JP6398602B2 - Power storage element, method for manufacturing the same, and power storage device - Google Patents

Description

  The present invention relates to a power storage element, a manufacturing method thereof, and a power storage device.

  Storage devices such as batteries and capacitors that can be repeatedly charged and discharged include hybrid vehicles (HEV), plug-in hybrid vehicles (PHEV), electric vehicles (PEV), vehicles such as electric motorcycles and electric assist bicycles, and stationary storage systems. Has been adopted. For example, the power storage element includes an electrode body as a power storage element housed in a case. And the electrical storage element is provided with the external terminal used for a connection with the exterior.

Here, the power storage element may be used alone, but when used in the vehicle or the power storage system as described above, a plurality of power storage elements are often connected to be used as a power storage device. At this time, a bus bar may be used for connection between the external terminals of the power storage elements. The connection between the external terminal and the bus bar may be made by welding.
By the way, for example, in a storage element such as a lithium ion battery, copper (Cu) is often used as a constituent material of a negative electrode core included in an electrode body, and aluminum (Al) is used as a constituent material of a positive electrode core. For this reason, when it is going to connect electricity storage elements in series, it is necessary to aim at the connection between dissimilar metals. Patent Documents 1 and 2 disclose techniques related to the connection between such different metals.

Patent Document 1 discloses that connection between a positive electrode external terminal and a negative electrode external terminal made of different metal materials is performed using a bus bar made of a clad material.
Patent Document 2 discloses that a rivet-shaped terminal composed of a multimetal of copper and aluminum is employed for one of the external terminals of the positive electrode and the negative electrode.

JP 2011-060623 A JP 2011-210720 A

However, in the prior art including the technique disclosed in Patent Document 1, it is necessary to use a bus bar to which dissimilar metals are connected. For this reason, provision of the electrical storage element accompanied by the connection between dissimilar metals is calculated | required.
In the prior art including the technique disclosed in Patent Document 2, it is considered that the manufacturing cost is increased in order to form the terminal to be used. Therefore, with this technology, it is difficult to provide a power storage element that involves connection between different metals while suppressing an increase in manufacturing cost.

  The present invention has been made to solve such a problem, and provides a power storage element with a connection between dissimilar metals, a manufacturing method thereof, and a power storage device while suppressing an increase in manufacturing cost. Objective.

A power storage element according to one embodiment of the present invention includes an electrode body, a case, and an external terminal.
The electrode body includes a positive electrode element and a negative electrode element.
The case houses the electrode body.
The external terminal is electrically connected to one of the positive electrode element and the negative electrode element (hereinafter referred to as “one element”), and is provided for external connection.

In the power storage device according to this aspect, the external terminal includes an external terminal portion that is at least partially arranged outside the case, and a ground portion that electrically connects the external terminal portion and one element, and the external terminal The part has a plate shape including a first metal part made of a first metal and a second metal part made of a second metal different from the first metal.
At least the first metal part is exposed on the first surface which is one main surface of the external terminal part, and the first metal part and the second metal part are exposed on the second surface which is the other main surface. When the external terminal portion is viewed in the thickness direction, at least a part of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface overlap.

  And the base part in an external terminal contains the same metal as a 1st metal part, and is weld-connected in the said overlapping area | region in the 1st surface among external terminal parts.

  In the above aspect, it is possible to provide a power storage element that involves connection between different metals while suppressing an increase in manufacturing cost.

It is a model expansion perspective view showing composition of power storage device 1 concerning an embodiment of the invention. 3 is a schematic cross-sectional view illustrating a configuration of a power storage element 13 in the power storage device 1. FIG. 3 is a schematic developed perspective view showing a configuration of an electrode body 130 in the electricity storage element 13. FIG. (A) is a schematic cross-sectional view showing the configuration of the negative electrode external terminal 132 and its periphery in the electricity storage device 13, and (b) is a schematic cross-sectional view showing the configuration of the positive electrode external terminal 131 and its periphery in the electricity storage device 13. is there. 4 is a schematic cross-sectional view showing a configuration of an external terminal portion 1322 in the negative electrode external terminal 132. FIG. 4 is a schematic developed cross-sectional view showing a configuration of a negative electrode external terminal 132. FIG. (A) is a schematic perspective view which shows the structure of the external terminal part 1322 in the negative electrode external terminal 132, (b) is a schematic cross section which shows the bus bar 15 and the external terminal part 1322 in the state joined mutually. is there. (A) is a schematic cross-sectional view showing the configuration of the external terminal portion 2322 according to Modification 1, and (b) is a schematic cross-sectional view showing the configuration of the external terminal portion 3322 according to Modification 2. 10 is a schematic cross-sectional view showing a configuration of a negative electrode external terminal 432 according to Modification 3. FIG.

[Embodiments of the present invention]
A power storage element according to one embodiment of the present invention includes an electrode body, a case, and an external terminal.
The electrode body includes a positive electrode element and a negative electrode element.
The case houses the electrode body.
The external terminal is electrically connected to one element of the electrode body and provided for electrical connection with the outside.

In the power storage device according to this aspect, the external terminal includes an external terminal portion that is at least partially arranged outside the case, and a ground portion that electrically connects the external terminal portion and one element, and the external terminal The part has a plate shape including a first metal part made of a first metal and a second metal part made of a second metal different from the first metal.
At least the first metal part is exposed on the first surface which is one main surface of the external terminal part, and the first metal part and the second metal part are exposed on the second surface which is the other main surface. When the external terminal portion is viewed in the thickness direction, at least a part of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface overlap.

And the base part in an external terminal contains the same metal as a 1st metal part, and is weld-connected in the said overlapping area | region in the 1st surface among external terminal parts.
In the electricity storage device according to the above aspect, the external terminal has a plate-like external terminal portion. In the external terminal portion, the first metal portion is exposed on the first surface and the second metal portion is exposed on the second surface. Therefore, in the electricity storage device according to this aspect, the second metal part made of a metal species different from the first metal part can be exposed. In addition, in the electricity storage device according to this aspect, by using the plate-like external terminal portion, it is possible to suppress an increase in manufacturing cost compared to the case of using a rivet-like external terminal made of multimetal as in Patent Document 2. be able to.

  Moreover, in the electrical storage element according to the above aspect, with respect to the welding joint between the external terminal portion and the base portion, the plane of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface This is done in areas that overlap visually. That is, the welded connection between the external terminal portion and the base portion is an area where the plate thickness direction from the first surface to the second surface is configured only by the first metal portion. Therefore, in the electrical storage element according to this aspect, high welding strength can be ensured, poor welding can be suppressed, and high joint strength can be secured over a long period of time.

In the electricity storage device according to the above aspect, when the external terminal portion has a plate shape and the second metal portion is exposed on the second surface, the bus bar is welded to the external terminal portion of the external terminal. In addition, joining in a surface contact state is possible, which is advantageous in ensuring welding strength and reducing electrical resistance related to connection.
Therefore, in the said aspect, the electrical storage element with the connection between dissimilar metals can be provided, suppressing the raise in manufacturing cost.

In the above, “the first metal portion is exposed on the first surface” means that the first metal portion is exposed on the first surface in a state before the base portion is welded, It is not always necessary that the first metal part be exposed on the first surface after the welding connection with the base part.
In the electricity storage device according to another aspect, in the above configuration, the case has a hole penetrating in the thickness direction, and the external terminal includes an intermediate terminal portion. The intermediate terminal portion in the external terminal is inserted through the hole of the case and has conductivity. Further, the intermediate terminal portion has a head portion protruding outward from the hole of the case, and the head portion corresponds to the base portion.

In the electricity storage device according to this aspect, since the external terminal has the intermediate terminal portion, the external terminal portion itself does not need to have a complicated shape, and an increase in manufacturing cost can be suppressed.
In the electricity storage device according to another aspect, in the external terminal configured as described above, the head portion of the intermediate terminal portion has a plate shape along the first surface of the external terminal portion, and the head portion extends in the penetration direction of the hole of the case. When viewed in a plan view, it has an area larger than the opening area of the hole of the case and covers the hole of the case. In the electricity storage device according to this aspect, it is possible to increase the connection area of the external terminal portion with respect to the intermediate terminal portion, and it is possible to ensure the welding strength and reduce the electrical resistance related to the connection.

  In the electricity storage device according to another aspect, in the external terminal configured as described above, the second surface of the external terminal portion is flush with the portion where the first metal portion is exposed and the portion where the second metal portion is exposed. In the electricity storage device according to this aspect, when the bus bar is welded to the external terminal portion of the external terminal, the boundary between the dissimilar metals (the first metal portion and the second metal portion between the second surface of the external terminal portion). It is possible to suppress the exposure of the edge related to the boundary), which is desirable from the viewpoint of corrosion resistance.

  In the electricity storage device according to another aspect, in the external terminal configured as described above, the second surface of the external terminal portion has a portion where the first metal portion is exposed recessed toward the first surface than a portion where the second metal portion is exposed. It has entered. Thereby, the cost concerning manufacture of an external terminal part can be aimed at. For example, after laminating the first metal part and the second metal part, the external terminal part is simply removed by removing a part of the second metal part until a part of the surface of the first metal part is exposed at the bottom part. Can be manufactured.

  In the electricity storage device according to another aspect, in the external terminal configured as described above, the exposed portion of the second metal portion on the second surface of the external terminal portion surrounds the recessed portion. In the electricity storage device according to this aspect, when the bus bar is welded to the second surface of the external terminal portion, the opening of the recessed portion is covered with the bus bar so that the inside of the recessed portion is covered. It is possible to suppress moisture adhesion or the like on the exposed boundary portion between the first metal portion and the second metal portion. Therefore, it is desirable to further improve the reliability.

  In the electricity storage device according to another aspect, in the external terminal configured as described above, the external terminal portion includes a clad material including a recess partly cut out on one main surface, and the first metal portion is provided at the bottom of the recess. The second metal part is exposed around the recess. Thus, by adopting a configuration having a clad plate including a recess partly cut out on one main surface, it is possible to improve reliability while suppressing an increase in manufacturing cost.

In the electricity storage device according to another aspect, in the external terminal configured as described above, the external terminal portion is formed by stacking the first element plate made of the first metal and the second element plate made of the second metal and caulking. A part of the second element plate is cut away. By adopting such an external terminal portion, an increase in manufacturing cost can be suppressed.
In the electricity storage device according to another aspect, in the external terminal configured as described above, the external terminal portion includes a corrosion prevention layer disposed between the first element plate and the second element plate. In the electricity storage device according to this aspect, the occurrence of corrosion between the first element plate and the second element plate in the external terminal portion can be suppressed.

In addition, as a constituent material of the corrosion prevention layer, for example, a metal having an ionization tendency between the first metal and the second metal, a conductor such as carbon, which is not easily ionized, or a noble metal can be employed.
The power storage device according to one embodiment of the present invention electrically connects the first power storage element and the second power storage element, and one positive external terminal and the other negative external terminal of the first power storage element and the second power storage element. With a bus bar.

Each of the first power storage element and the second power storage element includes an electrode body, a case, a positive external terminal, and a negative external terminal. The electrode body includes a positive electrode element and a negative electrode element. The case houses the electrode body. The positive electrode external terminal is electrically connected to the positive electrode element and is provided for electric connection with the outside. The negative electrode external terminal is electrically connected to the negative electrode element and provided for external connection.
In the power storage device according to this aspect, one positive external terminal of the first power storage element and the second power storage element and one terminal of the other negative external terminal (hereinafter referred to as “one terminal”). ) Includes an external terminal portion disposed outside the case, and a base portion that electrically connects the external terminal portion and one of the positive electrode element and the negative electrode element.

  On the other hand, the external terminal portion of the terminal is plate-shaped including a first metal portion made of a first metal and a second metal portion made of a second metal different from the first metal, and is one main portion of the external terminal portion. At least the first metal part is exposed on the first surface that is the surface, and the first metal part and the second metal part are exposed on the second surface that is the other main surface. That is, on the second surface, the second metal part made of a metal species different from the first metal part can be exposed.

  On the other hand, when the external terminal portion of the terminal is viewed in the thickness direction, at least a portion of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface overlap. The base portion includes the same metal as the first metal portion, and is welded and connected in the overlapping region on the first surface of the external terminal portion. And the bus bar is weld-connected with respect to the 2nd metal part exposed to the 2nd surface at the external terminal part in one terminal.

  Here, also in this aspect, “the first metal portion is exposed on the first surface” means that the first metal portion is exposed on the first surface in a state before the base portion is welded. In addition, it is not always necessary that the first metal portion is exposed on the first surface after the welding connection with the base portion. Further, “the first metal part and the second metal part are exposed on the second surface” means that the first metal part and the second metal part are on the second surface in a state before the bus bar is welded. It means to be exposed.

In the power storage device according to this aspect, one terminal of one of the first power storage element and the second power storage element has the same configuration as the external terminal of the power storage element according to the above aspect.
Therefore, in this aspect, it is possible to provide a power storage device that involves connection between different metals while suppressing an increase in manufacturing cost.
In the power storage device according to another aspect, in the one terminal configured as described above, the second surface of the external terminal portion has a portion where the first metal portion is exposed recessed toward the first surface than a portion where the second metal portion is exposed. The recessed portion is covered by the joining of the bus bar to the second metal portion exposed on the second surface. In the power storage device adopting such a configuration, for the reasons described above, it is possible to suppress moisture adhesion to the boundary portion between the first metal portion and the second metal portion exposed to the inside of the recessed portion. Can do. Therefore, it is desirable to further improve the reliability.

A manufacturing method according to an aspect of the present invention includes (a) a step of preparing an electrode body, (b) a step of housing the electrode body, and (c) a step of forming an external terminal.
(A) Step of preparing an electrode body; an electrode body including a positive electrode element and a negative electrode element is prepared.
(B) The step of accommodating the electrode body; the electrode body is accommodated in the case.
(C) Step of forming an external terminal; forming an external terminal that is electrically connected to one of the positive electrode element and the negative electrode element and used for electrical connection with the outside.

In the method for manufacturing a power storage device according to this aspect, the step (c) of forming the external terminal includes (c-1) a sub-step of preparing the external terminal portion, and (c-2) a sub-step of welding connection.
(C-1) Sub-step of preparing an external terminal portion; preparing an external terminal portion at least partially arranged outside the case.
(C-2) Sub-process for welding connection: The external terminal portion is welded to the base portion that electrically connects the external terminal portion and one of the positive electrode element and the negative electrode element.

  In the manufacturing method of this aspect, (c-1) in the sub-step of preparing the external terminal portion, as the external terminal portion, a first metal portion made of the first metal and a second metal made of the second metal different from the first metal. A plate-like member including two metal parts, and in a state before connection to the base part, at least the first metal part is exposed on the first surface which is one main surface of the external terminal part, and the other side The second surface, which is the main surface of the first, is a portion where the first metal portion and the second metal portion are exposed, and the first metal portion is exposed on the first surface when the external terminal portion is viewed in the plate thickness direction. And a portion where the first metal portion is exposed on the second surface is prepared as a member at least partially overlapping.

Moreover, in the manufacturing method of this aspect, (c-2) In the sub-process for welding connection, the above-described overlapping region on the first surface of the external terminal portion, and the region including the same metal as the first metal portion in the base portion, , Welded.
In the method for manufacturing the electricity storage device according to the above aspect, in the sub-step (c-1), the external terminal is prepared as a plate-like external terminal portion, and in the sub-step (c-2), the external terminal portion is An external terminal is provided. As described above, the external terminal portion to be used is a member in which the first metal portion is exposed on the first surface and the second metal portion is exposed on the second surface. Therefore, in the method for manufacturing the electricity storage device according to this aspect, the use of the plate-like external terminal portion increases the manufacturing cost compared to the case of using rivet-like external terminals made of multimetal as in Patent Document 2. Can be suppressed.

  Moreover, in the manufacturing method of the electrical storage element which concerns on the said aspect, in the sub process of (c-2), with respect to a foundation | substrate part, the part which exposed the 1st metal part to the 1st surface in an external terminal part, and a 2nd surface Welding connection is made in a region overlapping with the exposed portion of the first metal portion in plan view. That is, the welded connection between the external terminal portion and the base portion is an area where the plate thickness direction from the first surface to the second surface is configured only by the first metal portion. Therefore, in the manufacturing method according to this aspect, welding connection can be performed with high welding strength, welding failure can be suppressed, and high bonding strength can be ensured over a long period of time.

In the manufacturing method according to the above aspect, the plate-shaped external terminal portion is used, and the second metal portion is exposed on the second surface of the external terminal portion before connection to the bus bar. When the bus bar is joined by welding, surface joining is possible, which is advantageous in securing welding strength and reducing electrical resistance related to the connection.
Therefore, in the manufacturing method according to the above aspect, it is possible to obtain a power storage element that involves connection between dissimilar metals while suppressing an increase in manufacturing cost.

Hereinafter, an example for carrying out the present invention will be described with reference to the drawings.
In addition, the form shown below is an example used in order to explain the configuration of the present invention and the operations and effects produced from the configuration in an easy-to-understand manner, and the present invention is not limited to the following form except for the essential part. You are not limited to this.
[Embodiment]
1. Configuration of Power Storage Device 1 The configuration of the power storage device 1 according to the embodiment will be described with reference to FIG.

  As shown in FIG. 1, the power storage device 1 includes four power storage elements 11 to 14 and three bus bars 15 to 17 that are used for electrical connection with each other. Each of the four power storage elements 11 to 14 has an external shape of a flat rectangular system having a narrow width in the X-axis direction. Further, positive electrode external terminals 111, 121, 131, 141 and negative electrode external terminals 112, 122, 132, 142 project from the sealing body that constitutes the upper side surface in the Z-axis direction of each power storage element 11-14.

The four power storage elements 11 to 14 are arranged in the X-axis direction.
Bus bar 15 is welded to positive electrode external terminal 121 of power storage element 12 and negative electrode external terminal 132 of power storage element 13. Bus bar 16 is welded to positive electrode external terminal 131 of power storage element 13 and negative electrode external terminal 142 of power storage element 14. The bus bar 17 is welded to the positive external terminal 111 of the power storage element 11 and the negative external terminal 122 of the power storage element 12.

In the present embodiment, bus bars 15 to 17 are made of aluminum (Al).
2. Configuration of Power Storage Elements 11-14 The configuration of the power storage elements 11-14 will be described with reference to FIG. 2 shows a schematic cross-sectional view of the power storage element 13, the remaining power storage elements 11, 12, and 14 have the same configuration.

In the electric storage element 13, a case is constituted by a bottomed rectangular tube-shaped case main body 133 and a sealing body 134 that seals the opening. The case main body 133 and the sealing body 134 are joined in an airtight manner, for example, by laser welding at the outer side portion of the sealing body 134.
An electrode body 130 is accommodated in a case configured by a combination of the case main body 133 and the sealing body 134. Although not shown, the case is also filled with a nonaqueous electrolyte.

A positive electrode current collector 135 and a negative electrode current collector 136 are connected to the electrode body 130. The positive electrode current collector 135 and the negative electrode current collector 136 are provided along the inner surfaces of the case main body 133 and the sealing body 134, and are bent in an L shape as a whole. It extends to each lower part of the positive external terminal 131 and the negative external terminal 132.
As indicated by arrows A and B in FIG. 2, each of the positive external terminal 131 and the negative external terminal 132 passes through a hole formed in the sealing body 134, and a part of each protrudes to the outside.

3. Configuration of Electrode Body 130 The configuration of the electrode body 130 included in the power storage element 13 will be described with reference to FIG. In addition, although illustration is abbreviate | omitted, also about the electrical storage elements 11, 12, and 14, the electrode body of the same structure is provided.
As shown in FIG. 3, the electrode body 130 is configured such that a positive electrode element 1301 that is a belt-like sheet body and a negative electrode element 1302 that is also a belt-like sheet body are arranged to face each other, and a separator 1303 is interposed therebetween. .

The positive electrode element 1301 is provided with a core portion 1301a where an active material layer is not formed at one edge in the width direction (Y-axis direction), and the portion covered with the separator 1303 is formed with an active material layer A portion 1301b is formed. Similarly, the negative electrode element 1302 is also provided with a core part 1302a and an active material forming part 1302b.
As shown in FIG. 3, the electrode body 130 includes a positive electrode element 1301 and a negative electrode element 1302 that are disposed so as to face each other with a separator 1303 interposed therebetween, and are wound around the winding axis Ax ₁₃₀ (rot.C). In the electrode body 130, the core body portion 1302a of the negative electrode element 1302 is exposed on the upper side in the Y-axis direction from the upper side of the separator 1303, and the core body portion 1301a of the positive electrode element 1301 is exposed on the lower side in the Y-axis direction from the lower side. The positive electrode current collector 135 and the negative electrode current collector 136 are connected to the core portions 1301a and 1302a.

The electrode body 130 is wound around the winding axis Ax ₁₃₀ (rot.C) and then flattened in the X-axis direction in order to match the shape of the inner space of the case main body 133.
Here, in the electrode body 130, the core body of the positive electrode element 1301 is made of aluminum (Al), and the negative electrode core body is made of copper (Cu). The positive electrode current collector 135 bonded to the core part 1301a of the positive electrode element 1301 is made of the same material, that is, aluminum (Al), and is bonded to the core part 1302a of the negative electrode element 1302. 136 is made of copper (Cu).

4). Configuration of Negative External Terminal 132 and Configuration of Positive External Terminal 131 (4-1) Configuration of Negative External Terminal 132 The configuration of the negative external terminal 132 will be described with reference to FIG.
As shown in FIG. 4A, the negative electrode external terminal 132 is laser-welded to the intermediate terminal part 1321 outside the sealing body 134 and the intermediate terminal part 1321 inserted through the hole formed in the sealing body 134. And a combination with the external terminal portion 1322 joined (welded location WP). Insulating members 137 and 138 are disposed between the intermediate terminal portion 1321 and the sealing body 134, and a negative electrode current collector 136 is connected inside the sealing body 134.

The intermediate terminal portion 1321 has a plate-like shape in which a portion protruding outward from the hole of the sealing body 134 extends in a direction perpendicular to the through direction (Z-axis direction) of the hole, and the sealing portion 134 The hole of the body 134 is covered. The intermediate terminal portion 1321 is airtightly fixed to the sealing body 134 by caulking inside.
The external terminal portion 1322 is made of a clad material in which a first metal portion 13221 and a second metal portion 13222 are laminated in the Z-axis direction. In the present embodiment, as an example, the first metal portion 13221 and the second metal portion The portions 13222 are both layered, but the present invention is not limited to this.

A part (center portion) of the second metal portion 13222 is cut out and opened (opening portion 1322a). In the external terminal portion 1322, the first metal portion 13221 is exposed on the lower surface in the Z-axis direction, and the portion where the first metal portion 13221 is exposed and the portion where the second metal portion 13222 is exposed on the upper surface in the Z-axis direction. (Exposed portion 13221a, exposed portion 13222a).
In addition, the term “exposed” in the present disclosure, including the present embodiment, means that each metal part is exposed in a state where the base part or the bus bar is not connected to the external terminal part. Yes.

In the external terminal portion 1322, the exposed portion 13222 a of the second metal portion 13222 is provided so as to surround the exposed portion 13221 a of the first metal portion 13221.
Note that the lower surface in the Z-axis direction of the external terminal portion 1322 is a flat surface along the upper surface in the Z-axis direction of the intermediate terminal portion 1321, and is welded and connected in surface contact with each other.
Here, the constituent material of the negative electrode external terminal 132 is as follows.

Intermediate terminal part 1321; copper (Cu)
First metal part 13221; copper (Cu)
Second metal part 13222; aluminum (Al)
(4-2) Configuration of Positive External Terminal 131 Next, the configuration of the positive external terminal 131 will be described with reference to FIG.

As shown in FIG. 4B, the positive external terminal 131 includes an intermediate terminal portion 1311 that passes through a hole formed in the sealing body 134. Insulating members 139 and 140 are interposed between the intermediate terminal portion 1311 and the sealing body 134, and a positive electrode current collector 135 is connected inside the sealing body 134.
The intermediate terminal portion 1311 also has a plate-like shape in which the portion protruding outward from the hole of the sealing body 134 extends in a direction perpendicular to the through direction (Z-axis direction) of the hole. The hole of the sealing body 134 is covered. The intermediate terminal portion 1311 is also airtightly fixed to the sealing body 134 by caulking, like the intermediate terminal portion 1321 of the negative electrode external terminal 132.

5. The configuration of the external terminal portion 1322 and the welding location The configuration of the external terminal portion 1322 and the welding location with the intermediate terminal portion 1321 will be described with reference to FIG.
As shown in FIG. 5, the external terminal portion 1322 is configured based on a clad material in which the second metal portion 13222 is laminated on the upper side in the Z-axis direction of the first metal portion 13221. In the external terminal portion 1322, a part of the second metal portion 13222 stacked above the first metal portion 13221 in the Z-axis direction is notched (opening portion 1322a), and the opening The first metal portion 13221 is exposed at the bottom of the portion 1322a (exposed portion 13221a). As described above, the second metal portion 13222 surrounds the opening 1322a where the exposed portion 13221a exists at the bottom.

That is, in the external terminal portion 1322, only the first metal portion 13221 is exposed on the lower surface in the Z-axis direction contacting the head portion 1321b of the intermediate terminal portion 1321 (lower exposed surface 13221b), and the first metal portion is exposed on the upper surface in the Z-axis direction. There is an exposed portion 13221a of 13221 and an exposed portion 13222a of the second metal portion 13222 (see FIG. 4A).
In the present embodiment, the exposed portion 13221a is recessed in the Z-axis direction.

  Here, as shown in FIG. 5, the region of the opening 1322a where the exposed portion 13221a of the first metal portion 13221 is present on the upper surface is defined as region E, and the entire lower surface region where the first metal portion 13221 is exposed is defined as region F. To do. At this time, when the areas E and F are viewed in plan from the direction of the arrow D, which is the thickness direction, there are areas that overlap each other. In this overlapping region, only the first metal portion 13221 exists in the thickness direction, and the second metal portion 13222 and other metal portions do not exist.

As shown in FIG. 4A, in the present embodiment, the external terminal portion 1322 and the intermediate terminal portion 1321 are connected by laser welding in the overlapping region of the regions E and F.
6). Manufacturing Method of Power Storage Elements 11-14 The power storage elements 11-14 according to the present embodiment are manufactured through the following steps.
(Step a) An electrode body 130 is prepared. As already described with reference to FIG. 3, the electrode body 130 is formed by arranging a positive electrode element 1301 and a negative electrode element 1302 so as to face each other with a separator 1303 interposed therebetween, and winding this.

(Step b) The electrode body 130 is accommodated in the case. As shown in FIG. 2, the electrode body 130 is accommodated inside the case main body 133, and the opening is sealed with the sealing body 134.
(Step c) The positive electrode external terminals 111, 121, 131, 141 and the negative electrode external terminals 112, 122, 132, 142 that are partially protruded to the outside are formed on the sealing body 134. In addition, the order of the process a and the process b, and the process c is not limited to said order. Specifically, in the present embodiment, the process c is executed before the process b is executed.

Among the methods for manufacturing the electricity storage elements 11 to 14 as described above, a method for forming the negative external terminals 112, 122, 132, 142 will be described with reference to FIG. In the following description, the negative electrode external terminal 132 is described as an example, but the negative electrode external terminals 112, 122, and 142 of the other power storage elements 11, 12, and 14 are also formed by using the same forming method. The
As described above, the external terminal portion 1322 that is a constituent element of the negative electrode external terminal 132 is a plate body having a concave portion in which a part of the clad material is cut out, and the first metal portion 13221 and the first metal portion 13221 both having a plate shape. Two metal parts 13222 are stacked. The lower exposed surface 13221b of the external terminal portion 1322 has a planar shape along the upper surface of the head portion 1321b of the intermediate terminal portion 1321, and is in close contact with the head portion 1321b of the intermediate terminal portion 1321 without a substantial gap.

Intermediate terminal portion 1321 and external terminal portion 1322 are connected by laser welding at a part of exposed portion 13221a at which first metal portion 13221 is exposed at the bottom of opening 1322a.
As shown in FIG. 6, a hole 134 a that penetrates the inside and outside of the case is opened at a corresponding portion of the sealing body 134. Then, a part of the insulating member 137 is inserted into the hole 134a from above in the Z-axis direction (case outward side). Further, the insulating member 138 is applied to the hole 134a from below in the Z-axis direction (inner side of the case). The insulating member 138 has a hole 138a having substantially the same opening size as the hole 134a formed in the sealing body 134, and the lower end portion of the insulating member 137 is inserted into the hole 138a.

The insulating members 137 and 138 are in close contact with the sealing body 134 without a substantial gap.
The body 1321a of the intermediate terminal portion 1321 with the external terminal portion 1322 connected to the inside 137a is inserted into the insulating member 137 attached to the sealing body 134. The body portion 1321 a of the intermediate terminal portion 1321 is inserted through the hole 138 a of the insulating member 138 attached to the back surface of the sealing body 134. In this state, the lower surface of the plate-shaped head portion 1321b of the intermediate terminal portion 1321 is in close contact with the shelf surfaces 137b and 137c of the insulating member 137 without any substantial gap.

The front end of the trunk portion 1321a of the intermediate terminal portion 1321 protruding from the hole 138a of the insulating member 138 also passes through the hole 136a of the negative electrode current collector 136 attached along the inner surface of the insulating member 138. In this state, the intermediate terminal portion 1321 is fixed in a state as shown in FIG. 4A by plastically deforming the front end of the body portion 1321a by, for example, spinning caulking.
As described above, the negative external terminal 132 can be formed.

7). The external shape of the external terminal part 1322 and the connection form of the external terminal part 1322 and the bus bar 15 The external form of the external terminal part 1322 and the connection form of the external terminal part 1322 and the bus bar 15 will be described with reference to FIG. In FIG. 7, only the external terminal portion 1322 is taken out and illustrated in the configuration of the power storage element 13.

  As shown in FIG. 7A, the external terminal portion 1322 according to the present embodiment is disposed above the first metal portion 13221 and the second metal portion 13222 stacked in the Z-axis direction. The second metal portion 13222 has a “B” shape in plan view, and the exposed portion 13222a of the second metal portion 13222 surrounds the exposed portion 13221a of the first metal portion 13221 on the upper surface in the Z-axis direction. Yes. In the external terminal 1322, the exposed portion 13221a on the upper surface in the Z-axis direction is recessed downward in the plate thickness direction (Z-axis direction) with respect to the exposed portion 13222a surrounding the periphery.

  As shown in FIG. 7B, the bus bar 15 is connected to the external terminal portion 1322 so as to cover the opening 1322a where the exposed portion 13221a is present at the bottom. As a result, the interface portion P1... P1 between the first metal portion 13221 and the second metal portion 13222 inside the opening 1322a in the external terminal portion 1322 is obtained. It is possible to suppress moisture or the like from P2 from the outside. Therefore, it is possible to suppress the occurrence of corrosion at the interface portions P1 and P2 including during charging and discharging.

In addition, in order to suppress generation | occurrence | production of corrosion with respect to interface part P1, P2, it is good also as coat | covering with an insulating member separately, or filling the opening part 1322a with an insulating member.
In addition, the opening 1322a of the external terminal portion 1322 is preferably sealed by connection of the bus bar 15 in order to obtain the above effect. However, even if it is not completely sealed, the above effect can be obtained even if it is covered. it can.

8). Effect In power storage elements 11 to 14 according to the present embodiment, each of negative electrode external terminals 112, 122, 132, 142 has a plate-shaped external terminal portion 1322,. The external terminal portions 1322,... Are formed using a clad material as a base, the exposed portion 13221a of the first metal portion 13221 is present on the lower surface in the Z-axis direction that is the first surface, and the Z surface that is the second surface. An exposed portion 13222a of the second metal portion 13222 exists on the upper surface in the axial direction. Therefore, in the electrical storage elements 11 to 14, the use of the plate-like external terminal portions 1322,... Increases the manufacturing cost compared to the case where rivet-like external terminals made of multimetal are used as in Patent Document 2. Can be suppressed.

  Further, in the storage elements 11 to 14, the region E and the region F in FIG. 5 overlap in a plan view with respect to the welding connection between the external terminal portions 1322,... And the intermediate terminal portions 1321,. Has been made. That is, the welded connection between the external terminal portion 1322,... And the intermediate terminal portion 1321,... Is a region where the plate thickness direction from the upper surface to the lower surface in the Z-axis direction is configured only by the first metal portion 13221. Yes. Therefore, in the electrical storage elements 111-14, high weld strength can be ensured, a welding failure can be suppressed, and it can be set as the structure accompanied by the connection between dissimilar metals.

  In addition, as shown in FIG. 7, in the power storage elements 11 to 14 and the power storage device 1 composed of these, the external terminal portions 1322,... Since the 13222 is exposed, when the bus bars 15 to 17 are welded to the external terminal portions 1322,... Of the negative electrode external terminals 112, 122, 132, 142, surface joining becomes possible, ensuring welding strength. This is significant for reducing the electrical resistance of the connection.

Therefore, in this Embodiment, the electrical storage elements 11-14 and the electrical storage apparatus 1 with the connection between dissimilar metals can be provided, suppressing the raise in manufacturing cost.
Further, in power storage elements 11 to 14 according to the present embodiment, negative electrode external terminals 112, 122, 132, 142 have intermediate terminal portions 1321,. Therefore, an increase in manufacturing cost can be suppressed.

  Further, in the power storage elements 11 to 14, in the negative electrode external terminals 112, 122, 132, and 142, the head portions 1321 b of the intermediate terminal portions 1321,. When the heads 1321b,... Are viewed in a plan view in the penetrating direction (Z-axis direction) of the holes 134a,... Of the sealing bodies 134,. It has an area larger than the opening area of 134a, ..., and covers holes 134a, .... Thereby, in the electrical storage elements 11-14, the connection area of the external terminal part 1322, ... with respect to the intermediate | middle terminal part 1321, ... can be taken large, and it is aimed at ensuring of welding strength and reduction of the electrical resistance concerning a connection. it can.

  Further, in the storage elements 11 to 14, in the negative electrode external terminals 112, 122, 132, 142, the upper surface in the Z-axis direction of the external terminal portion 1322, ... is the exposed portion 13221a, ... is the exposed portion 13222a, ...・ It is recessed downward in the Z-axis direction. And, since the external terminal portions 1322,... Are formed by notching the clad plate as a base, it is possible to reduce the cost for manufacturing the external terminal portions 1322,.

  In the storage elements 11 to 14, the negative electrode external terminals 112, 122, 132, and 142 surround the exposed portion 13221a in which the exposed portion 13222a on the upper surface in the Z-axis direction of the external terminal portion 1322,. Therefore, when the bus bars 15 to 17 are welded to the upper surfaces in the Z-axis direction of the external terminal parts 1322,..., The openings 1322a,. And the adhesion of moisture to the boundary portions P1, P2 between the first metal portions 13221,... And the second metal portions 13222,. . Therefore, further improvement in reliability can be achieved.

[Modification 1]
A configuration of the external terminal portion 2322 according to Modification 1 will be described with reference to FIG. Note that, in FIG. 8A, only the external terminal portion 2322 is illustrated, but the other configurations of the power storage element and the power storage device can be the same as those in the above embodiment.
As shown in FIG. 8A, in the external terminal portion 2322 according to the modified example 1, the first element plate 23221 and the second element plate 23222, both of which are plates, are overlapped, and a plurality of locations (arrows G and H). It is clinched and composed. Then, a part (center portion) of the second element plate 23222 is opened (opening portion 2322a), similarly to the second metal portion 13222 of the external terminal portion 1322 according to the above embodiment. The surface of the first element plate 23221 is exposed at the bottom of the opening 2322a (exposed portion 23221a). And the surface (exposed part 23222a) of the 2nd element board 23222 exists in the state which surrounds the circumference | surroundings of the opening part 2322a.

Also in the external terminal portion 2322, the lower surface in the Z-axis direction is in a state where only the surface of the first element plate 23221 is exposed (lower exposed surface 23221b).
In the external terminal portion 2322 according to this modification, the first element plate 23221 is made of a first metal (for example, copper (Cu)), and the second element plate 23222 is made of a second metal (for example, aluminum (Al)). Become.

Even when the external terminal portion 2322 configured as described above is employed, the same operations and effects as those of the above embodiment can be obtained.
Further, when the external terminal portion 2322 according to this modification is employed, the manufacturing cost can be further reduced as compared with the above embodiment.
[Modification 2]
A configuration of the external terminal portion 3322 according to Modification 2 will be described with reference to FIG. Note that, in FIG. 8B, only the external terminal portion 3322 is illustrated, but the other configurations of the power storage element and the power storage device can be the same as those in the above embodiment.

  As shown in FIG. 8B, also in the external terminal portion 3322 according to this modification, the second element plate 33222 is laminated and fixed to the first element plate 33221 by clinching. In this modification, a corrosion prevention layer 33223 is interposed between the first element plate 33221 and the second element plate 33222. The corrosion prevention layer 33223 is made of a material whose ionization tendency is between the first element plate 33221 and the second element plate 33222, for example. Specifically, when the first element plate 33221 is made of copper (Cu) and the second element plate 33222 is made of aluminum (Al), the corrosion prevention layer 33223 is made of nickel (Ni).

However, the constituent material of the corrosion prevention layer 33222 is not limited to the above. For example, a non-ionized conductor such as carbon or a noble metal may be employed.
Further, the corrosion prevention layer 33223 may be a plate material different from the first element plate 33221 and the second element plate 33222, or the surface portion of the first element plate 33221 or the second element plate 33222 is plated. It is good also as forming in.

  In the present modification, the corrosion prevention layer 33223 does not protrude into the opening 3322a, and only the first element plate 33221a is exposed at the bottom of the opening 3322a (exposed portion 33221a). Further, the lower surface in the Z-axis direction of the external terminal portion 3322 is in a state where only the first element plate 33221 is exposed (lower exposed surface 33221b). Therefore, also with respect to the external terminal portion 3322 according to this modification, welding connection with the intermediate terminal portion can be performed from the opening 3322a, and high joint strength can be obtained.

  Further, also in the present modification, an exposed portion 33221a exists at the bottom of the opening 3322a on the upper surface in the Z-axis direction of the external terminal portion 3322, and an exposed portion 33222a exists so as to surround the periphery thereof. For this reason, high joint strength can be ensured also at the time of welding connection of a bus bar. In the external terminal portion 3322 according to this modification, since the corrosion prevention layer 33223 is disposed between the first element plate 33221 and the second element plate 33222, the first element plate 33221 and the second element plate Corrosion with 33222 can be suppressed. “Corrosion” in the present disclosure includes “electric corrosion” that is corrosion caused by a difference in ionization tendency.

Here, the constituent material of the corrosion prevention layer 33223 is not necessarily nickel (Ni), and the conductivity between the first element plate 33221 and the second element plate 33222 is ensured while the corrosion of the first element plate 33221 and the second element plate 33222 is suppressed. If possible, it can be changed as appropriate.
Further, the corrosion prevention layer 33223 may be configured to protrude toward the inside of the opening 3322a. What is necessary is just to be able to ensure the connection area | region with an intermediate | middle terminal part.

[Modification 3]
The configuration of the negative external terminal 432 according to Modification 3 will be described with reference to FIG. In FIG. 9, only the negative external terminal 432 is illustrated, but the configuration of the positive external terminal can be the same as that of the positive external terminal 131 in the above embodiment, and the storage element and the storage For other configurations of the apparatus, configurations similar to those in the above embodiment can be employed.

  As shown in FIG. 9, the negative electrode external terminal 432 according to this modification includes an external terminal portion 4322 and a sealing body 434 as a conductive underlying layer. The external terminal portion 4322 has substantially the same configuration as the external terminal portion 1322 according to the above embodiment, includes a first metal portion 43221 and a second metal portion 43222, and has a plate shape. The first metal portion 43221 and the sealing body 434 in the external terminal portion 4322 are made of the same metal, and are part of the exposed portion 43221a where the first metal portion 43221 is exposed at the bottom of the opening 4322a, and are connected by laser welding. (Welded point WP).

In this modification, the negative electrode current collector 436 is in close contact with the sealing body 434 on the lower side surface (inner side surface) in the Z-axis direction, and is connected by laser welding or the like in a part of the contact region. (Welded point WP).
As described above, in the present modification, illustration of the configuration of the positive electrode external terminal is omitted, but the configuration of the positive electrode external terminal is the same as that of the above embodiment, so Even if the current collector 436 is electrically connected, the negative external terminal 432 and the positive external terminal can be prevented from being electrically connected.

In this modification, considering the connection of the plate-like bus bar, the height in the Z-axis direction up to the upper end of the negative external terminal 432 and the Z axis up to the upper end of the positive external terminal are based on the outer bottom surface of the case body. It is preferable to align the direction height.
[Other variations]
(1) Power storage device In the above-described embodiment, the power storage device 1 is configured by the four power storage elements 11 to 14 and the three bus bars 15 to 17. There is no limitation to this. For example, a power storage device including two or three power storage elements or a configuration including five or more power storage elements can be used. In addition, as for the connection form of the plurality of power storage elements, it is possible to adopt not only series connection but also series-parallel connection form.

(2) Electric storage element Moreover, in the said embodiment, about each electric storage element 11-14, the element which has a flat each cylindrical external appearance was made into an example, However, About the external appearance shape of an electrical storage element, it is limited to this There is no. For example, a power storage element having a cylindrical appearance, a power storage element having a button-like appearance, a power storage element having an outer relative shape made of a laminate sheet, and having a flat appearance can be used.

  Moreover, in the said embodiment, positive electrode external terminal 111,121,131,141 and negative electrode external terminal 112,122,132,142 protrude outward from the sealing body 134, ... about each electrical storage element 11-14. An example of this was taken. Moreover, in the said modification 3, the negative electrode external terminal 432 which employ | adopted the sealing body 434 as an underlayer which has electroconductivity was made into an example. However, the formation form of the external terminals is not limited to this. For example, one of the positive electrode external terminal and the negative electrode external terminal can be configured by welding the external terminal portion to the case body. In this case, the case main body corresponds to a conductive base portion, and the external terminal portions welded to the outer surface of the case main body can employ those of the above-described embodiment and modifications 1, 2, and 3. .

Moreover, in the said embodiment, although the spinning caulking was employ | adopted as an example of the fixing method of the intermediate terminal part 1321 with respect to the sealing body 134, this invention is not limited to this. For example, fixing by screwing may be employed.
Moreover, in the said embodiment, although the lithium ion secondary battery was employ | adopted as an example of an electrical storage element, it is not limited to this about the kind of electrical storage element. For example, a battery such as a nickel cadmium secondary battery or a nickel hydride secondary battery, or a capacitor such as an electric double layer capacitor or a lithium ion capacitor may be employed.

  Moreover, in the said embodiment, what was called a winding electrode body was employ | adopted as the electrode body 130 and ... which are the components of the electrical storage elements 11-14, However, The form of an electrode body is not limited to this. . For example, a stacked electrode body in which positive electrode elements and negative electrode elements are alternately stacked with a separator interposed therebetween can be used.

  Although not particularly mentioned, in the above embodiment, as shown in FIG. 2 or FIG. 4, the height of the upper end of the negative external terminal 132 in the Z-axis direction and the upper end of the positive external terminal 131 in the Z-axis direction. It is aligned with the height. However, it is not limited to this. For example, the height of the upper end of the negative electrode external terminal may be different from the height of the upper end of the positive electrode external terminal. The said embodiment is preferable at the point that a flat bus bar can be used by aligning the height of the upper end of a negative electrode external terminal, and the height of the upper end of a positive electrode external terminal.

(3) External terminal portion In the embodiment and the first and second modifications, the external terminal portions 1322, 2322, 3322, and 4322 having a rectangular plate in plan view are employed. This is not a limitation. For example, it may be a plan view circular plate, a plan view elliptical plate, a plan view oval plate, a plan view polygonal plate, or the like.

  Further, in the above embodiment, the negative electrode external terminals 112, 122, 132, 142 are configured to include the external terminal portions 1322,... It is also possible to adopt a configuration including the above, or a configuration including the above external terminal portion for both the positive external terminal and the negative external terminal.

  Further, the external terminal portions 1322, 4322,... In the above-described embodiment adopt a configuration having a concave portion in which a part of one main surface of the clad plate is cut out, and the external terminal portions 2322, 3322 in the first and second modifications. The plurality of element plates are joined by clinch caulking, but the method of forming the external terminal portion is not limited to this. For example, the external terminal portion formed by laminating a plurality of element plates can also be formed by using a friction stir welding method.

  Moreover, in the said embodiment and the modifications 1, 2, 3, the part which the 1st metal part exposes the part which the 2nd metal part exposes about the Z-axis direction upper surface of the external terminal parts 1322, 2322, 3322, 4322 Although the configuration indented in the thickness direction is taken as an example, it may be configured to be flush with each other.

  Regarding the metal material constituting the external terminal portion, in the above embodiment and the first and second modified examples, copper (Cu) and aluminum (Al) are taken as an example, but the present invention is not limited to this. That is, about the 1st metal part which concerns on a connection with an intermediate terminal part, what is necessary is just the same kind metal as the head in an intermediate terminal part. Here, the “same metal” does not need to have a completely identical composition including the valence, and includes a range in which a good connection can be obtained at the time of welding connection.

  Further, the second metal may be the same metal as the bus bar. Also in this case, the definition of “same metal” is the same as described above.

  Further, in the above-described embodiment and modifications 1, 2, and 3, the external terminal portions 1322, 2322, 3322, and 4322 employ a laminated structure of two or three layers of metal parts as an example. It is not limited to. For example, it is possible to employ an external terminal portion having a configuration in which the end sides of two or three plate bodies are connected to each other. Thereby, thickness reduction of an external terminal part can be aimed at and the enlargement of the size of an electrical storage element can be suppressed.

As the first metal and the second metal, for example, the following materials can be used.
(Example of first metal)
As the first metal, aluminum (Al), nickel (Ni), iron (Fe), or an alloy material containing these as a main component can be used in addition to copper (Cu). When the second metal is aluminum or an alloy material containing aluminum as a main component, the first metal is preferably copper, nickel, or an alloy material containing these as a main component. When the second metal uses copper, nickel, iron, or an alloy material containing these as the main components, it is preferable to use aluminum or an alloy material containing these as the main components for the first metal.

(Example of second metal)
As the second metal, aluminum, copper, nickel, iron, or an alloy material containing these as a main component can be used. When the first metal is copper or an alloy material containing copper as a main component, the second metal is preferably aluminum, nickel, or an alloy material containing these as a main component. When the first metal is aluminum or an alloy material containing aluminum as a main component, it is preferable to use copper, nickel, iron, or an alloy material containing these as a main component as the second metal.

  In order to obtain the effects of the present embodiment, the first metal preferably has a higher melting point than the second metal. The second metal having a lower melting point than the first metal in a region where the portion where the first metal portion is exposed on the first surface of the external terminal portion and the portion where the first metal portion is exposed on the second surface overlap in plan view When welding is performed in a state in which the second metal is contained, the second metal is melted in preference to the first metal. For this reason, welding is performed with a region constituted only by the first metal portion in the thickness direction from the first surface to the second surface as a target location. Accordingly, even when the second metal having a lower melting point than the first metal is used, the first metal is effectively melted. Therefore, it is advantageous for ensuring the welding strength.

  Furthermore, in the said embodiment, although it did not mention in particular about the constituent material of the case main body 133 and the sealing body 134, a stainless steel plate, a resin material, etc. are employable, for example. In addition, when using an electroconductive material as a material of a case main body or a sealing body, it is desirable to insert an insulating member between the electrode body and the current collector and the case main body and the sealing body. Alternatively, the inner surface of the case body or the sealing body may be coated with an insulating material.

(4) Bus bar In the above embodiment, the bus bars 15 to 17 are made of aluminum (Al), but the constituent material of the bus bar is not limited thereto. For example, a nickel (Ni) plated steel sheet or the like can be used.
Also, the bus bar may have any part that can be welded to the external terminal, and a form in which two plate-like parts are connected by a wire or the like is adopted. You can also.

  INDUSTRIAL APPLICABILITY The present invention is useful for realizing a power storage element that can secure a stable bonding strength with a bus bar over a long period while suppressing an increase in manufacturing cost.

DESCRIPTION OF SYMBOLS 1 Power storage device 11, 12, 13, 14 Power storage element 15, 16, 17 Bus bar 111, 121, 131, 141 Positive external terminal 112, 122, 132, 142, 432 Negative external terminal 130 Electrode body 133 Case main body 134, 434 Sealing Body 135 Positive electrode current collector 136, 436 Negative electrode current collector 137, 138, 139, 140 Insulating member 1301 Positive electrode element 1302 Negative electrode element 1303 Separator 1311, 1321 Intermediate terminal part 1322, 2322, 3322, 4322 External terminal part 13221, 43221 First 1 metal part 13222, 43222 2nd metal part 23221, 33221 1st element board 23222, 33222 2nd element board 33223 Corrosion prevention layer

Claims (6)

An electrode body including a positive electrode element and a negative electrode element;
A cases for housing the electrode body, a case having a hole penetrating in the thickness direction,
An external terminal that is electrically connected to one of the positive electrode element and the negative electrode element, and provided for electrical connection with the outside ;
An insulating member partially inserted into the hole of the case;
With
The external terminal includes an external terminal portion at least a part of which is disposed outside the case, and an intermediate terminal portion that is inserted through the hole of the case and has conductivity,
The intermediate terminal portion is a head portion protruding outward from the hole , and includes a head portion that is a base portion that electrically connects the external terminal portion and one of the positive electrode element and the negative electrode element ,
The external terminal portion has a plate shape including a first metal portion made of a first metal and a second metal portion made of a second metal different from the first metal,
The first surface, which is one main surface of the external terminal portion, exposes at least the first metal portion, and the second surface, which is the other main surface, includes the first metal portion and the second metal portion. Exposed
When the external terminal portion is viewed in the thickness direction, at least a part of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface overlap. And
The base portion includes the same metal as the first metal portion, and is welded and connected in the overlapping region in the first surface of the external terminal portion ,
The intermediate terminal portion, said in a state of being inserted in the insulating member, the tip is the case fixed in a state of being plastically deformed, a charge reservoir element. An electrode body including a positive electrode element and a negative electrode element;
A case containing the electrode body, and a case having a hole penetrating in the thickness direction;
An external terminal that is electrically connected to one of the positive electrode element and the negative electrode element, and provided for electrical connection with the outside;
An insulating member partially inserted into the hole of the case;
With
The external terminal includes an external terminal portion at least a part of which is disposed outside the case, and an intermediate terminal portion that is inserted through the hole of the case and has conductivity,
The intermediate terminal portion is a body portion inserted into the insulating member and a head portion protruding outward from the hole, and is between the external terminal portion and one of the positive electrode element and the negative electrode element. Including the head part, which is the base part for electrical connection,
The external terminal portion has a plate shape including a first metal portion made of a first metal and a second metal portion made of a second metal different from the first metal,
The first surface, which is one main surface of the external terminal portion, exposes at least the first metal portion, and the second surface, which is the other main surface, includes the first metal portion and the second metal portion. Exposed
When the external terminal portion is viewed in the thickness direction, at least a part of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface overlap. And
The base portion includes the same metal as the first metal portion, and is welded and connected in the overlapping region in the first surface of the external terminal portion,
The intermediate terminal portion is a component in which the body portion and the head portion are integrally formed.
Power storage element. The body portion is fixed to the case in a state in which the body portion is inserted into the insulating member and its tip is plastically deformed.
The electricity storage device according to claim 2. An electrode body including a positive electrode element and a negative electrode element;
A case for housing the electrode body;
An external terminal that is electrically connected to one of the positive electrode element and the negative electrode element, and provided for electrical connection with the outside;
With
The external terminal includes an external terminal portion at least a part of which is disposed outside the case, and a base portion that electrically connects the external terminal portion and one of the positive electrode element and the negative electrode element,
The external terminal portion has a plate shape including a first metal portion made of a first metal and a second metal portion made of a second metal different from the first metal,
The first surface, which is one main surface of the external terminal portion, exposes at least the first metal portion, and the second surface, which is the other main surface, includes the first metal portion and the second metal portion. Exposed
When the external terminal portion is viewed in the thickness direction, at least a part of the portion where the first metal portion is exposed on the first surface and the portion where the first metal portion is exposed on the second surface overlap. And
The base portion includes the same metal as the first metal portion, and is welded and connected in the overlapping region in the first surface of the external terminal portion,
In the second surface of the external terminal portion, the portion where the first metal portion is exposed is recessed closer to the first surface than the portion where the second metal portion is exposed,
The external terminal portion is configured by stacking and caulking a first element plate made of the first metal and a second element plate made of the second metal,
A portion of the second element plate is cut away;
Power storage element. Preparing an electrode body including a positive electrode element and a negative electrode element;
Accommodating the electrode body in a case;
Forming an external terminal that is electrically connected to one of the positive electrode element and the negative electrode element and provided for electrical connection with the outside;
A method of manufacturing a storage element comprising:
The step of forming the external terminal includes a sub-step of preparing an external terminal portion at least a part of which is arranged outside the case, and the external terminal portion of the external terminal portion, the positive electrode element, and the negative electrode element. on the other hand and a sub-step during welding connecting the base portion for electrically connecting the, the intermediate terminal portion for inserting the hole of the case have a, a sub-step of fixing to the casing,
In the sub-process for preparing the external terminal portion, the external terminal portion includes a plate-like shape including a first metal portion made of a first metal and a second metal portion made of a second metal different from the first metal. The first surface which is a member and is one main surface of the external terminal portion in a state before being connected to the base portion, at least the first metal portion is exposed and the second surface is the other main surface. The surface is exposed of the first metal portion and the second metal portion, and when the external terminal portion is viewed in the plate thickness direction, the portion where the first metal portion is exposed on the first surface and the surface Prepare a member at least partially overlapping with the portion where the first metal part is exposed on the second surface,
Wherein in the sub-step of welding connection, the said overlapping regions in the first surface of the external terminal portion, and the area including the first metal part and the same metal in the base unit, combined welding contact,
Wherein in the fixed sub-step, with respect to the mounted insulating member to the case, the manufacturing method of the power storage element characterized that you plastically deforming the front end while inserting the intermediate terminal portion inside of the insulating member . In the step of forming the external terminal, the fixing sub-step is performed after the sub-step of welding connection.
The manufacturing method of the electrical storage element of Claim 5.