JP6628580B2 - Hair cosmetic composition - Google Patents
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- JP6628580B2 JP6628580B2 JP2015233311A JP2015233311A JP6628580B2 JP 6628580 B2 JP6628580 B2 JP 6628580B2 JP 2015233311 A JP2015233311 A JP 2015233311A JP 2015233311 A JP2015233311 A JP 2015233311A JP 6628580 B2 JP6628580 B2 JP 6628580B2
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Description
本発明は、液状炭化水素とシア脂とが配合されており、シア脂の分散性が良好な毛髪化粧料組成物に関するものである。 TECHNICAL FIELD The present invention relates to a hair cosmetic composition containing a liquid hydrocarbon and a shea fat, and having a good dispersibility of the shea fat.
従来から、整髪剤などの毛髪化粧料の構成成分として、流動パラフィンなどの液状炭化水素やシア脂が、しばしば使用されている（特許文献１など）。こうした毛髪化粧料において、液状炭化水素は毛髪の艶や保湿感を向上させる機能を発揮し、また、シア脂は毛髪の感触を向上させる機能を発揮するといわれている。 Conventionally, liquid hydrocarbons such as liquid paraffin and shea butter are often used as constituents of hair cosmetics such as hair styling agents (Patent Document 1 and the like). In such hair cosmetics, it is said that the liquid hydrocarbon exhibits a function of improving the gloss and moisturizing feeling of the hair, and the shea butter exhibits a function of improving the feel of the hair.
ところが、液状炭化水素とシア脂とを配合した毛髪化粧料においては、シア脂が粒状に析出しやすく、特にシア脂の配合量が多くなると、その析出が顕著になることが、本発明者らの検討により明らかとなった。 However, in hair cosmetics containing a liquid hydrocarbon and shea butter, shea butter is likely to precipitate in a granular form, and in particular, when the amount of shea butter is increased, the precipitation becomes remarkable. It became clear by examination of.
本発明は、上記事情に鑑みてなされたものであり、その目的は、液状炭化水素とシア脂とが配合されており、シア脂の分散性が良好な毛髪化粧料組成物を提供することにある。 The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a hair cosmetic composition in which a liquid hydrocarbon and shea fat are blended, and the dispersibility of the shea fat is good. is there.
上記目的を達成し得た本発明の毛髪化粧料組成物は、下記（Ａ）〜（Ｃ）の成分が配合されており、水の配合量が２質量％以下であることを特徴とするものである。
（Ａ）液状炭化水素
（Ｂ）シア脂
（Ｃ）（モリンガ油／水添モリンガ油）エステルズ
The hair cosmetic composition of the present invention, which has achieved the above object, is characterized by containing the following components (A) to (C) and having a water content of 2% by mass or less. It is.
(A) Liquid hydrocarbon (B) Shea butter (C) (moringa oil / hydrogenated moringa oil) esters
本発明によれば、液状炭化水素とシア脂とが配合されており、シア脂の分散性が良好な毛髪化粧料組成物を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the liquid hydrocarbon and the shea fat are mix | blended, and the dispersibility of a shea fat can provide the favorable hair cosmetic composition.
本発明の毛髪化粧料組成物は、水の配合量が２質量％以下といった水の配合量が極めて少ないもの、実質的には、いわゆる非水系の毛髪化粧料組成物であり、（Ａ）液状炭化水素と、（Ｂ）シア脂と、（Ｃ）（モリンガ油／水添モリンガ油）エステルズとが配合されている。本発明の毛髪化粧料組成物は、整髪剤として特に有用である。 The hair cosmetic composition of the present invention is a so-called non-aqueous hair cosmetic composition in which the amount of water is very small, such as 2% by mass or less, and (A) a liquid Hydrocarbon, (B) shea butter, and (C) (moringa oil / hydrogenated moringa oil) esters are blended. The hair cosmetic composition of the present invention is particularly useful as a hairdressing agent.
本発明の毛髪化粧料組成物において、（Ａ）成分である液状炭化水素は、主に、毛髪に艶や保湿感を付与するための成分であり、また、後述する（Ｅ）ポリエチレンの溶媒としても機能する成分である。 In the hair cosmetic composition of the present invention, the liquid hydrocarbon, which is the component (A), is mainly a component for imparting gloss and moisturizing feeling to the hair, and is used as a solvent for the polyethylene (E) described below. Is also a functional component.
液状炭化水素としては、少なくとも２０〜５０℃の温度範囲において液状であるもの（２０〜５０℃の温度範囲で液状であればよく、５０℃以上の温度や２０℃未満の温度においても液状であるものであってもよい）が挙げられ、具体的には、流動パラフィン、流動イソパラフィン、スクワランなどが挙げられ、頭皮への刺激を抑止する観点からは、流動パラフィンが良い。 As the liquid hydrocarbon, those which are liquid at least in a temperature range of 20 to 50 ° C. (the liquid hydrocarbons may be liquids in a temperature range of 20 to 50 ° C., and are liquid even at a temperature of 50 ° C. or more and a temperature of less than 20 ° C.) Liquid paraffin, liquid isoparaffin, squalane, etc., and liquid paraffin is preferred from the viewpoint of suppressing irritation to the scalp.
毛髪化粧料組成物における（Ａ）成分の配合量は、１０〜６０質量％であることが好ましく、毛髪化粧料組成物の高温環境下での剤型の安定性を高める観点からは、４０質量％以下であることがより好ましい。 The amount of the component (A) in the hair cosmetic composition is preferably from 10 to 60% by mass, and from the viewpoint of enhancing the stability of the hair cosmetic composition in a high-temperature environment, the amount is 40% by mass. % Is more preferable.
本発明の毛髪化粧料組成物において、（Ｂ）成分であるシア脂は、主に、毛髪の感触の向上や、整髪力の確保に寄与する成分である。 In the hair cosmetic composition of the present invention, the shea butter, which is the component (B), is a component that mainly contributes to improving the feel of the hair and securing hair styling power.
なお、本発明の毛髪化粧料組成物に配合するシア脂は、毛髪化粧料組成物の整髪性が向上することから、液状でないものが望ましく、具体的には、融点（凝固点）が３０〜４５℃のものが好ましい。毛髪化粧料組成物を毛髪に塗布後、ある程度の時間がたってから整髪するような場合、例えば、毛髪化粧料組成物を就寝前に毛髪に塗布し、朝に起床してから整髪するような場合には、毛髪用化粧料組成物に液状でないシア脂を配合していると、整髪にドライヤーを使用することで毛髪表面に付着しているシア脂が溶けて流動性が生じるためにヘアスタイルが整えやすくなり、また、その後に冷えてシア脂が毛髪表面で再度流動性を失うことで、整えたヘアスタイルを良好に維持することができるようになる。 The shea butter to be added to the hair cosmetic composition of the present invention is preferably not liquid because the hair styling property of the hair cosmetic composition is improved, and specifically, the melting point (freezing point) is 30 to 45. ° C is preferred. When the hair is applied after a certain period of time after applying the hair cosmetic composition to the hair, for example, when the hair cosmetic composition is applied to the hair before going to bed and the hair is woken up in the morning and then If the hair cosmetic composition contains non-liquid shea butter, a hair dryer is used for hairdressing to dissolve the shea butter adhering to the surface of the hair, causing fluidity, resulting in a hairstyle. It becomes easier to prepare, and after cooling, the shea butter loses fluidity again on the hair surface, so that the prepared hairstyle can be maintained well.
毛髪化粧料組成物における（Ｂ）成分の配合量は、毛髪の感触をより高めやすくなることから、５質量％以上であることが好ましく、１０質量％以上であることがより好ましく、また、（Ｂ）成分の粒状析出をより抑えやすくなることから、５０質量％以下であることが好ましく、２５質量％以下であることがより好ましく、２０質量％以下であることが更に好ましく、１５質量％以下であることが特に好ましい。 The amount of the component (B) in the hair cosmetic composition is preferably 5% by mass or more, more preferably 10% by mass or more, because the feel of the hair is more easily enhanced. Since it is easier to suppress the granular precipitation of the component (B), the content is preferably 50% by mass or less, more preferably 25% by mass or less, further preferably 20% by mass or less, and more preferably 15% by mass or less. Is particularly preferred.
本発明の毛髪化粧料組成物において、（Ｃ）成分である（モリンガ油／水添モリンガ油）エステルズは、ワサビノキ種子油と水添モリンガ油とのエステル交換により得られるものであり、（Ｂ）成分であるシア脂の粒状析出を抑制して、その分散性を高めるための成分である。 In the hair cosmetic composition of the present invention, the (C) component (moringa oil / hydrogenated moringa oil) esters are obtained by transesterification of wasabi tree seed oil and hydrogenated moringa oil, and (B) It is a component for suppressing the granular precipitation of shea butter, which is a component, and for enhancing its dispersibility.
本発明の毛髪化粧料組成物において、（Ｂ）成分であるシア脂の配合量に対する（Ｃ）成分である（モリンガ油／水添モリンガ油）エステルズの配合量の比率、すなわち、（Ｂ）成分の配合量をｂ（質量％）とし、（Ｃ）成分の配合量をｃ（質量％）としたときの、比ｃ／ｂは、シア脂の粒状析出を抑制する効果がより向上することから０．５以上であることが好ましく、毛髪化粧料組成物が硬くなることを回避しやすいことから２．０以下であることが好ましく、１．５以下であることがより好ましく、１．０以下であることが更に好ましい。 In the hair cosmetic composition of the present invention, the ratio of the compounding amount of the (C) component (moringa oil / hydrogenated moringa oil) esters to the compounding amount of the shea fat as the component (B), that is, the component (B) The ratio c / b when the blending amount of b is (mass%) and the blending amount of the component (C) is c (mass%) is because the effect of suppressing granular precipitation of shea fat is further improved. It is preferably at least 0.5, and is preferably at most 2.0, more preferably at most 1.5, more preferably at most 1.0, because it is easy to avoid the hair cosmetic composition from becoming hard. Is more preferable.
本発明の毛髪化粧料組成物には、（Ｄ）液状ジメチルポリシロキサンを配合することが好ましい。（Ｄ）成分を配合することで、毛髪化粧料組成物の操作性を高めることができる。（Ｄ）成分には、例えば、化粧品原料基準一般試験法粘度測定法第１法に準拠して測定した粘度が１０〜１００ｍｍ２／ｓである液状ジメチルポリシロキサンを用いる。毛髪化粧料組成物における（Ｄ）成分の配合量は、例えば１０〜４０質量％である。 The hair cosmetic composition of the present invention preferably contains (D) a liquid dimethylpolysiloxane. By blending the component (D), the operability of the hair cosmetic composition can be improved. As the component (D), for example, a liquid dimethylpolysiloxane having a viscosity of 10 to 100 mm 2 / s measured according to the Cosmetic Ingredients Standard General Test Method, Viscosity Measurement Method 1, is used. The amount of the component (D) in the hair cosmetic composition is, for example, 10 to 40% by mass.
また、本発明の毛髪化粧料組成物には、（Ｅ）ポリエチレンを配合することが好ましい。（Ｅ）成分を配合することで、液状炭化水素や液状シリコーンといった液状油の配合量を高めても、毛髪化粧料組成物を、例えばワックス状の剤型にすることが容易となる。毛髪化粧料組成物における（Ｅ）成分の配合量は、例えば２〜８質量％である。 Further, it is preferable that the hair cosmetic composition of the present invention contains (E) polyethylene. By blending the component (E), the hair cosmetic composition can be easily made into, for example, a wax-like dosage form even when the blending amount of a liquid oil such as a liquid hydrocarbon or a liquid silicone is increased. The amount of the component (E) in the hair cosmetic composition is, for example, 2 to 8% by mass.
なお、上記の通り、（Ａ）成分である液状炭化水素は（Ｅ）成分の溶媒としても機能するため、毛髪化粧料組成物に（Ｅ）成分を配合する場合には、（Ａ）成分の配合量を、上記の好適範囲の中でもより多くすることが望ましい。 As described above, since the liquid hydrocarbon as the component (A) also functions as a solvent for the component (E), when the component (E) is blended into the hair cosmetic composition, the component (A) It is desirable to increase the blending amount within the above-mentioned preferred range.
更に、本発明の毛髪化粧料組成物には、（Ｆ）ノニオン界面活性剤を配合することが好ましい。（Ｆ）成分を配合することで、毛髪から本発明の毛髪化粧料組成物を洗い流す際に、毛髪化粧料組成物の毛髪からの落ちがより良好にとなる。 Further, the hair cosmetic composition of the present invention preferably contains (F) a nonionic surfactant. By blending the component (F), when the hair cosmetic composition of the present invention is washed away from the hair, the hair cosmetic composition can be more favorably removed from the hair.
（Ｆ）成分の具体例としては、例えば、ステアリン酸ＰＥＧ−５グリセリル、ステアリン酸ＰＥＧ−１５グリセリル、イソステアリン酸ＰＥＧ−５グリセリル、イソステアリン酸ＰＥＧ−８グリセリル、イソステアリン酸ＰＥＧ１０−グリセリル、イソステアリン酸ＰＥＧ−２０グリセリル、イソステアリン酸ＰＥＧ−２５グリセリル、イソステアリン酸ＰＥＧ−３０グリセリル、オレイン酸ＰＥＧ−５グリセリル、オレイン酸ＰＥＧ−１５グリセリル、トリイソステアリン酸ＰＥＧ−２０グリセリルなどのポリオキシエチレングリセリン脂肪酸エステル；ポリオキシエチレンセチルエーテル、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテルなどのポリオキシエチレンアルキルエーテル；ポリオキシエチレンポリオキシプロピレンセチルエーテルなどのポリオキシエチレンポリオキシプロピレンアルキルエーテル；テトラステアリン酸ソルベス−６０、テトラオレイン酸ソルベス−６、テトラオレイン酸ソルベス−３０、テトラオレイン酸ソルベス−４０、テトラオレイン酸ソルベス−６０、テトライソステアリン酸ソルベス−３０などのポリオキシエチレンソルビトール脂肪酸エステル；パルミチン酸ソルビタン、ステアリン酸ソルビタン、セスキステアリン酸ソルビタン、イソステアリン酸ソルビタン、セスキイソステアリン酸ソルビタン、オレイン酸ソルビタン、セスキオレイン酸ソルビタンなどのソルビタン脂肪酸エステル；ショ糖脂肪酸エステル；などが挙げられる。 Specific examples of the component (F) include, for example, PEG-5 glyceryl stearate, PEG-15 glyceryl stearate, PEG-5 glyceryl isostearate, PEG-8 glyceryl isostearate, PEG10-glyceryl isostearate, and PEG-isostearate. Polyoxyethylene glycerin fatty acid esters such as 20 glyceryl, PEG-25 glyceryl isostearate, PEG-30 glyceryl isostearate, PEG-5 glyceryl oleate, PEG-15 glyceryl oleate, PEG-20 glyceryl triisostearate; polyoxyethylene Polyoxyethylene alkyl ethers such as cetyl ether, polyoxyethylene lauryl ether, and polyoxyethylene oleyl ether; Polyoxyethylene polyoxypropylene alkyl ethers such as oxypropylene cetyl ether; sorbeth-60 tetrastearate, sorbeth-6 tetraoleate, sorbeth-30 tetraoleate, sorbeth-40 tetraoleate, sorbeth-60 tetraoleate, Polyoxyethylene sorbitol fatty acid esters such as sorbeth-30 tetraisostearate; sorbitan fatty acid esters such as sorbitan palmitate, sorbitan stearate, sorbitan sesquistearate, sorbitan isostearate, sorbitan sesquiisostearate, sorbitan oleate, sorbitan sesquioleate Sucrose fatty acid esters, and the like.
毛髪化粧料組成物における（Ｆ）成分の配合量は、例えば１〜５質量％である。 The compounding amount of the component (F) in the hair cosmetic composition is, for example, 1 to 5% by mass.
また、本発明の毛髪化粧料組成物には、上記の（Ａ）〜（Ｆ）の各成分以外にも、例えば、通常の整髪剤などの毛髪化粧料に配合されている各種の成分を、本発明の効果を損なわない範囲で配合することができる。このような成分としては、例えば、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、高級アルコール、多価アルコール、糖類、エステル油、油脂、脂肪酸、炭化水素、ロウ、シリコーン、高分子化合物、アミノ酸、動植物抽出物、微生物由来物、無機化合物、香料、防腐剤、金属イオン封鎖剤、紫外線吸収剤などが挙げられる〔ただし、上記の各成分のうち、（Ａ）〜（Ｆ）の各成分に該当するものを除く〕。 In addition to the components (A) to (F), the hair cosmetic composition of the present invention may contain, for example, various components blended in hair cosmetics such as ordinary hair styling agents. It can be blended within a range that does not impair the effects of the present invention. Such components include, for example, anionic surfactants, cationic surfactants, amphoteric surfactants, higher alcohols, polyhydric alcohols, saccharides, ester oils, oils and fats, fatty acids, hydrocarbons, waxes, silicones, and high molecular compounds , Amino acids, plant and animal extracts, microorganisms, inorganic compounds, fragrances, preservatives, sequestering agents, ultraviolet absorbers, etc. [However, among the above components, each of (A) to (F) Excludes those that fall under the components.
本発明の毛髪化粧料組成物の剤型は、クリーム状またはワックス状である。 The dosage form of the hair cosmetic composition of the present invention is creamy or waxy.
また、本発明の毛髪化粧料組成物の粘度は、例えば１００〜１００００Ｐａ・ｓである。本明細書でいう「毛髪化粧料組成物の粘度」は、応力制御型レオメーター（例えば、ＨＡＡＫＥ社製「Ｒｈｅｏ Ｓｔｒｅｓｓ ６０００」）を使用し、測定温度２５℃、コーンプレートセンサーの直径３５ｍｍ及び傾斜角２°、定常フローカーブモード、待ち時間１分、せん断速度０．７ｓ−１の条件で測定される値を意味している。 The viscosity of the hair cosmetic composition of the present invention is, for example, 100 to 10000 Pa · s. The “viscosity of the hair cosmetic composition” as used herein is measured using a stress control rheometer (eg, “Rheo Stress 6000” manufactured by HAAKE) at a measurement temperature of 25 ° C., a cone plate sensor diameter of 35 mm, and an inclination. It means a value measured under the conditions of an angle of 2 °, a steady flow curve mode, a waiting time of 1 minute, and a shear rate of 0.7 s −1 .
本発明の毛髪化粧料組成物は、例えば、適量を手に取って、濡れた毛髪または乾いた毛髪に塗布する方法により使用することができる。なお、上記の通り、例えば就寝前の毛髪に塗布しておけば、起床後などでのドライヤーを用いた整髪の際に有用である。 The hair cosmetic composition of the present invention can be used, for example, by a method in which an appropriate amount is picked up and applied to wet or dry hair. As described above, if the hair is applied to the hair before going to bed, for example, it is useful for hair styling using a dryer after getting up.
以下、実施例に基づいて本発明を詳細に述べる。ただし、下記実施例は、本発明を制限するものではない。 Hereinafter, the present invention will be described in detail based on examples. However, the following examples do not limit the present invention.
実施例１〜４
流動パラフィン〔（Ａ）成分〕、シア脂〔（Ｂ）成分。融点３０〜４０℃〕、（モリンガ油／水添モリンガ油）エステルズ〔（Ｃ）成分〕、液状ジメチルポリシロキサン、ポリエチレン〔（Ｅ）成分〕、テトラオレイン酸ソルベス−３０〔（Ｆ）成分。ＨＬＢ：１１．５〕、ミツロウ、ヒマワリ種子ロウ、ベヘントリモニウムメトサルフェート、セタノール、１，３−ブチレングリコール、２−フェノキシエタノール（防腐剤）および香料を、表１に示す質量比率で配合して、毛髪化粧料組成物を調製した。
Examples 1-4
Liquid paraffin [component (A)], shea butter [component (B). Melting point 30-40 ° C], (moringa oil / hydrogenated moringa oil) esters [(C) component], liquid dimethylpolysiloxane, polyethylene [(E) component], Solves-30 tetraoleate [(F) component. HLB: 11.5], beeswax, sunflower seed wax, behentrimonium methosulfate, cetanol, 1,3-butylene glycol, 2-phenoxyethanol (preservative) and fragrance were blended in the mass ratio shown in Table 1, A hair cosmetic composition was prepared.
毛髪化粧料組成物の調製は、防腐剤および香料以外の成分を９０℃程度に加熱しながら混合し、その後６０℃以下に冷却してから防腐剤および香料を添加することにより行った。 The preparation of the hair cosmetic composition was carried out by mixing components other than the preservative and the fragrance while heating it to about 90 ° C., then cooling the mixture to 60 ° C. or lower, and then adding the preservative and the fragrance.
比較例１〜５
表２に示すように、（モリンガ油／水添モリンガ油）エステルズなどを配合せず、流動パラフィンおよびシア脂の配合量を変更した以外は、実施例１などと同様にして毛髪化粧料組成物を調製した。
Comparative Examples 1 to 5
As shown in Table 2, a hair cosmetic composition was prepared in the same manner as in Example 1 and the like, except that (moringa oil / hydrogenated moringa oil) esters and the like were not blended and the blending amounts of liquid paraffin and shea butter were changed. Was prepared.
実施例および比較例の各毛髪化粧料組成物について、２０〜３０℃の環境下で保管した後に、その表面を目視観察することで、シア脂の粒状析出の有無を調べた。
それらの結果を表１および表２に併記する。
About each hair cosmetic composition of an Example and a comparative example, after storing in 20-30 degreeC environment, the presence or absence of granular precipitation of shea butter was investigated by visually observing the surface.
The results are also shown in Tables 1 and 2.
なお、表１および表２には、毛髪化粧料組成物の調製初期にシア脂の粒状析出が認められなかったものを「○」で示し、毛髪化粧料組成物の調製初期からシア脂の粒状析出が認められたものを「×」で示す。また、表１および表２において、「比ｃ／ｂ」は、（Ｂ）成分であるシア脂の配合量ｂに対する、（Ｃ）成分である（モリンガ油／水添モリンガ油）エステルズの配合量ｃの比率を意味し、「比ａ／ｂ」は、（Ｂ）成分であるシア脂の配合量ｂに対する、（Ａ）成分である流動パラフィンの配合量ａの比率を意味している（比ｃ／ｂ、比ａ／ｂのいずれも、質量基準での配合量の比率である）。 In Tables 1 and 2, those in which no shea fat was precipitated in the initial stage of the preparation of the hair cosmetic composition were indicated by “○”, and granules of the shea fat were observed from the beginning of the preparation of the hair cosmetic composition. Those for which precipitation was observed are indicated by "x". In Tables 1 and 2, the “ratio c / b” is the compounding amount of the (C) component (moringa oil / hydrogenated moringa oil) esters with respect to the compounding amount b of the shea butter component (B). The “ratio a / b” means the ratio of the blending amount a of the liquid paraffin as the component (A) to the blending amount b of the shea butter as the component (B) (ratio a / b). Both c / b and ratio a / b are the ratios of the blending amounts on a mass basis.)
表１に示す通り、（Ａ）〜（Ｃ）の各成分が配合されており、かつ水が配合されていない実施例１〜４の毛髪化粧料組成物では、比ｃ／ｂが大きいほど、２週間程度の保管後におけるシア脂の粒状析出が抑制されていた。 As shown in Table 1, in the hair cosmetic compositions of Examples 1 to 4 in which the components (A) to (C) were blended and water was not blended, as the ratio c / b was larger, Granular precipitation of shea butter after storage for about two weeks was suppressed.
これに対し、表２に示す通り、（モリンガ油／水添モリンガ油）エステルズを配合していない比較例１〜５の毛髪化粧料組成物では、シア脂と流動パラフィンとの配合比率を変化させても、調製初期からシア脂の粒状析出が生じており、その分散性が実施例の毛髪化粧料組成物よりも劣っていた。
On the other hand, as shown in Table 2, in the hair cosmetic compositions of Comparative Examples 1 to 5 which did not contain (moringa oil / hydrogenated moringa oil) esters, the mixing ratio of shea fat and liquid paraffin was changed. However, granular precipitation of shea butter occurred from the initial stage of preparation, and its dispersibility was inferior to that of the hair cosmetic composition of Example.
Claims (7)
（Ａ）液状炭化水素
（Ｂ）シア脂
（Ｃ）（モリンガ油／水添モリンガ油）エステルズ A hair cosmetic composition comprising the following components (A) to (C), wherein the amount of the following (B) is 25% by mass or less, and the amount of water is 2% by mass or less. object.
(A) Liquid hydrocarbon (B) Shea butter (C) (moringa oil / hydrogenated moringa oil) esters
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