JP6398878B2 - COATING LINER, ITS MANUFACTURING METHOD, AND CARDBOARD SHEET WITH COATING LINER - Google Patents

Description

  The present invention relates to a coating liner, a method for producing the same, and a corrugated cardboard sheet using the coating liner. In particular, the present invention relates to a coating liner for a cosmetic corrugated cardboard that has less dust on the liner surface and is excellent in strength and flexographic printing suitability.

  In general, the liner is a thick paper made of about 2 to 9 layers, and a white liner in which the raw material mainly containing bleached pulp is used for the surface layer (the outermost layer that becomes the surface of the liner), and unbleached pulp ( The color tone of unbleached pulp is roughly divided into unbleached liners (hereinafter also referred to as tea liners) in which the raw material whose main material is tea-based color) is used for the surface layer. As the surface layer of the white liner, virgin pulp or waste paper pulp having high whiteness subjected to deinking or bleaching is usually used. Further, since measures for the surface layer alone are costly, pulp having a certain degree of whiteness may be used for the surface lower layer (layer immediately below the surface layer) to conceal the color of the intermediate layer. Waste paper pulp that has not been deinked or bleached is used for layers other than the surface layer of the liner.

  The liner is processed into a corrugated cardboard sheet in combination with the core base paper and used in various packaging boxes. The function of the corrugated cardboard box is not only to protect it from physical forces that are received during the distribution process such as storage and transportation. Absent. In the case of a corrugated cardboard box with color printing, it has a high effect of attracting people's eyes and has an excellent aspect that can strongly appeal the superiority of the contents in order to faithfully represent the contents. . In recent years, it has become common to display and sell products packed in cardboard boxes at stores, mainly in mass retailers. Therefore, there is a demand for cosmetic liners that have a high printing surface and a beautiful print surface.

  As a method of obtaining a cosmetic liner having an excellent white paper appearance and printing appearance, liners (Patent Documents 1 and 2) that provide a calm visual effect by defining the whiteness and hue of the liner surface have been proposed. Yes. Further, a liner (Patent Document 3) has been proposed in which the brightness of the surface layer is adjusted within a predetermined range and the amount of ash in the surface layer is 3 wt% or more and less than 9 wt%. In addition, a coating layer mainly composed of a pigment and an adhesive is provided on the liner surface, and the smoothness is defined so that no printing mottling occurs and the coating liner is excellent in blank paper gloss and printing gloss (Patent Document 4). Has been proposed. However, these proposals relate to liners that define whiteness, hue, and smoothness, and are not proposals relating to liners that sufficiently satisfy printing suitability such as ink drying properties and ink coloring properties in flexographic printing. There is a coating liner (Patent Document 5) that defines the relative burst strength of a coating liner that uses a corrugated cardboard and unbleached kraft pulp as a middle layer and a back layer, and has a coating layer containing calcined kaolin and talc as pigments. Although proposed, good print gloss is not obtained.

All of these coated liners have improved printing gloss and ink colorability as compared to the uncoated liner. However, in order to be able to form a beautiful and vivid printing surface, to have sufficient strength when boxed on cardboard, and to have a well-balanced required characteristic such as excellent printing workability, it is further necessary There is room for improvement.

  In recent years, in the corrugated cardboard industry, the weight of the liner has been reduced in order to make the cardboard thinner and lighter due to increased environmental awareness. In addition, when varnishing is applied as a surface treatment for cosmetic and surface protection of the coated liner surface, it has been required to improve ink drying without impairing varnish glossiness. There is room for further improvement in order to be able to sufficiently meet these requirements.

JP 2002-317395 A JP 2001-146697 A Japanese Patent Laid-Open No. 2007-100300 JP 2000-314095 A JP 2010-77552 A

  The present invention provides a coating liner having excellent ink drying properties for flexographic printing, excellent ink inking properties and varnish glossiness, strength, a corrugated cardboard sheet using the coating liner, and a method for producing the coating liner The main purpose is to do.

  As a result of intensive studies in view of the requirements of the corrugated cardboard industry, the present inventors have formed a coating layer having a specific coating amount having a specific pigment on the paper layer as the surface layer of the liner base paper, The inventors have made the following invention relating to a coating liner having a good balance of various properties required for the cosmetic cardboard liner.

(1) A coating liner comprising a coating layer containing a pigment and an adhesive on a paper layer as a surface layer of a liner base paper having at least two paper layers, wherein the coating layer comprises all pigments A coating liner comprising a synthetic amorphous silica in an amount of 3 to 30% by mass and having a coating amount of 3 to 25 g / m ² (total solid content).

(2) The liner base paper contains a pulp having a whiteness of 78% or more in an amount of 10 to 50% by weight of the total pulp in the entire paper layer of the liner base paper in the paper layer as the surface layer, and other than the paper layer as the surface layer Containing a newspaper waste paper pulp in an amount of 30 to 80% by mass and 3 to 15% by mass of unbleached kraft pulp in an amount of 3 to 15% by mass of the entire pulp of the liner base paper. The coated liner according to (1), wherein the whiteness on the front side is 70% or more.

(3) The coating liner according to item (1) or (2), wherein the number of dust particles having an area of 0.05 mm ² or more on the surface of the coating layer of the coating liner is 600 pieces / m ² or less.

(4) The coating liner according to any one of (1) to (3), wherein the specific compressive force of the coating liner is 100 N / (g / m ² ) or more.

(5) A flexographic printing liner using the coating liner described in any one of (1) to (4) above.

(6) A corrugated cardboard sheet provided with the coating liner described in any one of the above items (1) to (5).

(7) A method for producing the coated liner according to any one of (1) to (4), wherein the paper layer is a surface layer of the liner base paper having at least two paper layers. A coating layer having a coating amount of 3 to 25 g / m ² (total solid content) is coated with a coating liquid containing a pigment and an adhesive in which 3 to 30% by mass of the total pigment is synthetic amorphous silica. Forming a coating liner.

  The coating liner of the present invention is a multi-layer paper coating liner having excellent ink drying properties for flexographic printing, excellent ink inking properties and varnish glossiness, and particularly as a coating liner for cosmetic cardboard having strength. Useful.

The coating liner in the present invention is a coating layer containing a pigment containing synthetic amorphous silica (silicon dioxide) and an adhesive on a paper layer which is a surface layer of a liner base paper having at least two paper layers. It has.
The surface layer having the coating layer of the coating liner forms the surface of the corrugated cardboard sheet, and the back layer forms the back surface bonded to the core of the corrugated cardboard sheet. Between the surface layer and the back layer, a front layer and a bottom layer formed in contact with the surface layer, a single layer formed between the front layer and the back layer, or a plurality of middle layers may be provided.

  The coating liner of the present invention preferably has a whiteness on the front side of the coating layer of 70% or more. In order to make the whiteness of the front side of the coating liner 70% or more, it is preferable that the paper layer as the surface layer of the liner base paper is made of pulp having a whiteness of 78% or more. As the pulp constituting the surface layer, white-based bleached pulp and waste paper pulp having high whiteness are preferable. Waste paper pulp includes, for example, waste paper (hereinafter also referred to as Kent waste paper) collected from printing coated paper generated from bookbinding, printing factories, magazine waste paper, flyer waste paper, waste paper waste, office waste paper, information paper What uses the pulp obtained by deinking waste paper etc. as a main raw material is preferable.

  In addition, from the viewpoint of resource protection, it is preferable to add a lot of waste paper pulp to the surface layer of the liner base paper, and the softwood bleached kraft pulp (hereinafter also referred to as NBKP) has a blending amount sufficient to express the target strength. Is preferred. As for the compounding quantity of used paper pulp, about 20-60 mass% in surface layer pulp is preferable. If the whiteness is not lowered, pulp other than the above may be appropriately blended.

  The beating degree (CSF) of the pulp constituting the surface layer of the liner base paper is not particularly limited, but is preferably 250 to 500 ml. By setting the beating degree to 250 ml or more, it is possible to maintain good dewaterability in the paper making process. On the other hand, when the amount is 500 ml or less, the strength is improved, the smoothness is also improved, and the printability can be enhanced.

  As the pulp constituting the surface layer, if the whiteness on the coating layer side of the coating liner does not become less than 70%, a pulp other than the above pulp may be appropriately blended. Other pulp types include, for example, pulp obtained by deinking used paper such as corrugated paper, used paperboard, and used paper and / or hardwood bleached kraft pulp (hereinafter also referred to as LBKP).

The content ratio of the pulp having a whiteness of 78% or more forming the surface layer is preferably 10 to 50% by mass, more preferably 13 to 35% by mass, based on the total pulp in the entire paper layer of the liner base paper. -30 mass% is still more preferable. If it is less than 10% by mass, the whiteness is low, and if it exceeds 50% by mass, sufficient strength may not be obtained.

There is no restriction | limiting in particular in the kind of pulp which forms paper layers other than the paper layer used as surface layer. For example, wood pulp unbleached, bleached chemical pulp, mechanical pulp, non-wood pulp, and used paper such as Kent waste paper, magazine waste paper, flyer waste paper, newspaper waste paper, office waste paper, information paper waste paper, paperboard waste paper, paper container waste paper, etc. Examples include pulp obtained by deinking, manila hemp, and corrugated used paper. Among these, from the viewpoint of achieving both strength and surface appearance (surface dust), it is preferable to contain old newspaper and softwood unbleached kraft pulp (hereinafter also referred to as NUKP).

If there is a lot of dust on the surface of the coating liner, not only the appearance of the blank paper will be inferior, but also depending on the printed design, it may become a printing defect. Is preferably an area 0.05 m ² or more dust is 600 / ^{m 2} or less, more preferably at 500 / ^{m 2} or less, and even more preferably 400 / ^{m 2} or less. Therefore, it is preferable to use old newspaper as the pulp constituting the lower layer, middle layer and back layer other than the surface layer. The content ratio of used newspaper is preferably 30 to 80% by mass, more preferably 35 to 75% by mass, and more preferably 40 to 70% by mass, based on the total pulp in the entire paper layer of the liner base paper. preferable. If it is less than 30% by mass, the number of dust increases, and if it exceeds 80% by mass, the strength decreases.

For the strength of the coating liner, it is preferable to use corrugated used paper pulp and / or NUKP as the pulp constituting the lower layer, middle layer and back layer other than the surface layer. The content ratio of the corrugated waste paper pulp and / or NUKP is preferably 3 to 15% by mass, more preferably 4 to 12% by mass, and more preferably 5 to 9% by mass based on the total pulp in the entire paper layer of the liner base paper. Is more preferable. If it is less than 3% by mass, sufficient specific burst strength and specific compressive strength may not be obtained, and if it exceeds 15% by mass, the whiteness and smoothness are lowered and the surface dust increases.
As for the strength of the coating liner, the specific burst strength is preferably 2.95 kPa / (g / m ² ) or more, and the specific compressive strength is preferably 100 N / (g / m ² ) or more. Use of NUKP is more preferable because surface dust can be reduced.

The beating degree (CSF) of the pulp used for the surface layer and each layer other than the surface layer is not particularly limited, but is preferably in the range of 250 to 500 ml. By setting the beating degree to 250 ml or more, it is possible to maintain good dewaterability in the paper making process. On the other hand, by making it 500 ml or less, the strength is improved and the surface dust can be reduced. In order to reduce the surface dust, the beating degree is more preferably 400 ml or less, and further preferably 350 ml or less.

  Internal chemicals can be used as needed for each paper layer of the liner base paper. For example, sizing agents such as sulfate bands and rosin, paper strength enhancers such as polyamide and starch, drainage retention improvers, and polyamide polyamine epichlorides. Water resistant agents such as phosphorus, dyes and the like are used. In particular, a sizing agent should be added to the surface layer on which the coating layer is formed from the viewpoint of suppressing the penetration of the coating liquid, and to the back layer from the viewpoint of suppressing the penetration of the glue during the bonding of the cardboard. Is preferred.

  The liner base paper in the coated liner of the present invention is a multi-layer structure formed by combining two or more paper layers made of pulp as a main raw material. It can be manufactured by a paper machine combined with a net former. It is also possible to increase the strength between the layers by spraying or coating an adhesive such as starch between the layers when the sheets are combined.

  The coating liner of the present invention includes a coating layer containing a pigment and an adhesive on a paper layer that is a surface layer of a liner base paper. Synthetic amorphous silica (silicon dioxide) is contained as a pigment for forming the coating layer, and the content ratio in the coating layer is 3 to 30% by mass of the total pigment in the coating layer. 5-20 mass% is preferable and 8-15 mass% is still more preferable.

By setting the content ratio of the synthetic amorphous silica (silicon dioxide) to 3% by mass or more, the ink drying property can be improved. On the other hand, varnish gloss can be improved by setting it as 30 mass% or less.

As the synthetic amorphous silica (silicon dioxide), wet silica (hydrous silicic acid) is preferably used. The secondary particle diameter of the wet silica is preferably about 1 to 20 μm, more preferably about 2 to 15 μm, and still more preferably 3 to 10 μm. When it is less than 1 μm, the whiteness is lowered and the ink drying property is deteriorated. If it exceeds 20 μm, the whiteness improvement effect is obtained, but the white paper gloss, printing gloss, varnish gloss, and ink inking properties are reduced.

The coating amount is 3 to 25 g / m ² (total solid content). The lower limit of the coating amount is preferably 5 g / m ² or more, more preferably 8 g / m ² or more. As an upper limit, Preferably it is 18 g / m < ² > or less, More preferably, it is 16 g / m < ² > or less. If the coating amount is less than 3 g / m ² , ink inking property and varnish glossiness are lowered, and desired cosmetic properties may not be imparted. When it exceeds 25 g / m ² , the ink drying property is deteriorated and the printing workability is deteriorated.

The coating layer in the coating liner of the present invention is not particularly limited as long as the coating amount is 3 to 25 g / m ² (total solid content), and may be a single layer structure or a multilayer structure. . In a multilayer structure of two or more layers, the composition of the coating liquid forming each layer may be the same or different. In other words, two or more coating layers may be formed using one kind of coating liquid, or two or more coating layers may be formed by using two or more coating liquids for each layer. .

  The coating liner of the present invention contains a specific pigment in the coating layer, but other pigments can be used as long as the desired effects of the present invention are not impaired. Specifically, pigments commonly used in the papermaking field, such as kaolin, talc, aluminum hydroxide, heavy calcium carbonate, light calcium carbonate, barium sulfate, zinc oxide, satin white, calcium sulfate, titanium oxide, etc. Can be mentioned. Among these, it is preferable to use kaolin from the viewpoint of exhibiting a good varnish gloss and improving the ink inking property. The kaolin content is preferably 50% by mass or more of the total pigment in the coating layer. By setting it to 50% by mass or more, good varnish gloss and ink depositability can be improved. The shape of the kaolin is not particularly limited, and fine particles, primary kaolin, secondary kaolin, delaminated kaolin, high aspect ratio kaolin, etc. can be used, but the fine kaolin has excellent gloss and smoothness, and the ink Excellent wearability and varnish gloss.

In addition, it is preferable not to use organic pigments, such as a plastic pigment, since the flexo ink drying property is bad.

  The coating layer in the coating liner of the present invention contains synthetic amorphous silica (silicon dioxide) as a pigment, and is coated on one side of the liner base paper and then dried. Can be formed. The adhesive in the coating liquid is not particularly limited, and for example, the following known adhesives used in the general coated paper manufacturing field are appropriately used. Conjugated diene copolymer latex such as styrene-butadiene copolymer latex, methyl methacrylate-butadiene copolymer latex, styrene-methyl methacrylate-butadiene copolymer latex. An acrylic polymer latex such as a polymer or copolymer latex of an acrylate ester and / or a methacrylate ester. Vinyl polymer latex such as ethylene-vinyl acetate polymer latex. Alternatively, a water-dispersible adhesive such as a polymer or copolymer latex obtained by modifying these various polymer latexes with a functional group-containing monomer such as a carboxyl group. Synthetic resin adhesives such as polyvinyl alcohol and olefin-maleic anhydride resin. Starches such as oxidized starch, positive starch, esterified starch and dextrin. One or more of these water-dispersible and / or water-soluble adhesives can be appropriately selected and used. As for content of an adhesive agent, 8-50 mass parts is preferable with respect to 100 mass parts of all the pigments in a coating layer, More preferably, it is 10-40 mass parts. By setting the content of the adhesive to 8 parts by mass or more, the strength of the coating layer can be increased. On the other hand, by setting it as 50 mass parts or less, the ratio of the pigment in a coating layer can be enlarged, and flexographic ink drying property and smoothness can be improved.

  It is preferable to contain a water retention agent in the coating liquid for forming the coating layer. Thereby, physical properties, such as a viscosity of a coating liquid, can be adjusted and coating suitability can be improved. Examples of water-retaining agents include sodium salt of carboxymethyl cellulose, which is generally called CMC in the papermaking field, hydroxyethyl cellulose, polyvalent carboxylic acid acrylic copolymer called synthetic water-retaining agent, and a copolymer of methacrylic acid and acrylic acid ester. A polymer etc. are mentioned.

  Additives such as mold release agents, anti-slip agents, and dyes may be included in the coating liquid as long as the effects on the finish of ink color development and printing uniformity are not impaired.

The coating system of the coating layer in the coating liner of the present invention is not particularly limited . Use the air knife coating method, bar coating method, or curtain coating method from the viewpoint of suppressing blanking on the surface of the liner paper and improving the white paper feel, reducing air permeability and improving ink drying properties Is preferred. As a result, it is possible to exhibit flexographic printing suitability, in particular, excellent ink drying properties and ink coloring properties and printing uniformity for aqueous flexographic inks.

The curtain coating method is a method in which the coating liquid is allowed to flow down and fall freely and is applied to the support in a non-contact manner. A known method such as a slide curtain method, a couple curtain method, or a twin curtain method can be adopted. There is no particular limitation. The blade coating method is not limited to a coating method using a blade represented by a bevel type or a vent type, but includes a rod blade method, a bill blade method, and the like.

The basis weight of the liner base paper in the coated liner of the present invention is preferably in the range of 100 to 220 g / m ² . When a liner base paper having a basis weight of 100 to 220 g / m ² and having a thin paper thickness is used, the cardboard sheet can be reduced in weight, but the strength is lowered. However, in the present invention, since corrugated cardboard pulp and / or NUKP is used, it can sufficiently withstand impact and compression during the transportation of goods, and can be used as a front liner for corrugated cardboard sheets for exterior use. Further, by providing a specific coating layer on the surface layer of the liner base paper, it is possible to simultaneously improve ink fillability, ink drying properties, and varnish gloss. Moreover, as a basic weight of a coating liner, 120-230 g / m < ² > is preferable and 130-220 g / m < ² > is more preferable.

  The coating liner of the present invention is a calender combined with a metal roll, a super calender using a cotton roll as an elastic roll, and a soft nip calender using a synthetic resin roll as an elastic roll in order to further improve the coating surface and printability. Smoothing processing can be performed by a device such as the above. The calendering process extrudes corrugated used paper, sticky material in NUKP, pitch, etc., and it may become dust on the surface of the coating liner and may reduce the appearance of blank paper. In the present invention, used newspaper paper is blended into paper layers other than the surface layer. This can suppress the generation of dust. The calendering linear pressure is preferably 100 to 500 kN / m as long as the number of dust on the surface of the coating liner can be suppressed. 130-400 kN / m is more preferable, and 150-360 kN / m is still more preferable. By setting the calendar linear pressure to 100 kN / m or more, the smoothness of the coating liner surface is improved, and the ink inking property and varnish gloss are improved. By setting it to 500 kN / m or less, the number of dust on the surface of the coating liner can be suppressed. The soft nip calender can set the heat-resistant temperature of the surface of the synthetic resin roll higher than that of the cotton roll, so it can be processed at high temperatures, and compared with the super calender when the same smoothness is targeted. This is a preferable mode because the treatment linear pressure can be set low.

  Corrugated cardboard printing methods include cases where the liner paper is printed before the cardboard is formed (preprint method) and cases where printing is performed after the cardboard is formed (direct print method). The coating liner of the present invention is applicable in any case. Since both flexographic ink drying properties and ink color development can be achieved, even when using the direct printing method, which is bonded to the core paper and then printed, the ink deposits on the top and bottom of the step where the core paper contacts the liner Can be made uniform, and excellent cosmetic properties can be exhibited.

  There is no restriction | limiting in particular as a flexo ink at the time of printing on the coating liner of this invention, Alcohol type | mold, a cosolvent type | mold, an aqueous | water-based type | mold, a UV curable type, etc. are mention | raise | lifted. Among these flexographic inks, the water-based type is excellent in terms of safety, workability, and economy, and is an embodiment in which the effects of the present invention appear most remarkably.

  In addition, the flexographic printing press used is classified into three types, a stack type, a line type, and a central impression type, depending on how the printing units are arranged, but any type can be used. The pre-print method can be printed with three types, but the direct print method is a line-type print.

  The coated liner of the present invention can be used as a liner disposed on at least one outermost surface of the corrugated cardboard sheet, thereby providing the corrugated cardboard sheet of the present invention. As a corrugated cardboard sheet, a single-sided cardboard sheet in which a liner is bonded only to one side of the core, a double-sided cardboard sheet in which a liner is bonded to both sides of the core, and a plurality of core / liner laminates provided in a plurality of stages There is a corrugated cardboard sheet. The coated liner of the present invention is applicable to any cardboard sheet.

There is no restriction | limiting in particular as a core of the corrugated member which comprises a corrugated board sheet with the coating liner of this invention. Since the coated liner of the present invention is thinner than the conventional one, it is preferable to use a reinforced core having a higher compressive strength and tensile strength than those used for general corrugated cardboard sheets. Moreover, although a reason is not understood well, there exists a tendency for a wash board to reduce by using a reinforced center core. As the raw material pulp, semi-chemical pulp (SCP), chemiground pulp (CGP), corrugated waste paper pulp, magazine waste paper pulp, unbleached kraft pulp, kraft pulp, synthetic fiber and the like can be used . Among these, from the viewpoint of resource protection, it is preferable to use a lot of waste paper pulp such as corrugated waste paper pulp and magazine waste paper pulp. The core may be a laminated paper, and may further be a laminated paper having a synthetic resin adhesive layer between layers.

  As a method for producing a corrugated cardboard sheet in the present invention, a conventionally known corrugated cardboard producing method can be applied as it is. For example, it can be manufactured through a corrugator treatment in which the core and the liner are bonded via an adhesive. Examples of the adhesive include starch paste and synthetic resin. Examples of the synthetic resin include polyethylene, polypropylene, polyamide, polyester, ethylene-unsaturated carboxylic acid copolymer, styrene-butadiene copolymer, butadiene-acrylonitrile copolymer, styrene-butadiene-acrylonitrile copolymer, polyacetic acid. Examples thereof include vinyl, ethylene-vinyl acetate copolymer, polyacrylic acid ester copolymer, and styrene-acrylic acid ester copolymer.

  Generally, (1) the core is formed into a corrugated shape, and an adhesive such as an emulsion such as a synthetic resin or starch paste is applied to the core, and then bonded to a liner. The method to adhere | attach is mentioned. Other methods include the following methods. (2) A method in which an adhesive layer is formed on the surface of the core or liner by extrusion lamination, synthetic resin emulsion coating, or the like, and then the layers are laminated, pressed and heated to be bonded. (3) A method in which a synthetic resin film is interposed between the core / liner, and this is pressed and heated to be bonded. In the method (3), a pre-molded synthetic resin film can be fed out and supplied between the core and the liner, or the synthetic resin film can be supplied between the core and the liner while being melt-extruded. You can also

  In each of the above methods, a single-sided cardboard sheet is manufactured by performing the corrugator process once, and a double-sided cardboard sheet or a multi-stage cardboard sheet is manufactured by repeatedly performing a plurality of times. The double-sided corrugated cardboard sheet is, for example, a single facer (SF) in which a core and a liner are bonded with a heat and pressure roll to form a single-sided cardboard sheet, and a liner is further provided on the core side of the single-sided cardboard sheet obtained by SF. It can be manufactured using a corrugator having a double facer (DF) that is laminated and pressed on a hot plate while being pressed. The heating and pressing conditions are not particularly limited. For example, SF heating temperature 120 to 200 ° C., linear pressure 20 to 40 kN / m, pressurization time 0.01 to 0.20 seconds, DF heating temperature 120 to 200 ° C., linear pressure 0.1 to 1.0 kN / m m, pressurization time is preferably 2 to 7 seconds.

  There are no particular restrictions on the type of flute when printing corrugated cardboard sheets using the direct printing method, as long as it can be used with a printing press. B flute and E flute are strong against flat pressure and pressure parallel to the step direction. Therefore, it is preferable because it has excellent printability.

EXAMPLES Hereinafter, although an Example demonstrates this invention in more detail, this invention is not limited by these. Unless otherwise specified, “parts” and “%” represent “parts by mass” and “mass%”, respectively.
Example 17 is a reference example.

Example 1
(Preparation of liner paper)
For the surface layer, pulp in which NBKP (whiteness 85%) adjusted to 420 ml Canadian Standard Freeness (CSF) and upper white waste paper pulp (whiteness 82%) adjusted to CSF 330 ml were blended at a mass ratio of 60:40 was used. For 100 parts by mass of this pulp, 1.0 part of a sizing agent (trade name: Size Pine 836, manufactured by Arakawa Chemical Industry Co., Ltd.), 4.0 parts of sulfuric acid band, 1 paper strength agent (trade name: PT-1001, Arakawa) A surface layer paper stock was prepared by adding 0.05 parts of Chemical Industries Co., Ltd. and 2.5 parts of paper strength agent 2 (trade name: OM-3, Arakawa Chemical Industries, Ltd.).
For the front and lower layers, 100% pulp of medium white waste paper pulp (whiteness 72%) adjusted to 270 ml of CSF was used. To 100 parts by mass of this pulp, 1.0 part of sulfuric acid band, 0.05 part of paper strength agent (trade name: PT-1001, supra), 2 parts of paper strength agent (trade name: OM-3, supra) ) 5.0 parts was added to prepare a front and lower layer paper stock.
For the middle layer, used was a waste paper pulp (whiteness 50%) adjusted to 350 ml CSF and NUKP (whiteness 27%) adjusted to 200 ml CSF in a mass ratio of 90:10. For 100 parts by mass of this pulp, 0.4 part of sizing agent (trade name: size pine 836, supra), 2.0 parts of sulfuric acid band, paper strength agent 1 (trade name: PT-1001, supra) 0 .15 parts, paper strength agent 2 (trade name: OM-3, supra) 5.0 parts was added to prepare a middle layer paper stock.
For the back layer, used was a waste paper pulp adjusted to 350 ml of CSF and NUKP adjusted to 200 ml of CSF at a mass ratio of 90:10. For 100 parts by mass of this pulp, 1.0 part of sizing agent (trade name: size pine 836, supra), 2.0 parts of sulfuric acid band, paper strength agent 1 (trade name: PT-1001, supra) 0 .15 parts, paper strength agent 2 (trade name: OM-3, supra) 2.0 parts was added to prepare a back layer paper stock.
The combined paper making four layers These paper stock, basis weight 21.6 g / ^{m 2} of the surface layer, basis weight 29.2 g / ^{m 2} of Table lower, basis weight 38.1 g / ^{m 2} of middle layer of the backing layer A liner base paper having a basis weight of 38.1 g / m ² and a base paper size of 127 g / m ² was obtained.

(Preparation of coating solution for coating layer)
As a pigment, a pigment slurry composed of 96 parts of fine kaolin (trade name: Amazon, manufactured by CADAM) and 4 parts of synthetic amorphous silica (trade name: Mizuka Seal P603, manufactured by Mizusawa Chemical Co., Ltd.) was prepared. A composition comprising 15 parts of styrene-butadiene copolymer latex (trade name: B1735, manufactured by Asahi Kasei Chemicals Corporation) (all in terms of solid content) is mixed as an adhesive in the pigment slurry, and an antifoaming agent and a dye are further added as auxiliary agents. Was added to obtain a coating solution for a coating layer having a solid content concentration of 63%.

(Preparation of coating liner)
The above coating layer coating solution is coated on the surface layer of the liner base paper using a bar coater and coated so as to have a coating amount of 13 g / m ² (total solids) and dried. A layer was formed. Thereafter, using a chilled calendar, a calendar treatment was performed at a calender linear pressure of 150 kN / m to obtain a coating liner having a weight of 140 g / m ² .

Example 2
(Preparation of coating solution for coating layer)
Example 1 except that 90 parts of fine kaolin (trade name: Amazon, manufactured by CADAM) and 10 parts of synthetic amorphous silica (trade name: Mizukaseal P603, manufactured by Mizusawa Chemical) were prepared as pigments. In the same manner as above, a coating layer coating solution was obtained. Thereafter, the same coating and calendering treatment as in Example 1 was applied to the liner base paper produced in the same manner as in Example 1 with this coating solution to obtain a coating liner having a rice basis weight of 140 g / m ² .

Example 3
(Preparation of coating solution for coating layer)
Example 1 except that 75 parts of fine kaolin (trade name: Amazon, manufactured by CADAM) and 25 parts of synthetic amorphous silica (trade name: Mizukaseal P603, manufactured by Mizusawa Chemical) were prepared as pigments. In the same manner as above, a coating layer coating solution was obtained. Thereafter, the same coating and calendering treatment as in Example 1 was applied to the liner base paper produced in the same manner as in Example 1 with this coating solution to obtain a coating liner having a rice basis weight of 140 g / m ² .

Example 4
(Preparation of liner paper)
The basis weight of the surface layer and 23.0 g / ^{m 2,} the basis weight of the table lower and 31.0 g / ^{m 2,} the basis weight of the intermediate layer and 40.5 g / ^{m 2,} the basis weight of the backing layer except that the 40.5 g / ^{m 2} in the same manner as in example 1 to obtain a liner base paper sheet rice basis 135.0 g / ^{m 2.} Thereafter, a coating layer solution was prepared in the same manner as in Example 2, and the coating and calendering were performed in the same manner as in Example 1 except that the coating amount was 5 g / m ² (total solid content). A coating liner of 140 g / m ² was obtained.

Example 5
(Preparation of liner paper)
The basis weight of the surface layer as 20.7 g / ^{m 2,} the basis weight of the table lower and 28.1 g / ^{m 2,} the basis weight of the intermediate layer and 36.6 g / ^{m 2,} the basis weight of the backing layer except that the 36.6 g / ^{m 2} in the same manner as in example 1 to obtain a liner base paper sheet rice basis 122.0 g / ^{m 2.} Thereafter, a coating layer solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 except that the coating amount was 18 g / m ² (total solid content). A coating liner of 140 g / m ² was obtained.

Example 6
(Preparation of liner paper)
The basis weight of the surface layer and 19.9 g / ^{m 2,} the basis weight of the table lower and 26.9 g / ^{m 2,} the basis weight of the intermediate layer and 35.1 g / ^{m 2,} the basis weight of the backing layer except that the 35.1 g / ^{m 2} in the same manner as in example 1 to obtain a liner base paper sheet rice basis 117.0 g / ^{m 2.} Thereafter, a coating layer solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 except that the coating amount was 23 g / m ² (total solid content). A coating liner of 140 g / m ² was obtained.

Example 7
(Preparation of liner paper)
The base paper rice paper weight 117 was used in the same manner as in Example 1 except that the middle layer waste paper pulp and NUKP were blended at a mass ratio of 80:20, and the back layer newspaper waste paper pulp and NUKP were blended at a mass ratio of 75:25. A liner base paper of 0.0 g / m ² was obtained. Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a basis weight of 140 g / m ² .

Example 8
(Preparation of liner paper)
Prepare a paper stock containing 12.7 g / m ² on the surface layer and 19.0 g / m ^{2 on the} bottom layer and blending the middle layer waste paper pulp and NUKP in a mass ratio of 96: 4. and, the basis weight and 50.8 g / ^{m 2,} the waste newspaper pulp and NUKP backing layer 96: except that the stock was blended at a weight ratio of 4 was prepared and the basis weight and 44.5 g / ^{m 2} In the same manner as in Example 1, a liner base paper having a base paper basis weight of 127.0 g / m ² was obtained. Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a basis weight of 140 g / m ² .

Example 9
(Preparation of liner paper)
The basis weight of the surface layer and 29.2 g / ^{m 2,} except that the basis weight of the intermediate layer was 30.5 g / ^{m 2} in the same manner as in Example 1, the liner material paper sheet rice basis 127.0 g / ^{m 2} Got. Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a basis weight of 140 g / m ² .

Example 10
(Preparation of liner paper)
The basis weight of the surface layer and 44.5 g / ^{m 2,} the basis weight of the table lower and 19.1 g / ^{m 2,} the stock pulp of the middle layer and 31.7 g / ^{m 2,} the stock of the backing layer A liner base paper having a base paper of 127.0 g / m ² was obtained in the same manner as in Example 1 except that the pulp was 31.7 g / m ² . Thereafter, a coating liquid for coating was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a rice basis weight of 140 g / m ² .

Example 11
(Preparation of liner paper)
On the surface layer, a stock was prepared by blending NBKP, upper white waste paper pulp, and spindle-shaped light calcium carbonate (trade name: TP121MC, manufactured by Okutama Kogyo Co., Ltd.) at a mass ratio of 55:35:10, and the rice paper weight was 21.6 g / except that the m ² in the same manner as in example 1 to obtain a liner base paper sheet rice basis 127.0 g / ^{m 2.} Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a basis weight of 140 g / m ² .

Example 12
(Preparation of coating solution for coating layer)
As pigments, fine kaolin (trade name: Amazon, manufactured by CADAM) 70 parts, spindle-shaped light calcium carbonate (trade name: TP-121MC, manufactured by Okutama Kogyo Co., Ltd.), synthetic amorphous silica (trade name: Mizukaseal P603) (Manufactured by Mizusawa Chemical Co., Ltd.) A coating liquid for coating layer was prepared in the same manner as in Example 1 except that 10 parts of pigment was prepared and used. A liner base paper of 127 g / m ² of base paper prepared in the same manner as in Example 1 was coated and calendered in the same manner as in Example 1 with the coating layer coating solution, and 140 g / m ^{2 of} rice basis weight. Coating liner was obtained.

Example 13
(Preparation of coating solution for coating layer)
As pigments, fine kaolin (trade name: Amazon, manufactured by CADAM) 50 parts, spindle-shaped light calcium carbonate (trade name: TP-121MC, manufactured by Okutama Kogyo Co., Ltd.), synthetic amorphous silica (trade name: Mizukaseal P603) (Manufactured by Mizusawa Chemical Co., Ltd.) A coating liquid for coating layer was prepared in the same manner as in Example 1 except that 10 parts of pigment was prepared and used. A liner base paper of 127 g / m ² of base paper prepared in the same manner as in Example 1 was coated and calendered in the same manner as in Example 1 with the coating layer coating solution, and 140 g / m ^{2 of} rice basis weight. Coating liner was obtained.

Example 14
(Preparation of liner paper)
The basis weight of the surface layer and 33.5 g / ^{m 2,} the basis weight of the table lower and 45.3 g / ^{m 2,} the basis weight of the intermediate layer and 59.1 g / ^{m 2,} the basis weight of the backing layer except that the 59.1 g / ^{m 2} was obtained a liner base paper of example 1 in the same manner as the base paper rice basis 197.0 g / ^{m 2.} Thereafter, a coating liquid for coating was prepared in the same manner as in Example 2, and this liner base paper was coated and calendered in the same manner as in Example 1 to obtain a coating liner having a basis weight of 210 g / m ² .

Example 15
(Preparation of liner paper)
The weight of the surface layer is 31.8 g / m ² , the weight of the lower layer is 43.0 g / m ² , the weight of the middle layer is 56.1 g / m ^2, and the weight of the back layer is 56.1 g / m ^2. as 56.1 g / ^{m 2,} except that the base paper rice basis was 187.0g / ^{m 2} was obtained in the same manner as the liner material paper as in example 1. Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and the coating amount was 23 g / m ² (total solid content), and the coating and calendering were applied in the same manner as in Example 1 to 210 g / m 2 A coating liner of ² was obtained.

Example 16
(Preparation of liner paper)
A liner base paper having a base weight of 197.0 g / m ² was used in the same manner as in Example 14 except that the surface area of the base layer was 45.3 g / m ² and the middle layer was 47.3 g / m ^2. Obtained. Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a basis weight of 210 g / m ² .

Example 17
(Preparation of liner paper)
127.0 g / sq.m. Of base paper in the same manner as in Example 9 except that the middle layer paper pulp was 100% new corrugated waste paper (whiteness 26%) and the back layer paper pulp was 100% new corrugated waste paper. An m ² liner base paper was obtained. Thereafter, a coating layer coating solution was prepared in the same manner as in Example 2, and coating and calender linear pressure treatment of 40 kN / cm were performed in the same manner as in Example 1 to obtain a coating liner having a rice basis weight of 140 g / m ^2. It was.

Comparative Example 1
(Preparation of coating solution for coating layer)
As a pigment, a coating solution for a coating layer was prepared by using 100 parts of fine kaolin (trade name: Amazon, manufactured by CADAM) as a pigment. A coating liner of ² was obtained.

Comparative Example 2
(Preparation of coating solution for coating layer)
As a pigment, 65 parts of fine kaolin (trade name: Amazon, manufactured by CADAM) and 35 parts of synthetic amorphous silica (trade name: Mizukaseal P603, manufactured by Mizusawa Chemical Co., Ltd.) are used. Except that the liquid was prepared and used, coating and calendering were performed in the same manner as in Example 1 to obtain a coating liner having a basis weight of 140 g / m ² .

Comparative Example 3
(Preparation of liner paper)
The basis weight of the surface layer and 18.7 g / ^{m 2,} the basis weight of the table lower and 25.3 g / ^{m 2,} the basis weight of the intermediate layer and 33.0 g / ^{m 2,} the basis weight of the backing layer A liner base paper having a base paper basis weight of 110.0 g / m ² was obtained in the same manner as in Example 1 except that the amount was 33.0 g / m ² . Thereafter, similarly to prepare a coating for coating solution as in Example 2, except that the coating amount was 30 g / m ² is the same manner as in Example 1 coating, subjected to a calendering treatment basis weight 140 g / m ² Coating liner was obtained.

Comparative Example 4
(Preparation of liner paper)
The basis weight of the surface layer and 23.5 g / ^{m 2,} the basis weight of the table lower and 31.7 g / ^{m 2,} the basis weight of the intermediate layer and 41.4 g / ^{m 2,} the basis weight of the backing layer 41.4 g / ^{m 2} and with other than the got liner base paper of example 1 and 138.0 g / ^{m 2} base paper rice basis in the same manner. Thereafter, a coating liquid for the coating layer was prepared in the same manner as in Example 2, and the coating and calendering were performed in the same manner as in Example 1 except that the coating amount was 2 g / m ^2. A coating liner of ² was obtained.

Comparative Example 5
(Preparation of coating solution for coating layer)
A coating liquid for a coating layer was prepared using a pigment in a proportion of 100 parts of fine kaolin (trade name: Amazon, manufactured by CADAM) as a pigment.
Using this coating layer coating solution, a liner paper produced in the same manner as in Example 14 was coated and calendered in the same manner as in Example 1 to obtain a coated liner having a basis weight of 210 g / m ² . .

The blank paper quality and flexographic printing quality of the coated liners produced in Examples and Comparative Examples were evaluated according to the following evaluation criteria. The results are shown in Table 1.

(Whiteness)
The whiteness on the coating layer side of the coating liner was measured using a spectral whiteness meter (SC-10WT, manufactured by Suga Test Instruments Co., Ltd.) according to JIS P 8148: 2001.

(White paper gloss)
The white paper gloss on the coating layer side of the coating liner was measured using a gloss meter (GM-26PRO, manufactured by Murakami Color Research Laboratory) according to JIS P 8142: 2005.

(PPS smoothness)
The PPS smoothness meter (model 165, manufactured by L & W) is used to apply PPS smoothness on the coating layer side of the coating liner side of the coating liner according to JIS P8151: 2004, and pressurize to 2 MPa using PPS. Measured as smoothness.

(Specific burst strength)
The coating liner was measured according to JIS P 8131: 1995.

(Specific compression strength)
The coating liner was measured according to JIS P 8126: 2005.

(Chile quantity)
The coating layer side of the coating liner was measured at a set threshold value of 27 using a paper dust measuring device (model DF-2000, manufactured by Oji Scientific Instruments).

(Flexo printing quality)
Water-based flexographic ink (manufactured by Sakata Ink Co., Ltd.) with an anilox roll engraved at 550 lines / inch using a direct flexo printing machine DYNA FLEX160 (manufactured by Bobst Co., Ltd.) with a paste sheet having a size of 500 × 1350 mm: red → ink → Printing was performed in the order of indigo → yellow → varnish.

(Ink drying)
Printing was performed at a printing speed of 4000 sheets / hour. Immediately after printing, the printing surface and the back liner surface were rubbed, and the degree of ink adhesion on the back liner surface was visually evaluated.
○: There is no ink adhesion and ink drying is good.
Δ: There is almost no ink adhesion and the ink drying property is slightly poor, but there is no practical problem.
X: There is ink adhesion, the ink drying property is poor, and this is a practical problem.

(Ink fillability)
The uneven coloring of the heavy color portion was evaluated according to the following criteria.
○: There is no uneven unevenness of printing, and the print finish is good.
Δ: Almost no unevenness of the flesh and slightly poor print finish, but no problem in practical use.
X: Ink unevenness is inferior, printing finish is poor, and this is a practical problem.

(Varnish gloss)
The black portion was measured for 60 ° gloss using a 60 ° gloss meter (TC-108DPA, manufactured by Tokyo Denshoku Technology Center Co., Ltd.).

  As shown in Table 1, the coated liner of the present invention has less surface dust, good white paper appearance, high strength, and excellent flexographic ink drying, ink color development, and varnish gloss. Such coating liners can sufficiently meet the requirements for reducing the weight of coating liners in the corrugated board industry, improving the cosmetic properties of the coating liner surface, and drying ink on the varnished surface for protecting the liner surface. It is.

Claims (6)

A coating liner comprising a coating layer containing a pigment and an adhesive on a paper layer serving as a surface layer of a liner base paper having at least two paper layers, wherein the coating layer comprises 3 of all pigments containing 30 wt% of the amount of synthetic amorphous silica, the coating amount 3 to 25 g / m 2 ^(total solids) der is, the liner base paper, liner base paper on the paper layer as a surface layer whole sheet 30 to 80 mass of the total pulp in the entire paper layer of the liner base paper is contained in the paper layer other than the paper layer as the surface layer, containing 10 to 50 mass% of the total pulp in the layer and having a whiteness of 78% or more. percent recycled newspaper pulp in the amount of, and contains 3 to 15 wt% of the amount of softwood unbleached kraft pulp, and characterized der Rukoto front whiteness of at least 70% with the coating layer Coating liner to do. The coating liner according to claim 1, wherein the number of dusts having an area of 0.05 mm ² or more on the surface of the coating layer of the coating liner is 600 pieces / m ² or less. The ratio compressive force of the coating liner is 100N / (g / ^{m 2)} or more, coating liner placing serial to claim 1 or 2. The liner for flexographic printing using the coating liner of any one of Claims 1-3 . A corrugated cardboard sheet comprising the coating liner according to any one of claims 1 to 4 . A method for producing the coated liner according to any one of claims 1 to 3 ,
On the paper layer that is the surface layer of the liner base paper having at least two paper layers, a coating liquid containing a pigment in which 3 to 30% by mass of the total pigment is synthetic amorphous silica and an adhesive, The manufacturing method of a coating liner characterized by forming the coating layer of 3-25 g / m < ² > (total solid content) of coating amount.