JP6460856B2 - Membrane element manufacturing method - Google Patents

Membrane element manufacturing method Download PDF

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JP6460856B2
JP6460856B2 JP2015050107A JP2015050107A JP6460856B2 JP 6460856 B2 JP6460856 B2 JP 6460856B2 JP 2015050107 A JP2015050107 A JP 2015050107A JP 2015050107 A JP2015050107 A JP 2015050107A JP 6460856 B2 JP6460856 B2 JP 6460856B2
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filter plate
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membrane element
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JP2016168547A (en
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▲高▼橋 誠
誠 ▲高▼橋
公博 石川
公博 石川
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Kubota Corp
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本発明は、膜分離活性汚泥処理に用いられる膜エレメントの製造方法に関する。 The present invention relates to a method for producing a membrane element used for membrane separation activated sludge treatment.

従来、膜分離活性汚泥処理においては、ケース内に、複数の膜エレメントが所定間隔をあけて配列され、これら膜エレメントの下方に散気装置を設けた膜分離装置が使用される。   Conventionally, in membrane separation activated sludge treatment, a membrane separation apparatus is used in which a plurality of membrane elements are arranged at predetermined intervals in a case and an air diffuser is provided below these membrane elements.

図9に示すように、膜エレメント101は、濾板102と、濾板102の両面に備えられた分離膜103とを有している。分離膜103は、周縁部に沿って、例えば熱溶着により濾板102に接合されている。分離膜103と濾板102との接合部104(溶着部)は直線からなる四角枠状に形成されている。尚、接合部104で囲まれた領域が有効濾過領域105であり、この有効濾過領域105内において、被処理液が分離膜103を透過して透過液が得られる。   As shown in FIG. 9, the membrane element 101 has a filter plate 102 and separation membranes 103 provided on both sides of the filter plate 102. The separation membrane 103 is joined to the filter plate 102 along the peripheral edge by, for example, heat welding. A joint 104 (welded part) between the separation membrane 103 and the filter plate 102 is formed in a square frame shape formed of a straight line. An area surrounded by the joint 104 is an effective filtration area 105. In this effective filtration area 105, the liquid to be treated passes through the separation membrane 103 to obtain a permeate.

これによると、濾過運転時において、散気装置で散気を行うことにより、膜エレメント101間を下から上へ流れる気液混相の上向流106が発生し、この上向流106によって濾板102が振動する。そして、この振動により、分離膜103が揺れて接合部104に応力が繰り返し発生し、接合部104が経年劣化し、分離膜103が接合部104の箇所で剥離又は破断するといった問題がある。また、分離膜103が接合部104の箇所で剥離又は破断すると、接合部104は直線状に形成されているため、接合部104の長さ方向に沿って剥離又は破断が拡大されてしまうといった問題がある。   According to this, during the filtration operation, by performing aeration with the aeration device, an upward flow 106 of the gas-liquid mixed phase flowing from the bottom to the top between the membrane elements 101 is generated, and the upward flow 106 causes the filter plate to flow. 102 vibrates. Due to this vibration, the separation membrane 103 is shaken, and stress is repeatedly generated in the joint portion 104, the joint portion 104 is deteriorated with time, and the separation film 103 is peeled off or broken at the location of the joint portion 104. Further, when the separation membrane 103 peels or breaks at the joint 104, the joint 104 is formed in a straight line, and therefore, the separation or break is enlarged along the length direction of the joint 104. There is.

この問題の対策として、図10に示すように、直線状の接合部104,110を内外に複数本形成したり、接合部110の外側に網目状の補助接合部111を形成することが考えられる。これによると、接合部104,110を多重に設けることで、接合部104,110の一部が剥離又は破断したとしても、接合部104,110全体としてのシール性を確保することができるが、接合部104,110に発生する応力自体を低減させるものではない。尚、このような複数本の接合部104,110および補助接合部111を形成した膜エレメント101については例えば下記特許文献1に記載されている。   As measures against this problem, as shown in FIG. 10, it is conceivable to form a plurality of linear joint portions 104 and 110 inside and outside, or to form a mesh-like auxiliary joint portion 111 outside the joint portion 110. . According to this, by providing the joints 104 and 110 in a multiple manner, even if a part of the joints 104 and 110 is peeled off or broken, it is possible to ensure the sealing performance of the joints 104 and 110 as a whole. It does not reduce the stress itself generated at the joints 104 and 110. The membrane element 101 in which such a plurality of joints 104 and 110 and auxiliary joints 111 are formed is described in, for example, Patent Document 1 below.

特許第4969079号Japanese Patent No. 4996979

上記図10に示した従来形式では、接合部104,110に発生する応力自体を低減することはできず、また、複数本の接合部104,110および補助接合部111を形成するのに要する接合領域112(スペース)が拡大するため、有効濾過領域105が縮小されてしまうことがある。   In the conventional type shown in FIG. 10, the stress itself generated in the joints 104 and 110 cannot be reduced, and the joints required to form the plurality of joints 104 and 110 and the auxiliary joints 111 are not possible. Since the area 112 (space) is enlarged, the effective filtration area 105 may be reduced.

本発明は、分離膜が接合部の箇所で剥離又は破断するのを防止することができる膜エレメントの製造方法を提供することを目的とする。 An object of this invention is to provide the manufacturing method of the membrane element which can prevent that a separation membrane peels or fractures | ruptures in the location of a junction part.

上記目的を達成するために、本第1発明は、合成樹脂製の濾板の表面に有機膜からなる分離膜が備えられ、分離膜は周縁部に沿って濾板に接合されている膜エレメントの製造方法であって、
押圧面に凹凸が形成された加熱板と濾板との間に分離膜を挟んだ状態で、加熱板を濾板に対して押圧することにより、分離膜の周縁部と濾板とを接合し、膜エレメントの厚み方向における凹凸を有する接合部を形成するものである。
In order to achieve the above object, the first invention is a membrane element in which a separation membrane made of an organic membrane is provided on the surface of a synthetic resin filter plate, and the separation membrane is joined to the filter plate along the peripheral edge. A manufacturing method of
By pressing the heating plate against the filter plate with the separation membrane sandwiched between the heating plate with the unevenness formed on the pressing surface and the filter plate, the peripheral edge of the separation membrane and the filter plate are joined. The junction part which has the unevenness | corrugation in the thickness direction of a membrane element is formed .

これによると、加熱した加熱板と濾板との間に分離膜を挟んだ状態で、加熱板を濾板に対して押圧することにより、分離膜の周縁部と濾板とが溶着されて接合され、厚み方向における凹凸を有する接合部が形成される。
接合部がその長さ方向に沿って膜エレメントの厚み方向における凹凸を有するため、接合部が厚み方向において凹凸状に屈曲(又は湾曲)し、凹凸の無い直線状の接合部に比べて、接合部の長さが長くなる。これにより、接合部に発生する応力が分散されることで、接合部の単位長さ当りの応力が低減され、分離膜が接合部の箇所で剥離又は破断するのを防止することができる。
According to this, by pressing the heating plate against the filter plate with the separation membrane sandwiched between the heated heating plate and the filter plate, the peripheral edge of the separation membrane and the filter plate are welded and joined. As a result, a joint having irregularities in the thickness direction is formed.
Since the joint has irregularities in the thickness direction of the membrane element along its length direction, the joint is bent (or curved) in an irregular shape in the thickness direction, and compared to a linear joint without irregularities. The length of the part becomes longer. Thereby, the stress generated in the joint is dispersed, whereby the stress per unit length of the joint is reduced, and the separation film can be prevented from peeling or breaking at the joint.

本第発明における膜エレメントの製造方法は、濾板は、表面の周縁部に、厚み方向に突出した突部を有しており、
加熱板を濾板の突部に対して押圧することにより、分離膜の周縁部と濾板とを接合するものである。
In the manufacturing method of the membrane element in the second invention, the filter plate has a protrusion protruding in the thickness direction on the peripheral edge of the surface,
By pressing the heating plate against the projection of the filter plate, the peripheral edge of the separation membrane and the filter plate are joined.

これによると、加熱した加熱板と濾板との間に分離膜を挟んだ状態で、加熱板を濾板の突部に対して押圧することにより、分離膜の周縁部と濾板の突部とが溶着されて接合される。この際、加熱板の凹凸に対応して、濾板の突部が凹凸状に溶融するため、加熱板の熱が濾板の突部に集中して伝わり、効率的に濾板の突部を軟化または溶融させることができ、厚み方向における凹凸を有する接合部が形成される。   According to this, with the separation membrane sandwiched between the heated heating plate and the filter plate, by pressing the heating plate against the projection of the filter plate, the peripheral edge of the separation membrane and the projection of the filter plate Are welded together. At this time, since the protrusions of the filter plate melt in an uneven shape corresponding to the unevenness of the heating plate, the heat of the heating plate is concentrated and transmitted to the protrusions of the filter plate, and the protrusions of the filter plate are efficiently transferred. It can be softened or melted, and a joint having unevenness in the thickness direction is formed.

本第発明における膜エレメントの製造方法は、加熱板の凹凸は同一パターンを繰り返して形成されているものである。 In the manufacturing method of the membrane element in the third invention, the unevenness of the heating plate is formed by repeating the same pattern.

以上のように本発明によると、接合部がその長さ方向に沿って厚み方向において凹凸状に屈曲(又は湾曲)しているため、凹凸の無い直線状の接合部に比べて、接合部の長さが長くなる。これにより、接合部に発生する応力が分散されることで、接合部の単位長さ当りの応力が低減され、分離膜が接合部の箇所で剥離又は破断するのを防止することができる。   As described above, according to the present invention, the joint portion is bent (or curved) in the uneven direction in the thickness direction along the length direction thereof. Length increases. Thereby, the stress generated in the joint is dispersed, whereby the stress per unit length of the joint is reduced, and the separation film can be prevented from peeling or breaking at the joint.

本発明の第1の実施の形態における膜エレメントを備えた膜分離装置の一部切欠き斜視図である。1 is a partially cutaway perspective view of a membrane separation apparatus including a membrane element according to a first embodiment of the present invention. 同、膜エレメントの正面図である。FIG. 2 is a front view of the membrane element. 同、膜エレメントの製造方法を示す一部拡大斜視図であり、(a)は分離膜を加熱板で濾板に溶着する前の状態を示し、(b)は分離膜を濾板に溶着した後の状態を示す。It is a partially expanded perspective view showing the manufacturing method of the membrane element, wherein (a) shows a state before the separation membrane is welded to the filter plate with a heating plate, and (b) shows the separation membrane welded to the filter plate. Shown later. 同、膜エレメントの一部拡大側面図である。FIG. 2 is a partially enlarged side view of the membrane element. 同、膜エレメントの分離膜と濾板との接合部の凹凸部の形状を示す拡大図である。It is an enlarged view which shows the shape of the uneven | corrugated | grooved part of the junction part of the separation membrane and filter plate of a membrane element similarly. 本発明の第2の実施の形態における膜エレメントの分離膜と濾板との接合部の凹凸部の形状を示す拡大図である。It is an enlarged view which shows the shape of the uneven | corrugated | grooved part of the junction part of the separation membrane of a membrane element and the filter plate in the 2nd Embodiment of this invention. 本発明の第3の実施の形態における膜エレメントの分離膜と濾板との接合部の凹凸部の形状を示す拡大図である。It is an enlarged view which shows the shape of the uneven | corrugated | grooved part of the junction part of the separation membrane of a membrane element and the filter plate in the 3rd Embodiment of this invention. 本発明の第4の実施の形態における膜エレメントの分離膜と濾板との接合部の拡大図であり、(a)は接合部を正面から見た図を示し、(b)は(a)におけるX−X矢視図である。It is an enlarged view of the junction part of the separation membrane of the membrane element in the 4th Embodiment of this invention, and a filter plate, (a) shows the figure which looked at the junction part from the front, (b) is (a). FIG. 従来の膜エレメントの正面図である。It is a front view of the conventional membrane element. 別の従来の膜エレメントの一部拡大正面図である。It is a partially expanded front view of another conventional membrane element.

以下、本発明における実施の形態を、図面を参照して説明する。
(第1の実施の形態)
第1の実施の形態では、図1に示すように、1は膜分離活性汚泥処理に用いられる膜分離装置であり、この膜分離装置1は処理槽(図示省略)内に浸漬されて設置されている。膜分離装置1は、ケース3と、ケース3内に収容された複数の平板状の膜エレメント4と、膜エレメント4の下方に設置された散気装置5とを有している。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
(First embodiment)
In the first embodiment, as shown in FIG. 1, reference numeral 1 denotes a membrane separation device used for membrane separation activated sludge treatment, and this membrane separation device 1 is installed by being immersed in a treatment tank (not shown). ing. The membrane separation device 1 includes a case 3, a plurality of plate-like membrane elements 4 accommodated in the case 3, and an air diffuser 5 installed below the membrane element 4.

ケース3は、上下両端部が開放されており、上部の膜ケース7と、下部の散気ケース8とに分割形成されている。散気装置5は散気ケース8内に設置されている。
図2〜図5に示すように、膜エレメント4は、熱可塑性の合成樹脂(例えばABS樹脂等)製の四角平板状の濾板9と、濾板9の両面に設けられた分離膜10とを有し、膜面同士を対向させた状態で所定間隔をあけて配列されている。分離膜10は、有機膜であり、周縁部に沿って、熱溶着により濾板9に接合されている。これにより、分離膜10の周縁部に、四角枠状の接合部12が形成される。尚、接合部12で囲まれた領域が有効濾過領域13である。
The case 3 is open at both upper and lower ends, and is divided into an upper film case 7 and a lower air diffusion case 8. The diffuser 5 is installed in the diffuser case 8.
As shown in FIGS. 2 to 5, the membrane element 4 includes a square plate-shaped filter plate 9 made of a thermoplastic synthetic resin (for example, ABS resin), and separation membranes 10 provided on both surfaces of the filter plate 9. And are arranged at predetermined intervals with the film surfaces facing each other. The separation membrane 10 is an organic membrane, and is joined to the filter plate 9 by thermal welding along the peripheral edge. As a result, a rectangular frame-shaped joint 12 is formed at the peripheral edge of the separation membrane 10. An area surrounded by the joint 12 is an effective filtration area 13.

濾板9と分離膜10との間および濾板9の内部には、透過液14が流れる透過液流路(図示省略)が形成され、透過液流路に連通する透過液取出口15が濾板9の上端部に設けられている。尚、図1に示すように、透過液取出口15には透過液取出管路16が接続され、透過液取出管路16には透過液14を吸引する吸引ポンプ(図示省略)が設けられている。   A permeate passage (not shown) through which the permeate 14 flows is formed between the filter plate 9 and the separation membrane 10 and inside the filter plate 9, and a permeate outlet 15 communicating with the permeate passage is connected to the filter plate 9. It is provided at the upper end of the plate 9. As shown in FIG. 1, the permeate outlet 15 is connected to the permeate outlet 15, and the permeate outlet 16 is provided with a suction pump (not shown) for sucking the permeate 14. Yes.

接合部12は、その長さ方向に沿って、膜エレメント4の厚み方向Tにおける複数の凹凸部20,21を有している。凹凸部20,21は波型形状の同一パターンを繰り返して形成されている。尚、図3〜図5では、形状を把握し易くするために、凹凸部20,21を実際のものよりも誇張して示しており、実際には、図5に示すように、凹部20の底部から凸部21の頂部までの高さHは凹凸部20,21のピッチPよりも小さく、上記高さHが0.3〜1mm、ピッチPが1〜3mmの範囲に設定されている。   The joint portion 12 has a plurality of concave and convex portions 20 and 21 in the thickness direction T of the membrane element 4 along the length direction thereof. The concavo-convex portions 20 and 21 are formed by repeating the same corrugated pattern. 3 to 5, the concave and convex portions 20 and 21 are shown exaggerated from the actual one in order to make it easier to grasp the shape. Actually, as shown in FIG. The height H from the bottom part to the top part of the convex part 21 is smaller than the pitch P of the uneven parts 20, 21, and the height H is set in a range of 0.3 to 1 mm and the pitch P is set to 1 to 3 mm.

図3(a)には、分離膜10を接合する前の濾板9が示されており、濾板9は、両面の周縁部にそれぞれ、厚み方向Tに突出した突部23を有している。両突部23はそれぞれ四角枠状に形成され、突部23の幅Wは一例として3mmに設定されている。   FIG. 3A shows the filter plate 9 before the separation membrane 10 is joined. The filter plate 9 has protrusions 23 protruding in the thickness direction T on the peripheral portions of both surfaces. Yes. Both protrusions 23 are each formed in a square frame shape, and the width W of the protrusion 23 is set to 3 mm as an example.

図3(a)に示すように、加熱板24は、膜エレメント4を製造する際に使用される四角枠状の部材であり、濾板9に対する押圧面24aに、膜エレメント4の厚み方向Tに対応した凹凸部25,26を有している。加熱板24の凹凸部25,26は、接合部12の凹凸部20,21と同様に、波型形状の同一パターンを繰り返して形成されている。   As shown in FIG. 3A, the heating plate 24 is a square frame-shaped member used when the membrane element 4 is manufactured, and the thickness direction T of the membrane element 4 is formed on the pressing surface 24 a against the filter plate 9. Concave and convex portions 25 and 26 corresponding to. The concave and convex portions 25 and 26 of the heating plate 24 are formed by repeating the same corrugated pattern in the same manner as the concave and convex portions 20 and 21 of the joining portion 12.

以下に、上記膜エレメント4の製造方法について説明する。
図3(a)に示すように、加熱板24と濾板9との間に分離膜10を挟み、この状態で、加熱板24を濾板9の突部23に対して押圧することにより、分離膜10の周縁部と濾板9の突部23とを溶着して接合する。この際、加熱板24の凹凸部25,26に対応して、濾板9の突部23が凹凸状に溶融するため、図3(b)に示すように、長さ方向に沿って厚み方向Tにおける凹凸部20,21を有する接合部12が形成される。その後、加熱板24を濾板9から離脱させる。
Below, the manufacturing method of the said membrane element 4 is demonstrated.
As shown in FIG. 3 (a), the separation membrane 10 is sandwiched between the heating plate 24 and the filter plate 9, and in this state, the heating plate 24 is pressed against the protrusion 23 of the filter plate 9, The peripheral edge of the separation membrane 10 and the protrusion 23 of the filter plate 9 are welded and joined. At this time, since the protrusions 23 of the filter plate 9 melt in an uneven shape corresponding to the uneven portions 25 and 26 of the heating plate 24, the thickness direction along the length direction is shown in FIG. The joint portion 12 having the uneven portions 20 and 21 at T is formed. Thereafter, the heating plate 24 is detached from the filter plate 9.

このようにして濾板9の表裏片面に分離膜10を接合した後、濾板9の表裏を反転させ、同様な方法で、濾板9の反対側の片面に分離膜10を接合する。
上記のようにして製造された膜エレメント4においては、接合部12がその長さ方向に沿って厚み方向Tにおける凹凸部20,21を有するため、接合部12が厚み方向Tにおいて凹凸状に屈曲(又は湾曲)し、従来の凹凸部の無い直線状の接合部に比べて、接合部12の長さが長くなる。これにより、接合部12に発生する応力が分散されることで、接合部12の単位長さ当りの応力が低減され、分離膜10が接合部12の箇所で剥離又は破断するのを防止することができる。
After the separation membrane 10 is bonded to the front and back surfaces of the filter plate 9 in this way, the front and back surfaces of the filter plate 9 are reversed, and the separation membrane 10 is bonded to the opposite surface of the filter plate 9 in the same manner.
In the membrane element 4 manufactured as described above, since the joint portion 12 has the uneven portions 20 and 21 in the thickness direction T along the length direction thereof, the joint portion 12 is bent in an uneven shape in the thickness direction T. (Or curved), and the length of the joint 12 becomes longer than that of a conventional straight joint without an uneven portion. Thereby, the stress generated in the joint 12 is dispersed, so that the stress per unit length of the joint 12 is reduced, and the separation film 10 is prevented from peeling or breaking at the joint 12. Can do.

上記第1の実施の形態では、熱溶着によって、凹凸部20,21を有する接合部12を形成しているが、超音波溶着によって、凹凸部20,21を有する接合部12を形成してもよく、或いは、予め濾板9に凹凸部20,21を形成しておき、レーザー溶着や接着剤等によって分離膜10を濾板9に接合することで、凹凸部20,21を有する接合部12を形成してもよい。   In the said 1st Embodiment, although the junction part 12 which has the uneven | corrugated parts 20 and 21 is formed by heat welding, even if the junction part 12 which has the uneven | corrugated parts 20 and 21 is formed by ultrasonic welding, Alternatively, the joining portions 12 having the concavo-convex portions 20 and 21 may be formed by forming the concavo-convex portions 20 and 21 on the filter plate 9 in advance and joining the separation membrane 10 to the filter plate 9 by laser welding or an adhesive. May be formed.

(他の実施の形態)
上記第1の実施の形態では図5に示すように接合部12の凹凸部20,21を円弧状の波型にしたが、第2の実施の形態では図6に示すように凹凸部20,21を三角状の波型にしてもよく、また、第3の実施の形態では図7に示すように凹凸部20,21を四角状の波型にしてもよい。或いは上記第1〜第3の実施の形態のような波型ではなく、第4の実施の形態として、図8に示すように、凹部20を膜エレメント4の厚み方向Tから見て円形(又は三角形や四角形等の多角形)の窪みとし、互いに隣り同士の凹部20間を凸部21としてもよい。
(Other embodiments)
In the first embodiment, the concavo-convex portions 20 and 21 of the joint portion 12 are formed in an arc shape as shown in FIG. 5, but in the second embodiment, the concavo-convex portions 20 and 21 are formed as shown in FIG. 21 may be a triangular wave shape, and in the third embodiment, the concavo-convex portions 20 and 21 may be a square wave shape as shown in FIG. Alternatively, as shown in FIG. 8, instead of the corrugated shape as in the first to third embodiments, as shown in FIG. 8, the recess 20 is circular when viewed from the thickness direction T of the membrane element 4 (or (A polygon such as a triangle or a quadrangle), and a convex portion 21 may be formed between the concave portions 20 adjacent to each other.

4 膜エレメント
9 濾板
10 分離膜
12 接合部
20,21 凹凸部
23 突部
24 加熱板
24a 押圧面
25,26 凹凸部
T 厚み方向
4 Membrane Element 9 Filter Plate 10 Separation Membrane 12 Joints 20 and 21 Concave and Convex 23 Protrusions 24 Heating Plate 24a Pressing Surfaces 25 and 26 Concave and Convex Part T Thickness Direction

Claims (3)

合成樹脂製の濾板の表面に有機膜からなる分離膜が備えられ、分離膜は周縁部に沿って濾板に接合されている膜エレメントの製造方法であって、A separation membrane made of an organic membrane is provided on the surface of a synthetic resin filter plate, and the separation membrane is a method for producing a membrane element joined to the filter plate along the peripheral edge,
押圧面に凹凸が形成された加熱板と濾板との間に分離膜を挟んだ状態で、加熱板を濾板に対して押圧することにより、分離膜の周縁部と濾板とを接合し、膜エレメントの厚み方向における凹凸を有する接合部を形成することを特徴とする膜エレメントの製造方法。By pressing the heating plate against the filter plate with the separation membrane sandwiched between the heating plate with the unevenness formed on the pressing surface and the filter plate, the peripheral edge of the separation membrane and the filter plate are joined. A method for producing a membrane element, comprising forming a joint having irregularities in the thickness direction of the membrane element.
濾板は、表面の周縁部に、厚み方向に突出した突部を有しており、The filter plate has a protrusion protruding in the thickness direction on the peripheral edge of the surface,
加熱板を濾板の突部に対して押圧することにより、分離膜の周縁部と濾板とを接合することを特徴とする請求項1記載の膜エレメントの製造方法。The method for manufacturing a membrane element according to claim 1, wherein the peripheral edge of the separation membrane and the filter plate are joined by pressing the heating plate against the protrusion of the filter plate.
加熱板の凹凸は同一パターンを繰り返して形成されていることを特徴とする請求項1又は請求項2記載の膜エレメントの製造方法。The method for manufacturing a membrane element according to claim 1 or 2, wherein the unevenness of the heating plate is formed by repeating the same pattern.
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