JP6391621B2 - Titanium copper foil, copper products, electronic equipment parts and autofocus camera module - Google Patents

Description

  TECHNICAL FIELD The present invention relates to a titanium copper foil, a wrought copper product, an electronic device component, and an autofocus camera module, and particularly has good solderability suitable for use in a conductive spring material such as an autofocus camera module. The present invention relates to a Cu-Ti copper alloy foil.

  An electronic component called an autofocus camera module is used for a camera lens portion of a cellular phone. The autofocus function of the mobile phone camera is based on the electromagnetic force generated by moving the lens in a certain direction and passing a current through the coil wound around the lens by the spring force of the material used for the autofocus camera module. The lens is moved in the direction opposite to the direction in which the spring force of the material works. The camera lens is driven by such a mechanism, and the autofocus function is exhibited.

  For an autofocus camera module, a Cu—Ni—Sn-based copper alloy foil having a foil thickness of 0.1 mm or less and a tensile strength of 1100 MPa or more or a 0.2% proof stress has been used. However, due to the recent cost reduction demand, Cu-Ti-based copper alloy foils, which are relatively cheaper than Cu-Ni-Sn-based copper alloys, have come to be used, and the demand is increasing.

  In addition, regarding this type of Cu-Ti-based copper alloy foil, for example, in Patent Document 1, when the foil thickness is as thin as 0.1 mm or less, if the load is removed after the material is loaded and deformed, a sag occurs. Attention is focused on the problem. And in patent document 1, in order to solve this problem, "The foil thickness is 0.1 mm or less, contains 1.5-4.5 mass% Ti, the remainder consists of copper and an unavoidable impurity, and rolling direction. The 0.2% proof stress in the direction parallel to the direction is 1100 MPa or more, and the arithmetic average roughness (Ra) in the direction perpendicular to the rolling direction is 0.1 μm or less ”.

  By the way, since the Cu—Ti alloy contains Ti, which is an extremely active and easily oxidizable element, a strong oxide film is generated in the aging treatment in the final process. Since such a strong oxide film remarkably lowers the solderability, a relatively thick Cu—Ti alloy such as a titanium copper plate or strip is subjected to an aging treatment as described in Patent Document 2, for example. Later, chemical polishing (pickling) and mechanical polishing are generally performed to remove the oxide film.

To remove the oxide film with the Cu—Ti alloy, first, chemical polishing is performed. Since the oxide film of Cu-Ti alloy containing titanium oxide is very stable against acid, chemical polishing is highly corrosive chemical such as a solution of hydrogen peroxide in hydrofluoric acid or sulfuric acid. It is necessary to use a polishing liquid.
However, when a chemical polishing solution having such a strong corrosive force is used, not only the oxide film but also the non-oxidized portion may be corroded, and uneven unevenness or discoloration occurs on the surface after chemical polishing. There is a fear. Further, the corrosion does not proceed uniformly, and the oxide film may remain locally. Therefore, in order to remove surface irregularities, discoloration, and residual oxide film, mechanical polishing is performed using, for example, a buff after the chemical polishing.
After mechanical polishing, the final surface treatment is a rust prevention treatment to produce a plate / strip product. An aqueous solution of benzotriazole (BTA) is used for the rust-proofing treatment of the titanium copper foil, similar to the one used for general copper and copper alloy plates and strips.

Japanese Patent No. 5723849 Japanese Patent No. 4068413

  However, unlike the case of a titanium copper plate / strip, for example, with a thin titanium copper foil having a thickness of 0.1 μm or less, mechanical polishing is performed to improve the solderability by removing the oxide film generated by the aging treatment. It is difficult. There are two reasons for this, the first is related to foil passing through the mechanical polishing line, and the second is related to thickness control in the mechanical polishing line.

  Regarding the foil passing through the mechanical polishing line, which is the first reason, when a buff is used, the buff is caught on the titanium copper foil as the baffle rotates, and the titanium copper foil may break starting from the caught point. . In the buffing, the surface of the titanium copper foil is polished by rotating around the central axis of a cylindrical buffule. The bafrol is a resin in which abrasive grains (SiC and other abrasive grains) are dispersed and fixed to a sponge-like organic fiber. The lump of resin is caught by the edge of the titanium copper foil where it is uneven, and the strength of the titanium copper foil It breaks when a tension exceeding is applied.

  Regarding the plate thickness control in the mechanical polishing line, which is the second reason, the cylindrical baffle is loaded with a rolling load to polish, and the titanium copper foil has a line passing through it. Tension is applied. This rolling load and tension both have a more or less periodic vibration component, and this vibration is called chattering. Depending on the chattering period, each vibration may resonate. When the resonance is large, a tatami pattern appears on the polished surface to be mechanically polished by chattering. A pattern generated by chattering is called a chatter mark. This indicates that the amount of polishing differs according to the pattern, in other words, the amount of polishing of the titanium copper foil varies. Here, in the case of titanium copper foil, since the thickness is smaller than that of the titanium copper plate / strip, the influence of the variation in the polishing amount is large. That is, when the titanium copper foil is buffed, the variation in thickness increases, and when this is used as a spring, the variation in spring characteristics increases, which is not preferable.

  Therefore, it is difficult to mechanically polish a thin titanium copper foil using a buff or the like as compared with a titanium copper plate / strip. In addition, in recent years, lead-free solder has been widely used for health reasons, and this lead-free solder is inferior in solderability compared to conventional lead-containing solder.

  As a result, the thin titanium copper foil inevitably deteriorates the solderability, and there is a problem that the solder wettability and the solder adhesion necessary for manufacturing an autofocus camera module cannot be ensured.

  An object of the present invention is to solve such a problem, a thin titanium copper foil having a foil thickness of 0.1 μm or less, excellent solder wettability and solder adhesion strength, and an autofocus camera module or the like. It aims at providing the titanium copper foil which can be used suitably as an electroconductive spring material used for electronic device components, and its manufacturing method.

As a result of intensive studies, the inventor has adjusted the 60 degree gloss G60 _RD of the surface measured in a direction parallel to the rolling direction to a predetermined range with a titanium copper foil having a foil thickness of 0.1 mm or less, It has been found that good solder wettability can be secured and high adhesion strength based on the so-called anchor effect can be exhibited.
Moreover, when manufacturing titanium copper foil, since the buffing is performed in the pickling process performed before the final cold rolling, the buffing marks can be formed on the surface of the material. Since the buffing marks remain without disappearing only by one-pass rolling of the final cold rolling, the surface gloss is hardly generated. Thus, it has been found that the glossiness is controlled by increasing the number of passes of the final cold rolling to realize the 60 ° glossiness G60 _RD in the predetermined range as described above.

Under such knowledge, the titanium copper foil of the present invention has a foil thickness of 0.1 mm or less, contains Ti in an amount of 1.5 to 4.5% by mass, the balance is made of copper and inevitable impurities, and the rolling direction. The 60 degree glossiness G60 _{RD of} the surface measured in the direction parallel to the surface is 200-600.

  Here, the titanium copper foil of the present invention preferably has a tensile strength in the direction parallel to the rolling direction of 1100 MPa or more.

  Moreover, here, the titanium copper foil of the present invention is composed of one or more of Ag, B, Co, Fe, Mg, Mn, Mo, Ni, P, Si, Cr and Zr in a total amount of 0 to 1.0 mass. % Content.

  The copper-stretched product of the present invention is provided with any of the above-described titanium copper foils.

The electronic device component of the present invention is provided with any of the above-described titanium copper foils.
The electronic device component is preferably an autofocus camera module.

  The autofocus camera module of the present invention includes a lens, a spring member that elastically urges the lens to an initial position in the optical axis direction, and an electromagnetic force that resists the urging force of the spring member to generate the lens. Electromagnetic drive means that can be driven in the axial direction is provided, and the spring member is any one of the above-described titanium copper foils.

According to the present invention, when the surface 60 degree gloss G60 _RD measured in a direction parallel to the rolling direction is set to 200 to 600, a titanium copper foil excellent in solderability and adhesion strength can be provided. . Such a titanium copper foil is particularly suitable for use as an electronic device component, in particular, an autofocus camera module.

It is sectional drawing which shows the autofocus camera module of one Embodiment of this invention. FIG. 2 is an exploded perspective view of the autofocus camera module of FIG. 1. It is sectional drawing which shows operation | movement of the auto-focus camera module of FIG. It is a graph which shows an example of the measurement result of the solder adhesion strength test in an example.

Hereinafter, embodiments of the present invention will be described in detail.
The titanium copper foil of one embodiment of the present invention has a foil thickness of 0.1 mm or less, contains Ti at 1.5 to 4.5% by mass, the balance is made of copper and unavoidable impurities, and the rolling direction. The 60 degree glossiness G60 _{RD of} the surface measured in the direction parallel to the surface is 200-600.

(Ti concentration)
In the titanium copper foil of the present invention, the Ti concentration is 1.5 to 4.5 mass%. Titanium copper increases strength and electrical conductivity by dissolving Ti in a Cu matrix by solution treatment and dispersing fine precipitates in the alloy by aging treatment.
If the Ti concentration is less than 1.5% by mass, precipitation of precipitates is insufficient and desired strength cannot be obtained. When the Ti concentration exceeds 4.5% by mass, workability deteriorates and the material is easily cracked during rolling. Considering the balance between strength and workability, the preferable Ti concentration is 2.9 to 3.5% by mass.

(Other additive elements)
In the titanium copper foil according to the present invention, the total amount of one or more of Ag, B, Co, Fe, Mg, Mn, Mo, Ni, P, Si, Cr and Zr is 0 to 1.0% by mass. By doing so, the strength can be further improved. The total content of these elements is 0, that is, these elements may not be included. The reason why the upper limit of the total content of these elements is set to 1.0% by mass is that if it exceeds 1.0% by mass, the workability deteriorates and the material is easily cracked during hot rolling.

(Tensile strength)
The tensile strength required for a titanium copper foil suitable as a conductive spring material for an autofocus camera module is 1100 MPa or more, preferably 1200 MPa or more, more preferably 1300 MPa or more. In the present invention, the tensile strength in a direction parallel to the rolling direction of the titanium copper foil is measured, and the tensile strength is measured in accordance with JIS Z2241 (metal material tensile test method).

(Glossiness)
The titanium copper foil of the present invention has a surface 60-degree glossiness G60 _RD measured in a direction parallel to the rolling direction of 200 to 600. As a result, the required excellent solder wettability can be ensured, and the adhesion strength by the solder can be increased, which is advantageous in the production of the autofocus camera module. The 60 degree gloss G60 _{LD on} the surface in a direction perpendicular to the rolling direction can also be in the same range as the direction parallel to the rolling direction.

More specifically, if the 60-degree glossiness G60 _RD is in the range of 200 to 600, the actual surface area is not too large, so that the solder tends to spread out, and there are moderate unevenness, so that the solder adhesion is improved. Because it is excellent.

In other words, if the 60 ° glossiness G60 _{RD in the} direction parallel to the rolling direction is less than 200, it takes a long time for solder wetting, and the solder wettability is poor. On the other hand, when the 60 degree gloss G60 _{RD in the} direction parallel to the rolling direction exceeds 600, the anchor effect cannot be obtained and the adhesion is poor.
From this viewpoint, the 60-degree glossiness G60 _RD of the surface in the direction parallel to the rolling direction is more preferably 300 to 580, and particularly preferably 450 to 550.

60 degree glossiness G60 _RD conforms to JIS Z8741 and uses, for example, various glossiness meters such as a gloss meter handy gloss meter PG-1 manufactured by Nippon Denshoku Industries Co., Ltd. in the direction parallel to the rolling direction. It can be determined by measuring the glossiness at an angle of 60 °.

(Thickness of copper foil)
The titanium copper foil of the present invention has a foil thickness of 0.1 mm or less, a typical embodiment has a foil thickness of 0.018 mm to 0.08 mm, and a more typical embodiment has a foil thickness of 0.02 mm. ~ 0.05 mm.

(Production method)
In order to manufacture the titanium copper foil as described above, first, raw materials such as electrolytic copper and Ti are melted in a melting furnace to obtain a molten metal having a desired composition. Then, this molten metal is cast into an ingot. In order to prevent oxidative wear of titanium, melting and casting are preferably performed in a vacuum or in an inert gas atmosphere. After that, typically for ingots, typically hot rolling, first cold rolling, solution treatment, second cold rolling, aging treatment, chemical polishing (pickling, mechanical polishing), third cold rolling, Rust prevention treatment is carried out in this order to finish a foil having a desired thickness and characteristics.

  The conditions for the hot rolling and the subsequent first cold rolling may be the conventional conditions used in the production of titanium copper, and there are no special requirements here. The solution treatment may be performed under conventional conditions, but can be performed at a temperature of 700 to 1000 ° C. for 5 seconds to 30 minutes, for example.

  In order to obtain the above-mentioned strength, it is preferable to set the reduction ratio of the second cold rolling to 55% or more. More preferably, it is 60% or more, More preferably, it is 65% or more. When the rolling reduction is less than 55%, it becomes difficult to obtain a tensile strength of 1100 MPa or more. The upper limit of the rolling reduction is not particularly defined from the viewpoint of the strength intended by the present invention, but industrially does not exceed 99.8%.

  The heating temperature for the aging treatment is 200 to 300 ° C., and the heating time is 2 to 20 hours. When the heating temperature is less than 200 ° C., it becomes difficult to obtain a tensile strength of 1100 MPa or more. If it exceeds 300 ° C., an oxide film or an oxygen-enriched layer is excessively generated. When the heating time is less than 2 hours or exceeds 20 hours, it becomes difficult to obtain a tensile strength of 1100 MPa or more.

  After the heat treatment, chemical polishing and mechanical polishing of the surface are performed for the purpose of removing the oxide film or oxide layer formed on the surface. In chemical polishing, in order to remove the oxide film of titanium copper foil that is stable against acid, a chemical polishing solution with extremely high corrosive power such as a solution in which hydrogen peroxide is mixed with hydrofluoric acid or sulfuric acid is used, as in the prior art. Can be used. Chemical polishing and mechanical polishing can be performed under the same conditions as before.

  Due to the buffing by mechanical polishing, polishing eyes are formed on the surface of the material, which lowers the glossiness of the product and causes deterioration of solder wettability and solder adhesion strength. For this, it is effective to increase the glossiness of the titanium-copper foil by increasing the number of passes of the rolling after reaching the predetermined plate thickness in the subsequent final cold rolling. In other words, in the rolling of only one pass, the buffing polishing eyes do not disappear and the surface glossiness cannot be effectively increased. On the other hand, if the number of passes in this rolling is increased too much, the glossiness becomes too high, the glossiness exceeds 600, and the solder adhesion deteriorates.

Therefore, the number of mechanical polishing rolling passes is preferably 8 to 24 passes, for example, in the case of rolling from a thickness of 0.14 mm to 40 μm, and more preferably 12 to 24 passes, especially 18 to 22 passes. It is even more preferable to do this.
It is effective to perform the rolling with such a number of passes after the plate thickness reaches 0.14 mm.

  Further, in the final cold rolling, for example, by rolling with a hard and smooth roll such as a chromium plating roll having a chromium plating on the surface, the surface of the roll is transferred to the material, and smooth rolling can be performed.

Thereafter, a rust prevention treatment can be performed. This rust prevention treatment can be performed under the same conditions as before, and an aqueous solution of benzotriazole (BTA) or the like can be used.
Note that low temperature annealing may be performed after the second cold rolling.

(Use)
The titanium copper foil of the present invention can be used for various applications, and in particular, it can be suitably used as a material for electronic equipment parts such as switches, connectors, jacks, terminals, relays, etc. It can be suitably used as a conductive spring material used for electronic device parts such as a focus camera module.

The autofocus camera module is, for example, a lens, a spring member that elastically biases the lens to an initial position in the optical axis direction, and an electromagnetic force that resists the biasing force of the spring member to generate the lens in the optical axis direction. It is possible to provide electromagnetic drive means that can be driven. And here, the said spring member can be made into the titanium copper foil of this invention.
For example, the electromagnetic driving means includes a U-shaped cylindrical yoke, a coil accommodated inside the inner peripheral wall of the yoke, and a magnet surrounding the coil and accommodated inside the outer peripheral wall of the yoke. Can do.

  1 is a sectional view showing an example of an autofocus camera module according to the present invention, FIG. 2 is an exploded perspective view of the autofocus camera module of FIG. 1, and FIG. 3 is a focus camera of FIG. It is sectional drawing which shows operation | movement of a module.

  The autofocus camera module 1 includes a U-shaped cylindrical yoke 2, a magnet 4 attached to the outer wall of the yoke 2, a carrier 5 having a lens 3 at a central position, a coil 6 attached to the carrier 5, a yoke 2, a frame 8 that supports the base 7, two spring members 9 a and 9 b that support the carrier 5 at the top and bottom, and two caps 10 a and 10 b that cover these top and bottom. Yes. The two spring members 9a and 9b are the same product, support the carrier 5 sandwiched from above and below in the same positional relationship, and function as a power feeding path to the coil 6. By applying a current to the coil 6, the carrier 5 moves upward. In the present specification, the terms “upper” and “lower” are used as appropriate. The upper and lower parts in FIG.

  The yoke 2 is a magnetic material such as soft iron, has a U-shaped cylindrical shape with a closed upper surface portion, and has a cylindrical inner wall 2a and an outer wall 2b. A ring-shaped magnet 4 is attached (adhered) to the inner surface of the U-shaped outer wall 2b.

  The carrier 5 is a molded product made of a synthetic resin or the like having a cylindrical structure having a bottom surface portion, supports a lens at a central position, and is mounted with a pre-formed coil 6 bonded to the outside of the bottom surface. The yoke 2 is fitted and incorporated in the inner peripheral portion of the base 7 of the rectangular upper resin molded product, and the entire yoke 2 is fixed by the frame 8 of the resin molded product.

  The spring members 9a and 9b are both fixed with the outermost peripheral part sandwiched between the frame 8 and the base 7, respectively, and the notch groove part for each inner peripheral part 120 ° is fitted to the carrier 5 and fixed by thermal caulking or the like. Is done.

  The spring member 9b and the base 7 and the spring member 9a and the frame 8 are fixed by adhesion, heat caulking, or the like. Further, the cap 10b is attached to the bottom surface of the base 7, and the cap 10a is attached to the upper portion of the frame 8, respectively. 9b is sandwiched between the base 7 and the cap 10b, and the spring member 9a is sandwiched and fixed between the frame 8 and the cap 10a.

  One lead wire of the coil 6 extends upward through a groove provided on the inner peripheral surface of the carrier 5 and is soldered to the spring member 9a. The other lead wire extends downward through a groove provided on the bottom surface of the carrier 5 and is soldered to the spring member 9b.

  The spring members 9a and 9b are titanium copper foil leaf springs according to the present invention. It has springiness and elastically biases the lens 3 to the initial position in the optical axis direction. At the same time, it acts as a power feeding path to the coil 6. One part of the outer peripheral part of the spring members 9a and 9b is projected outward to function as a power supply terminal.

  The cylindrical magnet 4 is magnetized in the radial direction, forms a magnetic path with the inner wall 2a, the upper surface portion and the outer wall 2b of the U-shaped yoke 2 as a path, and a gap between the magnet 4 and the inner wall 2a. The coil 6 is arranged.

  Since the spring members 9a and 9b have the same shape and are attached with the same positional relationship as shown in FIGS. 1 and 2, it is possible to suppress the axial displacement when the carrier 5 moves upward. Since the coil 6 is manufactured by pressure molding after winding, the accuracy of the finished outer diameter is improved, and the coil 6 can be easily arranged in a predetermined narrow gap. Since the carrier 5 hits the base 7 at the lowermost position and hits the yoke 2 at the uppermost position, the carrier 5 is provided with an abutting mechanism in the vertical direction, thereby preventing the carrier 5 from falling off.

  FIG. 3 shows a cross-sectional view when a current is applied to the coil 6 to move the carrier 5 having the lens 3 for autofocus upward. When power is applied to the power supply terminals of the spring members 9a and 9b, a current flows through the coil 6 and an upward electromagnetic force acts on the carrier 5. On the other hand, the restoring force of the two connected spring members 9a and 9b acts downward on the carrier 5. Accordingly, the upward moving distance of the carrier 5 is a position where the electromagnetic force and the restoring force are balanced. Thereby, the amount of movement of the carrier 5 can be determined by the amount of current applied to the coil 6.

  Since the upper spring member 9 a supports the upper surface of the carrier 5 and the lower spring member 9 b supports the lower surface of the carrier 5, the restoring force acts equally downward on the upper surface and lower surface of the carrier 5, so that the lens 3 Axis misalignment can be kept small.

  Therefore, when the carrier 5 is moved upward, a guide by ribs or the like is not necessary and used. Since there is no sliding friction due to the guide, the movement amount of the carrier 5 is governed purely by the balance between the electromagnetic force and the restoring force, and the lens 3 can be moved smoothly and accurately. This achieves autofocus with little lens blur.

  Although the magnet 4 has been described as having a cylindrical shape, the present invention is not limited to this, and the magnet 4 may be divided into three or four parts and magnetized in the radial direction, and this may be attached to the inner surface of the outer wall 2b of the yoke 2 and fixed.

  Next, the titanium copper foil of the present invention was prototyped and its effect was confirmed, and will be described below. However, the description here is for illustrative purposes only and is not intended to be limiting.

<Production conditions>
The prototype was manufactured as follows. First, 2.5 kg of electrolytic copper was melted in a vacuum melting furnace, and Ti was added so as to obtain a predetermined Ti concentration. This molten metal was cast into a cast iron mold to produce an ingot having a thickness of 30 mm, a width of 60 mm, and a length of 120 mm.
This ingot was heated at 950 ° C. for 3 hours and subjected to hot rolling for rolling to a thickness of 10 mm. Grinding was performed by removing the oxidized scale produced by hot rolling with a grinder. The thickness after this grinding was 9 mm. Next, the first cold rolling was carried out and rolled to a thickness of 1 mm. In the subsequent solution treatment, the sample was placed in an electric furnace heated to 800 ° C. and held for 5 minutes, and then the sample was placed in a water bath and rapidly cooled. Then, second cold rolling was performed, and rolling was performed to a foil thickness of 0.04 mm at a reduction rate of 96%. After that, it was heated at 280 ° C. for 10 hours as an aging treatment. Here, this temperature of the aging treatment was selected so that the tensile strength after aging was maximized. After aging treatment, chemical polishing (pickling, mechanical polishing) and final cold rolling were performed. In chemical polishing, sulfuric acid and hydrogen peroxide were used as the chemical polishing liquid. In the final cold rolling, a chromium plating roll was used, and as shown in Table 1, the number of rolling passes after the plate thickness reached 0.14 mm was changed.
The following evaluations were performed on the prototype manufactured as described above.

<Glossiness>
The 60 degree gloss G60 _RD in the rolling parallel direction on the surface of the prototype was measured using a gloss meter handy gloss meter PG-1 manufactured by Nippon Denshoku Industries Co., Ltd. based on JIS Z8741.

<Solder wettability and solder adhesion>
A soldering test was performed using Senju Metal Pb-free solder M705 solder. In the evaluation of solder wettability, soldering was performed by a solder checker (SAT-2000 manufactured by Reska Co., Ltd.) according to JIS C60068-2-54 in the same procedure as the meniscograph method, and the appearance of the soldered portion was observed. The measurement conditions are as follows. The sample was degreased using acetone as a pretreatment. Next, it pickled using 10 vol% sulfuric acid aqueous solution. The test temperature of the solder was 245 ± 5 ° C. The flux is not particularly specified, but GX5 manufactured by Asahi Chemical Laboratory was used. The immersion depth was 2 mm, the immersion time was 10 seconds, the immersion speed was 25 mm / second, and the sample width was 10 mm. The evaluation criteria are a visual observation with a 20-fold stereo microscope, and the case where the entire surface of the soldering part is covered with solder is judged as good (◯), and part or the whole surface of the soldering part is not covered with solder. The thing was made into bad (x). In the evaluation of solder adhesion, a peel strength of 1N or more was judged as ◯, and a peel strength of less than 1N was judged as x. This peel strength is obtained by using a titanium copper foil having a plating layer and a pure copper foil (alloy number C1100 defined in JIS H3100-2012, foil thickness 0.02 mm to 0.05 mm) with lead-free solder (Sn-3.0 mass% Ag). -0.5% by mass Cu). The titanium copper foil has a strip shape with a width of 15 mm and a length of 200 mm, the pure copper foil has a strip shape with a width of 20 mm and a length of 200 mm, and has a lead-free solder (diameter: 0. 4 ± 0.02 mm and length 120 ± 1 mm) are arranged so as to be within the above-mentioned area, and then the joining temperature is 245 ° C. ± 5 ° C. After joining, the adhesion strength is measured by performing a 180 ° peeling test at a speed of 100 mm / min. The average value of the load (N) in the section of 40 mm from 30 mm to 70 mm of the peeling displacement is defined as the adhesion strength. An example of the measurement result in the solder adhesion strength test is shown in FIG.
These results are shown in Table 1.

As shown in Table 1, in each of Invention Examples 1 to 22 in which the number of passes from a predetermined plate thickness in the final cold rolling is set within a predetermined range, the 60 ° gloss G60 _RD is within a preferable range, As a result, good solder wetting spread and solder adhesion were obtained.
On the other hand, in Comparative Examples 1 and 2, the 60 ° gloss G60 _RD became too high due to the excessive number of passes of the final cold rolling, and the solder adhesion deteriorated. In Comparative Examples 3 and 4, since the number of passes of the final cold rolling was small, the 60-degree glossiness G60 _RD was lowered and the solder wettability was deteriorated. In Comparative Example 5, the tensile strength decreased due to the Ti concentration being too low. In Comparative Examples 6 and 7, since the concentration of Ti or the subcomponent was too high, cracks were generated by rolling and a prototype could not be produced.

  As described above, according to the present invention, it has been found that the solder wettability and the solder adhesion strength can be effectively improved with a thin titanium copper foil having a foil thickness of 0.1 μm or less.

DESCRIPTION OF SYMBOLS 1 Autofocus camera module 2 Yoke 3 Lens 4 Magnet 5 Carrier 6 Coil 7 Base 8 Frame 9a Upper spring member 9b Lower spring member 10a, 10b Cap

Claims (7)

The foil thickness is 0.1 mm or less, Ti is contained in an amount of 1.5 to 4.5% by mass, the balance is made of copper and inevitable impurities, and the surface has a 60 degree glossiness measured in a direction parallel to the rolling direction. Titanium copper foil whose G60 _RD is 200-600.   The titanium copper foil according to claim 1, wherein the tensile strength in a direction parallel to the rolling direction is 1100 MPa or more.   3. The titanium according to claim 1, comprising at least one of Ag, B, Co, Fe, Mg, Mn, Mo, Ni, P, Si, Cr and Zr in a total amount of 0 to 1.0 mass%. Copper foil.   The copper-stretched article provided with the titanium copper foil as described in any one of Claims 1-3.   The electronic device component provided with the titanium copper foil as described in any one of Claims 1-3.   The electronic device component according to claim 5, wherein the electronic device component is an autofocus camera module.   A lens, a spring member that elastically biases the lens to an initial position in the optical axis direction, and an electromagnetic drive means that can drive the lens in the optical axis direction by generating an electromagnetic force that resists the biasing force of the spring member An autofocus camera module, wherein the spring member is the titanium copper foil according to any one of claims 1 to 3.