JP6255482B2 - Compound, coloring composition, ink for ink jet recording, ink jet recording method, ink jet printer cartridge, ink jet recorded material, color filter, color toner, and transfer ink - Google Patents

Description

  The present invention relates to a compound, a colored composition, an ink for ink jet recording, an ink jet recording method, an ink jet printer cartridge, an ink jet recorded material, a color filter, a color toner, and a transfer ink.

As is well known, the ink jet recording method is a method of performing printing by causing a small droplet of ink to fly and adhere to a recording medium such as paper. This printing method is capable of printing high-resolution, high-quality images at high speed and easily with an inexpensive apparatus. In particular, in color printing, technical development has recently been carried out as an image forming method that can replace photographs. .
When forming a color image using an inkjet recording method, it is common to use at least yellow ink, magenta ink, cyan ink, and black ink. These inks have physical properties such as viscosity and surface tension within an appropriate range, nozzle clogging, excellent storage stability, and a high density recording image, light resistance, ozone resistance, Properties such as excellent water resistance and moisture resistance are required.

  These performances often meet the required levels by using water or a water-based ink containing a mixture of water and a water-soluble organic solvent as a main solvent, but in particular, color tone, vividness, light resistance, Ozone resistance, water resistance, moisture resistance, and the like depend largely on the colorant, and various dyes have been studied in the past.

For example, Patent Document 1 describes a xanthene derivative substituted with an anilino group, and a compound in which an acylamino group is substituted for the anilino group, and an ink jet recording material formed using a colored composition containing the compound The saturation, light resistance, ozone resistance, etc. are being studied.
Patent Document 2 describes a colored composition containing a multimer of xanthene derivatives substituted with an anilino group.

Japanese Unexamined Patent Publication No. 2011-148773 International Publication No. 2013/031838

  However, in the field of dyes, further improvement in performance is required, and compounds that can further improve image fastness such as light resistance, ozone resistance, and humidity resistance, and filterability during ink preparation Is required.

  An object of this invention is to provide the compound and coloring composition which can form the image excellent in light resistance, ozone resistance, and moisture resistance, and are excellent also in the filterability at the time of ink preparation. Another object of the present invention is to provide an ink jet recording ink containing the above compound and a coloring composition, an ink jet recording method using the ink for ink jet recording, an ink jet printer cartridge, and an ink jet recorded product. Furthermore, it aims at providing the color filter, color toner, and transfer ink containing the said compound.

一般式（１）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３ 、Ｒ ^８ 、Ｒ ^１０１、Ｒ^１０２、Ｒ^１０３、及びＲ^１０４ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^１０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ１０１は２〜１００を表す。
一般式（２）

一般式（２）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３ 及びＲ ^８ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^２０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ２０１は２〜１００を表す。
一般式（３）

一般式（３）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３ 及びＲ ^８ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^３０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ３０１は２〜１００を表す。
一般式（４）

一般式（４）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３ 、Ｒ ^８ 、Ｒ ^１０５、及びＲ^１０６ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^４０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ４０１は２〜１００を表す。
一般式（５）

一般式（５）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３、Ｒ^８、Ｒ^１０７及びＲ^１０８は各々独立に水素原子又は置換基を表し、Ｌ^５０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ５０１は２〜１００を表す。Ｘ^５０１及びＸ^５０２ はＳＯ _３ Ｎａが置換したモノアリールアミノカルボニル基を表す。
一般式（６）

一般式（６）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^２ 、Ｒ ^７ 、Ｒ ^１０１、Ｒ^１０２、Ｒ^１０３、及びＲ^１０４ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^６０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ６０１は２〜１００を表す。
一般式（７）

一般式（７）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^２ 及びＲ ^７ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^７０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ７０１は２〜１００を表す。
一般式（８）

一般式（８）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^２ 及びＲ ^７ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^８０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ８０１は２〜１００を表す。
一般式（９）

一般式（９）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^２ 、Ｒ ^７ 、Ｒ ^１０５、及びＲ^１０６ は各々独立に水素原子又は置換基を表し、Ｒ ^４ 、Ｒ ^９ 、Ｒ ^１１２ 及びＲ ^１１５ は水素原子又はＳＯ _３ Ｎａを表すものであり、Ｒ ^４ 及びＲ ^９ がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表すか、又は、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ ^１１２ 及びＲ ^１１５ がＳＯ _３ Ｎａを表す。Ｌ^９０１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ９０１は２〜１００を表す。
一般式（１０）

一般式（１０）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^２、Ｒ^３、Ｒ^７，Ｒ^８、Ｒ^１０７及びＲ^１０８は各々独立に水素原子又は置換基を表し、Ｌ^１００１はアルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらから選ばれる２種以上を組み合わせてなる基から選択される少なくとも１つの基が置換したアルキレン基若しくは無置換のアルキレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアリーレン基若しくは無置換のアリーレン基、アルキル基、アラルキル基、アルケニル基、アルキニル基、アリール基、スルホ基、及びこれらの組み合わせからなる基から選択される少なくとも１つの基が置換したアルケニレン基若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基を表し、ｎ１００１は２〜１００を表す。Ｘ^５０１及びＸ^５０２は各々独立に、置換若しくは無置換のアルキル基、置換若しくは無置換のアリール基、置換若しくは無置換のヘテロ環基、置換若しくは無置換のアルキルカルボニル基、置換若しくは無置換のアリールカルボニル基、置換若しくは無置換のアルキルスルホニル基、置換若しくは無置換のアリールスルホニル基、置換若しくは無置換のアルコキシカルボニル基、置換若しくは無置換のアリールオキシカルボニル基、置換若しくは無置換のモノアルキルアミノカルボニル基、置換若しくは無置換のジアルキルアミノカルボニル基、置換若しくは無置換のモノアリールアミノカルボニル基、置換若しくは無置換のジアリールアミノカルボニル基、又は置換若しくは無置換のアルキルアリールアミノカルボニル基を表す。
ただし、Ｌ ^１００１ が下記式（ＬＬ４）で表される２価の連結基を表すか、又は、Ｘ ^５０１ 及びＸ ^５０２ がＣＯ _２ Ｎａ及びＯＨが置換したモノアリールアミノカルボニル基を表す。

＜２＞
上記一般式（１）、（２）、（３）、（４）、（６）、（７）、（８）又は（９）で表される繰り返し単位を有する化合物であって、Ｒ ^４ 及びＲ ^９ が水素原子を表し、かつＲ^１１２及びＲ^１１５がＳＯ _３ Ｎａを表す＜１＞に記載の化合物。
＜３＞
上記一般式（１）、（２）、（３）、（４）、（５）又は（１０）で表される繰り返し単位を有する化合物であって、Ｒ^３及びＲ^８が各々独立に置換若しくは無置換のアルキル基を表す＜１＞に記載の化合物。
＜４＞
上記一般式（１）、（２）、（３）又は（４）で表される繰り返し単位を有する化合物であって、Ｒ^３ 及びＲ ^８ が各々独立に水素原子、置換若しくは無置換のアルキル基、置換若しくは無置換のアリール基、置換若しくは無置換のアルコキシ基、置換若しくは無置換のアリールオキシ基、置換若しくは無置換のアミノ基、置換若しくは無置換のアシルアミノ基、置換若しくは無置換のアルコキシカルボニルアミノ基、置換若しくは無置換のアルキルスルホニルアミノ基、置換若しくは無置換のアリールスルホニルアミノ基、置換若しくは無置換のアルキルウレイド基、置換若しくは無置換のアリールウレイド基、スルホ基、カルボキシル基、又はハロゲン原子を表す＜１＞〜＜３＞のいずれか１項に記載の化合物。
＜５＞
上記一般式（１）、（２）、（３）又は（４）で表される繰り返し単位を有する化合物であって、Ｒ^４及びＲ^９がＳＯ _３ Ｎａを表し、かつＲ ^１１２ 及びＲ ^１１５ が水素原子を表す＜１＞に記載の化合物。
＜６＞
＜１＞〜＜５＞のいずれか１項に記載の化合物を含有する着色組成物。
＜７＞
＜１＞〜＜５＞のいずれか１項に記載の化合物を含有するインクジェット記録用インク。
＜８＞
＜７＞に記載のインクジェット記録用インクを用いるインクジェット記録方法。
＜９＞
＜７＞に記載のインクジェット記録用インクを充填したインクジェットプリンタカートリッジ。
＜１０＞
＜７＞に記載のインクジェット記録用インクを用いて、被記録材に着色画像を形成したインクジェット記録物。
＜１１＞
＜１＞〜＜５＞のいずれか１項に記載の化合物を含有するカラーフィルタ。
＜１２＞
＜１＞〜＜５＞のいずれか１項に記載の化合物を含有するカラートナー。
＜１３＞
＜１＞〜＜５＞のいずれか１項に記載の化合物を含有する転写用インク。
本発明は、上記＜１＞〜＜１３＞に係る発明であるが、以下、それ以外の事項についても参考のため記載している。 As a result of intensive studies, the present inventors have found that the above problem can be solved by a compound having a repeating unit represented by the following general formula (I).
The compound having a repeating unit represented by the general formula (I) has an alkyl group at a specific position (ortho position with respect to a carbon atom bonded to a nitrogen atom) of the anilino group of the xanthene derivative substituted with the anilino group. And a multimer having a specific linking group at a specific position (meta position with respect to a carbon atom bonded to a nitrogen atom). Although the mechanism of action is unknown, it is considered that the compound has a specific linking group at the meta position with respect to the carbon atom bonded to the nitrogen atom of the anilino group, thereby exhibiting excellent light resistance and ozone resistance. In addition, it is considered that the increase in molecular weight reduces the diffusibility due to the increase in molecular weight and improves the moisture resistance. Furthermore, although the mechanism of action is unclear, it is considered that the filterability at the time of ink preparation was improved by the specific linking group and the increase in quantity.
That is, the present invention is as follows.
<1>
It has a repeating unit represented by the following general formula (1), (2), (3), (4), (5), (6), (7), (8), (9) or (10) Compound.
General formula (1)

In general formula (1), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , and R ^{10 4} represents a hydrogen atom or a substituent ^{independently, R 4, R 9, R} 112 and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ¹⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n101 represents 2 to 100.
General formula (2)

In the general formula ^{(2), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, a hydrogen atom or a substituent each independently ^{R 3} and R ^8, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ²⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n201 represents 2 to 100.
General formula (3)

In the general formula ^{(3), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, a hydrogen atom or a substituent each independently ^{R 3} and R ^8, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ³⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n301 represents 2 to 100.
General formula (4)

In general formula (4), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represents a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰⁵ and R ^{10 6} are each independently hydrogen. represents an atom or a substituent, ^{R 4,} R ^{9, R 112} and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and ^{R 112} and ^{R 115} is Represents a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁴⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n401 represents 2 to 100.
General formula (5)

In general formula (5), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰⁷ and R ¹⁰⁸ each independently represent a hydrogen atom or L ⁵⁰¹ represents an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and at least one group selected from a combination of two or more selected from these substituted An arylene group or an unsubstituted group substituted with at least one group selected from an alkylene group or an unsubstituted alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and combinations thereof Arylene groups, alkyl groups, aralkyl groups, alkenyl groups, alkynyl groups, aryl groups, sulfo groups, and these An alkenylene group or an unsubstituted alkenylene group substituted with at least one group selected from a group consisting of a combination, or a divalent linking group formed by combining two or more selected from these groups, n501 represents 2 to 100 Represent. X ⁵⁰¹ and X ⁵⁰² represent a monoarylaminocarbonyl group substituted with SO ₃ Na .
General formula (6)

In General Formula (6), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁷ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , and R ^{10 4} represents a hydrogen atom or a substituent ^{independently, R 4, R 9, R} 112 and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁶⁰¹ represents an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n601 represents 2 to 100.
General formula (7)

In the general formula ^{(7), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, ^{R 2} and R ⁷ each independently represent a hydrogen atom or a substituent radical, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁷⁰¹ represents an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an alkylene group or an unsubstituted group substituted by at least one group selected from a combination of two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n701 represents 2 to 100.
General formula (8)

In the general formula ^{(8), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, ^{R 2} and R ⁷ each independently represent a hydrogen atom or a substituent radical, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁸⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n801 represents 2 to 100.
General formula (9)

In general formula (9), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁷ , R ¹⁰⁵ and R ^{10 6} are each independently hydrogen. represents an atom or a substituent, ^{R 4,} R ^{9, R 112} and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and ^{R 112} and ^{R 115} is Represents a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁹⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n901 represents 2 to 100.
General formula (10)

In general formula (10), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ³ , R ⁷ , R ⁸ , R ¹⁰⁷ and R ¹⁰⁸ are Each independently represents a hydrogen atom or a substituent, and L ¹⁰⁰¹ is at least selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these. At least one group selected from the group consisting of an alkylene group substituted by one group or an unsubstituted alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof is substituted. Arylene group or unsubstituted arylene group, alkyl group, aralkyl group, alkenyl group, alkynyl group, aryl group, An alkenylene group or an unsubstituted alkenylene group substituted with at least one group selected from a group consisting of a fo group and a combination thereof, or a divalent linking group formed by combining two or more selected from these groups; n1001 represents 2-100. X ⁵⁰¹ and X ⁵⁰² are each independently a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted aryl Carbonyl group, substituted or unsubstituted alkylsulfonyl group, substituted or unsubstituted arylsulfonyl group, substituted or unsubstituted alkoxycarbonyl group, substituted or unsubstituted aryloxycarbonyl group, substituted or unsubstituted monoalkylaminocarbonyl group Represents a substituted or unsubstituted dialkylaminocarbonyl group, a substituted or unsubstituted monoarylaminocarbonyl group, a substituted or unsubstituted diarylaminocarbonyl group, or a substituted or unsubstituted alkylarylaminocarbonyl group.
However, L ¹⁰⁰¹ represents a divalent linking group represented by the following formula (LL4), or X ⁵⁰¹ and X ⁵⁰² represent a monoarylaminocarbonyl group substituted with CO ₂ Na and OH.

<2>
A compound having a repeating unit represented by the general formula (1), (2), (3), (4), (6), (7), (8) or (9), wherein R ⁴ and The compound according to <1>, wherein R ⁹ represents a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na .
<3>
A compound having a repeating unit represented by the general formula (1), (2), (3), (4), (5) or (10), wherein R ³ and R ⁸ are each independently substituted or The compound according to <1>, which represents an unsubstituted alkyl group.
<4>
A compound having a repeating unit represented by the general formula (1), (2), (3) or (4), wherein R ³ and R ⁸ are each independently a hydrogen atom, a substituted or unsubstituted alkyl group Substituted or unsubstituted aryl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino A group, a substituted or unsubstituted alkylsulfonylamino group, a substituted or unsubstituted arylsulfonylamino group, a substituted or unsubstituted alkylureido group, a substituted or unsubstituted arylureido group, a sulfo group, a carboxyl group, or a halogen atom. The compound according to any one of <1> to <3>.
<5>
The general formula (1), (2), (3) or a compound having a repeating unit represented by (4), ^{R 4} and ^{R 9} to display the SO ₃ Na, and ^{R 112} and ^{R 115} There compounds described in Table to <1> a hydrogen atom.
<6>
A coloring composition containing the compound according to any one of <1> to <5>.
<7>
<1>-<5> The ink for inkjet recording containing the compound of any one of <5>.
<8>
An ink jet recording method using the ink for ink jet recording according to <7>.
<9>
An ink jet printer cartridge filled with the ink for ink jet recording according to <7>.
<10>
An ink jet recorded matter in which a colored image is formed on a recording material using the ink for ink jet recording described in <7>.
<11>
A color filter containing the compound according to any one of <1> to <5>.
<12>
A color toner containing the compound according to any one of <1> to <5>.
<13>
<1>-<5> The transfer ink containing the compound of any one of <5>.
The present invention is an invention according to the above <1> to <13>, but other matters are described below for reference.

一般式（Ｄ）

一般式（Ｉ）中、Ｌ^１は２価の連結基を表し、Ｄ^１は一般式（Ｄ）で表される化合物から水素原子を２個取り除いた部分構造を表す。ｎ^１は、２〜１００を表す。
一般式（Ｄ）中、Ｒ^１、Ｒ^５、Ｒ^６、及びＲ^１０は各々独立に置換若しくは無置換のアルキル基を表し、Ｒ^４、Ｒ^９、Ｒ^１１２及びＲ^１１５は各々独立に水素原子又は置換基を表す。Ｒ^ａ１は置換基を表し、ｎ^ａ１は０〜４の整数を表す。Ｘ^１、Ｘ^２、Ｘ^３及びＸ^４は各々独立に水素原子又は置換基を表す。ただし、Ｘ^１、Ｘ^２、Ｘ^３及びＸ^４のいずれか１つは、下記Ｘ群から選ばれる基を表す。
Ｘ群：ヒドロキシル基、置換若しくは無置換のアミノ基、置換若しくは無置換のアシルアミノ基、置換若しくは無置換のアシルオキシ基、置換若しくは無置換のスルホニル基、置換若しくは無置換のアミノカルボニルオキシ基、置換若しくは無置換のスルホニルアミノ基、置換若しくは無置換のスルファモイル基、置換若しくは無置換のウレイド基、置換若しくは無置換のアシル基、カルボキシル基、置換若しくは無置換のカルバモイル基、置換若しくは無置換のオキシカルボニル基、メルカプト基。
［２］
上記一般式（Ｉ）で表される繰り返し単位が、下記一般式（１）、（２）、（３）又は（４）で表される繰り返し単位である、［１］に記載の化合物。
一般式（１）

一般式（１）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３、Ｒ^４、Ｒ^８、Ｒ^９、Ｒ^１０１、Ｒ^１０２、Ｒ^１０３、Ｒ^１０４、Ｒ^１１２及びＲ^１１５は各々独立に水素原子又は置換基を表し、Ｌ^１０１は２価の連結基を表し、ｎ１０１は２〜１００を表す。
一般式（２）

一般式（２）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３、Ｒ^４、Ｒ^８、Ｒ^９、Ｒ^１１２及びＲ^１１５は各々独立に水素原子又は置換基を表し、Ｌ^２０１は２価の連結基を表し、ｎ２０１は２〜１００を表す。
一般式（３）

一般式（３）中、Ｒ^１、Ｒ^５、Ｒ^６、及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３、Ｒ^４、Ｒ^８、Ｒ^９、Ｒ^１１２及びＲ^１１５は各々独立に水素原子又は置換基を表し、Ｌ^３０１は２価の連結基を表し、ｎ３０１は２〜１００を表す。
一般式（４）

一般式（４）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３、Ｒ^４、Ｒ^８、Ｒ^９、Ｒ^１０５、Ｒ^１０６、Ｒ^１１２及びＲ^１１５は各々独立に水素原子又は置換基を表し、Ｌ^４０１は２価の連結基を表し、ｎ４０１は２〜１００を表す。
［３］
Ｌ^１０１、Ｌ^２０１及びＬ^３０１が各々独立に置換若しくは無置換のアルキレン基、置換若しくは無置換のアリーレン基、置換若しくは無置換のアルケニレン基、又はこれらから選ばれる２種以上を組み合わせてなる２価の連結基である［２］に記載の化合物。
［４］
Ｒ^３、Ｒ^４、Ｒ^８及びＲ^９が各々独立に水素原子、置換若しくは無置換のアルキル基、置換若しくは無置換のアリール基、置換若しくは無置換のアルコキシ基、置換若しくは無置換のアリールオキシ基、置換若しくは無置換のアミノ基、置換若しくは無置換のアシルアミノ基、置換若しくは無置換のアルコキシカルボニルアミノ基、置換若しくは無置換のアルキルスルホニルアミノ基、置換若しくは無置換のアリールスルホニルアミノ基、置換若しくは無置換のアルキルウレイド基、置換若しくは無置換のアリールウレイド基、スルホ基、カルボキシル基、又はハロゲン原子を表す［２］又は［３］に記載の化合物。
［５］
Ｒ^４及びＲ^９がスルホ基を表す［１］〜［３］のいずれか１項に記載の化合物。
［６］
Ｒ^１１２及びＲ^１１５がスルホ基を表す［１］〜［３］のいずれか１項に記載の化合物。
［７］
Ｒ^３及びＲ^８が各々独立に置換若しくは無置換のアルキル基を表す［１］〜［４］のいずれか１項に記載の化合物。
［８］
［１］〜［７］のいずれか１項に記載の化合物を含有する着色組成物。
［９］
［１］〜［７］のいずれか１項に記載の化合物を含有するインクジェット記録用インク。
［１０］
［９］に記載のインクジェット記録用インクを用いるインクジェット記録方法。
［１１］
［９］に記載のインクジェット記録用インクを充填したインクジェットプリンタカートリッジ。
［１２］
［９］に記載のインクジェット記録用インクを用いて、被記録材に着色画像を形成したインクジェット記録物。
［１３］
［１］〜［７］のいずれか１項に記載の化合物を含有するカラーフィルタ。
［１４］
［１］〜［７］のいずれか１項に記載の化合物を含有するカラートナー。
［１５］
［１］〜［７］のいずれか１項に記載の化合物を含有する転写用インク。[1]
The compound which has a repeating unit represented by the following general formula (I).

Formula (D)

In General Formula (I), L ¹ represents a divalent linking group, and D ¹ represents a partial structure in which two hydrogen atoms are removed from the compound represented by General Formula (D). n ¹ represents 2 to 100.
In general formula (D), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represents a substituted or unsubstituted alkyl group, and R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom. Or represents a substituent. R ^a1 represents a substituent, and n ^a1 represents an integer of 0 to 4. X ¹ , X ² , X ³ and X ⁴ each independently represent a hydrogen atom or a substituent. However, any one of X ¹ , X ² , X ³ and X ⁴ represents a group selected from the following group X.
Group X: hydroxyl group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted acyloxy group, substituted or unsubstituted sulfonyl group, substituted or unsubstituted aminocarbonyloxy group, substituted or Unsubstituted sulfonylamino group, substituted or unsubstituted sulfamoyl group, substituted or unsubstituted ureido group, substituted or unsubstituted acyl group, carboxyl group, substituted or unsubstituted carbamoyl group, substituted or unsubstituted oxycarbonyl group , Mercapto group.
[2]
The compound according to [1], wherein the repeating unit represented by the general formula (I) is a repeating unit represented by the following general formula (1), (2), (3) or (4).
General formula (1)

In general formula (1), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , R ¹⁰⁴ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, L ¹⁰¹ represents a divalent linking group, and n101 represents 2 to 100.
General formula (2)

In general formula (2), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹¹² and R ¹¹⁵ are Each independently represents a hydrogen atom or a substituent, L ²⁰¹ represents a divalent linking group, and n201 represents 2 to 100.
General formula (3)

In general formula (3), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹¹² and R ^115. Each independently represents a hydrogen atom or a substituent, L ³⁰¹ represents a divalent linking group, and n301 represents 2 to 100.
General formula (4)

In the general formula (4), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹⁰⁵ , R ¹⁰⁶ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, L ⁴⁰¹ represents a divalent linking group, and n ⁴⁰¹ represents 2 to 100.
[3]
L ¹⁰¹ , L ²⁰¹ and L ³⁰¹ are each independently a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted alkenylene group, or a divalent combination of two or more selected from these [2] The compound according to [2].
[4]
R ³ , R ⁴ , R ⁸ and R ⁹ are each independently a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group Substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino group, substituted or unsubstituted alkylsulfonylamino group, substituted or unsubstituted arylsulfonylamino group, substituted or unsubstituted The compound according to [2] or [3], which represents a substituted alkylureido group, a substituted or unsubstituted arylureido group, a sulfo group, a carboxyl group, or a halogen atom.
[5]
The compound according to any one of [1] to [3], wherein R ⁴ and R ⁹ represent a sulfo group.
[6]
The compound according to any one of [1] to [3], wherein R ¹¹² and R ¹¹⁵ represent a sulfo group.
[7]
The compound according to any one of [1] to [4], wherein R ³ and R ⁸ each independently represents a substituted or unsubstituted alkyl group.
[8]
A coloring composition containing the compound according to any one of [1] to [7].
[9]
[1] An ink for ink jet recording containing the compound according to any one of [7].
[10]
An ink jet recording method using the ink for ink jet recording according to [9].
[11]
An ink jet printer cartridge filled with the ink for ink jet recording according to [9].
[12]
An ink-jet recorded matter in which a colored image is formed on a recording material using the ink for ink-jet recording described in [9].
[13]
A color filter containing the compound according to any one of [1] to [7].
[14]
A color toner comprising the compound according to any one of [1] to [7].
[15]
A transfer ink containing the compound according to any one of [1] to [7].

  The compound of the present invention can be suitably used for a colored composition and an ink for inkjet recording, and is excellent in filterability at the time of ink preparation. The coloring composition and the ink for inkjet recording of the present invention can form an image excellent in light resistance, ozone resistance, and moisture resistance. In addition, according to the present invention, there are provided an ink jet recording method, an ink jet printer cartridge, and an ink jet recorded matter using the above ink jet recording ink. Furthermore, a color filter, a color toner, and a transfer ink containing the above compound are provided.

  Hereinafter, the present invention will be described in detail. First, specific examples of the substituent in the present invention are defined as a substituent group A.

(Substituent group A)
Halogen atom, alkyl group, aralkyl group, alkenyl group, alkynyl group, aryl group, heterocyclic group, cyano group, hydroxyl group, nitro group, alkoxy group, aryloxy group, silyloxy group, heterocyclic oxy group, acyloxy group, carbamoyl Oxy group, alkoxycarbonyloxy group, aryloxycarbonyloxy group, amino group, acylamino group, aminocarbonylamino group, alkoxycarbonylamino group, aryloxycarbonylamino group, sulfamoylamino group, alkyl or arylsulfonylamino group, mercapto Group, alkylthio group, arylthio group, heterocyclic thio group, sulfamoyl group, alkyl or arylsulfinyl group, alkyl or arylsulfonyl group, acyl group, aryloxycarbonyl group, Job aryloxycarbonyl group, a carbamoyl group, an aryl or heterocyclic azo group, an imido group, a phosphino group, phosphinyl group, phosphinyloxy group, phosphinylamino group, a silyl group, an ionic hydrophilic group mentioned as an example. These substituents may be further substituted, and examples of the further substituent include a group selected from the substituent group A described above.

  As a halogen atom, a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom is mentioned, for example.

Examples of the alkyl group include linear, branched, and cyclic substituted or unsubstituted alkyl groups, and include cycloalkyl groups, bicycloalkyl groups, and tricyclo structures having many ring structures. An alkyl group (for example, an alkyl group of an alkoxy group or an alkylthio group) in a substituent described below also represents such an alkyl group.
As the alkyl group, an alkyl group having 1 to 30 carbon atoms such as a methyl group, an ethyl group, an n-propyl group, an i-propyl group, a t-butyl group, an n-octyl group, an eicosyl group, 2- Examples thereof include a chloroethyl group, a 2-cyanoethyl group, a 2-ethylhexyl group, etc. The cycloalkyl group is preferably a substituted or unsubstituted cycloalkyl group having 3 to 30 carbon atoms, such as a cyclohexyl group, a cyclopentyl group, 4 -N-dodecylcyclohexyl group and the like, and the bicycloalkyl group is preferably a substituted or unsubstituted bicycloalkyl group having 5 to 30 carbon atoms, that is, one hydrogen atom from a bicycloalkane having 5 to 30 carbon atoms. Removed monovalent groups such as bicyclo [1,2,2] heptan-2-yl group, bicyclo [2,2 2] octan-3-yl group.

  Examples of the aralkyl group include a substituted or unsubstituted aralkyl group, and the substituted or unsubstituted aralkyl group is preferably an aralkyl group having 7 to 30 carbon atoms. For example, a benzyl group and a 2-phenethyl group can be mentioned.

Examples of the alkenyl group include linear, branched, and cyclic substituted or unsubstituted alkenyl groups, and include cycloalkenyl groups and bicycloalkenyl groups.
Preferred examples of the alkenyl group include substituted or unsubstituted alkenyl groups having 2 to 30 carbon atoms such as vinyl group, allyl group, prenyl group, geranyl group, and oleyl group. Preferred examples of the cycloalkenyl group include Is a substituted or unsubstituted cycloalkenyl group having 3 to 30 carbon atoms, that is, a monovalent group obtained by removing one hydrogen atom of a cycloalkene having 3 to 30 carbon atoms, such as a 2-cyclopenten-1-yl group, 2-cyclohexen-1-yl group and the like. As the bicycloalkenyl group, a substituted or unsubstituted bicycloalkenyl group, preferably a substituted or unsubstituted bicycloalkenyl group having 5 to 30 carbon atoms, that is, a double bond A monovalent group obtained by removing one hydrogen atom from a bicycloalkene having one of, for example, bicyclo [2,2,1] Hept-2-en-1-yl group, a bicyclo [2,2,2] oct-2-en-4-yl group and the like.

  The alkynyl group is preferably a substituted or unsubstituted alkynyl group having 2 to 30 carbon atoms such as an ethynyl group, a propargyl group, and a trimethylsilylethynyl group.

  The aryl group is preferably a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, such as a phenyl group, a p-tolyl group, a naphthyl group, an m-chlorophenyl group, an o-hexadecanoylaminophenyl group, and the like. Can be mentioned.

  The heterocyclic group is preferably a monovalent group obtained by removing one hydrogen atom from a 5- or 6-membered substituted or unsubstituted aromatic or non-aromatic heterocyclic compound, and more preferably a carbon number. Examples thereof include 3 to 30 5- or 6-membered aromatic heterocyclic groups such as a 2-furyl group, a 2-thienyl group, a 2-pyrimidinyl group, and a 2-benzothiazolyl group. Examples of non-aromatic heterocyclic groups include morpholinyl groups.

  The alkoxy group is preferably a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, such as a methoxy group, an ethoxy group, an isopropoxy group, a t-butoxy group, an n-octyloxy group, or a 2-methoxyethoxy group. Etc.

  The aryloxy group is preferably a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, such as a phenoxy group, 2-methylphenoxy group, 4-t-butylphenoxy group, 3-nitrophenoxy group, 2 -Tetradecanoylaminophenoxy group etc. are mentioned.

  Preferred examples of the silyloxy group include substituted or unsubstituted silyloxy groups having 0 to 20 carbon atoms such as a trimethylsilyloxy group and a diphenylmethylsilyloxy group.

  Preferred examples of the heterocyclic oxy group include substituted or unsubstituted heterocyclic oxy groups having 2 to 30 carbon atoms, such as a 1-phenyltetrazole-5-oxy group and a 2-tetrahydropyranyloxy group.

  The acyloxy group is preferably a formyloxy group, a substituted or unsubstituted alkylcarbonyloxy group having 2 to 30 carbon atoms, a substituted or unsubstituted arylcarbonyloxy group having 6 to 30 carbon atoms, such as an acetyloxy group, Examples include a pivaloyloxy group, a stearoyloxy group, a benzoyloxy group, and a p-methoxyphenylcarbonyloxy group.

  The carbamoyloxy group is preferably a substituted or unsubstituted carbamoyloxy group having 1 to 30 carbon atoms, such as N, N-dimethylcarbamoyloxy group, N, N-diethylcarbamoyloxy group, morpholinocarbonyloxy group, N , N-di-n-octylaminocarbonyloxy group, Nn-octylcarbamoyloxy group and the like.

  The alkoxycarbonyloxy group is preferably a substituted or unsubstituted alkoxycarbonyloxy group having 2 to 30 carbon atoms, such as a methoxycarbonyloxy group, an ethoxycarbonyloxy group, a t-butoxycarbonyloxy group, or an n-octylcarbonyloxy group. Etc.

  The aryloxycarbonyloxy group is preferably a substituted or unsubstituted aryloxycarbonyloxy group having 7 to 30 carbon atoms, such as phenoxycarbonyloxy group, p-methoxyphenoxycarbonyloxy group, pn-hexadecyloxy. Examples include phenoxycarbonyloxy group.

  The amino group includes an alkylamino group, an arylamino group, and a heterocyclic amino group, preferably an amino group, a substituted or unsubstituted alkylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted group having 6 to 30 carbon atoms. Examples of the substituted anilino group include a methylamino group, a dimethylamino group, an anilino group, an N-methyl-anilino group, a diphenylamino group, and a triazinylamino group.

  The acylamino group is preferably a formylamino group, a substituted or unsubstituted alkylcarbonylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted arylcarbonylamino group having 6 to 30 carbon atoms, such as an acetylamino group, Examples include pivaloylamino group, lauroylamino group, benzoylamino group, 3,4,5-tri-n-octyloxyphenylcarbonylamino group, and the like.

  The aminocarbonylamino group is preferably a substituted or unsubstituted aminocarbonylamino group having 1 to 30 carbon atoms, such as a carbamoylamino group, N, N-dimethylaminocarbonylamino group, or N, N-diethylaminocarbonylamino group. And a morpholinocarbonylamino group.

  The alkoxycarbonylamino group is preferably a substituted or unsubstituted alkoxycarbonylamino group having 2 to 30 carbon atoms, such as methoxycarbonylamino group, ethoxycarbonylamino group, t-butoxycarbonylamino group, n-octadecyloxycarbonylamino. Group, N-methyl-methoxycarbonylamino group and the like.

  The aryloxycarbonylamino group is preferably a substituted or unsubstituted aryloxycarbonylamino group having 7 to 30 carbon atoms, such as phenoxycarbonylamino group, p-chlorophenoxycarbonylamino group, mn-octyloxyphenoxy. Examples thereof include a carbonylamino group.

  The sulfamoylamino group is preferably a substituted or unsubstituted sulfamoylamino group having 0 to 30 carbon atoms, such as a sulfamoylamino group, N, N-dimethylaminosulfonylamino group, Nn- Examples include octylaminosulfonylamino group.

The alkyl or arylsulfonylamino group is preferably a substituted or unsubstituted alkylsulfonylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfonylamino group having 6 to 30 carbon atoms, such as a methylsulfonylamino group. Butylsulfonylamino group, phenylsulfonylamino group, 2,3,5-trichlorophenylsulfonylamino group, p-methylphenylsulfonylamino group, and the like.
Preferred examples of the alkylthio group include substituted or unsubstituted alkylthio groups having 1 to 30 carbon atoms, such as a methylthio group, an ethylthio group, and an n-hexadecylthio group.

  Preferred examples of the arylthio group include substituted or unsubstituted arylthio groups having 6 to 30 carbon atoms such as a phenylthio group, a p-chlorophenylthio group, and an m-methoxyphenylthio group.

  Preferred examples of the heterocyclic thio group include substituted or unsubstituted heterocyclic thio groups having 2 to 30 carbon atoms, such as a 2-benzothiazolylthio group and a 1-phenyltetrazol-5-ylthio group.

  The sulfamoyl group is preferably a substituted or unsubstituted sulfamoyl group having 0 to 30 carbon atoms, such as N-ethylsulfamoyl group, N- (3-dodecyloxypropyl) sulfamoyl group, N, N-dimethylsulfuryl group. Examples include a famoyl group, an N-acetylsulfamoyl group, an N-benzoylsulfamoyl group, and an N- (N′-phenylcarbamoyl) sulfamoyl group.

  The alkyl or arylsulfinyl group is preferably a substituted or unsubstituted alkylsulfinyl group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfinyl group having 6 to 30 carbon atoms, such as a methylsulfinyl group or an ethylsulfinyl group. , Phenylsulfinyl group, p-methylphenylsulfinyl group and the like.

  The alkyl or arylsulfonyl group is preferably a substituted or unsubstituted alkylsulfonyl group having 1 to 30 carbon atoms, a substituted or unsubstituted arylsulfonyl group having 6 to 30 carbon atoms, such as a methylsulfonyl group or an ethylsulfonyl group. , Phenylsulfonyl group, p-methylphenylsulfonyl group and the like.

  The acyl group is preferably a formyl group, a substituted or unsubstituted alkylcarbonyl group having 2 to 30 carbon atoms, a substituted or unsubstituted arylcarbonyl group having 7 to 30 carbon atoms, a substituted or unsubstituted group having 2 to 30 carbon atoms. Heterocyclic carbonyl groups bonded to carbonyl groups at substituted carbon atoms, such as acetyl, pivaloyl, 2-chloroacetyl, stearoyl, benzoyl, pn-octyloxyphenylcarbonyl, 2-pyridyl Examples thereof include a carbonyl group and a 2-furylcarbonyl group.

  The aryloxycarbonyl group is preferably a substituted or unsubstituted aryloxycarbonyl group having 7 to 30 carbon atoms, such as phenoxycarbonyl group, o-chlorophenoxycarbonyl group, m-nitrophenoxycarbonyl group, pt- A butylphenoxycarbonyl group etc. are mentioned.

  The alkoxycarbonyl group is preferably a substituted or unsubstituted alkoxycarbonyl group having 2 to 30 carbon atoms, such as a methoxycarbonyl group, an ethoxycarbonyl group, a t-butoxycarbonyl group, and an n-octadecyloxycarbonyl group.

  The carbamoyl group is preferably a substituted or unsubstituted carbamoyl group having 1 to 30 carbon atoms, such as a carbamoyl group, an N-methylcarbamoyl group, an N, N-dimethylcarbamoyl group, or an N, N-di-n-octyl group. Examples thereof include a carbamoyl group and an N- (methylsulfonyl) carbamoyl group.

  The aryl or heterocyclic azo group is preferably a substituted or unsubstituted arylazo group having 6 to 30 carbon atoms, a substituted or unsubstituted heterocyclic azo group having 3 to 30 carbon atoms, such as a phenylazo group or p-chlorophenylazo group. Group, 5-ethylthio-1,3,4-thiadiazol-2-ylazo group and the like.

  Preferred examples of the imide group include an N-succinimide group and an N-phthalimide group.

  The phosphino group is preferably a substituted or unsubstituted phosphino group having 0 to 30 carbon atoms, such as a dimethylphosphino group, a diphenylphosphino group, a methylphenoxyphosphino group, and the like.

  The phosphinyl group is preferably a substituted or unsubstituted phosphinyl group having 0 to 30 carbon atoms, such as a phosphinyl group, a dioctyloxyphosphinyl group, a diethoxyphosphinyl group, and the like.

  Preferred examples of the phosphinyloxy group include substituted or unsubstituted phosphinyloxy groups having 0 to 30 carbon atoms such as a diphenoxyphosphinyloxy group and a dioctyloxyphosphinyloxy group.

  The phosphinylamino group is preferably a substituted or unsubstituted phosphinylamino group having 0 to 30 carbon atoms, such as a dimethoxyphosphinylamino group or a dimethylaminophosphinylamino group.

  Preferred examples of the silyl group include substituted or unsubstituted silyl groups having 0 to 30 carbon atoms such as a trimethylsilyl group, a t-butyldimethylsilyl group, and a phenyldimethylsilyl group.

  Examples of the ionic hydrophilic group include a sulfo group, a carboxyl group, a thiocarboxyl group, a sulfino group, a phosphono group, a dihydroxyphosphino group, and a quaternary ammonium group. Particularly preferred are a sulfo group and a carboxyl group. The carboxyl group, phosphono group and sulfo group may be in the form of a salt. Examples of counter cations that form a salt include ammonium ion, alkali metal ion (eg, lithium ion, sodium ion, potassium ion) and organic. Cation (eg, tetramethylammonium ion, tetramethylguanidinium ion, tetramethylphosphonium) is included, lithium salt, sodium salt, potassium salt, ammonium salt is preferable, sodium salt or mixed salt containing sodium salt as main component Are more preferred, and the sodium salt is most preferred.

  In the present invention, when the compound is a salt, the salt is dissociated into ions in the water-soluble ink.

[Compound having a repeating unit represented by formula (I)]

  Formula (D)

In General Formula (I), L ¹ represents a divalent linking group, and D ¹ represents a partial structure in which two hydrogen atoms are removed from the compound represented by General Formula (D). n ¹ represents 2 to 100.
In general formula (D), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represents a substituted or unsubstituted alkyl group, and R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom. Or represents a substituent. R ^a1 represents a substituent, and n ^a1 represents an integer of 0 to 4. X ¹ , X ² , X ³ and X ⁴ each independently represent a hydrogen atom or a substituent. However, any one of X ¹ , X ² , X ³ and X ⁴ represents a group selected from the following group X.
Group X: hydroxyl group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted acyloxy group, substituted or unsubstituted sulfonyl group, substituted or unsubstituted aminocarbonyloxy group, substituted or Unsubstituted sulfonylamino group, substituted or unsubstituted sulfamoyl group, substituted or unsubstituted ureido group, substituted or unsubstituted acyl group, carboxyl group, substituted or unsubstituted carbamoyl group, substituted or unsubstituted oxycarbonyl group , Mercapto group.

In general formula (I), X ¹ , X ² , X ³ and X ⁴ each independently represent a hydrogen atom or a substituent.
In general formula (I), X ¹ , X ² , X ³ and X ⁴ are each independently a hydrogen atom, a substituted or unsubstituted alkyl group, substituted or unsubstituted, from the viewpoint of availability of raw materials and ease of synthesis. Substituted aryl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino group, substituted or It preferably represents an unsubstituted alkylsulfonylamino group, a substituted or unsubstituted arylsulfonylamino group, a substituted or unsubstituted alkylureido group, a substituted or unsubstituted arylureido group, a sulfo group, a carboxyl group, or a halogen atom. , More preferably a hydrogen atom, a substituted or unsubstituted alkyl group, or sulfo , And particularly preferably a substituted or unsubstituted alkyl group. As an alkyl group, a C1-C6 alkyl group is preferable, a C1-C3 alkyl group is more preferable, and a methyl group is still more preferable. In addition, when each group has a substituent, examples of the substituent include a substituent selected from the above substituent group A. A substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a hydroxyl group, a substituted or An unsubstituted amino group is preferred.
In the case where X ¹ , X ² , X ³ and X ⁴ further have a substituent, the substituent is selected from the substituent group A, and preferably an alkyl group. X ¹ , X ² , X ³ and X ⁴ are preferably unsubstituted.

However, in the general formula (I), any one of X ¹ , X ² , X ³ and X ⁴ represents a group selected from the group X.
The group X is preferably a hydroxyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted acyloxy group, a substituted or unsubstituted sulfonylamino group, and a substituted or unsubstituted ureido group More preferably, it is a substituted or unsubstituted alkylamino group, a substituted or unsubstituted arylamino group, a substituted or unsubstituted heterylamino group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted alkylsulfonylamino group. A substituted or unsubstituted arylsulfonylamino group, and a substituted or unsubstituted ureido group.

In general formula (I), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and from the viewpoint of availability of raw materials and ease of synthesis, A C1-C6 alkyl group is preferable, a C1-C3 alkyl group is more preferable, and a methyl group is still more preferable. Moreover, as a substituent in case an alkyl group has a substituent, the substituent chosen from the said substituent group A is mentioned, A chlorine atom is preferable.

In general formula (I), R ⁴ and R ⁹ each independently represent a hydrogen atom or a substituent, and examples of the substituent include a substituent selected from the above substituent group A.

In general formula (I), R ⁴ and R ⁹ are each independently a hydrogen atom, a substituted or unsubstituted alkyl group, substituted or unsubstituted, from the viewpoints of availability of raw materials and ease of synthesis, light resistance, and ozone resistance. Unsubstituted aryl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino group, substituted Or unsubstituted alkylsulfonylamino group, substituted or unsubstituted arylsulfonylamino group, substituted or unsubstituted alkylureido group, substituted or unsubstituted arylureido group, sulfo group, substituted or unsubstituted sulfonamido group, carboxyl Preferably represents a group or a halogen atom, more preferably a substituent. Is an unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino group, substituted or unsubstituted alkylsulfonylamino group, substituted or unsubstituted arylsulfonylamino group, substituted or unsubstituted alkylureido group, substituted or unsubstituted Of the arylureido group or sulfo group, particularly preferably a sulfo group. In addition, examples of the substituent in the case where each group has a substituent include a substituent selected from the above substituent group A, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted group. An amino group is preferred.

In the general formula (I), R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, and examples of the substituent include a substituent selected from the above-mentioned substituent group A. From the viewpoints of ease and light resistance, each independently preferably a hydrogen atom, a substituted or unsubstituted alkyl group, a sulfo group, or a substituted or unsubstituted sulfamoyl group, more preferably a hydrogen atom or a sulfo group. preferable.

From the viewpoint of solubility, at least ^one of R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² and R ¹¹⁵ in general formula (I) is It preferably has an ionic hydrophilic group such as a carboxyl group, a sulfo group, or a phosphono group, more preferably at least two are ionic hydrophilic groups, and represents a sulfo group among the ionic hydrophilic groups. Is preferred. Examples of the counter cation of these ionic hydrophilic groups include a hydrogen atom (proton), an alkali metal cation (lithium ion, sodium ion, or potassium ion), an ammonium ion, and the like, but easy synthesis (as dye powder) From the viewpoint of ease of handling, it is preferably an alkali metal cation.

In the general formula (I), L ¹ represents a divalent linking group, and is a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted alkenylene group, a substituted or unsubstituted divalent divalent group. It is preferably a heterocyclic group or a divalent linking group formed by combining two or more selected from these.
The alkylene group may be linear, branched or cyclic. The number of carbon atoms of the alkylene group is preferably 1-18, more preferably 2-16, and still more preferably 4-8. Preferable specific examples of the alkylene group include a methylene group, an ethylene group, a propylene group, and a cyclohexylene group (preferably 1,3-cyclohexylene group or 1,4-cyclohexylene group). Examples of the substituent in the case where the alkylene group has a substituent include a substituent selected from the above substituent group A, and a 1,4-cyclohexylene group is preferable.
The arylene group is preferably an arylene group having 6 to 14 carbon atoms, more preferably an arylene group having 6 to 10 carbon atoms, a phenylene group (preferably a 1,3-phenylene group or a 1,4-phenylene group) or a naphthylene group. (Preferably 1,5-naphthylene group, 2,6-naphthylene group) is more preferable. In addition, examples of the substituent in the case where the aryloxy group has a substituent include a substituent selected from the above substituent group A, an ionic hydrophilic group is preferable, a carboxyl group or a sulfo group is more preferable, and a sulfo group is Further preferred.
The alkenylene group is preferably an alkenylene group having 2 to 18 carbon atoms, more preferably an alkenylene group having 2 to 12 carbon atoms, and still more preferably an alkenylene group having 2 to 8 carbon atoms. Preferred specific examples of the alkenylene group are preferably a vinylene group and a 2-butenyl group. Examples of the substituent when the alkenylene group has a substituent include a substituent selected from the above substituent group A, and an alkyl group is preferable.
In addition, as a divalent linking group formed by combining two or more selected from a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, and a substituted or unsubstituted alkenylene group, specifically, the following formula (LL1), (LL2), (LL3), (LL4), (LL5) and the like are preferable. The following (LL6) is mentioned as an example of a bivalent heterocyclic group. Further, an oxygen atom may be present in the alkylene chain of the alkylene group, and examples of such a case include the following (LL7).

In the general formula (I), R ^a1 represents a substituent, and a substituent selected from the above substituent group A is preferable. n ^a1 represents an integer of 0 to 4, preferably 0 to 3, more preferably 0 to 2, still more preferably 0 or 1, and particularly preferably 0.

In the general formula (I), ^{n 1} represents 2 to 100, preferably 2 to 50 from the viewpoint of solubility and moisture resistance, and more preferably from 2 to 30, more preferably 2 to 15. n ¹ does not need to be an integer, and when it is a decimal, it represents an average value of the mixture and can be calculated from molecular weight measurement by gel permeation chromatography (GPC) measurement. In this specification, unless otherwise specified, GPC uses HLC-8020 GPC (manufactured by Tosoh Corporation), and columns are TSKgel SuperHZM-H, TSKgel SuperHZ4000, TSKgel.
Measured with Super HZ200 (manufactured by Tosoh Corporation), the number average molecular weight was calculated in terms of polystyrene. The carrier may be selected as appropriate, but tetrahydrofuran is used as long as it can be dissolved.
Moreover, the structure of the terminal of the compound which has a repeating unit represented by general formula (I) is not specifically limited, It is based on the compound etc. which are used for a synthesis | combination. The same applies to the compounds having the repeating units represented by the general formulas (1) to (9).

  The repeating unit represented by the general formula (I) is preferably a repeating unit represented by any one of the following general formulas (1) to (9), and any one of the general formulas (1) to (5). It is more preferable that it is a repeating unit represented by general formula (1)-(4), and it is still more preferable that it is a repeating unit represented by either.

[Compound having a repeating unit represented by general formula (1) or general formula (6)]
The repeating unit represented by the following general formula (1) or general formula (6) will be described.

  General formula (1)

In general formula (1), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , R ¹⁰⁴ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, L ¹⁰¹ represents a divalent linking group, and n101 represents 2 to 100.

  General formula (6)

In General Formula (6), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁴ , R ⁷ , R ⁹ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , R ¹⁰⁴ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, L ⁶⁰¹ represents a divalent linking group, and n601 represents 2 to 100.

Formula (1), the general formula (6) in n101, and n601 are synonymous with ^{n 1} of formula (I), and also specific examples and preferred ranges.
The divalent linking group represented by L ¹⁰¹ and L ⁶⁰¹ has the same meaning as the divalent linking group represented by L ¹ in formula (I), and specific examples and preferred ranges thereof are also the same.
R ¹ , R ⁴ , R ⁵ , R ⁶ , R ⁹ , R ¹⁰ , R ¹¹² and R ¹¹⁵ in general formula (1) and general formula (6) are respectively R ¹ and R in general formula (D). ⁴ , R ⁵ , R ⁶ , R ⁹ , R ¹⁰ , R ¹¹² and R ¹¹⁵ , and specific examples and preferred ranges are also the same.
In general formula (1) and general formula (6), R ² , R ³ , R ⁷ and R ⁸ each independently represent a hydrogen atom or a substituent, and the substituent is a substituent selected from the above substituent group A. Groups. In view of availability of raw materials and ease of synthesis, each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy Group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino group, substituted or unsubstituted alkylsulfonylamino group, substituted or unsubstituted arylsulfonylamino group, substituted or It preferably represents an unsubstituted alkylureido group, a substituted or unsubstituted arylureido group, a sulfo group, a carboxyl group, or a halogen atom, more preferably a hydrogen atom, a substituted or unsubstituted alkyl group, or a sulfo group. Particularly preferably substituted or unsubstituted al A Le group. As an alkyl group, a C1-C6 alkyl group is preferable, a C1-C3 alkyl group is more preferable, and a methyl group is still more preferable. In addition, when each group has a substituent, examples of the substituent include a substituent selected from the above substituent group A. A substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a hydroxyl group, a substituted or An unsubstituted amino group is preferred.

From the viewpoint of solubility, at least one of R ^{1 to} R ¹⁰ , R ¹¹² and R ^{115 in} the general formulas (1) and (6) is an ionic hydrophilic group such as a carboxyl group, a sulfo group, or a phosphono group. It is preferable to have an ionic group, more preferably at least two are ionic hydrophilic groups, and it is preferable to represent a sulfo group among the ionic hydrophilic groups. Examples of the counter cation of these ionic hydrophilic groups include a hydrogen atom (proton), an alkali metal cation (lithium ion, sodium ion, or potassium ion), an ammonium ion, and the like, but easy synthesis (as dye powder) From the viewpoint of ease of handling, it is preferably an alkali metal cation.

In general formula (1) and general formula (6), R ¹⁰¹ , R ¹⁰² , R ¹⁰³ and R ¹⁰⁴ each independently represent a hydrogen atom or a substituent, and from the viewpoint of availability of raw materials, a hydrogen atom, substituted or unsubstituted An alkyl group, a substituted or unsubstituted aryl group is preferred, a hydrogen atom or a substituted or unsubstituted alkyl group is more preferred, a hydrogen atom or an alkyl group having 1 to 6 carbon atoms is further preferred, and a hydrogen atom is most preferred.

Although the specific example of the compound which has a repeating unit represented by General formula (1) or General formula (6) below is given, it is not necessarily limited to these. In the structural formulas of the following specific compounds, Me represents a methyl group.
In each of the following specific compounds, the terminal structure is a residue based on the following intermediate (B).

  The compound having a repeating unit represented by the general formula (1) can be synthesized, for example, according to the following route. Ph represents a phenyl group.

Intermediate (A) (for example, synthesized by the method described in JP2011-148993A) is reacted with phenyl chlorocarbonate to synthesize intermediate (B), and a diamine compound represented by linking group (1) By making it react, the compound which has a repeating unit represented by General formula (1) can be obtained. In addition, R < ¹ >, R < ³ >, R < ⁴ >, R < ⁵ >, R < ⁶ >, R < ⁸ >, R <^9> , R < ¹⁰ > in intermediate (A), intermediate (B), linking group (1) and general formula (1), R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , R ¹⁰⁴ , R ¹¹² , R ¹¹⁵ and L ¹⁰¹ are R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ^{9 in} the general formula (1). , R ¹⁰ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , R ¹⁰⁴ , R ¹¹² , R ¹¹⁵ and L ¹⁰¹ , and preferred examples are also the same. More specific synthesis methods are exemplified in the examples. A compound having a repeating unit represented by the general formula (6) can also be synthesized by the same method as described above.

[Compound having a repeating unit represented by formula (2) or formula (7)]
The compound having a repeating unit represented by the following general formula (2) or general formula (7) will be described.

  General formula (2)

In general formula (2), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹¹² and R ¹¹⁵ are Each independently represents a hydrogen atom or a substituent, L ²⁰¹ represents a divalent linking group, and n201 represents 2 to 100.

  General formula (7)

In general formula (7), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁴ , R ⁷ , R ⁹ , R ¹¹² and R ¹¹⁵ are Each independently represents a hydrogen atom or a substituent, L ⁷⁰¹ represents a divalent linking group, and n701 represents 2 to 100.

In general formula (2), R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ²⁰¹ , and n201 are each in general formula (1). R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ¹⁰¹ , and n101 are synonymous and the preferred ranges are also the same.
In General Formula (7), R ¹ , R ² , R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁷⁰¹ , and n701 are each in General Formula (6). R ¹ , R ² , R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁶⁰¹ , n601 have the same meanings and preferred ranges are also the same.

Although the specific example of the compound which has a repeating unit represented by General formula (2) or General formula (7) below is given, it is not necessarily limited to these. In the structural formulas of the following specific compounds, Me represents a methyl group.
In each of the following specific compounds, the terminal structure is an amino group.

  The compound having the repeating unit represented by the general formula (2) can be synthesized, for example, according to the following route.

By reacting the intermediate (A) (for example, synthesized by the method described in JP2011-148993A) with the compound represented by the linking group (2), the repeating unit represented by the general formula (2) is converted. The compound which has can be obtained. Note Intermediate (A), ^R 1 in the linking group (2) and the general formula ^{(2), R 3, R} 4, R 5, R 6, R 8, R 9, R 10, R 112, R 115 and L ²⁰¹ is the same as or preferable to R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ and L ^{201 in} the general formula (2). The example is the same. A compound having a repeating unit represented by the general formula (7) can also be synthesized by the same method as described above. More specific synthesis methods are exemplified in the examples.

[Compound having a repeating unit represented by general formula (3) or general formula (8)]
The compound having a repeating unit represented by the following general formula (3) or general formula (8) will be described.

  General formula (3)

一般式（３）中、Ｒ^１、Ｒ^５、Ｒ^６及びＲ^１０は各々独立に置換又は無置換のアルキル基を表し、Ｒ^３、Ｒ^４、Ｒ^８、Ｒ^９、Ｒ^１１２及びＲ^１１５は各々独立に水素原子又は置換基を表し、Ｌ^３０１は２価の連結基を表し、ｎ３０１は２〜１００を表す。

In general formula (3), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹¹² and R ¹¹⁵ are Each independently represents a hydrogen atom or a substituent, L ³⁰¹ represents a divalent linking group, and n301 represents 2 to 100.

  General formula (8)

In the general formula (8), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁴ , R ⁷ , R ⁹ , R ¹¹² and R ¹¹⁵ are Each independently represents a hydrogen atom or a substituent, L ⁸⁰¹ represents a divalent linking group, and n801 represents 2 to 100.

In general formula (3), R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ³⁰¹ , and n301 are each in general formula (1). R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ¹⁰¹ , and n101 are synonymous and the preferred ranges are also the same.
In General Formula (8), R ¹ , R ² , R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁸⁰¹ , and n801 are each in General Formula (6). R ¹ , R ² , R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁶⁰¹ , n601 have the same meanings and preferred ranges are also the same.

Although the specific example of the compound which has a repeating unit represented by General formula (3) or General formula (8) below is given, it is not necessarily limited to these. In the structural formulas of the following specific compounds, Me represents a methyl group.
In each of the following specific compounds, the terminal structure is a hydroxyl group.

  The compound having a repeating unit represented by the general formula (3) can be synthesized according to the following scheme.

The intermediate (C) (for example, synthesized by a method according to JP2011-148993) is reacted with the compound represented by the linking group (3), thereby repeating the compound represented by the general formula (3). A compound having a unit can be obtained. Note Intermediate (C), the linking group (3) and general formula ^{(3) R 1, R 3} , R 4, R 5, R 6, R 8, R 9, R 10, R 112, R 115 and in L ³⁰¹ is the same as or preferable to R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ and L ^{301 in} the general formula (3). The example is the same. A compound having a repeating unit represented by the general formula (8) can also be synthesized by the same method as described above. More specific synthesis methods are exemplified in the examples.

[Compound having a repeating unit represented by formula (4) or formula (9)]
The compound having a repeating unit represented by the following general formula (4) and general formula (9) will be described.

  General formula (4)

In the general formula (4), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁴ , R ⁸ , R ⁹ , R ¹⁰⁵ , R ¹⁰⁶ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, L ⁴⁰¹ represents a divalent linking group, and n ⁴⁰¹ represents 2 to 100.

  General formula (9)

In the general formula (9), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁴ , R ⁷ , R ⁹ , R ¹⁰⁵ , R ¹⁰⁶ , R ¹¹² and R ¹¹⁵ each independently represent a hydrogen atom or a substituent, L ⁹⁰¹ represents a divalent linking group, and n901 represents 2 to 100.

In general formula (4), R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁴⁰¹ , and n401 are each in general formula (1). R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ¹⁰¹ , and n101 are synonymous and the preferred ranges are also the same.
In general formula (9), R ¹ , R ² , R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁹⁰¹ , and n901 are each in general formula (6). R ¹ , R ² , R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁹ , R ¹⁰ , R ¹¹² , R ¹¹⁵ , L ⁶⁰¹ , n601 have the same meanings and preferred ranges are also the same.

In general formula (4) and general formula (9), R ¹⁰⁵ and R ¹⁰⁶ have the same meanings as R ¹⁰² and R ^{103 in} general formula (1) and general formula (6), respectively, and preferred ranges are also included. It is the same.

Although the specific example of a compound which has a repeating unit represented by General formula (4) and General formula (9) below is given, it is not necessarily limited to these. In the structural formulas of the following specific compounds, Me represents a methyl group.
In each of the following specific compounds, the terminal structure is an amino group.

  The compound having a repeating unit represented by the general formula (4) can be synthesized according to the following scheme.

By reacting the intermediate (A) (for example, synthesized by the method described in JP2011-148993A) with the compound represented by the linking group (4), the repeating unit represented by the general formula (4) is converted. The compound which has can be obtained. The intermediate (A), the linking group (4), and R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹⁰⁵ , R ¹⁰⁶ in the general formula (4), R ¹¹² , R ¹¹⁵ and L ⁴⁰¹ are R ¹ , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁸ , R ⁹ , R ¹⁰ , R ¹⁰⁵ , R ¹⁰⁶ , R ^{112 in} the general formula (4). , R ¹¹⁵ and L ⁴⁰¹ , and preferred examples are also the same. A compound having a repeating unit represented by the general formula (9) can also be synthesized by the same method as described above.

[Compound having a repeating unit represented by formula (5) or formula (10)]
The compound having a repeating unit represented by the following general formula (5) and general formula (10) will be described.

  General formula (5)

In general formula (5), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰⁷ and R ¹⁰⁸ each independently represent a hydrogen atom or Represents a substituent, L ⁵⁰¹ represents a divalent linking group, and n501 represents 2 to 100. X ⁵⁰¹ and X ⁵⁰² are each independently a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted aryl Carbonyl group, substituted or unsubstituted alkylsulfonyl group, substituted or unsubstituted arylsulfonyl group, substituted or unsubstituted alkoxycarbonyl group, substituted or unsubstituted aryloxycarbonyl group, substituted or unsubstituted monoalkylaminocarbonyl group Represents a substituted or unsubstituted dialkylaminocarbonyl group, a substituted or unsubstituted monoarylaminocarbonyl group, a substituted or unsubstituted diarylaminocarbonyl group, or a substituted or unsubstituted alkylarylaminocarbonyl group.

General formula (10)

In general formula (10), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ³ , R ⁷ , R ⁸ , R ¹⁰⁷ and R ¹⁰⁸ are Each independently represents a hydrogen atom or a substituent, L ¹⁰⁰¹ represents a divalent linking group, and n1001 represents 2 to 100. X ⁵⁰¹ and X ⁵⁰² are each independently a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted aryl Carbonyl group, substituted or unsubstituted alkylsulfonyl group, substituted or unsubstituted arylsulfonyl group, substituted or unsubstituted alkoxycarbonyl group, substituted or unsubstituted aryloxycarbonyl group, substituted or unsubstituted monoalkylaminocarbonyl group Represents a substituted or unsubstituted dialkylaminocarbonyl group, a substituted or unsubstituted monoarylaminocarbonyl group, a substituted or unsubstituted diarylaminocarbonyl group, or a substituted or unsubstituted alkylarylaminocarbonyl group.

In the general formula ^{(5), R 1, R} 3, R 5, R 6, R 8, R 10, L 501, n501 R 1 of each general formula ^{(1), R 3, R 5, R} 6, R ^8, is ^{R 10,} L ^101, synonymous with n101, the preferred range is also the same. In general formula (10), R ¹ , R ² , R ³ , R ⁵ , R ⁶ , R ⁷ , R ⁸ , R ¹⁰ , L ¹⁰⁰¹ , and n1001 are R ¹ , R ² , ^{R 3, R 5, R 6} , R 7, R 8, is ^{R 10,} L 101, synonymous with n101, the preferred range is also the same.

In the general formula ^(5), it has the same meanings as ^{R 107} and ^{R 108 R 102} and ^{R 103} each general formula (1), and preferred ranges are also the same. In general formula (10), R ¹⁰⁷ and R ¹⁰⁸ have the same meanings as R ¹⁰² and R ^{103 in} general formula (1), respectively, and the preferred ranges are also the same.

In general formula (5), X ⁵⁰¹ and X ⁵⁰² are each independently a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted arylcarbonyl group, a substituted or unsubstituted monoalkylaminocarbonyl group, a substituted or unsubstituted Are preferably a dialkylaminocarbonyl group, a substituted or unsubstituted monoarylaminocarbonyl group, a substituted or unsubstituted diarylaminocarbonyl group, or a substituted or unsubstituted alkylarylaminocarbonyl group. In general formula (10), X ⁵⁰¹ and X ⁵⁰² are each independently a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted arylcarbonyl group, a substituted or unsubstituted monoalkylaminocarbonyl group, substituted or unsubstituted. Are preferably a dialkylaminocarbonyl group, a substituted or unsubstituted monoarylaminocarbonyl group, a substituted or unsubstituted diarylaminocarbonyl group, or a substituted or unsubstituted alkylarylaminocarbonyl group.

Although the specific example of a compound which has a repeating unit represented by General formula (5) and General formula (10) below is given, it is not necessarily limited to these. In the structural formulas of the following specific compounds, Me represents a methyl group.
In each of the following specific compounds, the terminal structure is a sulfo group.

  The compound having a repeating unit represented by the general formula (5) can be synthesized according to the following scheme.

By reacting the intermediate (E) (for example, synthesized by the method described in JP2011-148893A) with the compound represented by the linking group (5), the repeating unit represented by the general formula (5) The compound which has can be obtained. Note Intermediate (E), the linking group (5) and general formula ^{(5) R 1, R 3} , R 5, R 6, R 8, R 10, R 107, R 108, X 501, X 502 and in L ⁵⁰¹ is the same as R ¹ , R ³ , R ⁵ , R ⁶ , R ⁸ , R ¹⁰ , R ¹⁰⁷ , R ¹⁰⁸ , X ⁵⁰¹ , X ⁵⁰² and L ^{501 in} the general formula (5), and is preferable. The example is the same. A compound having a repeating unit represented by the general formula (10) can also be synthesized by the same method as described above.

(Coloring composition)
The colored composition of the present invention contains at least one compound having a repeating unit represented by the above general formula (I). The coloring composition of the present invention can contain a medium, but when a solvent is used as the medium, it is particularly suitable as an ink for inkjet recording. The coloring composition of the present invention is obtained by dissolving and / or dispersing a compound having a repeating unit represented by the above general formula (I) in a lipophilic medium or an aqueous medium as a medium. Can be produced. Preferably, an aqueous medium is used. The coloring composition of the present invention includes an ink composition excluding a medium.

  In the present invention, the content of the compound of the present invention contained in the colored composition is determined by the type of substituent in the general formula (I) used and the type of solvent component used for producing the colored composition. However, it is preferable that the content of the compound having the repeating unit represented by the general formula (I) in the colored composition is 0.2 to 20% by mass with respect to the total mass of the colored composition. It is more preferable that 10 mass% is contained, and it is still more preferable that 2-6 mass% is contained.

  By setting the content of the compound having the repeating unit represented by the general formula (I) contained in the coloring composition to 1% by mass or more, the printing density of the ink on the recording medium when printed can be improved. And the required image density can be secured. In addition, when the total amount of the compound having the repeating unit represented by the general formula (I) contained in the coloring composition is 20% by mass or less, the discharging property of the coloring composition when used in the ink jet recording method. In addition, the ink jet nozzle can be prevented from being clogged.

  The coloring composition of the present invention may contain other additives as necessary within a range that does not impair the effects of the present invention. Examples of other additives include additives that can be used in ink jet recording inks described later.

[Ink for inkjet recording]
Next, the ink for inkjet recording of the present invention will be described.
The ink for inkjet recording of the present invention contains at least one compound having a repeating unit represented by the above general formula (I).
The ink for inkjet recording can be produced by dissolving and / or dispersing a compound having a repeating unit represented by the general formula (I) in an oleophilic medium or an aqueous medium. The ink for inkjet recording is preferably an ink using an aqueous medium.
The ink for ink jet recording can contain other additives as required within a range that does not impair the effects of the present invention. Other additives include, for example, anti-drying agents (wetting agents), anti-fading agents, emulsion stabilizers, penetration enhancers, ultraviolet absorbers, preservatives, anti-fungal agents, pH adjusters, surface tension adjusters, Well-known additives, such as a foaming agent, a viscosity modifier, a dispersing agent, a dispersion stabilizer, a rust preventive agent, a chelating agent, are mentioned. These various additives are directly added to the ink liquid in the case of water-soluble ink. When an oil-soluble dye is used in the form of a dispersion, it is generally added to the dispersion after the preparation of the dye dispersion, but it may be added to the oil phase or the aqueous phase at the time of preparation.

  Examples of the additive that can be used in the present invention include those described in JP-A-2013-133394, [0091] to [0101]. Regarding the usage form and usage method, the contents described in the above-mentioned patent documents can be preferably referred to.

  It is preferable to contain 0.2% by mass or more and 10% by mass or less of the compound having a repeating unit represented by the general formula (I) in 100% by mass of the inkjet recording ink of the present invention. % Or less is more preferable. In addition, the inkjet recording ink of the present invention may be used in combination with a compound having a repeating unit represented by the general formula (I) in combination with another dye. When using 2 or more types of pigment | dyes together, it is preferable that the sum total of content of a pigment | dye is the said range.

  The ink for inkjet recording of the present invention preferably has a viscosity of 30 mPa · s or less. The surface tension is preferably 25 mN / m or more and 70 mN / m or less. Viscosity and surface tension are various additives such as viscosity modifiers, surface tension modifiers, specific resistance modifiers, film modifiers, UV absorbers, antioxidants, antifading agents, antifungal agents, and rust inhibitors. It can be adjusted by adding a dispersant and a surfactant.

  The ink for inkjet recording of the present invention can be used not only for forming a single color image but also for forming a full color image. In particular, it is preferably used as an ink jet recording ink having a magenta color tone.

  The ink composition of the present invention can be used in recording methods such as printing, copying, marking, writing, drawing, stamping, and the like, and is particularly suitable for use in an inkjet recording method.

[Inkjet recording method]
The present invention also relates to an inkjet recording method for forming an image using the colored composition or the inkjet recording ink of the present invention.

[Inkjet printer cartridge and inkjet recording]
The ink cartridge for ink jet recording of the present invention is filled with the ink for ink jet recording of the present invention described above. Further, the ink-jet recorded matter of the present invention is obtained by forming a colored image on a recording material using the above-described ink for ink-jet recording of the present invention.

Hereinafter, a recording paper and a recording film used for ink jet printing using the ink of the present invention will be described.
The support in recording paper and recording film is made of chemical pulp such as LBKP and NBKP, mechanical pulp such as GP, PGW, RMP, TMP, CTMP, CMPMP, CGP, and waste paper pulp such as DIP. Additives such as known pigments, binders, sizing agents, fixing agents, cationic agents, paper strength enhancers, etc. can be mixed and manufactured using various devices such as long net paper machines and circular net paper machines. is there. In addition to these supports, either synthetic paper or plastic film sheets may be used. The thickness of the support is preferably 10 to 250 μm and the basis weight is preferably 10 to 250 g / m ² .

  Polymer latex may be added to the constituent layers (including the backcoat layer) of the ink jet recording paper and recording film. The polymer latex is used for the purpose of improving film physical properties such as dimensional stabilization, curling prevention, adhesion prevention, and film cracking prevention. The polymer latex is described in JP-A Nos. 62-245258, 62-136648, and 62-110066. When a polymer latex having a low glass transition temperature (40 ° C. or lower) is added to a layer containing a mordant, cracking and curling of the layer can be prevented. Also, curling can be prevented by adding a polymer latex having a high glass transition temperature to the backcoat layer.

  The ink of the present invention is not limited to an ink jet recording system, and is a known system, for example, a charge control system that discharges ink using electrostatic attraction, a drop-on-demand system (pressure) that uses the vibration pressure of a piezo element. Pulse method), acoustic ink jet method that converts electrical signal into acoustic beam and irradiates ink and uses ink to discharge ink, and thermal ink jet that heats ink to form bubbles and uses generated pressure Used for systems. Inkjet recording methods use a method of ejecting a large number of low-density inks called photo inks in a small volume, a method of improving image quality using a plurality of inks having substantially the same hue and different concentrations, and colorless and transparent inks. The method is included.

[Color filter]
The present invention also relates to a color filter containing a compound having a repeating unit represented by the above general formula (I).
As a method for forming a color filter, a pattern is first formed with a photoresist and then dyed, or disclosed in JP-A-4-163552, JP-A-4-128703, and JP-A-4-175653. Thus, there is a method of forming a pattern with a photoresist to which a dye is added. Any of these methods may be used as a method used when the compound of the present invention is introduced into a color filter. Preferred methods are described in JP-A-4-175753 and JP-A-6-35182. The positive resist composition comprising a thermosetting resin, a quinonediazide compound, a cross-linking agent, a dye and a solvent, and coating the substrate on the substrate, exposing through a mask, and developing the exposed portion. Then, a positive resist pattern is formed, the positive resist pattern is exposed on the entire surface, and then the exposed positive resist pattern is cured, and a color filter forming method can be mentioned. In addition, a black matrix can be formed according to a conventional method to obtain an RGB primary color system or Y, M, C complementary color system color filter. In the case of a color filter, the amount of the compound of the present invention is not limited, but is preferably 0.1 to 50% by mass.

  Regarding the thermosetting resin, quinonediazide compound, crosslinking agent, and solvent used in this case, and those used, those described in the above-mentioned patent documents can be preferably used.

[Color toner]
The present invention also relates to a color toner containing a compound having a repeating unit represented by the above general formula (I).
The content of the compound of the present invention in 100 parts by weight of the color toner is not particularly limited, but is preferably 0.1 parts by weight or more, more preferably 1 to 20 parts by weight, and 2 to 10 parts by weight. Is most preferred. As the binder resin for a color toner into which the compound of the present invention is introduced, all commonly used binders can be used. Examples thereof include styrene resin, acrylic resin, styrene / acrylic resin, and polyester resin.
Inorganic fine powders and organic fine particles may be externally added to the toner for the purpose of improving fluidity and controlling charging. Silica fine particles and titania fine particles whose surface is treated with an alkyl group-containing coupling agent or the like are preferably used. These have a number average primary particle size of preferably 10 to 500 nm, and more preferably 0.1 to 20% by mass in the toner.

  As the release agent, all conventionally used release agents can be used. Specific examples include olefins such as low molecular weight polypropylene, low molecular weight polyethylene, and ethylene-propylene copolymer, microcrystalline wax, carnauba wax, sazol wax, and paraffin wax. These addition amounts are preferably 1 to 5% by mass in the toner.

  The charge control agent may be added as necessary, but is preferably colorless from the viewpoint of color development. Examples thereof include those having a quaternary ammonium salt structure and those having a calixarene structure.

  As the carrier, either an uncoated carrier composed only of magnetic material particles such as iron and ferrite, or a resin-coated carrier whose magnetic material particle surface is coated with a resin or the like may be used. The average particle diameter of this carrier is preferably 30 to 150 μm in terms of volume average particle diameter.

  The image forming method to which the toner is applied is not particularly limited. For example, a method of forming a color image by repeatedly forming a color image on a photoconductor to form an image, or an image formed on a photoconductor For example, a method of sequentially transferring to an intermediate transfer member or the like and forming a color image on the intermediate transfer member or the like and then transferring it to an image forming member such as paper to form a color image, or the like.

[Transfer ink]
The present invention also relates to a transfer ink containing a compound having a repeating unit represented by the general formula (I).
As the transfer ink, a sublimation transfer ink is preferable. Ink for sublimation transfer generally contains a sublimable dye and water, but further, one that contains a water-soluble organic solvent is widely used to prevent clogging of the nozzles of the inkjet head and to ensure ejection stability. It has been. Examples of the water-soluble organic solvent include polyol compounds, glycol ethers, saccharides, and betaine compounds.

  The sublimation transfer ink of the present invention includes, as other components, a dispersant, an antiseptic / antifungal agent, a pH adjuster, a chelating reagent, an antirust agent, an ultraviolet absorber, an antifoaming agent, a surface tension adjusting agent, a polysiloxane compound, and the like. May be included. The dispersant is not particularly limited, but anionic dispersants such as formalin condensates of aromatic sulfonic acids, nonionic dispersants such as ethylene oxide adducts of phytosterols, ethylene oxide adducts of cholestanol, polyalkyl acrylate partial alkyls Polymer dispersing agents such as esters, polyalkylene polyamines, polyacrylates, styrene-acrylic acid copolymers, vinyl naphthalene-maleic acid copolymers, and the like can be used.

  As a method for creating a dyed product, the methods described in JP-A No. 2004-107647, JP-A No. 2009-202541, JP-A No. 2013-163716, JP-A No. 2014-1585, and JP-A No. 2014-80539 are described. Can be created by the method.

  With respect to the additives and solvents used in this case, the amounts used thereof, and the ink physical properties, those described in the above-mentioned patent documents or those used in the above-mentioned ink jet recording ink can be preferably used.

  Any material may be used as the material to be dyed. For example, a sheet-like material such as a fabric (hydrophobic fiber fabric, etc.), a resin (plastic) film, paper, or the like is preferably used. An object having a three-dimensional shape such as a rectangular parallelepiped shape may be used.

  EXAMPLES Hereinafter, although an Example is shown and this invention is demonstrated in detail, this invention is not limited to these Examples at all. Unless otherwise specified, “%” and “parts” in the examples are% by mass and parts by mass.

Synthesis Example 1 Synthesis of Exemplary Compound (1-1) Exemplary compound (1-1) can be synthesized, for example, according to the following scheme.

[Synthesis of Intermediate (E)]
3,6-dichloroxanthene derivative (abbreviation: DCSF, manufactured by Chugai Kasei Co., Ltd., product code 11ZDCSF) 20 g, DAMS (2,4-diaminomesitylene-6-sulfonic acid, manufactured by Wako Pure Chemical Industries) 46 g, diazabicycloundecene (DBU) 30 g and 6.7 g of zinc chloride were added to 250 g of ethylene glycol and reacted at 150 ° C. for 6 hours. The obtained reaction solution was cooled to room temperature, poured into 1 L of acetonitrile, and the obtained crystal was purified by column chromatography (filler: Sephadex LH-20 (Pharmacia), developing solvent: water / methanol), Body (E) was obtained. Yield 7.7 g, 19% yield, MS (m / z) = 836 ([M-1] ⁻ , 100%).

[Synthesis of Intermediate (F)]
20 g of intermediate (E) was dissolved in 120 mL of N, N-dimethylformamide (DMAc), and the internal temperature was cooled to 0 ° C. After 10 mL of phenyl chloroformate (manufactured by Tokyo Chemical Industry) was added dropwise while keeping the internal temperature at 5 ° C. or lower, the mixture was reacted at 0 to 5 ° C. for 90 minutes. The obtained reaction solution was poured into 1500 mL of ethyl acetate, the precipitated crystals were filtered off, dissolved in 200 mL of water, the pH was adjusted to 7 with dilute aqueous sodium hydroxide solution, and the resulting aqueous solution was subjected to column chromatography (filler : Sephadex LH-20 (Pharmacia), developing solvent: water / methanol). After concentrating with a rotary evaporator, it is dissolved again in water, and after passing through a strongly acidic ion exchange resin (Amberlite IR124-H (trade name), manufactured by Oregano Co., Ltd.), pH is adjusted using a dilute aqueous sodium hydroxide solution. Was subjected to dust filtration using a membrane filter, and then concentrated to dryness using a rotary evaporator to obtain an intermediate (F) green glossy solid. Yield 23 g, MS (m / z) = 1053 ([M-Na] ^- , 100%).

[Synthesis of Exemplary Compound (1-1)]
Intermediate (F) (3.0 g) was dissolved in N, N-dimethylformamide (DMAc) (30 mL), and the internal temperature was cooled to 0 ° C. A solution prepared by dissolving 0.17 g of ethylenediamine in 10 mL of N, N-dimethylformamide (DMAc) was added dropwise over 30 minutes, and then reacted at room temperature for 24 hours. The reaction solution was poured into 300 mL of isopropyl alcohol, and the precipitated crystals were separated by filtration and redissolved in 100 mL of water. After passing through a strongly acidic ion exchange resin (Amberlite IR-124H (trade name), manufactured by Organo), the pH was adjusted to 7.0 using a dilute aqueous sodium hydroxide solution. After removing the inorganic salt from the aqueous solution using a dialysis membrane (fractionated molecular weight 3500, Spectra / Por3 Dialysis Membrane (trade name, Spectrum = Laboratory)), the solution was concentrated to dryness and the metal of the exemplary compound (1-1) 2.5 g of glossy crystals were obtained. The repeating unit was estimated to be 5.6 from the molecular weight in terms of polystyrene by GPC measurement. Moreover, the absorption maximum wavelength of the UV-Vis spectrum of the dilute aqueous solution of exemplary compound (1-1) was 529 nm.

Synthesis Example 1 Synthesis of Exemplary Compound (1-16) Exemplary compound (1-16) can be synthesized, for example, according to the following scheme.

[Synthesis of Intermediate (B)]
23.0 g of the intermediate (A) (synthesized by the method described in paragraph No. 0065 on page 17 of JP 2011-148873 A) was added to 420 g of 10% fuming sulfuric acid and reacted at room temperature for 48 hours. . The reaction solution was poured into a large excess of ethyl acetate, and the precipitated crystals were filtered off. The crystals separated by filtration were dissolved in 500 mL of methanol, adjusted to pH 7 using a 28% sodium methoxide methanol solution, and the precipitated sodium sulfate was removed by filtration. The filtrate was concentrated using a rotary evaporator, and the resulting residue was purified by column chromatography (filler: Sephadex LH-20 (Pharmacia), developing solvent: methanol) to obtain an intermediate (B) crystal. It was. Yield 21.0 g, MS (m / z) = 793 ([M-2Na + H] ⁻ , 100%).

[Synthesis of Intermediate (C)]
20 g of intermediate (B) was dissolved in 120 mL of N, N-dimethylformamide (DMAc), and the internal temperature was cooled to 0 ° C. 10 mL of phenyl chlorocarbonate (manufactured by Tokyo Chemical Industry Co., Ltd.) was added dropwise while keeping the internal temperature at 5 ° C. or lower, and then reacted at 0 to 5 ° C. for 90 minutes. The obtained reaction solution was poured into 1500 mL of ethyl acetate, the precipitated crystals were filtered off, dissolved in 200 mL of water, the pH was adjusted to 7 with dilute aqueous sodium hydroxide solution, and the resulting aqueous solution was subjected to column chromatography (filler : Sephadex LH-20 (Pharmacia), developing solvent: water / methanol). After concentrating with a rotary evaporator, it is dissolved again in water, and after passing through a strongly acidic ion exchange resin (Amberlite IR124-H (trade name), manufactured by Oregano Co., Ltd.), pH is adjusted using a dilute aqueous sodium hydroxide solution. Was subjected to dust removal filtration using a membrane filter and then concentrated to dryness using a rotary evaporator to obtain an intermediate (C) green glossy solid. Yield 24 g, MS (m / z) = 1053 ([M-Na] ^- , 100%).

[Synthesis of Exemplary Compound (1-16)]
Intermediate (C) (3.0 g) was dissolved in N, N-dimethylformamide (DMAc) (30 mL), and the internal temperature was cooled to 0 ° C. A solution prepared by dissolving 0.32 g of 1,3-cyclohexanediamine in 10 mL of N, N-dimethylformamide (DMAc) was added dropwise over 30 minutes, and then reacted at room temperature for 24 hours. The reaction solution was poured into 300 mL of isopropyl alcohol, and the precipitated crystals were separated by filtration and redissolved in 100 mL of water. After passing through a strongly acidic ion exchange resin (Amberlite IR-124H (trade name), manufactured by Organo), the pH was adjusted to 7.0 using a dilute aqueous sodium hydroxide solution. After removing the inorganic salt from the aqueous solution using a dialysis membrane (fractionated molecular weight 3500, Spectra / Por3 Dialysis Membrane (trade name, Spectrum = Laboratory)), the solution was concentrated to dryness and the metal of the exemplified compound (1-16) 2.5 g of glossy crystals were obtained. The repeating unit was estimated to be 10.9 from the molecular weight in terms of polystyrene by GPC measurement. Moreover, the absorption maximum wavelength of the UV-Vis spectrum of the dilute aqueous solution of exemplary compound (1-16) was 532 nm.

(Synthesis example 2) Synthesis | combination of exemplary compound (2-4) Exemplary compound (2-4) is compoundable according to the following schemes, for example.

  The synthetic intermediate (B) 8.4 g of the exemplary compound (2-4) was dissolved in 100 mL of N, N-dimethylformamide (DMAc), and the internal temperature was cooled to 0 ° C. To this, 3.3 g of 1,5-naphthalenedisulfonic acid dichloride was added and reacted at room temperature for 24 hours. The reaction solution was poured into 1000 mL of isopropyl alcohol, and the precipitated crystals were separated by filtration and redissolved in 300 mL of water. After passing through a strongly acidic ion exchange resin (Amberlite IR-124H (trade name), manufactured by Organo), the pH was adjusted to 7.0 using a dilute aqueous sodium hydroxide solution. After removing the inorganic salt from the aqueous solution using a dialysis membrane (fractionated molecular weight 3500, Spectra / Por3 Dialysis Membrane (trade name, Spectrum = Laboratory)), it was concentrated to dryness and the metal of the exemplified compound (2-4) 8.4 g of glossy crystals were obtained. It was estimated that the repeating unit was 7.9 from the molecular weight in terms of polystyrene by GPC measurement. Moreover, the absorption maximum wavelength of the UV-Vis spectrum of the dilute aqueous solution of exemplary compound (2-4) was 534 nm.

(Synthesis example 3) Synthesis | combination of exemplary compound (3-3) Exemplary compound (3-3) is compoundable according to the following schemes, for example.

  8.4 g of intermediate (D) (synthesized according to the above synthesis method of intermediate (B)) was dissolved in 100 mL of N, N-dimethylformamide (DMAc), and the internal temperature was cooled to 0 ° C. 1,4-Cyclohexane dichloride 1.5g, sodium carbonate 2.2g, and sodium iodide 0.8g were added here, and it was made to react at internal temperature 60 degreeC for 24 hours. The reaction solution was poured into 1000 mL of isopropyl alcohol, and the precipitated crystals were separated by filtration and redissolved in 300 mL of water. After passing through a strongly acidic ion exchange resin (Amberlite IR-124H (trade name), manufactured by Organo), the pH was adjusted to 7.0 using a dilute aqueous sodium hydroxide solution. After removing the inorganic salt from the aqueous solution using a dialysis membrane (fractionated molecular weight 3500, Spectra / Por3 Dialyzation Membrane (trade name, Spectrum = Laboratory)), the solution was concentrated to dryness and the metal of the exemplified compound (3-3) 8.4 g of glossy crystals were obtained. The repeating unit was estimated to be 16.8 from the molecular weight in terms of polystyrene by GPC measurement. Moreover, the absorption maximum wavelength of the UV-Vis spectrum of the dilute aqueous solution of exemplary compound (3-3) was 533 nm.

  Other exemplary compounds can also be synthesized according to the above method.

[Example 1]
Deionized water was added to the following components to make 100 g, and the mixture was stirred for 1 hour while heating at 30 to 40 ° C. Thereafter, the pH was adjusted to 9 with a 10 mol / L sodium hydroxide aqueous solution, and the mixture was filtered under reduced pressure through a microfilter having an average pore size of 0.25 μm to prepare an ink jet recording ink 1 for magenta.

Inkjet recording ink 1 composition:
Dye (Exemplary Compound (1-1)) 3.50 g
Diethylene glycol 10.65g
Glycerin 14.70g
Diethylene glycol monobutyl ether 12.70g
Triethanolamine 0.65g
Olfin E1010 (Nissin Chemical Industry Co., Ltd.) 0.9g

[Examples 2-30, Comparative Examples 1-2]
Except that the dye was changed as shown in Tables 1 to 3 below, the same comparative compounds shown below as the inkjet recording inks 2 to 30 and the comparative inkjet recording ink, in the same manner as the preparation of the inkjet recording ink 1 1 to Inkjet recording inks using Comparative Compound 2 were prepared.

(Image recording and evaluation)
The following evaluation was performed on the inks for ink jet recording in each of the examples and comparative examples. The results are shown in Tables 1-3.
In Tables 1 to 3, ozone resistance, light resistance, and moisture resistance are as follows: each ink jet recording ink is loaded into an ink cartridge, and photo glossy paper (Canon photo) is printed with an ink jet printer (Canon Pixus iP8600, product name). Evaluation was made after an image was recorded on paper professional PT-201 (product name). The image consists of a monochromatic image pattern in which the density is changed stepwise so that the OD value measured by a reflection densitometer (trade name: X-Rite 310TR, manufactured by X-Rite) is 0.7 to 1.8, and a check pattern A pattern (a pattern in which squares having 1.5 mm squares having a density of 100% and 0% were alternately combined) was printed.

<Light resistance>
After measuring the image density Ci immediately after recording, the image was irradiated with xenon light (100,000 lux) for 7 days using a weather meter (Atlas C.165), and then the image density Cf was measured again. The dye residual ratio (Cf / Ci × 100%) was calculated from the image density before and after irradiation and evaluated. The image density was measured using a reflection densitometer (trade name: X-Rite 310TR, manufactured by X-Rite). The dye residual ratio was measured using an image portion having an initial image density of around 1.0.
The residual dye ratio was evaluated in three stages: A for 85% or more, B for 75% to less than 85%, and C for less than 75%.

<Ozone resistance>
While passing dry air through the Siemens type ozonizer's double glass tube, an AC voltage of 5 kV is applied, and this is used to form an image in a box where the ozone gas concentration is 5 ± 0.1 ppm, set at room temperature in a dark place. The photo glossy paper is allowed to stand for 3 days, and the image density before and after being left under ozone gas is measured using a reflection densitometer (trade name: X-Rite 310TR, manufactured by X-Rite), and after being left under the initial image density Ci and ozone gas. From the image density Cf ₂ , the dye residual ratio (Cf ₂ / Ci × 100%) was evaluated. The dye residual ratio was measured using an image portion having an initial image density of around 1.0. The ozone gas concentration in the box was set using an ozone gas monitor (model: OZG-EM-01) manufactured by APPLICS.
The dye residual ratio was evaluated in three stages: A for 80% or more, B for 70% or more and less than 80%, and C for less than 70%.

<Moisture resistance>
During ink-jet recording, a check pattern (a pattern in which squares having a 1.5 mm square with a density of 100% and 0% were alternately combined) was created to obtain a magenta-white check pattern print with high contrast. . After the printing, the check pattern printed matter dried for 24 hours is allowed to stand for 7 days under the condition of 80 ° C. and 70% RH, and the degree of bleeding from the colored portion to the white portion is visually evaluated. Evaluation was made in three stages, where B was slightly blurred and C was blurred.

<Filterability>
When 100 g of ink for inkjet recording was filtered with a microfilter having an average pore diameter of 0.25 μm and a diameter of 47 mm at a degree of vacuum of 0.1 Pa, the required filtration time was measured to evaluate the filterability. Evaluation was made in three stages, with A being less than 30 seconds, B being 30 seconds to less than 3 minutes, and C being 3 minutes or more.

As is clear from the results of Tables 1 to 3, the inks of Examples using the compounds of the present invention were excellent in all of light resistance, ozone resistance, moisture resistance and filterability.
Comparative compound 1: Exemplified compound (8) of JP2011-148973A
Me represents a methyl group, and Ac represents an acetyl group.

Comparative compound 2: Example compound (1-2) of International Publication No. 2013/031838

[Example 31] Preparation and evaluation of color filter (Preparation of positive resist composition)
Using 3.4 parts by mass of a cresol novolak resin (polystyrene equivalent mass average molecular weight 4300) obtained from a mixture of m-cresol / p-cresol / formaldehyde (reaction molar ratio = 5/5 / 7.5), the following phenol compound Produced o-naphthoquinonediazide-5-sulfonic acid ester (average two hydroxyl groups are esterified) 1.8 parts by mass, hexamethoxymethylolated melamine 0.8 parts by mass, ethyl lactate 20 parts by mass, and examples 1 part by mass of the compound (4-5) was mixed to obtain a positive resist composition.

(Production and evaluation of color filter)
The obtained positive resist composition was spin-coated on a silicon wafer, and then the solvent was evaporated. Next, the silicon wafer was exposed through a mask to decompose o-naphthoquinonediazide-5-sulfonic acid ester. Thereafter, heating was performed at 100 ° C., and then the exposed portion was removed by alkali development to obtain a positive colored pattern having a resolution of 0.8 μm. After the entire surface was exposed, it was heated at 150 ° C. for 15 minutes to obtain a magenta complementary color filter. The exposure was performed using an i-line exposure stepper HITACHILD-5010-i (trade name, manufactured by Hitachi, Ltd., NA = 0.40).
The developer used was SOPD or SOPD-B (both trade names, manufactured by Sumitomo Chemical Co., Ltd.).
The obtained color filter had good color purity, high transparency, and good performance.

[Example 32] Preparation and evaluation of color toner (preparation of color toner)
3 parts by mass of the exemplary compound (4-5) which is the xanthene dye of the present invention, 100 parts by mass of a resin for toner [styrene-acrylic acid ester copolymer; Hymer TB-1000F (trade name, manufactured by Sanyo Chemical Co., Ltd.)] After being mixed and pulverized with a ball mill, the mixture was heated and mixed at 150 ° C., cooled, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet type pulverizer. Further, classification was performed to select particles having a particle diameter of 1 to 20 μm to obtain toner.

(Evaluation of color toner)
To 10 parts by mass of the toner, 900 parts by mass of carrier iron powder (EFV250 / 400, trade name, manufactured by Nippon Iron Powder Co., Ltd.) was uniformly mixed to obtain a developer. When this developer is used for copying with a dry plain paper electrophotographic copying machine (NP-5000, trade name, manufactured by Canon Inc.), it has excellent spectral characteristics and exhibits excellent properties as a toner. I understood.

[Example 33] Preparation and evaluation of sublimation transfer ink (preparation of sublimation transfer ink)
A mixture of 4.0 g of exemplary compound (4-5), 2.0 g of a formalin condensate of β-naphthalenesulfonic acid as an anionic dispersant, and 40.0 g of ion-exchanged water was added to 0.2 mm diameter glass beads. Was subjected to a dispersion treatment for about 15 hours under cooling in a sand mill. After dispersion treatment, ion-exchanged water is added for dilution, and then the dispersion is filtered through glass fiber filter paper GC-50 (Toyo Filter Paper Co., Ltd., filter pore size 0.5 μm) to remove components with large particle size. An aqueous dispersion was obtained.
Next, 46.0 g of the aqueous dispersion obtained as described above, 20.0 g of glycerin, 3.0 g of triethylene glycol monomethyl ether, and 31.0 g of ion-exchanged water are mixed to perform sublimation transfer. Ink was obtained.

(Evaluation of sublimation transfer ink)
The sublimation transfer ink is put into an ink jet apparatus, a paper having an ink receiving layer made of a material containing silica is prepared as an intermediate transfer medium, and 1440 × 720 dpi (dot) is provided on the ink receiving layer of the intermediate transfer medium. per inch), the ink for sublimation transfer was ejected at 100% duty, 50% duty, 5% duty. “Duty” is defined by the following formula (A) and indicates a unit of the calculated value D.
D = {(actual printing dot number) / (vertical resolution × horizontal resolution)} × 100 (duty) (A)
Thereafter, the ink receiving layer of the intermediate transfer medium provided with the sublimation transfer ink is brought into intimate contact with a fabric (a material to be dyed) made of polyester fibers, and in this state, a heat press TP-608M manufactured by Taiyo Seiki Co., Ltd. Was used for heating and sublimation transfer at 200 ° C. for 60 seconds.
The obtained fabric did not lose its color even after washing with water, and a dyed product dyed magenta was obtained.

  The compound of the present invention can be suitably used for a colored composition and an ink for inkjet recording, and is excellent in filterability at the time of ink preparation. The coloring composition and the ink for inkjet recording of the present invention can form an image excellent in light resistance, ozone resistance, and moisture resistance. In addition, according to the present invention, there are provided an ink jet recording method, an ink jet printer cartridge, and an ink jet recorded matter using the above ink jet recording ink. Furthermore, a color filter, a color toner, and a transfer ink containing the above compound are provided.

Although the present invention has been described in detail and with reference to specific embodiments, it will be apparent to those skilled in the art that various changes and modifications can be made without departing from the spirit and scope of the invention.
The present application includes a Japanese patent application filed on March 27, 2014 (Japanese Patent Application No. 2014-0667259), a Japanese patent application filed on August 27, 2014 (Japanese Patent Application No. 2014-173230), and an application filed on February 26, 2015. Japanese patent application (Japanese Patent Application No. 2015-036851), the contents of which are incorporated herein by reference.

Claims (13)

It has a repeating unit represented by the following general formula (1), (2), (3), (4), (5), (6), (7), (8), (9) or (10) Compound.
General formula (1)

In general formula (1), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , and R ^{10 4} represents a hydrogen atom or a substituent ^{independently, R 4, R 9, R} 112 and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ¹⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n101 represents 2 to 100.
General formula (2)

In the general formula ^{(2), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, a hydrogen atom or a substituent each independently ^{R 3} and R ^8, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ²⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n201 represents 2 to 100.
General formula (3)

In the general formula ^{(3), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, a hydrogen atom or a substituent each independently ^{R 3} and R ^8, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ³⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n301 represents 2 to 100.
General formula (4)

In general formula (4), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represents a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰⁵ and R ^{10 6} are each independently hydrogen. represents an atom or a substituent, ^{R 4,} R ^{9, R 112} and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and ^{R 112} and ^{R 115} is Represents a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁴⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n401 represents 2 to 100.
General formula (5)

In general formula (5), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ³ , R ⁸ , R ¹⁰⁷ and R ¹⁰⁸ each independently represent a hydrogen atom or L ⁵⁰¹ represents an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and at least one group selected from a combination of two or more selected from these substituted An arylene group or an unsubstituted group substituted with at least one group selected from an alkylene group or an unsubstituted alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and combinations thereof Arylene groups, alkyl groups, aralkyl groups, alkenyl groups, alkynyl groups, aryl groups, sulfo groups, and these An alkenylene group or an unsubstituted alkenylene group substituted with at least one group selected from a group consisting of a combination, or a divalent linking group formed by combining two or more selected from these groups, n501 represents 2 to 100 Represent. X ⁵⁰¹ and X ⁵⁰² represent a monoarylaminocarbonyl group substituted with SO ₃ Na .
General formula (6)

In General Formula (6), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁷ , R ¹⁰¹ , R ¹⁰² , R ¹⁰³ , and R ^{10 4} represents a hydrogen atom or a substituent ^{independently, R 4, R 9, R} 112 and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁶⁰¹ represents an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n601 represents 2 to 100.
General formula (7)

In the general formula ^{(7), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, ^{R 2} and R ⁷ each independently represent a hydrogen atom or a substituent radical, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁷⁰¹ represents an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an alkylene group or an unsubstituted group substituted by at least one group selected from a combination of two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n701 represents 2 to 100.
General formula (8)

In the general formula ^{(8), R 1, R} 5, R 6 and ^{R 10} each independently represent a substituted or unsubstituted alkyl group, ^{R 2} and R ⁷ each independently represent a hydrogen atom or a substituent radical, R ⁴ , R ⁹ , R ¹¹² and R ¹¹⁵ represent a hydrogen atom or SO ₃ Na, R ⁴ and R ⁹ represent SO ₃ Na and R ¹¹² and R ¹¹⁵ represent a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁸⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n801 represents 2 to 100.
General formula (9)

In general formula (9), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ⁷ , R ¹⁰⁵ and R ^{10 6} are each independently hydrogen. represents an atom or a substituent, ^{R 4,} R ^{9, R 112} and ^{R 115} are those that represent a hydrogen atom or _SO 3 Na, ^{R 4} and ^{R 9} represents _SO 3 Na, and ^{R 112} and ^{R 115} is Represents a hydrogen atom, or R ⁴ and R ⁹ represent a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na. L ⁹⁰¹ is an alkylene group or an unsubstituted group substituted with at least one group selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these An alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and an arylene group or an unsubstituted arylene group substituted with at least one group selected from a combination thereof. At least one group selected from a group consisting of a group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof, or a substituted alkenylene group or an unsubstituted alkenylene group, or 2 selected from these Divalent linkage consisting of more than one species Represents a group, and n901 represents 2 to 100.
General formula (10)

In general formula (10), R ¹ , R ⁵ , R ⁶ and R ¹⁰ each independently represent a substituted or unsubstituted alkyl group, and R ² , R ³ , R ⁷ , R ⁸ , R ¹⁰⁷ and R ¹⁰⁸ are Each independently represents a hydrogen atom or a substituent, and L ¹⁰⁰¹ is at least selected from an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a group formed by combining two or more selected from these. At least one group selected from the group consisting of an alkylene group substituted by one group or an unsubstituted alkylene group, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a sulfo group, and a combination thereof is substituted. Arylene group or unsubstituted arylene group, alkyl group, aralkyl group, alkenyl group, alkynyl group, aryl group, An alkenylene group or an unsubstituted alkenylene group substituted with at least one group selected from a group consisting of a fo group and a combination thereof, or a divalent linking group formed by combining two or more selected from these groups; n1001 represents 2-100. X ⁵⁰¹ and X ⁵⁰² are each independently a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted aryl Carbonyl group, substituted or unsubstituted alkylsulfonyl group, substituted or unsubstituted arylsulfonyl group, substituted or unsubstituted alkoxycarbonyl group, substituted or unsubstituted aryloxycarbonyl group, substituted or unsubstituted monoalkylaminocarbonyl group Represents a substituted or unsubstituted dialkylaminocarbonyl group, a substituted or unsubstituted monoarylaminocarbonyl group, a substituted or unsubstituted diarylaminocarbonyl group, or a substituted or unsubstituted alkylarylaminocarbonyl group.
However, L ¹⁰⁰¹ represents a divalent linking group represented by the following formula (LL4), or X ⁵⁰¹ and X ⁵⁰² represent a monoarylaminocarbonyl group substituted with CO ₂ Na and OH.

A compound having a repeating unit represented by the general formula (1), (2), (3), (4), (6), (7), (8) or (9), wherein R ⁴ and The compound according to claim 1, wherein R ⁹ represents a hydrogen atom, and R ¹¹² and R ¹¹⁵ represent SO ₃ Na . A compound having a repeating unit represented by the general formula (1), (2), (3), (4), (5) or (10), wherein R ³ and R ⁸ are each independently substituted or 2. A compound according to claim 1, which represents an unsubstituted alkyl group. A compound having a repeating unit represented by the general formula (1), (2), (3) or (4), wherein R ³ and R ⁸ are each independently a hydrogen atom, a substituted or unsubstituted alkyl group. Substituted or unsubstituted aryl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted aryloxy group, substituted or unsubstituted amino group, substituted or unsubstituted acylamino group, substituted or unsubstituted alkoxycarbonylamino A group, a substituted or unsubstituted alkylsulfonylamino group, a substituted or unsubstituted arylsulfonylamino group, a substituted or unsubstituted alkylureido group, a substituted or unsubstituted arylureido group, a sulfo group, a carboxyl group, or a halogen atom. The compound according to any one of claims 1 to 3. Formula (1), (2), (3) or a compound having a repeating unit represented by (4), ^{R 4} and ^{R 9} to display the SO ₃ Na, and ^{R 112} and ^{R 115} There compound of claim 1 to display the hydrogen atom.   The coloring composition containing the compound of any one of Claims 1-5.   Ink for inkjet recording containing the compound of any one of Claims 1-5.   An ink jet recording method using the ink for ink jet recording according to claim 7.   An ink jet printer cartridge filled with the ink for ink jet recording according to claim 7.   An ink-jet recorded matter in which a colored image is formed on a recording material using the ink for ink-jet recording according to claim 7.   The color filter containing the compound of any one of Claims 1-5.   A color toner containing the compound according to claim 1.   A transfer ink containing the compound according to claim 1.