JP6479356B2 - Thermochromic stamp - Google Patents

Thermochromic stamp Download PDF

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JP6479356B2
JP6479356B2 JP2014135419A JP2014135419A JP6479356B2 JP 6479356 B2 JP6479356 B2 JP 6479356B2 JP 2014135419 A JP2014135419 A JP 2014135419A JP 2014135419 A JP2014135419 A JP 2014135419A JP 6479356 B2 JP6479356 B2 JP 6479356B2
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stamp
thermochromic
friction
friction portion
sheet member
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JP2015193205A (en
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伸一 瀬利
伸一 瀬利
康孝 上原
康孝 上原
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Pilot Corp KK
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本発明はスタンプに関し、詳細には、紙面などへ熱変色性インキを押印する熱変色性スタンプに関する。   The present invention relates to a stamp, and more particularly to a thermochromic stamp for imprinting a thermochromic ink on paper or the like.

特許文献1には、可逆熱変色性スタンプ用インキ組成物が記載されており、前記可逆熱変色性スタンプ用インキ組成物が含まれたインキで紙面に印像が得られるものが記載されている。   Patent Document 1 describes an ink composition for reversibly thermochromic stamps, and describes an ink containing the ink composition for reversibly thermochromic stamps, in which an image can be obtained on paper. .

特許第3792497号公報Patent No. 3792497 gazette

本発明では、紙面に熱変色性インキを押印することができ、さらに前記熱変色性インキを熱変色させることができる熱変色性スタンプを得ることを目的とした。   In the present invention, it is an object of the present invention to obtain a thermochromic stamp capable of imprinting a thermochromic ink on a sheet of paper and further capable of thermodiscoloring the thermochromic ink.

本発明は、
「1.熱変色性インキを押印する印面と、前記熱変色性インキにより得られた紙面上の印像を摩擦してその摩擦熱で前記印像を熱変色可能な弾性材料から成る摩擦部とを有した熱変色性スタンプであって、
前記摩擦部に凹部を形成し、前記印面により得られる印像と同様の図柄を有したシート部材を、前記凹部に、前記摩擦部の表面が前記シート部材の表面より外方に位置して前記凹部が凹んだ状態となり当該シート部材が前記摩擦部で囲まれるよう貼着したことを特徴とする熱変色性スタンプ。
2.熱変色性インキを押印する印面と、前記熱変色性インキにより得られた紙面上の印像を摩擦してその摩擦熱で前記印像を熱変色可能な弾性材料から成る摩擦部とを有した熱変色性スタンプであって、
前記摩擦部に貫通孔を形成し、前記貫通孔内に、前記印面を前方に有するスタンプ本体の後方を嵌着し、前記印面により得られる印像と同様の図柄を有したシート部材を、前記スタンプ本体の後端部に、前記摩擦部の表面が前記シート部材の表面より外方に位置して前記貫通孔が凹んだ状態となり当該シート部材が前記摩擦部で囲まれるよう貼着したことを特徴とする熱変色性スタンプ。
3.熱変色性インキを押印する印面と、前記熱変色性インキにより得られた紙面上の印像を摩擦してその摩擦熱で前記印像を熱変色可能な弾性材料から成る摩擦部とを有した熱変色性スタンプであって、
前記熱変色性スタンプがスタンプ本体と該スタンプ本体の前後に着脱可能なキャップとを有し、前記キャップの開口部の反対側に前記摩擦部を設けると共に該摩擦部の端面に前記印面により得られる印像と同様の図柄を有したシート部材を配し、前記スタンプ本体の後部に係止部を設け且つ前記キャップに係止受部を設け、前記スタンプ本体に前記キャップを装着した状態で前記係止部と前記係止受部とが係合することにより、前記印面を押印して得られる図柄の向きと前記シート部材の図柄の向きとを一致させることを特徴とした熱変色性スタンプ。」である。
The present invention
1. A seal surface for imprinting a thermochromic ink, and a frictional portion made of an elastic material capable of thermally discoloring the image by the frictional heat by rubbing the imprint on the paper surface obtained by the thermochromic ink A thermochromic stamp having
A recess is formed in the friction portion, and a sheet member having a pattern similar to the impression obtained by the seal surface is positioned in the recess with the surface of the friction portion positioned outward from the surface of the sheet member. A thermochromic stamp characterized in that the recessed portion is in a recessed state and the sheet member is pasted so as to be surrounded by the friction portion.
2. It has a seal surface for imprinting a thermochromic ink, and a friction portion made of an elastic material which can thermally discolor the imprint by the frictional heat by rubbing the imprint on the paper surface obtained by the thermochromic ink A thermochromic stamp,
A sheet member having a through hole formed in the friction portion, a rear side of a stamp main body having the seal surface in front is fitted in the through hole, and a sheet member having a pattern similar to an image obtained by the seal surface At the rear end of the stamp body, the surface of the friction portion is positioned outward from the surface of the sheet member, and the through hole is recessed so that the sheet member is enclosed by the friction portion. Characteristic thermochromic stamp.
3. It has a seal surface for imprinting a thermochromic ink, and a friction portion made of an elastic material which can thermally discolor the imprint by the frictional heat by rubbing the imprint on the paper surface obtained by the thermochromic ink A thermochromic stamp,
The thermochromic stamp has a stamp body and a detachable cap on the front and back of the stamp body, the friction portion is provided on the opposite side of the opening of the cap, and the seal surface is obtained on the end face of the friction portion A seat member having a pattern similar to that of the stamped image is disposed, a locking portion is provided at the rear of the stamp body, a lock receiving portion is provided on the cap, and the cap is attached to the stamp body. A thermochromic stamp characterized in that the direction of the design obtained by pressing the seal surface and the direction of the design of the sheet member are made to coincide with each other by the engagement of the stop portion and the engagement receiving portion. ".

本発明における印面は、浸透材に熱変色性インキを含浸させた構造(浸透印構造)や、熱変色性インキを含浸させたスタンプ台に表面の凹凸部を接触させてから押印する構造などが使用できる。前記の浸透印構造としては、連続気泡を有する多孔質熱可塑性樹脂の表面部分を熱融解してシールし、シールしていない箇所に文字や図形等を形成したものや、連続気泡を有する多孔質弾性体の表面に加熱した金型を押圧したりレーザ加工機で彫刻して文字や図形等を形成した構造などを用いることができる。   The seal surface in the present invention has a structure (permeation seal structure) in which a penetrant material is impregnated with a thermochromic ink, or a structure in which an uneven portion on the surface is brought into contact with a stamp stand impregnated with a thermochromic ink and then imprinted. It can be used. As the above-mentioned penetration mark structure, the thing which heat-melted and sealed the surface part of the porous thermoplastic resin which has an open cell, formed the character, the figure, etc. in the part which is not sealed, and the porous which has an open cell. It is possible to use a structure in which a heated mold is pressed onto the surface of an elastic body or engraved with a laser processing machine to form characters, figures, and the like.

スタンプ本体は、ABS樹脂(アクリロニトリル−ブタジエン−スチレン共重合体)、PP樹脂(ポリプロピレン)、POM樹脂(ポリオキシメチレン)、PC樹脂(ポリカーボネート)、PS樹脂(ポリスチレン)、PET樹脂(ポリエチレンテレフタレート)などの樹脂材で形成することができ、金属材や木材で形成することもできる。   The stamp body is made of ABS resin (acrylonitrile-butadiene-styrene copolymer), PP resin (polypropylene), POM resin (polyoxymethylene), PC resin (polycarbonate), PS resin (polystyrene), PET resin (polyethylene terephthalate), etc. It can be formed of a resin material, or can be formed of a metal material or wood.

摩擦部は、弾性を有する樹脂(ゴム、エラストマー)が摩擦部を形成する材料として挙げられ、例えば、シリコーン樹脂、SBS樹脂(スチレン−ブタジエン−スチレン共重合体)、SEBS樹脂(スチレン−エチレン−ブタジエン−スチレン共重合体)、フッ素系樹脂、クロロプレン樹脂、ニトリル樹脂、ポリエステル系樹脂、エチレンプロピレンジエンゴム(EPDM)等が挙げられる。前記摩擦部を構成する弾性材料は、高摩耗性の弾性材料(例えば、消しゴム等)ではなく、摩擦時に消しカスが生じない低摩耗性の弾性材料で形成することが好ましい。また摩擦部は、スタンプ本体に対して嵌着や接着などで固着することができ、弾性材料によりスタンプ本体と摩擦部とを一体で形成することもできる。あるいはスタンプの印面を被覆するキャップに摩擦部を設けることも可能である。   The friction portion is exemplified by a resin (rubber, elastomer) having elasticity as a material forming the friction portion, and, for example, silicone resin, SBS resin (styrene-butadiene-styrene copolymer), SEBS resin (styrene-ethylene-butadiene) -Styrene copolymer), fluorine resin, chloroprene resin, nitrile resin, polyester resin, ethylene propylene diene rubber (EPDM), etc. may be mentioned. It is preferable that the elastic material constituting the friction portion is not made of a highly wearable elastic material (for example, an eraser or the like), but is made of a low wear elastic material which does not generate erase dust at the time of friction. Further, the friction portion can be fixed to the stamp body by fitting, adhesion or the like, and the stamp body and the friction portion can be integrally formed of an elastic material. Alternatively, it is possible to provide a friction portion on a cap that covers the seal face of the stamp.

また、摩擦部の外形形状は、三角形状でも四角形状でも円形状でも楕円形状でもよい。尚、前記外形形状とは、摩擦部を他端側から平面視した場合の外周部の形状のことであり、三角形状や四角形状などの多角形状にした場合には、紙面への接触状態を縁辺部と角部とで使い分けることが可能となる。   Further, the external shape of the friction portion may be triangular, square, circular or elliptical. The above-mentioned external shape is the shape of the outer peripheral portion when the friction portion is viewed in plan from the other end side, and in the case of a polygonal shape such as a triangular shape or a square shape, the contact state to the paper is It becomes possible to use properly by an edge and a corner.

熱変色性インキとしては、可逆、不可逆を問わず汎用のものが適用でき、摩擦熱による印像の加温によって、印像の色相を変化させることや、消色、着色させることができるものが選択的に適用できる。
特に、前記印像の変化は、熱変色性組成物をマイクロカプセルに内包させることで、組成変化を生じることなく長期間安定して発現できるものとなる。
マイクロカプセル顔料に内包される熱変色性組成物としては、繰り返しの使用性、温度変化の正確性等の点から、(イ)電子供与性呈色性有機化合物、(ロ)電子受容性化合物、(ハ)前記両者の呈色反応の生起温度を決める反応媒体からなる可逆熱変色性組成物が好適である。
As the thermochromic ink, a general-purpose ink can be applied regardless of whether it is reversible or irreversible, and the color of the printed image can be changed, erased, or colored by heating the printed image by frictional heat. It can be applied selectively.
In particular, by incorporating the thermochromic composition in microcapsules, the change in the impression image can be stably expressed for a long time without causing the composition change.
As the thermochromic composition to be contained in the microcapsule pigment, from the viewpoint of repeated usability, accuracy of temperature change, etc., (i) electron donating colored organic compound, (ii) electron accepting compound, (C) A reversible thermochromic composition comprising a reaction medium which determines the temperature at which both of the color reaction take place is suitable.

具体的に、可逆熱変色性組成物を内包させたマイクロカプセル顔料としては、特公昭51−44706号公報、特公昭51−44707号公報、特公平1−29398号公報等に記載された、所定の温度(変色点)を境としてその前後で熱変色し、高温側変色点以上の温度域で消色状態、低温側変色点以下の温度域で発色状態を呈し、両状態のうち常温域では特定の一方の状態しか存在せず、もう一方の状態は、その状態が発現するのに要した熱または冷熱が適用されている間は維持されるが、熱または冷熱の適用がなくなれば常温域で呈する状態に戻る、ヒステリシス幅が比較的小さい特性(ΔH=1〜7℃)を有する加熱消色型の可逆熱変色性組成物を内包したマイクロカプセル顔料を適用できる。
さらに、特公平4−17154号公報、特開平7−179777号公報、特開平7−33997号公報、特開平8−39936号公報等に記載されている比較的大きなヒステリシス特性(ΔH=8〜50℃)を示すものも適用できる。
Specifically, as microcapsule pigments in which the reversible thermochromic composition is contained, predetermined ones described in JP-B 51-44706, JP-B 51-44707, JP-B 1-29398, etc. Heat-discoloring before and after the temperature (color change point) of the color, decolorize in the temperature range above the color change point on the high temperature side, exhibit color development in the temperature range below the color change point on the low temperature side, Only one specific state exists, and the other state is maintained while the heat or cold required for the state to appear is applied, but if the heat or cold is not applied, the normal temperature range It is possible to apply a microcapsule pigment encapsulating a heat-discoloring type reversible thermochromic composition having a relatively small hysteresis width (ΔH = 1 to 7 ° C.), which returns to the state of
Furthermore, relatively large hysteresis characteristics (ΔH = 8 to 50 described in JP-B 4-17154, JP-A 7-179777, JP-A 7-33997, JP-A 8-39936, etc. The indication of ° C. is also applicable.

また、特開2005−1369号公報、特開2006−137886号公報、特開2006−188660号公報、特開2008−45062号公報、特開2008−280523号公報等に記載されている大きなヒステリシス特性を示す、即ち、温度変化による着色濃度の変化をプロットした曲線の形状が、温度を変色温度域より低温側から上昇させていく場合と逆に変色温度域より高温側から下降させていく場合とで大きく異なる経路を辿って変色し、完全発色温度以下の低温域での発色状態、または完全消色温度以上の高温域での消色状態が、特定温度域(実質的二相保持温度域)で色彩記憶性を有する可逆熱変色性組成物を内包させたマイクロカプセル顔料を用いることもできる。   In addition, the large hysteresis characteristics described in Japanese Patent Application Laid-Open Nos. 2005-1369, 2006-137886, 2006-188660, 2008-45062, 2008-280523, etc. In other words, the shape of the curve in which the change in coloring density due to the temperature change is plotted is the case where the temperature is lowered from the high temperature side rather than the high temperature side from the high temperature side. The color changes in a very different route, and the color development state in the low temperature range below the full color development temperature or the decoloration state in the high temperature range above the complete color removal temperature is a specific temperature range (substantially two phase holding temperature range) It is also possible to use microcapsule pigments in which a reversible thermochromic composition having a color memory property is encapsulated.

マイクロカプセルを分散させる溶剤としては、水、グリセリン、エチレングリコール、プロピレングリコール、ジエチレングリコール、トリエチレングリコール、1,3−ブチレングリコール、エチレングリコールモノメチルエーテル等のグリコール類及びそれらの低級アルキルエーテル、2−ピロリドン、N−ビニルピロリドン、尿素等の適宜量を配合することができる。   Solvents for dispersing the microcapsules include water, glycerin, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, 1,3-butylene glycol, glycols such as ethylene glycol monomethyl ether, and lower alkyl ethers thereof, 2-pyrrolidone Appropriate amounts of N-vinyl pyrrolidone, urea and the like can be blended.

印像の固着性や粘度調整等のためには適宜量のバインダー樹脂が添加される。前記バインダー樹脂は樹脂エマルション、アルカリ可溶性樹脂、水溶性樹脂から選ばれる。
前記樹脂エマルションとしては、ポリアクリル酸エステル、スチレン−アクリル酸共重合体、ポリ酢酸ビニル、エチレン−酢酸ビニル共重合体、エチレン−塩化ビニル共重合体、メタクリル酸−マレイン酸共重合体、エチレン−メタクリル酸共重合体、α−オレフィン−マレイン酸共重合体、ポリエステル、ポリウレタン等の水分散体が挙げられ、前記アルカリ可溶性樹脂としては、スチレン−マレイン酸共重合体、エチレン−マレイン酸共重合体、スチレン−アクリル酸共重合体等が挙げられ、前記水溶性樹脂としては、ポリビニルアルコール、ポリビニルブチラール等を挙げることができ、一種又は二種以上を混合して用いることができる。
An appropriate amount of binder resin is added for the fixing property of the image, the viscosity adjustment and the like. The binder resin is selected from a resin emulsion, an alkali soluble resin, and a water soluble resin.
Examples of the resin emulsion include polyacrylic acid ester, styrene-acrylic acid copolymer, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-vinyl chloride copolymer, methacrylic acid-maleic acid copolymer, ethylene- Water dispersions such as methacrylic acid copolymer, α-olefin-maleic acid copolymer, polyester, polyurethane and the like can be mentioned, and as the alkali-soluble resin, styrene-maleic acid copolymer, ethylene-maleic acid copolymer Styrene-acrylic acid copolymer and the like can be mentioned, and as the water-soluble resin, polyvinyl alcohol, polyvinyl butyral and the like can be mentioned, and one or two or more kinds can be mixed and used.

また、キサンタンガム、ウェランガム、構成単糖がグルコースとガラクトースの有機酸修飾ヘテロ多糖体であるサクシノグリカン(平均分子量約100乃至800万)、グアーガム、ローカストビーンガム及びその誘導体、ヒドロキシエチルセルロース、アルギン酸アルキルエステル類、メタクリル酸のアルキルエステルを主成分とする分子量10万〜15万の重合体、グリコマンナン、寒天やカラゲニン等の海藻より抽出されるゲル化能を有する増粘多糖類、ベンジリデンソルビトール及びベンジリデンキシリトール又はこれらの誘導体、架橋性アクリル酸重合体、無機質微粒子、ポリグリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレンヒマシ油、ポリオキシエチレンラノリン・ラノリンアルコール・ミツロウ誘導体、ポリオキシエチレンアルキルエーテル・ポリオキシプロピレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、脂肪酸アミド等のHLB値が8〜12のノニオン系界面活性剤、ジアルキル又はジアルケニルスルホコハク酸の塩類等を例示でき、単独或いは混合して使用することができる。
更に、N−アルキル−2−ピロリドンとアニオン系界面活性剤の混合物、ポリビニルアルコールとアクリル系樹脂の混合物等、剪断減粘性を示す化合物を添加して印像の固着性や粘度調整を行うこともできる。
In addition, xanthan gum, welan gum, succinoglycan (average molecular weight about 100 to 8,000,000) in which the constituent monosaccharide is an organic acid modified heteropolysaccharide of glucose and galactose, guar gum, locust bean gum and derivatives thereof, hydroxyethyl cellulose, alginic acid alkyl ester , Polymers with a molecular weight of 100,000 to 150,000 mainly composed of alkyl esters of methacrylic acid, glycomannans, thickening polysaccharides having gelling ability extracted from seaweeds such as agar and carrageenan, benzylidene sorbitol and benzylidene xylitol Or derivatives thereof, crosslinkable acrylic acid polymers, inorganic fine particles, polyglycerin fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyethylene glycol fatty acid esters, polyoxyethylene castor oil, Nonionic surfactants, dialkyl or dialkenyl having an HLB value of 8 to 12, such as oxyethylene lanolin, lanolin alcohol, beeswax derivative, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, fatty acid amide, etc. Sulfosuccinic acid salts and the like can be exemplified, and they can be used alone or in combination.
Further, a compound exhibiting shear thinning property such as a mixture of N-alkyl-2-pyrrolidone and an anionic surfactant, a mixture of polyvinyl alcohol and an acrylic resin, or the like may be added to adjust the fixing property and viscosity of the impression image. it can.

その他、必要に応じてpH調整剤、防腐剤或いは防黴剤を添加することができる。
前記pH調整剤としては、アンモニア、炭酸ナトリウム、リン酸ナトリウム、水酸化ナトリウム、酢酸ソーダ等の無機塩類、トリエタノールアミンやジエタノールアミン等の水溶性のアミン化合物等の有機塩基性化合物等が挙げられる。
前記防腐剤或いは防黴剤としては、石炭酸、1、2−ベンズイソチアゾリン−3−オンのナトリウム塩、安息香酸ナトリウム、デヒドロ酢酸ナトリウム、ソルビン酸カリウム、パラオキシ安息香酸プロピル、2,3,5,6−テトラクロロ−4−(メチルスルフォニル)ピリジン等が挙げられる。
その他、溶剤の浸透性を向上させるフッ素系界面活性剤やノニオン、アニオン、カチオン系界面活性剤、ジメチルポリシロキサン等の消泡剤を添加することもできる。
In addition, pH adjusters, preservatives or fungicides can be added as required.
Examples of the pH adjuster include inorganic salts such as ammonia, sodium carbonate, sodium phosphate, sodium hydroxide and sodium acetate, and organic basic compounds such as water-soluble amine compounds such as triethanolamine and diethanolamine.
As the antiseptic agent or mildew proofing agent, there can be mentioned carboxylic acid, sodium salt of 1,2-benzisothiazolin-3-one, sodium benzoate, sodium dehydroacetate, potassium sorbate, propyl parahydroxybenzoate, 2, 3, 5, 6 -Tetrachloro -4- (methyl sulfonyl) pyridine etc. are mentioned.
In addition, it is also possible to add an antifoaming agent such as a fluorine-based surfactant or a nonionic, an anion, a cationic surfactant or dimethylpolysiloxane which improves the permeability of the solvent.

摩擦部の後端面に凹部を形成することにより、印面により得られる印像と同様の図柄を有したシート部材を貼着した状態で、シート部材が摩擦部から剥がれにくくなり、さらに、摩擦部に形成する凹部の内面にスタンプを持つ指先が当接するように形成すれば、スタンプを安定した姿勢で押印させることも可能となる。
By forming a recess on the rear end face of the friction portion, the sheet member is less likely to be peeled off from the friction portion in a state in which the sheet member having the same pattern as the image obtained by the seal surface is attached. If a finger tip having a stamp is formed in contact with the inner surface of the concave portion to be formed, the stamp can be stamped in a stable posture.

スタンプ本体の後部に設ける係止部及びキャップに設ける係止受部の関係は、スタンプ本体にキャップを装着した状態で係止部と係止受部とが係合することにより、印面を押印して得られる図柄の向きとシート部材の図柄の向きとが一致すればよく、例えば、スタンプ本体の後部に凸部または凹部を設けキャップに凹部または凸部を設けて凹凸係合させる方法や、キャップ本体の後部の外面形状とキャップの内面形状とを一定方向にしか装着できない形状としたり、スタンプ本体の後部に雄螺子部を形成しキャップに雌螺子部を形成し互いの螺合が一定位置で完了できるようにする方法などがある。   The relationship between the locking portion provided on the rear of the stamp body and the locking receiving portion provided on the cap is such that the locking portion and the locking receiving portion are engaged with each other while the cap is mounted on the stamp body. The direction of the pattern obtained can be matched with the direction of the pattern of the sheet member, for example, a method of making convex portions or concave portions at the rear of the stamp body, forming concave portions or convex portions in the cap and engaging in concavo-convex engagement, The external shape of the rear of the main body and the inner surface of the cap can be attached only in a certain direction, or a male screw is formed at the rear of the stamp main body, and a female screw is formed on the cap. There are ways to get it done.

本発明の熱変色性スタンプによれば、印面で紙面に熱変色性インキを押印することができ、摩擦部で紙面に押印された熱変色性インキを熱変色することができる。
また、摩擦部の外形形状を多角形状とすることにより、紙面に対して摩擦部の縁辺部で直線状に広く接触させたり、摩擦部の角部で狭く接触させたりして、熱変色させる印像の大きさに応じて適宜選択することが可能となる。
また、摩擦部の後端面に、印面により得られる印像と同様の図柄を有したシート部材を、そのシートの図柄の向きと印面の向きとを合わせて貼着することにより、使用者がスタンプを押印する際の方向性を認識することができ、さらにシート部材が凹部に貼着されていることから、摩擦部がシリコーン樹脂やフッ素系樹脂のように、粘着テープや接着剤が定着し難い材質であっても、シート部材が剥がれ難い構成となる。
According to the thermochromic stamp of the present invention, the thermochromic ink can be imprinted on the paper surface by the seal surface, and the thermochromic ink imprinted on the paper surface by the friction portion can be thermochromic.
Also, by making the external shape of the friction part into a polygonal shape, it is possible to make a thermal discoloration by making wide contact linearly at the edge of the friction part with the paper surface or making narrow contact at the corners of the friction part. It becomes possible to select suitably according to the size of the image.
In addition, the user applies a stamp to the rear end face of the friction portion by attaching a sheet member having a design similar to the impression obtained by the seal face, with the direction of the design of the sheet and the direction of the seal face. It is possible to recognize the directionality at the time of imprinting, and further, since the sheet member is stuck in the recess, it is difficult for the adhesive tape or the adhesive to be fixed like the silicone resin or fluorine resin in the friction portion. Even if it is a material, it becomes the structure which a sheet member does not separate easily.

図1は第一の実施例の熱変色性スタンプの斜視図である。FIG. 1 is a perspective view of the thermochromic stamp of the first embodiment. 図2は図1のA−A線端面図である。FIG. 2 is an end view taken along line A-A of FIG. 図3は第一の実施例の熱変色性スタンプを組立てている状態の図である。FIG. 3 is a view of the thermochromic stamp of the first embodiment being assembled. 図4は図3の次工程の図である。FIG. 4 is a diagram of the next process of FIG. 図5は第一の実施例の熱変色性スタンプで紙面に押印した状態の図である。FIG. 5 is a view showing a state in which the thermochromic stamp of the first embodiment is stamped on the paper surface. 図6は第一の実施例の熱変色性スタンプで熱変色性インキにより得られた紙面上の印像を摩擦している状態の図である。FIG. 6 is a view showing a state in which the image on the paper surface obtained by the thermochromic ink is rubbed with the thermochromic stamp of the first embodiment. 図7は第二の実施例の熱変色性スタンプの斜視図である。FIG. 7 is a perspective view of the thermochromic stamp of the second embodiment. 図8は図7のB−B線端面図である。FIG. 8 is an end view taken along line B-B of FIG. 図9は第二の実施例の熱変色性スタンプを組立てている状態の図である。FIG. 9 is a view of a state in which the thermochromic stamp of the second embodiment is assembled. 図10は図9の次工程の図である。FIG. 10 is a diagram of the next process of FIG. 図11は第二の実施例の熱変色性スタンプで紙面に押印した状態の図である。FIG. 11 is a view showing a state in which the thermochromic stamp of the second embodiment is stamped on the paper surface. 図12は第二の実施例の熱変色性スタンプで熱変色性インキにより得られた紙面上の印像を摩擦している状態の図である。FIG. 12 is a view showing a state in which the image on the paper surface obtained by the thermochromic ink is rubbed with the thermochromic stamp of the second embodiment. 図13は第三の実施例の熱変色性スタンプの斜視図である。FIG. 13 is a perspective view of the thermochromic stamp of the third embodiment. 図14は図13のC−C線端面図である。FIG. 14 is an end view taken along the line C-C of FIG. 図15は第三の実施例の熱変色性スタンプを組立てている状態の図である。FIG. 15 is a view of a state in which the thermochromic stamp of the third embodiment is assembled. 図16は第三の実施例の熱変色性スタンプで紙面に押印した状態の図である。FIG. 16 is a view showing a state in which the thermochromic stamp of the third embodiment is stamped on the paper surface. 図17は第三の実施例の熱変色性スタンプで熱変色性インキにより得られた紙面上の印像を摩擦している状態の図である。FIG. 17 is a view showing a state in which the impression on the paper obtained by the thermochromic ink is rubbed with the thermochromic stamp of the third embodiment. 図18は第四の実施例の熱変色性スタンプの斜視図である。FIG. 18 is a perspective view of the thermochromic stamp of the fourth embodiment. 図19は図18のD−D線端面図である。FIG. 19 is an end view taken along the line D-D of FIG. 図20は第四の実施例の熱変色性スタンプを組立てている状態の図である。FIG. 20 is a view of a state in which the thermochromic stamp of the fourth embodiment is assembled. 図21は第四の実施例の熱変色性スタンプで紙面に押印した状態の図である。FIG. 21 is a view showing the thermochromic stamp of the fourth embodiment in a state of being sealed on the paper. 図22は第四の実施例の熱変色性スタンプで熱変色性インキにより得られた紙面上の印像を摩擦している状態の図である。FIG. 22 is a view showing a state in which the image on the paper surface obtained with the thermochromic ink is rubbed with the thermochromic stamp of the fourth embodiment.

以下、図面を参照して本発明における熱変色性スタンプの実施例について説明を行う。尚、説明を分かりやすくするために、図面中の同様の部材、同様の部分については同じ番号を付してある。   Hereinafter, embodiments of the thermochromic stamp in the present invention will be described with reference to the drawings. In order to make the description easy to understand, similar members in the drawings and similar portions are denoted by the same reference numerals.

図1から図6を用いて第一の実施例の熱変色性スタンプについて説明を行う。熱変色性スタンプ1は、PP樹脂(ポリプロピレン)で角筒状に成形したスタンプ本体2の前方開口部2aに、印面3aを有したEVA樹脂(エチレン・酢酸ビニル共重合体)で成形した印面体3の後方部3bを嵌着し、スタンプ本体2の後方開口2bに、SEBS樹脂(スチレン−エチレン−ブタジエン−スチレン共重合体)で成形した摩擦体4の前方部4aを嵌着してある。また、スタンプ本体2の前方には、段部2cを設けて一回り小さな角筒部2dを形成してあり、角筒部2dをキャップ5で被覆できるようにしてある。   The thermochromic stamp of the first embodiment will be described using FIGS. 1 to 6. The thermochromic stamp 1 is a stamped body molded with an EVA resin (ethylene-vinyl acetate copolymer) having a stamped surface 3a at the front opening 2a of the stamp main body 2 molded in a square tube shape with PP resin (polypropylene). The rear portion 3b of 3 is fitted, and the front portion 4a of the friction body 4 molded with SEBS resin (styrene-ethylene-butadiene-styrene copolymer) is fitted into the rear opening 2b of the stamp body 2. Further, a stepped portion 2c is provided in front of the stamp body 2 to form a slightly smaller rectangular tube portion 2d, so that the rectangular tube portion 2d can be covered with the cap 5.

印面体3は、連続気泡を有するEVA樹脂の表面部分を熱融解してシールし、シールしていない箇所が音符の図柄3c(鏡像状態)となるように印面3aを形成してある。印面体3には、熱変色性組成物を内包したマイクロカプセル顔料を水性媒体中に分散させた熱変色性インキ(図示せず)を含浸してある。本実施例の熱変色性インキは、摩擦熱により消色するものを使用した。また、摩擦体4の後端面4bには凹部4cを形成してあり、凹部4cの表面に前記音譜と同様の図柄6aを印刷した紙製のラベル6を粘着材(図示せず)で貼着してある。   The seal face 3 is formed by thermally melting and sealing the surface portion of the EVA resin having open cells, and the seal face 3a is formed so that the unsealed portion becomes the design 3c (mirror image state) of the note. The stamp board 3 is impregnated with a thermochromic ink (not shown) in which microcapsule pigments containing a thermochromic composition are dispersed in an aqueous medium. As the thermochromic ink of this example, one which is decolored by frictional heat was used. Further, a concave portion 4c is formed on the rear end surface 4b of the friction body 4, and a paper label 6 having a pattern 6a similar to the above-mentioned musical note printed on the surface of the concave portion 4c is adhered with an adhesive (not shown) Yes.

図5は、第一の実施例の熱変色性スタンプ1で押印を行った状態であり、紙面100に対し、印面体3に含浸させた熱変色性インキによる音譜の印像101を押印した図である。熱変色性スタンプ1では、摩擦体4の凹部4cに指の腹を添えて押印することができた。図6は、第一の実施例の熱変色性スタンプ1で紙面上の印像101を摩擦している状態であり、紙面100上の印像101を摩擦体4で摩擦して、その摩擦熱で印像101を消色させている図である。本実施例の摩擦体4は外形形状が四角形状であることから、図6に示すように角部4dを用いて細かい箇所の摩擦を行うことができた。   FIG. 5 shows a state in which the thermochromic stamp 1 of the first embodiment is used for imprinting, and an imprint 101 of a musical note made of thermochromic ink impregnated in the stamp body 3 is imprinted on the sheet 100. It is. In the thermochromic stamp 1, the concave portion 4 c of the friction body 4 can be sealed by applying the belly of the finger. FIG. 6 shows the thermochromic stamp 1 according to the first embodiment in a state in which the impression 101 on the paper is abraded, and the impression 101 on the paper 100 is abraded with the friction body 4 so as to have its frictional heat In which the image 101 is erased. Since the friction body 4 of the present embodiment has a rectangular outer shape, as shown in FIG. 6, it was possible to carry out friction at a fine place using the corner 4 d.

次に、図7から図12を用いて第二の実施例の熱変色性スタンプについて説明を行う。熱変色性スタンプ11は、PP樹脂(ポリプロピレン)で角筒状に成形したスタンプ本体12の前方開口部12aへ角筒状の連結筒20を嵌着してある。連結筒20の前方開口部20aには、印面3aを有したEVA樹脂(エチレン・酢酸ビニル共重合体)で成形した印面体3の後方部3bを嵌着してある。スタンプ本体12の後方には、一回り小さな角筒部12bを形成してあり、SEBS樹脂(スチレン−エチレン−ブタジエン−スチレン共重合体)で成形した摩擦体14に形成した貫通孔14aへ嵌着してある。連結筒20の中間部には段部20bを突設してあり、連結筒20の段部20bがスタンプ本体12の前端に当接するまで、連結筒20の後方部20cをスタンプ本体12の前方開口部12aへ挿着している。また、連結筒20の前方部20dには、キャップ5を、連結筒20の段部20bにキャップ5の後端が当接するまで装着させて前方部20dが被覆されるようにしてある。   Next, the thermochromic stamp of the second embodiment will be described with reference to FIGS. 7 to 12. In the thermochromic stamp 11, a rectangular cylindrical connecting cylinder 20 is fitted to the front opening 12a of the stamp body 12 which is formed into a rectangular cylindrical shape by PP resin (polypropylene). The front opening 20a of the connecting cylinder 20 is fitted with the rear portion 3b of the seal 3 formed of EVA resin (ethylene-vinyl acetate copolymer) having the seal 3a. At the rear of the stamp body 12, a slightly smaller rectangular cylinder 12b is formed, and fitted into the through hole 14a formed in the friction body 14 molded with SEBS resin (styrene-ethylene-butadiene-styrene copolymer) Yes. A stepped portion 20b is provided in the middle of the connecting cylinder 20 so that the rear portion 20c of the connecting cylinder 20 can be opened forward of the stamp body 12 until the stepped portion 20b of the connecting cylinder 20 abuts on the front end of the stamp body 12. It is attached to the part 12a. Further, the cap 5 is mounted on the front portion 20d of the connecting cylinder 20 until the rear end of the cap 5 abuts on the step 20b of the connecting cylinder 20 so that the front portion 20d is covered.

印面体3は、連続気泡を有するEVA樹脂の表面部分を熱融解してシールし、シールしていない箇所が音符の図柄3c(鏡像状態)となるように印面3aを形成してある。印面体3には、熱変色性組成物を内包したマイクロカプセル顔料を水性媒体中に分散させた熱変色性インキ(図示せず)を含浸してある。本実施例の熱変色性インキは、摩擦熱により消色するものを使用した。また、摩擦体14は貫通孔14aを形成してあり、貫通孔14aを通じてスタンプ本体12の後端部12cの表面に前記音譜と同様の図柄6aを印刷した紙製のラベル6を粘着材(図示せず)で貼着してある。   The seal face 3 is formed by thermally melting and sealing the surface portion of the EVA resin having open cells, and the seal face 3a is formed so that the unsealed portion becomes the design 3c (mirror image state) of the note. The stamp board 3 is impregnated with a thermochromic ink (not shown) in which microcapsule pigments containing a thermochromic composition are dispersed in an aqueous medium. As the thermochromic ink of this example, one which is decolored by frictional heat was used. The friction member 14 has a through hole 14a, and a paper label 6 on which a pattern 6a similar to the above-mentioned musical note is printed on the surface of the rear end 12c of the stamp body 12 through the through hole 14a It is stuck by (not shown).

図11は、第二の実施例の熱変色性スタンプ11で押印を行った状態であり、紙面100に対し、印面体3に含浸させた熱変色性インキによる音譜の印像101を押印した図である。熱変色性スタンプ11では、摩擦体14の貫通孔14aに指の腹を添えて押印することができた。図12は、第二の実施例の熱変色性スタンプ11で紙面上の印像101を摩擦している状態であり、紙面100上の印像101を摩擦体14で摩擦して、その摩擦熱で印像101を消色させている図である。本実施例の摩擦体14は外形形状が四角形状であることから、図12に示すように角部14dを用いて細かい箇所の摩擦を行うことができた。   FIG. 11 shows a state in which the thermochromic stamp 11 of the second embodiment is used for imprinting, and an imprint 101 of a musical note made of thermochromic ink impregnated in the stamp body 3 is imprinted on the sheet 100. It is. In the thermochromic stamp 11, the through hole 14a of the friction body 14 can be sealed by applying the belly of a finger. FIG. 12 shows a state in which the thermochromic stamp 11 of the second embodiment is rubbing the impression 101 on the paper, and the friction 101 is used to rub the impression 101 on the paper 100 with the friction body 14. In which the image 101 is erased. Since the friction body 14 of the present embodiment has a rectangular outer shape, as shown in FIG. 12, it was possible to carry out friction at a fine place using the corner portion 14d.

次に、図13から図17を用いて第三の実施例の熱変色性スタンプについて説明を行う。熱変色性スタンプ21は、PP樹脂(ポリプロピレン)で角筒状に成形したスタンプ本体22の前方開口部22aへ角筒状の連結筒20を嵌着してある。連結筒20の前方開口部20aには、印面3aを有したEVA樹脂(エチレン・酢酸ビニル共重合体)で成形した印面体3の後方部3bを嵌着してある。連結筒20の中間部には段部20bを突設してあり、連結筒20の段部20bがスタンプ本体12の前端に当接するまで、連結筒20の後方部20cをスタンプ本体12の前方開口部12aへ挿着している。また、連結筒20の前方部20dには、キャップ25を、連結筒20の段部20bにキャップ25の後端が当接するまで装着させて前方部20dが被覆されるようにしてある。キャップ本体250に形成した前方開口部250aには、SEBS樹脂(スチレン−エチレン−ブタジエン−スチレン共重合体)で成形した摩擦体24の後方部24aを嵌着してある。   Next, the thermochromic stamp of the third embodiment will be described with reference to FIGS. 13 to 17. The thermochromic stamp 21 has a rectangular cylindrical connecting cylinder 20 fitted to the front opening 22a of the stamp main body 22 which is molded into a rectangular cylindrical shape from PP resin (polypropylene). The front opening 20a of the connecting cylinder 20 is fitted with the rear portion 3b of the seal 3 formed of EVA resin (ethylene-vinyl acetate copolymer) having the seal 3a. A stepped portion 20b is provided in the middle of the connecting cylinder 20 so that the rear portion 20c of the connecting cylinder 20 can be opened forward of the stamp body 12 until the stepped portion 20b of the connecting cylinder 20 abuts on the front end of the stamp body 12. It is attached to the part 12a. Further, the cap 25 is attached to the front portion 20d of the connecting cylinder 20 until the rear end of the cap 25 abuts on the step 20b of the connecting cylinder 20 so that the front portion 20d is covered. In a front opening 250a formed in the cap main body 250, a rear portion 24a of the friction body 24 molded with SEBS resin (styrene-ethylene-butadiene-styrene copolymer) is fitted.

印面体3は、連続気泡を有するEVA樹脂の表面部分を熱融解してシールし、シールしていない箇所が音符の図柄3c(鏡像状態)となるように印面3aを形成してある。印面体3には、熱変色性組成物を内包したマイクロカプセル顔料を水性媒体中に分散させた熱変色性インキ(図示せず)を含浸してある。本実施例の熱変色性インキは、摩擦熱により消色するものを使用した。また、摩擦体24の前端面24bには凹部24cを形成してあり、凹部24cの表面に前記音譜と同様の図柄6aを印刷した紙製のラベル6を粘着材(図示せず)で貼着してある。   The seal face 3 is formed by thermally melting and sealing the surface portion of the EVA resin having open cells, and the seal face 3a is formed so that the unsealed portion becomes the design 3c (mirror image state) of the note. The stamp board 3 is impregnated with a thermochromic ink (not shown) in which microcapsule pigments containing a thermochromic composition are dispersed in an aqueous medium. As the thermochromic ink of this example, one which is decolored by frictional heat was used. In addition, a concave portion 24c is formed on the front end surface 24b of the friction body 24, and a paper label 6 on which a pattern 6a similar to the above-mentioned musical note is printed is adhered on the surface of the concave portion 24c with an adhesive (not shown). Yes.

図16は、第三の実施例の熱変色性スタンプ21で押印を行った状態であり、紙面100に対し、印面体3に含浸させた熱変色性インキによる音譜の印像101を押印した図である。熱変色性スタンプ21では、摩擦体24の凹部24cに指の腹を添えて押印することができた。図17は、第三の実施例の熱変色性スタンプ21で紙面上の印像101を摩擦している状態であり、紙面100上の印像101を摩擦体24で摩擦して、その摩擦熱で印像101を消色させている図である。本実施例の摩擦体24は外形形状が四角形状であることから、図17に示すように角部24dを用いて細かい箇所の摩擦を行うことができた。   FIG. 16 shows a state in which the thermochromic stamp 21 of the third embodiment is used for imprinting, and an imprint 101 of a musical note made of thermochromic ink impregnated in the stamp body 3 is imprinted on the sheet 100. It is. In the thermochromic stamp 21, the concave portion 24 c of the friction body 24 can be sealed by applying the belly of a finger. FIG. 17 shows a state in which the thermochromic stamp 21 of the third embodiment is used to rub the impression 101 on the paper, and the impression 101 on the paper 100 is rubbed with the friction body 24 so that the heat of friction thereof is generated. In which the image 101 is erased. Since the friction body 24 of the present example has a rectangular outer shape, as shown in FIG. 17, it was possible to carry out friction at a fine place using the corner 24 d.

次に、図18から図22を用いて第四の実施例の熱変色性スタンプについて説明を行う。熱変色性スタンプ31は、PP樹脂(ポリプロピレン)で角筒状に成形したスタンプ本体32の前方開口部32aへ角筒状の連結筒20を嵌着してある。連結筒20の前方開口部20aには、印面3aを有したEVA樹脂(エチレン・酢酸ビニル共重合体)で成形した印面体3の後方部3bを嵌着してある。連結筒20の中間部には段部20cを突設してあり、連結筒20の段部20bがスタンプ本体32の前端に当接するまで、連結筒20の後方部20cをスタンプ本体32の前方開口部32aへ挿着している。また、連結筒20の前方部20dには、キャップ35を、連結筒20の段部20bにキャップ35の後端が当接するまで装着させて前方部20dが被覆されるようにしてある。キャップ本体350に形成した前方開口部350aには、SEBS樹脂(スチレン−エチレン−ブタジエン−スチレン共重合体)で成形した摩擦体34の後方部34aを嵌着してある。   Next, the thermochromic stamp of the fourth embodiment will be described with reference to FIGS. 18 to 22. FIG. The thermochromic stamp 31 has a rectangular cylindrical connecting cylinder 20 fitted to the front opening 32a of the stamp main body 32 which is molded into a rectangular cylindrical shape from PP resin (polypropylene). The front opening 20a of the connecting cylinder 20 is fitted with the rear portion 3b of the seal 3 formed of EVA resin (ethylene-vinyl acetate copolymer) having the seal 3a. A stepped portion 20c is provided in the middle of the connecting cylinder 20 so that the rear portion 20c of the connecting cylinder 20 can be opened forward of the stamp body 32 until the stepped portion 20b of the connecting cylinder 20 abuts on the front end of the stamp body 32. It is attached to the part 32a. Further, the cap 35 is mounted on the front portion 20d of the connecting cylinder 20 until the rear end of the cap 35 abuts on the step 20b of the connecting cylinder 20 so that the front portion 20d is covered. The rear portion 34a of the friction body 34 molded with SEBS resin (styrene-ethylene-butadiene-styrene copolymer) is fitted to the front opening 350a formed in the cap body 350.

印面体3は、連続気泡を有するEVA樹脂の表面部分を熱融解してシールし、シールしていない箇所が音符の図柄3c(鏡像状態)となるように印面3aを形成してある。印面体3には、熱変色性組成物を内包したマイクロカプセル顔料を水性媒体中に分散させた熱変色性インキ(図示せず)を含浸してある。本実施例の熱変色性インキは、摩擦熱により消色するものを使用した。また、摩擦体34の前端面34bには凹部34cを形成してあり、凹部34cの表面に前記音譜と同様の図柄6aを印刷した紙製のラベル6を粘着材(図示せず)で貼着してある。   The seal face 3 is formed by thermally melting and sealing the surface portion of the EVA resin having open cells, and the seal face 3a is formed so that the unsealed portion becomes the design 3c (mirror image state) of the note. The stamp board 3 is impregnated with a thermochromic ink (not shown) in which microcapsule pigments containing a thermochromic composition are dispersed in an aqueous medium. As the thermochromic ink of this example, one which is decolored by frictional heat was used. In addition, a concave portion 34c is formed on the front end surface 34b of the friction body 34, and a paper label 6 printed with a pattern 6a similar to the above-mentioned musical note is stuck on the surface of the concave portion 34c with an adhesive (not shown). Yes.

図21は、第四の実施例の熱変色性スタンプ31で押印を行った状態であり、紙面100に対し、印面体3に含浸させた熱変色性インキによる音譜の印像101を押印した図である。熱変色性スタンプ31では、摩擦体34の凹部34cに指の腹を添えて押印することができた。尚、本実施例の熱変色性スタンプ31は、図20で示したように、スタンプ本体32の後方に一回り小さな角筒部32bを形成してあり、キャップ35をスタンプ本体32の角筒部32bに装着した際には、角筒部32bに形成した係止凸部32cとキャップ本体350の内部に形成した係止凹部350bとが係合して、印面3aを押印して得られる印像101の向きと摩擦体34の凹部34cの表面に貼着した図柄6aの向きとが一致するので、使用者が使いやすい。図22は、第四の実施例の熱変色性スタンプ31で紙面上の印像101を摩擦している状態であり、紙面100上の印像101を摩擦体34で摩擦して、その摩擦熱で印像101を消色させている図である。本実施例の摩擦体34は外形形状が四角形状であることから、図22に示すように角部34dを用いて細かい箇所の摩擦を行うことができた。   FIG. 21 shows a state in which the thermochromic stamp 31 of the fourth embodiment is used for imprinting, and an imprint 101 of a musical note made of thermochromic ink impregnated in the stamp body 3 is imprinted on the sheet 100. It is. In the thermochromic stamp 31, the concave portion 34c of the friction body 34 can be sealed by applying the belly of a finger. In the thermochromic stamp 31 of this embodiment, as shown in FIG. 20, a small square tube portion 32b is formed at the rear of the stamp body 32, and the cap 35 is used as the square tube portion of the stamp body 32. When mounted on 32b, the engagement convex portion 32c formed on the square cylinder portion 32b engages with the engagement concave portion 350b formed on the inside of the cap main body 350, and an image is obtained by imprinting the seal surface 3a. The direction of the arrow 101 coincides with the direction of the pattern 6a attached to the surface of the recess 34c of the friction body 34, so that the user can easily use it. FIG. 22 shows a state in which the thermochromic stamp 31 of the fourth embodiment is rubbing the impression 101 on the paper, and the friction 101 is used to rub the impression 101 on the paper 100 with the friction body 34. In which the image 101 is erased. Since the friction body 34 of the present example has a rectangular outer shape, as shown in FIG. 22, it was possible to carry out friction at a fine place using the corner 34 d.

1…熱変色性スタンプ、
2…スタンプ本体、2a…前方開口部、2b…後方開口、
2c…段部、2d…角筒部、
3…印面体、3a…印面、3b…後方部、3c…図柄、
4…摩擦体、4a…前方部、4b…後端面、4c…凹部、
4d…角部、
5…キャップ、
6…ラベル、6a…図柄、
100…紙面、101…印像、
11…熱変色性スタンプ、
12…スタンプ本体、12a…前方開口部、
12b…角筒部、12c…後端部、
20…連結筒、20a…前方開口部、
20b…段部、20c…後方部、20d…前方部、
14…摩擦体、14a…貫通孔、14d…角部、
21…熱変色性スタンプ、
22…スタンプ本体、22a…前方開口部、
24…摩擦体、24a…後方部、24b…前端面、24c…凹部、
24d…角部、
25…キャップ、250…キャップ本体、250a…前方開口部、
31…熱変色性スタンプ、
32…スタンプ本体、32a…前方開口部、
32b…角筒部、32c…係止凸部、
34…摩擦体、34a…後方部、34b…前端面、34c…凹部、
34d…角部、
35…キャップ、350…キャップ本体、350a…前方開口部、
350b…係止凹部。
1 ... Thermochromic stamp,
2 ... stamp body, 2a ... front opening, 2b ... rear opening,
2c: Step part, 2d: Square tube part,
3 ... Seal face, 3a ... Seal face, 3b ... Rear part, 3c ... Design,
4 friction body 4a front portion 4b rear end surface 4c concave portion
4d ... corner,
5 ... Cap,
6 ... label, 6a ... design,
100 ... paper surface, 101 ... impression image,
11 ... Thermochromic stamp,
12: Stamp main body, 12a: front opening,
12b: Square tube portion, 12c: Rear end portion,
20 ... connected cylinder, 20 a ... front opening,
20b: step portion, 20c: rear portion, 20d: front portion,
14 friction body 14a through hole 14d corner portion
21 ... Thermochromic stamp,
22: Stamp main body, 22a: front opening,
24: friction body, 24a: rear part, 24b: front end face, 24c: recess,
24d ... corner,
25 ... cap, 250 ... cap body, 250a ... front opening,
31 ... Thermochromic stamp,
32: Stamp main body, 32a: front opening,
32b: Square tube portion, 32c: Locking convex portion,
34: friction body, 34a: rear part, 34b: front end face, 34c: recess,
34d ... corner,
35: Cap, 350: Cap body, 350a: front opening,
350b: Locking recess.

Claims (3)

熱変色性インキを押印する印面と、前記熱変色性インキにより得られた紙面上の印像を摩擦してその摩擦熱で前記印像を熱変色可能な弾性材料から成る摩擦部とを有した熱変色性スタンプであって、
前記摩擦部に凹部を形成し、前記印面により得られる印像と同様の図柄を有したシート部材を、前記凹部に、前記摩擦部の表面が前記シート部材の表面より外方に位置して前記凹部が凹んだ状態となり当該シート部材が前記摩擦部で囲まれるよう貼着したことを特徴とする熱変色性スタンプ。
It has a seal surface for imprinting a thermochromic ink, and a friction portion made of an elastic material which can thermally discolor the imprint by the frictional heat by rubbing the imprint on the paper surface obtained by the thermochromic ink A thermochromic stamp,
A recess is formed in the friction portion, and a sheet member having a pattern similar to the impression obtained by the seal surface is positioned in the recess with the surface of the friction portion positioned outward from the surface of the sheet member. A thermochromic stamp characterized in that the recessed portion is in a recessed state and the sheet member is pasted so as to be surrounded by the friction portion.
熱変色性インキを押印する印面と、前記熱変色性インキにより得られた紙面上の印像を摩擦してその摩擦熱で前記印像を熱変色可能な弾性材料から成る摩擦部とを有した熱変色性スタンプであって、
前記摩擦部に貫通孔を形成し、前記貫通孔内に、前記印面を前方に有するスタンプ本体の後方を嵌着し、前記印面により得られる印像と同様の図柄を有したシート部材を、前記スタンプ本体の後端部に、前記摩擦部の表面が前記シート部材の表面より外方に位置して前記貫通孔が凹んだ状態となり当該シート部材が前記摩擦部で囲まれるよう貼着したことを特徴とする熱変色性スタンプ。
It has a seal surface for imprinting a thermochromic ink, and a friction portion made of an elastic material which can thermally discolor the imprint by the frictional heat by rubbing the imprint on the paper surface obtained by the thermochromic ink A thermochromic stamp,
A sheet member having a through hole formed in the friction portion, a rear side of a stamp main body having the seal surface in front is fitted in the through hole, and a sheet member having a pattern similar to an image obtained by the seal surface At the rear end of the stamp body, the surface of the friction portion is positioned outward from the surface of the sheet member, and the through hole is recessed so that the sheet member is enclosed by the friction portion. Characteristic thermochromic stamp.
熱変色性インキを押印する印面と、前記熱変色性インキにより得られた紙面上の印像を摩擦してその摩擦熱で前記印像を熱変色可能な弾性材料から成る摩擦部とを有した熱変色性スタンプであって、
前記熱変色性スタンプがスタンプ本体と該スタンプ本体の前後に着脱可能なキャップとを有し、前記キャップの開口部の反対側に前記摩擦部を設けると共に該摩擦部の端面に前記印面により得られる印像と同様の図柄を有したシート部材を配し、前記スタンプ本体の後部に係止部を設け且つ前記キャップに係止受部を設け、前記スタンプ本体に前記キャップを装着した状態で前記係止部と前記係止受部とが係合することにより、前記印面を押印して得られる図柄の向きと前記シート部材の図柄の向きとを一致させることを特徴とした熱変色性スタンプ。
It has a seal surface for imprinting a thermochromic ink, and a friction portion made of an elastic material which can thermally discolor the imprint by the frictional heat by rubbing the imprint on the paper surface obtained by the thermochromic ink A thermochromic stamp,
The thermochromic stamp has a stamp body and a detachable cap on the front and back of the stamp body, the friction portion is provided on the opposite side of the opening of the cap, and the seal surface is obtained on the end face of the friction portion A seat member having a pattern similar to that of the stamped image is disposed, a locking portion is provided at the rear of the stamp body, a lock receiving portion is provided on the cap, and the cap is attached to the stamp body. A thermochromic stamp characterized in that the direction of the design obtained by pressing the seal surface and the direction of the design of the sheet member are made to coincide with each other by the engagement of the stop portion and the engagement receiving portion.
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