JP6526258B2 - System and method for preparation and application of non-portland cementitious materials - Google Patents

System and method for preparation and application of non-portland cementitious materials Download PDF

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JP6526258B2
JP6526258B2 JP2017568460A JP2017568460A JP6526258B2 JP 6526258 B2 JP6526258 B2 JP 6526258B2 JP 2017568460 A JP2017568460 A JP 2017568460A JP 2017568460 A JP2017568460 A JP 2017568460A JP 6526258 B2 JP6526258 B2 JP 6526258B2
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ジェームズ カマリ,ユージーン
ジェームズ カマリ,ユージーン
シュレル,アンドレアス
ジョージ ベンズ,ロバート
ジョージ ベンズ,ロバート
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C9/00General arrangement or layout of plant
    • B28C9/04General arrangement or layout of plant the plant being mobile, e.g. mounted on a carriage or a set of carriages
    • B28C9/0454Self-contained units, i.e. mobile plants having storage containers for the ingredients
    • B28C9/0463Self-contained units, i.e. mobile plants having storage containers for the ingredients with a mixing discharge trough with a free end, e.g. provided with a mixing screw or pivotable about a vertical or horizontal axis
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • CCHEMISTRY; METALLURGY
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • C04B7/153Mixtures thereof with other inorganic cementitious materials or other activators
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • C04B7/153Mixtures thereof with other inorganic cementitious materials or other activators
    • C04B7/1535Mixtures thereof with other inorganic cementitious materials or other activators with alkali metal containing activators, e.g. sodium hydroxide or waterglass
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D15/00Handling building or like materials for hydraulic engineering or foundations
    • E02D15/02Handling of bulk concrete specially for foundation or hydraulic engineering purposes
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G21/00Preparing, conveying, or working-up building materials or building elements in situ; Other devices or measures for constructional work
    • E04G21/02Conveying or working-up concrete or similar masses able to be heaped or cast
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00146Sprayable or pumpable mixtures
    • C04B2111/00155Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Mechanical Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
  • Combustion & Propulsion (AREA)
  • Dispersion Chemistry (AREA)
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Description

関連出願の相互参照
本出願は、2015年5月6日に米国特許商標庁に出願された米国特許出願第14/705,534号に対する優先権を主張する。この開示の全てを援用して本明細書の記載の一部とする。
This application claims priority to US Patent Application No. 14 / 705,534, filed May 6, 2015, to the US Patent and Trademark Office. The entire disclosure of this disclosure is incorporated herein by reference.

本開示は、建設材料に関し、より詳細には、建設材料の作製及び塗布方法に関する。   The present disclosure relates to construction materials, and more particularly, to methods of making and applying construction materials.

下水管の修復並びにコンクリートの修復及び構築分野における既存の方法は、修復又は構築が必要な面に向けて空気圧により投射されるショットクリートの塗布を含み得る。このショットクリートは、基本コンクリートに含まれる材料、例えば、砂、ポルトランドセメント、及び液体を含む。特定の作業現場において、このショットクリートは、乾式混合又は湿式混合のいずれかの形態であり得る。用語「乾式混合」は、一般的に、乾燥状態での材料の一部又は全部を、ホースを介してノズルに空気圧移動させ、ノズルにて作業者が、液体の乾燥混合物への付加を制御し、次いで、混合された物質を投射する工程を含む。反対に、用語「湿式混合」は、一般的に、予め混合されている、液体を含むコンクリートを、投射前にホースを通して移動させる工程を含む。   Existing methods in the field of sewer repair and concrete repair and construction may include the application of shotcrete that is projected pneumatically to the surface that needs repair or construction. The shotcrete comprises the materials contained in the base concrete, such as sand, portland cement and liquid. At a particular worksite, the shotcrete may be in the form of either dry or wet mixing. The term "dry mixing" generally refers to pneumatically moving some or all of the material in a dry state through a hose to a nozzle where the operator controls the addition of liquid to the dry mixture. , And then, projecting the mixed substance. Conversely, the term "wet mixing" generally involves moving the premixed liquid-containing concrete through a hose prior to projection.

幾つかの企業が、幾らかの利益を得る為に、ショットクリートの材料組成を変更しようとしてきた。従って、幾つかの方法は、ジオポリマーの使用を含み得る。しかし、これらの材料は、しばしば、これらの製品に固有の有機材料が原因で、腐食され易い。例えば、ミリケン(Milliken)社(登録商標)は、様々な製品を、GeoSprayTM及びGeoSprayTMAMSの製品ラインで製造している。AMS製品は、GeoSprayTM製品の前処理及び/又は後処理品として用いられ得る。GeoSprayは、ポルトランドセメント系であり、含まれるジオポリマーの割合が非常に小さい。この混合物は酸安定性ではない。AMSは、ポルトランドセメント系コンクリートへの酸の影響、及び、ポルトランドセメント系材料で生じる微生物誘発腐食に対して有効な有機物を含む。 Several companies have tried to change the material composition of the shotcrete to gain some benefit. Thus, some methods may involve the use of geopolymers. However, these materials are often susceptible to corrosion due to the organic materials inherent in these products. For example, Milliken (Milliken) Corporation (R), a variety of products are manufactured in line of GeoSpray TM and GeoSpray TM AMS. AMS product can be used as before GeoSpray TM product processing and / or post-treatment products. GeoSpray is a Portland cement-based and contains a very small proportion of geopolymers. This mixture is not acid stable. AMS contains the effect of acid on Portland cement concrete and organics that are effective against microbial induced corrosion that occurs in Portland cement materials.

第1の実施態様において、建材を塗布する為の方法が提供される。この方法は、高炉スラグ材料、ジオポリマー材料、アルカリ系粉体、及び砂を、バッチング及び混合装置にて混合して非ポルトランドセメント系材料を生成する工程を含み得る。また、この方法は、前記非ポルトランドセメント系材料を、前記バッチング及び混合装置から、導管を介してノズルに移送し、そして、前記ノズルにて、前記移送された非ポルトランドセメント系材料を液体と組み合わせて、部分的に液化された非ポルトランドセメント系材料を生成する工程も含み得る。さらに、この方法は、前記部分的に液化された非ポルトランドセメント系材料を、空気圧を用いて面に塗布する工程も含み得る。   In a first embodiment, a method is provided for applying a building material. The method may include mixing blast furnace slag material, geopolymer material, alkaline powder, and sand in a batching and mixing apparatus to produce non-portland cementitious material. Also, the method transfers the non-Portland cement based material from the batching and mixing device through a conduit to a nozzle, and combines the transferred non-Portland cement based material with a liquid at the nozzle It may also include the step of producing a partially liquefied non-Portland cement based material. In addition, the method may also include the step of applying the partially liquefied non-Portland cement based material to a surface using air pressure.

以下の特徴の1以上が含まれ得る。幾つかの実施形態において、前記ジオポリマー材料が、火山岩粉又は軽石の少なくとも一方である。前記アルカリ系粉体がケイ酸塩を含み得る。混合する工程が乾式混合として行われ得る。前記非ポルトランドセメント系材料が無機物であり得る。前記混合する工程が、移動式のバッチング及び混合車両にて行われ得る。前記非ポルトランドセメント系材料が、粘土、片麻岩、花崗岩、石英粗面岩、安山岩、ピクライト、カリウム長石、曹長石、軽石、又はゼオライトのうちの少なくとも1つを含み得る。前記混合する工程が、前記非ポルトランドセメント系材料を前記バッチング及び混合装置から受け取るように構成されたポータブルガンにて混合する工程を含み得る。前記非ポルトランドセメント系材料の構成要素が、約2500〜5000cm/gのブレーン微細値を含み得る。 One or more of the following features may be included. In some embodiments, the geopolymer material is at least one of volcanic rock and pumice. The alkaline powder may include silicate. The step of mixing may be performed as dry mixing. The non-Portland cement based material may be inorganic. The mixing may be performed on a mobile batching and mixing vehicle. The non-Portland cement based material may include at least one of clay, gneiss, granite, quartz trachyte, andesite, piclite, potassium feldspar, albite, pumice, or zeolite. The mixing may include mixing with a portable gun configured to receive the non-Portland cement-based material from the batching and mixing apparatus. The components of the non-Portland cementitious material may include brane fines of about 2500-5000 cm 2 / g.

別の実施形態において、建材を塗布する為のシステムが提供される。このシステムは、高炉スラグ材料、ジオポリマー材料、アルカリ系粉体、及び砂をバッチ処理及び混合して非ポルトランドセメント系材料を生成するように構成された、バッチング及び混合装置を含み得る。また、このシステムは、前記バッチング及び混合装置から前記非ポルトランドセメント系材料を移送するように構成された導管も含み得る。さらに、このシステムは、前記非ポルトランドセメント系材料を受け取るように、そして、前記移送された非ポルトランドセメント系材料を液体と組み合わせて、部分的に液化された非ポルトランドセメント系材料を生成するように構成されたノズルも含み得る。前記ノズルは、さらに、前記部分的に液化された非ポルトランドセメント系材料を、空気圧を用いて面に塗布するように構成されている。   In another embodiment, a system for applying a building material is provided. The system may include a batching and mixing device configured to batch process and mix blast furnace slag material, geopolymer material, alkaline powder, and sand to produce non-Portland cementitious material. The system may also include a conduit configured to transfer the non-Portland cementitious material from the batching and mixing device. In addition, the system receives the non-Portland cement based material and combines the transferred non-Portland cement based material with a liquid to produce a partially liquefied non-Portland cement based material It may also include a configured nozzle. The nozzle is further configured to apply the partially liquefied non-Portland cement-based material to a surface using air pressure.

以下の特徴の1以上が含まれ得る。幾つかの実施形態において、前記ジオポリマー材料が、火山岩粉又は軽石の少なくとも一方であり得る。前記アルカリ系粉体がケイ酸塩を含み得る。混合する工程が乾式混合として行われ得る。前記非ポルトランドセメント系材料が無機物であり得る。前記混合する工程が、移動式のバッチング及び混合車両にて行われ得る。前記非ポルトランドセメント系材料が、粘土、片麻岩、花崗岩、石英粗面岩、安山岩、ピクライト、カリウム長石、曹長石、軽石、又はゼオライトのうちの少なくとも1つを含み得る。前記混合する工程が、前記非ポルトランドセメント系材料を前記バッチング及び混合装置から受け取るように構成されたポータブルガンにて混合する工程を含み得る。前記非ポルトランドセメント系材料の構成要素が、約2500〜5000cm/gのブレーン微細値を含み得る。 One or more of the following features may be included. In some embodiments, the geopolymer material can be at least one of volcanic rock or pumice. The alkaline powder may include silicate. The step of mixing may be performed as dry mixing. The non-Portland cement based material may be inorganic. The mixing may be performed on a mobile batching and mixing vehicle. The non-Portland cement based material may include at least one of clay, gneiss, granite, quartz trachyte, andesite, piclite, potassium feldspar, albite, pumice, or zeolite. The mixing may include mixing with a portable gun configured to receive the non-Portland cement-based material from the batching and mixing apparatus. The components of the non-Portland cementitious material may include brane fines of about 2500-5000 cm 2 / g.

別の実施態様において、非ポルトランドセメント系建材が提供される。当該非ポルトランドセメント系建材は、高炉スラグ材、火山岩粉、アルカリ系粉体、及び、砂であり得る。幾つかの実施形態において、前記アルカリ系粉体はケイ酸塩であり得る。   In another embodiment, a non-portland cement-based building material is provided. The non-portland cement-based building material may be blast furnace slag material, volcanic rock, alkaline powder, and sand. In some embodiments, the alkaline powder can be a silicate.

1以上の実施形態の詳細を、添付図面、及び、以下の説明に記載する。その他の特徴及び利点も、詳細な説明、図面、及び、特許請求の範囲から明らかになろう。   The details of one or more embodiments are set forth in the accompanying drawings and the description below. Other features and advantages will be apparent from the detailed description, the drawings, and the claims.

本開示の実施形態による、非セメント系材料を、バッチング、混合、及び塗布するように構成された移動システムの側面図である。FIG. 1 is a side view of a transfer system configured to batch, mix and apply non-cement-based materials, according to an embodiment of the present disclosure. 本開示の実施形態による、非セメント系材料を、バッチング、混合、及び塗布するように構成された移動システムの後方側面図である。FIG. 1 is a rear side view of a transfer system configured to batch, mix, and apply non-cement-based materials, according to an embodiment of the present disclosure. 本開示の実施形態による、非セメント系の塗布プロセスに合致した作業を示すフローチャートである。FIG. 5 is a flow chart illustrating operations consistent with a non-cement based application process, according to embodiments of the present disclosure.

異なる図面における類似の参照番号は、類似の要素を示し得る。   Similar reference numbers in different drawings may indicate similar elements.

本開示の実施形態は、アルカリ活性化結合剤を有する建材(すなわち、非ポルトランドセメント系)、及び、その作製及び塗布の為のシステム及び方法に関する。本明細書に含まれる例の多くを、コンクリートの修復の文脈で論じるが、本明細書に記載される建材が任意の適切な用途に用いられ得ることに留意すべきである。これらの幾つかは、下水管の修復事業、酸による攻撃を受けるコンクリート構造物を含み得るが、これらに限定されない。   Embodiments of the present disclosure relate to building materials having an alkali activated binder (i.e., non-portland cement systems), and systems and methods for their preparation and application. Although many of the examples contained herein are discussed in the context of concrete restoration, it should be noted that the building materials described herein may be used for any suitable application. Some of these may include, but are not limited to, sewer repair projects, concrete structures subject to acid attack.

図1を参照すると、多数の容器、コンパートメント、及びこれらに関連する装置を有する移動式のバッチング及び混合(batching and mixing)車両100が示されている。幾つかの実施形態において、車両100は、砂又はその他の材料を保管するように構成され得る第1の容器102を含み得る。保管ユニット104は、水又はその他の液体を保管するように構成され得る。車両100は、さらに、バッチング及び混合装置106を含み得る。装置106は多数の部品を含み得、それらの幾つかは、第2の容器108、調節可能な配送機構110、及び、ポータブルガン212を含み得るが、これらに限定されない。図2に示されているように、ポータブルガン212は、導管又はホース216を介してノズル214に接続され得る。   Referring to FIG. 1, a mobile batching and mixing vehicle 100 is shown having a number of containers, compartments, and devices associated therewith. In some embodiments, the vehicle 100 can include a first container 102 that can be configured to store sand or other material. Storage unit 104 may be configured to store water or other liquid. Vehicle 100 may further include batching and mixing device 106. Device 106 may include multiple parts, some of which may include, but are not limited to, the second container 108, the adjustable delivery mechanism 110, and the portable gun 212. As shown in FIG. 2, portable gun 212 may be connected to nozzle 214 via conduit or hose 216.

幾つかの実施形態において、移動式のバッチング及び混合車両100は、非ポルトランドセメント系の建材をバッチ処理、混合、及び塗布するように構成され得る。この材料は、車両にて(例えば、バッチング及び混合装置106内で)、又は、第2容器108内に配置される前に、バッチ処理及び混合され得る。この材料はノズル214に移送されることができ、ノズル214にて、保管ユニット104からの液体と、構築又は修理が必要な面に塗布される前に混合され得る。非ポルトランドセメント系建材の詳細に関し、本文以下に、さらに詳細に説明する。   In some embodiments, the mobile batching and mixing vehicle 100 may be configured to batch process, mix and apply non-Portland cement based building materials. This material may be batch processed and mixed prior to being placed in the vehicle (eg, in the batching and mixing device 106) or in the second container 108. This material can be transferred to the nozzle 214, where it can be mixed with the liquid from the storage unit 104 before being applied to the surface that needs construction or repair. The details of the non-portland cement-based building materials are described in more detail below in the text.

幾つかの実施形態において、本明細書に記載する非ポルトランドセメント系建材は、既存の材料と比較して、より高い強度値、無機酸及び有機酸に対する高い耐性及び無反応性、さらに、高い初期強度値を有し得る。材料は、高炉スラグ材料、ジオポリマー材料、アルカリ系粉体、及び砂から成る乾燥混合物を含み得、これらの材料を、バッチング及び混合装置で混合して、非ポルトランドセメント系材料を生成し得る。   In some embodiments, the non-Portland cementitious building materials described herein have higher strength values, higher resistance and resistance to inorganic and organic acids, and higher initial properties as compared to existing materials. It may have an intensity value. The material may comprise a dry mixture of blast furnace slag material, geopolymer material, alkaline powder, and sand, which may be mixed in a batching and mixing apparatus to produce non-portland cementitious material.

幾つかの実施形態において、非ポルトランドセメント系建材は、様々なタイプのジオポリマー材料を含み得る。これらの材料の幾つかは、限定はしないが、ポゾラン材料を含む。これらの材料は、強アルカリと反応し、また、砂(サンド)及び/又は粗砂(グリット)と混合され得る。幾つかの実施形態において、ポゾラン材料は、活性ケイ酸塩、例えば、スラグサンド又はフライアッシュを含み得る。火山岩などの天然材料も用いられ得るが、その場合、より低い比率で微粉末として用いることが望ましいであろう。本明細書で使用する用語「フライアッシュ」は、非天然ポゾランを示し得る。   In some embodiments, non-Portland cement-based construction materials can include various types of geopolymer materials. Some of these materials include, but are not limited to, pozzolanic materials. These materials react with strong alkalis and can also be mixed with sand (sand) and / or coarse sand (grit). In some embodiments, the pozzolanic material may comprise an activated silicate, such as slag sand or fly ash. Natural materials such as volcanic rock may also be used, in which case it may be desirable to use as a fine powder in lower proportions. The term "fly ash" as used herein may indicate non-natural pozzolanes.

幾つかの実施形態において、非ポルトランドセメント系建材は、任意の個数のポゾラン材料を含み得る。それらの幾つかは、微粉砕された粘土、片麻岩、花崗岩、石英粗面岩、安山岩(アンデサイト)、ピクライト、カリウム長石、曹長石、軽石、ゼオライトなど、並びにこれらの混合物を含み得るが、これらに限定されない。これらの材料は、焼成及び/又は非焼成された微粉砕形態で使用され得る。追加的に及び/又は代替的に、十分な量の反応性(例えば、準安定性、ガラス状)の二酸化ケイ素(SiO)及び酸化アルミニウム(Al)を含む全ての原材料(アッシュ、ポゾラン、スラグを含むがこれらに限定されない)も、本開示の実施形態に適し得る。 In some embodiments, non-Portland cement-based construction materials can include any number of pozzolanic materials. Some of them may include finely divided clay, gneiss, granite, quartz trachyte, andesite, picrite, potassium feldspar, albite, pumice, zeolite etc, as well as mixtures thereof. Not limited to these. These materials can be used in calcined and / or uncalcined finely divided form. Additionally and / or alternatively, all the raw materials (ash, comprising a sufficient amount of reactive (eg metastable, glassy) silicon dioxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) Pozzolas, including but not limited to slag, may also be suitable for the embodiments of the present disclosure.

幾つかの実施形態において、非ポルトランドセメント系建材は、アルカリ系粉体材料、及び/又は、様々な混合液を含み得る。幾つかの可能な混合液は、カリウム水ガラス及びナトリウム水ガラス、アルカリ水酸化物などを含み得るが、これらに限定されない。   In some embodiments, non-Portland cement-based building materials can include alkaline-based powder materials, and / or various mixtures. Some possible mixtures may include, but are not limited to, potassium water glass and sodium water glass, alkali hydroxides, and the like.

幾つかの実施形態において、二酸化ケイ素/酸化アルミニウム含有成分とアルカリ混合液との間の反応が、3次元構造を有するアルミノケイ酸塩を生じ得る。これらの骨格構造が、化合物中にポルトランドセメントを必要としない建材の作製を可能にする。   In some embodiments, the reaction between the silicon dioxide / aluminum oxide containing component and the alkali mixture can result in an aluminosilicate having a three dimensional structure. These skeletal structures allow the preparation of building materials that do not require Portland cement in the compound.

作業中、原材料は、完全にバッチ処理及び混合され(例えば、全体又は一部が車両100にて)、次いで、ポータブルガン212に配送され得る。非ポルトランドセメント系建材は、導管216内の圧縮空気を介してノズル214に運ばれ得る。特定の一実施形態において、部分的に液化された混合物が、対象となる面に空気圧により塗布され得る前に、ケイ酸カリウム(固形成分48%、密度1,52g/cm、SiO(二酸化ケイ素):KO(酸化カリウム)重量1,14)と、ある種の液体とが短時間(例えば、1秒未満)で添加されてノズル214内で完全に混合され得る。 During operation, the raw materials may be fully batch processed and mixed (eg, in whole or in part at the vehicle 100) and then delivered to the portable gun 212. Non-Portland cement-based construction materials may be conveyed to the nozzle 214 via compressed air in the conduit 216. In a particular embodiment, potassium silicate (solid content 48%, density 1,52 g / cm 3 , SiO 2 (dioxide) is used before the partially liquefied mixture can be applied pneumatically to the surface in question. Silicon): K 2 O (potassium oxide) weight 1, 14) and certain liquids can be added in a short time (eg, less than 1 second) and thoroughly mixed in the nozzle 214.

本明細書に含まれる実施形態は、以下の材料の幾つか又は全てを含む混合物を含み得る。これらの材料は、スラグ(例えば、非天然ポゾラン、基材)、ジオポリマー材料(例えば、フライアッシュ(例えば、非天然ポゾラン、任意選択的に配合)、及び/又は天然ポゾラン、及び、任意選択的に、粉砕された火山岩材料、アルカリ(例えば、粉体又は液体)、水(任意選択的)を含むその他の液体、及び、砂/又は粗砂である。特定の混合物の例を以下に示すが、本明細書にて提示される特定の混合物が単に例として含まれることに留意されたい。さらなる多数の追加の代替的な実施形態も本開示の範囲内にある。 Embodiments included herein may include mixtures that include some or all of the following materials. These materials may be slag (e.g. non-natural pozzolan, substrate), geopolymeric material (e.g. fly ash (e.g. non-natural pozzolan, optionally formulated), and / or natural pozzolan, and optionally Crushed volcanic rock material ) , alkali (eg, powder or liquid), other liquid including water (optional), and sand and / or coarse sand. Examples of specific mixtures are given below, but it should be noted that the specific mixtures presented herein are included by way of example only. Many additional additional alternative embodiments are also within the scope of the present disclosure.

特定の一実施形態において、非ポルトランドセメント系建材は、以下の混合物から構成され得る。

Figure 0006526258
表1 In a particular embodiment, the non-Portland cementitious building material may be comprised of the following mixture:
Figure 0006526258
Table 1

幾つかの実施形態において、混合物の構成要素は、約2500〜5000cm/gのブレーン微細度を有し得る。 In some embodiments, components of the mixture can have a brane fineness of about 2500-5000 cm 2 / g.

別の例において、非ポルトランドセメント系建材は、以下の混合物から構成され得る。

Figure 0006526258
表2 In another example, the non-portland cement-based building material may be comprised of the following mixture:
Figure 0006526258
Table 2

別の例において、非ポルトランドセメント系建材は、以下の混合物から構成され得る。

Figure 0006526258
表3 In another example, the non-portland cement-based building material may be comprised of the following mixture:
Figure 0006526258
Table 3

非ポルトランドセメント系建材の実施形態は、アルカリ成分と岩粉との反応時間が、粘着性化合物を生成するのに十分であった為、予想外の結果になった。多数の試験の全体を通じて、この化合物が、鉛直面に非常に良好に付着し、密着結合を構築し、そして、3日以内に50N/mm(8000psi)を超える圧縮強度値で硬化すること分かった。 The non-Portland cement-based building material embodiments produced unexpected results because the reaction time between the alkali component and the rock powder was sufficient to produce a sticky compound. Throughout all the tests, this compound was found to adhere very well to the vertical surface, build a tight bond and cure within 3 days at compressive strength values exceeding 50 N / mm 2 (8000 psi) The

本明細書で用いた用語は、特定の実施形態を説明する為に過ぎず、本開示を限定することを意図されていない。本明細書で用いた単数形「1つの」(“a”),(“an”)及び「その」(“the”)は、文脈がそうでないことを明確に示さない限り、複数形も含むことが意図されている。また、用語「含む」(“comprises”)及び/又は(“comprising”)は、本明細書で使用する場合、記載された特徴、整数、工程、動作、要素、及び/又は部品の存在を特定するが、その他の特徴、整数、工程、動作、要素、部品、及び/又はそれらの群の1以上の存在も追加も排除しないことが理解されよう。   The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the present disclosure. As used herein, the singular forms "one" ("a"), ("an") and "the" ("the") also include the plural, unless the context clearly indicates otherwise. It is intended. Also, the terms "comprises" and / or ("comprising"), as used herein, specify the presence of the recited features, integers, steps, operations, elements and / or parts. However, it will be appreciated that neither the presence nor the addition of one or more of the other features, integers, steps, operations, elements, parts and / or groups thereof are excluded.

以下の請求項における全ての手段又は工程・プラス・ファンクション要素の対応する構造,材料,作用,及び等価物は、具体的に請求されているその他のクレームの要素と組み合わせて機能を果たす為のいずれの構造、材料,又は作用も含むものとする。本開示の記載は、例示及び説明を目的として提示されているが、網羅的であることも、開示された形態の開示に限定されることも意図されていない。本開示の範囲及び精神から逸脱しない多くの修正及び変型が、当業者には明らかであろう。実施形態は、本発明の原理及び実際の使用を最良に説明する為に、また、他の当業者が、想定される特定の用途に適するような様々な改変を伴う様々な実施形態の為に本開示を理解できるように選択及び記載されている。   The corresponding structures, materials, acts and equivalents of all means or steps plus function elements in the following claims are to be carried out in combination with the elements of the other claims which are specifically claimed. It also includes the structure, material, or function of Although the description of the present disclosure is presented for purposes of illustration and description, it is not intended to be exhaustive or to limit the disclosure of the disclosed form. Many modifications and variations will be apparent to those skilled in the art without departing from the scope and spirit of the present disclosure. The embodiments are provided to best explain the principles and practical use of the present invention, as well as other embodiments with various modifications as would be appropriate to the particular application envisioned. It has been selected and described so that the present disclosure can be understood.

以上に、本出願の開示を、詳細に、且つ、本発明の実施形態を参照しつつ記載してきたが、添付の特許請求の範囲に定義されている開示の範囲から逸脱しない改変及び変更が可能であることが明らかであろう。   While the disclosure of the present application has been described in detail and with reference to embodiments of the present invention, modifications and variations are possible without departing from the scope of the disclosure as defined in the appended claims. It will be clear that

100 移動式のバッチング及び混合車両
102 第1の容器
104 保管ユニット
106 バッチング及び混合装置
108 第2の容器
110 調節可能な配送機構
212 ポータブルガン
214 ノズル
216 導管
DESCRIPTION OF SYMBOLS 100 Mobile batching and mixing vehicle 102 1st container 104 storage unit 106 batching and mixing apparatus 108 2nd container 110 adjustable delivery mechanism 212 portable gun 214 nozzle 216 conduit

Claims (7)

建材を塗布する方法であって、
0.5質量部〜1質量部の高炉スラグ材料、0.5質量部以下のジオポリマー材料、0.2質量部〜2質量部のアルカリ系粉体、及び1質量部〜1.35質量部の砂を、車両に関連するバッチング及び混合装置にて混合して、非ポルトランドセメント系材料を生成する工程であって、前記ジオポリマー材料はポゾラン材料を含む工程と、
前記非ポルトランドセメント系材料を、前記バッチング及び混合装置から、導管を介して、前記非ポルトランドセメント系材料を受け取るように構成されたポータブルガンに移送する工程であって、前記ポータブルガンは、前記車両から前記非ポルトランドセメント系材料を直接受け取るように構成された容器を有する、工程と、
前記非ポルトランドセメント系材料を、前記容器から、ホースを介して、オペレータによって保持されるように構成されたノズルに移送する工程と、
前記移送された非ポルトランドセメント系材料を、前記ノズルにおいて液体と組み合わせて、部分的に液化された非ポルトランドセメント系材料を生成する工程と、
前記部分的に液化した非ポルトランドセメント系材料を、前記ノズルを使用して、空気圧を用いて面に塗布する工程と、を含み、
前記アルカリ系粉体がケイ酸塩を含む、
方法。
A method of applying building materials,
0.5 parts by mass to 1 part by mass of blast furnace slag material, 0.5 parts by mass or less of geopolymer material, 0.2 parts by mass to 2 parts by mass of alkali-based powder, and 1 part by mass to 1.35 parts by mass B. sand in a vehicle-related batching and mixing apparatus to produce a non-portland cement-based material , the geopolymer material comprising pozzolanic material ;
Transferring the non-Portland cement based material from the batching and mixing device to a portable gun configured to receive the non-Portland cement based material via a conduit, the portable gun being the vehicle Having a container configured to directly receive said non-Portland cementitious material from
Transferring the non-portland cementitious material from the container, via a hose, to a nozzle configured to be held by an operator;
Combining the transferred non-Portland cementitious material with a liquid at the nozzle to produce a partially liquefied non-Portland cementitious material;
Applying the partially liquefied non-portland cement-based material to a surface using air pressure using the nozzle;
The alkaline powder comprises a silicate,
Method.
前記ジオポリマー材料が、火山岩粉又は軽石を含む、請求項1に記載の方法。   The method of claim 1, wherein the geopolymer material comprises volcanic rock or pumice. 前記バッチング及び混合装置による混合が、乾式混合として行われる、請求項1に記載の方法。 Mixing by the batching and mixing apparatus is performed as a dry mixed-method of claim 1. 前記非ポルトランドセメント系材料が無機物である、請求項1に記載の方法。   The method of claim 1, wherein the non-Portland cementitious material is inorganic. 前記混合が、前記バッチング及び混合装置を備える移動式の車両にて行われる、請求項1に記載の方法。   The method according to claim 1, wherein the mixing is performed on a mobile vehicle comprising the batching and mixing device. 前記ジオポリマー材料が、粘土、片麻岩、花崗岩、石英粗面岩、安山岩、ピクライト、カリウム長石、曹長石、軽石、及びゼオライトのうちの少なくとも1つを含む、請求項1に記載の方法。 The method of claim 1, wherein the geopolymer material comprises at least one of clay, gneiss, granite, quartz trachyte, andesite, picrite, potassium feldspar, albite, pumice, and zeolite. 前記非ポルトランドセメント系材料の構成要素が、2500〜5000cm/gのブレーン微細値を有する、請求項1に記載の方法。 The method of claim 1, wherein the non-Portland cementitious material component has a brane fine value of 2500-5000 cm 2 / g.
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