JP6452388B2 - Lawn growth promoter and how to use it. - Google Patents

Description

  The present invention relates to turf growth promoters comprising PPO-inhibiting active compounds or VLCFA synthesis-inhibiting active compounds or combinations thereof and methods of their use to promote turf growth.

  In the maintenance of lawns such as golf courses, sports facilities, park green spaces, road slopes, etc., growth and growth are carried out in the same way as fertilization, weeding, pest control, watering, joint soil, lawn mowing, aeration, slicing, and satching. It is also important to use accelerators. Labor savings can be expected in grass maintenance if the above work can be done simultaneously rather than doing it alone. For example, if a herbicide can be used as a growth promoter, not only weeding but also promotion of grass growth can be expected.

  Conventionally, chlorella extract (trade name: Green Age), shiitake extract (trade name: Retemin solution), mixed herbal extract (trade name: Amgreen), etc. have been used as grass growth promoters, but weeding There is no effect.

  Oxadiazone and oxadialgyl are known as herbicidal active compounds having PPO (protoporphyrinogen oxidase) inhibitory activity, and are used as active ingredients in herbicides for paddy rice or herbicides for turf. Oxadiazone has been reported to have no effect on the growth of roots of seedlings such as Inge box and Azalea, and to bermuda turf (Weed science, 1980, 28 (5), Journal of Environmental Horticulture, 1996, 14 (4). ). Oxaziargyl has also been reported to be safe for turf (Bayer Crop Science website, description of the herbicide FENAX FLOWABLE (trade name), http://www.es.bayer.jp/product_green/lawn/fenax. html). However, although there is a description about the safety to seedlings and turf which are protected crops, there is no specific description about the growth promoting effect on turf, and there is no suggestion.

  Cavenstrol is known as a herbicidal active compound having VLCFA (very long chain fatty acids) synthesis inhibitory activity, and is used as an active ingredient in a herbicide for paddy rice or a herbicide for turf. . Caffentrol has also been reported to be safe for turf (Maruwa Biochemical Co., Ltd., explanation of La Poste Flowable (trade name), http://www.mbc-g.co.jp/green/products/126k. shml). On the other hand, when Arabidopsis thaliana was treated with cfentrolol as a herbicide at an appropriate concentration of 1/100 or less, the leaf size increased 1.3 times compared to the case of normal growth. VCLA synthesis inhibitors) have been reported to reduce VCLA synthesis and promote organ growth through activation of cell proliferation (PLoS Biology 11: e1001531, 3013). However, there is no specific description or suggestion that it has a growth promoting effect when used at an appropriate concentration as a herbicide.

Weed science, 1980, 28 (5) Journal of Environmental Horticulture, 1996, 14 (4) Bayer CropScience website, description of the herbicide FENAX flowable (trade name), http: // www. es. Bayer. jp / product_green / lawn / fenax. html Maruwa Biochemical Co., Ltd. Group, explanation of La Poste Floable (trade name), http: // www. mbc-g. co. jp / green / products / 126k. shml PLoS Biology 11: e1001531, 3013

  An object of the present invention is to provide a growth promoter capable of promoting the growth of turf and a method for using the same.

  Accordingly, the present invention provides a turf growth promoter comprising a PPO inhibitory active compound or a VLCFA synthesis inhibitory active compound or a combination thereof.

  Further, in the present invention, the PPO-inhibiting active compound is acifluorfen, bifenox, clomethoxynyl (clomethoxyphen), fluoroglycopheneethyl, fomesafen, halosulfene, lactophen, oxyflowphene, ethoxyphenethyl, fluazolate, pyraflufenethyl, Sinidone ethyl, flumioxazin, flumicrolacpentyl, fluthiaset methyl, thiadiazimine, oxadiazone, oxadiargyl, azaphenidine, carfentrazone ethyl, sulfentrazone, bencarbazone, pentoxazone, benzphendizone, butaphenacyl, pyraclonyl, profluazole, The lawn growth promoter is provided, which is selected from the group consisting of flufenpyrethyl and saflufenacil.

  Further, in the present invention, compounds having VLCFA synthesis inhibitory activity are acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, metazachlor, metolachlor, petoxamide, pretilachlor, propachlor, propisochlor, tenyl chlor, diphenamide, napropamide, naproanilide. A turf growth promoter selected from the group consisting of: flufenacet, mefenacet, fentolazamide, ipfencarbazone, anilophos, fenfentrol, pyroxasulfone, phenoxasulfone and piperophos.

  Furthermore, the present invention relates to a PPO inhibitory active compound or a VLCFA synthesis inhibitory active compound or a combination thereof and a bactericidal agent, bactericidal agent, acaricide, nematicide, insecticide, microbicide, fertilizer, attractant, infertility agent And a lawn growth promoter comprising a combination of at least one active ingredient selected from the group consisting of synergists, safeners, information chemicals, herbicides and plant growth regulators.

  Furthermore, the present invention is performed directly on the turf by spraying, spraying, spreading, etc., any of the above turf growth promoters, or sprayed on the soil before the turf grows or transplants the turf, Provided is a method for promoting turf growth, characterized by performing irrigation and mixing.

  Examples of the PPO-inhibiting active compound in the present invention include: acifluorfen, bifenox, clomethoxynyl (clomethoxyphene), fluoroglycofenethyl, fomesafen, halosafene, lactofen, oxyflowphene, ethokifenethyl, fluazolate, Piraflufenethyl, sinidoneethyl, flumioxazin, flumicrolacpentyl, fluthiaset methyl, thiadimine, oxadiazone, oxadiargyl, azaphenidine, carfentrazoneethyl, sulfentrazone, bencarbazone, pentoxazone, benzphendizone, butaphenacyl, pyraclonyl , Profluazole, flufenpyrethyl and saflufenacil.

  Therefore, in the present invention, the PPO inhibitory active compound is acifluorfen, bifenox, clomethoxynyl (clomethoxyphene), fluoroglycophene ethyl, fomesafen, halosulfene, lactophen, oxyflowphene, ethoxyphenethyl, fluazolate, pyraflufenethyl, sinidoneethyl , Flumioxazin, full microlac pentyl, fluthiaset methyl, thiadiazimine, oxadiazon, oxadiargyl, azaphenidine, carfentrazone ethyl, sulfentrazone, bencarbazone, pentoxazone, benzphendizone, butaphenacyl, pyraclonyl, profluazole, full The present invention relates to a turf growth promoter selected from the group consisting of fenpyrethyl and saflufenacil and a method of using the same. .

  Examples of suitable PPO-inhibiting active compounds in the present invention include: biphenox, pyraflufenethyl, flumioxazin, oxadiazone, oxadialgyl, azaphenidine, carfentrazoneethyl, sulfentrazone, pentoxazone, pyraclonyl And saflufenacil.

    Thus, the present invention relates to the above wherein the PPO inhibitory active compound is selected from the group consisting of bifenox, pyraflufenethyl, flumioxazin, oxadiazone, oxadialgyl, azaphenidine, carfentrazone ethyl, sulfentrazone, pentoxazone, pyraclonyl and saflufenacil. The present invention relates to a lawn growth promoter and a method of using the same.

  More preferred examples of the PPO-inhibiting active compound in the present invention include oxadiazone, carfentrazone ethyl, pyraflufen ethyl, biphenox or oxadialgyl.

  Therefore, the present invention relates to the turf growth promoter and the method of using the same, wherein the PPO-inhibiting active compound is selected from oxadiazone, carfentrazone ethyl, pyraflufenethyl, bifenox or oxadialgyl.

  Examples of the VLCFA synthesis-inhibiting active compounds in the present invention include: acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, metazachlor, metolachlor, petoxamide, pretilachlor, propachlor, propisochlor, tenyl chlor, diphenamide, Napropamide, naproanilide, flufenacet, mefenacet, fentolazamide, ipfencarbazone, anilofos, caffentrol, pyroxasulfone, phenoxasulfone and piperophos.

  Therefore, in the present invention, the active compound for inhibiting VLCFA synthesis is acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, metazachlor, metolachlor, petoxamide, pretilachlor, propachlor, propisochlor, tenylchlor, diphenamide, napropamide, naproanilide, flufena The present invention relates to a turf growth promoter selected from the group consisting of set, mefenacet, fentolazamide, ipfencarbazone, anilofos, fenfentrol, pyroxasulfone, phenoxasulfone and piperofos, and a method for using the same.

  Suitable examples of the VLCFA synthesis inhibitory active compound in the present invention include caffentrol, pyroxasulfone, phenoxasulfone, fluphenacet, napropamide, metolachlor, and alachlor.

  Therefore, the present invention relates to the turf growth promoter selected from the group consisting of fenfentrol, pyroxasulfone, phenoxasulfone, flufenacet, napropamide, metolachlor and alachlor, and a method for using the same, as the VLCFA synthesis inhibitory active compound. .

  In the present invention, it is surprising that a turf growth promoter comprising a PPO inhibitory active compound, a VLCFA synthesis inhibitory active compound or a combination thereof showed a turf growth promoting effect, particularly a root elongation promoting effect.

  In the PPO inhibitory active compound, Proto accumulated in the cell generates singlet oxygen in the presence of light, destroys the cell membrane, and kills the weeds. In the rhizomes that are not exposed to sunlight, there is a possibility that no photoreaction occurs and the cells are not destroyed. And even if some phytotoxicity etc. occur in the above-ground part, since the underground stem is healthy, the above-ground part recovers rapidly, and it is thought that growth is further promoted. In addition, there is a possibility that a VLCFA synthesis inhibitory active compound activates cell proliferation and promotes growth by reducing VLCFA in turf. Therefore, a turf growth promoter comprising a PPO inhibitory active compound or a VLCFA synthesis inhibitory active compound or a combination thereof is very advantageous and effective as a turf growth promoter.

  A lawn growth promoter comprising a PPO inhibitory active compound or a VLCFA synthesis inhibitory active compound or a combination thereof is a solution, emulsion, wettable powder, aqueous suspension, oily suspension, powder, powder, paste Such as soluble powders, soluble granules, dispersible granules, suspoemulsion formulations, natural compounds impregnated with active compounds, synthetic materials impregnated with active compounds, fertilizers and even microencapsulated in polymer materials Can be converted into conventional formulations.

  These formulations are prepared in a known manner, for example using surfactants (ie emulsifiers and / or dispersants and / or foam formers), optionally using the active compounds as extenders (ie liquid solvents and / or Or a solid support). Such formulations are prepared with appropriate equipment or prepared before or during application.

  Suitable for use as an adjunct is that the composition itself and / or preparations derived therefrom (eg spraying liquids, seed dressings) have certain characteristics, such as certain technical characteristics and / Also a substance that is suitable for imparting specific biological properties. Typical suitable adjuvants are bulking agents, solvents and carriers.

  Suitable bulking agents are, for example, water and polar and non-polar organic chemical liquids such as those selected from the following types: aromatic and non-aromatic hydrocarbons (eg paraffins) Alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (where appropriate, they may be substituted, etherified and / or esterified). ), Ketones (eg, acetone, cyclohexanone), esters (including fats and oils) and (poly) ethers, unsubstituted and substituted amines, amides , Lactams (eg N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (eg dimethylsulfoxy) ).

  When the extender used is water, for example, an organic solvent can be used as an auxiliary solvent. In essence, suitable liquid solvents are aromatic compounds such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic compounds and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic Hydrocarbons such as cyclohexane or paraffins such as petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycols and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, Strong polar solvents such as dimethyl sulfoxide and water are also suitable.

  According to the present invention, the carrier can be a solid or liquid, which can be solid or liquid, mixed or combined with the active compound to improve applicability, especially for application to plants or plant parts. Synthetic organic or inorganic materials. Such solid or liquid carriers are generally inert and should be suitable for use in the lawn.

  Suitable solid carriers are, for example, ammonium salts and ground natural minerals such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic materials such as high Solid supports suitable for granules include, for example, crushed and separated natural stones such as calcite, marble, pumice, cuff and dolomite, and also inorganic and organic, such as dispersed silica, alumina and silicates Synthetic granules made of coarse corn flour and granules made of organic materials such as paper, sawdust, coconut shells, corn cob and tobacco petiole; suitable emulsifiers and / or foam formers include, for example: Nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohols Ethers such as alkyl aryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, and also protein hydrolysates; suitable dispersants are nonionic and / or ionic Substances such as alcohol-POE and / or -POP ethers, acids and / or POP-POE esters, alkylaryl and / or POP-POE ethers, fats and / or POP-POE adducts, POE- And / or POP-polyol derivatives, POE- and / or POP-sorbitan or -sugar adducts, alkyl sulfates or aryl sulfates, alkyl sulfonates or aryl sulfonates and alkyl phosphates or aryls Those selected from the class of phosphates or their corresponding PO- ether adduct. In addition, suitable oligomers or polymers, such as those derived from vinyl monomers, those derived from acrylic acid, EO and / or PO alone or in combination with, for example, (poly) alcohols or (poly) amines Derived from. Furthermore, lignin and its sulfonic acid derivatives, unmodified cellulose and modified cellulose, aromatic and / or aliphatic sulfonic acids and their adducts with formaldehyde can also be used.

  In the above formulations, tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the form of powders or granules or latex such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipids such as Sephaline and lecithin, synthetic phospholipids, and the like can be used.

  Colorants such as inorganic pigments such as iron oxide, titanium oxide and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes, and micronutrients such as iron salts, manganese salts, boron Salts, copper salts, cobalt salts, molybdenum salts, zinc salts, and the like can be used.

  Other possible additives are fragrances, optionally modified mineral or vegetable oils, waxes, and nutrients (including micronutrients) such as iron salts, manganese salts, boron salts, copper salts Cobalt salts, molybdenum salts, zinc salts and the like.

  Stabilizers (eg, low temperature stabilizers), preservatives, antioxidants, light stabilizers, or other agents that improve chemical and / or physical stability can also be present.

  The above-mentioned preparation is generally 0.01 to 98% by weight of a PPO inhibitory active compound and / or VLCFA synthesis inhibitory active compound, preferably 0.5 to 90% by weight of a PPO inhibitory active compound or VLCFA synthesis inhibitory active compound or a compound thereof. Contains a combination of

  One form of the present invention can be used solely with a PPO inhibitory compound or a VLCFA synthesis inhibitory active compound or a combination thereof, or it can be used in a formulation and can be used in one or more suitable forms. Fungicides, bactericides, acaricides, nematicides, insecticides, microbicides, fertilizers, attractants, fertility agents, synergists, safeners, information chemicals, herbicides and / or plant growth Includes mixtures with co-components such as regulators. Combining the co-component with a PPO inhibitory active compound or VLCFA synthesis inhibitory active compound or a combination thereof produces a synergistic effect. That is, the activity of the mixture is greater than expected based on the activity of the individual components. In general, the combination can be used in a premix, tank mix or ready-made mixture.

  Each additional co-component is present in a broad range, preferably in a ratio of 100: 1 to 1: 100, particularly preferably in a ratio of 5: 1 to 1: 5. It can be mixed with a VLCFA synthesis inhibitory active compound or a combination thereof.

One aspect of the present invention provides a PPO-inhibiting active compound or a VLCFA synthesis-inhibiting active compound or a combination thereof as a bactericidal agent, bactericidal agent, acaricide, nematicide, insecticide, microbicide, fertilizer, attractant. Used to promote turf growth in combination with one or more active ingredients selected from the group consisting of agents, fertility agents, synergists, safeners, information chemicals, herbicides and plant growth regulators That is.

  The co-components are, for example, those listed below, but are not limited thereto.

Insecticide / acaricide / nematicide:
The active compounds identified by their generic names herein are known and are described, for example, in the Pesticide Handbook (“The Pesticide Manual” 14th Ed., British Crop Protection Council 2006), or It can be found on the Internet (for example, “http://www.alanwood.net/pesticides”).

(1) Acetylcholinesterase (AChE) inhibitors, such as
Carbamates such as alanic carb, aldicarb, bendiocarb, benfuracarb, butocarboxyme, butoxycarboxym, carbaryl, carbofuran, carbosulfan, etiofencarb, fenobucarb, formethanate, furthiocarb, isoprocarb, methiocarb, mesomil, metorcarb, oxamyl, pirimicurpro Thiodicarb, thiophanox, triazamate, trimetacarb, XMC, and xylylcarb; or
Organophosphates such as acephate, azamethiphos, azinephos (-methyl, -ethyl), kazusafos, chloroethoxyphos, chlorfenvinphos, chlormefos, chlorpyrifos (-methyl), coumaphos, cyanophos, dimethone-S-methyl, Diazinon, dichlorvos / DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, etoprophos, famfur, phenamiphos, fenitrothion, fenthion, phostiazate, heptenophos, isofenphos, O- (methoxyaminothiophosphoryl) malathione, isoxathione , Mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, nared, ometoate, oxydimethone-me , Parathion (-methyl), phentoate, folate, hosalon, phosmet, phosphamidone, phoxime, pyrimifos (-methyl), propenofos, propetophos, prothiophos, pyraclophos, pyridafenthion, quinalphos, sulfotep, tebupyrimphos, temufos, terbufos, tetrachlorvinphos Thiometone, triazophos, trichlorfone, and bamidethione;
(2) GABA-regulated chloride channel antagonist, such as
Organochlorine systems, such as chlordane and endosulfan (alpha-); or
Fiprol-based (phenylpyrazole-based), such as ethiprol, fipronil, pyrafluprolol, and pyriprolol;
(3) Sodium channel modulator / voltage-dependent sodium channel blocker, eg
Pyrethroids such as acrinathrin, allethrin (d-cis-trans, d-trans), bifenthrin, bioareslin, bioareslin-S-cyclopentenyl, violesmethrin, cycloprotorin, cyfluthrin (beta-), cyhalothrin (gamma-, Lambda), cypermethrin (alpha-, beta-, theta, zeta-), ciphenothrin [(1R) -trans-isomer], deltamethrin, dimefluthrin, empentrin [(EZ)-(1R) -isomer] , Esfenvalerate, etofenprox, fenpropatoline, fenvalerate, flucitrinate, flumethrin, fulvalinate (tau-), halfenprox, imiprothrin, methutothrin, permethrin, phenothrin [(1 ) -Trans-isomer)], praretrin, profluthrin, pyrethrin (pyrethrum), resmethrin, RU 15525, silafluophene, tefluthrin, tetramethrin [(1R) -isomer], tralomethrin, transfluthrin, and ZXI 8901 Or
DDT; or methoxychlor;
(4) nicotinic acetylcholine receptor agonists, such as
Neonicotinoids such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam; or
nicotine;
(5) allosteric acetylcholine receptor modulators (agonists), for example
Spinosyn systems such as spinetoram and spinosad;
(6) Chloride channel activator, eg
Avermectins / milbemycins such as abamectin, emamectin benzoate, repimectin, and milbemectin;
(7) juvenile hormone analogs, eg
Hydroprene, quinoprene, methoprene; or phenoxycarb; pyriproxyfen;
(8) active compounds whose mechanism of action is unknown or non-specific, eg
A fumigant such as methyl bromide and another alkyl halide; or
Chloropicrin; sulfuryl fluoride; borax;
(9) Selective feeding inhibitors, for example
Pymetrozine; or flonicamid;
(10) Tick growth inhibitor, for example
Clofentezin, diflovidazine, hexothiazox, etoxazole;
(11) Microbial disruptor of insect digestive tract membrane, for example,
Bacillus thuringiensis subspecies israelensis (Bacillus thuringiensis subspecies israelensis), Bacillus sphaericus subspecies isawai (Bacillus thuringiensis Subspecies Kurstaki (Bacillus thuringiensis subspecies kurstaki), Bacillus thuringiensis subsp. Tenebrionis (Bacillus thuringiensis subspecies tenebrionis), and BT plant protein A, for example, c: Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Ab1;
(12) Oxidative phosphorylation inhibitors, ATP disruptors, such as
Diafenthiuron; or
An organotin compound, such as azocyclotin, cyhexatin, fenbutane oxide; or
Propargit; Tetradiphone;
(13) Oxidative phosphorylation decouplers that act by blocking the H proton gradient, eg
Chlorfenapyr and DNOC;
(14) nicotinic acetylcholine receptor antagonists such as
Bensultap, cartap (hydrochloride), thiocyclam, and thiosultap (sodium);
(15) Chitin biosynthesis inhibitors (type 0), for example
Benzoylurea series, such as bistrifluron, chlorfluazuron, diflubenzuron, fullcycloxuron, flufenoxuron, hexaflumuron, lufenuron, novallon, nobiflumuron, teflubenzuron, and triflumuuron;
(16) Chitin biosynthesis inhibitor (type 1), for example
Buprofezin;
(17) moulting disruptors, such as
Cyromazine;
(18) ecdysone agonist / disrupter, eg
Diacylhydrazines such as chromafenozide, halofenozide, methoxyphenozide, and tebufenozide;
(19) Octopamine agonist, for example
Amitraz;
(20) Complex-III electron transport inhibitors, for example
Hydramethylnon; acequinosyl; fluacrylpyrim; furometokin (21) complex-I electron transport inhibitors, such as
Belonging to the group of METI acaricides, for example phenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad; or
Rotenon (Derris);
(22) Voltage-gated sodium channel blockers, such as
Indoxacarb; metaflumizone;
(23) inhibitors of acetyl CoA carboxylase, for example
Tetronic acid derivatives such as spirodiclofen and spiromesifen; or
Tetramic acid derivatives, such as spirotetramat;
(24) Complex-IV electron transport inhibitors, such as
Phosphine-based, such as aluminum phosphide, calcium phosphide, phosphine, zinc phosphide; or cyanide;
(25) Complex-II electron transport inhibitors, such as
Sienopyrafen; cyflumetofen; pivlumide (28) Ryanodine receptor effector, eg
Diamides such as fulvendiamide, chlorantraniliprole (linaxypyr), cyantraniliprole (siadipyl), and also 3-bromo-N- {2-bromo-4-chloro-6-[(1- Cyclopropylethyl) carbamoyl] phenyl} -1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from WO 2005/077934) or 2- [3,5- Dibromo-2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -1,2-dimethylhydrazinecarboxylate methyl (WO 2007/043677). IKI-3106 Solution 50 (New Agricultural Practical Application Test Results) Further active compounds whose mechanism of action is unknown, such as azadirachtin, amidoflumet, benzoximate, biphenazate, quinomethionate, cryolite, dicophol, fluene Sulfone (5-chloro-2-[(3,4,4-trifluorobut-3-en-1-yl) sulfonyl] -1,3-thiazole), flufenelim, fluopyram, pyridalyl, and pyrifluquinazone As well as a product based on Bacillus films (I-1582, BioNeem, Votivo) and also the following known active compounds:
4-{[(6-Bromopyrid-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(6-Fluoropyrida-3 -Yl) methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(2-chloro-1,3-thiazol-5-yl) ) Methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(6-chloropyrid-3-yl) methyl] (2-fluoroethyl) amino } Furan-2 (5H) -one (known from WO 2007/115644), 4-{[(6-chloropyrid-3-yl) methyl] (2,2-difluoroethyl) amino} Furan-2 (5H) -one (known from WO 2007/115644), 4-{[(6-chloro-5-fluoropyrid-3-yl) methyl] (methyl) amino} furan-2 (5H) -one ( WO 2007/1155643), 4-{[(5,6-dichloropyrid-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115646), 4-{[(6-chloro-5-fluoropyrid-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (known from WO 2007/1155643), 4-{[(6-chloropyrida -3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (known from EP-A-0539588), 4-{[(6-chloropyrida- 3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from EP-A-0539588), [(6-chloropyridin-3-yl) methyl] (methyl) oxide-λ ⁴ − Sulfanilidenecyanamide (known from WO 2007/149134), [1- (6-chloropyridin-3-yl) ethyl] (methyl) oxide-λ ⁴ -sulfanilidenecyanamide (known from WO 2007/149134) and its Diastereomers (A) and (B)

(Also known from WO 2007/149134), [(6-trifluoromethylpyridin-3-yl) methyl] (methyl) oxide-λ ⁴ -sulfanilidenecyanamide (known from WO 2007/095229), suloxafurol ( Similarly known from WO 2007/149134), 11- (4-chloro-2,6-dimethylphenyl) -12-hydroxy-1,4-dioxa-9-azadispiro [4.2.4.2] tetradeca- 11-en-10-one (known from WO 2006/089633), 3- (4′-fluoro-2,4-dimethylbiphenyl-3-yl) -4-hydroxy-8-oxa-1-azaspiro [4. 5] Dec-3-en-2-one (known from WO 2008/067911), 1- [2-fluoro-4-methyl-5- [(2,2,2-trifluoroethyl) sulfinyl] phenyl] -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (known from WO 2006/043635), [(3S , 4aR, 12R, 12aS, 12bS) -3-[(cyclopropylcarbonyl) oxy] -6,12-dihydroxy-4,12b-dimethyl-11-oxy-9- (pyridin-3-yl) -1,3 , 4,4a, 5,6,6a, 12,12a, 12b-decahydro-2H, 11H-benzo [f] pyrano [4,3-b] chromen-4-yl] methyl cyclopropanecarboxylate (WO 2006 / 129714), 2-cyano-3- (difluoromethoxy) -N, N-dimethylbenzenesulfonamide (WO 2006/05643). 3), 2-cyano-3- (difluoromethoxy) -N-methylbenzenesulfonamide (known from WO 2006/100288), 2-cyano-3- (difluoromethoxy) -N-ethylbenzenesulfonamide (WO 2005). / Known from WO 2007/057407), 4- (difluoromethoxy) -N-ethyl-N-methyl-1,2-benzothiazol-3-amine 1,1-dioxide (known from WO 2007/057407) and N- [ 1- (2,3-Dimethylphenyl) -2- (3,5-dimethylphenyl) ethyl] -4,5-dihydro-1,3-thiazol-2-amine (known from WO 2008/104503).

Particularly preferred co-components are
Chlorantraniprol, thiodicarb, cyfluthrin, imidacloprid, thiacloprid, cyfluthrin, silafluophene, acetamiprid, thiamethoxam, fulbenzamide, permethrin, methoxyphenozide, etofenprox, terfbenzuron, diazinone, tralomethrin, BT, indoxycarb , But not limited to this.

Bactericides (1) Ergosterol biosynthesis inhibitors, such as aldimorph, azaconazole, viteltanol, bromconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, Etaconazole, phenalimol, fenbuconazole, fenhexamide, fenpropidin, fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriazole, fluconazole, fluconazole-cis, hexaconazole, imazalyl, imazalyl sulfate, imi Benconazole, ipconazole, metconazole, microbutanyl, naphthifine, nuarimol, oxypoconazole, paclobutrazol, pefrazo , Penconazole, piperalin, prochloraz, propiconazole, prothioconazole, piributicalbu, pyrifenox, quinconazole, cimeconazole, spiroxamine, tebuconazole, terbinafine, tetraconazole, triadimethone, triadimenol, tridemorph, triflumizole, Trifolin, triticonazole, uniconazole, uniconazole-p, biniconazole, voriconazole, 1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, 1- (2, 2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5-carboxylate methyl, N ′-{5- (difluoromethyl) -2-methyl-4- [3- ( Trimethylsilyl Propoxy] phenyl} -N-ethyl-N-methylimidoformamide, N-ethyl-N-methyl-N ′-{2-methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl } Imidoformamide and O- [1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl] -1H-imidazole-1-carbothioate.

  (2) Respiratory inhibitors (respiratory chain inhibitors) such as bixafen, boscalid, carboxin, diflumetrim, fenfram, fluopyram, flutolanil, fluxapiloxad, flametopir, flumeciclox, syn-epimeric racemate 1RS, 4SR, Isopyrazam mixture of 9RS and anti-epimeric racemate 1RS, 4SR, 9SR, isopyrazam (anti-epimeric racemate), isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), isopyrazam (syn-epimeric racemic 1RS, 4SR, 9RS), isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), isopyrazam (syn-epimeric enantiomer 1S, 4) , 9S), mepronil, oxycarboxyl, penflufen, penthiopyrad, sedaxane, tifluzamide, 1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, 3 -(Difluoromethyl) -N- [4-fluoro-2- (1,1,2,3,3,3-hexafluoropropoxy) phenyl] -1-methyl-1H-pyrazole-4-carboxamide and N- [ 1- (2,4-Dichlorophenyl) -1-methoxypropan-2-yl] -3- (difluoromethyl) -1-methyl-1 - pyrazole-4-carboxamide.

  (3) Respiratory inhibitors (respiratory chain inhibitors) that act on the complex III of the respiratory chain, such as amethoctrazine, amisulbrom, azoxystrobin, cyazofamide, dimoxystrobin, enestroburin, famoxadone, fenamidone , Fluoxastrobin, cresoxime-methyl, metminostrobin, orissastrobin, picoxystrobin, pyraclostrobin, pyramethostrobin, pyraoxystrobin, pyribencarb, trifloxystrobin, (2E) -2- (2-{[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylethane Amide, (2E) -2- (methoxyimino) -N-methyl-2- (2-{[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} Phenyl) ethaneamide, (2E) -2- (methoxyimino) -N-methyl-2- {2-[(E)-({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl } Ethanamide, (2E) -2- {2-[({[(1E) -1- (3-{[(E) -1-fluoro-2-phenylethenyl] oxy} phenyl) ethylidene] amino} oxy ) Methyl] phenyl} -2- (methoxyimino) -N-methylethanamide, (2E) -2- {2-[({[(2E, 3E) -4- (2,6-dichlorophenyl) but-3. -En-2-ylidene] No} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethanamide, 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl ) Pyridine-3-carboxamide, 5-methoxy-2-methyl-4- (2-{[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-1,2,4-triazol-3-one, (2E) -2- {2-[({cyclopropyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] Methyl phenyl} -3-methoxyprop-2-enoate, N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide, 2 -{2-[(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide and (2R) -2- {2-[(2,5-dimethylphenoxy) methyl] phenyl}- 2-Methoxy-N-methylacetamide.

  (4) Mitotic and cell division inhibitors, such as benomyl, carbendazim, chlorphenazole, dietofencarb, ethaboxam, fluopicolide, fuberidazole, pencyclon, thiabendazole, thiophanate-methyl, thiophanate, zoxamide, 5-chloro-7- (4-Methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine and 3-chloro-5- (6- Chloropyridin-3-yl) -6-methyl-4- (2,4,6-trifluorophenyl) pyridazine.

  (5) Compounds having multi-site activity, such as Bordeaux solution, captahol, captan, chlorothalonil, copper hydroxide, copper naphthenate, copper oxide, basic copper chloride, copper sulfate, etc., dicloflurane, dithianone, dodine, Dodine free base, farbum, fluorophorpet, holpet, guazatine, guazatine acetate, iminotadine, iminotazine arbesylate, iminoctadine triacetate, mankappa, mancozeb, manneb, methylam, methylam-zinc, oxine-copper, propamidine ), Propineb, sulfur and sulfur agents such as calcium polysulfide, thiuram, tolylfluanid, dineb and ziram.

  (6) Resistance inducers, such as acibenzoral-S-methyl, isotianil, probenazole and thiazinyl.

  (7) Amino acid and protein biosynthesis inhibitors, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil.

  (8) ATP production inhibitors such as fentin acetate, fentin chloride, hydroxylated fentin and silthiophan.

  (9) Cell wall synthesis inhibitors such as Bench Avaricarb, Dimethomorph, Flumorph, Iprovaricarb, Mandipropamide, Polyoxins, Polyoxorim, Validamycin A and Varifenalate.

  (10) Lipid and membrane synthesis inhibitors such as biphenyl, chloronebu, dichlorane, edifenphos, etridiazole, iodocarb, iprobenphos, isoprothiolane, propamocarb, propamocarb hydrochloride, prothiocarb, pyrazophos, quintozen, technazen and tolcrophos-methyl.

  (11) Melanin biosynthesis inhibitors such as carpropamide, diclocimet, phenoxanyl, phthalide, pyroxylone and tricyclazole.

  (12) Nucleic acid synthesis inhibitors such as benalaxyl, benalaxyl M (kiraraxyl), bupirimate, cloziracone, dimethymol, ethylimol, furalaxyl, himexazole, metalaxyl, metalaxyl-M (mephenoxam), ofrase, oxadixyl, oxophosphate.

  (13) Signaling inhibitors such as clozolinate, fenpicuronyl, fludioxonil, iprodione, procymidone, quinoxyphene and vinclozoline.

  (14) Uncouplers such as binapacryl, dinocup, ferrimzone, fluazinam and meptyldinocup.

  (15) Yet another compound, such as benazole, betoxazine, capsimycin, carvone, quinomethionate, clazaphenone, churafeneb, cyflufenamide, simoxanyl, cyprosulfamide, dazomet, debacarb, dichlorophen, dichromedin, diphenzoquat, Diphenzoquat methylsulfate, diphenylamine, ecomat, fenpyrazamine, flumethoverl, fluoromide, fursulfanamide, fluthianyl, fosetyl-aluminum, fosetyl-calcium, fosetyl-sodium, hexachlorobenzene, ilumamycin, metasulfocarb, methylisothiocyanate, metolaphenone, Mildiomycin, Natamycin, Dimethyldithiocarbamate, Nitro Allyl-isopropyl, octyninone, oxamocarb, oxyfentiin, pentachlorophenol and its salt, phenothrin, phosphoric acid and its salt, propamocarb-focetylate, propanocin-sodium, proquinazide, pyrrolnitrin, tebufloquine, teclophthalam, toluniphanide, triazoxide, Trichlamide, zalylamide, 1- (4- {4-[(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazole -2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, 1- (4- {4-[(5S)- 5- (2,6-difluorophenyl) -4,5-dihydro-1,2-o Sazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, -(4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidine-1- Yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, 1H-imidazole-1-carboxylic acid 1- (4-methoxyphenoxy) -3,3-dimethyl Butan-2-yl, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) -one, 2- [5-Methyl-3 -(Trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4-[(5R) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl]- 1,3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4- [(5S) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl -3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- {4- [4- (5-phenyl-4,5-dihydro-1,2-oxazol-3-yl) -1, 3-thiazol-2-yl] piperidin-1-yl} ethanone, -Butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4-methyl-1H -Imidazol-5-yl] pyridine, 2-phenylphenol and salts thereof, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3- [5- (4-chlorophenyl) -2,3- Dimethyl-1,2-oxazolidine-3-yl] pyridine, 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, 4- (4-chlorophenyl)- 5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, 5-amino-1,3,4-thiadiazole-2-thiol, 5-chloro-N′-phenyl-N ′ (Prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, 5-methyl-6-octyl [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (2Z) Ethyl 3-amino-2-cyano-3-phenylprop-2-enoate, N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl ] Propanamide, N-[(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, N-[(5-bromo -3-chloropyridin-2-yl) methyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4- Dichloropyridine -3-carboxamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodopyridine-3-carboxamide, N-{(E)-[(cyclo Propylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N-{(Z)-[(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidine -4-yl) -N- (1,2,3,4-tetrahydronaphthalen-1-yl) -1,3-thiazole-4-carboxamide, N-methyl- -(1-{[5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N-[(1R) -1,2,3,4- Tetrahydronaphthalen-1-yl] -1,3-thiazole-4-carboxamide, N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl } Piperidin-4-yl) -N-[(1S) -1,2,3,4-tetrahydronaphthalen-1-yl] -1,3-thiazole-4-carboxamide, pentyl {6-[({[( 1-methyl-1H-tetrazol-5-yl) (phenyl) methylidene] amino} oxy) methyl] pyridin-2-yl} carbamate, phenazine-1-carboxylic acid, quinolin-8-ol and quino Down-8-ol sulfate (2: 1).

(16) Further compounds such as 1-methyl-3- (trifluoromethyl) -N- [2 '-(trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, N- ( 4'-chlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, N- (2 ', 4'-dichlorobiphenyl-2-yl) -3- ( Difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [4 '-(trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4 Carboxamide, N- (2 ', 5'-difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole-4-carbo Samido, 3- (difluoromethyl) -1-methyl-N- [4 '-(prop-1-in-1-yl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, 5-fluoro-1 , 3-Dimethyl-N- [4 '-(prop-1-in-1-yl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, 2-chloro-N- [4'-(prop- 1-in-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 3- (difluoromethyl) -N- [4 ′-(3,3-dimethylbut-1-in-1-yl) biphenyl- 2-yl] -1-methyl-1H-pyrazole-4-carboxamide, N- [4 ′-(3,3-dimethylbut-1-in-1-yl) biphenyl-2-yl] -5-fluoro-1 , 3-Dimethyl-1H Pyrazole-4-carboxamide, 3- (difluoromethyl) -N- (4'-ethynylbiphenyl-2-yl) -1-methyl-1H-pyrazole-4-carboxamide, N- (4'-ethynylbiphenyl-2- Yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- (4'-ethynylbiphenyl-2-yl) pyridine-3-carboxamide, 2-chloro-N- [4 '-(3,3-Dimethylbut-1-in-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 4- (difluoromethyl) -2-methyl-N- [4'-(tri Fluoromethyl) biphenyl-2-yl] -1,3-thiazole-5-carboxamide, 5-fluoro-N- [4 ′-(3-hydroxy-3-methylbut- 1-in-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 ′-(3-hydroxy-3-methylbut-1- In-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 3- (difluoromethyl) -N- [4 ′-(3-methoxy-3-methylbut-1-in-1-yl) biphenyl- 2-yl] -1-methyl-1H-pyrazole-4-carboxamide, 5-fluoro-N- [4 ′-(3-methoxy-3-methylbut-1-in-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '-(3-methoxy-3-methylbut-1-in-1-yl) biphenyl-2-yl] pyridine- 3-ka Boxamide, (5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone and N- [2- (4-{[3- (4 -Chlorophenyl) prop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] -N2- (methylsulfonyl) valinamide. BAF-1207 flowable (new agricultural chemical practical application test results published by the Japan Plant Protection Association), NF-171 granule wettable powder 20 (same as left), GG226SC (same as left), NNF-0721 flowable 20 (same as left), NR-29 wettable powder (Same as left)
Particularly preferred co-components are
Tifluzamide, polyoxin D zinc salt, tolcrofos methyl, boscalid, captan, organic copper agent, penthiopyrad, iminoctazine acetate, thiophanate methyl, isoprothiolane, fosetyl, flutolanil, tebuconazole, polycarbamate, metalaxyl, metconazole, azoxystrobin, cyproconazole, Hexaconazole, mepronil, pencyclon, chloronebu, procamocarb, clothoxime methyl, difenoconazole, TPN, hydroxyisoxazole, iprodione, imibenconazole, metconazole, propiconazole, triadimefone, vitertanol, cimeconazole, valididamycin, propinebu, amisulprom Kispoconazole fumarate, benomyl, manzeb, fludioxonil Myclobutanil, Jiazofamido, furametpyr, but there is such trifloxystrobin, this does not apply.

Herbicides and plant regulators such as acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvyl shikimate-3-phosphate synthase, glutamine synthase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase, photosystem I , Photosystem II, known active compounds based on inhibition of protoporphyrinogen oxidase, for example Weed Research 26 (1986) 441-445 or “The Pesticide Manual”, 14th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2006 and references cited therein. With known herbicides or plant growth regulators that can be combined with penflufen according to the invention, for example the following active substances (compounds specified by the general name by the International Organization for Standardization (ISO) or by chemical name or code number) Yes and always includes all forms of use such as acids, salts, esters and isomers, eg stereoisomers and optical isomers.

Acetochlor, acibenzoral, acibenzoral-S-methyl, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, aridocrol, aloxidim, aroxidim-sodium, amethrin, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrochlor, aminopyrlide, Amitrol, ammonium sulfamate, ansimidol, anilophos, aslam, atrazine, azaphenidine, azimsulfuron, adiprotrin, beflubutamide, benazoline, benazoline-ethyl, bencarbazone, benfluralin, benfrate, bensulide, bensulfuron, bensulfuron-methyl, bentazone, Benzfendizone, benzobicyclon, benzophenap, benzofluo , Benzoylprop, bicyclopyrone, bifenox, biranfos, biranfos-sodium, bispyribac, bispyribac-sodium, bromacil, bromobutide, bromophenoxime, bromoxynil, bromron, buminafos, busoxine, butachlor, butafenyl, butamichlor, butrachlor Butroxidim, Butyrate, Caffefentrol, Carbetamid, Carfentrazone, Carfentrazone-Ethyl, Chlomethoxyphen, Chloramben, Chlorazihop, Chlorazihop-Butyl, Chlorbromulone, Chlorbufam, Chlorfenac, Chlorfenac-Sodium, Chlorfenprop, Chlorflu Renol, chloroflurenol-methyl, black Dazon, chlorimuron, chlorimuron-ethyl, chlormequat-chloride, chlornitrimphene, chlorophthalim, chlortarim, chlorotoluron, chlorsulfuron, sinidone, sinidone-ethyl, cinmethyline, sinosulfuron, cretodim, clodinaf, proprazine Fencet, Chromazone, Chromep, Cloprop, Clopyralide, Chloranthram, Chloranthram-Methyl, Cumyllon, Cyanamide, Cyanazine, Cyclanilide, Cycloate, Cyclosulfamlone, Cycloxydim, Cyclulone, Cyhalohop, Cyhalohop-Butyl, Cypercoat, Ciprazine, Cyprazole, 2 , 4-D, 2,4-DB, Daimuron on) / Dimron, darapon, daminozide, dazomet, n-decanol, desmedifam, desmethrin, detosylpyrazolate (DTP), diallate, dicamba, diclobenil, dichlorprop, dichlorprop-P, diclohop , Diclohop-methyl, diclohop-P-methyl, dicrolam, diethyl, diethyl-ethyl, diphenoxuron, difenzocote, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimeflon, dikeglac-sodium, dimeflon, dimethylpiperate, dimethametrol, dimethamethrin , Dimethenamide, dimethenamide-P, dimethipine, dimetrasulfuron, dinitramine, dinocebu, dinoterb, diphena , Dipropetrin, diquat, diquat dibromide, dithiopyr, diuron, triamon, DNOC, eglinazine-ethyl, endal, EPTC, esprocarb, ethalfluralin, etameturflon, etameturflon-methyl, etephone, etizimuron, etiodin, ethofetose Ethoxyphen-ethyl, ethoxysulfuron, ethozanide, F-5331, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1H -Tetrazol-1-yl] -phenyl] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro-2- (trifluoromethyl) -1H-benzimidazol-4-yl] -1 − Tyl-6- (trifluoromethyl) pyrimidine-2,4 (1H, 3H) -dione, phenopprop, phenoxaprop, phenoxaprop-P, phenoxaprop-ethyl, phenoxaprop-P-ethyl, phenoxy Sasulfone, fentolazamide, phenuron, framprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, flurothram, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-P-butyl, fluazolate , Flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloraline, fluphenacet (thiafluamide), flufenpyr, flufenpyr-ethyl, Lumetraline, flumeturum, full microrack, full microrack-pentyl, flumioxazin, flumipropine, fluomethrone, fluorodiphen, fluoroglycophene, fluoroglycophene-ethyl, flupoxam, flurpacil, flupropanate, flupirsulfuron, flupirsulfuron -Methyl-sodium, flulenol, flulenol-butyl, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurprimidol, flurtamone, fluthiaset, fluthiaset-methyl, fluthiamide, fomesafen, horamsulfuron , Forchlorphenuron, fosamine, furyloxyphen, gibber Acid, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate-isopropylammonium, H-9201, ie O- (2,4-dimethyl-6-nitrophenyl) ) -O-ethyl-isopropylphosphoramidothioate, halosafen, halosulfuron, halosulfuron-methyl, haloxyhop, haloxyhop-P, haloxyhop-ethoxyethyl, haloxyhop-P-ethoxyethyl, haloxyhop-methyl, haloxyhop- P-methyl, hexazinone, HW-02, ie, (2,4-dichlorophenoxy) acetic acid 1- (dimethoxyphosphoryl) -ethyl, imazametabenz Imazametabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-ammonium, imazetapyr, imazetapyr-ammonium, imazosulfuron, inabenfide, indanophane, indafram A, indoleflamin -Ylbutyric acid (IBA), iodosulfuron, iodosulfuron-methyl-sodium, oxynyl, ipfencarbazone, isocarbamide, isoproparin, isoproturon, isouron, isoxaben, isoxacrotol, isoxaflutol, isoxa Pyrihop, KUH-043, ie 3-({[5- (difluoromethyl) -1-methyl-3- (trifluorome Til) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dimethyl-4,5-dihydro-1,2-oxazole, carbylate, ketospiradox, lactofen, lenacyl, linuron, malein Acid hydrazide, MCPA, MCPB, MCPB-methyl, -ethyl and -sodium, mecoprop, mecoprop-sodium, mecoprop-butyl, mecoprop-P-butyl, mecoprop-P-dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop- P-potassium, mefenacet, mefluidide, mepiquat-chloride, mesosulfuron, mesosulfuron-methyl, mesotrione, metabenzthiazurone, metam, metamihop (metamif) p), metamitron, metazachlor, metazasulfuron, metazole, methiopyrsulfuron, methiozoline, methoxyphenone, methyl diimron, 1-methylcyclopropene, methyl isothiocyanate, metbenzuron, metrochlorone, metolachlor, S-metolachlor, methotram, methoxuron, metribudine, metsulfuron, metsulfuron-methyl, molinate, monalide, monocarbamide, monocarbamide dihydrogen sulfate, monolinuron, monosulfuron, monosulfuron-ester, monuron, MT128, ie 6-chloro-N- [(2E) -3-Chloroprop-2-en-1-yl] -5-methyl-N-phenylpyridazine-3 Amine, MT-5950, ie N- [3-chloro-4- (1-methylethyl) -phenyl] -2-methylpentanamide, NGGC-011, naproanilide, napropamide, naptalam, NC-310, 4- ( 2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazole, nebulon, nicosulfuron, nipyraclofen, nitralin, nitrophene, nitrophenolate sodium (mixture of isomers), nitrofluorfen, nonanoic acid, Norflurazon, olvencarb, orthosulfamlone, oryzalin, oxadiargyl, oxadiazone, oxasulfuron, oxadiclomephone, oxyfluorfen, paclobutrazol, paraquat, paraco Todichloride, pelargonic acid (nonanoic acid), pendimethalin, pendralin, penoxsulam, pentanochlor, pentoxazone, perfludon, petoxamide, phenicofam, fenmedifam, fenmedifam-ethyl, picloramen, picolinafen, pinoxapynopyropopirop Butyl, pretilachlor, primsulfuron, primsulfuron-methyl, probenazole, profluazole, profluazole, prodiamine, prifluraline, profoxydim, prohexadione, prohexadione-calcium, prohydro Jasmon, prome T, promethrin, propachlor, propanil, propoxahop, propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propizzamide, prosulfarin, prosulfocarb, prosulfuron, plinachlor, Pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotol, pyrazolinate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxifene, pyribambenz (pyribambenz), pyrivambenz-isopropyl, pyrivambenz-propyl, pyribenzoxim, pyributicarb p , Pyriminobac, Liminobac-methyl, pyrimisulfurphan, pyrithiobac, pyrithiobac-sodium, pyroxasulphone, piroxislam, benzylaminopurine, quinclolac, quinmerac, quinoclamine, quizalofop, quizalofop-ethyl, xylohop-P, xylohop- P-ethyl, quizalofop-P-tefryl, rimsulfuron, saflufenacil, secbumethone, cetoxidim, ciduron, simazine, cymetrin, SN-106279, ie methyl- (2R) -2 ({7- [2-chloro-4- (tri Fluoromethyl) phenoxy] -2-naphthyl} oxy) propanoate, sulcotrione, sulfarate (CDEC), sulfentrazone, sulfometsu , Sulfometuron-methyl, sulfosate (glyphosate-trimesium), sulfosulfuron, SYN-523, SYP-249, ie 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl-5- [2 -Chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, SYP-300, ie 1- [7-fluoro-3-oxo-4- (prop-2-yn-1-yl) -3, 4-dihydro-2H-1,4-benzoxazin-6-yl] -3-propyl-2-thioxoimidazolidine-4,5-dione, tebutam, tebuthiuron, technazen, tefryltrione, tembotrione, teploroxidim , Terbacil, terbucarb, terbuchlor, terbumeton, terbutyrazine, terbutrin (ter utryne), tenyl chlor, thiafluamide, thiafluurone, thiazopyr, thiadiamine, thidiazurone, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, thiocarbazyl, topracozyl, topracozyl Ruflon, triaziflam, triazophenamide, tribenuron, tribenuron-methyl, trichloroacetic acid (TCA), triclopyr, tridiphan, triethazine, trifloxysulfuron, trifloxysulfuron-sodium, trifluralin, triflusulfuron, triflus Ruflon-methyl, trimethuron, trinexapack, Trinexapac-ethyl, tritosulfuron, chitodef, uniconazole, uniconazole-P, vernolate, ZJ-0862, ie 3,4-dichloro-N- {2-[(4,6-dimethoxypyrimidine -2-yl) oxy] benzyl} aniline and the following compounds.

Particularly preferred co-components are
Atrazine, Mesotrione, Oryzalin, Pendimethalin, Caventrol, Lenacil, Pyributicarb, Imazaquinammonium, Quinoclamine, Propizzamid, Prodiamine, Napropamide, DCBN, Halosulfuronmethyl, Cyanazine, Flupoxam, Ethoxysulfuron, S-metolachlor, Indazifram , Isoxaben, Floraslam, Triadifram, Butamifos, Dithiopyr, Indanophan, Bethrosin, Alachlor, Oxadialgyl, Oxadichromene, Imazosulfuron, Ashram, Chlorimlone ethyl, Mecoprop P potassium salt, Mecoprop, Ethoxysulfuron, Metosulfuron methyl, Triclopyr Ruflon, imazosulfuron, pyraflufenethyl, carfentrazone Chill, cyclosulfamuron, iodosulfuron methyl sodium salt, foramsulfuron, rimsulfuron, MDBA, MCPA isopropylamine salt, benfrecetate, flucetosulfuron, flufenacet, trifloxysulfuron sodium salt, metamihop, fluazifop, full This includes but is not limited to phenasets.

  In a preferred embodiment of the invention, penetrants are additionally added to the crop protection composition to enhance activity. Suitable penetrants also include substances that enhance the utility of the compound of formula (I) in the coating, for example by spraying. Such includes, for example, mineral oil or vegetable oil. Suitable oils are all mineral or vegetable oils (optionally modified) commonly used in agrochemical compositions. Examples include sunflower oil, rapeseed oil, olive oil, castor oil, rapeseed oil, corn oil, cottonseed oil and soybean oil or esters of these oils. Rapeseed oil, sunflower oil and their methyl and ethyl esters are preferred, and rapeseed oil methyl ester is particularly preferred.

  The concentration of penetrant in the composition of the invention can vary within wide limits. In the case of formulated crop protection compositions, the concentration is generally 1% to 95% by weight, preferably 1% to 55% by weight, particularly preferably 15% to 40% by weight. In a ready-to-use composition (spraying solution), the concentration is generally from 0.1 g / L to 10 g / L, preferably from 0.5 g / L to 5 g / L.

  Application is carried out in a customary manner appropriate to the form of use.

  The treatment according to the invention with a PPO-inhibiting active compound or a VLCFA synthesis-inhibiting active compound or a combination thereof is carried out directly on the turf by conventional treatment methods, for example by spraying, spraying, spreading etc., or This is done by spraying, irrigating, and mixing the soil with turf or before transplanting the turf.

  The application rate of the PPO-inhibiting active compound, the VLCFA synthesis-inhibiting active compound, or a combination thereof in the case of spraying is in accordance with the application rate showing effective herbicidal activity. For example, in the case of oxadiargyl, it is 205 ppm to 821 ppm, preferably 410 ppm to 820 ppm.

  Although the application time is not limited, it is the time before weeds generation to the early stage of weeds generation, preferably the time until weeds are generated.

  The following biological examples illustrate the invention. In order to clearly show the growth promoting effect of the turf root, an example using transplanted turf was shown, but the present invention is not limited to this biological example.

Biological Example 1 :
Prototype: turf (Zoysia matrella)
Reagents: Phenax (registered trademark) flowable (Oxadialgyl wettable powder, containing 35.4%) was used as the composition of the present invention, and Concreed (registered trademark) granular wettable powder (flupoxam hydrated) was used as a comparative control drug. Agent, containing 50%). The crude granule wettable powder is a turf soil treatment type herbicide containing 50% flupoxam as an active ingredient, and flupoxam exhibits herbicidal activity by inhibiting cell wall biosynthesis during cell division.

試験結果：比較対照薬剤であるフルポキサム水和剤は未処理と比較して、地上部の成長を約２２％に抑制し、根部の成長を完全に抑制した。一方、本発明のオキサジアルギル水和剤は、地上部の成長を約４８％増大させ、根部の成長を約４２％増大させた。 Test method: A plastic container (length 75 cm, width 26 cm, depth 36 cm) is filled with soil (sand + clay soil mixed 1: 1), and the test compound adjusted to a predetermined concentration just before turf transplanting is sprayed. 149 days later, the turf was peeled off by 100 cm ² and the weight of the above-ground part and the root part was measured.

Test result: Flupoxam wettable powder as a comparative control agent suppressed the growth of the above-ground part to about 22% and completely suppressed the growth of the root part compared with untreated. On the other hand, the oxadiargyl wettable powder of the present invention increased the above-ground growth by about 48% and the root growth by about 42%.

Claims (1)

Spraying oxadiargyl, spraying, on handouts Therefore, either directly perform the turf, or sprayed on the soil prior to transplanting or grass has grown turf, irrigation, and performs by blending, grass To promote growth.