JP6633284B2 - Texture improver for baked goods - Google Patents

Texture improver for baked goods Download PDF

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JP6633284B2
JP6633284B2 JP2015046452A JP2015046452A JP6633284B2 JP 6633284 B2 JP6633284 B2 JP 6633284B2 JP 2015046452 A JP2015046452 A JP 2015046452A JP 2015046452 A JP2015046452 A JP 2015046452A JP 6633284 B2 JP6633284 B2 JP 6633284B2
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耕児 大島
耕児 大島
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Adeka Corp
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Description

本発明は、口どけ、歯切れの良い焼菓子を得ることのできる、焼菓子用食感改良材に関する。   TECHNICAL FIELD The present invention relates to a texture improving material for baked confectionery, which can obtain a crisp and crisp baked confectionery.

クッキーやビスケットに代表される焼菓子は、小麦粉を主原料とし、副原料としてバターやショートニング等の油脂類、糖類を配合することで製造される。このような焼菓子は、一般にサクサクとした歯切れの良い食感や口どけの良さが求められることが多く、そのためには小麦タンパク質に由来するグルテンの形成を適切に抑制することが不可欠である。   Baked confectionery represented by cookies and biscuits is produced by mixing wheat flour as a main ingredient and fats and oils such as butter and shortening, and sugars as auxiliary ingredients. In general, such baked confectionery is often required to have a crisp and crisp texture and a good mouthfeel, and for that purpose, it is essential to appropriately suppress the formation of gluten derived from wheat protein.

グルテンは小麦粉タンパク質であるグリアジンとグルテニンが水分存在下で混捏されることで形成され、弾力や粘着力を有する。グルテンが過度に形成されると、食感に粘りやひきが現れて口どけが悪くなったり、歯切れの悪い食感となってしまう。グルテンの形成を抑制するため、クッキーやビスケット等の一般的な製法では、水分を含まない状態で油脂を小麦粉へ添加することにより、疎水性の油脂が小麦粉タンパク粒子のまわりを被覆し、小麦粉と水との接触を妨げるという方法がとられている。   Gluten is formed by kneading flour proteins gliadin and glutenin in the presence of moisture, and has elasticity and adhesive strength. If gluten is formed excessively, stickiness and grind will appear in the texture, resulting in poor mouthfeel and crisp texture. In order to suppress the formation of gluten, in a general manufacturing method such as cookies and biscuits, by adding fats and oils to flour in a state that does not contain moisture, hydrophobic fats and fats coat around flour protein particles, and The approach is to prevent contact with water.

近年、嗜好の多様化から従来よりも特徴のある焼菓子が求められる傾向にあり、食感についても、歯切れや口どけが更に良好な焼菓子が求められている。
歯切れと口どけを同時に改善するためのアプローチとしては、主に(1)油脂による方法(例えば特許文献1)、(2)澱粉類による方法(例えば特許文献2,3)、(3)その他添加材による方法(例えば特許文献4,5)が報告されている。
In recent years, there has been a tendency for baked confectioneries having more distinctive characteristics than ever before due to diversification of tastes, and baked confectioneries with a better crispness and mouthfeel have been demanded.
Approaches for simultaneously improving crispness and mouthfeel are mainly (1) a method using fats and oils (for example, Patent Document 1), (2) a method using starches (for example, Patent Documents 2 and 3), and (3) other additives. Methods using materials (for example, Patent Documents 4 and 5) have been reported.

(1)に該当する発明としては、特許文献1ではPOP含有量が焼き菓子用油脂組成物全体中12〜40重量%であり、且つ焼き菓子用油脂組成物に含まれるラウリン酸の含有量が構成脂肪酸全体中2〜15重量%である焼き菓子用油脂組成物について報告されている。   As an invention corresponding to (1), in Patent Document 1, the POP content is 12 to 40% by weight in the whole fat and oil composition for baked confectionery, and the content of lauric acid contained in the fat and oil composition for baked confectionery is reduced. It has been reported that the fat and oil composition for baked confectionery accounts for 2 to 15% by weight of the total constituent fatty acids.

(2)に該当する発明としては、特許文献2では加工澱粉を10〜30質量%、有機酸モノグリセリドを0.1〜4質量%含有し、油分が25〜70質量%であることを特徴とする製菓練り込み用油中水型乳化物について報告されている。また、特許文献3では(A)α化澱粉及び(B)β澱粉を含む澱粉質を含み、更に(C)小麦蛋白質及び(D)油脂から選択される少なくとも一種を含む焼き菓子用組成物であって、(A)と(B)の合計質量に対し、(A)が3〜10質量%、(B)が97〜90質量%の範囲で含まれており、(A)と(B)の合計量100質量部に対し、(C)は40質量部以下であり、(D)は40質量部以下の範囲で含まれている、上記焼き菓子用組成物について報告されている。   As the invention corresponding to (2), Patent Document 2 discloses that the modified starch contains 10 to 30% by mass, the organic acid monoglyceride is 0.1 to 4% by mass, and the oil content is 25 to 70% by mass. A water-in-oil emulsion for kneading confectionery has been reported. Patent Document 3 discloses a composition for baked confectionery containing (A) a starch containing (a) pregelatinized starch and (B) β-starch, and further containing (C) at least one selected from wheat protein and (D) fats and oils. In addition, (A) is contained in the range of 3 to 10% by mass and (B) is contained in the range of 97 to 90% by mass based on the total mass of (A) and (B), and (A) and (B) (C) is 40 parts by mass or less and (D) is contained in a range of 40 parts by mass or less based on 100 parts by mass of the composition for baked confectionery.

(3)に該当する発明としては、特許文献4ではHLBが15〜19であるショ糖脂肪酸エステルと、糖類化合物とを、重量比15/85〜40/60で水に溶解させてから、乾燥させて得られる粉末であることを特徴とする焼き菓子用食感改質剤について報告されている。また、特許文献5では、茹卵を原料とする粉末卵であって、粉末卵1部を清水4部に分散させ、1時間経過させた時の分散液の粘度が5Pa・s以上であり、粉末卵1部を清水9部に分散させ、1時間経過させた時の分散液中の粉末卵の平均粒子径が80μm以下である粉末卵を有効成分として含有することを特徴とするクッキー用食感改良材について報告されている。   As an invention corresponding to (3), in Patent Document 4, a sucrose fatty acid ester having an HLB of 15 to 19 and a saccharide compound are dissolved in water at a weight ratio of 15/85 to 40/60, and then dried. There has been reported a texture modifier for baked confectionery, which is characterized by being obtained as a powder. Patent Document 5 discloses a powdered egg made from boiled egg, in which 1 part of the powdered egg is dispersed in 4 parts of fresh water, and the viscosity of the dispersion after one hour has passed is 5 Pa · s or more. 1 part of egg is dispersed in 9 parts of fresh water, and after 1 hour, the powdered egg in the dispersion has an average particle diameter of 80 μm or less as an active ingredient. Improvements have been reported.

特開2010−4806号公報JP 2010-4806 A 特開2014−50351号公報JP 2014-50351 A 特開2012−165741号公報JP 2012-165741 A 特開2011−125310号公報JP 2011-125310A 特開2009−189343号公報JP 2009-189343 A

しかし、(1)や(2)の方法では、配合割合の多い主原料や副原料として特定の材料を使用する必要があるため、配合の自由度が狭くなり適用できる範囲が限られる場合がある。また、(3)の方法では焼菓子に雑味が生じたり、焼菓子の風味に影響する場合が想定され、さらなる食感改良方法、とくに必要に応じて他の方法と併用しうる方法が求められていた。   However, in the methods (1) and (2), it is necessary to use a specific material as a main raw material or an auxiliary raw material having a large blending ratio, so that the flexibility of blending is narrowed and the applicable range may be limited. . In addition, in the method (3), it is assumed that the baked confectionery may have an unpleasant taste or affect the flavor of the baked confectionery. Therefore, a further texture improvement method, particularly a method that can be used in combination with another method as required, is required. Had been.

よって本発明の目的は、主原料である澱粉類や副原料である油脂配合の自由度を保ちながら、焼菓子の風味に影響を与えずに、口どけ、歯切れの良い焼菓子を得ることができる焼菓子用食感改良材を提供することにある。   Therefore, an object of the present invention is to obtain a crisp, crisp baked confectionery without affecting the flavor of the baked confectionery, while maintaining the freedom of blending the starch as the main raw material and the oil and fat as the auxiliary raw material. An object of the present invention is to provide a texture-improving material for baked confectionery.

本発明者等は、上記のアプローチと異なるアプローチ、すなわち場合によっては上記の発明と併用しうる方法について鋭意検討したところ、乳由来のリン脂質及び乳タンパク質を含有し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部含有する水性液を焼菓子用食感改良材として使用することで、上記の課題を解決できることを見出した。本発明は上記知見に基づいて完成されたものである。
すなわち、本発明は乳由来のリン脂質及び乳タンパク質を含有し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部含有する水性液であることを特徴とする、焼菓子用食感改良材である。
The present inventors have intensively studied an approach different from the above-mentioned approach, that is, a method that may be used in combination with the above-described invention, and containing milk-derived phospholipids and milk protein, and having a milk-derived phospholipid content of 1 mass It has been found that the above problem can be solved by using an aqueous liquid containing 1 to 15 parts by mass of milk protein per part as a texture improving material for baked confectionery. The present invention has been completed based on the above findings.
That is, the present invention is an aqueous liquid containing milk-derived phospholipids and milk protein, wherein the aqueous liquid contains milk protein in an amount of 1 to 15 parts by mass with respect to 1 part by mass of milk-derived phospholipid. It is a texture improving material.

本発明の焼菓子用食感改良材によれば、口どけ、歯切れの良い焼菓子を得ることができる。   ADVANTAGE OF THE INVENTION According to the texture improving material for baked confectionery of this invention, a baked confectionery with a sharp mouth and crispness can be obtained.

以下、本発明の焼菓子用食感改良材について詳述する。
本発明の焼菓子用食感改良材は、乳由来のリン脂質及び乳タンパク質を含有し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部、好ましくは1.2〜13質量部、より好ましくは1.5〜10質量部、最も好ましくは2〜5質量部含有する水性液である。
本発明の焼菓子用食感改良材は、乳由来のリン脂質と乳タンパク質との比率が重要である。上記水性液中における乳タンパク質の含有量が、乳由来のリン脂質1質量部に対して1質量部よりも少なかったり、15質量部よりも多いと、焼菓子用食感改良材として使用した際に、最終的に得られる焼菓子の歯切れや口どけを改良することができず、また、焼菓子に雑味が生じてしまう場合がある。
Hereinafter, the texture improving material for baked confectionery of the present invention will be described in detail.
The texture-improving material for baked confectionery of the present invention contains milk-derived phospholipids and milk protein, and 1 to 15 parts by mass of milk protein per 1 part by mass of milk-derived phospholipid, preferably 1.2 to 13 parts by mass. It is an aqueous liquid containing 1.5 parts by mass, more preferably 1.5 to 10 parts by mass, and most preferably 2 to 5 parts by mass.
In the texture improving material for baked confectionery of the present invention, the ratio of phospholipid derived from milk to milk protein is important. When the content of milk protein in the aqueous liquid is less than 1 part by mass or more than 15 parts by mass per 1 part by mass of phospholipid derived from milk, when used as a texture improving material for baked confectionery. In addition, the crispness and mouthfeel of the finally obtained baked confectionery cannot be improved, and the baked confectionery may have an unpleasant taste.

なお、上記水性液中の乳由来のリン脂質の含有量は、該水性液の固形分を基準として、好ましくは2質量%以上、より好ましくは3質量%以上、最も好ましくは5質量%以上である。
乳由来のリン脂質としてはホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルセリン、ホスファチジルイノシトール、スフィンゴミエリン、リゾリン脂質等が挙げられる。
The content of the milk-derived phospholipid in the aqueous liquid is preferably 2% by mass or more, more preferably 3% by mass or more, and most preferably 5% by mass or more, based on the solid content of the aqueous liquid. is there.
Examples of milk-derived phospholipids include phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, sphingomyelin, and lysophospholipid.

また、上記水性液中の乳タンパク質の含有量は、該水性液の固形分を基準として好ましくは20〜40質量%、より好ましくは23〜37質量%、最も好ましくは25〜35質量%である。
上記乳タンパク質としては、例えばα−ラクトアルブミンやβ−ラクトグロブリン、ラクトアルブミン等のホエイタンパク質、カゼイン、またこれらの乳タンパク質を含有する脱脂粉乳、全粉乳、トータルミルクプロテイン等が挙げられる。
Further, the content of the milk protein in the aqueous liquid is preferably 20 to 40% by mass, more preferably 23 to 37% by mass, and most preferably 25 to 35% by mass based on the solid content of the aqueous solution. .
Examples of the milk protein include whey proteins such as α-lactalbumin, β-lactoglobulin, and lactalbumin, casein, and skim milk powder, whole milk powder, and total milk protein containing these milk proteins.

また、本発明の焼菓子用食感改良材である上記水性液中の固形分含量は2〜60質量%が好ましく、5〜50質量%がより好ましく、10〜40質量%が最も好ましい。   The solid content in the aqueous liquid, which is the texture improving material for baked confectionery of the present invention, is preferably 2 to 60% by mass, more preferably 5 to 50% by mass, and most preferably 10 to 40% by mass.

本発明の焼菓子用食感改良材は、水性液である。焼菓子用食感改良材が粉末状や顆粒状などの性状であると、本発明の効果を発揮できない。
なお、本発明において、水性液とは、水溶液のほか、水相を主体として少量の油溶性成分が分散した水中油型乳化物を含むものとする。
The texture improving material for baked confectionery of the present invention is an aqueous liquid. If the texture improving material for baked confectionery is in the form of powder or granules, the effects of the present invention cannot be exhibited.
In the present invention, the aqueous liquid includes an oil-in-water emulsion in which a small amount of an oil-soluble component is mainly dispersed in an aqueous phase, in addition to an aqueous solution.

次に、本発明の焼菓子用食感改良材である、上記水性液を得る方法について述べる。
本発明の焼菓子用食感改良材である上記水性液は、乳由来のリン脂質及び乳タンパク質、あるいはこれらを含有する乳原料を使用し、乳由来のリン脂質含有量1質量部に対し乳タンパク質が1〜15質量部、好ましくは1.2〜13質量部、より好ましくは1.5〜10質量部、最も好ましくは2〜5質量部となるように混合するか、あるいは水又は水性液に溶解することにより得ることができる。
Next, a method for obtaining the above-mentioned aqueous liquid, which is the texture improving material for baked confectionery of the present invention, will be described.
The aqueous liquid, which is the texture improving material for baked confectionery of the present invention, uses milk-derived phospholipids and milk proteins, or a milk raw material containing these, and has a milk-derived phospholipid content of 1 part by mass and milk. The protein is mixed so as to be 1 to 15 parts by mass, preferably 1.2 to 13 parts by mass, more preferably 1.5 to 10 parts by mass, and most preferably 2 to 5 parts by mass, or water or an aqueous liquid. Can be obtained by dissolving the

具体的には、リン脂質含有量1質量部に対し乳タンパク質が1〜15質量部を含有する乳原料そのもの(以下、単に「乳原料」ということもある)を使用する方法のほか、乳由来のリン脂質を多く含有する原料と乳タンパク質を多く含有する原料を、乳由来のリン脂質1質量部に対し乳タンパク質が1〜15質量部となるように混合する方法、または、乳由来のリン脂質及び乳タンパク質を多く含有する原料へ乳由来のリン脂質及び/又は乳タンパク質を添加し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部となるように調整する方法等が挙げられる。
本発明においては上記方法の中でも、上記乳原料を使用することが、雑味を生じることなく本発明の効果を発揮できる点で好ましい。
Specifically, in addition to a method using a milk raw material itself containing 1 to 15 parts by mass of a milk protein per 1 part by mass of a phospholipid (hereinafter sometimes simply referred to as a “milk raw material”), A method in which a raw material containing a large amount of phospholipid and a raw material containing a large amount of milk protein are mixed so that milk protein is 1 to 15 parts by mass with respect to 1 part by mass of phospholipid derived from milk, A method in which milk-derived phospholipid and / or milk protein is added to a raw material containing a large amount of lipid and milk protein, and milk protein is adjusted to 1 to 15 parts by mass with respect to 1 part by mass of milk-derived phospholipid. Is mentioned.
In the present invention, among the above-mentioned methods, the use of the above-mentioned dairy raw material is preferable in that the effects of the present invention can be exerted without causing unpleasant taste.

上記乳原料の具体的な例としては、クリーム又はバターからバターオイルを製造する際に生じる水相成分があげられる。上記乳原料は、牛乳、ヤギ乳、ヒツジ乳、人乳などの乳から製造されたものであるのが好ましく、特に牛乳から製造されたものであるのが好ましい。   Specific examples of the above-mentioned milk raw material include an aqueous phase component produced when producing butter oil from cream or butter. The milk raw material is preferably produced from milk such as cow's milk, goat's milk, sheep's milk and human milk, and particularly preferably produced from milk.

上記のクリームからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まず、牛乳を遠心分離して得られる脂肪濃度30〜40質量%のクリームをプレートで加温し、遠心分離機によってクリームの脂肪濃度を70〜95質量%まで高める。次いで、乳化破壊機で乳化を破壊し、再び遠心分離機で処理することによってバターオイルが得られる。本発明で用いられる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。   A method for producing an aqueous phase component produced when producing butter oil from the cream described above is, for example, as follows. First, a cream having a fat concentration of 30 to 40% by mass obtained by centrifuging milk is heated in a plate, and the fat concentration of the cream is increased to 70 to 95% by mass using a centrifuge. Next, the emulsification is destroyed by an emulsification destroyer, and the mixture is again processed by a centrifugal separator, thereby obtaining butter oil. The aqueous phase component used in the present invention is generated as a by-product of butter oil in the last centrifugation step.

上記のバターからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。まず、バターを溶解機で溶解し熱交換機で加温する。これを遠心分離機で分離することによってバターオイルが得られる。本発明で用いられる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。該バターオイルの製造に用いられるバターとしては、通常のものが用いられる。   A method for producing an aqueous phase component generated when producing butter oil from the above-mentioned butter is, for example, as follows. First, butter is melted with a melting machine and heated with a heat exchanger. This is separated by a centrifuge to obtain butter oil. The aqueous phase component used in the present invention is generated as a by-product of butter oil in the last centrifugation step. As the butter used in the production of the butter oil, conventional butter is used.

本発明では上記の乳原料を更に濃縮したものや乾燥したもの、冷凍処理をしたものなどを用いることも可能であるが、最終的に得られる焼菓子用食感改良材として本発明の効果がより大きい点で、乾燥工程を経ていないものを使用することが好ましい。また、溶剤を用いて濃縮したものは風味上の問題から用いないのが好ましい。   In the present invention, those obtained by further concentrating or drying the above-mentioned milk raw material, and those subjected to freezing treatment can be used, but the effect of the present invention as a texture improving material for baked confectionery obtained finally is obtained. In view of the larger point, it is preferable to use one that has not been subjected to a drying step. Further, it is preferable not to use a concentrate obtained by using a solvent from the viewpoint of flavor.

上記乳原料は、均質化処理を行っても良い。均質化処理は1回でも良く、2回以上行っても良い。該均質化処理に用いられる均質化機としては、例えば、ケトル型チーズ乳化釜、ステファンミキサーの様な高速せん断乳化釜、スタティックミキサー、インラインミキサー、バブル式ホモジナイザー、ホモミキサー、コロイドミル、ディスパーミルなどがあげられる。均質化圧力は特に制限はないが、好ましくは0〜100MPaである。2段式ホモゲナイザーを用いて均質化処理をする場合は、例えば、1段目3〜100MPa、2段目0〜5MPaの均質化圧力にて行っても良い。   The milk raw material may be subjected to a homogenization treatment. The homogenization treatment may be performed once or twice or more. Examples of the homogenizer used in the homogenization treatment include a kettle-type cheese emulsification vessel, a high-speed shearing emulsification vessel such as a Stephan mixer, a static mixer, an in-line mixer, a bubble homogenizer, a homomixer, a colloid mill, and a disper mill. Is raised. The homogenization pressure is not particularly limited, but is preferably 0 to 100 MPa. When the homogenization treatment is performed using a two-stage homogenizer, for example, the homogenization pressure may be 3 to 100 MPa in the first stage and 0 to 5 MPa in the second stage.

上記乳原料は、UHT加熱処理を行っても良い。UHT加熱処理の条件としては特に制限はないが、温度条件は好ましくは120〜150℃であり、処理時間は好ましくは1〜6秒である。   The milk raw material may be subjected to a UHT heat treatment. The conditions of the UHT heat treatment are not particularly limited, but the temperature condition is preferably 120 to 150 ° C., and the treatment time is preferably 1 to 6 seconds.

本発明では、上記の乳原料中のリン脂質の一部または全部がリゾ化されたリゾ化物を使用することもできるが、風味の面からリゾ化物は使用しない方が好ましい。リゾ化物を使用した場合、最終的に得られる焼菓子に苦味が生じる場合がある。
なお、該リゾ化物は、乳原料をそのままリゾ化したものや乳原料を濃縮した後にリゾ化したものが挙げられる。これらのリゾ化物は本発明における乳由来のリン脂質の含有量に含めるものとする。
In the present invention, a lysate in which a part or all of the phospholipid in the above-mentioned milk raw material is lysated can be used, but it is preferable not to use a lysate in terms of flavor. When a lysotide is used, the baked confection finally obtained may have a bitter taste.
Examples of the lysate include lysified dairy raw materials and lysated dairy raw materials after concentrating the dairy raw materials. These lysates are included in the content of milk-derived phospholipid in the present invention.

上記の乳原料中のリン脂質をリゾ化する場合には、ホスホリパーゼAで処理する方法が挙げられる。ホスホリパーゼAは、リン脂質分子のグリセロール部分と脂肪酸残基とを結びつけている結合を切断し、この脂肪酸残基を水酸基で置換する作用を有する酵素である。ホスホリパーゼAは、作用する部位の違いによってホスホリパーゼA1とホスホリパーゼA2とに分かれるが、ホスホリパーゼA2が好ましい。ホスホリパーゼA2の場合、リン脂質分子のグリセロール部分の2位の脂肪酸残基が選択的に切り離される。   When the phospholipid in the above-mentioned milk raw material is lysated, a method of treating with phospholipase A may be mentioned. Phospholipase A is an enzyme having an action of cleaving a bond connecting a glycerol portion of a phospholipid molecule and a fatty acid residue and substituting the fatty acid residue with a hydroxyl group. Phospholipase A is divided into phospholipase A1 and phospholipase A2 depending on the site of action, but phospholipase A2 is preferred. In the case of phospholipase A2, the fatty acid residue at position 2 of the glycerol portion of the phospholipid molecule is selectively cleaved.

本発明におけるリン脂質の定量は、例えば以下のような方法にて測定することができる。
ここでは、上記乳原料の場合を例に説明する。但し、抽出方法などについては乳原料の形態などによって適正な方法が異なるため、以下の定量方法に限定されるものではない。
まず、乳原料の脂質をFolch法を用いて抽出する。次いで、抽出した脂質溶液を湿式分解法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載の湿式分解法に準じる)にて分解した後、モリブデンブルー吸光度法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載のリンのモリブデン酸による定量に準じる)によりリン量を求める。求められたリン量から以下の計算式を用いて乳原料の乳固形分100g中のリン脂質の含有量(g)を求める。
リン脂質(g/100g)=〔リン量(μg)/(乳原料−乳原料の水分(g))×25.4×(0.1/1000)
The quantification of the phospholipid in the present invention can be measured, for example, by the following method.
Here, the case of the milk raw material will be described as an example. However, the extraction method and the like are not limited to the following quantification methods because the appropriate method differs depending on the form of the milk raw material and the like.
First, the milk raw material lipid is extracted using the Folch method. Next, the extracted lipid solution is decomposed by a wet digestion method (according to the wet digestion method described in the Japanese Pharmaceutical Society, edited by the Japanese Society of Pharmaceutical Sciences, Hygiene Test Method, Commentary 2000 2.1 Food Component Test Method), and then molybdenum blue absorbance method (Japan Pharmaceutical Association) Ed., Hygiene Test Method / Comment 2000 2.1 Determine the phosphorus amount according to the determination of phosphorus with molybdic acid described in Food Component Test Method). The content (g) of the phospholipid in 100 g of the milk solid content of the milk raw material is determined from the obtained phosphorus amount using the following formula.
Phospholipid (g / 100 g) = [phosphorus content (μg) / (milk raw material-water content of milk raw material (g)) × 25.4 × (0.1 / 1000)

本発明の焼菓子用食感改良材は、pHが2.5〜6.4であることが好ましい。pHがこの範囲であると、本発明の効果を顕著に高めることができ、最終的に得られる焼菓子はより口どけがよく歯切れの良いものとなる。なお、上記pHは、好ましくは4.0〜6.0、より好ましくは4.7〜5.8である。   The texture improving material for baked confectionery of the present invention preferably has a pH of 2.5 to 6.4. When the pH is within this range, the effects of the present invention can be significantly enhanced, and the finally obtained baked confectionery is more palatable and crisp. In addition, the above-mentioned pH is preferably 4.0 to 6.0, and more preferably 4.7 to 5.8.

本発明の焼菓子用食感改良材のpHが2.5〜6.4となるように調整する方法としては、たとえば上記「乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部含有する水性液」に対し酸を添加し該水性液のpHを2.5〜6.4となるように調整する方法、該水性液を乳酸醗酵させて該水性液のpHを2.5〜6.4となるように調整する方法等が挙げられる。
本発明においては、簡便かつ効率的であり、酸の種類を適宜変えることにより風味を調節することも可能となるため、酸を添加し焼菓子用食感改良材のpHが2.5〜6.4となるように調整する方法が好ましい。
As a method of adjusting the pH of the texture improving material for baked confectionery of the present invention to be 2.5 to 6.4, for example, the above-mentioned “1 to 15 parts by mass of milk protein per 1 part by mass of phospholipid derived from milk” Part of the aqueous liquid ", an acid is added to adjust the pH of the aqueous liquid to be 2.5 to 6.4, and the aqueous liquid is subjected to lactic acid fermentation to adjust the pH of the aqueous liquid to 2.5 to 6.4. To 6.4.
In the present invention, it is simple and efficient, and the flavor can be adjusted by appropriately changing the type of acid. .4 is preferable.

酸を添加する場合において使用する酸は無機酸であっても有機酸であってもよいが、有機酸であることが好ましい。該有機酸としては、酢酸、乳酸、クエン酸、グルコン酸、フィチン酸、ソルビン酸、アジピン酸、コハク酸、酒石酸、フマル酸、リンゴ酸、アスコルビン酸等が挙げられ、果汁、濃縮果汁、発酵乳、ヨーグルトなどの有機酸を含有する飲食品も用いることができるが、本発明においては、より酸味が少なく、風味に影響しない点でフィチン酸、及び/またはグルコン酸を使用することが好ましい。   When the acid is added, the acid used may be an inorganic acid or an organic acid, but is preferably an organic acid. Examples of the organic acid include acetic acid, lactic acid, citric acid, gluconic acid, phytic acid, sorbic acid, adipic acid, succinic acid, tartaric acid, fumaric acid, malic acid, and ascorbic acid. Although foods and drinks containing organic acids such as yogurt and the like can also be used, in the present invention, it is preferable to use phytic acid and / or gluconic acid because they have less acidity and do not affect the flavor.

焼菓子用食感改良材のpHが上記の範囲となるように酸で調整する場合の温度条件、処理時間は特に制限なく任意の条件を設定することができるが、0〜70℃条件下で30秒以上攪拌することが好ましい。   Temperature conditions when adjusting the pH of the texture-improving material for baked confectionery with an acid so as to be in the above range, and the treatment time can be set to any condition without any particular limitation. It is preferable to stir for 30 seconds or more.

本発明では、焼菓子用食感改良材である水性液を調製する途中及び/又は調製した後、均質化機にて均質化するのが好ましい。均質化処理は1回でも良く、2回以上行っても良い。該均質化処理に用いられる均質化機としては、例えば、ケトル型チーズ乳化釜、ステファンミキサーの様な高速せん断乳化釜、スタティックミキサー、インラインミキサー、バブル式ホモジナイザー、ホモミキサー、コロイドミル、ディスパーミルなどがあげられる。均質化圧力は、好ましくは0〜100MPaである。2段式ホモゲナイザーを用いて均質化処理をする場合は、例えば、1段目3〜100MPa、2段目0〜5MPaの均質化圧力にて行なっても良い。   In the present invention, it is preferable to homogenize with a homogenizer during and / or after preparing the aqueous liquid as the texture improving material for baked confectionery. The homogenization treatment may be performed once or twice or more. Examples of the homogenizer used in the homogenization treatment include a kettle-type cheese emulsification vessel, a high-speed shearing emulsification vessel such as a Stephan mixer, a static mixer, an in-line mixer, a bubble homogenizer, a homomixer, a colloid mill, and a disper mill. Is raised. The homogenization pressure is preferably between 0 and 100 MPa. When the homogenization treatment is performed using a two-stage homogenizer, for example, the homogenization pressure may be 3 to 100 MPa in the first stage and 0 to 5 MPa in the second stage.

更に必要に応じてUHT加熱処理を行っても良い。UHT加熱処理の条件としては特に制限はないが、温度条件は、好ましくは120〜160℃、更に好ましくは130〜150℃、最も好ましくは139〜146℃であり、処理時間は好ましくは1〜6秒、更に好ましくは2〜6秒、最も好ましくは4〜6秒である。
上記の均質化処理とUHT加熱処理は、均質化処理のみを行っても良く、UHT加熱処理のみを行って良く、UHT加熱処理の前及び/または後に均質化処理を行っても良い。
そして急速冷却、徐冷却などの冷却操作を行っても良い。
Further, if necessary, a UHT heat treatment may be performed. The condition of the UHT heat treatment is not particularly limited, but the temperature condition is preferably 120 to 160 ° C, more preferably 130 to 150 ° C, most preferably 139 to 146 ° C, and the treatment time is preferably 1 to 6 ° C. Seconds, more preferably 2 to 6 seconds, most preferably 4 to 6 seconds.
The above homogenization treatment and the UHT heat treatment may be performed only by the homogenization treatment, only the UHT heat treatment may be performed, or the homogenization treatment may be performed before and / or after the UHT heat treatment.
Then, a cooling operation such as rapid cooling or slow cooling may be performed.

次に、本発明の焼菓子用食感改良材を含有する本発明の焼菓子用油中水型乳化物について説明する。
本発明の焼菓子用食感改良材は水性液として焼菓子生地へ直接添加することもできるが、焼菓子生地中でより均一に分散し本発明の効果を高めることができる点で、焼菓子用食感改良材を含有する油中水型乳化物として利用することが好ましい。
Next, the water-in-oil emulsion for baked confectionery of the present invention containing the texture improving material for baked confectionery of the present invention will be described.
The texture-improving material for baked confectionery of the present invention can also be directly added to baked confectionery dough as an aqueous liquid, but the baked confectionery can be more uniformly dispersed in baked confectionery dough and the effect of the present invention can be enhanced. It is preferably used as a water-in-oil emulsion containing a texture improving material for food.

本発明の焼菓子用食感改良材を油中水型乳化物中に含有させる場合、該食感改良材を水相中に含有させることが好ましい。本発明の焼菓子用油中水型乳化物における本発明の焼菓子用食感改良材の好ましい含有量は、油中水型乳化物中の油脂100質量部に対し、焼菓子用食感改良材が1〜60質量部、より好ましくは3〜40質量部、更に好ましくは5〜25質量部、もっとも好ましくは8〜20質量部である。
焼菓子用油中水型乳化物の含有量が1質量部よりも少ないと、本発明の効果が不十分となる場合があり、60質量部よりも多いと、生地中での分散性に劣る場合があるため好ましくない。
When the texture improving material for baked confectionery of the present invention is contained in a water-in-oil emulsion, it is preferable that the texture improving material is contained in an aqueous phase. The preferred content of the texture-improving material for baked confectionery of the present invention in the water-in-oil emulsion for baked confectionery of the present invention is, based on 100 parts by mass of the fat or oil in the water-in-oil emulsion, improved texture for baked confectionery. The amount of the material is 1 to 60 parts by mass, more preferably 3 to 40 parts by mass, still more preferably 5 to 25 parts by mass, and most preferably 8 to 20 parts by mass.
If the content of the water-in-oil emulsion for baked confectionery is less than 1 part by mass, the effect of the present invention may be insufficient, and if it is more than 60 parts by mass, dispersibility in dough is poor. In some cases, this is not preferable.

本発明の焼菓子用油中水型乳化物で使用可能な油脂としては、例えば、パーム油、パーム核油、ヤシ油、コーン油、綿実油、大豆油、ナタネ油、米油、ヒマワリ油、サフラワー油、オリーブ油、キャノーラ油、牛脂、乳脂、豚脂、カカオ脂、魚油、鯨油等の各種植物油脂及び動物油脂、並びにこれらに水素添加、分別及びエステル交換から選択される1又は2以上の処理を施した加工油脂等が挙げられる。これらの油脂は、単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。
本発明の焼菓子用油中水型乳化物の上記油脂の含有量は、本発明の焼菓子用油中水型乳化物中、好ましくは50〜99質量%、より好ましくは60〜98質量%、更に好ましくは70〜95質量%である。
Examples of fats and oils usable in the water-in-oil emulsion for baked confectionery of the present invention include palm oil, palm kernel oil, coconut oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, sunflower oil, Various vegetable oils and animal oils such as flower oil, olive oil, canola oil, beef tallow, milk fat, lard, cocoa butter, fish oil, whale oil, and one or more treatments selected from hydrogenation, fractionation and transesterification thereof And the like. These fats and oils can be used alone or in combination of two or more.
The content of the above fats and oils in the water-in-oil emulsion for baked confectionery of the present invention is preferably 50 to 99% by mass, more preferably 60 to 98% by mass in the water-in-oil-based emulsion for baked confectionery of the present invention. , More preferably 70 to 95% by mass.

尚、本発明の焼菓子用油中水型乳化物に、油脂を含有する副原料を使用した場合は、上記油脂の含有量には、それらの副原料に含まれる油脂分も含めるものとする。   In addition, in the water-in-oil type emulsion for baked confectionery of the present invention, when an auxiliary material containing an oil or fat is used, the content of the oil or fat includes the oil or fat component contained in the auxiliary material. .

本発明では、油中水型乳化物とは、連続した油相中に水相が分散していることをいう。また、本発明でいう油中水型には油中水中油型を含むものとする。   In the present invention, the water-in-oil emulsion means that an aqueous phase is dispersed in a continuous oil phase. Further, the water-in-oil type referred to in the present invention includes an oil-in-water-in-oil type.

本発明の焼菓子用油中水型乳化物の水分の含有量は、上記焼菓子用食感改良材や後述するその他の原料に含まれる水分も含め、好ましくは0.5〜50質量%、更に好ましくは1〜40質量%である。   The water content of the water-in-oil emulsion for baked confectionery of the present invention is preferably 0.5 to 50% by mass, including the water contained in the texture improving material for baked confectionery and other raw materials described below. More preferably, it is 1 to 40% by mass.

本発明の油中水型乳化物は、必要に応じ一般の油中水型乳化物に使用することのできる上記以外のその他の原料を使用することができる。該その他の原料としては、例えば、乳化剤、澱粉類、食塩や塩化カリウム等の塩味剤、酢酸、乳酸、グルコン酸等の酸味料、牛乳・練乳・脱脂粉乳・酵素・カゼイン・ホエーパウダー・バター・クリーム・ナチュラルチーズ・プロセスチーズ・発酵乳等の乳や乳製品、糖類や糖アルコール類、ステビア、アスパルテーム等の甘味料、β−カロチン、カラメル、紅麹色素等の着色料、トコフェロール、茶抽出物等の酸化防止剤、小麦蛋白や大豆蛋白等の植物蛋白卵及び各種卵加工品、着香料、調味料、pH調整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒー、ナッツペースト、香辛料、カカオマス、ココアパウダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物が挙げられる。   As the water-in-oil emulsion of the present invention, other raw materials other than those described above that can be used for general water-in-oil emulsions can be used as needed. Examples of the other ingredients include emulsifiers, starches, salting agents such as salt and potassium chloride, acetic acid, lactic acid, acidulants such as gluconic acid, milk, condensed milk, skim milk powder, enzymes, casein, whey powder, butter, Milk and dairy products such as cream, natural cheese, processed cheese, and fermented milk, sugars and sugar alcohols, sweeteners such as stevia, aspartame, coloring agents such as β-carotene, caramel, and red koji pigment, tocopherol, and tea extract Antioxidants such as wheat protein, soy protein, etc., vegetable protein eggs and processed egg products, flavors, seasonings, pH adjusters, food preservatives, shelf life improvers, fruit, fruit juice, coffee, nut paste, spices , Cacao mass, cocoa powder, cereals, beans, vegetables, meat, seafood, and other food materials and food additives.

次に、本発明の焼菓子生地について説明する。
本発明の焼菓子生地は、上述した本発明の焼菓子用食感改良材及び/又は油中水型乳化物を含有するものである。
Next, the baked confectionery dough of the present invention will be described.
The baked confectionery dough of the present invention contains the above-described texture improving material for baked confectionery of the present invention and / or a water-in-oil emulsion.

すなわち、本発明の焼菓子生地では、焼菓子用食感改良材をそのまま添加してもよく、また上記焼菓子用食感改良材を含有する油中水型乳化物の形態で添加してもよい。焼菓子用食感改良材と焼菓子用油中水型乳化物を併用することももちろん可能である。   That is, in the baked confectionery dough of the present invention, the texture-improving material for baked confectionery may be added as it is, or may be added in the form of a water-in-oil emulsion containing the texture-improving material for baked confectionery. Good. It is of course possible to use a texture improving material for baked confectionery and a water-in-oil emulsion for baked confectionery in combination.

上記の焼菓子生地としては、例えば、クッキー生地、ショートブレッド生地、マフィン生地、バターケーキ生地、ドライケーキ生地、クラッカー生地、プレッツェル生地等様々なタイプの焼菓子類の生地に用いることができる。
本発明の焼菓子生地における、上記焼菓子用食感改良材又は油中水型乳化物の含有量は、焼菓子生地の種類によって適宜選択されるものであるが、好ましくは生地に含まれる澱粉類100質量部に対し、焼菓子用食感改良材として好ましくは1〜20質量部、より好ましくは2〜15質量部、最も好ましくは3〜10質量部となるように添加する。(油中水型乳化物では含有する焼菓子用食感改良材として算出)
Examples of the baked confectionery dough include various types of baked confectionery dough such as cookie dough, shortbread dough, muffin dough, butter cake dough, dry cake dough, cracker dough, and pretzel dough.
The content of the texture-improving material for baked confectionery or the water-in-oil emulsion in the baked confectionery dough of the present invention is appropriately selected depending on the type of the baked confectionery dough, but is preferably starch contained in the dough. The amount is preferably 1 to 20 parts by mass, more preferably 2 to 15 parts by mass, and most preferably 3 to 10 parts by mass as a texture improving material for baked confectionery with respect to 100 parts by mass of the baked confectionery. (Calculated as a texture-improving material for baked confections contained in water-in-oil emulsions)

本発明の焼菓子生地における、上記焼菓子用食感改良材及び/又は油中水型乳化物の含有量について、焼菓子用食感改良材及び/又は油中水型乳化物に含まれる乳由来の乳リン脂質を基準とした場合には、生地に含まれる澱粉類100質量部に対し、焼菓子用食感改良材及び/又は油中水型乳化物由来の乳リン脂質が好ましくは0.02〜0.8質量部、より好ましくは0.05〜0.5質量部、もっとも好ましくは0.1〜0.4質量部となるように添加する。   In the baked confectionery dough of the present invention, the content of the texture improving material for baked confectionery and / or the content of the water-in-oil emulsion, the milk contained in the texture improving material for baked confectionery and / or the water-in-oil emulsion. Based on the milk phospholipids derived from the starch, 100 parts by mass of the starch contained in the dough, the texture improving material for baked confectionery and / or the milk phospholipids derived from the water-in-oil emulsion is preferably 0. 0.02 to 0.8 parts by mass, more preferably 0.05 to 0.5 parts by mass, and most preferably 0.1 to 0.4 parts by mass.

次に、本発明の焼菓子について説明する。
本発明の焼菓子は上記焼菓子生地を必要に応じて成形し、焼成したものである。
成型は、ワイヤーカット成型、モールド成型、棒状成型、デポジット成型、シート成型等のいずれでもよく、また、機械成型、手成型の別は問わない。
そして、焼成する。焼成時間は、焼菓子生地の水分が逸散し、軽い食感になるまで行う。焼成温度は、一般的には180〜210℃程度の焼成時間が汎用されるが、150℃付近や120℃付近での焼成、又は100℃付近で乾燥焼きしてもよい。
Next, the baked confectionery of the present invention will be described.
The baked confectionery of the present invention is obtained by shaping the above baked confectionery dough as required and firing it.
The molding may be any of wire cut molding, mold molding, rod-shaped molding, deposit molding, sheet molding and the like, and it does not matter whether it is mechanical molding or hand molding.
Then, it is fired. The baking time is maintained until the moisture of the baked confectionery material dissipates and the texture becomes light. The firing temperature is generally about 180 to 210 ° C., but firing at about 150 ° C. or 120 ° C., or drying and baking at about 100 ° C. may be performed.

最後に、本発明の焼菓子の食感改良方法について説明する。
本発明の焼菓子の食感改良方法は、乳由来のリン脂質及び乳タンパク質を含有し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部含有する水性液を焼菓子生地に含有させるものである。
Finally, the method for improving the texture of the baked confectionery of the present invention will be described.
The method for improving the texture of a baked confectionery of the present invention comprises a baked confectionery dough containing an aqueous liquid containing milk-derived phospholipids and milk protein, and containing 1 to 15 parts by mass of milk protein per 1 part by mass of milk-derived phospholipid. To be contained.

上記水性液は、焼成前の焼菓子、すなわち焼菓子生地中に好ましくは生地に含まれる澱粉類100質量部に対し、焼菓子用食感改良材として好ましくは1〜20質量部、より好ましくは2〜15質量部、最も好ましくは3〜10質量部となるように添加する。(油中水型乳化物では含有する焼菓子用食感改良材として算出)   The aqueous liquid is preferably a baked confectionery before baking, that is, 1 to 20 parts by mass, more preferably 1 to 20 parts by mass, as a texture improving material for baked confectionery, based on 100 parts by mass of starches preferably contained in the dough. It is added so as to be 2 to 15 parts by mass, most preferably 3 to 10 parts by mass. (Calculated as a texture-improving material for baked confections contained in water-in-oil emulsions)

次に実施例、及び比較例を挙げ、本発明を更に詳細に説明するが、これらは本発明を何ら制限するものではない。   Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but these do not limit the present invention at all.

焼菓子用食感改良材の製造
[表1]に記載した配合のうち、酸(フィチン酸)以外の成分を55℃条件下で攪拌しながら混合し、続いて酸(フィチン酸)を添加してそれぞれpHを調整した後、3MPaの圧力で均質化し、実施例1〜4からそれぞれ本発明の焼菓子用食感改良材A〜Dを得た。また、下記乳原料Aをそのまま3MPaの圧力で均質化し、焼菓子用食感改良材Eとした(実施例5)。なお、実施例5の焼菓子用食感改良材Eは、乳タンパク質を、乳由来のリン脂質1質量部に対して2.84質量部含有するものであった。
Production of texture improving materials for baked goods
Of the formulations described in Table 1, components other than the acid (phytic acid) were mixed while stirring at 55 ° C., and then the acid (phytic acid) was added to adjust the pH, and then 3 MPa To obtain the texture improving materials A to D for baked confectionery of the present invention from Examples 1 to 4, respectively. In addition, the following milk raw material A was homogenized at a pressure of 3 MPa as it was to obtain a texture improving material E for baked confectionery (Example 5). The texture improving material E for baked confectionery of Example 5 contained 2.84 parts by mass of milk protein based on 1 part by mass of phospholipid derived from milk.

なお、表1に記載した原料のうち、乳原料A、及び、バターミルク濃縮物については以下の製造方法によって得られたものであり、そのリン脂質含量及び乳タンパク質含量についても記載した。
なお、各原料中の乳リン脂質、乳タンパク質含有量は以下の通りである。
乳原料A:クリームからバターオイルを製造する際に生じる水相成分の濃縮物(リン脂質含有量3.7質量%、タンパク質含有量10.5質量%、乳固形分38質量%、及び乳固形分中のリン脂質の含有量9.7質量%、pH6.5)
バターミルク濃縮物:生クリーム(油分:47質量%)100質量部を10℃条件下でチャーニングし、続いて濾過を行って濾液(43質量部)を回収し、バターミルクを得た。続いて、得られたバターミルクを液量がおおよそ三分の一程度になるように濃縮し、バターミルク濃縮物を得た。(バターミルク濃縮物のリン脂質含有量0.53質量%、タンパク質含有量10.9質量%、乳固形分33質量%)
In addition, among the raw materials described in Table 1, the milk raw material A and the buttermilk concentrate were obtained by the following production method, and the phospholipid content and the milk protein content were also described.
The contents of milk phospholipid and milk protein in each raw material are as follows.
Milk raw material A: Concentrate of aqueous phase component generated when producing butter oil from cream (phospholipid content 3.7% by mass, protein content 10.5% by mass, milk solids 38% by mass, and milk solids) Content of 9.7 mass% of phospholipids per minute, pH 6.5)
Buttermilk concentrate: 100 parts by mass of fresh cream (oil content: 47% by mass) was charged at 10 ° C., followed by filtration to collect a filtrate (43 parts by mass) to obtain buttermilk. Subsequently, the obtained buttermilk was concentrated so that the amount of the liquid became about one-third, to obtain a buttermilk concentrate. (Phospholipid content of buttermilk concentrate 0.53 mass%, protein content 10.9 mass%, milk solid content 33 mass%)

Figure 0006633284
Figure 0006633284

〔実施例6〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水21.5質量部、焼菓子用食感改良材Aを8質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Aを得た。
[Example 6]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase, an aqueous phase consisting of 21.5 parts by mass of water and 8 parts by mass of the texture-improving material A for baked confectionery was added, followed by stirring and emulsification, followed by rapid cooling and plasticization, and the water-in-oil emulsion for baked confectionery of the present invention. The product A was obtained.

続いて、焼菓子用油中水型乳化物Aを用いて、次の配合及び製法により型抜きクッキー生地Aを製造した。
(配合)
薄力粉100質量部、砂糖40質量部、食塩0.7質量部、重炭安1質量部、重曹1質量部、水5質量部、焼菓子用油中水型乳化物A60質量部
(製法)
卓上ミキサー(ケンウッドミキサー)に焼菓子用油中水型乳化物A及び砂糖を投入し、軽く混合した後、中速で2分クリーミングした。次いで、あらかじめ水、食塩及び重炭安を混合した水相を少しずつ加えて攪拌・混合した(比重:0.9)。更に薄力粉及び重曹を加えた後、低速で1分混合して本発明の焼菓子生地である型抜きクッキー生地Aを得た。得られた型抜きクッキー生地Aを、厚さ4ミリ、直径4センチの丸型で抜き、オーブン(フジサワ社製)で180℃にて10分焼成した後、25℃で40分冷却し、包装して本発明の焼菓子である型抜きクッキーAを得た。
Subsequently, using the water-in-oil emulsion A for baked confectionery, die-cut cookie dough A was produced by the following formulation and production method.
(Combination)
100 parts by weight of flour, 40 parts by weight of sugar, 0.7 parts by weight of sodium chloride, 1 part by weight of bicarbonate, 1 part by weight of sodium bicarbonate, 5 parts by weight of water, 60 parts by weight of water-in-oil emulsion A for baked confectionery (production method)
The water-in-oil emulsion A for baked confectionery and sugar were put into a table mixer (Kenwood mixer), mixed lightly, and then creamed at medium speed for 2 minutes. Next, an aqueous phase in which water, salt and ammonium bicarbonate were previously mixed was added little by little, followed by stirring and mixing (specific gravity: 0.9). After further adding flour and baking soda, the mixture was mixed at low speed for 1 minute to obtain a cut cookie dough A, which is a baked confectionery dough of the present invention. The obtained die-cut cookie dough A was cut out with a 4 mm-thick, 4 cm-diameter round die, baked in an oven (manufactured by Fujisawa) at 180 ° C. for 10 minutes, cooled at 25 ° C. for 40 minutes, and packaged. As a result, a die-cut cookie A as a baked confectionery of the present invention was obtained.

〔実施例7〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水21.5質量部、焼菓子用食感改良材Bを8質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Bを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Bを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地B及び型抜きクッキーBを製造した。
[Example 7]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase was added 21.5 parts by mass of water and an aqueous phase composed of 8 parts by mass of the texture improving material B for baked confectionery, followed by stirring and emulsification, followed by rapid cooling and plasticization, and the water-in-oil emulsion for baked confectionery of the present invention. The product B was obtained.
Subsequently, except that the water-in-oil type emulsion for baked confectionery B was used instead of the water-in-oil type emulsion for baked confectionery A, the die-cut cookie dough B and the die-cut cookie of the present invention were prepared in the same manner as in Example 1. B was produced.

〔実施例8〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水21.5質量部、焼菓子用食感改良材Cを8質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Cを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Cを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地C及び型抜きクッキーCを製造した。
Example 8
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase, 21.5 parts by mass of water and an aqueous phase consisting of 8 parts by mass of the texture improving material C for baked confectionery were added, followed by stirring and emulsification, followed by rapid cooling and plasticization, and the water-in-oil type emulsion for baked confectionery of the present invention. The product C was obtained.
Subsequently, the stamped cookie dough C and the stamped cookie of the present invention were prepared in the same manner as in Example 1, except that the water-in-oil type emulsion for baked confectionery A was replaced with the water-in-oil type emulsion C for baked confectionery. C was produced.

〔実施例9〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水21.5質量部、焼菓子用食感改良材Dを8質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Dを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Dを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地D及び型抜きクッキーDを製造した。
[Example 9]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase, an aqueous phase consisting of 21.5 parts by mass of water and 8 parts by mass of the texture-improving material D for baked confectionery was added, followed by stirring and emulsification, followed by rapid cooling and plasticization, and the water-in-oil type emulsion for baked confectionery of the present invention. The product D was obtained.
Subsequently, the stamped cookie dough D and the stamped cookie of the present invention were prepared in the same manner as in Example 1 except that the water-in-oil type emulsion for baked confectionery A was replaced with the water-in-oil type emulsion for baked confectionery D. D was manufactured.

〔実施例10〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水27.5質量部、焼菓子用食感改良材Aを2質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Eを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Eを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地E及び型抜きクッキーEを製造した。
[Example 10]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase, 27.5 parts by weight of water and an aqueous phase consisting of 2 parts by weight of the texture improving material A for baked confectionery were added, followed by stirring and emulsification, followed by rapid plasticization, and the water-in-oil emulsion for baked confectionery of the present invention. The product E was obtained.
Subsequently, except that the water-in-oil type emulsion for baked confectionery A was used in place of the water-in-oil type emulsion for baked confectionery E, the die-cut cookie dough E and the die-cut cookie of the present invention were prepared in the same manner as in Example 1. E was produced.

〔実施例11〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水15.5質量部、焼菓子用食感改良材Aを14質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Fを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Fを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地F及び型抜きクッキーFを製造した。
[Example 11]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase, 15.5 parts by mass of water and an aqueous phase comprising 14 parts by mass of the texture-improving material A for baked confectionery were added, followed by stirring and emulsification, followed by rapid cooling and plasticization, and the water-in-oil type emulsion for baked confectionery of the present invention. The product F was obtained.
Subsequently, the die-cut cookie dough F and the die-cut cookie of the present invention were prepared in the same manner as in Example 1 except that the water-in-oil type emulsion for baked confectionery A was replaced with the water-in-oil type emulsion for baked confectionery F. F was produced.

〔実施例12〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水9.5質量部、焼菓子用食感改良材Aを20質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Gを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Gを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地G及び型抜きクッキーGを製造した。
[Example 12]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase was added an aqueous phase consisting of 9.5 parts by mass of water and 20 parts by mass of the texture-improving material A for baked confectionery. The product G was obtained.
Subsequently, except that the water-in-oil type emulsion for baked confectionery G was used instead of the water-in-oil type emulsion for baked confectionery A, the die-cut cookie dough G and the die-cut cookie of the present invention were prepared in the same manner as in Example 1. G was produced.

〔実施例13〕
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水21.5質量部、焼菓子用食感改良材Eを8質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、本発明の焼菓子用油中水型乳化物Hを得た。
続いて、焼菓子用油中水型乳化物Aに代えて焼菓子用油中水型乳化物Hを用いた以外、実施例1と同様にして本発明の型抜きクッキー生地H及び型抜きクッキーHを製造した。
[Example 13]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. To this oil phase, 21.5 parts by mass of water and an aqueous phase consisting of 8 parts by mass of the texture improving material E for baked confectionery are added, and after stirring and emulsification, quenched and plasticized, the water-in-oil type emulsion for baked confectionery of the present invention is obtained. The product H was obtained.
Subsequently, the die-cut cookie dough H and the die-cut cookie of the present invention were prepared in the same manner as in Example 1 except that the water-in-oil type emulsion for baked confectionery A was used instead of the water-in-oil type emulsion for baked confectionery A. H was produced.

[比較例1]
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水29.5質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、比較例である油中水型乳化物Iを得た。
続いて、焼菓子用油中水型乳化物Aに代えて油中水型乳化物Iを用いた以外、実施例1と同様にして比較例である型抜きクッキー生地I及び型抜きクッキーIを製造した。
[Comparative Example 1]
0.5 parts by mass of glycerin fatty acid ester was added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. An aqueous phase consisting of 29.5 parts by mass of water was added to the oil phase, and the mixture was stirred and emulsified, followed by rapid cooling and plasticization to obtain a water-in-oil emulsion I as a comparative example.
Subsequently, except that the water-in-oil type emulsion I was used in place of the water-in-oil type emulsion A for baked confectionery, the die cut cookie dough I and the die cut cookie I, which are comparative examples, were prepared in the same manner as in Example 1. Manufactured.

[比較例2]
パーム油とナタネ油を9:1の質量比で混合した配合油70質量部にグリセリン脂肪酸エステル0.5質量部、レシチン1質量部を添加し、65℃に加温溶解して油相を得た。この油相へ、水28.5質量部からなる水相を加え、撹拌乳化後、急冷可塑化し、比較例である油中水型乳化物Jを得た。
続いて、焼菓子用油中水型乳化物Aに代えて油中水型乳化物Jを用いた以外、実施例1と同様にして比較例である型抜きクッキー生地J及び型抜きクッキーJを製造した。
[Comparative Example 2]
0.5 part by mass of glycerin fatty acid ester and 1 part by mass of lecithin are added to 70 parts by mass of a blended oil obtained by mixing palm oil and rapeseed oil at a mass ratio of 9: 1, and heated and dissolved at 65 ° C. to obtain an oil phase. Was. An aqueous phase consisting of 28.5 parts by mass of water was added to the oil phase, and the mixture was stirred and emulsified, followed by quenching and plasticization to obtain a water-in-oil emulsion J as a comparative example.
Subsequently, except that the water-in-oil type emulsion J was used instead of the water-in-oil type emulsion A for baked confectionery, a die cut cookie dough J and a die cut cookie J which were comparative examples were prepared in the same manner as in Example 1. Manufactured.

[実施例14]
比較例1で得られた油中水型乳化物Iを用いて、次の配合及び製法により型抜きクッキー生地K及び型抜きクッキーKを製造した。
(配合)
薄力粉100質量部、砂糖40質量部、食塩0.7質量部、重炭安1質量部、重曹1質量部、水2質量部、油中水型乳化物Iを60質量部、焼菓子用食感改良材A5質量部
(製法)
卓上ミキサー(ケンウッドミキサー)に油中水型乳化物I及び砂糖を投入し、軽く混合した後、中速で2分クリーミングした。次いで、あらかじめ水、焼菓子用食感改良材A、食塩及び重炭安を混合した水相を少しずつ加えて攪拌・混合した(比重:0.9)。更に薄力粉及び重曹を加えた後、低速で1分混合して本発明の焼菓子生地である型抜きクッキー生地Kを得た。得られた型抜きクッキー生地Kを、厚さ4ミリ、直径4センチの丸型で抜き、オーブン(フジサワ社製)で180℃にて10分焼成した後、25℃で40分冷却し、包装して本発明の型抜きクッキーKを得た。
[Example 14]
Using the water-in-oil type emulsion I obtained in Comparative Example 1, a die cut cookie dough K and a die cut cookie K were produced by the following formulation and production method.
(Combination)
100 parts by weight of flour, 40 parts by weight of sugar, 0.7 parts by weight of sodium chloride, 1 part by weight of bicarbonate, 1 part by weight of baking soda, 2 parts by weight of water, 60 parts by weight of water-in-oil emulsion I, food for baked confectionery A5 parts by weight of a feeling improving material (production method)
The water-in-oil emulsion I and sugar were charged into a table mixer (Kenwood mixer), mixed lightly, and then creamed at medium speed for 2 minutes. Next, an aqueous phase in which water, the texture-improving material A for baked confectionery, salt and ammonium bicarbonate were previously added little by little and stirred and mixed (specific gravity: 0.9). After further adding flour and baking soda, the mixture was mixed at low speed for 1 minute to obtain a cut cookie dough K which is a baked confectionery dough of the present invention. The obtained die-cut cookie dough K was cut out with a 4 mm-thick, 4 cm-diameter round die, baked in an oven (manufactured by Fujisawa) at 180 ° C. for 10 minutes, cooled at 25 ° C. for 40 minutes, and packed. Thus, a die-cut cookie K of the present invention was obtained.

焼菓子の評価
得られた本発明の焼菓子である型抜きクッキーA〜H及びKと、比較のための焼菓子である型抜きクッキーI〜Jは、10人のパネラーにより下記[評価基準]に従って官能評価をさせ、10人のパネラーの合計点を評価点数とし、結果を下記のようにして〔表2〕に示した。
44〜50点:◎+、37〜43点:◎、30〜36点:○、10〜29点:△、9点以下:×
[評価基準]
・口どけ
5点…非常に口どけが良い。
3点…口どけが良い。
1点…口どけが悪い。
0点…非常に口どけが悪い。
・ 食感(歯切れ)
5点 …非常にサクサクした食感で、歯切れも良好である。
3点 …サクサクした食感で、歯切れも良好である。
1点…やや硬い食感で、歯切れが悪い。
0点…硬い食感で、歯切れが悪い。
Evaluation of baked confectionery The obtained baked confectionery of the present invention, die-cut cookies A to H and K, and baked confectionery for comparison, die-cut cookies I to J were evaluated by 10 panelists as follows [Evaluation criteria]. The sensory evaluation was performed according to the above, and the total score of 10 panelists was used as the evaluation score. The results are shown in [Table 2] as follows.
44-50 points: ++, 37-43 points: 、, 30-36 points: ○, 10-29 points: Δ, 9 points or less: ×
[Evaluation criteria]
・ 5 lipsticks: Very good lipstick.
3 points ... Good mouthfeel.
1 point ... Mouth is bad.
0 point: very bad.
・ Texture (crisp)
5 points: Very crispy texture and good crispness.
3 points: Crispy texture and good crispness.
1 point: Slightly hard texture and poor crispness.
0 point: Hard texture, poor crispness.

Figure 0006633284
Figure 0006633284

Claims (8)

乳由来のリン脂質及び乳タンパク質を含有し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部含有する水性液(ただし、ゲル化剤を含有する水性液を除く)であることを特徴とする、焼菓子用食感改良材。 An aqueous liquid containing milk-derived phospholipids and milk protein, and containing 1 to 15 parts by mass of milk protein per 1 part by mass of milk-derived phospholipids (excluding an aqueous liquid containing a gelling agent) . A texture improving material for baked confectionery, characterized in that: pH2.5〜6.4である、請求項1記載の焼菓子用食感改良材。   The texture improving material for baked confectionery according to claim 1, which has a pH of 2.5 to 6.4. 有機酸を含有する、請求項1又は2記載の焼菓子用食感改良材。   The texture-improving material for baked confectionery according to claim 1 or 2, which contains an organic acid. 請求項1〜3いずれか一項記載の焼菓子用食感改良材を含有する、焼菓子用油中水型乳化物。   A water-in-oil emulsion for baked confectionery, comprising the texture improving material for baked confectionery according to claim 1. 請求項1〜3いずれか一項記載の焼菓子用食感改良材を含有する、焼菓子生地。   A baked confectionery material containing the texture improving material for baked confectionery according to any one of claims 1 to 3. 請求項4記載の焼菓子用油中水型乳化物を含有する焼菓子生地。   A baked goods containing the water-in-oil emulsion for baked goods according to claim 4. 請求項5又は6記載の焼菓子生地を焼成してなる焼菓子。   A baked confectionery obtained by baking the baked confectionery material according to claim 5 or 6. 乳由来のリン脂質及び乳タンパク質を含有し、乳由来のリン脂質1質量部に対し乳タンパク質を1〜15質量部含有する水性液(ただし、ゲル化剤を含有する水性液を除く)を含有させることを特徴とする焼菓子の食感改良方法。 Contains an aqueous liquid containing milk-derived phospholipids and milk protein, and 1 to 15 parts by weight of milk protein per 1 part by weight of milk-derived phospholipids (excluding an aqueous liquid containing a gelling agent) A method for improving the texture of baked confectionery, characterized in that the method comprises:
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