JP6325353B2 - Acid oil-in-water emulsified seasoning - Google Patents

Acid oil-in-water emulsified seasoning Download PDF

Info

Publication number
JP6325353B2
JP6325353B2 JP2014113785A JP2014113785A JP6325353B2 JP 6325353 B2 JP6325353 B2 JP 6325353B2 JP 2014113785 A JP2014113785 A JP 2014113785A JP 2014113785 A JP2014113785 A JP 2014113785A JP 6325353 B2 JP6325353 B2 JP 6325353B2
Authority
JP
Japan
Prior art keywords
water emulsified
emulsified seasoning
oil
acidic oil
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2014113785A
Other languages
Japanese (ja)
Other versions
JP2015226512A (en
Inventor
児玉 大介
大介 児玉
徹 梅津
徹 梅津
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QP Corp
Original Assignee
QP Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QP Corp filed Critical QP Corp
Priority to JP2014113785A priority Critical patent/JP6325353B2/en
Publication of JP2015226512A publication Critical patent/JP2015226512A/en
Application granted granted Critical
Publication of JP6325353B2 publication Critical patent/JP6325353B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Seasonings (AREA)

Description

本発明は、焼成、熱風乾燥、及び油ちょう等の加熱を施しても酸性水中油型乳化調味料の酸味が維持され,調味料全体の味のバランスも維持された、酸性水中油型乳化調味料およびその用途に関する。 The present invention is an acidic oil-in-water emulsified seasoning in which the acidity of the acid oil-in-water emulsified seasoning is maintained even when heating such as baking, hot air drying, and oil-boiled, and the balance of the taste of the whole seasoning is maintained. The fee and its use.

酸性水中油型乳化調味料とは、pHを4.6以下にすることで常温流通を可能にした酸性乳化食品であり、代表的なものとして、マヨネーズ様食品等の半固体状ドレッシング、乳化液状ドレッシング等が挙げられる。 An acidic oil-in-water type emulsified seasoning is an acidic emulsified food that can be distributed at room temperature by setting the pH to 4.6 or less. Typical examples include semi-solid dressings such as mayonnaise-like foods, and emulsified liquids. Dressing etc. are mentioned.

マヨネーズ等の酸性水中油型乳化調味料は、サラダにかける、または野菜と和える等の用途が一般的であるが、近年その用途が拡大している。具体的には、パン等の焼成食品、せんべい等の米菓、ポテトチップス等のスナック菓子、及びチキンカツ等のフライ食品等、従来マヨネーズを使用しなかった業態においてマヨネーズ味を付した加熱食品の開発が進んでいる。 The use of acidic oil-in-water emulsified seasonings such as mayonnaise is generally applied to salads or mixed with vegetables, but in recent years its use has expanded. Specifically, the development of heated foods with a mayonnaise flavor, such as baked foods such as bread, rice crackers such as rice crackers, snacks such as potato chips, and fried foods such as chicken cutlet, etc. Progressing.

しかしながら、パンの製造工程において、マヨネーズを添加した後、焼成を行ったり、米菓の製造工程において、マヨネーズをからめた後、熱風乾燥を行ったり、フライ食品の製造工程において、バッター液としてマヨネーズを付着させた後、油ちょうを行うと、加熱によってマヨネーズの酸味が消失し、調味料全体の味のバランスが失われてしまうという問題があった。 However, in the bread manufacturing process, mayonnaise is added and then baked, in the rice cracker manufacturing process, after garnishing mayonnaise, hot air drying is performed, and in the manufacturing process of fried food, mayonnaise is used as batter liquid. When oiling is performed after adhering, there is a problem that the sourness of mayonnaise disappears due to heating, and the balance of the taste of the whole seasoning is lost.

加熱による酸性水中油型乳化調味料の物性変化を抑制する技術としては、従来からホスフォリパーゼA処理卵黄を乳化剤として使用する方法(特許文献1)、ホエー蛋白を乳化剤として使用する方法(特許文献2)等が提案されている。 As techniques for suppressing changes in physical properties of acidic oil-in-water emulsified seasonings due to heating, a conventional method using phospholipase A-treated egg yolk as an emulsifier (Patent Document 1), a method using whey protein as an emulsifier (Patent Document) 2) etc. have been proposed.

しかしながら、これらの耐熱性を有した酸性水中油型乳化調味料は、一定条件下で加熱処理を施した際に、その乳化状態が破壊されることなく、乳化安定性は有しているものの、当該酸性水中油型乳化調味料に焼成、熱風乾燥、及び油ちょう等の加熱を施した際に、酸性水中油型乳化調味料の酸味が消失し、調味料全体の味のバランスが失われてしまうという問題は解決されていなかった。 However, these heat-resistant acidic oil-in-water type emulsified seasonings, when subjected to heat treatment under certain conditions, the emulsified state is not destroyed, but the emulsion stability is, When the acidic oil-in-water emulsified seasoning is heated, such as baking, hot-air drying, and oil frying, the acidity of the acid oil-in-water emulsified seasoning disappears and the balance of the taste of the whole seasoning is lost. The problem of end was not solved.

一方、加熱食品にマヨネーズ味を付す方法としては、米菓や、パン、フライ食品の製造工程において、熱風乾燥や油ちょう等を行った後、粉末マヨネーズ(特許文献3)を振りかける方法が知られている。しかしながら、これらの方法でマヨネーズ味を付した加熱食品は、製造工程が増え、コスト面で満足できるものではなかった。 On the other hand, as a method of adding a mayonnaise flavor to a heated food, a method of sprinkling powdered mayonnaise (Patent Document 3) after hot air drying or oil frying is known in the manufacturing process of rice crackers, bread and fried foods. ing. However, heated foods with a mayonnaise flavor by these methods are not satisfactory in terms of cost due to an increased number of manufacturing processes.

特開昭51−84785号公報Japanese Patent Laid-Open No. 51-84785 特開2004−180577号公報JP 2004-180577 A 特開平8−56608号公報JP-A-8-56608

そこで、本発明の目的は、酸性水中油型乳化調味料において、焼成、熱風乾燥、及び油ちょう等の加熱を施しても酸性水中油型乳化調味料の酸味が維持され,調味料全体の味のバランスも維持された、酸性水中油型乳化調味料およびその用途を提供するものである。 Therefore, the object of the present invention is to maintain the acidity of the acidic oil-in-water emulsified seasoning in the acidic oil-in-water emulsified seasoning even when subjected to heating such as baking, hot-air drying, and oil frying. The oil-in-water emulsified seasoning and its use are also maintained.

本発明者等は、上記目的を達成すべく酸性水中油型乳化調味料に使用されている様々な配合原料、及び製造工程について鋭意研究を重ねた。その結果、酢酸及び/又はその塩(ただし、カルシウム塩を除く)を酢酸換算で1%以上5%以下、食塩を3%以上15%以下、卵黄を含有した酸性水中油型乳化調味料であって、特定の有機酸及び/又はその塩とカルシウム塩とを配合するならば、意外にも焼成、熱風乾燥、及び油ちょう等の加熱を施しても酸性水中油型乳化調味料の酸味が維持され,調味料全体の味のバランスも維持されることを見出し、本発明を完成するに至った。 In order to achieve the above object, the present inventors have conducted extensive research on various blended raw materials used in acidic oil-in-water emulsion seasonings and production processes. As a result, it is an acidic oil-in-water emulsified seasoning containing acetic acid and / or a salt thereof (excluding calcium salt) in terms of acetic acid in an amount of 1% to 5%, salt in an amount of 3% to 15%, and egg yolk. If a specific organic acid and / or a salt thereof and a calcium salt are blended, the acidity of the acidic oil-in-water emulsified seasoning can be maintained even when subjected to heating such as baking, hot-air drying, and oil frying. As a result, the inventors found that the balance of the taste of the whole seasoning can be maintained, and completed the present invention.

すなわち、本発明は、
(1)酢酸及び/又はその塩(ただし、カルシウム塩を除く)を酢酸換算で1%以上5%以下、食塩を3%以上15%以下、卵黄を含有した酸性水中油型乳化調味料であって、
乳酸及び/又はその塩(ただし、カルシウム塩を除く)を乳酸換算で0.5%以上4.5%以下、並びにカルシウム塩をカルシウム換算で0.01%以上0.6%以下含有する、
酸性水中油型乳化調味料、
(2)(1)記載の乳化調味料において、
カルシウム塩が、塩化カルシウム、乳酸カルシウム又は酢酸カルシウムから選択された1種以上である、
酸性水中油型乳化調味料、
(3)(1)又は(2)に記載の酸性水中油型乳化調味料を用いた加熱固形状食品、
(4)(1)又は(2)に記載の酸性水中油型乳化調味料を用いた焼成食品、
(5)(1)又は(2)に記載の酸性水中油型乳化調味料を用いた米菓、
(6)(1)又は(2)に記載の酸性水中油型乳化調味料を用いたパン、
(7)(1)又は(2)に記載の酸性水中油型乳化調味料を加熱前の加熱固形状食品表面に付着させた後に加熱する、加熱固形状食品の製造方法、である。
That is, the present invention
(1) An acidic oil-in-water emulsified seasoning containing acetic acid and / or a salt thereof (excluding calcium salt) in terms of acetic acid in an amount of 1% to 5%, salt in an amount of 3% to 15%, and egg yolk. And
Containing lactic acid and / or a salt thereof (excluding calcium salt) in an amount of 0.5% to 4.5% in terms of lactic acid, and a calcium salt in an amount of 0.01% to 0.6% in terms of calcium;
Acidic oil-in-water emulsified seasonings,
(2) In the emulsified seasoning according to (1),
The calcium salt is at least one selected from calcium chloride, calcium lactate or calcium acetate,
Acidic oil-in-water emulsified seasonings,
(3) A heated solid food using the acidic oil-in-water emulsified seasoning according to (1) or (2),
(4) A baked food using the acidic oil-in-water emulsified seasoning according to (1) or (2),
(5) Rice crackers using the acidic oil-in-water emulsified seasoning according to (1) or (2),
(6) Bread using the acidic oil-in-water emulsified seasoning according to (1) or (2),
(7) A method for producing a heated solid food, wherein the acidic oil-in-water emulsified seasoning according to (1) or (2) is heated after adhering to the surface of the heated solid food before heating.

本発明によれば、焼成、熱風乾燥、及び油ちょう等の加熱を施しても酸味が維持され,調味料全体の味のバランスも維持された酸性水中油型乳化調味料を提供することが出来る。したがって、酸性水中油型乳化調味料を従来使用しにくかった加熱食品に使い易くなり、酸性水中油型乳化調味料の更なる需要拡大が期待できる。 According to the present invention, it is possible to provide an acidic oil-in-water emulsified seasoning in which acidity is maintained even when heating such as baking, hot-air drying, and oil cooking is performed, and the balance of the taste of the entire seasoning is maintained. . Therefore, it becomes easy to use the acidic oil-in-water type emulsified seasoning for the heated food that has been difficult to use conventionally, and further expansion of demand for the acidic oil-in-water type emulsified seasoning can be expected.

以下、本発明を詳細に説明する。なお、本発明において「%」は「質量%」を意味する。 Hereinafter, the present invention will be described in detail. In the present invention, “%” means “mass%”.

<本発明の特徴>
本発明は、上記酸性水中油型乳化調味料の中でも、カルシウム塩を除く特定量の酢酸及び/又はその塩、食塩並びに卵黄を含有した酸性水中油型乳化調味料において、カルシウム塩を除く特定量の乳酸及び/又はその塩、並びにカルシウム塩を含有することを特徴としており、これにより、焼成、熱風乾燥、及び油ちょう等の加熱を施してもマヨネーズ等の酸性水中油型乳化調味料と同様の酸味が維持され、調味料全体の味のバランスも維持された酸性水中油型乳化調味料となる。
<Features of the present invention>
In the acidic oil-in-water emulsified seasoning described above, the acidic oil-in-water emulsified seasoning containing a specific amount of acetic acid and / or its salt, salt and egg yolk excluding the calcium salt is a specific amount excluding the calcium salt. Of lactic acid and / or a salt thereof, and a calcium salt, which is similar to an acidic oil-in-water emulsified seasoning such as mayonnaise even when subjected to heating such as baking, hot-air drying, and oil-blowing. Thus, an acidic oil-in-water emulsified seasoning is maintained in which the acidity is maintained and the balance of the taste of the entire seasoning is maintained.

<酸性水中油型乳化調味料>
本発明において酸性水中油型乳化調味料とは、食用油脂が油滴として水相中に略均一に分散して水中油型の乳化状態が維持され、常温流通を可能ならしめるためにpHを4.6以下に調整された酸性乳化食品である。
<Acid oil-in-water emulsified seasoning>
In the present invention, the acidic oil-in-water type emulsified seasoning means that edible fats and oils are dispersed almost uniformly in the water phase as oil droplets to maintain an oil-in-water type emulsified state, and a pH of 4 is set to enable normal temperature circulation. It is an acidic emulsified food adjusted to .6 or less.

<酢酸及び/又はその塩、並びにその含有量>
本発明の酸性水中油型乳化調味料中の酢酸及び/又はその塩としては、カルシウム塩を除く、例えば、酢酸、酢酸ナトリウム、食酢、醸造酢、合成酢等が挙げられる。本発明の酸性水中油型乳化調味料中の酢酸及び/又はその塩の含有量は、加熱しても酸味が維持され,調味料全体の味のバランスが維持される程度であればよく、酢酸換算で1%以上5%以下であり、さらに1.5%以上4%以下であるとよい。
<Acetic acid and / or salt thereof, and content thereof>
Examples of acetic acid and / or a salt thereof in the acidic oil-in-water emulsified seasoning of the present invention include, for example, acetic acid, sodium acetate, vinegar, brewed vinegar, and synthetic vinegar. The content of acetic acid and / or a salt thereof in the acidic oil-in-water emulsified seasoning of the present invention may be such that the acidity is maintained even when heated, and the balance of the taste of the entire seasoning is maintained. It is preferably 1% or more and 5% or less in terms of conversion, and more preferably 1.5% or more and 4% or less.

<食塩の含有量>
本発明の酸性水中油型乳化調味料中の食塩の含有量は、加熱しても塩味が得られ、調味料全体の味のバランスが維持される程度であればよく、3%以上15%以下であり、さらに5%以上10%以下であるとよい。
<Content of salt>
The salt content in the acidic oil-in-water emulsified seasoning of the present invention is not limited as long as the salty taste is obtained even when heated and the balance of the taste of the whole seasoning is maintained. Furthermore, it is good that it is 5% or more and 10% or less.

<卵黄>
本発明の酸性水中油型乳化調味料は、卵黄を配合したものである。本発明に用いる卵黄は、マヨネーズ等の乳化調味料に用いられるものであればいずれのものでも良い。例えば、鶏卵を割卵し卵白と分離させた生卵黄あるいは卵黄液、前記生卵黄あるいは卵黄液にスプレードライやフリーズドライ等の乾燥処理を施した乾燥卵黄、前記生卵黄あるいは卵黄液に砂糖を加えた加糖卵黄、前記生卵黄あるいは卵黄液や加糖卵黄等を凍結した凍結卵黄、その他、脱糖処理、殺菌処理、ホスフォリパーゼAやタンパク分解酵素処理等を施した酵素処理、脱コレステロール処理等を施した処理卵黄等が挙げられる。また、本発明においては、本発明の効果を損なわない範囲で卵白を含んだ例えば、全卵や上述した処理等を施したもの等も用いることができる。この場合、全卵の卵黄部分が本発明の卵黄に相当する。
<Yellow>
The acidic oil-in-water emulsified seasoning of the present invention contains egg yolk. The egg yolk used in the present invention may be any one as long as it is used in an emulsified seasoning such as mayonnaise. For example, raw egg yolk or egg yolk liquid obtained by dividing chicken eggs and separated from egg white, dried egg yolk obtained by subjecting the raw egg yolk or egg yolk liquid to a drying treatment such as spray drying or freeze drying, and sugar added to the raw egg yolk or egg yolk liquid Frozen egg yolk, frozen egg yolk frozen from the above-mentioned raw egg yolk or egg yolk liquid or sweetened egg yolk, etc., and other enzyme treatments such as deglycosylation treatment, sterilization treatment, phospholipase A or proteolytic enzyme treatment, decholesterolization treatment, etc. Examples include treated egg yolk. Further, in the present invention, for example, whole eggs or those subjected to the above-described treatment or the like containing egg white can be used as long as the effects of the present invention are not impaired. In this case, the yolk portion of the whole egg corresponds to the yolk of the present invention.

<卵黄の含有量>
本発明の酸性水中油型乳化調味料中の卵黄の含有量は生卵黄換算で2%以上40%以下であるとよく、さらに4%以上20%以下であるとよい。卵黄の含有量が前記数値範囲であることにより、加熱しても酸性水中油型乳化調味料中の酸味消失が感じられにくく、調味料全体の味のバランスが失われにくくなる。また、卵黄の含有量を前記範囲よりも多くしたとしても、含有量に応じた効果が期待し難く経済的でない。
<Content of egg yolk>
The content of egg yolk in the acidic oil-in-water emulsified seasoning of the present invention is preferably 2% or more and 40% or less in terms of raw egg yolk, and more preferably 4% or more and 20% or less. When the content of egg yolk is in the above numerical range, even when heated, the sourness disappearance in the acidic oil-in-water emulsified seasoning is hardly felt, and the balance of the taste of the whole seasoning is hardly lost. Further, even if the content of egg yolk is made larger than the above range, it is difficult to expect an effect according to the content, which is not economical.

<ホスフォリパーゼA処理卵黄>
本発明で用いる卵黄は、その一部または全部をホスフォリパーゼA処理卵黄に置換することで、酸性水中油型乳化調味料に焼成、熱風乾燥、及び油ちょう等の加熱を施した際の、酸性水中油型乳化調味料の酸味が消失し難くなることができる。ホスフォリパーゼA処理卵黄とは、卵黄の主成分である卵黄リポ蛋白質(卵黄リン脂質、卵黄油およびコレステロール等の卵黄脂質と卵黄蛋白の複合体)の構成リン脂質にリン脂質分解酵素であるホスフォリパーゼAあるいはホスフォリパーゼAを作用させてリン脂質の1位あるいは2位の脂肪酸残基を加水分解してリゾリン脂質とした卵黄をいう。
<Phospholipase A treated egg yolk>
The egg yolk used in the present invention is replaced with a phospholipase A-treated egg yolk, when the acidic oil-in-water emulsified seasoning is baked, dried with hot air, and heated with oil, etc. The acidity of the acidic oil-in-water emulsified seasoning can be difficult to disappear. Phospholipase A-treated egg yolk is a phospholipid-degrading enzyme that is a phospholipid-degrading enzyme of the yolk lipoprotein (a complex of egg yolk phospholipid, egg yolk oil and egg yolk lipid and egg yolk protein) that is the main component of egg yolk. Foripaze a 1 or by the action of phospholipase a 2 at the 1-position or 2-position of the fatty acid residues of phospholipids hydrolyzing refers to the yolk and lysophospholipids by.

<ホスフォリパーゼA処理卵黄の加水分解の程度>
ホスフォリパーゼA処理卵黄の前記酵素処理による加水分解の程度としては、リゾホスファチジルコリンとホスファチジルコリンの合計量に対するリゾホスファチジルコリンの割合がイアトロスキャン法(TLC−FID法)で分析した場合、その値(本発明の「リゾ化率」)が、10%以上80%以下が好ましく、30%以上70%以下がより好ましい。リゾ化率が前記範囲内であることにより、加熱しても酸性水中油型乳化調味料中の酸味消失が感じられにくく、酸性水中油型乳化調味料全体の味のバランスが失われにくくなる。
<Degree of hydrolysis of phospholipase A-treated egg yolk>
As the degree of hydrolysis of the phospholipase A-treated egg yolk by the enzyme treatment, when the ratio of lysophosphatidylcholine to the total amount of lysophosphatidylcholine and phosphatidylcholine was analyzed by the iatroscan method (TLC-FID method), the value (this) The “resolubilization rate” of the invention is preferably from 10% to 80%, more preferably from 30% to 70%. When the lysification rate is within the above range, even when heated, the sourness disappearance in the acidic oil-in-water emulsified seasoning is hardly felt, and the taste balance of the entire acidic oil-in-water emulsified seasoning is less likely to be lost.

<ホスフォリパーゼA処理卵黄の含有量>
ホスフォリパーゼA処理卵黄の含有量は生卵黄換算で2%以上20%以下であるとよく、さらに5%以上15%以下であるとよい。なお、前述のホスフォリパーゼA処理卵黄を含有する場合、卵黄の含有量(生卵黄換算)とは、ホスフォリパーゼA処理卵黄の含有量(生卵黄換算)を合算した数値のことをいう。ホスフォリパーゼA処理卵黄の含有量が前記範囲内であることにより、加熱しても酸性水中油型乳化調味料中の酸味消失が感じられにくくすることができ、酸性水中油型乳化調味料全体の味のバランスが失われにくくすることができる。また、ホスフォリパーゼA処理卵黄の含有量を前記数値範囲よりも多くしたとしても、含有量に応じた効果が期待し難く経済的でない。なお、卵白を含有した全卵等をホスフォリパーゼAで処理したホスフォリパーゼA処理全卵等を用いた場合は、当該酵素処理された卵黄部分がホスフォリパーゼA処理卵黄に相当する。
<Content of phospholipase A-treated egg yolk>
The content of phospholipase A-treated egg yolk is preferably 2% or more and 20% or less in terms of raw egg yolk, and more preferably 5% or more and 15% or less. In addition, when it contains the above-mentioned phospholipase A processing egg yolk, content of egg yolk (raw egg yolk conversion) means the numerical value which added together content (raw egg yolk conversion) of phospholipase A processing egg yolk. The content of the phospholipase A-treated egg yolk is within the above range, so that the disappearance of sourness in the acidic oil-in-water emulsified seasoning can be made difficult to feel even when heated, and the entire acidic oil-in-water emulsified seasoning The balance of taste can be hard to lose. Further, even if the content of phospholipase A-treated egg yolk is increased from the above numerical range, it is difficult to expect an effect according to the content, and this is not economical. When a phospholipase A-treated whole egg or the like obtained by treating whole egg containing egg white with phospholipase A is used, the enzyme-treated egg yolk portion corresponds to phospholipase A-treated egg yolk.

<乳酸及び/又はその塩、並びにその含有量>
本発明の酸性水中油型乳化調味料中の乳酸及び/又はその塩としては、カルシウム塩を除き、例えば乳酸、発酵乳酸、乳酸ナトリウム、乳酸カリウム、乳酸鉄等が挙げられる。本発明の酸性水中油型乳化調味料中の乳酸及び/又はその塩の含有量は、乳酸換算で0.5%以上4.5%以下であり、さらに1%以上4%以下であるとよい。
酸性水中油型乳化調味料の乳酸及び/又はその塩の含有量が前記数値範囲より少ないと、たとえ前述の酢酸及び/又はその塩、食塩、卵黄、後述のカルシウム塩を特定量含有したとしても、酸性水中油型乳化調味料に焼成、熱風乾燥、及び油ちょう等の加熱を施した際、酸性水中油型乳化調味料の酸味が消失し、調味料全体の味のバランスが失われてしまう。一方、酸性水中油型乳化調味料の乳酸及び/又はその塩の含有量が前記数値範囲より多いと、加熱しても酸味を強く感じ、調味料全体の味のバランスが失われてしまう。
<Lactic acid and / or salt thereof, and content thereof>
Examples of lactic acid and / or a salt thereof in the acidic oil-in-water emulsified seasoning of the present invention include, for example, lactic acid, fermented lactic acid, sodium lactate, potassium lactate, and iron lactate, except for calcium salts. The content of lactic acid and / or a salt thereof in the acidic oil-in-water emulsified seasoning of the present invention is 0.5% to 4.5% in terms of lactic acid, and more preferably 1% to 4%. .
If the content of lactic acid and / or salt thereof in the acidic oil-in-water type emulsified seasoning is less than the above numerical range, even if the acetic acid and / or salt thereof, salt, egg yolk, and the calcium salt described later are contained in a specific amount When the acidic oil-in-water emulsified seasoning is subjected to baking, hot-air drying, and oil heating, the acidity of the acidic oil-in-water emulsified seasoning disappears and the balance of the taste of the entire seasoning is lost. . On the other hand, if the content of lactic acid and / or a salt thereof in the acidic oil-in-water emulsified seasoning is more than the above numerical range, the acidity is strongly felt even when heated, and the balance of the taste of the whole seasoning is lost.

<カルシウム塩、並びにその含有量>
本発明の酸性水中油型乳化調味料中のカルシウム塩は、特に限定されず、例えば塩化カルシウム、乳酸カルシウム、酢酸カルシウム、炭酸カルシウム等が挙げられるが、加熱による酸性水中油型乳化調味料中の酸味消失が感じられにくく、調味料全体の味のバランスが失われにくくなることから、塩化カルシウム、乳酸カルシウム又は酢酸カルシウムの1種以上が含まれるとよく、さらに少なくとも塩化カルシウムが含まれるとよい。
酸性水中油型乳化調味料中のカルシウム塩の含有量は、カルシウム換算で0.01%以上0.6%以下であり、さらに0.02%以上0.4%以下であるとよく、さらに0.03%以上0.1%以下であるとよい。酸性水中油型乳化調味料のカルシウム塩の含有量が前記数値範囲より少ないと、たとえ、前述のカルシウム塩を除く酢酸及び/又はその塩、食塩、卵黄、カルシウム塩を除く乳酸及び/又はその塩を特定量含有したとしても、酸性水中油型乳化調味料に焼成、熱風乾燥、及び油ちょう等の加熱を施した際、マヨネーズ等の酸性水中油型乳化調味料と同様の酸味が消失し、調味料全体の味のバランスが失われてしまう。一方、酸性水中油型乳化調味料のカルシウム塩の含有量が前記数値範囲より多いと、カルシウム塩のえぐみ・苦み等を感じやすくなり、調味料全体の味のバランスが失われてしまう。
<Calcium salt and its content>
The calcium salt in the acidic oil-in-water emulsified seasoning of the present invention is not particularly limited, and examples thereof include calcium chloride, calcium lactate, calcium acetate, and calcium carbonate. One or more of calcium chloride, calcium lactate, or calcium acetate is preferably included, and at least calcium chloride is preferably included because it is difficult for the disappearance of sourness to be felt and the balance of the taste of the entire seasoning is difficult to be lost.
The content of calcium salt in the acidic oil-in-water type emulsified seasoning is 0.01% or more and 0.6% or less in terms of calcium, more preferably 0.02% or more and 0.4% or less, and further 0 It is good that it is 0.03% or more and 0.1% or less. If the content of calcium salt in the acidic oil-in-water type emulsified seasoning is less than the above numerical range, acetic acid and / or its salt excluding the aforementioned calcium salt, salt, egg yolk, lactic acid excluding calcium salt and / or its salt Even when the acid oil-in-water emulsified seasoning is baked, dried with hot air, and heated like oil cane, the acidity similar to the acid oil-in-water emulsified seasoning such as mayonnaise disappears, The balance of the taste of the whole seasoning will be lost. On the other hand, when the content of the calcium salt in the acidic oil-in-water emulsified seasoning is larger than the above numerical range, it becomes easy to feel the bitterness and bitterness of the calcium salt and the balance of the taste of the whole seasoning is lost.

<酸性水中油型乳化調味料に用いる他の食品原料>
本発明の酸性水中油型乳化調味料は、上述の原料の他に本発明の効果を損なわない範囲で酸性水中油型乳化調味料に通常用いられている各種原料を適宜選択し含有させることができる。例えば、グルタミン酸ナトリウム、砂糖、醤油、味噌等の各種調味料、各種エキス、キサンタンガム、タマリンド種子ガム、ローカストビーンガム、ジェランガム、グアーガム、アラビアガム、サイリュームシードガム等のガム質、馬鈴薯澱粉、コーンスターチ、タピオカ澱粉、小麦澱粉、米澱粉、これらの澱粉をアルファ化、架橋等の処理を施した加工澱粉、並びに湿熱処理澱粉等の澱粉類、澱粉分解物、デキストリン、デキストリンアルコール、オリゴ糖、オリゴ糖アルコール等の糖類、全卵、液卵白、レシチン、リゾレシチン、ラクトアルブミン、カゼインナトリウム、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、オクテニルコハク酸化澱粉等の乳化材、アスコルビン酸又はその塩、ビタミンE等の酸化防止剤、からし粉、胡椒等の香辛料、各種蛋白質やこれらの分解物等が挙げられる。
<Other food ingredients used in acidic oil-in-water emulsified seasonings>
The acidic oil-in-water emulsified seasoning of the present invention may contain various raw materials usually used for acidic oil-in-water emulsified seasonings in addition to the above-mentioned raw materials as long as the effects of the present invention are not impaired. it can. For example, various seasonings such as sodium glutamate, sugar, soy sauce, miso, various extracts, xanthan gum, tamarind seed gum, locust bean gum, gellan gum, guar gum, gum arabic, silly seed gum, gum starch, potato starch, corn starch, tapioca Starch, wheat starch, rice starch, processed starch obtained by subjecting these starches to pregelatinization and crosslinking, and starches such as wet heat-treated starch, starch degradation products, dextrin, dextrin alcohol, oligosaccharide, oligosaccharide alcohol, etc. Sugar, whole egg, liquid egg white, lecithin, lysolecithin, lactalbumin, sodium caseinate, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, octenyl succinylated starch, etc., ascor Phosphate or a salt thereof, antioxidants such as vitamin E, mustard flour, spices pepper, etc., various proteins and their degradation products, and the like.

<加熱固形状食品>
加熱固形状食品とは、料理の分野で一般的に行われている、焼成、フライ、煮る、蒸す、炒める等の他、レトルト処理等の加熱処理を施す、具体的には、80℃以上で加熱処理する加熱固形状食品をいう。このような加熱処理を施し、マヨネーズ味が要望される固形状加熱食品としては、例えば、パン、パン用フィリング又はトッピング、クッキー、ボーロ、スポンジケーキ等の焼成食品、せんべい、あられ、おかき等の熱風乾燥品、スナック等の押出成形品等の加熱固形状食品等が挙げられる。上記加熱固形状食品中でも、特に、パン等の焼成食品や米菓等の熱風乾燥品は加熱後の酸性水中油型乳化調味料の酸味が消失し、酸性水中油型乳化調味料全体の味のバランスが失われることから、本発明を用いることが好適である。
<Heating solid food>
The heated solid food is generally subjected to heat treatment such as baking, frying, boiling, steaming, frying, etc., as well as retort treatment, specifically at 80 ° C. or higher. Heated solid food to be heat treated. Examples of solid heated foods that have undergone such heat treatment and that mayonnaise taste are desired include, for example, baking foods such as bread, bread fillings or toppings, baked foods such as cookies, bolo, sponge cakes, hot air such as rice crackers, hail, oysters, etc. Heated solid foods such as dried products, extruded products such as snacks, and the like can be mentioned. Among the above heated solid foods, the acidity of the acid oil-in-water emulsified seasoning after heating disappears particularly in the hot air dried products such as baked foods such as bread and rice crackers, and the taste of the acid oil-in-water emulsified seasonings as a whole Since the balance is lost, it is preferable to use the present invention.

<加熱固形状食品の製造方法>
本発明の酸性水中油型乳化調味料は、加熱固形状食品に用いることができる。ここで、本発明の加熱固形状食品の製造方法は、例えば、加熱前の米菓生地やパン生地表面等の加熱前の加熱固形状食品表面に酸性水中油型乳化食品を噴霧等の付着処理を施して加熱するとよい。
<Method for producing heated solid food>
The acidic oil-in-water emulsified seasoning of the present invention can be used for heated solid foods. Here, the method for producing a heated solid food according to the present invention includes, for example, an adhesion treatment such as spraying an acidic oil-in-water emulsified food on the surface of the heated solid food before heating, such as the rice confectionery dough or bread dough surface before heating. Apply and heat.

以下、本発明の酸性水中油型乳化調味料について、実施例、及び試験例に基づき具体的に説明する。なお、本発明は、これらに限定するものではない。 Hereinafter, the acidic oil-in-water type emulsified seasoning of the present invention will be specifically described based on Examples and Test Examples. The present invention is not limited to these.

[実施例1]
<酸性水中油型乳化調味料>
下記に示す配合割合で酸性水中油型乳化調味料を製した。つまり、食酢、食塩、乳酸、塩化カルシウム、生卵黄、リゾ化率50%のホスフォリパーゼA処理卵黄、清水をミキサーに入れ、攪拌しながら植物油を徐々に添加して粗乳化し、更にコロイドミルに通して仕上げ乳化を施した。次に、得られた乳化物を容量300gのラミネート容器に充填することにより本発明品の酸性水中油型乳化調味料を製した。なお、得られた酸性水中油型乳化調味料は、酢酸を2.5%、食塩を5%、乳酸(乳酸50%含有)を乳酸換算で3%、塩化カルシウムをカルシウム換算で0.08%、生卵黄を4%、ホスフォリパーゼA処理卵黄を生卵黄換算で8%含有した。
[Example 1]
<Acid oil-in-water emulsified seasoning>
Acidic oil-in-water emulsified seasonings were produced at the following blending ratios. In other words, vinegar, salt, lactic acid, calcium chloride, raw egg yolk, phospholipase A 2 treated egg yolk with a lysification rate of 50%, and fresh water are put into a mixer, and vegetable oil is gradually added with stirring to coarsely emulsify. Finish emulsification was performed through a mill. Next, an acidic oil-in-water type emulsified seasoning of the present invention was produced by filling the obtained emulsion into a laminate container having a capacity of 300 g. The obtained acidic oil-in-water emulsified seasoning is 2.5% acetic acid, 5% salt, 3% lactic acid (containing 50% lactic acid) in terms of lactic acid, and 0.08% in terms of calcium chloride in terms of calcium. , raw egg yolk 4%, the phospholipase a 2 treated egg yolk contained 8% raw egg yolk terms.

<酸性水中油型乳化調味料の配合割合>
(油相)
植物油 20%
(水相)
食酢(酸度20%) 12.5%
食塩 5%
乳酸 6%
塩化カルシウム 0.29%
生卵黄 4%
ホスフォリパーゼA処理卵黄 8%
(リゾ化率50%)
清水 残余
―――――――――――――――――――――――
合計 100%
<Mixing ratio of acidic oil-in-water emulsified seasoning>
(Oil phase)
Vegetable oil 20%
(Water phase)
Vinegar (acidity 20%) 12.5%
5% salt
Lactic acid 6%
Calcium chloride 0.29%
Raw egg yolk 4%
Phospholipase A 2 treated egg yolk 8%
(Lizification rate 50%)
Shimizu Residue ―――――――――――――――――――――――
Total 100%

[実施例2]
<せんべい>
精米したもち米を水に4時間浸漬した後、当該吸水米をセイロに移し蒸煮した。蒸煮の途中で打ち水を加水しながら芯が残らないまで蒸煮し約46%の水分とした。得られた蒸煮米をもち搗き機で搗き練り処理を行い、4℃の冷蔵庫で一晩冷却した後、直径4cm、厚さ0.3cmに大きさに切断して成形し、次いで水分含量が15〜16%となるまで乾燥させた。次いで、当該乾燥物を油温約240℃の油で1分間揚げた後、油切りし、当該揚げ処理物に実施例1で得られた酸性水中油型乳化調味料を揚げ処理物100部に対し20部となるように噴霧して付着させ、次いで80℃の熱風で60分間乾燥させてせんべいを得た。得られたせんべいを喫食したところ、加熱後の酸性水中油型乳化調味料の酸味が十分に維持され、酸性水中油型乳化調味料全体の味のバランスも十分に維持されていた。
[Example 2]
<Senbei>
After the polished glutinous rice was soaked in water for 4 hours, the water-absorbed rice was transferred to a steamer and steamed. During the cooking, the water was squeezed and water was added until the core remained. The obtained steamed rice is kneaded with a moisturizer and cooled overnight in a refrigerator at 4 ° C., then cut into a size of 4 cm in diameter and 0.3 cm in thickness, and then has a moisture content of 15 Dry to ~ 16%. Next, the dried product is fried with oil having an oil temperature of about 240 ° C. for 1 minute, drained, and the acidic oil-in-water emulsified seasoning obtained in Example 1 is added to 100 parts of the deep-fried product. On the other hand, it was sprayed so as to be 20 parts, and then dried with hot air at 80 ° C. for 60 minutes to obtain a rice cracker. When the obtained rice crackers were eaten, the acidity of the acidic oil-in-water emulsified seasoning after heating was sufficiently maintained, and the balance of the taste of the entire acidic oil-in-water emulsified seasoning was also sufficiently maintained.

[試験例1]
乳酸、塩化カルシウムの含有量の違いによる、酸性水中油型乳化調味料を熱風乾燥した際の、酸性水中油型乳化調味料の酸味の残存効果を調べた。具体的には、実施例1において、乳酸、塩化カルシウムの含有量を表1に示す割合に変更した以外は、実施例1と同様の方法で酸性水中油型乳化調味料を製した。次いで、得られた酸性水中油型乳化調味料を用いて、実施例2と同様の方法でせんべいを製造し、得られたせんべいを喫食し、下記の評価基準に従って、加熱後の酸性水中油型乳化調味料の酸味の残存効果と調味料全体の味のバランスを評価した。
[Test Example 1]
The acidity remaining effect of the acidic oil-in-water emulsified seasoning when hot air drying the acidic oil-in-water emulsified seasoning due to the difference in the contents of lactic acid and calcium chloride was investigated. Specifically, an acidic oil-in-water emulsified seasoning was produced in the same manner as in Example 1 except that the contents of lactic acid and calcium chloride were changed to the ratios shown in Table 1 in Example 1. Next, using the obtained acidic oil-in-water type emulsified seasoning, a rice cracker was produced in the same manner as in Example 2, and the resulting rice cracker was eaten. In accordance with the following evaluation criteria, the acid oil-in-water type after heating The balance between the sourness remaining effect of the emulsified seasoning and the taste of the whole seasoning was evaluated.

「加熱後の酸性水中油型乳化調味料の酸味の残存効果と調味料全体の味のバランス」の評価ランク:基準
A:加熱後の酸性水中油型乳化調味料の酸味が十分に維持され、酸性水中油型乳化調味料全体の味のバランスも十分に維持されている。
B:加熱後の酸性水中油型乳化調味料の酸味が若干弱いが、酸性水中油型乳化調味料全体の味のバランスは問題とならない程度である。
C:加熱後の酸性水中油型乳化調味料の酸味が弱く、酸性水中油型乳化調味料全体の味のバランスもやや悪いが、問題とならない程度である。
D:加熱後の酸性水中油型乳化調味料の酸味が感じられず、酸性水中油型乳化調味料全体の味のバランスが悪い。
Evaluation rank of "Balance of acidity remaining effect of acid oil-in-water emulsified seasoning after heating and taste of whole seasoning": Standard A: Acidity of acid oil-in-water emulsified seasoning after heating is sufficiently maintained, The balance of the taste of the entire acidic oil-in-water emulsified seasoning is also sufficiently maintained.
B: Although the acidity of the acidic oil-in-water emulsified seasoning after heating is slightly weak, the balance of the taste of the entire acidic oil-in-water emulsified seasoning is not problematic.
C: The acid oil-in-water emulsified seasoning after heating is weak and the balance of the taste of the entire acid oil-in-water emulsified seasoning is slightly bad, but is not problematic.
D: The acidity of the acidic oil-in-water emulsified seasoning after heating is not felt, and the overall balance of the taste of the acidic oil-in-water emulsified seasoning is poor.

Figure 0006325353
Figure 0006325353

表1より、乳酸の含有量が0.5%以上4.5%以下、かつ塩化カルシウムの含有量がカルシウム換算で0.01%以上0.6%以下、である酸性水中油型乳化調味料(No.5、6)は、加熱後の酸性水中油型乳化調味料の酸味が弱く、酸性水中油型乳化調味料全体の味のバランスもやや悪いが、問題とならない程度であることが理解される。さらに、乳酸の含有量が1%以上4%以下、かつ塩化カルシウムの含有量がカルシウム換算で0.02%以上0.4%以下である酸性水中油型乳化調味料(No.3、4、8、9)は、加熱後の酸性水中油型乳化調味料の酸味が若干弱いが、酸性水中油型乳化調味料全体の味のバランスは問題とならない程度であることが理解される。特に、乳酸の含有量が1%以上4%以下、かつ塩化カルシウムの含有量がカルシウム換算で0.03%以上0.1%以下である酸性水中油型乳化調味料(No.1、2、7)は、加熱後の酸性水中油型乳化調味料の酸味が十分に維持され、酸性水中油型乳化調味料全体の味のバランスも十分に維持されていることが理解される。 From Table 1, the acidic oil-in-water emulsified seasoning has a lactic acid content of 0.5% to 4.5% and a calcium chloride content of 0.01% to 0.6% in terms of calcium. (Nos. 5 and 6) have a weak acidity of the acidic oil-in-water emulsified seasoning after heating, and the taste balance of the acidic oil-in-water emulsified seasoning as a whole is somewhat poor, but it is understood that it is not a problem. Is done. Furthermore, the acidic oil-in-water type emulsified seasoning (No. 3, 4, or 4), wherein the content of lactic acid is 1% or more and 4% or less and the content of calcium chloride is 0.02% or more and 0.4% or less in terms of calcium. 8 and 9), it is understood that the acid oil-in-water emulsified seasoning after heating is slightly weak, but the balance of the taste of the entire acid oil-in-water emulsified seasoning is not a problem. In particular, an acidic oil-in-water emulsified seasoning (No. 1, 2, 4), wherein the content of lactic acid is 1% or more and 4% or less and the content of calcium chloride is 0.03% or more and 0.1% or less in terms of calcium. 7) It is understood that the acidity of the acidic oil-in-water emulsified seasoning after heating is sufficiently maintained, and the balance of the taste of the entire acidic oil-in-water emulsified seasoning is also sufficiently maintained.

[実施例3]
<酸性水中油型乳化調味料>
下記に示す配合割合で酸性水中油型乳化調味料を製した。つまり、食酢、食塩、乳酸ナトリウム、酢酸カルシウム、生卵黄、リゾ化率60%のホスフォリパーゼA処理卵黄、清水をミキサーに入れ、攪拌しながら植物油を徐々に添加して粗乳化し、更にコロイドミルに通して仕上げ乳化を施した。次に、得られた乳化物を容量300gのラミネート容器に充填することにより本発明品の酸性水中油型乳化調味料を製した。なお、得られた酸性水中油型乳化調味料は、酢酸を1.6%、食塩を3%、乳酸ナトリウムを乳酸換算で2%、酢酸カルシウムをカルシウム換算で0.08%、生卵黄を2%、ホスフォリパーゼA処理卵黄を生卵黄換算で6%含有した。
[Example 3]
<Acid oil-in-water emulsified seasoning>
Acidic oil-in-water emulsified seasonings were produced at the following blending ratios. In other words, vinegar, salt, sodium lactate, calcium acetate, raw egg yolk, phospholipase A 2 treated egg yolk with a lysification rate of 60%, and fresh water are put into a mixer, and vegetable oil is gradually added with stirring to coarsely emulsify. Final emulsification was performed through a colloid mill. Next, an acidic oil-in-water type emulsified seasoning of the present invention was produced by filling the obtained emulsion into a laminate container having a capacity of 300 g. The obtained acidic oil-in-water emulsified seasoning is 1.6% acetic acid, 3% sodium chloride, 2% sodium lactate in terms of lactic acid, 0.08% calcium acetate in terms of calcium, and 2 raw egg yolks. %, 6% of phospholipase A 2 treated egg yolk in terms of raw egg yolk was contained.

<酸性水中油型乳化調味料の配合割合>
(油相)
植物油 20%
(水相)
食酢(酸度20%) 8%
食塩 3%
乳酸ナトリウム 2.5%
酢酸カルシウム 0.32%
生卵黄 2%
ホスフォリパーゼA処理卵黄 6%
(リゾ化率60%)
清水 残余
―――――――――――――――――――――――
合計 100%
<Mixing ratio of acidic oil-in-water emulsified seasoning>
(Oil phase)
Vegetable oil 20%
(Water phase)
Vinegar (acidity 20%) 8%
Salt 3%
Sodium lactate 2.5%
Calcium acetate 0.32%
Raw egg yolk 2%
Phospholipase A 2 treated egg yolk 6%
(Lizification rate 60%)
Shimizu Residue ―――――――――――――――――――――――
Total 100%

[試験例2]
塩化カルシウム、酢酸カルシウム、乳酸カルシウム、又は炭酸カルシウムの1種以上であるカルシウム塩の種類と含有量の違いによる、酸性水中油型乳化調味料を熱風乾燥した際の、酸性水中油型乳化調味料の酸味の残存効果と調味料全体の味のバランスへの影響を調べた。具体的には、実施例3において、カルシウム塩の種類と含有量を表2に示す割合に変更した以外は、実施例3と同様の方法で酸性水中油型乳化調味料を製した。次いで、得られた酸性水中油型乳化調味料を用いて、実施例2と同様の方法でせんべいを製造し、得られたせんべいを喫食し、加熱後の酸性水中油型乳化調味料の酸味の残存効果と調味料全体の味のバランスを評価した。また、評価基準は試験例1と同様とする。
[Test Example 2]
Acid oil-in-water emulsified seasonings when hot-air dried acid oil-in-water emulsified seasonings due to differences in the type and content of calcium salt that is one or more of calcium chloride, calcium acetate, calcium lactate, or calcium carbonate The effect of the remaining sourness on the balance of the taste of the whole seasoning was investigated. Specifically, in Example 3, an acidic oil-in-water emulsion seasoning was produced in the same manner as in Example 3 except that the type and content of the calcium salt were changed to the ratios shown in Table 2. Next, using the obtained acidic oil-in-water emulsified seasoning, rice crackers were produced in the same manner as in Example 2, and the resulting rice crackers were eaten. The balance between the residual effect and the taste of the whole seasoning was evaluated. The evaluation criteria are the same as in Test Example 1.

Figure 0006325353
Figure 0006325353

表2より、塩化カルシウム、酢酸カルシウム、乳酸カルシウム、又は炭酸カルシウムの1種以上が含まれるとよい(No.1、12〜15)。さらに今回用いた4種のカルシウム塩の中でも、少なくとも塩化カルシウムを用いた場合は、酸味の残存効果は他の3種のカルシウム塩に比べ特に優れていた(No.1、12)。また炭酸カルシウムは、酸性水中油型乳化調味料の製造行程中で炭酸カルシウム配合時に発泡し、本発明後の効果が他の3種のカルシウム塩(塩化カルシウム、酢酸カルシウム、乳酸カルシウム)にやや劣った(No.15)。 From Table 2, it is good that 1 or more types of calcium chloride, calcium acetate, calcium lactate, or calcium carbonate are contained (No. 1, 12-15). Furthermore, among the four types of calcium salts used this time, when at least calcium chloride was used, the sourness remaining effect was particularly superior to the other three types of calcium salts (Nos. 1 and 12). Calcium carbonate foams when calcium carbonate is blended in the production process of acidic oil-in-water emulsified seasonings, and the effect after the present invention is slightly inferior to the other three calcium salts (calcium chloride, calcium acetate, calcium lactate). (No. 15).

[実施例4]
<酸性水中油型乳化調味料>
下記に示す配合割合で酸性水中油型乳化調味料を製した。つまり、酢酸、酢酸ナトリウム、食塩、発酵乳酸、酢酸カルシウム、生卵黄、リゾ化率30%のホスフォリパーゼA処理卵黄、清水をミキサーに入れ、攪拌しながら植物油を徐々に添加して粗乳化し、更にコロイドミルに通して仕上げ乳化を施した。次に、得られた乳化物を容量300gのラミネート容器に充填することにより本発明品の酸性水中油型乳化調味料を製した。なお、得られた酸性水中油型乳化調味料は、酢酸ナトリウムを酢酸換算で2%、食塩を4%、発酵乳酸(乳酸50%含有)を乳酸換算で3%、塩化カルシウムをカルシウム換算で0.08%、生卵黄を2%、ホスフォリパーゼA処理卵黄を生卵黄換算で10%含有した。
[Example 4]
<Acid oil-in-water emulsified seasoning>
Acidic oil-in-water emulsified seasonings were produced at the following blending ratios. That is, acetic acid, sodium acetate, sodium chloride, fermented lactic acid, calcium acetate, raw egg yolk, put lyso ratio of 30% phospholipase A 2 processing egg yolks, fresh water in a mixer and gradually added to the crude emulsified vegetable oil while stirring Further, the mixture was passed through a colloid mill and subjected to final emulsification. Next, an acidic oil-in-water type emulsified seasoning of the present invention was produced by filling the obtained emulsion into a laminate container having a capacity of 300 g. In addition, the obtained acidic oil-in-water emulsified seasoning was 2% sodium acetate in terms of acetic acid, 4% salt, 3% fermented lactic acid (containing 50% lactic acid) in terms of lactic acid, and 0% in terms of calcium chloride in terms of calcium. 0.08%, the raw egg yolk 2%, the phospholipase a 2 treated egg yolk containing 10% raw egg yolk terms.

<酸性水中油型乳化調味料の配合割合>
(油相)
植物油 20%
(水相)
食酢(酸度20%) 10%
酢酸ナトリウム 2.7%
食塩 4%
発酵乳酸 6%
塩化カルシウム 0.29%
生卵黄 2%
ホスフォリパーゼA処理卵黄 10%
(リゾ化率30%)
清水 残余
―――――――――――――――――――――――
合計 100%
<Mixing ratio of acidic oil-in-water emulsified seasoning>
(Oil phase)
Vegetable oil 20%
(Water phase)
Vinegar (acidity 20%) 10%
Sodium acetate 2.7%
Salt 4%
Fermented lactic acid 6%
Calcium chloride 0.29%
Raw egg yolk 2%
Phospholipase A 2 treated egg yolk 10%
(Lizification rate 30%)
Shimizu Residue ―――――――――――――――――――――――
Total 100%

[実施例5]
<酸性水中油型乳化調味料>
下記に示す配合割合で酸性水中油型乳化調味料を製した。つまり、酢酸ナトリウム、食塩、乳酸、酢酸カルシウム、生卵黄、リゾ化率30%のホスフォリパーゼA処理卵黄、清水をミキサーに入れ、攪拌しながら植物油を徐々に添加して粗乳化し、更にコロイドミルに通して仕上げ乳化を施した。次に、得られた乳化物を容量300gのラミネート容器に充填することにより本発明品の酸性水中油型乳化調味料を製した。なお、得られた酸性水中油型乳化調味料は、酢酸ナトリウムを酢酸換算で4%、食塩を4%、乳酸(乳酸50%含有)を乳酸換算で2%、酢酸カルシウムをカルシウム換算で0.08%、生卵黄を2%、ホスフォリパーゼA処理卵黄を生卵黄換算で10%含有した。
[Example 5]
<Acid oil-in-water emulsified seasoning>
Acidic oil-in-water emulsified seasonings were produced at the following blending ratios. That is, sodium acetate, salt, lactic acid, calcium acetate, raw egg yolk, phospholipase A 2 treated egg yolk with a lysification rate of 30%, and fresh water are put into a mixer, and vegetable oil is gradually added with stirring to coarsely emulsify. Final emulsification was performed through a colloid mill. Next, an acidic oil-in-water type emulsified seasoning of the present invention was produced by filling the obtained emulsion into a laminate container having a capacity of 300 g. The acidic oil-in-water emulsified seasoning obtained was 4% sodium acetate in terms of acetic acid, 4% sodium chloride, 2% lactic acid (containing 50% lactic acid) in terms of lactic acid, and calcium acetate in terms of calcium in the range of 0. 08%, a raw egg yolk 2%, the phospholipase a 2 treated egg yolk containing 10% raw egg yolk terms.

<酸性水中油型乳化調味料の配合割合>
(油相)
植物油 20%
(水相)
酢酸ナトリウム 5.5%
食塩 4%
乳酸 4%
酢酸カルシウム 0.32%
生卵黄 2%
ホスフォリパーゼA処理卵黄 10%
(リゾ化率30%)
清水 残余
―――――――――――――――――――――――
合計 100%
<Mixing ratio of acidic oil-in-water emulsified seasoning>
(Oil phase)
Vegetable oil 20%
(Water phase)
Sodium acetate 5.5%
Salt 4%
Lactic acid 4%
Calcium acetate 0.32%
Raw egg yolk 2%
Phospholipase A 2 treated egg yolk 10%
(Lizification rate 30%)
Shimizu Residue ―――――――――――――――――――――――
Total 100%

[実施例6]
<焼成パン>
調製した一次発酵済みのパン生地100g、二次発酵させた後、実施例1、3、4、5で得られた酸性水中油型乳化調味料30gをパン生地にのせ、焼成してマヨネーズパンを調製した。得られた焼成パンを喫食したところ、実施例1、3、4、5のいずれも加熱後の酸性水中油型乳化調味料の酸味が十分に維持され、酸性水中油型乳化調味料全体の味のバランスも十分に維持されていた。中でも、実施例4は、酸味の維持に特に優れており、調味料全体の味のバランスの維持も優れていた。
[Example 6]
<Baked bread>
After 100 g of the prepared primary fermented bread dough and secondary fermented, 30 g of the acidic oil-in-water emulsified seasoning obtained in Examples 1, 3, 4, and 5 was placed on the dough and baked to prepare mayonnaise bread. . When the obtained baked bread was eaten, the acidity of the acidic oil-in-water emulsified seasoning after heating was sufficiently maintained in all of Examples 1, 3, 4, and 5, and the taste of the entire acidic oil-in-water emulsified seasoning was maintained. Was well maintained. Among them, Example 4 was particularly excellent in maintaining sourness, and maintaining the balance of the taste of the whole seasoning was also excellent.

[実施例7]
<チキンカツ>
鶏胸肉を一口大にカットし、塩、胡椒で調味した。実施例1、3、4、5で得られた酸性水中油型乳化調味料をバッター液として用い、調味した鶏胸肉100部に対し酸性水中油型乳化調味料20部となるように付着させ、パン粉を付けた後、170℃の植物油で4分間油ちょうした。得られたチキンカツを喫食したところ、実施例1、3、4、5のいずれも加熱後の酸性水中油型乳化調味料の酸味が十分に維持され、酸性水中油型乳化調味料全体の味のバランスも十分に維持されていた。中でも、実施例4は、酸味の維持に特に優れており、調味料全体の味のバランスの維持も優れていた。











[Example 7]
<Chicken cutlet>
Chicken breast was cut into bite-sized pieces and seasoned with salt and pepper. The acidic oil-in-water emulsified seasoning obtained in Examples 1, 3, 4, and 5 was used as a batter liquid, and adhered to 100 parts of seasoned chicken breast so as to be 20 parts of acidic oil-in-water emulsified seasoning. After applying bread crumbs, the mixture was oiled with vegetable oil at 170 ° C. for 4 minutes. When the obtained chicken cutlet was eaten, the acidity of the acidic oil-in-water emulsified seasoning after heating was sufficiently maintained in all of Examples 1, 3, 4, and 5, and the taste of the entire acidic oil-in-water emulsified seasoning was maintained. The balance was well maintained. Among them, Example 4 was particularly excellent in maintaining sourness, and maintaining the balance of the taste of the whole seasoning was also excellent.











Claims (7)

酢酸及び/又はその塩(ただし、カルシウム塩を除く)を酢酸換算で1%以上5%以下、食塩を3%以上15%以下、卵黄を含有した酸性水中油型乳化調味料であって、
乳酸及び/又はその塩(ただし、カルシウム塩を除く)を乳酸換算で0.5%以上4.5%以下、並びにカルシウム塩をカルシウム換算で0.01%以上0.6%以下含有する、
酸性水中油型乳化調味料。
An acidic oil-in-water emulsified seasoning containing acetic acid and / or a salt thereof (excluding calcium salt) in terms of acetic acid in an amount of 1% to 5%, sodium chloride in an amount of 3% to 15%, and egg yolk,
Containing lactic acid and / or a salt thereof (excluding calcium salt) in an amount of 0.5% to 4.5% in terms of lactic acid, and a calcium salt in an amount of 0.01% to 0.6% in terms of calcium;
Acid oil-in-water emulsified seasoning.
請求項1記載の乳化調味料において、
カルシウム塩が、塩化カルシウム、乳酸カルシウム又は酢酸カルシウムから選択された1種以上である、
酸性水中油型乳化調味料。
In the emulsified seasoning according to claim 1,
The calcium salt is at least one selected from calcium chloride, calcium lactate or calcium acetate,
Acid oil-in-water emulsified seasoning.
請求項1又は2に記載の酸性水中油型乳化調味料を用いた加熱固形状食品。 A heated solid food product using the acidic oil-in-water emulsified seasoning according to claim 1 or 2. 請求項1又は2に記載の酸性水中油型乳化調味料を用いた焼成食品。 A baked food using the acidic oil-in-water emulsified seasoning according to claim 1 or 2. 請求項1又は2に記載の酸性水中油型乳化調味料を用いた米菓。 Rice confectionery using the acidic oil-in-water emulsified seasoning according to claim 1 or 2. 請求項1又は2に記載の酸性水中油型乳化調味料を用いたパン。 Bread using the acidic oil-in-water emulsified seasoning according to claim 1 or 2. 請求項1又は2に記載の酸性水中油型乳化調味料を加熱前の加熱固形状食品表面に付着させた後に加熱する、加熱固形状食品の製造方法。 The manufacturing method of the heating solid foodstuff which heats, after making the acidic oil-in-water type emulsion seasoning of Claim 1 or 2 adhere to the heating solid foodstuff surface before a heating.
JP2014113785A 2014-06-02 2014-06-02 Acid oil-in-water emulsified seasoning Active JP6325353B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2014113785A JP6325353B2 (en) 2014-06-02 2014-06-02 Acid oil-in-water emulsified seasoning

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2014113785A JP6325353B2 (en) 2014-06-02 2014-06-02 Acid oil-in-water emulsified seasoning

Publications (2)

Publication Number Publication Date
JP2015226512A JP2015226512A (en) 2015-12-17
JP6325353B2 true JP6325353B2 (en) 2018-05-16

Family

ID=54884479

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014113785A Active JP6325353B2 (en) 2014-06-02 2014-06-02 Acid oil-in-water emulsified seasoning

Country Status (1)

Country Link
JP (1) JP6325353B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6608510B1 (en) * 2018-11-30 2019-11-20 キユーピー株式会社 Acid liquid seasoning

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5571476A (en) * 1978-11-24 1980-05-29 Asahi Denka Kogyo Kk O/w-type emulsified fat
JPS5571475A (en) * 1978-11-24 1980-05-29 Asahi Denka Kogyo Kk O/w-type emulsified fat
JP2864280B2 (en) * 1990-06-21 1999-03-03 雪印乳業株式会社 Mayonnaise sauce having good heat resistance and method for producing the same
JPH04126050A (en) * 1990-09-18 1992-04-27 Snow Brand Milk Prod Co Ltd Mayonnaise sauce excellent in heat resistance and production thereof
JPH0856608A (en) * 1994-08-23 1996-03-05 Takeda Shokuhin Kogyo Kk Powdery mayonnaise-like seasoning and method for producing the same
JP4994330B2 (en) * 2008-08-26 2012-08-08 キユーピー株式会社 Acid oil-in-water emulsified food and use thereof
JP4861385B2 (en) * 2008-08-26 2012-01-25 キユーピー株式会社 Acid oil-in-water emulsified food and use thereof

Also Published As

Publication number Publication date
JP2015226512A (en) 2015-12-17

Similar Documents

Publication Publication Date Title
KR20190003579A (en) Powdery breader, and breader mix, coating material, and deep-fried (-like) food product using powdery breader, and production methods therefor
WO2013172118A1 (en) Production method for frozen noodles and composition for preventing freezer burn
JP7310260B2 (en) Frozen gyoza and its manufacturing method
JPWO2015041234A1 (en) Method for producing a loosening improver for noodles
JP2018019645A (en) Corn dog mix powder and manufacturing method of corn dog
WO2012002559A1 (en) Method for producing non-fried food
JP2007135460A (en) Method for producing retort pasta sauce
JP4994330B2 (en) Acid oil-in-water emulsified food and use thereof
JP4861385B2 (en) Acid oil-in-water emulsified food and use thereof
JPWO2018181749A1 (en) Clothing for fried food
JP2019041633A (en) Composition for fried jiaozi blade
JP6325353B2 (en) Acid oil-in-water emulsified seasoning
WO2020004632A1 (en) Frozen gyoza and method for producing same
JP2020074688A (en) Composition for forming crisp skirt around gyoza dumpling and production method of gyoza dumpling with crisp skirt
WO2021141101A1 (en) Agent for forming crispy wings on gyoza dumplings
JP2016165250A (en) Manufacturing method of food for non-fry cooking, mix for non-fry cooking and food for non-fry cooking
JP7190318B2 (en) Fried food manufacturing method
US9743677B2 (en) Wheat flour for frying batter
JP5878390B2 (en) Batter mix for fried foods
JP6892809B2 (en) Bacteriostatic agent for food
JPH10327788A (en) Tempura flour composition and tempura prepared by using the composition
JP4805875B2 (en) Method for producing non-fried food
JP6289933B2 (en) Acid oil-in-water emulsified seasoning
JP7402384B1 (en) fried food
JP5890701B2 (en) Batter mix for frozen fried food

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20170427

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20180403

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20180412

R150 Certificate of patent or registration of utility model

Ref document number: 6325353

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250