JP6810885B2 - Rechargeable battery - Google Patents

Rechargeable battery Download PDF

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JP6810885B2
JP6810885B2 JP2016183508A JP2016183508A JP6810885B2 JP 6810885 B2 JP6810885 B2 JP 6810885B2 JP 2016183508 A JP2016183508 A JP 2016183508A JP 2016183508 A JP2016183508 A JP 2016183508A JP 6810885 B2 JP6810885 B2 JP 6810885B2
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electrode terminal
short
negative electrode
positive electrode
battery case
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JP2018049710A (en
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中山 博之
博之 中山
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02E60/10Energy storage using batteries

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Description

本発明は、二次電池に関する。 The present invention relates to a secondary battery.

リチウムイオン二次電池(リチウム二次電池)等の二次電池は、既存の電池に比べて軽量かつエネルギー密度が高いことから、近年、パソコンや携帯端末等のいわゆるポータブル電源や車両駆動用電源として用いられている。特に、軽量で高エネルギー密度が得られるリチウムイオン二次電池は、電気自動車(EV)、ハイブリッド自動車(HV)、プラグインハイブリッド自動車(PHV)等の車両の駆動用高出力電源として今後ますます普及していくことが期待されている。 Secondary batteries such as lithium-ion secondary batteries (lithium secondary batteries) are lighter and have a higher energy density than existing batteries. Therefore, in recent years, they have been used as so-called portable power sources for personal computers and mobile terminals and power sources for driving vehicles. It is used. In particular, lithium-ion secondary batteries, which are lightweight and have high energy density, will become more and more popular as high-output power sources for driving vehicles such as electric vehicles (EV), hybrid vehicles (HV), and plug-in hybrid vehicles (PHV). It is expected to continue.

二次電池、特にリチウムイオン二次電池は、その安全性、特に過充電時の安全性が高いことが求められている。リチウムイオン二次電池は、一般的に密閉型電池であり、何らかの原因で充電時に所定以上の電流が流れて過充電状態になると、電池電圧が高くなり、電池内圧の上昇や電池温度の上昇が起こる。そのため、リチウムイオン二次電池では、過充電に対して様々な安全策が講じられており、その安全策の一つは、圧力型安全機構である。 Secondary batteries, especially lithium-ion secondary batteries, are required to have high safety, especially when overcharged. Lithium-ion secondary batteries are generally sealed batteries, and if for some reason a current exceeding a specified value flows during charging and the battery becomes overcharged, the battery voltage rises, and the internal pressure of the battery rises and the battery temperature rises. Occur. Therefore, in lithium-ion secondary batteries, various safety measures are taken against overcharging, and one of the safety measures is a pressure type safety mechanism.

圧力型安全機構を備える二次電池としては、例えば、特許文献1に、電極組立体と、当該電極組立体を収容するケースと、当該ケースを密封し短絡孔を有する蓋板を含むキャップ組立体と、当該短絡孔に設けられる第1短絡板、当該蓋板から離隔した外側に当該短絡孔を覆うように設けられる第2短絡板、および当該第1短絡板と当該第2短絡板の間に設けられる第3短絡板を含む短絡部材と、を備えることを特徴とする二次電池が開示されている。当該第1短絡板は、典型的には、下方に突出するラウンド部と、当該蓋板に固定され当該ラウンド部の縁に形成された縁部とを含む反転板からなる。特許文献1に開示の二次電池において、過充電が発生して内部圧力が設定圧力より大きくなる場合、第1短絡板の下方に突出するラウンド部が、反転して上方に突出する。第1短絡板のラウンド部が反転して突出すると、第2短絡板が押し上げられて第3短絡板と接触し、短絡が誘発される。短絡が起こると、二次電池が安全に放電される。 As a secondary battery provided with a pressure type safety mechanism, for example, in Patent Document 1, a cap assembly including an electrode assembly, a case for accommodating the electrode assembly, and a lid plate for sealing the case and having a short-circuit hole. A first short-circuit plate provided in the short-circuit hole, a second short-circuit plate provided so as to cover the short-circuit hole on the outside separated from the lid plate, and between the first short-circuit plate and the second short-circuit plate. A secondary battery including a short-circuit member including a third short-circuit plate is disclosed. The first short-circuit plate typically comprises an inversion plate that includes a downwardly projecting round portion and an edge portion that is fixed to the lid plate and formed on the edge of the round portion. In the secondary battery disclosed in Patent Document 1, when overcharging occurs and the internal pressure becomes larger than the set pressure, the round portion protruding downward of the first short-circuit plate is inverted and protrudes upward. When the round portion of the first short-circuit plate is inverted and protrudes, the second short-circuit plate is pushed up and comes into contact with the third short-circuit plate, and a short circuit is induced. When a short circuit occurs, the secondary battery is safely discharged.

特開2011−154992号公報Japanese Unexamined Patent Publication No. 2011-154992

しかしながら特許文献1に記載のように、反転板を用いる場合には、反転板は、内圧上昇により反転可能な程度に柔軟性のある構造とするために、その厚さを小さくする必要がある。そのため、短絡時の電流で発熱が起きた際に、反転板が溶断するおそれがあった。 However, as described in Patent Document 1, when an inversion plate is used, the thickness of the inversion plate needs to be reduced in order to have a structure flexible enough to be inverted by an increase in internal pressure. Therefore, when heat is generated by the current at the time of short circuit, the reversing plate may be melted.

そこで本発明は、過充電時の内圧上昇により短絡を起こし得る圧力型安全機構であって、短絡時に部材の溶断が起こりにくい圧力型安全機構を備える二次電池を提供することを目的とする。 Therefore, an object of the present invention is to provide a secondary battery provided with a pressure-type safety mechanism capable of causing a short circuit due to an increase in internal pressure during overcharging, and a pressure-type safety mechanism in which members are less likely to be blown during a short circuit.

ここに開示される二次電池は、電池ケースと、前記電池ケースの一の面に設けられた、正極端子および負極端子と、短絡部材と、を備える。前記正極端子は、前記負極端子に向かって突出した正極端子突出部を有し、前記負極端子は、前記正極端子に向かって突出した負極端子突出部を有している。前記電池ケースの一の面の前記正極端子と前記負極端子との間に、前記電池ケースの内部と連通する穴部が設けられている。前記短絡部材は、摺動部と、短絡板部と、を有する。前記摺動部は、前記穴部内に配置され、前記電池ケースの内圧が上昇した際に、電池ケースの内部方向から外部方向に向かって摺動するものである。前記短絡板部は、前記正極端子突出部および前記負極端子突出部と接触可能な長さを有する。前記短絡板部は、前記摺動部が、前記電池ケースの内部方向から外部方向に向かって摺動した際に、前記正極端子突出部と前記負極端子突出部とを電気的に接続可能に配置されている。前記短絡板部は、前記正極端子突出部と前記負極端子突出部の少なくとも一方よりも溶断耐性が高い。 The secondary battery disclosed herein includes a battery case, positive electrode terminals and negative electrode terminals provided on one surface of the battery case, and a short-circuit member. The positive electrode terminal has a positive electrode terminal protruding portion protruding toward the negative electrode terminal, and the negative electrode terminal has a negative electrode terminal protruding portion protruding toward the positive electrode terminal. A hole that communicates with the inside of the battery case is provided between the positive electrode terminal and the negative electrode terminal on one surface of the battery case. The short-circuit member has a sliding portion and a short-circuit plate portion. The sliding portion is arranged in the hole portion and slides from the inside direction to the outside direction of the battery case when the internal pressure of the battery case rises. The short-circuit plate portion has a length that allows contact with the positive electrode terminal protruding portion and the negative electrode terminal protruding portion. The short-circuit plate portion is arranged so that the positive electrode terminal protruding portion and the negative electrode terminal protruding portion can be electrically connected when the sliding portion slides from the internal direction to the external direction of the battery case. Has been done. The short-circuit plate portion has higher fusing resistance than at least one of the positive electrode terminal protruding portion and the negative electrode terminal protruding portion.

このような構成によれば、圧力型安全機構となる短絡部材が、内圧の上昇に伴う摺動により短絡を引き起こすものであるため、短絡部材の短絡板部の設計の自由度が高い。その結果、短絡部材は、溶断耐性が高い短絡板部を備えるものとすることができる。よって、過充電時の内圧上昇により短絡を起こし得る圧力型安全機構であって、短絡時に部材の溶断が起こりにくい圧力型安全機構を備える二次電池を提供することができる。 According to such a configuration, since the short-circuit member serving as the pressure-type safety mechanism causes a short-circuit due to sliding due to an increase in the internal pressure, the degree of freedom in designing the short-circuit plate portion of the short-circuit member is high. As a result, the short-circuit member can be provided with a short-circuit plate portion having high fusing resistance. Therefore, it is possible to provide a secondary battery provided with a pressure-type safety mechanism that can cause a short circuit due to an increase in internal pressure during overcharging, and a pressure-type safety mechanism in which members are less likely to be blown during a short circuit.

図1(a)は本発明の第1の実施形態に係る二次電池の構成を模式的に示す上面図であり、図1(b)は図1(a)の線X−Xでの断面を模式的に示す図であり、図1(c)は図1(b)の丸枠Yの中央部を模式的に示す拡大図である。FIG. 1A is a top view schematically showing a configuration of a secondary battery according to a first embodiment of the present invention, and FIG. 1B is a cross section taken along line XX of FIG. 1A. 1 (c) is an enlarged view schematically showing the central portion of the round frame Y of FIG. 1 (b). 本発明の第1の実施形態に係る二次電池の内圧が上昇した状態を模式的に示す断面図である。It is sectional drawing which shows typically the state which the internal pressure of the secondary battery which concerns on 1st Embodiment of this invention increased. 本発明の第2の実施形態に係る二次電池の構成を模式的に示す断面図である。It is sectional drawing which shows typically the structure of the secondary battery which concerns on 2nd Embodiment of this invention. 本発明の第3の実施形態に係る二次電池の構成を模式的に示す断面図である。It is sectional drawing which shows typically the structure of the secondary battery which concerns on 3rd Embodiment of this invention. 本発明の第4の実施形態に係る二次電池の構成を模式的に示す断面図である。It is sectional drawing which shows typically the structure of the secondary battery which concerns on 4th Embodiment of this invention.

以下、図面を参照しながら、本発明による実施の形態を説明する。なお、本明細書において特に言及している事項以外の事柄であって本発明の実施に必要な事柄(例えば、本発明を特徴付けない二次電池の一般的な構成および製造プロセス)は、当該分野における従来技術に基づく当業者の設計事項として把握され得る。本発明は、本明細書に開示されている内容と当該分野における技術常識とに基づいて実施することができる。また、以下の図面においては、同じ作用を奏する部材・部位には同じ符号を付して説明している。また、各図における寸法関係(例、長さ、幅、厚さ等)は実際の寸法関係を反映するものではない。 Hereinafter, embodiments according to the present invention will be described with reference to the drawings. It should be noted that matters other than those specifically mentioned in the present specification and necessary for carrying out the present invention (for example, general configurations and manufacturing processes of secondary batteries that do not characterize the present invention) are said to be relevant. It can be grasped as a design matter of a person skilled in the art based on the prior art in the field. The present invention can be carried out based on the contents disclosed in the present specification and common general technical knowledge in the art. Further, in the following drawings, members / parts having the same action are described with the same reference numerals. In addition, the dimensional relationships (eg, length, width, thickness, etc.) in each drawing do not reflect the actual dimensional relationships.

なお、本明細書において「二次電池」とは、繰り返し充放電可能な蓄電デバイス一般をいい、いわゆる蓄電池ならびに電気二重層キャパシタ等の蓄電素子を包含する用語である。 In the present specification, the "secondary battery" generally refers to a power storage device capable of repeatedly charging and discharging, and is a term including a so-called storage battery and a power storage element such as an electric double layer capacitor.

〔第1の実施形態〕
図1は、第1の実施形態に係る二次電池100Aの構成を模式的に示す図である。図1(a)は、二次電池100Aの通常の使用状態における上面図、図1(b)は図1(a)の線X−Xでの断面図、図1(c)は図1(b)の丸枠Yの中央部を模式的に示す拡大図である。二次電池100Aは、例えば、リチウムイオン二次電池である。
[First Embodiment]
FIG. 1 is a diagram schematically showing the configuration of the secondary battery 100A according to the first embodiment. 1 (a) is a top view of the secondary battery 100A in a normal use state, FIG. 1 (b) is a sectional view taken along line XX of FIG. 1 (a), and FIG. 1 (c) is FIG. 1 (c). It is an enlarged view which shows typically the central part of the round frame Y of b). The secondary battery 100A is, for example, a lithium ion secondary battery.

図1に示されるように、二次電池100Aは、電池ケース10と、電池ケース10の一の面としての上面に、正極端子32および負極端子42とを備える。電池ケース10の上面には、正極端子32と負極端子42との間に、電池ケース10の内部と連通する穴部12が設けられている。ここで、穴部12は円形である。電池ケース10は、ここでは扁平角形の電池ケースが用いられている。電池ケース10は、例えば、アルミニウム等の軽量で熱伝導性の良い金属製である。
二次電池100Aは、電池ケース10内に、非水電解液(図示せず)を備える。非水電解液は、従来の二次電池(例、リチウムイオン二次電池)のものと同様の構成を有していてよい。例えば、非水電解液は、非水溶媒としてカーボネート系溶媒等、および支持塩としてLiPF等のリチウム塩を含んでいてよい。
二次電池100Aは、電池ケース10の内部に収容された電極体20を備える。
As shown in FIG. 1, the secondary battery 100A includes a battery case 10 and a positive electrode terminal 32 and a negative electrode terminal 42 on the upper surface as one surface of the battery case 10. On the upper surface of the battery case 10, a hole 12 communicating with the inside of the battery case 10 is provided between the positive electrode terminal 32 and the negative electrode terminal 42. Here, the hole portion 12 is circular. As the battery case 10, a flat and square battery case is used here. The battery case 10 is made of a lightweight metal having good thermal conductivity, such as aluminum.
The secondary battery 100A includes a non-aqueous electrolytic solution (not shown) in the battery case 10. The non-aqueous electrolyte solution may have the same configuration as that of a conventional secondary battery (eg, a lithium ion secondary battery). For example, the non-aqueous electrolytic solution may contain a carbonate-based solvent or the like as the non-aqueous solvent and a lithium salt such as LiPF 6 as the supporting salt.
The secondary battery 100A includes an electrode body 20 housed inside the battery case 10.

電極体20においては、正極30と負極40とが積層されている。正極30と負極40とはセパレータ(図示せず)を介して絶縁されている。電極体20は、複数の正極シートと複数の負極シートと複数のセパレータとが積層された積層型電極体であってもよく、1枚の正極シートと1枚の負極シートと2枚のセパレータとが積層され捲回された捲回型電極体であってもよい。
正極30は、従来の二次電池(例、リチウムイオン二次電池)のものと同様の構成を有していてよい。例えば、正極30は、アルミニウム箔等の正極集電体上に、リチウム遷移金属複合酸化物等を正極活物質として含む正極活物質層が設けられた構成であってよい。
負極40は、従来の二次電池(例、リチウムイオン二次電池)のものと同様の構成を有していてよい。例えば、負極40は、銅箔等の負極集電体上に、黒鉛等を負極活物質として含む負極活物質層が設けられた構成であってよい。
セパレータは、従来の二次電池(例、リチウムイオン二次電池)のものと同様の構成を有していてよい。例えば、セパレータは、多孔質ポリオレフィン樹脂シートであってよい。
In the electrode body 20, the positive electrode 30 and the negative electrode 40 are laminated. The positive electrode 30 and the negative electrode 40 are insulated via a separator (not shown). The electrode body 20 may be a laminated electrode body in which a plurality of positive electrode sheets, a plurality of negative electrode sheets, and a plurality of separators are laminated, and one positive electrode sheet, one negative electrode sheet, and two separators. May be a wound electrode body in which is laminated and wound.
The positive electrode 30 may have the same configuration as that of a conventional secondary battery (eg, a lithium ion secondary battery). For example, the positive electrode 30 may have a configuration in which a positive electrode active material layer containing a lithium transition metal composite oxide or the like as a positive electrode active material is provided on a positive electrode current collector such as an aluminum foil.
The negative electrode 40 may have the same configuration as that of a conventional secondary battery (eg, a lithium ion secondary battery). For example, the negative electrode 40 may have a configuration in which a negative electrode active material layer containing graphite or the like as a negative electrode active material is provided on a negative electrode current collector such as a copper foil.
The separator may have the same configuration as that of a conventional secondary battery (eg, a lithium ion secondary battery). For example, the separator may be a porous polyolefin resin sheet.

電極体20において、水平方向の一方の端部(図1(b)の左端)には正極30の集電部が設けられており、正極30の集電部は、正極集電端子34を介して正極端子32と電気的に接続されている。同様に、電極体20において、水平方向の他方の端部(図1(b)の右端)には負極40の集電部が設けられており、負極40の集電部は、負極集電端子44を介して負極端子42と電気的に接続されている。 In the electrode body 20, a current collecting portion of the positive electrode 30 is provided at one end in the horizontal direction (the left end of FIG. 1B), and the current collecting portion of the positive electrode 30 passes through the positive electrode current collecting terminal 34. Is electrically connected to the positive electrode terminal 32. Similarly, in the electrode body 20, a current collecting portion of the negative electrode 40 is provided at the other end (right end of FIG. 1B) in the horizontal direction, and the current collecting portion of the negative electrode 40 is a negative electrode current collecting terminal. It is electrically connected to the negative electrode terminal 42 via 44.

正極端子32と電池ケース10との間には正極絶縁材63が配置されており、正極絶縁材63によって、正極端子32と電池ケース10とが絶縁されている。負極端子42と電池ケース10との間には負極絶縁材64が配置されており、負極絶縁材64によって、負極端子42と電池ケース10とが絶縁されている。
正極端子32は、負極端子42に向かって突出した正極端子突出部32aを有する。同様に、負極端子42は、正極端子32に向かって突出した負極端子突出部42aを有する。
A positive electrode insulating material 63 is arranged between the positive electrode terminal 32 and the battery case 10, and the positive electrode insulating material 63 insulates the positive electrode terminal 32 and the battery case 10. A negative electrode insulating material 64 is arranged between the negative electrode terminal 42 and the battery case 10, and the negative electrode insulating material 64 insulates the negative electrode terminal 42 and the battery case 10.
The positive electrode terminal 32 has a positive electrode terminal protruding portion 32a protruding toward the negative electrode terminal 42. Similarly, the negative electrode terminal 42 has a negative electrode terminal projecting portion 42a protruding toward the positive electrode terminal 32.

二次電池100Aは、短絡部材50Aを備える。短絡部材50Aは、摺動部となる摺動部材52Aと、短絡板部となる短絡板54Aとを備える。摺動部材52Aは、円柱形状を有している。
摺動部材52Aは、電池ケース10の上面に設けられた穴部12に挿入されることにより、穴部12内に配置されている。二次電池100Aが完全に密閉されるように、穴部12には、シール材56Aが装着されている。また、摺動部材54Aは、シール材56Aの形状に適合する形状の溝を有し、シール材56Aは当該溝に勘合されている。シール材56Aは、摺動部材52Aと穴部12との間の空隙を確実に埋めるためのものであり、また、電池ケース10の内圧が所定圧力以上に上昇した際の摺動を容易にするためものである。特に、シール材56Aの材質、寸法等を選択することにより、摺動が開始される内圧を容易に調節することが可能である。
なお、摺動部材52Aにシール材56Aが装着されていてもよい。また、二次電池100Aが摺動部材52Aによって完全に密閉される場合には、シール材56Aを使用しない態様も可能である。
二次電池100Aの電池ケース10の内部であって穴部12の周囲には、短絡部材50Aを所定の高さに保持するための保持部材80が設けられている。二次電池100Aの通常使用時には、短絡部材50Aの摺動部材52Aは、保持部材に接して保持されている。
摺動部材52Aは、電池ケース10の内圧が上昇した際、電池ケース10の内部方向から外部方向に向かって摺動する。すなわち、図1(b)において摺動部材52Aは上方に摺動する。
The secondary battery 100A includes a short-circuit member 50A. The short-circuit member 50A includes a sliding member 52A that serves as a sliding portion and a short-circuit plate 54A that serves as a short-circuit plate portion. The sliding member 52A has a cylindrical shape.
The sliding member 52A is arranged in the hole portion 12 by being inserted into the hole portion 12 provided on the upper surface of the battery case 10. A sealing material 56A is attached to the hole 12 so that the secondary battery 100A is completely sealed. Further, the sliding member 54A has a groove having a shape that matches the shape of the sealing material 56A, and the sealing material 56A is fitted into the groove. The sealing material 56A is for surely filling the gap between the sliding member 52A and the hole 12, and facilitates sliding when the internal pressure of the battery case 10 rises above a predetermined pressure. It is a purpose. In particular, by selecting the material, dimensions, etc. of the sealing material 56A, it is possible to easily adjust the internal pressure at which sliding is started.
The sealing material 56A may be attached to the sliding member 52A. Further, when the secondary battery 100A is completely sealed by the sliding member 52A, the sealing material 56A may not be used.
A holding member 80 for holding the short-circuit member 50A at a predetermined height is provided around the hole 12 inside the battery case 10 of the secondary battery 100A. During normal use of the secondary battery 100A, the sliding member 52A of the short-circuit member 50A is held in contact with the holding member.
When the internal pressure of the battery case 10 rises, the sliding member 52A slides from the inside direction to the outside direction of the battery case 10. That is, in FIG. 1B, the sliding member 52A slides upward.

短絡板54Aは、正極端子突出部32aおよび負極端子突出部42aと接触可能な長さを有する。また、短絡板54Aの上面の短辺方向(すなわち幅方向)の寸法は、同方向の正極端子突出部32aおよび負極端子突出部42aの寸法と同じであるか大きい。しかしながら短絡板54Aのこの寸法は、最終的に短絡板54Aの溶断耐性が正極端子突出部32aと負極端子突出部42aとの少なくとも一方より高ければ、必ずしも同方向の正極端子突出部32aおよび負極端子突出部42aの寸法と同等以上である必要はない。
短絡板54Aは、導電性材料で形成されている。
短絡板54Aは、正極端子突出部32aと負極端子突出部42aの少なくとも一方よりも溶断耐性が高い。言い換えると、所定の高電流値で電流を流した場合に、短絡板54Aの溶断は、正極端子突出部32aと負極端子突出部42aの少なくとも一方の溶断よりも遅く起きる。
第1の実施形態では、図1(b)に示すように、短絡板54Aは、正極端子突出部32aの電池ケース10の上面に垂直な方向の寸法および負極端子突出部42aの電池ケース10の上面に垂直な方向の寸法よりも大きい厚さを有している。図1(b)では、正極端子突出部32aの電池ケース10の上面に垂直な方向の寸法は、正極端子突出部32aの厚さであり、負極端子突出部42aの電池ケース10の上面に垂直な方向の寸法は、負極端子突出部42aの厚さである。
このように短絡板54Aの厚さを大きくすることにより、短絡板54Aは、正極端子突出部32aおよび負極端子突出部42aよりも溶断耐性が高くなっている。短絡板54Aの溶断耐性が、正極端子突出部32aまたは負極端子突出部42aの一方のみよりも高くなるような寸法設計にすることも可能である。
なお、短絡板54Aの溶断耐性を、正極端子突出部32aと負極端子突出部42aの少なくとも一方よりも高くする方法は上記に限られない。例えば、短絡板54Aに、正極端子突出部32aと負極端子突出部42aの少なくとも一方よりも電気抵抗の低い導電性材料を用いて、短絡板54Aの溶断耐性を正極端子突出部32aと負極端子突出部42aの少なくとも一方よりも高くしてもよい。また、例えば、短絡板54Aに、正極端子突出部32aと負極端子突出部42aとの少なくとも一方よりも融点の高い導電性材料を用いて、短絡板54Aの溶断耐性を正極端子突出部32aと負極端子突出部42aの少なくとも一方よりも高くしてもよい。
The short-circuit plate 54A has a length that allows contact with the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a. Further, the dimensions of the upper surface of the short-circuit plate 54A in the short side direction (that is, the width direction) are the same as or larger than the dimensions of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a in the same direction. However, this dimension of the short-circuit plate 54A does not necessarily mean that the positive electrode terminal protrusion 32a and the negative electrode terminal in the same direction are required if the fusing resistance of the short-circuit plate 54A is higher than at least one of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a. It does not have to be equal to or larger than the size of the protrusion 42a.
The short circuit plate 54A is made of a conductive material.
The short-circuit plate 54A has higher fusing resistance than at least one of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a. In other words, when a current is passed at a predetermined high current value, the short-circuit plate 54A is blown later than at least one of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a.
In the first embodiment, as shown in FIG. 1B, the short-circuit plate 54A has dimensions in the direction perpendicular to the upper surface of the battery case 10 of the positive electrode terminal protrusion 32a and the battery case 10 of the negative electrode terminal protrusion 42a. It has a thickness larger than the dimension in the direction perpendicular to the upper surface. In FIG. 1B, the dimension of the positive electrode terminal protrusion 32a in the direction perpendicular to the upper surface of the battery case 10 is the thickness of the positive electrode terminal protrusion 32a and perpendicular to the upper surface of the battery case 10 of the negative electrode terminal protrusion 42a. The dimension in the above direction is the thickness of the negative electrode terminal protrusion 42a.
By increasing the thickness of the short-circuit plate 54A in this way, the short-circuit plate 54A has higher fusing resistance than the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a. It is also possible to design the dimensions so that the fusing resistance of the short-circuit plate 54A is higher than that of only one of the positive electrode terminal protrusion 32a or the negative electrode terminal protrusion 42a.
The method of increasing the fusing resistance of the short-circuit plate 54A to be higher than at least one of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a is not limited to the above. For example, the short-circuit plate 54A is made of a conductive material having a lower electrical resistance than at least one of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a, and the short-circuit plate 54A is made to have a fusing resistance of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion. It may be higher than at least one of the portions 42a. Further, for example, the short-circuit plate 54A is made of a conductive material having a melting point higher than at least one of the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a to improve the fusing resistance of the short-circuit plate 54A between the positive electrode terminal protrusion 32a and the negative electrode. It may be higher than at least one of the terminal protrusions 42a.

電池ケース10の上面には、正極端子32の両側に正極堅壁73が設けられており、かつ負極端子42の両側に負極堅壁74が設けられている。正極堅壁73および負極堅壁74により、短絡板54Aの回転が防止され、よって短絡板54Aの位置が調整されている。また、電池ケース10の内圧が上昇して、摺動部材52Aが電池ケース10の内部方向から外部方向に向かって摺動した際に、短絡板54Aは、正極端子突出部32aと負極端子突出部42aとを電気的に接続可能に配置されている。このような配置は、正極端子32の外形と寸法と位置、負極端子42の外形と寸法と位置、および短絡部材50Aの寸法と位置を適切に設定することにより実現されている。 On the upper surface of the battery case 10, positive electrode hard walls 73 are provided on both sides of the positive electrode terminal 32, and negative electrode hard walls 74 are provided on both sides of the negative electrode terminal 42. The positive electrode hard wall 73 and the negative electrode hard wall 74 prevent the short-circuit plate 54A from rotating, thereby adjusting the position of the short-circuit plate 54A. Further, when the internal pressure of the battery case 10 rises and the sliding member 52A slides from the internal direction to the external direction of the battery case 10, the short-circuit plate 54A has the positive electrode terminal protruding portion 32a and the negative electrode terminal protruding portion. It is arranged so that it can be electrically connected to 42a. Such an arrangement is realized by appropriately setting the outer shape, size and position of the positive electrode terminal 32, the outer shape, size and position of the negative electrode terminal 42, and the size and position of the short-circuit member 50A.

図2は、例えば過充電等によって二次電池100Aの内圧が異常に上昇した状態を模式的に示す断面図である。二次電池100Aの電池ケース10の内圧の上昇により、短絡部材50Aの摺動部材52Aは上方に摺動し、短絡板54Aが正極端子突出部32aおよび負極端子突出部42aと接触した状態にある。このため、正極端子突出部32aと負極端子突出部42aとが電気的に接続される。この結果、図2の矢印に示される電流経路が形成され、短絡が引き起こされる。 FIG. 2 is a cross-sectional view schematically showing a state in which the internal pressure of the secondary battery 100A is abnormally increased due to, for example, overcharging. Due to the increase in the internal pressure of the battery case 10 of the secondary battery 100A, the sliding member 52A of the short-circuit member 50A slides upward, and the short-circuit plate 54A is in contact with the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a. .. Therefore, the positive electrode terminal protruding portion 32a and the negative electrode terminal protruding portion 42a are electrically connected. As a result, the current path shown by the arrow in FIG. 2 is formed, causing a short circuit.

このようにして、二次電池100Aの内圧が上昇した際に、短絡部材50Aの作用によって、短絡を引き起こすことができ、短絡部材50Aは、圧力型安全機構として機能する。ここで、従来技術においては、短絡板となる反転板の厚さが小さいことに起因して、短絡時の電流で発熱が起きた際に、反転板が溶断するおそれがあるという問題がある。しかしながら、二次電池100Aの圧力型安全機構となる短絡部材50Aが、内圧の上昇に伴う摺動により短絡を引き起こすものであるため、短絡部材50Aの短絡板部である短絡板54Aの設計の自由度が高い。その結果、短絡部材50Aは、溶断耐性が高い短絡板部を備えるものとすることができる。
以上のようにして、二次電池100Aは、過充電時の内圧上昇により短絡を起こし得る圧力型安全機構であって、短絡時に部材の溶断が起こりにくい圧力型安全機構を備える二次電池として構成されている。
In this way, when the internal pressure of the secondary battery 100A rises, a short circuit can be caused by the action of the short circuit member 50A, and the short circuit member 50A functions as a pressure type safety mechanism. Here, in the prior art, there is a problem that the reversing plate may be melted when heat is generated by the current at the time of short circuit due to the small thickness of the reversing plate serving as the short-circuit plate. However, since the short-circuit member 50A, which is the pressure-type safety mechanism of the secondary battery 100A, causes a short circuit due to sliding due to an increase in the internal pressure, the design of the short-circuit plate 54A, which is the short-circuit plate portion of the short-circuit member 50A, is free. The degree is high. As a result, the short-circuit member 50A can be provided with a short-circuit plate portion having high fusing resistance.
As described above, the secondary battery 100A is a pressure-type safety mechanism capable of causing a short circuit due to an increase in internal pressure during overcharging, and is configured as a secondary battery provided with a pressure-type safety mechanism in which members are unlikely to be blown during a short circuit. Has been done.

以下、第1の実施形態を変形した別の実施形態について説明する。以下、説明する別の実施形態においては、第1の実施形態とは短絡部材のみが異なるため、短絡部材以外の説明については省略する。 Hereinafter, another embodiment obtained by modifying the first embodiment will be described. In another embodiment described below, only the short-circuit member is different from the first embodiment, and therefore description other than the short-circuit member will be omitted.

〔第2の実施形態〕
図3に、第2の実施形態の二次電池100Bの構成を模式的に示す。二次電池100Bは、短絡部材50Bを備え、短絡部材50Bは、摺動部となる摺動部材52Bと、短絡板部となる短絡板54Bとを備えている。二次電池100Bは、シール材56Bを備える。あるいは摺動部材52Bは、シール材56Bを備える。摺動部材52Bは、球状形状を有し、この点が第1の実施形態のものとは異なっている。
第2の実施形態の球状形状の摺動部材52Bは、第1の実施形態の円柱形状の摺動部材52Aと同様に、電池ケース10の上昇した圧力を受けて、穴部を摺動して上昇することができる。これにより、短絡板54Bが正極端子突出部32aと負極端子突出部42aとを電気的に接続可能であり、短絡部材50Bは圧力型安全機構として機能し得る。
このように、短絡部材の摺動部材の形状は、電池ケース内の上昇した圧力を受けて、摺動部材が穴部を摺動して上昇することができるものである限り、短絡部材が圧力型安全機構として機能し得るので、特に限定されない。
以上のようにして、二次電池100Bは、過充電時の内圧上昇により短絡を起こし得る圧力型安全機構であって、短絡時に部材の溶断が起こりにくい圧力型安全機構を備える二次電池として構成されている。
[Second Embodiment]
FIG. 3 schematically shows the configuration of the secondary battery 100B of the second embodiment. The secondary battery 100B includes a short-circuit member 50B, and the short-circuit member 50B includes a sliding member 52B as a sliding portion and a short-circuit plate 54B as a short-circuit plate portion. The secondary battery 100B includes a sealing material 56B. Alternatively, the sliding member 52B includes a sealing material 56B. The sliding member 52B has a spherical shape, which is different from that of the first embodiment.
Similar to the cylindrical sliding member 52A of the first embodiment, the spherical sliding member 52B of the second embodiment slides in the hole portion in response to the increased pressure of the battery case 10. Can rise. As a result, the short-circuit plate 54B can electrically connect the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a, and the short-circuit member 50B can function as a pressure-type safety mechanism.
As described above, the shape of the sliding member of the short-circuit member is such that the short-circuit member is under pressure as long as the sliding member can slide and rise in the hole in response to the increased pressure in the battery case. Since it can function as a mold safety mechanism, it is not particularly limited.
As described above, the secondary battery 100B is a pressure-type safety mechanism capable of causing a short circuit due to an increase in internal pressure during overcharging, and is configured as a secondary battery provided with a pressure-type safety mechanism in which members are unlikely to be blown during a short circuit. Has been done.

〔第3の実施形態〕
図4に、第3の実施形態の二次電池100Cの構成を模式的に示す。二次電池100Cは、短絡部材50Cを備える。短絡部材50Cは、単一部品として構成されており、摺動部52Cと、短絡板部54Cとを有している。二次電池100Cは、シール材56Cを備える。あるいは摺動部52Cは、シール材56Cを備える。第3の実施形態の短絡部材50Cは、第1の実施形態に対しては、摺動部材および短絡板が一体化して単一部品として形成されている点で異なっている。
このような構成でも、電池ケース10の上昇した圧力を受けて、短絡部材50Cは、穴部を摺動して上昇し、短絡板部54Cが正極端子突出部32aと負極端子突出部42aとを電気的に接続可能である。よって、短絡部材50Cは、圧力型安全機構として機能し得る。
このように短絡部材は、摺動部と短絡板部が別々の部材で作製されていなくてもよい。
以上のようにして、二次電池100Cは、過充電時の内圧上昇により短絡を起こし得る圧力型安全機構であって、短絡時に部材の溶断が起こりにくい圧力型安全機構を備える二次電池として構成されている。
なお、二次電池の用途としては車両の駆動用電源がある。車両の駆動用電源に二次電池が用いられた場合には、車両の振動により、二次電池は上下動する。車両の振動により二次電池が上下動する場合には、短絡部材の短絡板部が振動しやすい。短絡板部の振動が非常に大きい場合には、短絡板部が正極端子突出部および負極端子突出部と接触し、圧力型安全機構の誤作動が発生するおそれがある。
しかしながら、第3の実施形態では、短絡部材50Cが単一部品として構成されることにより、二次電池100Cが上下動する際の短絡部材50Cの短絡板部54Cの振動が抑えられている。このため、第3の実施形態では、圧力型安全機構の誤作動が起こりにくいという利点がある。
[Third Embodiment]
FIG. 4 schematically shows the configuration of the secondary battery 100C of the third embodiment. The secondary battery 100C includes a short-circuit member 50C. The short-circuit member 50C is configured as a single component, and has a sliding portion 52C and a short-circuit plate portion 54C. The secondary battery 100C includes a sealing material 56C. Alternatively, the sliding portion 52C includes a sealing material 56C. The short-circuit member 50C of the third embodiment is different from the first embodiment in that the sliding member and the short-circuit plate are integrally formed as a single component.
Even in such a configuration, the short-circuit member 50C slides up in the hole portion in response to the increased pressure of the battery case 10, and the short-circuit plate portion 54C connects the positive electrode terminal protrusion 32a and the negative electrode terminal protrusion 42a. It can be electrically connected. Therefore, the short-circuit member 50C can function as a pressure-type safety mechanism.
As described above, in the short-circuit member, the sliding portion and the short-circuit plate portion do not have to be made of separate members.
As described above, the secondary battery 100C is a pressure-type safety mechanism capable of causing a short circuit due to an increase in internal pressure during overcharging, and is configured as a secondary battery provided with a pressure-type safety mechanism in which members are unlikely to be blown during a short circuit. Has been done.
The secondary battery is used as a power source for driving a vehicle. When a secondary battery is used as a power source for driving a vehicle, the secondary battery moves up and down due to the vibration of the vehicle. When the secondary battery moves up and down due to the vibration of the vehicle, the short-circuit plate portion of the short-circuit member tends to vibrate. If the vibration of the short-circuit plate portion is very large, the short-circuit plate portion may come into contact with the positive electrode terminal protrusion and the negative electrode terminal protrusion, and the pressure type safety mechanism may malfunction.
However, in the third embodiment, the short-circuit member 50C is configured as a single component, so that the vibration of the short-circuit plate portion 54C of the short-circuit member 50C when the secondary battery 100C moves up and down is suppressed. Therefore, in the third embodiment, there is an advantage that the pressure type safety mechanism is less likely to malfunction.

〔第4の実施形態〕
図5に、第4の実施形態の二次電池100Dの構成を模式的に示す。二次電池100Dは、短絡部材50Dを備え、短絡部材50Dは、摺動部となる摺動部材52Dと、支持部材58Dと、短絡板部となる2枚の短絡板54Dとを備えている。二次電池100Dは、シール材56Dを備える。あるいは摺動部材52Dは、シール材56Dを備える。支持部材58Dは、摺動部材52Dに取り付けられ、支持部材58D上に2枚の短絡板54Dが離れて設置されている。2枚の短絡板54D間は、支持部材58Dにより電気的に接続されている。支持部材58Dおよび短絡板54Dは、正極端子突出部32aと負極端子突出部42aのいずれか一方よりも溶断耐性が高い。
このような構成でも、電池ケース10の上昇した圧力を受けて、摺動部材52Dは、穴部を摺動して上昇し、2枚の短絡板54Dが正極端子突出部32aと負極端子突出部42aとを電気的に接続可能である。よって、短絡部材50Dは、圧力型安全機構として機能し得る。
このように短絡部材は、短絡板と短絡板以外の部材を含んでいてもよい。
以上のようにして、二次電池100Dは、過充電時の内圧上昇により短絡を起こし得る圧力型安全機構であって、短絡時に部材の溶断が起こりにくい圧力型安全機構を備える二次電池として構成されている。
なお、二次電池の用途としては車両の駆動用電源がある。車両の駆動用電源に二次電池が用いられた場合には、車両の振動により、二次電池は上下動する。車両の振動により二次電池が上下動する場合には、短絡部材の短絡板が振動しやすい。短絡板の振動が非常に大きい場合には、短絡板が正極端子突出部および負極端子突出部と接触し、圧力型安全機構の誤作動が発生するおそれがある。
しかしながら、第4の実施形態では、短絡板を2枚の短絡板54Dに分けた構成とすることにより、二次電池100Dが上下動する際の短絡部材50Dの短絡板54Dの振動が抑えられている。このため、第4の実施形態では、圧力型安全機構の誤作動が起こりにくいという利点がある。
[Fourth Embodiment]
FIG. 5 schematically shows the configuration of the secondary battery 100D of the fourth embodiment. The secondary battery 100D includes a short-circuit member 50D, and the short-circuit member 50D includes a sliding member 52D as a sliding portion, a support member 58D, and two short-circuit plates 54D as short-circuit plate portions. The secondary battery 100D includes a sealing material 56D. Alternatively, the sliding member 52D includes a sealing material 56D. The support member 58D is attached to the sliding member 52D, and two short-circuit plates 54D are separately installed on the support member 58D. The two short-circuit plates 54D are electrically connected by a support member 58D. The support member 58D and the short-circuit plate 54D have higher fusing resistance than either the positive electrode terminal protrusion 32a or the negative electrode terminal protrusion 42a.
Even in such a configuration, the sliding member 52D slides up in the hole portion in response to the increased pressure of the battery case 10, and the two short-circuit plates 54D have the positive electrode terminal protruding portion 32a and the negative electrode terminal protruding portion. It can be electrically connected to 42a. Therefore, the short-circuit member 50D can function as a pressure-type safety mechanism.
As described above, the short-circuit member may include a short-circuit plate and a member other than the short-circuit plate.
As described above, the secondary battery 100D is a pressure-type safety mechanism capable of causing a short circuit due to an increase in internal pressure during overcharging, and is configured as a secondary battery provided with a pressure-type safety mechanism in which members are unlikely to be blown during a short circuit. Has been done.
The secondary battery is used as a power source for driving a vehicle. When a secondary battery is used as a power source for driving a vehicle, the secondary battery moves up and down due to the vibration of the vehicle. When the secondary battery moves up and down due to the vibration of the vehicle, the short-circuit plate of the short-circuit member tends to vibrate. If the vibration of the short-circuit plate is very large, the short-circuit plate may come into contact with the positive electrode terminal protrusion and the negative electrode terminal protrusion, and the pressure type safety mechanism may malfunction.
However, in the fourth embodiment, by dividing the short-circuit plate into two short-circuit plates 54D, vibration of the short-circuit plate 54D of the short-circuit member 50D when the secondary battery 100D moves up and down is suppressed. There is. Therefore, in the fourth embodiment, there is an advantage that the pressure type safety mechanism is less likely to malfunction.

以上、本発明の具体例を詳細に説明したが、これらは例示にすぎず、請求の範囲を限定するものではない。請求の範囲に記載の技術には、以上に例示した具体例を様々に変形、変更したものが含まれる。 Although specific examples of the present invention have been described in detail above, these are merely examples and do not limit the scope of claims. The techniques described in the claims include various modifications and modifications of the specific examples illustrated above.

10 電池ケース
12 穴部
20 電極体
30 正極
32 正極端子
32a 正極端子突出部
34 正極集電端子
40 負極
42 負極端子
42a 負極端子突出部
44 負極集電端子
50A,50B,50C,50D 短絡部材
52A,52B,52D 摺動部材
52C 摺動部
54A,54B,54D 短絡板
54C 短絡板部
56A,56B,56C,56D シール材
58D 支持部材
63 正極絶縁材
64 負極絶縁材
73 正極堅壁
74 負極堅壁
80 保持部材
100A,100B,100C,100D 二次電池
10 Battery case 12 Hole 20 Electrode body 30 Positive electrode 32 Positive electrode terminal 32a Positive electrode terminal protruding part 34 Positive current collecting terminal 40 Negative electrode 42 Negative electrode terminal 42a Negative electrode terminal protruding part 44 Negative electrode current collecting terminal 50A, 50B, 50C, 50D Short circuit member 52A, 52B, 52D Sliding member 52C Sliding part 54A, 54B, 54D Short-circuit plate 54C Short-circuit plate part 56A, 56B, 56C, 56D Sealing material 58D Support member 63 Positive electrode insulating material 64 Negative electrode insulating material 73 Positive electrode hard wall 74 Negative electrode hard wall 80 Holding member 100A, 100B, 100C, 100D secondary battery

Claims (4)

電池ケースと、
前記電池ケースの一の面に設けられた、正極端子および負極端子と、
短絡部材と、
を備える二次電池であって、
前記正極端子は、前記負極端子に向かって突出した正極端子突出部を有し、
前記負極端子は、前記正極端子に向かって突出した負極端子突出部を有し、
前記正極端子と前記電池ケースとの間には正極絶縁材が配置されて、前記正極絶縁材によって、前記正極端子と前記電池ケースとが絶縁されており、
前記負極端子と前記電池ケースとの間には負極絶縁材が配置されて、前記負極絶縁材によって、前記負極端子と前記電池ケースとが絶縁されており、
前記電池ケースの一の面の前記正極端子と前記負極端子との間に、前記電池ケースの内部と連通する穴部が設けられており、
前記短絡部材は、摺動部と、短絡板部と、を有し、
前記摺動部は、前記穴部内に配置され、前記電池ケースの内圧が上昇した際に、電池ケースの内部方向から外部方向に向かって摺動するものであり、
前記短絡板部は、前記正極端子突出部および前記負極端子突出部と接触可能な長さを有し、
前記短絡板部は、前記摺動部が、前記電池ケースの内部方向から外部方向に向かって摺動した際に、前記正極端子突出部と前記負極端子突出部とを電気的に接続可能に配置されており、
前記短絡板部は、前記正極端子突出部と前記負極端子突出部の少なくとも一方よりも溶断耐性が高く、
前記電池ケースの内圧が上昇した際に、前記短絡板部が、前記正極端子突出部および前記負極端子突出部と接触して、前記正極端子突出部と前記負極端子突出部とが電気的に接続される、
ことを特徴とする二次電池。
Battery case and
A positive electrode terminal and a negative electrode terminal provided on one surface of the battery case,
Short-circuit member and
It is a secondary battery equipped with
The positive electrode terminal has a positive electrode terminal projecting portion protruding toward the negative electrode terminal.
The negative electrode terminal has a negative electrode terminal projecting portion protruding toward the positive electrode terminal.
A positive electrode insulating material is arranged between the positive electrode terminal and the battery case, and the positive electrode insulating material insulates the positive electrode terminal and the battery case.
A negative electrode insulating material is arranged between the negative electrode terminal and the battery case, and the negative electrode insulating material insulates the negative electrode terminal and the battery case.
A hole communicating with the inside of the battery case is provided between the positive electrode terminal and the negative electrode terminal on one surface of the battery case.
The short-circuit member has a sliding portion and a short-circuit plate portion.
The sliding portion is arranged in the hole portion and slides from the inside direction to the outside direction of the battery case when the internal pressure of the battery case rises.
The short-circuit plate portion has a length that allows contact with the positive electrode terminal protrusion and the negative electrode terminal protrusion.
The short-circuit plate portion is arranged so that the positive electrode terminal protruding portion and the negative electrode terminal protruding portion can be electrically connected when the sliding portion slides from the internal direction to the external direction of the battery case. Has been
The short plate portion, said at least one fusing resistance than the positive terminal protrusion of the negative electrode terminal protrusions rather high,
When the internal pressure of the battery case rises, the short-circuit plate portion comes into contact with the positive electrode terminal protrusion and the negative electrode terminal protrusion, and the positive electrode terminal protrusion and the negative electrode terminal protrusion are electrically connected. Be done,
A secondary battery characterized by that.
前記短絡板部の上面の短辺方向の寸法である幅方向の寸法は、同方向の前記正極端子突出部および前記負極端子突出部の寸法と同じであるか大きく、
前記短絡板部の上面に垂直な方向の寸法である厚さは、前記正極端子突出部の電池ケースの上面に垂直な方向の寸法および前記負極端子突出部の電池ケースの上面に垂直な方向の寸法よりも大きい、請求項1に記載の二次電池。
The width direction, which is the short-side dimension of the upper surface of the short-circuit plate portion, is the same as or larger than the dimensions of the positive electrode terminal protrusion and the negative electrode terminal protrusion in the same direction.
The thickness, which is the dimension in the direction perpendicular to the upper surface of the short-circuit plate portion, is the dimension in the direction perpendicular to the upper surface of the battery case of the positive electrode terminal protrusion and the direction perpendicular to the upper surface of the battery case of the negative electrode terminal protrusion. The secondary battery according to claim 1, which is larger than the size.
前記短絡板部は、前記正極端子突出部と前記負極端子突出部の少なくとも一方よりも電気抵抗の低い導電性材料から構成されている、請求項1に記載の二次電池。 The secondary battery according to claim 1, wherein the short-circuit plate portion is made of a conductive material having a lower electrical resistance than at least one of the positive electrode terminal protruding portion and the negative electrode terminal protruding portion. 前記短絡板部は、前記正極端子突出部と前記負極端子突出部の少なくとも一方よりも融点の高い導電性材料から構成されている、請求項1に記載の二次電池。 The secondary battery according to claim 1, wherein the short-circuit plate portion is made of a conductive material having a melting point higher than at least one of the positive electrode terminal protruding portion and the negative electrode terminal protruding portion.
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