JP6782044B1 - Flavor-enhancing composition, its manufacturing method, and foods and drinks containing the flavor-enhancing composition. - Google Patents

Flavor-enhancing composition, its manufacturing method, and foods and drinks containing the flavor-enhancing composition. Download PDF

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JP6782044B1
JP6782044B1 JP2020078499A JP2020078499A JP6782044B1 JP 6782044 B1 JP6782044 B1 JP 6782044B1 JP 2020078499 A JP2020078499 A JP 2020078499A JP 2020078499 A JP2020078499 A JP 2020078499A JP 6782044 B1 JP6782044 B1 JP 6782044B1
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雅広 赤尾
雅広 赤尾
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Abstract

【課題】食品本来の風味を向上させるための組成物及びその製造方法の提供。【解決手段】膠原繊維由来のたん白加水分解物を含有する、飲食品の風味を向上させるための組成物であって、当該組成物に含まれるたん白加水分解物中のアミノ酸組成が、重量比率で、酸性アミノ酸8〜29%、中性アミノ酸55〜82%、塩基性アミノ酸6〜19%であり、ペプチド結合を有しておらず、当該組成物中に含まれる有機酸が、全窒素に対するモル当量比で0.01〜2.0モルであり、更に全窒素に対する塩化物イオンがモル当量比で0.01〜1.2モルである。この組成物は、膠原繊維を含む組織を加水分解して得られた、ペプチド結合を有しない分解産物を準備し、この分解産物を所定の塩化物イオン濃度にまで脱塩処理した後に、有機酸等を用いて酸性化処理することによって製造できる。【選択図】なしPROBLEM TO BE SOLVED: To provide a composition for improving the original flavor of a food and a method for producing the same. SOLUTION: The composition contains a protein hydrolyzate derived from collagen fiber for improving the flavor of food and drink, and the amino acid composition in the protein hydrolyzate contained in the composition is weight. The ratio is 8 to 29% acidic amino acid, 55 to 82% neutral amino acid, 6 to 19% basic amino acid, does not have a peptide bond, and the organic acid contained in the composition is total nitrogen. The molar equivalent ratio to the total nitrogen is 0.01 to 2.0 mol, and the chloride ion to total nitrogen is 0.01 to 1.2 mol in terms of molar equivalent ratio. This composition prepares a degradation product having no peptide bond, which is obtained by hydrolyzing a tissue containing collagen fibers, desalting the degradation product to a predetermined chloride ion concentration, and then performing an organic acid. It can be produced by acidification treatment using or the like. [Selection diagram] None

Description

本発明は、飲食品の風味を向上させるための組成物(風味向上組成物)及びその製造方法に関する。又、本発明は、上記の組成物が配合された飲食品に関するものでもある。 The present invention relates to a composition for improving the flavor of food and drink (flavor improving composition) and a method for producing the same. The present invention also relates to foods and drinks containing the above compositions.

風味向上素材として、酵母由来のエキス、HVP(植物たん白加水分解物)、HAP(動物たん白加水分解物)や食品由来のエキス類などが知られている。その中でもたん白加水分解物の歴史は古く、例えば下記の特許文献1には、「動物又ハ植物蛋白質ヲ酸又ハ「アルカリ」ヲ以テ加水分解ヲ行ヒ中和シテ調味料ヲ製造スルコトハ既ニ知ラルル所ナルモ」と記載されている。
しかし、酸又はアルカリにて加水分解処理した分解産物は異味異臭を生じさせる。その問題解決として、例えば下記の特許文献2には、非極性アミノ酸を20%から50%低減させるたん白加水分解物に関する報告がなされているが、非極性アミノ酸も食品の味を構成する要因の一つであり、全体の風味増強の観点では課題もある。
さらに、各種プロテアーゼにより加水分解させる手法による問題解決が図られているが、酸又はアルカリ加水分解のように完全にアミノ酸まで分解するのは容易ではない。なお分解する目的としては、旨味成分である「グルタミン酸」に着目し、グルタミン酸の豊富な加水分解物の製法に関しては報告例が散見される。それ以外の成分でも遊離塩基性アミノ酸に着目し、旨味のみに限らず塩味増強や食品フレーバー増強を目的とした製法に関する報告がなされている(特許文献3参照)。また、近年では完全加水分解せずにペプチドに着目し食品のコク、旨味、乳感、脂肪感向上する効果の報告がなされている(特許文献4参照)。
Known flavor-enhancing materials include yeast-derived extracts, HVP (plant protein hydrolyzate), HAP (animal protein hydrolyzate), and food-derived extracts. Among them, protein hydrolyzate has a long history. For example, in Patent Document 1 below, "animal or plant protein, acid or" alkali ", hydrolyzate, neutralize, seasoning, etc. It is described as "Narmo, already known as Laruru".
However, the decomposition products hydrolyzed with acid or alkali give off an offensive odor. As a solution to this problem, for example, Patent Document 2 below reports on a protein hydrolyzate that reduces non-polar amino acids by 20% to 50%. Non-polar amino acids are also a factor that constitutes the taste of foods. It is one, and there is a problem from the viewpoint of enhancing the overall flavor.
Furthermore, although problems have been solved by hydrolyzing with various proteases, it is not easy to completely decompose amino acids as in acid or alkaline hydrolysis. As the purpose of decomposition, we focus on "glutamic acid", which is an umami component, and there are some reports on the method of producing a hydrolyzate rich in glutamic acid. Focusing on free basic amino acids for other components as well, reports have been made on manufacturing methods aimed at enhancing not only umami but also saltiness and food flavor (see Patent Document 3). Further, in recent years, it has been reported that the peptide is not completely hydrolyzed and the effect of improving the richness, umami, milkiness and fatness of food is improved (see Patent Document 4).

このように、これまで特定の味や質感に関する報告はなされているが、食品全体の風味向上を相加的又は相乗的に向上させる報告例は見当たらない。 As described above, although reports on specific tastes and textures have been made so far, there are no reports that additively or synergistically improve the flavor of foods as a whole.

特許第99741号Patent No. 99741 特開昭61−268139号公報Japanese Unexamined Patent Publication No. 61-268139 特開平7−289198号公報Japanese Unexamined Patent Publication No. 7-289198 特開2017−135991号公報JP-A-2017-135991

かかる現状に鑑み、発明者は、従来のたん白加水分解物では得られない食品本来の風味を向上させ得るたん白加水分解物、特に食品の風味を相加的又は相乗的に向上させることが可能な、全く新しいたん白加水分解物である風味向上組成物及びその製造方法を提供することを課題とした。 In view of this situation, the inventor may additively or synergistically improve the flavor of a protein hydrolyzate, particularly a food, which can improve the original flavor of the food, which cannot be obtained by the conventional protein hydrolyzate. An object of the present invention is to provide a flavor-enhancing composition, which is a completely new protein hydrolyzate, and a method for producing the same.

前記課題を解決するために発明者は、各種たん白からのたん白加水分解物を得る分解方法及び分解産物について鋭意検討を重ねた結果、動物性たん白質のうち膠原繊維たん白(コラーゲン)に着目し、膠原繊維を含む組織を加水分解した後に脱塩処理及び酸性化処理することによって、飲食品により異なるが、添加又は配合した飲食品の風味を相加的又は相乗的に向上可能であることを見出し、本発明を完成させるに至った。 In order to solve the above problems, the inventor has made extensive studies on the decomposition method for obtaining protein hydrolysates from various proteins and the decomposition products, and as a result, the collagen fiber protein (collagen) among the animal proteins has been selected. Focusing on this, by hydrolyzing the tissue containing collagen fibers and then desalting and acidifying it, it is possible to additively or synergistically improve the flavor of the added or blended food or drink, although it depends on the food or drink. This has led to the completion of the present invention.

飲食品の風味を向上させるための組成物(風味向上組成物)を製造するための本発明の方法は、膠原繊維を含む組織を加水分解して得られる、ペプチド結合を有しない分解産物を準備する工程、前記分解産物を、全窒素に対する塩化物イオン濃度のモル当量比が0.01〜1.2モルとなるまで脱塩処理する工程、及び、前記脱塩処理後の分解産物を、有機酸又は酸性物質を含む酸性食品から成るグループより選ばれた1種又は2種以上を用いてpH2.5〜4.5の範囲内に酸性化処理する工程を含むことを特徴とする。 The method of the present invention for producing a composition for improving the flavor of food and drink (flavor improving composition) prepares a degradation product having no peptide bond, which is obtained by hydrolyzing a tissue containing collagen fibers. The step of desalting the decomposition product until the molar equivalent ratio of the chloride ion concentration to the total nitrogen is 0.01 to 1.2 mol, and the step of desalting the decomposition product after the desalting treatment are organic. It is characterized by including a step of acidifying treatment within the range of pH 2.5 to 4.5 using one or more selected from the group consisting of acidic foods containing an acid or an acidic substance.

又、本発明は、上記の特徴を有した風味向上組成物の製造方法において、前記有機酸又は、酸性物質を含む酸性食品が、乳酸、クエン酸、酒石酸、リンゴ酸、コハク酸、グルコン酸、酢酸、蟻酸、食酢及びヨーグルトから成るグループより選ばれたものであることを特徴とするものである。 Further, according to the present invention, in the method for producing a flavor-enhancing composition having the above-mentioned characteristics, the acidic food containing the organic acid or the acidic substance is lactic acid, citric acid, tartaric acid, malic acid, succinic acid, gluconic acid. It is characterized by being selected from the group consisting of acetic acid, formic acid, lactic acid and yogurt.

又、本発明は、上記の特徴を有した風味向上組成物の製造方法において、前記の酸性化処理した分解物処理物に、塩基性を呈する水酸化塩、炭酸塩、有機酸塩、アンモニウム塩、リン酸塩から成るグループより選ばれる1種又は2種以上を用いてpH5.0〜7.0に調整する酸味軽減処理を行うことを特徴とするものでもある。 Further, according to the present invention, in the method for producing a flavor-enhancing composition having the above-mentioned characteristics, a hydroxide salt, a carbonate, an organic acid salt, and an ammonium salt exhibiting basicity in the acidified decomposition product treated product. It is also characterized in that an acidity reducing treatment for adjusting the pH to 5.0 to 7.0 is performed using one or more selected from the group consisting of phosphates.

又、本発明の風味向上組成物は、膠原繊維由来のたん白加水分解物を含有する、飲食品の風味を向上させるための組成物であって、当該組成物に含まれるたん白加水分解物中のアミノ酸組成が、重量比率で、酸性アミノ酸8〜29%、中性アミノ酸55〜82%、塩基性アミノ酸6〜19%であり、ペプチド結合を有しておらず、当該組成物中に含まれる有機酸が、全窒素に対するモル当量比で0.01〜2.0モルであり、更に全窒素に対する塩化物イオンがモル当量比で0.01〜1.2モルであることを特徴とするものである。 Further, the flavor improving composition of the present invention is a composition for improving the flavor of foods and drinks, which contains a protein hydrolyzate derived from collagen fibers, and is a protein hydrolyzate contained in the composition. The amino acid composition in the composition is 8 to 29% acidic amino acid, 55 to 82% neutral amino acid, and 6 to 19% basic amino acid by weight, does not have a peptide bond, and is contained in the composition. The organic acid is 0.01 to 2.0 mol in terms of molar equivalent to total nitrogen, and the chloride ion to total nitrogen is 0.01 to 1.2 mol in molar equivalent ratio. It is a thing.

又、本発明は、上記の特徴を有した風味向上組成物において、必要に応じて賦形剤として、デキストリン、でん粉、加工でんぷん、食物繊維より選ばれる1種又は2種以上が配合されていることを特徴とするものである。 Further, in the flavor-enhancing composition having the above-mentioned characteristics, one or more selected from dextrin, starch, modified starch, and dietary fiber are blended as excipients, if necessary. It is characterized by that.

更に本発明の飲食品は、上記の風味向上組成物が、飲食品に対して0.1重量%〜10.0重量%配合されていることを特徴とする。 Further, the food or drink of the present invention is characterized in that the above-mentioned flavor improving composition is blended in an amount of 0.1% by weight to 10.0% by weight based on the food or drink.

膠原繊維を有する動物又は魚類の組織を、酸又はアルカリにて加水分解させ中和させた際に生成する分解産物は、そのままでは分解物特有の異味異臭があるが、本発明による脱塩処理及び酸性化処理を行うことによって、異味異臭がなく、飲食品の風味を相加的又は相乗的に向上させる風味向上組成物を得ることができ、この風味向上組成物を飲食品に添加又は配合することにより、風味が向上した飲食品が提供できる。 The decomposition product produced when the tissue of an animal or fish having collagen fibers is hydrolyzed and neutralized with an acid or alkali has an offensive odor peculiar to the decomposition product as it is, but the desalting treatment according to the present invention and By performing the acidification treatment, it is possible to obtain a flavor-enhancing composition that does not have an offensive odor and improves the flavor of the food or drink additively or synergistically, and the flavor-improving composition is added or blended into the food or drink. As a result, food and drink with improved flavor can be provided.

まず最初に、飲食品の風味を向上させるための組成物を製造するための本発明の製造方法について説明する。
本発明の製造方法における最初の工程は、膠原繊維を含む組織を加水分解して得られる、ペプチド結合を有しない分解産物を準備する工程であり、この際に使用される原料は、膠原繊維を含む組織であればよく特に限定されないが、動物性膠原繊維が好ましく、魚介類の膠原繊維でもよい。具体的には、豚、鶏、牛,羊,ダチョウ,馬などの膠原繊維を含む動物由来のものが好ましく、その動物種を1種又は2種以上を組み合わせて使用できる。又、魚介類であれば、鮫,鯉,鮭,鱒など膠原繊維を含む魚介類であれば特に限定されるものではなく、1種又は2種以上を組み合わせて使用できる。さらに、動物性膠原繊維と魚介類の膠原繊維を組み合わせて使用することもできる。本発明では、分解処理する膠原繊維組織として、表皮、腱、骨、筋、臓器、鱗、鶏冠等の膠原繊維を含む1種又は2種以上組み合わせて使用してもよい。
First, the production method of the present invention for producing a composition for improving the flavor of food and drink will be described.
The first step in the production method of the present invention is a step of preparing a degradation product having no peptide bond, which is obtained by hydrolyzing a tissue containing collagen fibers, and the raw material used at this time is collagen fibers. It is not particularly limited as long as it contains a tissue, but animal collagen fiber is preferable, and fish and shellfish collagen fiber may be used. Specifically, those derived from animals containing collagen fibers such as pigs, chickens, cows, sheep, ostriches, and horses are preferable, and one or a combination of two or more of the animal species can be used. The seafood is not particularly limited as long as it is a seafood containing collagen fibers such as shark, carp, salmon, and trout, and one kind or a combination of two or more kinds can be used. Furthermore, animal collagen fibers and seafood collagen fibers can be used in combination. In the present invention, as the collagen fiber tissue to be decomposed, one type or a combination of two or more types containing collagen fibers such as epidermis, tendon, bone, muscle, organ, scale, and chicken crown may be used.

本発明では、膠原繊維を加水分解する方法は特に限定されないが、酸加水分解又はアルカリ加水分解が好ましく、プロテアーゼ加水分解、ペプチダーゼ加水分解を単独又は併用して加水分解してもよい。酸加水分解に使用する酸としては、無機酸又は有機酸など酸性を呈する酸であれば限定されず、2種以上を組み合わせて使用してもよい。又、アルカリ加水分解に使用するアルカリとしては、水酸化塩、炭酸塩、有機酸塩、リン酸塩などアルカリ性を呈する物資であれば限定されず、2種以上を組み合わせて使用してもよい。
さらに本発明では、上記の加水分解によって得られた加水分解物を中和してもよく、分解処理した分解物を噴霧乾燥や凍結乾燥若しくはドラム乾燥等粉末化処理しても良い。なお、得られた分解産物はペプチド結合を有しない分解産物であり、具体的には、原液にてビウレット反応が青紫色への変色を呈さず陰性反応を示す。
In the present invention, the method for hydrolyzing collagen fibers is not particularly limited, but acid hydrolysis or alkali hydrolysis is preferable, and protease hydrolysis and peptidase hydrolysis may be used alone or in combination. The acid used for acid hydrolysis is not limited as long as it is an acidic acid such as an inorganic acid or an organic acid, and two or more kinds may be used in combination. The alkali used for alkali hydrolysis is not limited as long as it is an alkaline substance such as a hydroxide salt, a carbonate, an organic acid salt, or a phosphate, and two or more kinds may be used in combination.
Further, in the present invention, the hydrolyzate obtained by the above hydrolysis may be neutralized, or the decomposed product may be powdered by spray drying, freeze drying or drum drying. The obtained degradation product is a degradation product that does not have a peptide bond. Specifically, the Biuret reaction does not show a discoloration to bluish purple in the undiluted solution and shows a negative reaction.

膠原繊維を含む組織を加水分解して得られるたん白加水分解物中のアミノ酸組成は、重量比率で、酸性アミノ酸8〜29%、中性アミノ酸55〜82%、塩基性アミノ酸6〜19%であり、これらの各アミノ酸の比率は、最終工程の酸性化処理により得られる最終製品(風味向上組成物)の比率と実質的に同じである。
又、上記加水分解物中に含まれる塩化物イオンの、全窒素に対するモル当量は0.8〜4.0モルであることが好ましく、1.0〜2.0モルであることがより好ましく、1.3〜1.7モルであることが更に好ましい。
The amino acid composition in the protein hydrolyzate obtained by hydrolyzing the tissue containing collagen fibers is 8 to 29% acidic amino acid, 55 to 82% neutral amino acid, and 6 to 19% basic amino acid by weight. Yes, the ratio of each of these amino acids is substantially the same as the ratio of the final product (flavor improving composition) obtained by the acidification treatment in the final step.
The molar equivalent of chloride ions contained in the hydrolyzate with respect to total nitrogen is preferably 0.8 to 4.0 mol, more preferably 1.0 to 2.0 mol. It is more preferably 1.3 to 1.7 mol.

上記の分解産物は分解産物特有の異味異臭を呈し、更に目的とする風味向上効果が得られないので、本発明では次工程として、上記の加水分解にて生成した余剰な塩類を除去するための脱塩処理が実施される。余剰な塩類を除去する方法としては、膜処理、透析、電気透析などの塩を除去できる方法であれば特に限定されないが、全窒素に対する塩化物イオン濃度のモル当量比が0.01〜1.2モル、好ましくは0.05〜1.0モル、より好ましくは0.1〜0.8モルとなるまで前記分解産物を脱塩処理する。 Since the above-mentioned decomposition product exhibits an off-flavor and off-flavor peculiar to the decomposition product and the desired flavor improving effect cannot be obtained, the next step in the present invention is to remove excess salts generated by the above-mentioned hydrolysis. Desalination is carried out. The method for removing excess salts is not particularly limited as long as it can remove salts such as membrane treatment, dialysis, and electrodialysis, but the molar equivalent ratio of chloride ion concentration to total nitrogen is 0.01 to 1. The degradation products are desalted to 2 mol, preferably 0.05 to 1.0 mol, more preferably 0.1 to 0.8 mol.

さらに、本発明では、上記の脱塩処理を行った後に、加水分解物特有の塩味以外の異味異臭を除去する目的で、食品に使用できる酸性原料、例えば有機酸などの酸性物質及び酸性物質を含む酸性食品を1種又は2種以上を使用して酸性化処理が行われ、この際、pHが2.5〜4.5の範囲にて酸性化処理を行うことが好ましい。この酸性化処理で使用可能な酸としては有機酸が好ましく、酸性食品がより好ましい。酸性食品としては、酢類がさらに好ましい。 Further, in the present invention, after the above desalting treatment, an acidic raw material that can be used in foods, for example, an acidic substance such as an organic acid and an acidic substance, is used for the purpose of removing an offensive odor other than the salty taste peculiar to the hydrolyzate. The acidification treatment is carried out using one or more kinds of acidic foods containing the same, and at this time, it is preferable to carry out the acidification treatment in the range of pH 2.5 to 4.5. As the acid that can be used in this acidification treatment, an organic acid is preferable, and an acidic food is more preferable. As the acidic food, vinegar is more preferable.

上記の酸性化処理を行う際の有機酸としては、乳酸、クエン酸、酒石酸、リンゴ酸、コハク酸、グルコン酸、酢酸、蟻酸などの有機酸であれば限定されず、酸性食品としては、食酢、ヨーグルトなどの発酵食品、果汁などのエキス類など酸性を呈する食品であれば特に限定されない。 The organic acid used for the above acidification treatment is not limited to any organic acid such as lactic acid, citric acid, tartaric acid, malic acid, succinic acid, gluconic acid, acetic acid, and formic acid, and the acidic food is vinegar. , Fermented foods such as yogurt, and foods exhibiting acidity such as extracts such as fruit juice are not particularly limited.

上記の酸性化処理を行った後の分解物処理物は、そのままでは酸味を強く呈する場合があり、酸味が強い場合には風味向上に向かない。そこで本発明では必要に応じて、塩基性物質を使用した酸味軽減工程が実施される。この際、使用できる塩基性物質は、酸味を軽減できる塩基性物質であればよく、水酸化塩、炭酸塩、有機酸塩、アンモニウム塩、リン酸塩より選ばれる1種又は2種以上を使用することができる。 The decomposed product treated product after the above acidification treatment may exhibit a strong sourness as it is, and when the sourness is strong, it is not suitable for improving the flavor. Therefore, in the present invention, a sourness reducing step using a basic substance is carried out as needed. At this time, the basic substance that can be used may be any basic substance that can reduce the acidity, and one or more selected from hydroxide salts, carbonates, organic acid salts, ammonium salts, and phosphates is used. can do.

前記有機酸塩としては、乳酸、クエン酸、酒石酸、リンゴ酸、コハク酸、グルコン酸、酢酸、蟻酸など有機酸の塩類であれば特に限定されず、塩についても、ナトリウム、カリウム、マグネシウム、カルシウムなどアルカリ金属類又はアルカリ土類金属類の塩であれば特に限定されない。また、水酸化物塩、炭酸塩、アンモニウム塩についても、その塩はナトリウム、カリウム、マグネシウム、カルシウムなどアルカリ金属類又はアルカリ土類金属類の塩であれば特に限定されない。さらに、リン酸塩の場合にも、その塩に関しては、ナトリウム、カリウム、マグネシウム、カルシウムなどアルカリ金属類又はアルカリ土類金属類の塩であれば限定されず、重合度も塩基性を呈する重合度であれば良く、正リン酸塩、ピロリン酸塩、トリポリリン酸塩など塩基性を呈する重合度であれば特に限定されない。また塩基性を呈する食品である卵殻末や海藻末などの食品を使用しても良い。 The organic acid salt is not particularly limited as long as it is a salt of an organic acid such as lactic acid, citric acid, tartaric acid, malic acid, succinic acid, gluconic acid, acetic acid and formic acid, and the salt is also sodium, potassium, magnesium and calcium. The salt is not particularly limited as long as it is a salt of alkali metals or alkaline earth metals. Further, the hydroxide salt, carbonate and ammonium salt are not particularly limited as long as they are salts of alkali metals such as sodium, potassium, magnesium and calcium or alkaline earth metals. Further, in the case of phosphate, the salt thereof is not limited as long as it is a salt of an alkali metal such as sodium, potassium, magnesium or calcium or an alkaline earth metal, and the degree of polymerization is also basic. The degree of polymerization is not particularly limited as long as it has a basic degree of polymerization such as normal phosphate, pyrophosphate, and tripolyphosphate. Further, foods such as eggshell powder and seaweed powder, which are basic foods, may be used.

本発明の製造方法を用いて製造された風味向上組成物は液体であり、そのまま使用しても良いが、品質を安定させるために、噴霧乾燥や凍結乾燥又はドラム乾燥を行うことにより、粉末化することも可能である。その際、製造工程のいずれかの段階で、処理液を減圧濃縮するなどして濃縮しても良く、賦形剤としてデキストリン、でん粉、加工でんぷん、食物繊維より選ばれる1種又は2種を用いてもよい。 The flavor-enhancing composition produced by the production method of the present invention is a liquid and may be used as it is, but in order to stabilize the quality, it is pulverized by spray drying, freeze drying or drum drying. It is also possible to do. At that time, the treatment liquid may be concentrated under reduced pressure at any stage of the manufacturing process, and one or two kinds selected from dextrin, starch, modified starch, and dietary fiber are used as excipients. You may.

次に、飲食品の風味を向上させるための本発明の風味向上組成物について説明する。
本発明の風味向上組成物には、膠原繊維由来のたん白加水分解物が含有されており、このたん白加水分解物中のアミノ酸組成は、重量比率で、酸性アミノ酸8〜29%、好ましくは12〜25%、より好ましくは16〜21%で、中性アミノ酸55〜82%、好ましくは60〜77%、より好ましくは65〜72%で、塩基性アミノ酸6〜19%、好ましくは8〜17%、より好ましくは10〜15%であり、ペプチド結合は有していない。
Next, the flavor improving composition of the present invention for improving the flavor of foods and drinks will be described.
The flavor-enhancing composition of the present invention contains a protein hydrolyzate derived from collagen fibers, and the amino acid composition in this protein hydrolyzate is 8 to 29%, preferably 8 to 29%, acidic amino acids by weight. 12-25%, more preferably 16-21%, neutral amino acids 55-82%, preferably 60-77%, more preferably 65-72%, basic amino acids 6-19%, preferably 8- It is 17%, more preferably 10 to 15% and has no peptide bond.

そして、本発明の風味向上組成物においては、当該組成物中に含まれる有機酸が、全窒素に対するモル当量比で0.01〜2.0モル、好ましくは0.1〜1.5モル、より好ましくは0.2〜0.8モルであり、全窒素に対する塩化物イオンは、モル当量比で0.01〜1.2モル、好ましくは0.05〜1.0モル、より好ましくは0.1〜0.8モルであり、このように低い塩化物イオン濃度は、脱塩処理工程によって達成される。
尚、本発明の風味向上組成物に含有される有機酸としては、乳酸、クエン酸、酒石酸、リンゴ酸、コハク酸、グルコン酸、酢酸、蟻酸などが挙げられ、有機酸塩としては、上記の有機酸のナトリウム塩、カリウム塩、マグネシウム塩、カルシウム塩などが挙げられる。
In the flavor-enhancing composition of the present invention, the organic acid contained in the composition is 0.01 to 2.0 mol, preferably 0.1 to 1.5 mol, in terms of molar equivalent ratio to total nitrogen. It is more preferably 0.2 to 0.8 mol, and the chloride ion with respect to total nitrogen is 0.01 to 1.2 mol, preferably 0.05 to 1.0 mol, more preferably 0 in molar equivalent ratio. .1 to 0.8 mol, such a low chloride ion concentration is achieved by the desalting step.
Examples of the organic acid contained in the flavor improving composition of the present invention include lactic acid, citric acid, tartaric acid, malic acid, succinic acid, gluconic acid, acetic acid, formic acid and the like, and examples of the organic acid salt include the above. Examples thereof include sodium salt, potassium salt, magnesium salt and calcium salt of organic acids.

本発明の風味向上組成物に含有されるたん白加水分解物中の酸性、中性又は塩基性アミノ酸としては、アルギニン、リジン、ヒスチジン、フェニルアラニン、チロシン、ロイシン、イソロイシン、メチオニン、バリン、アラニン、グリシン、プロリン、グルタミン酸、セリン、スレオニン、アスパラギン酸、トリプトファン、シスチンが挙げられる。 Examples of the acidic, neutral or basic amino acids in the protein hydrolyzate contained in the flavor improving composition of the present invention include arginine, lysine, histidine, phenylalanine, tyrosine, leucine, isoleucine, methionine, valine, alanine and glycine. , Proline, glutamate, serine, leucine, aspartic acid, tryptophan, cystine.

膠原繊維由来のたん白加水分解物を含有する本発明の風味向上組成物の、JIS Z8802に従ってガラス電極法にて測定された際のpHは5.0〜7.0の範囲内であり、本発明では、上記組成物の粉末形態を安定化させる目的で、賦形剤として、デキストリン、でん粉、加工でんぷん、食物繊維より選ばれる1種又は2種以上が配合されてもよい。又、本発明の風味向上組成物中の有機酸類の量は、高速液体クロマトグラフィー法による全窒素に対するモル当量比で0.01〜2.0モル、好ましくは0.1〜1.5モル、より好ましくは0.2〜0.8モルである。 The pH of the flavor-enhancing composition of the present invention containing a protein hydrolyzate derived from collagen fiber as measured by the glass electrode method according to JIS Z8802 is in the range of 5.0 to 7.0. In the present invention, for the purpose of stabilizing the powder form of the above composition, one or more selected from dextrin, starch, modified starch and dietary fiber may be blended as an excipient. The amount of organic acids in the flavor-enhancing composition of the present invention is 0.01 to 2.0 mol, preferably 0.1 to 1.5 mol, in terms of molar equivalent ratio to total nitrogen by high performance liquid chromatography. More preferably, it is 0.2 to 0.8 mol.

液体又は粉体の形態である本発明の風味向上組成物は、様々な飲食品に添加・配合して用いることができる。例えば食品であれば、総菜全般に利用可能でありさらに、食肉製品、魚肉製品、スープ類、ソース類、調味液、乳製品、菓子類、粉末調味料、介護食、流動食、健康食品などの素材や食品を限定せずに製品の風味を向上させる目的で、食品に0.1%〜10.0%添加又は配合して使用することができる。また、この風味向上組成物は飲料にも利用可能であり、清涼飲料、炭酸飲料、乳飲料、アルコール飲料、野菜ジュース、ゼリー飲料、粉末飲料など飲用する物であれば特に飲料を限定せずに、飲料に0.1%〜10.0%添加又は配合して使用することができる。 The flavor-enhancing composition of the present invention in the form of a liquid or powder can be added or blended with various foods and drinks. For example, in the case of foods, it can be used for all side dishes, and further, meat products, fish products, soups, sauces, seasonings, dairy products, confectionery, powdered seasonings, nursing foods, liquid foods, health foods, etc. For the purpose of improving the flavor of the product without limiting the material and food, 0.1% to 10.0% can be added or blended with the food. In addition, this flavor-enhancing composition can also be used for beverages, and the beverages are not particularly limited as long as they are drinkable such as soft drinks, carbonated beverages, milk beverages, alcoholic beverages, vegetable juices, jelly beverages, and powdered beverages. , 0.1% to 10.0% can be added or blended with beverages.

上記の各種飲食品に、本発明の風味向上組成物を上記の割合にて添加又は配合することにより、風味向上効果だけでなく、歩留向上効果、物性改善効果、微生物増殖抑制による日持ち向上効果、退色防止効果、栄養補給効果などの効果が付与された本発明の飲食品が製造できる。 By adding or blending the flavor improving composition of the present invention to the above various foods and drinks in the above ratio, not only the flavor improving effect but also the yield improving effect, the physical property improving effect, and the shelf life improving effect by suppressing the growth of microorganisms , The food and drink of the present invention to which effects such as fading prevention effect and nutritional supplement effect are imparted can be produced.

以下、本発明を実施例により説明するが、本発明はこれら実施例に限定されるものではない。 Hereinafter, the present invention will be described with reference to Examples, but the present invention is not limited to these Examples.

〔実施例1〕
豚の皮及び骨より得られた膠原繊維を、塩酸水溶液にて酸加水分解後、水酸化ナトリウム水溶液にてpHを5.2にした。さらに、不溶性不純物を濾過した濾液を風味向上組成物の原料とした。なお、原料として使用した分解産物のビウレット反応が原液で青紫色への変色を呈さず陰性反応を示し、加水分解物中に含まれる塩化物イオンの、全窒素に対するモル当量は1.6モルであり、アミノ酸分析の結果、全アミノ酸中の酸性アミノ酸が20%、中性アミノ酸が66%、塩基性アミノ酸が14%の組成であることを確認した。
[Example 1]
The collagen fibers obtained from pig skin and bone were acid-hydrolyzed with an aqueous hydrochloric acid solution, and then the pH was adjusted to 5.2 with an aqueous sodium hydroxide solution. Further, the filtrate obtained by filtering insoluble impurities was used as a raw material for the flavor improving composition. The Biuret reaction of the decomposition product used as a raw material showed a negative reaction without discoloration to bluish purple in the undiluted solution, and the molar equivalent of chloride ions contained in the hydrolyzate to total nitrogen was 1.6 mol. As a result of amino acid analysis, it was confirmed that the composition of all amino acids was 20% for acidic amino acids, 66% for neutral amino acids, and 14% for basic amino acids.

次に、上記で得られた分解産物を、電気透析装置を使用して脱塩処理を行った。脱塩後においては、全窒素に対する塩化物イオン濃度のモル当量比は0.3モルで、pHは5.4であった。
次いで減圧濃縮装置を用いて3倍濃縮を行い、さらに酢を加えpHを3.7に調整し、酸性化処理した後に水酸化ナトリウム水溶液を使用してpHを5.5に調整した。得られた風味向上組成物に、更に粉末の安定化目的でデキストリンを加え、噴霧乾燥機を用いて粉末化した。
Next, the decomposition product obtained above was desalted using an electrodialysis machine. After desalting, the molar equivalent ratio of chloride ion concentration to total nitrogen was 0.3 mol and the pH was 5.4.
Then, it was concentrated three times using a vacuum concentrator, and further added vinegar to adjust the pH to 3.7, and after acidification treatment, the pH was adjusted to 5.5 using an aqueous sodium hydroxide solution. Dextrin was further added to the obtained flavor-enhancing composition for the purpose of stabilizing the powder, and the powder was pulverized using a spray dryer.

粉末化して得られた組成物は、pHが5.6で、当該組成物に含まれるたん白加水分解物中のアミノ酸組成が、重量比率で、酸性アミノ酸20%、中性アミノ酸68%、塩基性アミノ酸12%であり、ペプチド結合を有しておらず、当該組成物中に含まれる有機酸が、全窒素に対するモル当量比で0.5モルであり、全窒素に対する塩化物イオンはモル当量比で0.3モルであった。このようにして得られた組成物を、以下の実施例2〜4において風味向上組成物として使用した。 The composition obtained by powdering has a pH of 5.6, and the amino acid composition in the protein hydrolyzate contained in the composition is 20% acidic amino acid, 68% neutral amino acid, and base by weight. It is 12% of sex amino acids, has no peptide bond, the organic acid contained in the composition is 0.5 molar equivalent to total nitrogen, and the chloride ion to total nitrogen is molar equivalent. The ratio was 0.3 mol. The composition thus obtained was used as a flavor-enhancing composition in Examples 2 to 4 below.

なお、実施例2〜4の各種官能評価試験は、味覚官能評価について訓練された4名のパネラーにより実施した。 The various sensory evaluation tests of Examples 2 to 4 were carried out by four panelists trained in taste sensory evaluation.

〔実施例2〕
実施例1記載の原料(脱塩処理を行う前の加水分解産物液)5.8%水溶液と、実施例1記載の風味向上組成物4.0%水溶液を用いて以下の評価法により官能評価を行った。なお、溶液濃度の違いは、風味向上組成物の全窒素濃度を基準として、全窒素値が等しくなる濃度とした。
[Example 2]
Sensory evaluation by the following evaluation method using the 5.8% aqueous solution of the raw material (hydrolyzed product solution before desalting treatment) described in Example 1 and the 4.0% aqueous solution of the flavor improving composition described in Example 1. Was done. The difference in solution concentration was set to a concentration at which the total nitrogen values were equal to each other, based on the total nitrogen concentration of the flavor improving composition.

分解産物を含む水溶液について、異なる任意3桁の数字を付けた被検液2検体と、上記の風味向上組成物を含む水溶液について、先の分解産物水溶液2検体と異なる任意3桁の数字を付けた被検液1検体の計3検体を用意した。
上記の3検体の内で、異なる検体を選択させる方式で風味の違いの有無判定を行った。また、判定理由を5つの味(塩味、酸味、苦味、甘味、旨味)より選択させ、その増減を以下の5段階で評価し、その他風味については自由記載で評価した。
For the aqueous solution containing the decomposition product, 2 samples of the test solution with different arbitrary 3-digit numbers and for the aqueous solution containing the above-mentioned flavor improving composition, give an arbitrary 3-digit number different from the previous 2 samples of the decomposition product aqueous solution. A total of 3 samples, 1 sample of the test solution, were prepared.
The presence or absence of a difference in flavor was determined by a method in which a different sample was selected from the above three samples. In addition, the reason for determination was selected from five tastes (salty, sour, bitter, sweet, and umami), the increase or decrease was evaluated in the following five stages, and other flavors were evaluated freely.

1:弱い
2:少し弱い
3:変わらない
4:少し強い
5:強い
1: Weak 2: Slightly weak 3: No change 4: Slightly strong 5: Strong

4名のパネラーによる官能評価結果が表1に記載されている。表1に示されるように、全てのパネラーが分解産物と風味向上組成物の違いを認識した。また、全てのパネラーが、風味向上組成物は分解産物より、甘味と旨味の増強を感じており、塩味に関しては弱いと感じていた。なお、酸味に関しては弱い傾向が認められた。その他の風味に関しては、「さっぱり」や「すっきり」などの表現から、雑味が低減されているとの結果が得られた。 The results of sensory evaluation by four panelists are shown in Table 1. As shown in Table 1, all panelists recognized the difference between the degradation products and the flavor-enhancing composition. In addition, all panelists felt that the flavor-enhancing composition had more sweetness and umami than the decomposition products, and that the salty taste was weaker. A weak tendency was observed for sourness. Regarding other flavors, expressions such as "refreshing" and "refreshing" gave the results that miscellaneous flavors were reduced.

Figure 0006782044
Figure 0006782044

〔実施例3〕
前記の分解産物と実施例1記載の風味向上組成物をそれぞれ添加して、以下の表2記載の配合組成を有するハンバーグを製造し、官能評価を実施した。なお、分解産物と風味向上組成物はいずれも、全窒素量が配合中0.09%となる様に調整して配合し、粉末水あめ及び水で固形分及び水分を調整した。
[Example 3]
The above-mentioned decomposition product and the flavor-enhancing composition described in Example 1 were added to each other to produce a hamburger having the compounding composition shown in Table 2 below, and a sensory evaluation was carried out. Both the decomposition product and the flavor-enhancing composition were blended so that the total nitrogen content was 0.09% during blending, and the solid content and water content were adjusted with powdered starch syrup and water.

Figure 0006782044
Figure 0006782044

〔官能評価検体(ハンバーグ)の製造〕
上記の表2の配合組成に従い、合挽ミンチ肉に分解産物又は風味向上組成物及びハンバーグ用調味MIXと水とソテーオニオンを加え、粘りが出るまでよく練り合わせた。練り上がり後、乾燥白パン粉を加え全体に均一になるまで分散させた。なお、各試験区間で成形前のハンバーグ種に差が出ない様にミキサーを用いて一定速度一定時間でミキシングを行い、ハンバーグ種を製造した。製造したハンバーグ種は小判型のハンバーグ成型機を用いて1個当たり55gの重量になるように均一に成形し、250℃に設定したコンベクションオーブンにて6分間焼成し、ついで85℃設定の蒸煮機にて10分間、ハンバーグの中心温度が75℃まで加熱を行った。加熱後は−20℃下で完全凍結させ、官能評価検体とした。
[Manufacturing of sensory evaluation sample (hamburger)]
According to the compounding composition shown in Table 2 above, a decomposition product or flavor-enhancing composition, a hamburger seasoning MIX, water and sautéed onion were added to the minced minced meat and kneaded well until it became sticky. After kneading, dried white bread crumbs were added and dispersed until uniform throughout. The hamburger steak was produced by mixing at a constant speed for a certain period of time using a mixer so that there was no difference in the hamburger steak before molding in each test section. The manufactured hamburger steak is uniformly molded using an oval hamburger molding machine so that each piece weighs 55 g, baked in a convection oven set at 250 ° C for 6 minutes, and then steamed at 85 ° C. The hamburger was heated to a core temperature of 75 ° C. for 10 minutes. After heating, it was completely frozen at −20 ° C. to prepare a sensory evaluation sample.

官能評価は、試験直前に検体を電子レンジにて中心温度80℃まで加熱し、以下の評価法にて評価した。 In the sensory evaluation, the sample was heated to a center temperature of 80 ° C. in a microwave oven immediately before the test, and evaluated by the following evaluation method.

分解産物区ハンバーグと風味向上組成物区ハンバーグには任意3桁の数字を付け、無添加区との比較を以下の評価項目にて評価した。 The decomposition product group hamburger and the flavor-enhancing composition group hamburger were given arbitrary 3-digit numbers, and the comparison with the additive-free group was evaluated by the following evaluation items.

・ハンバーグとして好ましい検体(無添加を含む)
・好ましい理由を以下から選べ(複数回答可)
(塩味、酸味、苦味、甘味、旨味、食感、香り、)
・ Preferred sample for hamburger steak (including no additives)
・ Choose the preferred reason from the following (multiple answers allowed)
(Salty, sour, bitter, sweet, umami, texture, aroma,)

以下の表3には、4名のパネラーによる官能評価結果が示されている。表3に示されるように、全てのパネラーがハンバーグとして好ましい試験区として、風味向上組成物を配合したハンバーグを選択した。全パネラーが旨味に関するハンバーグらしさの評価理由として回答した。さらに、選択項目にはバラツキがあるものの、全パネラーが複数回答をしており、一つの理由のみでハンバーグらしいとの評価をしておらず、風味向上組成物が複合的にハンバーグの風味を向上しているとの結果に至った。 Table 3 below shows the sensory evaluation results by four panelists. As shown in Table 3, a hamburger steak containing a flavor-enhancing composition was selected as a preferred test group for all panelists as a hamburger steak. All panelists answered as the reason for evaluating the hamburger steak regarding umami. Furthermore, although there are variations in the selection items, all panelists answered multiple times, and they did not evaluate it as hamburger steak for only one reason, and the flavor improving composition improves the flavor of hamburger steak in a complex manner. I came to the result that it is doing.

Figure 0006782044
Figure 0006782044

〔実施例4〕
分解産物と実施例1記載の風味向上組成物を準備し、表4の調味液配合組成の調味液を用いて焼き豚を製造し、官能評価を実施した。なお、分解産物と風味向上組成物は、全窒素量が配合中0.09%となる様に調整して配合し、粉末水あめ及び水で固形分及び水分を調整した。
[Example 4]
The decomposition product and the flavor-improving composition described in Example 1 were prepared, and roast pork was produced using the seasoning liquid having the seasoning liquid-blended composition shown in Table 4, and sensory evaluation was carried out. The decomposition product and the flavor-enhancing composition were blended so that the total nitrogen content was 0.09% during blending, and the solid content and water content were adjusted with powdered starch syrup and water.

Figure 0006782044
Figure 0006782044

豚ロース肉を準備する一方、表4に示される調味液配合割合の調味液を調製し、この調味液を、豚ロース肉の重量に対して30%量加え、真空下で1時間タンブリングを行い、15時間7℃設定冷蔵庫にて静置した。次いで、70℃にて30分間乾燥後、80℃にて中心温度が72℃まで蒸煮を行い、130℃で20分間焼成して一晩冷蔵庫にて完冷し、官能評価検体とした。 While preparing the pork loin, prepare the seasoning liquid having the seasoning liquid blending ratio shown in Table 4, add 30% of this seasoning liquid to the weight of the pork loin, and tumbl for 1 hour under vacuum. , It was allowed to stand in a refrigerator set at 7 ° C. for 15 hours. Then, after drying at 70 ° C. for 30 minutes, steaming was performed at 80 ° C. until the center temperature was 72 ° C., calcined at 130 ° C. for 20 minutes, and completely cooled in a refrigerator overnight to prepare a sensory evaluation sample.

官能評価は、厚さ2.0mm幅にスライスした焼き豚について、以下の評価方法にて実施した。 The sensory evaluation was carried out by the following evaluation method for roast pork sliced to a thickness of 2.0 mm.

分解産物区と風味向上組成物区の焼き豚には任意3桁の数字をつけ、無添加区との比較を以下の評価項目にて評価した。 The roast pork in the decomposition product group and the flavor-enhancing composition group was given an arbitrary three-digit number, and the comparison with the additive-free group was evaluated by the following evaluation items.

・焼き豚として好ましい検体(無添加を含む)
・好ましい理由を以下から選べ(複数回答可)
(塩味、酸味、苦味、甘味、旨味、食感、香り、)
・ Preferred sample for roast pork (including no additives)
・ Choose the preferred reason from the following (multiple answers allowed)
(Salty, sour, bitter, sweet, umami, texture, aroma,)

以下の表5には、4名のパネラーによる官能評価結果が示されている。表5に示されるように、全てのパネラーが焼き豚として好ましい試験区として、風味向上組成物区焼き豚を選択した。又、全パネラーが甘味に関して焼き豚らしさの評価理由として回答した。さらに、選択理由にはバラツキがあるものの、全てのパネラーが複数回答をしており、一つの理由のみで焼き豚らしいとの評価をしておらず、風味向上組成物が複合的に焼き豚の風味を向上しているとの結果に至った。 Table 5 below shows the sensory evaluation results by four panelists. As shown in Table 5, all panelists selected the flavor-enhancing composition group roast pork as the preferred test group for roast pork. In addition, all panelists responded as a reason for evaluating the sweetness of roast pork. Furthermore, although there are variations in the reasons for selection, all panelists answered multiple times, and they did not evaluate it as pork-like for only one reason, and the flavor-enhancing composition combined the flavor of roast pork. The result was that it was improving.

Figure 0006782044
Figure 0006782044

実施例1記載の風味向上組成物は、実施例3「ハンバーグ」と実施例4「焼き豚」についての評価において、それぞれ無添加区と分解産物区と比較して適しているとの評価であった。なお、食品には個々の食品に適した風味があり、一様に旨味のみで食品としての風味を表しておらず、実施例3及び実施例4の結果のとおり、主要な選択理由は異なっていた。また、全てのパネラーが複数回答していることから、実施例1記載の風味向上組成物は個々の食品の特徴的な味を向上させるだけでなく、複合的に風味を向上させたと思われる。 The flavor-enhancing composition described in Example 1 was evaluated to be more suitable than the additive-free group and the decomposition product group in the evaluation of Example 3 "hamburger" and Example 4 "roast pork", respectively. .. It should be noted that the food has a flavor suitable for each food, and the flavor as a food is not uniformly expressed only by the umami, and as shown in the results of Examples 3 and 4, the main reasons for selection are different. It was. In addition, since all the panelists answered a plurality of answers, it seems that the flavor-enhancing composition described in Example 1 not only improved the characteristic taste of each food, but also improved the flavor in a complex manner.

膠原繊維組織を加水分解して得られる分解産物を脱塩処理及び酸性化処理することによって風味向上組成物を製造することができ、本発明の風味向上組成物は、食品の風味を相加的又は相乗的に向上させる効果を有しているので、飲食品に所定量を添加又は配合することにより、風味を向上させた各種飲食品を提供することができる。 A flavor-enhancing composition can be produced by desalting and acidifying a decomposition product obtained by hydrolyzing a collagen fiber structure, and the flavor-enhancing composition of the present invention adds to the flavor of food. Alternatively, since it has the effect of synergistically improving, various foods and drinks having improved flavor can be provided by adding or blending a predetermined amount to the food or drink.

Claims (6)

飲食品の風味を向上させるための組成物を製造するための方法であって、当該方法が、
膠原繊維を含む組織を加水分解して得られる、ペプチド結合を有しない分解産物を準備する工程、前記分解産物を、全窒素に対する塩化物イオン濃度のモル当量比が0.01〜1.2モルとなるまで脱塩処理する工程、及び、前記脱塩処理後の分解産物を、有機酸又は酸性物質を含む酸性食品から成るグループより選ばれた1種又は2種以上を用いてpH2.5〜4.5の範囲内に酸性化処理する工程を含むことを特徴とする風味向上組成物の製造方法。
A method for producing a composition for improving the flavor of food and drink, which is a method.
A step of preparing a decomposition product having no peptide bond, which is obtained by hydrolyzing a tissue containing collagen fibers. The decomposition product has a molar equivalent ratio of chloride ion concentration to total nitrogen of 0.01 to 1.2 mol. The step of desalting until the substance becomes, and the decomposition product after the desalting treatment is pH 2.5 to 2 or more selected from the group consisting of acidic foods containing organic acids or acidic substances. A method for producing a flavor-enhancing composition, which comprises a step of acidifying treatment within the range of 4.5.
前記有機酸又は、酸性物質を含む酸性食品が、乳酸、クエン酸、酒石酸、リンゴ酸、コハク酸、グルコン酸、酢酸、蟻酸、食酢及びヨーグルトから成るグループより選ばれたものであることを特徴とする請求項1に記載の風味向上組成物の製造方法。 The acidic food containing the organic acid or acidic substance is characterized by being selected from the group consisting of lactic acid, citric acid, tartaric acid, malic acid, succinic acid, gluconic acid, acetic acid, formic acid, vinegar and yogurt. The method for producing a flavor-enhancing composition according to claim 1. 前記の酸性化処理した分解物処理物に、塩基性を呈する水酸化塩、炭酸塩、有機酸塩、アンモニウム塩、リン酸塩から成るグループより選ばれる1種又は2種以上を用いてpH5.0〜7.0に調整する酸味軽減処理を行うことを特徴とする請求項1又は2に記載の風味向上組成物の製造方法。 The acidified decomposition product was subjected to pH 5. Using one or more selected from the group consisting of hydroxide salts, carbonates, organic acid salts, ammonium salts and phosphates exhibiting basicity. The method for producing a flavor-enhancing composition according to claim 1 or 2, wherein the acidity-reducing treatment adjusted to 0 to 7.0 is performed. 膠原繊維由来のたん白加水分解物を含有する、飲食品の風味を向上させるための組成物であって、当該組成物に含まれるたん白加水分解物中のアミノ酸組成が、重量比率で、酸性アミノ酸8〜29%、中性アミノ酸55〜82%、塩基性アミノ酸6〜19%であり、ペプチド結合を有しておらず、当該組成物中に含まれる有機酸が、全窒素に対するモル当量比で0.01〜2.0モルであり、更に全窒素に対する塩化物イオンがモル当量比で0.01〜1.2モルであることを特徴とする風味向上組成物。 A composition for improving the flavor of foods and drinks, which contains a protein hydrolyzate derived from collagen fibers, and the amino acid composition in the protein hydrolyzate contained in the composition is acidic in weight ratio. Amino acids 8 to 29%, neutral amino acids 55 to 82%, basic amino acids 6 to 19%, no peptide bond, and the organic acid contained in the composition is the molar equivalent ratio to total nitrogen. The flavor-enhancing composition is 0.01 to 2.0 mol, and the chloride ion with respect to total nitrogen is 0.01 to 1.2 mol in molar equivalent ratio. 賦形剤として、デキストリン、でん粉、加工でんぷん、食物繊維より選ばれる1種又は2種以上が配合されていることを特徴とする請求項4記載の風味向上組成物。 The flavor-enhancing composition according to claim 4, wherein one or more selected from dextrin, starch, modified starch, and dietary fiber are blended as an excipient. 請求項4又は5に記載の風味向上組成物が、飲食品に対して0.1重量%〜10.0重量%配合されていることを特徴とする飲食品。 A food or drink containing 0.1% by weight to 10.0% by weight of the flavor-enhancing composition according to claim 4 or 5.
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