above, the tightening plate 100 was manufactured by a plurality of pressure pressing steps using a mold, and the strength and appearance shape of the tightening plate 100 were evaluated. FIG. 4 is a diagram showing a tightening plate of Comparative Example 1 used as a reference for evaluation, and shows a perspective view of the tightening plate 100a on the front surface side and a perspective view of the tightening plate 100b on the back surface side. .. In the tightening plate of FIG. 4, the convex heights of the convex beam portions 120A are made the same along the longitudinal direction for comparison reference. FIG. 5 is a diagram showing a tightening plate of Comparative Example 2. This tightening plate is not provided with a folded portion. The structure of the convex portion in FIG. 5 is the same as that of the convex portion of the present embodiment shown in FIG. Further, a tightening plate having the same structure as the tightening plate described in Patent Document 1 was evaluated as a conventional example.

The thickness of the base material of the tightening plate 100 according to the present embodiment was changed between 1.5 and 3.5 mm, and the strength and appearance shape of the tightening plate 100 were evaluated. The material of the tightening plate 100 was high-strength steel (tensile strength 400 MPa), and it was formed through a plurality of pressure pressing steps using a die.

Next, the actions and effects of this embodiment will be described. First, the effect of the convex heights of the convex portions 124A, 124B, 124C, and 124D shown in FIG. 3 will be described. FIG. 6 is a diagram summarizing the strength and shape change of the evaluated tightening plate. As shown in FIG. 6, even if the same base material is used, the convex height of the convex beam portion is the same in the central portion and the outer peripheral portion as in the tightening plate (FIG. 4) of Comparative Example 1. Then, a crack occurs in a part. It is considered that this is because the wall thickness is insufficient when the convex beam portion is formed at the central portion in the pressure pressing process.

On the other hand, in the tightening plate 100 (Specific Example 1) according to the present embodiment shown in FIG. 3, the convex height of the beam portion is provided with a gradient, and one end side of the convex portions 124A, 124B, 124C, 124D is provided. A shape is adopted in which the convex height is continuously changed from the fastening portion to the fastening portion on the other end side, and gradually increases from the central portion to the outer peripheral portion. By adopting such a shape, the wall thickness size at the central portion is not reduced, so that the convex beam portion is not cracked.

Further, as described above, by lowering the convex height on the central side of the convex portions 124A, 124B, 124C, and 124D, the amount of the plate material constituting the beam portion 120 can be reduced, and the tightening plate 100 can be used. Can be made lighter.

Next, the actions and effects of the folded-back portions 112A, 112B, 112C, 112D (folded-back structure) of the tightening plate 100 according to the present embodiment will be described. When Comparative Example 2 (FIG. 5), which is a tightening plate having no folded portion, was fastened to the connector 200 with a predetermined tightening pressure, the boundary between the pressing portion and the beam portion was deformed.

On the other hand, when the tightening plate 100 according to the present embodiment shown in FIG. 3 was fastened to the connector 200 with the same tightening pressure as in Comparative Example 2 (FIG. 5), the deformation as in Comparative Example 2 did not occur. .. This is because the strength of the tightening plate 100 is further increased by providing the folded-back portions 112A, 112B, 112C, and 112D.

Next, the action and effect regarding the thickness of the base material of the tightening plate 100 according to the present embodiment will be described. FIG. 7 is a diagram summarizing the thickness of the base material, the strength of the tightening plate, and the shape change. As shown in FIG. 7, when a 1.5 mm meter (Comparative Example 3) having a base metal thickness of less than 2.0 mm is used, there are some places where the wall thickness is locally undersized after the integral breathing. And wrinkles occurred. On the other hand, when a base material having a thickness of more than 3.0 mm (Comparative Example 4) was used, the wall thickness distribution became non-uniform in the integral pressing process, and cracks occurred in some parts.

On the other hand, as shown in Specific Examples 1 to 4, when the base material thickness of the high-strength steel (tensile strength 400 MPa) is 2.0 mm or more and 3.0 mm or less, the appearance shape of the tightening plate 100 is wrinkled. No cracks occurred. As a result, when the base metal thickness of high-strength steel (tensile strength 400 MPa) is 2.0 mm or more and 3.0 mm or less, the tightening plate 100 is subjected to a plurality of pressure pressing steps using a die. It turns out that it is suitable for manufacturing.

As described above, according to the fuel cell tightening structure 30 according to the present embodiment, the convex height of the beam portion 120 of the tightening plate 100 is provided with a gradient so that the convex portions 124A, 124B, 124C , 124D A shape in which the convex height is continuously changed from the fastening portion on one end side to the fastening portion on the other end side, and the convex height gradually increases from the central portion in the longitudinal direction to the fastening portion side. And said. As a result, the insufficient wall thickness in the pressure pressing process of integrally molding the pressing portion 110 and the beam portion 120 can be eliminated and the weight can be reduced.

Further, the convex portions 124A, 124B, 124C, and 124D are arranged point-symmetrically with respect to the center position of the pressing portion 110 in the plane of the pressing portion 110. As a result, the surface pressure that presses the cell laminate 10 can be made more uniform.

Furthermore, the strength of the tightening plate 100 can be improved by providing the tightening plate 100 with folded portions 112A, 112B, 112C, 112D. In the present embodiment, since the tightening plate 100 having the pressing portion 110, the beam portion 120, and the folded-back portions 112A to D is integrally molded, the tightening plate 100 can be manufactured without welding, which is more than welding. Manufacturing man-hours can be reduced.

(Modification example)
FIG. 8 is a perspective view of the tightening plate according to the modified example. As shown in FIG. 8, in the tightening plate according to the modified example, the convex height of the convex body is continuously changed from the fastening portion on one end side to the fastening portion on the other end side, and the convex height is increased. It has a shape that gradually increases from the central portion to the outer peripheral portion. As a result, similarly to FIG. 3, the shortage of the wall thickness in the pressure pressing process of integrally molding the pressing portion 110 and the beam portion 120 can be eliminated and the weight can be reduced. Further, the convex shape of the beam portion 120 may have the same shape as the convex shape shown in FIG.

(Second Embodiment)
When the cell laminate 10 is tightened by the tightening plate 100 according to the first embodiment, stress is concentrated near the joint between the beam portion 120 and the folded portions 112A, 112B, 112C, 112D, and the pressing force of the pressing portion 110 If the value becomes high, cracks may occur in the vicinity of the above-mentioned joint (hereinafter referred to as a stress concentration portion). The second embodiment relieves the stress of the stress concentration portion described above.

The tightening plate 100 according to the second embodiment has the surface joining portions 300A, 300B, 300C, 300D, 300E, 300F, 300G, 300H for face-joining the flange portion and the folded portion. It is different from the tightening plate 100. The differences from the first embodiment will be described below. The same number will be assigned to the configuration equivalent to that of the first embodiment, and the description thereof will be omitted.

FIG. 9 is a perspective view of the tightening plate 100 according to the second embodiment. As shown in FIG. 9, the pressing portion 110 includes surface joining portions 300A, 300B, 300C, 300D, 300E, which face-join the flange portions 126A, 126B, 126C, 126D and the folded portions 112A, 112B, 112C, 112D. It also has 300F, 300G, and 300H.

FIG. 10 is a side view of the tightening plate 100 as viewed from the A direction. FIG. 11 is a side view of the tightening plate 100 as viewed from the B direction. As can be seen from FIGS. 10 and 11, the side views of the tightening plate 100 are substantially the same in both the A direction and the B direction. 12 (a) is an enlarged view of the portion of the tightening plate shown in FIG. 3 corresponding to the partial region C of FIG. 9, and FIG. 12 (b) is an enlarged view of the partial region C of FIG. Is.

As shown in FIGS. 9 to 12, the collar portions 126A, 126B, 126C, 126D and the folded portions 112A, 112B, 112C, 112D are surface-bonded. As a result, the joint area between the collar portions 126A, 126B, 126C, 126D and the folded portions 112A, 112B, 112C, 112D becomes wider than that in the first embodiment.

FIG. 13 is a diagram summarizing the strength and shape change of the tightening plate 100 according to the first embodiment and the tightening plate 100 according to the second embodiment. That is, the tightening plate 100 according to the first embodiment shown in FIG. 3 corresponds to the specific example 3, and the tightening plate 100 according to the second embodiment shown in FIG. 9 corresponds to the specific example 5. Here, the strength was analyzed by the finite element method.

As shown in FIG. 13, both the tightening plate 100 (Specific Example 3) according to the first embodiment and the tightening plate 100 (Specific Example 5) according to the second embodiment have cracks, wrinkles, etc. in the surface shape. Abnormal area does not occur. On the other hand, comparing the tightening plate 100 according to the first embodiment and the tightening plate 100 according to the second embodiment, the surface joint portions 300A, 300B, 300C, 300D, 300E, 300F, 300G, and 300H are provided. Therefore, the equivalent stress of the stress concentration portion is reduced by 68% from 891 MPa to 285 MPa. By providing the surface joining portions 300A, 300B, 300C, 300D, 300E, 300F, 300G, and 300H on the tightening plate 100 in this way, the stress of the stress concentration portion in the tightening plate 100 can be relaxed, and the tightening plate 100 can be relaxed. The tightening pressure can be increased.

As described above, according to the fuel cell tightening structure 30 according to the present embodiment, the flange portions 126A, 126B, 126C, 126D flush with the pressing portion 110 of the tightening plate 100, and the surfaces of the pressing portion 110. In order to provide the surface joint portions 300A, 300B, 300C, 300D, 300E, 300F, 300G, 300H for surface-joining the folded-back portions 112A, 112B, 112C, 112D bent in the directions intersecting the directions, the surface joint portions of these surface joint portions are provided. The equivalent stress can be reduced, and the strength of the tightening plate 100 can be improved.

(Third Embodiment)
In the tightening plate 100 according to the third embodiment, the central portion 110E of the pressing portion 110 on the surface side facing the cell laminate 10 is set closer to the edge portion of the pressing portion 110 on the surface side facing the cell laminate 10. It is projected toward the cell laminate 10 side. The differences from the second embodiment will be described below. The same number will be assigned to the configuration equivalent to that of the second embodiment, and the description thereof will be omitted.

FIG. 14 is a diagram showing a tightening plate 100 and a current terminal 350. As shown in FIG. 14, the partial pressing portion 110E in the central portion is provided with a current terminal 350 connected to the current collector plate 20.

FIG. 15 is a diagram schematically showing a cross-sectional view of the fuel cell structure 1. As shown in FIG. 15, the cell laminated body 10 is configured by laminating a plurality of fuel cell cells 12. The fuel cell structure 1 is configured by arranging a current collector plate 20, an insulating plate 25, and a tightening plate 100 at both ends of the cell laminate 10 and tightening them with a tie rod 202 and two nuts 206. .. The fuel cell 12 has a fuel electrode flow path plate in which a fuel electrode coated with a catalyst and an oxidant electrode are arranged at both ends of a solid polymer membrane, and a fuel electrode flow path and an oxidant electrode flow path are provided at both ends thereof. It is composed of an oxidizer electrode flow path plate. In such a fuel cell structure 1, since the electromotive force of one fuel cell is as small as about 1 V, generally 10 or more fuel cell cells 12 are laminated and electrically connected in series to obtain a high voltage output. ing.

Further, the insulating plate 25 is provided with a hole for passing the current terminal 350 to the current collector plate 20 at a position corresponding to the current terminal 350 shown in FIG. The current terminal 350 is connected to the current collector plate 20 via this hole.

FIG. 16 is a view showing a side view of the tightening plate 100 according to the third embodiment. As shown in FIG. 16, the central portion 110E on the surface side of the pressing portion 110 facing the cell laminate 10 is the partial pressing portions 110A, 110B, 110C on the surface side of the pressing portion 110 facing the cell laminate 10. It protrudes toward the cell laminate 10 side from 110D. In FIG. 16, the step distance of the central portion 110E protruding from the partial pressing portions 110A, 110B, 110C, and 110D on the surface side facing the cell laminated body 10 is defined as Δt.

In a state where the plurality of connecting members 200 are not fixed to the plurality of fastening portions 122A, 122B, 122C, 122D, the central portion 110E of the pressing portion 110 is more than the folded portion 112A, 112B, 112C, 112D of the pressing portion 110. It protrudes toward the cell laminate 10 with a size within the range of 0.6 mm to 0.7 mm.

On the other hand, in a state where the plurality of connecting members 200 are fixed to the plurality of fastening portions 122A, 122B, 122C, 122D, the partial pressing portion 110E located at the center of the pressing portion 110 facing the cell laminated body 10 , The partial pressing portions 110A, 110B, 110C, 110D around the same tighten the cell laminate 10. That is, in this case, the partial pressing portion 110E located in the center of the pressing portion 110 on the surface side facing the cell laminate 10 and the peripheral partial pressing portions 110A, 110B, 110C, 110D are both a plurality of connecting tools 200. By the tightening force of, the cell laminate 10 is pressed so as to be flush with each other, and the surface pressure becomes uniform.

As described above, the tightening plate 100 was manufactured by using a high-strength steel (tensile strength of 440 MPa) having a thickness of 2.6 mm as a base material and performing a plurality of pressure pressing steps using a die. Here, as a comparative example, a tightening plate 100 having a step distance Δt = 0.1 to 0.7 millimeter was manufactured. Further, a tightening plate having the same configuration as the tightening plate described in Patent Document 1 was evaluated as a conventional example.

As an evaluation, the surface pressure distribution of the cell laminate 10 was measured. FIG. 17 is a diagram showing a region where the surface pressure at the interface between the current collector plate 20 and the cell laminate 10 is measured. Here, as shown in FIG. 17, the surface pressures of regions 1 to 13 at the interface between the current collector plate 20 and the cell laminate 10 were measured and evaluated.

FIG. 18 is a diagram summarizing the relationship between the step distance Δt and the standard deviation of the surface pressure. FIG. 19 is a graph showing the standard deviation of the surface pressure distribution in the cell laminate 10. The horizontal axis represents the step distance Δt, and the vertical axis represents the standard deviation of the surface pressure distribution. As shown in FIGS. 18 and 19, the standard deviation of the surface pressure increases as the step distance Δt decreases. This is because the central portion of the tightening plate 100 is bent by the tightening force of the connector 200, and the pressure applied to the central portion is reduced as the step distance Δt becomes smaller. As a result, the surface pressure becomes non-uniform and causes an increase in resistance.

On the contrary, as Δt increases, the lack of surface pressure near the central portion is resolved. Therefore, by adjusting the value of Δt, the standard deviation of the surface pressure is minimized. In the tightening plate 100 according to the present embodiment, the standard deviation of the surface pressure is minimized by setting Δt within the range of 0.6 to 0.7 millimeter. This value is lower than that of the tightening plate obtained by welding the bent member shown in Conventional Example 1. That is, when the tightening plate 100 according to the present embodiment is fastened to the connector 200, the surface pressure becomes more uniform than that of a general tightening plate conventionally used. As described above, the deflection that may occur due to the weight reduction and thinning of the tightening plate 100 can be dealt with by providing a step of less than 1 mm, for example.

FIG. 20 is a diagram showing the power generation characteristics of the cell laminate 10. The vertical axis shows the average cell voltage, and the horizontal axis shows the current density. Here, the average cell voltage is the voltage average value of each single cell constituting the cell laminate 10, and the current density is the density of the current flowing through each single cell. As shown in FIG. 20, when the tightening plate 100 according to the present embodiment is fastened to the connector 200, the decrease in the average cell voltage due to the increase in the current density is the smallest in the entire range, and the power generation characteristic is the highest. Shows that is good. By making the surface pressure distribution of the cell laminate 10 uniform in this way, the power generation characteristics of the cell laminate 10 are further improved.

As described above, according to the fuel cell tightening structure 30 according to the present embodiment, the central portion 110E on the surface side of the pressing portion 110 of the tightening plate 100 facing the cell laminate 10 is the cell of the pressing portion. By projecting toward the cell laminate 10 side from the edge portion on the surface side facing the laminate, even if bending occurs when the tightening plate 110 is fastened at a predetermined pressure, it faces the cell laminate of the pressing portion 110. The pressing force of the central portion 110E on the surface side can be maintained, and the surface pressure distribution of the cell laminate 10 can be made more uniform. Therefore, the power generation characteristics of the cell laminate 10 are further improved.

(Fourth Embodiment)
The tightening plate 100 according to the fourth embodiment optimizes the tightening force of the tightening body 100 without damaging the cell laminated body 10.

The differences from the third embodiment will be described below. The same number will be assigned to the configuration equivalent to that of the third embodiment, and the description thereof will be omitted.

The configuration of the tightening plate 100 according to the fourth embodiment will be described with reference to FIGS. 9 and 22 with reference to FIGS. 21 and 22. FIG. 21 is a diagram showing a structure on the back surface of the tightening plate 100 according to the fourth embodiment, that is, on the surface side facing the cell laminate 10. FIG. 22 is a diagram showing a process sequence for fastening the tightening plate 100 to the connector 200.

As shown in FIGS. 21 and 22, the tightening plate 100 has a plurality of partial pressing portions 110A, 110B, 110C, 110D, 110E divided by the beam portion 120, and the plurality of partial pressing portions 110A, 110B, Of the 110C, 110D and 110E, the partial pressing portion 110E is arranged in the center of the pressing portion 110, and the other partial pressing portions 110A, 110B, 110C and 110D are arranged around the partial pressing portion 110E. The partial pressing portion 110E may or may not protrude toward the cell laminate 10 side as in the third embodiment, or may not protrude as in the first or second embodiment.

Further, as shown in FIGS. 9, 21 and 22, the partial pressing portions 110A, 110B, 110C, 110D and 110E are in contact with the beam portion 120. FIG. 21 is a view of the tightening body 100 viewed from the cell laminated body 10 side, and the portion of the beam portion 120 is recessed in a concave shape. The partial pressing portions 110A, 110B, 110C, 110D, and 110E are arranged so as to be in contact with the concavely recessed portions.

The surface side of the partial pressing portions 110A, 110B, 110C, 110D, and 110E facing the cell laminate 10 is flat or curved, and functions as the laminate receiving portion 400. The laminate receiving portion 400 is a portion that presses the cell laminate 10 from both sides in the lamination direction, and ideally, it is desirable that the entire end surface of the cell laminate 10 comes into surface contact with the laminate receiving portion 400. In the present embodiment, since the surfaces of the partial pressing portions 110A, 110B, 110C, 110D, and 110E on the cell laminate 10 side are flat or curved, the contact with both end surfaces of the cell laminate 10 is improved. Insulating plates 25 are arranged on both end faces of the cell laminate 10 as described above.

Further, making the surface of the partial pressing portions 110A, 110B, 110C, 110D, 110E on the cell laminate 10 side flat or curved means that there are no corners, and the cell laminate 100 is used as the tightening body 100. When the 10 is tightened, there is no risk of damaging both end surfaces of the cell laminate 10.

Further, as in the third embodiment, by projecting the partial pressing portion 110E located at the center of the pressing portion 110 toward the cell laminated body 10, the contact property with the cell laminated body 10 can be further improved. As a result, when the tightening plate 100 is bent when it is fastened, the curved surface is flattened and the influence of the bending can be reduced. The material of the tightening plate 100 according to the present embodiment is, for example, high-strength steel, galvanized plate, SUS plate, or the like.

As shown in FIG. 22, the fastening portions 122A, 122B, 122C, and 122D of the tightening plate 100 according to the present embodiment have flat surface portions 128A, 128B, 128C, and 128D. The flat surface portions 128A, 128B, 128C, and 128D are arranged around the hole portion through which the tie rod 202 is passed in the beam portion 120, and are the portions where the washer 204 contacts. If the portion in contact with the washer 204 has a curved shape, the washer 204 may be tilted on the beam portion 120 and the tie rod 202 may be tilted with respect to the cell laminate 10 at the time of tightening. If the cell laminate 10 is tightened with the tie rod 202 tilted at an angle, the tightening force of the cell laminate 10 will not be the target tightening pressure. Therefore, the function of the sealing function in the cell laminate 10 is weakened, and a gas leak may occur. Further, as the tightening surface pressure becomes smaller, the contact resistance between the fuel cell cells becomes larger, and the power generation efficiency may decrease. Further, if the cell laminate 10 is tightened with the tie rod 202 tilted at an angle, a force is applied to the washer contact portion of the tightening plate 100 in the tilted direction, and the tightening plate 100 may be damaged.

On the other hand, in the tightening plate 100 according to the present embodiment, since the flat surface portions 128A, 128B, 128C, 128D are provided at the portions where the washer 204 contacts, the washer 204 has the flat surface portions 128A, 128B, 128C, 128D. Face contact with. Therefore, the problem that the tie rod 202 is tilted with respect to the cell laminated body 10 does not occur. Therefore, according to the present embodiment, the tightening pressure of the cell laminate 10 can be increased, gas leakage can be prevented, power generation efficiency can be improved, and damage to the tightening plate 100 can be prevented.

More specifically, as shown in FIG. 22, the tie rod 202 passes through the facing holes of the tightening plate 100, and the flat surface portions 128A, 128B, 128C of the tightening plate 100 on the side opposite to the cell laminate 10 , 128D is attached by a nut 206 and a washer 204, which are fasteners. That is, the connecting tool 200 is fixed to the corresponding fastening portions 122A, 122B, 122C, 122D by fastening the fasteners 204 and 206.

Further, the tightening plate 100 according to the present embodiment has holding portions 130A, 130B, 130C, and 130D in which a part of the convex shape of the beam portion 120 is flattened. The holding portions 130A, 130B, 130C, and 130D are provided to increase the contact area with a tightening device (not shown) when fastening the tightening plate 100. The area of the holding portions 130A, 130B, 130C, and 130D may be different from the area of the contact portion on the tightening device side. For example, by making the area of the contact portion on the tightening device side larger than the area of the pressing portions 130A, 130B, 130C, 130D, the displacement between the pressing portions 130A, 130B, 130C, 130D and the contact portion on the tightening device side It will also be possible to deal with.

When the fuel cell structure 1 is fastened by the fuel cell tightening structure 30, first, the cell laminate 10 is narrowed by the two tightening plates 100. Subsequently, a predetermined pressure is applied to the tightening plate 100 by a tightening device (not shown) to temporarily fix the cell laminate 10, the current collector plate 20, the insulating plate 25, and the tightening plate 100. In this case, the holding portions 130A, 130B, 130C, and 130D of the tightening plate 100 come into contact with the tightening device. Since the holding portions 130A, 130B, 130C, and 130D are flat, and the contacting portion of the tightening device is also flat, the holding portions 130A, 130B, 130C, 130D and the tightening device are in contact with each other so that the flat surfaces overlap.

Next, the nut 206, which is a fastener, is tightened and fixed with a predetermined tightening pressure. Then, the pressure applied to the tightening plate 100 by the tightening device is reduced, and the tightening device is released from the tightening plate 100.

In the fuel cell tightening structure 30 according to the present embodiment, since the surface side of the partial pressing portions 110A, 110B, 110C, 110D, 110E facing the cell laminate 10 is flat or curved, the tightening plate 100 The contact with the cell laminate 10 is improved at the time of fastening, and the cell laminate 10 can be tightened with a desired tightening force without damaging both end surfaces of the cell laminate 10.

Further, in the present embodiment, since the flat surface portions 128A, 128B, 128C and 128D are provided on the fastening portions 122A, 122B, 122C and 122D, the washer 204 is in surface contact with the flat surface portions 128A, 128B, 128C and 128D, and the tie rod 202 is formed. There is no risk of tilting with respect to the cell laminate 10.

Furthermore, by providing the holding portions 130A, 130B, 130C, and 130D on the tightening plate 100, the contact between the tightening device and the tightening plate 100 is improved, and the cell laminate 10 is tightened by the tightening plate 100. The force can be optimized. As a result, the surface pressure of the cell laminate 10 can be made uniform.

Although some embodiments of the present invention have been described above, these embodiments are presented as examples and are not intended to limit the scope of the invention. These novel embodiments can be implemented in various other embodiments, and various omissions, replacements, and changes can be made without departing from the gist of the invention. These embodiments and variations thereof are included in the scope and gist of the invention, and are included in the scope of the invention described in the claims and the equivalent scope thereof.

1: Fuel cell structure, 10: Cell laminate, 20: Current collector plate, 25: Insulation plate 25, 30: Fuel cell tightening structure, 100: Tightening plate, 110: Pressing part, 110A to E: Part Pressing part, 112A to D: Folded part, 120: Beam part, 122A to D: Fastening part, 124A to D: Convex part, 126A to D: Flange part, 200: Connecting tool, 300A to H: Surface joining part, 350: Current terminal

Claims (8)

A cell laminate in which multiple fuel cell cells are laminated, and
Two tightening plates for tightening the cell laminate from both end faces in the stacking direction of the cell laminate are provided.
Each of the two tightening plates
A pressing portion that is arranged to face both end faces of the cell laminate in the stacking direction and presses the cell laminate in the stacking direction.
It has a convex beam portion that protrudes toward the surface of the pressing portion opposite to the surface facing the cell laminate and extends along the surface of the pressing portion.
The beam portion has a shape in which the convex height is continuously changed from the fastening portion on one end side to the fastening portion on the other end side, and gradually increases from the central portion to the outer peripheral portion.
The pressing portion has a folded portion that is bent in a direction intersecting the surface direction.
The central portion of the pressing portion on the surface side facing the cell laminate protrudes toward the cell laminate side from the edge portion of the pressing portion on the surface side facing the cell laminate.
A fuel cell structure in which the pressing portion and the beam portion are integrally molded. The fuel cell structure according to claim 1, wherein the beam portion is arranged point-symmetrically with respect to the center position of the pressing portion. A plurality of connecting tools for connecting the two tightening portions are provided.
The beam portion has a plurality of fastening portions for fixing the plurality of connecting members.
The plurality of fastening portions are arranged on the veranda side of the beam portion in the longitudinal direction.
The fuel cell structure according to claim 2, wherein the two tightening plates press the cell laminate in the stacking direction by fixing the plurality of connecting tools to the plurality of fastening portions. When the plurality of connecting tools are fixed to the plurality of fastening portions, the edge portion and the central portion of the pressing portion on the surface side facing the cell laminate both press the cell laminate in the stacking direction. , The fuel cell structure according to claim 3. When the plurality of connecting tools are not fixed to the plurality of fastening portions, the central portion of the pressing portion on the surface side facing the cell laminate is the surface side of the pressing portion facing the cell laminate. The fuel cell structure according to claim 3 or 4, which protrudes toward the cell laminate with a size within the range of 0.6 mm to 0.7 mm from the edge of the fuel cell. The pressing portion has a plurality of partial pressing portions divided by the beam portion.
One of the plurality of partial pressing portions is arranged at a location including the center position of the pressing portion.
The partial pressing portion arranged at a location including the central position of the pressing portion is closer to the cell laminate side than the other partial pressing portions when the plurality of connecting tools are not fixed to the plurality of fastening portions. The fuel cell structure according to any one of claims 3 to 5, which is protruding. The fastening portion has a flat surface portion and has a flat surface portion.
The fuel cell structure according to any one of claims 3 to 6, wherein the connecting tool is fixed to the corresponding fastening portion by fastening the fastener to the flat surface portion. A current collector plate arranged to face the end face of the cell laminate in the stacking direction,
An insulating plate arranged between the current collector plate and the tightening plate,
A current terminal connected to the current collector plate is provided.
The current terminal passes through a hole provided in the insulating plate when the two tightening portions are connected to the plurality of connecting tools, and the surface of the pressing portion facing the cell laminate. The fuel cell structure according to any one of claims 1 to 7, which is brought into contact with the central portion of the side.

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